Temperatura Frac.

Masa Etanol Temperatura Entalpía (BTU/lbm) Entalpía (kJ/kg)

Frac. Masa
°C °F wL wV °C °F Líquido Vapor Líquido Vapor
100.00 212.00 0.0000 0.0000 100.00 212.00 0.0000 180.10 1150.00 418.90 2674.82
98.10 208.58 0.0200 0.1920 91.80 197.24 0.1000 159.80 1082.00 371.68 2516.66
95.20 203.36 0.0500 0.3770 84.70 184.46 0.3000 135.00 943.00 314.00 2193.35
91.80 197.24 0.1000 0.5270 82.00 179.60 0.5000 122.90 804.00 285.86 1870.05
87.30 189.14 0.2000 0.6560 80.10 176.18 0.7000 111.10 664.00 258.41 1544.42
84.70 184.46 0.3000 0.7130 78.30 172.94 0.9000 96.60 526.00 224.68 1223.44
83.20 181.76 0.4000 0.7460 78.30 172.94 1.0000 89.00 457.50 207.01 1064.11
82.00 179.60 0.5000 0.7710
81.00 177.80 0.6000 0.7940
80.10 176.18 0.7000 0.8220 x y
79.10 174.38 0.8000 0.8580 0.0000 0.0000
78.30 172.94 0.9000 0.9120 1.0000 1.0000
78.20 172.76 0.9400 0.9420
78.10 172.58 0.9600 0.9590
78.20 172.76 0.9800 0.9780
78.30 172.94 1.0000 1.0000
 Temperatura Frac. Mol Etanol
°C °F x y
100.00 212.00 0.0000 0.0000
98.10 208.58 0.0496 0.3778
95.20 203.36 0.1186 0.6073
91.80 197.24 0.2212 0.7401
87.30 189.14 0.3898 0.8297
84.70 184.46 0.5227 0.8639
83.20 181.76 0.6301 0.8824
82.00 179.60 0.7188 0.8959
81.00 177.80 0.7931 0.9078
80.10 176.18 0.8564 0.9219
79.10 174.38 0.9109 0.9392
78.30 172.94 0.9583 0.9636
78.20 172.76 0.9756 0.9765
78.10 172.58 0.9840 0.9835
78.20 172.76 0.9921 0.9913
78.30 172.94 1.0000 1.0000
 Diagrama Ebullición Sist. Etanol-Agua, P = 101.325 kPa

102.00
f(x)
f(x)==-21.1766202385
80.9058942085 ln(x)
x^-0.2376588699
+ 80.7826586346
101.00 R²R²==0.8143435696
0.7960309254

100.00
f(x) f(x) = - 17.4778592649x^3
= - 44.1013585348x^4 + 41.4797936398x^2
+ 20.5218030799x^3 - 46.1735815227x
+ 2.4092500022x^2 + 100.1271325576
- 6.6426436484x + 100.0035853989
99.00R² =R² = 0.9995552444
0.9985695667

98.00

97.00

96.00

95.00

94.00

93.00

92.00

91.00

90.00
T, Temperatura

89.00

88.00

87.00

86.00

85.00

84.00

83.00

82.00

81.00

80.00

79.00

78.00

77.00

76.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

x, y, fracción mol de etanol en la fase líquida, y en la fase vapor

 Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
1.00

0.95

0.90

0.85

0.80

0.75

0.70

0.65
wy, fracción masa del etanol en el vapor

0.60

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
10

30

65

85
00
05

15
20
25

35
40
45
50
55
60

70
75
80

90
95
00
0.
0.

0.

0.

0.

0.
0.
0.

0.
0.

0.
0.
0.

0.
0.

0.
0.
0.

0.
0.
1.

wx, Fracción masa del etanol en el líquido

C.Eq. Diagonal
RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA
Se desea destilar una mezcla líquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presión.
La alimentación es de 100 kg mol/h y está en estado líquido, a una temperatura de 40°C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relación de reflujo a usar en este proceso es de 3:1. La capacidad calorífica promedio de la alimentación es de: y el
calor latente promedio es de kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Número de platos y Plato de alimentación.

Datos Inciales del problema

F* = 100.00 kg mol/h

xF = 0.2500 Kg mol EtOH/kg mol tot

PF = 101.33 kPa Destilado

TF = 40.00 °C D* = 24.69
yV = 0.8600 Kg mol EtOH/kg mol tot yD = 0.8600
xL = 0.0500 Kg mol EtOH/kg mol tot TD = 87.80
R= 3.00 PD = 101.33
Cp*F,prom = 20.84 Kcal/ kg mol K H*D = 12385.08
DH*Vap = 10246.02 Kcal/ kg mol (1- yD) = 0.14000
D* yD = 21.23
Alimentación D*(1-yD) = 3.46
F* = 100.00 kgmol/h Cp*D,L = 27.28
xF = 0.2500 frac mol EtOH DH*Vap = 9990.15
TF = 40.00 °C L* = 74.07
PF = 101.33 kPa

H*F = 805.12 Kcal/Kg mol D* H*D = 305804.39

(1- xF) = 0.7500 frac mol agua

F* xF = 25.00 kgmol EtOH/h

F* (1-xF) = 75.00 kgmol agua/h

Cp*F = 20.13 Kcal/Kg mol K

26.479
18.011 Fondo
F* H*F = 80511.93 Kcal/h L* = 75.31
xL = 0.0500
TL = 87.80
Q = -F* H*F + L* H*L + V* H*V PL = 101.33
368684.29 H*L = 1633.16
(1- xL) = 0.95000
 SOLUCION DEL PROBLEMA L* xL = 3.77
1. Cálculo del valor TB : 90.80 °C L* (1-xL) = 71.54
2. Cálculo del valor H*F,Lsat: 1827.621 Kcal/kg mol Cp*L = 18.60
3. Cálculo del valor q : 1.121 Adimens.

4. Pendiente de q : 9.233 Adimens. L* H*L = 143391.83

5. Pendiente de L.Op. Enriquec.: 0.7500
6. Interc. de L.Op. Enriquec.: 0.2150

Eje X Eje Y
7. Trazado de L.Op. Enriquec.: 0.860 0.860
0.200 0.365
Eje X Eje Y
8. Trazado de Linea "q" : 0.250 0.250
0.275 0.481
Eje X Eje Y
9. Calc. Interc. L.Op.E. y L. "q" : 0.2680 0.4160

Eje X Eje Y
9. Trazado de L.Op. Empobrecim. : 0.050 0.050
0.268 0.416

Eje X Eje Y
10. Trazado de las etapas : 0.860 0.860
0.508 0.860
0.508 0.595
0.114 0.595
0.114 0.159
0.020 0.159
0.020 0.020

11. Cálculo del V* y de L* : 24.691 kgmol/h

75.309 kgmol/h

Kcal/Kg mol K
T P°EtOH (kPa) P°H2O (kPa) a CpEtOH (l) CpH2O (l) CpEtOH (v) CpH2O (v)
0.00 1.545 0.609 2.537 25.378 17.965 7.183 7.682
2.00 1.783 0.704 2.533 25.453 17.970 7.178 7.688
4.00 2.052 0.811 2.529 25.534 17.974 7.173 7.693
6.00 2.356 0.933 2.524 25.620 17.979 7.168 7.699
8.00 2.698 1.071 2.520 25.711 17.984 7.162 7.705
10.00 3.083 1.226 2.515 25.808 17.988 7.157 7.711
12.00 3.515 1.401 2.509 25.911 17.993 7.151 7.716
14.00 3.999 1.597 2.504 26.019 17.997 7.145 7.722
16.00 4.539 1.817 2.498 26.133 18.002 7.139 7.728
18.00 5.141 2.063 2.493 26.252 18.006 7.133 7.734
20.00 5.812 2.337 2.487 26.377 18.011 7.127 7.739
22.00 6.557 2.643 2.481 26.508 18.016 7.121 7.745
24.00 7.382 2.983 2.475 26.644 18.020 7.115 7.751
26.00 8.296 3.361 2.468 26.785 18.025 7.109 7.757
28.00 9.306 3.780 2.462 26.932 18.029 7.102 7.763
30.00 10.420 4.243 2.456 27.085 18.034 7.096 7.768
32.00 11.646 4.755 2.449 27.243 18.038 7.089 7.774
34.00 12.994 5.320 2.442 27.407 18.043 7.082 7.780
36.00 14.473 5.942 2.436 27.576 18.047 7.076 7.786
38.00 16.094 6.626 2.429 27.751 18.052 7.069 7.791
40.00 17.868 7.377 2.422 27.931 18.057 7.062 7.797
42.00 19.806 8.200 2.415 28.117 18.061 7.055 7.803
44.00 21.921 9.102 2.408 28.309 18.066 7.048 7.809
46.00 24.224 10.087 2.401 28.506 18.070 7.040 7.814
48.00 26.730 11.163 2.394 28.708 18.075 7.033 7.820
50.00 29.453 12.337 2.387 28.916 18.079 7.025 7.826
52.00 32.407 13.614 2.380 29.130 18.084 7.018 7.832
54.00 35.608 15.004 2.373 29.349 18.088 7.010 7.837
56.00 39.073 16.513 2.366 29.574 18.093 7.002 7.843
58.00 42.818 18.150 2.359 29.804 18.097 6.995 7.849
60.00 46.861 19.924 2.352 30.040 18.102 6.987 7.855
62.00 51.222 21.844 2.345 30.282 18.106 6.979 7.861
64.00 55.918 23.920 2.338 30.528 18.111 6.970 7.866
66.00 60.971 26.161 2.331 30.781 18.115 6.962 7.872
68.00 66.401 28.578 2.323 31.039 18.120 6.954 7.878
70.00 72.230 31.182 2.316 31.303 18.124 6.945 7.884
72.00 78.482 33.986 2.309 31.572 18.129 6.937 7.889
74.00 85.180 37.000 2.302 31.847 18.133 6.928 7.895
76.00 92.347 40.237 2.295 32.127 18.138 6.920 7.901
78.00 100.010 43.710 2.288 32.413 18.142 6.911 7.907
80.00 108.195 47.434 2.281 32.704 18.147 6.902 7.912
82.00 116.929 51.422 2.274 33.001 18.151 6.893 7.918
84.00 126.240 55.688 2.267 33.303 18.156 6.884 7.924
86.00 136.158 60.249 2.260 33.612 18.160 6.875 7.930
88.00 146.711 65.119 2.253 33.925 18.165 6.865 7.935
90.00 157.932 70.317 2.246 34.244 18.169 6.856 7.941
92.00 169.851 75.857 2.239 34.569 18.174 6.847 7.947
94.00 182.503 81.759 2.232 34.899 18.178 6.837 7.953
2.394 29.139 18.072 7.027 7.817
esión.
l 25% mol de etanol.
n el 5% mol de etanol.
ntación es de: y el

Destilado
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h

kgmol agua/h

Kcal/Kg mol K
28.777 9921.665
Kcal/Kg mol
18.065 10410.868
Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h

kgmol agua/h

Kcal/Kg mol K

Kcal/h

DHVap,EtOH DHVap,H2O
10714.866 10918.897
10681.717 10896.973 Constantes de Antoine (T °C, P mmHg)
10648.395 10874.975 P° = 10^(A- (B/(C+T)))
10614.899 10852.903 Compuesto A B C
10581.226 10830.755 Etanol 8.04494 1554.3 222.65
10547.373 10808.532 Agua 8.10765 1750.286 235
10513.338 10786.233
10479.118 10763.856
10444.712 10741.402 Constantes de Cp (liq) (T °K)

10410.115 10718.869 (Cp/R) = A + BT + CT 2

10375.325 10696.257 Compuesto A B C

10340.340 10673.565 Etanol 33.866 -1.73E-01 3.49E-04
10305.157 10650.792 Agua 8.712 1.26E-03 -1.80E-07
10269.772 10627.938
10234.183 10605.002 Constantes de Cp (vap) (T °K)
10198.386 10581.982 (Cp/R) = A + BT + CT2
10162.379 10558.879 Compuesto A B C
10126.158 10535.691 Etanol 3.518 2.00E-03 -6.02E-06
10089.720 10512.418 Agua 3.47 1.45E-03 0.00E+00
10053.061 10489.059
10016.177 10465.613 D Hvap (T °K)
9979.066 10442.079 D Hv,2 = D Hv,1 ((1-Tr2)/(1-Tr1))0.375
9941.724 10418.456 Compuesto Tc Tb D Hvap,Tb
9904.146 10394.743 Etanol 516.20 351.50 9260.00
9866.330 10370.940 Agua 647.3 373.15 9717.00
9828.270 10347.046
9789.962 10323.059
9751.404 10298.979
9712.589 10274.805
9673.515 10250.535
9634.175 10226.170
9594.566 10201.707
9554.682 10177.147
9514.520 10152.487
9474.072 10127.726
9433.335 10102.865
9392.302 10077.901
9350.968 10052.833
9309.328 10027.661
9267.374 10002.384
9225.102 9976.999
9182.505 9951.506
9139.575 9925.904
9096.307 9900.191
9052.693 9874.367
9008.726 9848.430
8964.399 9822.378
8919.703 9796.210
9861.828 10374.085
 Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

1.00

0.90

0.80

0.70
y, fracción mol del etanol en el vapor

0.60

0.50

0.40

0.30

0.20

0.10

0.00
00
0.

x, Fracción mol del etanol en el líquido

Diagonal L.Op.Enr. q L.Op.Emp Etapas
RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA
Se desea destilar una mezcla líquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presión.
La alimentación es de 100 kg mol/h y está en estado líquido, a una temperatura de 40°C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relación de reflujo a usar en este proceso es de 3:1. La capacidad calorífica promedio de la alimentación es de: y el
calor latente promedio es de kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Número de platos y Plato de alimentación.

Datos Inciales del problema

F* = 100.00 kg mol/h

xF = 0.1500 Kg mol EtOH/kg mol tot

PF = 101.33 kPa Destilado

TF = 60.00 °C D* = 11.76
yV = 0.9000 Kg mol EtOH/kg mol tot yD = 0.9000
xL = 0.0500 Kg mol EtOH/kg mol tot TD = 87.80
R= 3.00 PD = 101.33
Cp*F,prom = 19.73 Kcal/ kg mol K H*D = 12403.13
DH*Vap = 10297.25 Kcal/ kg mol (1- yD) = 0.10000
D* yD = 10.59
Alimentación D*(1-yD) = 1.18
F* = 100.00 kgmol/h Cp*D,L = 27.71
xF = 0.1500 frac mol EtOH DH*Vap = 9970.59
TF = 60.00 °C L* = 35.29
PF = 101.33 kPa

H*F = 1156.87 Kcal/Kg mol D* H*D = 145919.15

(1- xF) = 0.8500 frac mol agua

F* xF = 15.00 kgmol EtOH/h

F* (1-xF) = 85.00 kgmol agua/h

Cp*F = 19.28 Kcal/Kg mol K

26.479
18.011 Fondo
TB,F = 94.05 °C L* = 88.24
F* H*F = 115687.09 Kcal/h xL = 0.0500
TL = 87.80
Q = -F* H*F + L* H*L + V* H*V PL = 101.33
173623.89 H*L = 1633.16
(1- xL) = 0.95000
SOLUCION DEL PROBLEMA L* xL = 4.41
 1. Cálculo del valor TB : 90.80 °C L* (1-xL) = 83.82
2. Cálculo del valor H*F,Lsat: 1750.731 Kcal/kg mol Cp*L = 18.60
3. Cálculo del valor q : 1.069 Adimens.

4. Pendiente de q : 15.391 Adimens. L* H*L = 143391.83

5. Pendiente de L.Op. Enriquec.: 0.7500
6. Interc. de L.Op. Enriquec.: 0.2250

Eje X Eje Y
7. Trazado de L.Op. Enriquec.: 0.900 0.900
0.100 0.300

Eje X Eje Y
8. Trazado de Linea "q" : 0.150 0.150
0.165 0.381

Eje X Eje Y
9. Calc. Interc. L.Op.E. y L. "q" : 0.1628 0.3471

Eje X Eje Y
9. Trazado de L.Op. Empobrecim. : 0.050 0.050
0.163 0.347

Eje X Eje Y
10. Trazado de las etapas : 0.900 0.900
0.740 0.900
0.740 0.778
0.280 0.778
0.280 0.435
0.062 0.435
0.062 0.080
0.010 0.080
0.010 0.010

11. Cálculo del V* y de L* : 11.765 kgmol/h

88.235 kgmol/h

Kcal/Kg mol K
T P°EtOH (kPa) P°H2O (kPa) a CpEtOH (l) CpH2O (l) CpEtOH (v) CpH2O (v)
0.00 1.545 0.609 2.537 25.378 17.965 7.183 7.682
2.00 1.783 0.704 2.533 25.453 17.970 7.178 7.688
4.00 2.052 0.811 2.529 25.534 17.974 7.173 7.693
6.00 2.356 0.933 2.524 25.620 17.979 7.168 7.699
8.00 2.698 1.071 2.520 25.711 17.984 7.162 7.705
10.00 3.083 1.226 2.515 25.808 17.988 7.157 7.711
12.00 3.515 1.401 2.509 25.911 17.993 7.151 7.716
14.00 3.999 1.597 2.504 26.019 17.997 7.145 7.722
16.00 4.539 1.817 2.498 26.133 18.002 7.139 7.728
18.00 5.141 2.063 2.493 26.252 18.006 7.133 7.734
20.00 5.812 2.337 2.487 26.377 18.011 7.127 7.739
22.00 6.557 2.643 2.481 26.508 18.016 7.121 7.745
24.00 7.382 2.983 2.475 26.644 18.020 7.115 7.751
26.00 8.296 3.361 2.468 26.785 18.025 7.109 7.757
28.00 9.306 3.780 2.462 26.932 18.029 7.102 7.763
30.00 10.420 4.243 2.456 27.085 18.034 7.096 7.768
32.00 11.646 4.755 2.449 27.243 18.038 7.089 7.774
34.00 12.994 5.320 2.442 27.407 18.043 7.082 7.780
36.00 14.473 5.942 2.436 27.576 18.047 7.076 7.786
38.00 16.094 6.626 2.429 27.751 18.052 7.069 7.791
40.00 17.868 7.377 2.422 27.931 18.057 7.062 7.797
42.00 19.806 8.200 2.415 28.117 18.061 7.055 7.803
44.00 21.921 9.102 2.408 28.309 18.066 7.048 7.809
46.00 24.224 10.087 2.401 28.506 18.070 7.040 7.814
48.00 26.730 11.163 2.394 28.708 18.075 7.033 7.820
50.00 29.453 12.337 2.387 28.916 18.079 7.025 7.826
52.00 32.407 13.614 2.380 29.130 18.084 7.018 7.832
54.00 35.608 15.004 2.373 29.349 18.088 7.010 7.837
56.00 39.073 16.513 2.366 29.574 18.093 7.002 7.843
58.00 42.818 18.150 2.359 29.804 18.097 6.995 7.849
60.00 46.861 19.924 2.352 30.040 18.102 6.987 7.855
62.00 51.222 21.844 2.345 30.282 18.106 6.979 7.861
64.00 55.918 23.920 2.338 30.528 18.111 6.970 7.866
66.00 60.971 26.161 2.331 30.781 18.115 6.962 7.872
68.00 66.401 28.578 2.323 31.039 18.120 6.954 7.878
70.00 72.230 31.182 2.316 31.303 18.124 6.945 7.884
72.00 78.482 33.986 2.309 31.572 18.129 6.937 7.889
74.00 85.180 37.000 2.302 31.847 18.133 6.928 7.895
76.00 92.347 40.237 2.295 32.127 18.138 6.920 7.901
78.00 100.010 43.710 2.288 32.413 18.142 6.911 7.907
80.00 108.195 47.434 2.281 32.704 18.147 6.902 7.912
82.00 116.929 51.422 2.274 33.001 18.151 6.893 7.918
84.00 126.240 55.688 2.267 33.303 18.156 6.884 7.924
86.00 136.158 60.249 2.260 33.612 18.160 6.875 7.930
88.00 146.711 65.119 2.253 33.925 18.165 6.865 7.935
90.00 157.932 70.317 2.246 34.244 18.169 6.856 7.941
92.00 169.851 75.857 2.239 34.569 18.174 6.847 7.947
94.00 182.503 81.759 2.232 34.899 18.178 6.837 7.953
2.394 29.139 18.072 7.027 7.817
esión.
l 25% mol de etanol.
n el 5% mol de etanol.
ntación es de: y el

Destilado
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h

kgmol agua/h

Kcal/Kg mol K
28.777 9921.665
Kcal/Kg mol
18.065 10410.868
Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h
kgmol agua/h

Kcal/Kg mol K

Kcal/h

DHVap,EtOH DHVap,H2O
10714.866 10918.897
10681.717 10896.973 Constantes de Antoine (T °C, P mmHg)
10648.395 10874.975 P° = 10^(A- (B/(C+T)))
10614.899 10852.903 Compuesto A B C
10581.226 10830.755 Etanol 8.04494 1554.3 222.65
10547.373 10808.532 Agua 8.10765 1750.286 235
10513.338 10786.233
10479.118 10763.856
10444.712 10741.402 Constantes de Cp (liq) (T °K)

10410.115 10718.869 (Cp/R) = A + BT + CT2

10375.325 10696.257 Compuesto A B C
10340.340 10673.565 Etanol 33.866 -1.73E-01 3.49E-04
10305.157 10650.792 Agua 8.712 1.26E-03 -1.80E-07
10269.772 10627.938
10234.183 10605.002 Constantes de Cp (vap) (T °K)
10198.386 10581.982 (Cp/R) = A + BT + CT2
10162.379 10558.879 Compuesto A B C
10126.158 10535.691 Etanol 3.518 2.00E-03 -6.02E-06
10089.720 10512.418 Agua 3.47 1.45E-03 0.00E+00
10053.061 10489.059
10016.177 10465.613 D Hvap (T °K)
9979.066 10442.079 D Hv,2 = D Hv,1 ((1-Tr2)/(1-Tr1))0.375
9941.724 10418.456 Compuesto Tc Tb D Hvap,Tb
9904.146 10394.743 Etanol 516.20 351.50 9260.00
9866.330 10370.940 Agua 647.3 373.15 9717.00
9828.270 10347.046
9789.962 10323.059
9751.404 10298.979
9712.589 10274.805
9673.515 10250.535
9634.175 10226.170
9594.566 10201.707
9554.682 10177.147
9514.520 10152.487
9474.072 10127.726
9433.335 10102.865
9392.302 10077.901
9350.968 10052.833
9309.328 10027.661
9267.374 10002.384
9225.102 9976.999
9182.505 9951.506
9139.575 9925.904
9096.307 9900.191
9052.693 9874.367
9008.726 9848.430
8964.399 9822.378
8919.703 9796.210
9861.828 10374.085
 Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

1.00

0.90

0.80

0.70

0.60
y, fracción mol del etanol en el vapor

0.50

0.40

0.30

0.20

0.10

0.00
1.00
0.00

x, Fracción mol del etanol en el líquido

Diagonal L.Op.Enr. q L.Op.Emp Etapas
RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA
Se desea destilar una mezcla líquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presión.
La alimentación es de 100 kg mol/h y está en estado líquido, a una temperatura de 40°C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relación de reflujo a usar en este proceso es de 3:1. La capacidad calorífica promedio de la alimentación es de: y el
calor latente promedio es de kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Número de platos y Plato de alimentación.

Datos Inciales del problema

F* = 100.00 kg mol/h

xF = 0.1500 Kg mol EtOH/kg mol tot

PF = 101.33 kPa Destilado

TF = 90.00 °C D* = 11.76
yV = 0.9000 Kg mol EtOH/kg mol tot yD = 0.9000
xL = 0.0500 Kg mol EtOH/kg mol tot TD = 87.80
R= 3.00 PD = 101.33
Cp*F,prom = 19.79 Kcal/ kg mol K H*D = 12403.13
DH*Vap = 10297.25 Kcal/ kg mol (1- yD) = 0.10000
9861.828 10374.085 D* yD = 10.59
Alimentación D*(1-yD) = 1.18
F* = 100.00 kgmol/h Cp*D,L = 27.71
xF = 0.1500 frac mol EtOH DH*Vap = 9970.59
TF = 90.00 °C L* = 35.29
PF = 101.33 kPa

H*F = 1772.26 Kcal/Kg mol D* H*D = 145919.15

(1- xF) = 0.8500 frac mol agua

F* xF = 15.00 kgmol EtOH/h

F* (1-xF) = 85.00 kgmol agua/h

Cp*F = 19.69 Kcal/Kg mol K

28.895
18.068 Fondo
L* = 88.24
TB,F = 94.05 °C xL = 0.0500
F* H*F = 177226.45 Kcal/h TL = 87.80
Cp*F,TB = 19.73 Kcal/Kg mol K Q = -F* H*F + L* H*L + V* H*V PL = 101.33
29.139 112084.52 H*L = 1633.16
18.072 (1- xL) = 0.95000
SOLUCION DEL PROBLEMA L* xL = 4.41
 1. Cálculo del valor TB : 94.05 °C L* (1-xL) = 83.82
2. Cálculo del valor H*F,Lsat: 1973.215 Kcal/kg mol Cp*L = 18.60
3. Cálculo del valor q : 1.02414 Adimens.

4. Pendiente de q : 42.423 Adimens. L* H*L = 143391.83

5. Pendiente de L.Op. Enriquec.: 0.7500
6. Interc. de L.Op. Enriquec.: 0.2250

y*xF = 0.0507

Eje X Eje Y
7. Trazado de L.Op. Enriquec.: 0.900 0.900
0.100 0.300

Eje X Eje Y
8. Trazado de Linea "q" : 0.150 0.150
0.155 0.362

Eje X Eje Y
9. Calc. Interc. L.Op.E. y L. "q" : 0.1545 0.3409

Eje X Eje Y
9. Trazado de L.Op. Empobrecim. : 0.050 0.050
0.154 0.341

Eje X Eje Y
10. Trazado de las etapas : 0.9000 0.9000
0.7450 0.9000
0.7450 0.7850
0.2935 0.7850
0.2935 0.4470
0.0650 0.4470
0.0650 0.0940
0.0115 0.0940
0.0115 0.0100

11. Cálculo del V* y de L* : 11.765 kgmol/h

88.235 kgmol/h

.
 Kcal/Kg mol K
T P°EtOH (kPa) P°H2O (kPa) a CpEtOH (l) CpH2O (l) CpEtOH (v) CpH2O (v)
0.00 1.545 0.609 2.537 25.378 17.965 7.183 7.682
2.00 1.783 0.704 2.533 25.453 17.970 7.178 7.688
4.00 2.052 0.811 2.529 25.534 17.974 7.173 7.693
6.00 2.356 0.933 2.524 25.620 17.979 7.168 7.699
8.00 2.698 1.071 2.520 25.711 17.984 7.162 7.705
10.00 3.083 1.226 2.515 25.808 17.988 7.157 7.711
12.00 3.515 1.401 2.509 25.911 17.993 7.151 7.716
14.00 3.999 1.597 2.504 26.019 17.997 7.145 7.722
16.00 4.539 1.817 2.498 26.133 18.002 7.139 7.728
18.00 5.141 2.063 2.493 26.252 18.006 7.133 7.734
20.00 5.812 2.337 2.487 26.377 18.011 7.127 7.739
22.00 6.557 2.643 2.481 26.508 18.016 7.121 7.745
24.00 7.382 2.983 2.475 26.644 18.020 7.115 7.751
26.00 8.296 3.361 2.468 26.785 18.025 7.109 7.757
28.00 9.306 3.780 2.462 26.932 18.029 7.102 7.763
30.00 10.420 4.243 2.456 27.085 18.034 7.096 7.768
32.00 11.646 4.755 2.449 27.243 18.038 7.089 7.774
34.00 12.994 5.320 2.442 27.407 18.043 7.082 7.780
36.00 14.473 5.942 2.436 27.576 18.047 7.076 7.786
38.00 16.094 6.626 2.429 27.751 18.052 7.069 7.791
40.00 17.868 7.377 2.422 27.931 18.057 7.062 7.797
42.00 19.806 8.200 2.415 28.117 18.061 7.055 7.803
44.00 21.921 9.102 2.408 28.309 18.066 7.048 7.809
46.00 24.224 10.087 2.401 28.506 18.070 7.040 7.814
48.00 26.730 11.163 2.394 28.708 18.075 7.033 7.820
50.00 29.453 12.337 2.387 28.916 18.079 7.025 7.826
52.00 32.407 13.614 2.380 29.130 18.084 7.018 7.832
54.00 35.608 15.004 2.373 29.349 18.088 7.010 7.837
56.00 39.073 16.513 2.366 29.574 18.093 7.002 7.843
58.00 42.818 18.150 2.359 29.804 18.097 6.995 7.849
60.00 46.861 19.924 2.352 30.040 18.102 6.987 7.855
62.00 51.222 21.844 2.345 30.282 18.106 6.979 7.861
64.00 55.918 23.920 2.338 30.528 18.111 6.970 7.866
66.00 60.971 26.161 2.331 30.781 18.115 6.962 7.872
68.00 66.401 28.578 2.323 31.039 18.120 6.954 7.878
70.00 72.230 31.182 2.316 31.303 18.124 6.945 7.884
72.00 78.482 33.986 2.309 31.572 18.129 6.937 7.889
74.00 85.180 37.000 2.302 31.847 18.133 6.928 7.895
76.00 92.347 40.237 2.295 32.127 18.138 6.920 7.901
 78.00 100.010 43.710 2.288 32.413 18.142 6.911 7.907
80.00 108.195 47.434 2.281 32.704 18.147 6.902 7.912
82.00 116.929 51.422 2.274 33.001 18.151 6.893 7.918
84.00 126.240 55.688 2.267 33.303 18.156 6.884 7.924
86.00 136.158 60.249 2.260 33.612 18.160 6.875 7.930
88.00 146.711 65.119 2.253 33.925 18.165 6.865 7.935
90.00 157.932 70.317 2.246 34.244 18.169 6.856 7.941
92.00 169.851 75.857 2.239 34.569 18.174 6.847 7.947
94.00 182.503 81.759 2.232 34.899 18.178 6.837 7.953
96.00 195.919 88.040 2.225 35.235 18.183 6.827 7.958
98.00 210.137 94.719 2.219 35.576 18.187 6.818 7.964
100.00 225.190 101.817 2.212 35.923 18.191 6.808 7.970
2.384 29.518 18.079 7.015 7.826
esión.
l 25% mol de etanol.
n el 5% mol de etanol.
ntación es de: y el

Destilado
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h

kgmol agua/h

Kcal/Kg mol K
28.777 9921.665
Kcal/Kg mol
18.065 10410.868
Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h
kgmol agua/h

Kcal/Kg mol K

Kcal/h
DHVap,EtOH DHVap,H2O
10714.866 10918.897
10681.717 10896.973 Constantes de Antoine (T °C, P mmHg)
10648.395 10874.975 P° = 10^(A- (B/(C+T)))
10614.899 10852.903 Compuesto A B C
10581.226 10830.755 Etanol 8.04494 1554.3 222.65
10547.373 10808.532 Agua 8.10765 1750.286 235
10513.338 10786.233
10479.118 10763.856
10444.712 10741.402 Constantes de Cp (liq) (T °K)

10410.115 10718.869 (Cp/R) = A + BT + CT 2

10375.325 10696.257 Compuesto A B C

10340.340 10673.565 Etanol 33.866 -1.73E-01 3.49E-04
10305.157 10650.792 Agua 8.712 1.26E-03 -1.80E-07
10269.772 10627.938
10234.183 10605.002 Constantes de Cp (vap) (T °K)
10198.386 10581.982 (Cp/R) = A + BT + CT2
10162.379 10558.879 Compuesto A B C
10126.158 10535.691 Etanol 3.518 2.00E-03 -6.02E-06
10089.720 10512.418 Agua 3.47 1.45E-03 0.00E+00
10053.061 10489.059
10016.177 10465.613 D Hvap (T °K)
9979.066 10442.079 D Hv,2 = D Hv,1 ((1-Tr2)/(1-Tr1))0.375
9941.724 10418.456 Compuesto Tc Tb D Hvap,Tb
9904.146 10394.743 Etanol 516.20 351.50 9260.00
9866.330 10370.940 Agua 647.3 373.15 9717.00
9828.270 10347.046
9789.962 10323.059
9751.404 10298.979
9712.589 10274.805
9673.515 10250.535
9634.175 10226.170
9594.566 10201.707
9554.682 10177.147
9514.520 10152.487
9474.072 10127.726
9433.335 10102.865
9392.302 10077.901
9350.968 10052.833
9309.328 10027.661
9267.374 10002.384
9225.102 9976.999
9182.505 9951.506
9139.575 9925.904
9096.307 9900.191
9052.693 9874.367
9008.726 9848.430
8964.399 9822.378
8919.703 9796.210
8874.630 9769.926
8829.173 9743.523
8783.323 9717.000
9801.076 10336.991
 Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

1.00

0.90

0.80

0.70

0.60
y, fracción mol del etanol en el vapor

0.50

0.40

0.30

0.20

0.10

0.00
1.00
0.00

x, Fracción mol del etanol en el líquido

Diagonal L.Op.Enr. q L.Op.Emp Etapas
RECTIFICACION
Dtl_ME_3 DE UNA MEZCLA DE ETANOL-AGUA
Se desea destilar una mezcla líquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presión.
La alimentación es de 100 kg mol/h y está en estado líquido, a una temperatura de 40°C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relación de reflujo a usar en este proceso es de 3:1. La capacidad calorífica promedio de la alimentación es de: y el
calor latente promedio es de kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Número de platos y Plato de alimentación.

Datos Inciales del problema

F* = 100.00 kg mol/h

xF = 0.1500 Kg mol EtOH/kg mol tot

PF = 101.33 kPa Destilado

TF = 90.00 °C D* = 11.76
yV = 0.9000 Kg mol EtOH/kg mol tot yD = 0.9000
xL = 0.0500 Kg mol EtOH/kg mol tot TD = 87.80
R= 2.00 PD = 101.33
Cp*F,prom = 19.79 Kcal/ kg mol K H*D = 12403.13
DH*Vap = 10297.25 Kcal/ kg mol (1- yD) = 0.10000
9861.828 10374.085 D* yD = 10.59
Alimentación D*(1-yD) = 1.18
F* = 100.00 kgmol/h Cp*D,L = 27.71
xF = 0.1500 frac mol EtOH DH*Vap = 9970.59
TF = 90.00 °C L* = 23.53
PF = 101.33 kPa

H*F = 1772.26 Kcal/Kg mol D* H*D = 145919.15

(1- xF) = 0.8500 frac mol agua

F* xF = 15.00 kgmol EtOH/h

F* (1-xF) = 85.00 kgmol agua/h

Cp*F = 19.69 Kcal/Kg mol K

28.895
18.068 Fondo
L* = 88.24
TB,F = 94.05 °C xL = 0.0500
F* H*F = 177226.45 Kcal/h TL = 87.80
Cp*F,TB = 19.73 Kcal/Kg mol K Q = -F* H*F + L* H*L + V* H*V PL = 101.33
29.139 112084.52 H*L = 1633.16
18.072 (1- xL) = 0.95000
SOLUCION DEL PROBLEMA L* xL = 4.41
 1. Cálculo del valor TB : 94.05 °C L* (1-xL) = 83.82
2. Cálculo del valor H*F,Lsat: 1973.215 Kcal/kg mol Cp*L = 18.60
3. Cálculo del valor q : 1.02414 Adimens.

4. Pendiente de q : 42.423 Adimens. L* H*L = 143391.83

5. Pendiente de L.Op. Enriquec.: 0.6667
6. Interc. de L.Op. Enriquec.: 0.3000

Eje X Eje Y
7. Trazado de L.Op. Enriquec.: 0.900 0.900
0.100 0.367

Eje X Eje Y
8. Trazado de Linea "q" : 0.150 0.150
0.160 0.574

Eje X Eje Y
9. Calc. Interc. L.Op.E. y L. "q" : 0.1560 0.4040

Eje X Eje Y
9. Trazado de L.Op. Empobrecim. : 0.050 0.050
0.156 0.404

Eje X Eje Y
10. Trazado de las etapas : 0.9000 0.9000
0.7450 0.9000
0.7450 0.7960
0.3150 0.7960
0.3150 0.5100
0.0810 0.5100
0.0810 0.1540
0.0180 0.1540
0.0180 0.0100

11. Cálculo del V* y de L* : 11.765 kgmol/h

88.235 kgmol/h

Kcal/Kg mol K
T P°EtOH (kPa) P°H2O (kPa) a CpEtOH (l) CpH2O (l) CpEtOH (v) CpH2O (v)
0.00 1.545 0.609 2.537 25.378 17.965 7.183 7.682
2.00 1.783 0.704 2.533 25.453 17.970 7.178 7.688
4.00 2.052 0.811 2.529 25.534 17.974 7.173 7.693
6.00 2.356 0.933 2.524 25.620 17.979 7.168 7.699
8.00 2.698 1.071 2.520 25.711 17.984 7.162 7.705
10.00 3.083 1.226 2.515 25.808 17.988 7.157 7.711
12.00 3.515 1.401 2.509 25.911 17.993 7.151 7.716
14.00 3.999 1.597 2.504 26.019 17.997 7.145 7.722
16.00 4.539 1.817 2.498 26.133 18.002 7.139 7.728
18.00 5.141 2.063 2.493 26.252 18.006 7.133 7.734
20.00 5.812 2.337 2.487 26.377 18.011 7.127 7.739
22.00 6.557 2.643 2.481 26.508 18.016 7.121 7.745
24.00 7.382 2.983 2.475 26.644 18.020 7.115 7.751
26.00 8.296 3.361 2.468 26.785 18.025 7.109 7.757
28.00 9.306 3.780 2.462 26.932 18.029 7.102 7.763
30.00 10.420 4.243 2.456 27.085 18.034 7.096 7.768
32.00 11.646 4.755 2.449 27.243 18.038 7.089 7.774
34.00 12.994 5.320 2.442 27.407 18.043 7.082 7.780
36.00 14.473 5.942 2.436 27.576 18.047 7.076 7.786
38.00 16.094 6.626 2.429 27.751 18.052 7.069 7.791
40.00 17.868 7.377 2.422 27.931 18.057 7.062 7.797
42.00 19.806 8.200 2.415 28.117 18.061 7.055 7.803
44.00 21.921 9.102 2.408 28.309 18.066 7.048 7.809
46.00 24.224 10.087 2.401 28.506 18.070 7.040 7.814
48.00 26.730 11.163 2.394 28.708 18.075 7.033 7.820
50.00 29.453 12.337 2.387 28.916 18.079 7.025 7.826
52.00 32.407 13.614 2.380 29.130 18.084 7.018 7.832
54.00 35.608 15.004 2.373 29.349 18.088 7.010 7.837
56.00 39.073 16.513 2.366 29.574 18.093 7.002 7.843
58.00 42.818 18.150 2.359 29.804 18.097 6.995 7.849
60.00 46.861 19.924 2.352 30.040 18.102 6.987 7.855
62.00 51.222 21.844 2.345 30.282 18.106 6.979 7.861
64.00 55.918 23.920 2.338 30.528 18.111 6.970 7.866
66.00 60.971 26.161 2.331 30.781 18.115 6.962 7.872
68.00 66.401 28.578 2.323 31.039 18.120 6.954 7.878
70.00 72.230 31.182 2.316 31.303 18.124 6.945 7.884
72.00 78.482 33.986 2.309 31.572 18.129 6.937 7.889
74.00 85.180 37.000 2.302 31.847 18.133 6.928 7.895
76.00 92.347 40.237 2.295 32.127 18.138 6.920 7.901
78.00 100.010 43.710 2.288 32.413 18.142 6.911 7.907
80.00 108.195 47.434 2.281 32.704 18.147 6.902 7.912
82.00 116.929 51.422 2.274 33.001 18.151 6.893 7.918
 84.00 126.240 55.688 2.267 33.303 18.156 6.884 7.924
86.00 136.158 60.249 2.260 33.612 18.160 6.875 7.930
88.00 146.711 65.119 2.253 33.925 18.165 6.865 7.935
90.00 157.932 70.317 2.246 34.244 18.169 6.856 7.941
92.00 169.851 75.857 2.239 34.569 18.174 6.847 7.947
94.00 182.503 81.759 2.232 34.899 18.178 6.837 7.953
96.00 195.919 88.040 2.225 35.235 18.183 6.827 7.958
98.00 210.137 94.719 2.219 35.576 18.187 6.818 7.964
100.00 225.190 101.817 2.212 35.923 18.191 6.808 7.970
2.384 29.518 18.079 7.015 7.826
esión.
l 25% mol de etanol.
n el 5% mol de etanol.
ntación es de: y el

Destilado
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h

kgmol agua/h

Kcal/Kg mol K
28.777 9921.665
Kcal/Kg mol
18.065 10410.868
Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h
kgmol agua/h

Kcal/Kg mol K

Kcal/h

DHVap,EtOH DHVap,H2O
10714.866 10918.897
10681.717 10896.973 Constantes de Antoine (T °C, P mmHg)
10648.395 10874.975 P° = 10^(A- (B/(C+T)))
10614.899 10852.903 Compuesto A B C
10581.226 10830.755 Etanol 8.04494 1554.3 222.65
10547.373 10808.532 Agua 8.10765 1750.286 235
10513.338 10786.233
10479.118 10763.856
10444.712 10741.402 Constantes de Cp (liq) (T °K)

10410.115 10718.869 (Cp/R) = A + BT + CT2

10375.325 10696.257 Compuesto A B C
10340.340 10673.565 Etanol 33.866 -1.73E-01 3.49E-04
10305.157 10650.792 Agua 8.712 1.26E-03 -1.80E-07
10269.772 10627.938
10234.183 10605.002 Constantes de Cp (vap) (T °K)
10198.386 10581.982 (Cp/R) = A + BT + CT2
10162.379 10558.879 Compuesto A B C
10126.158 10535.691 Etanol 3.518 2.00E-03 -6.02E-06
10089.720 10512.418 Agua 3.47 1.45E-03 0.00E+00
10053.061 10489.059
10016.177 10465.613 D Hvap (T °K)
9979.066 10442.079 D Hv,2 = D Hv,1 ((1-Tr2)/(1-Tr1))0.375
9941.724 10418.456 Compuesto Tc Tb D Hvap,Tb
9904.146 10394.743 Etanol 516.20 351.50 9260.00
9866.330 10370.940 Agua 647.3 373.15 9717.00
9828.270 10347.046
9789.962 10323.059
9751.404 10298.979
9712.589 10274.805
9673.515 10250.535
9634.175 10226.170
9594.566 10201.707
9554.682 10177.147
9514.520 10152.487
9474.072 10127.726
9433.335 10102.865
9392.302 10077.901
9350.968 10052.833
9309.328 10027.661
9267.374 10002.384
9225.102 9976.999
9182.505 9951.506
9139.575 9925.904
9096.307 9900.191
9052.693 9874.367
9008.726 9848.430
8964.399 9822.378
8919.703 9796.210
8874.630 9769.926
8829.173 9743.523
8783.323 9717.000
9801.076 10336.991
 Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

1.00

0.90

0.80

0.70

0.60
y, fracción mol del etanol en el vapor

0.50

0.40

0.30

0.20

0.10

0.00
1.00
0.00

x, Fracción mol del etanol en el líquido

Diagonal L.Op.Enr. q L.Op.Emp Etapas
RECTIFICACION
Dtl_ME_3 DE UNA MEZCLA DE ETANOL-AGUA
Se desea destilar una mezcla líquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presión.
La alimentación es de 100 kg mol/h y está en estado líquido, a una temperatura de 40°C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relación de reflujo a usar en este proceso es de 3:1. La capacidad calorífica promedio de la alimentación es de: y el
calor latente promedio es de kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Número de platos y Plato de alimentación.

Datos Inciales del problema

F* = 100.00 kg mol/h

xF = 0.1500 Kg mol EtOH/kg mol tot

PF = 101.33 kPa Destilado

TF = 90.00 °C D* = 11.76
yV = 0.9000 Kg mol EtOH/kg mol tot yD = 0.9000
xL = 0.0500 Kg mol EtOH/kg mol tot TD = 87.80
R= 1.00 PD = 101.33
Cp*F,prom = 19.79 Kcal/ kg mol K H*D = 12403.13
DH*Vap = 10297.25 Kcal/ kg mol (1- yD) = 0.10000
9861.828 10374.085 D* yD = 10.59
Alimentación D*(1-yD) = 1.18
F* = 100.00 kgmol/h Cp*D,L = 27.71
xF = 0.1500 frac mol EtOH DH*Vap = 9970.59
TF = 90.00 °C L* = 11.76
PF = 101.33 kPa

H*F = 1772.26 Kcal/Kg mol D* H*D = 145919.15

(1- xF) = 0.8500 frac mol agua

F* xF = 15.00 kgmol EtOH/h

F* (1-xF) = 85.00 kgmol agua/h

Cp*F = 19.69 Kcal/Kg mol K

28.895
18.068 Fondo
L* = 88.24
TB,F = 94.05 °C xL = 0.0500
F* H*F = 177226.45 Kcal/h TL = 87.80
Cp*F,TB = 19.73 Kcal/Kg mol K Q = -F* H*F + L* H*L + V* H*V PL = 101.33
29.139 112084.52 H*L = 1633.16
18.072 (1- xL) = 0.95000
SOLUCION DEL PROBLEMA L* xL = 4.41
 1. Cálculo del valor TB : 94.05 °C L* (1-xL) = 83.82
2. Cálculo del valor H*F,Lsat: 1973.215 Kcal/kg mol Cp*L = 18.60
3. Cálculo del valor q : 1.02414 Adimens.

4. Pendiente de q : 42.423 Adimens. L* H*L = 143391.83

5. Pendiente de L.Op. Enriquec.: 0.5000
6. Interc. de L.Op. Enriquec.: 0.4500

Eje X Eje Y
7. Trazado de L.Op. Enriquec.: 0.900 0.900
0.100 0.500

Eje X Eje Y
8. Trazado de Linea "q" : 0.150 0.150
0.160 0.574

Eje X Eje Y
9. Calc. Interc. L.Op.E. y L. "q" : 0.1589 0.5295

Eje X Eje Y
9. Trazado de L.Op. Empobrecim. : 0.050 0.050
0.159 0.529

Eje X Eje Y
10. Trazado de las etapas : 0.9000 0.9000
0.7450 0.9000
0.7450 0.8230
0.3750 0.8230
0.3750 0.6380
0.1345 0.6380
0.1345 0.4200
0.0600 0.4200
0.0600 0.0950
0.0120 0.0950
0.0120 0.0000

11. Cálculo del V* y de L* : 11.765 kgmol/h

88.235 kgmol/h

.
 Kcal/Kg mol K
T P°EtOH (kPa) P°H2O (kPa) a CpEtOH (l) CpH2O (l) CpEtOH (v) CpH2O (v)
0.00 1.545 0.609 2.537 25.378 17.965 7.183 7.682
2.00 1.783 0.704 2.533 25.453 17.970 7.178 7.688
4.00 2.052 0.811 2.529 25.534 17.974 7.173 7.693
6.00 2.356 0.933 2.524 25.620 17.979 7.168 7.699
8.00 2.698 1.071 2.520 25.711 17.984 7.162 7.705
10.00 3.083 1.226 2.515 25.808 17.988 7.157 7.711
12.00 3.515 1.401 2.509 25.911 17.993 7.151 7.716
14.00 3.999 1.597 2.504 26.019 17.997 7.145 7.722
16.00 4.539 1.817 2.498 26.133 18.002 7.139 7.728
18.00 5.141 2.063 2.493 26.252 18.006 7.133 7.734
20.00 5.812 2.337 2.487 26.377 18.011 7.127 7.739
22.00 6.557 2.643 2.481 26.508 18.016 7.121 7.745
24.00 7.382 2.983 2.475 26.644 18.020 7.115 7.751
26.00 8.296 3.361 2.468 26.785 18.025 7.109 7.757
28.00 9.306 3.780 2.462 26.932 18.029 7.102 7.763
30.00 10.420 4.243 2.456 27.085 18.034 7.096 7.768
32.00 11.646 4.755 2.449 27.243 18.038 7.089 7.774
34.00 12.994 5.320 2.442 27.407 18.043 7.082 7.780
36.00 14.473 5.942 2.436 27.576 18.047 7.076 7.786
38.00 16.094 6.626 2.429 27.751 18.052 7.069 7.791
40.00 17.868 7.377 2.422 27.931 18.057 7.062 7.797
42.00 19.806 8.200 2.415 28.117 18.061 7.055 7.803
44.00 21.921 9.102 2.408 28.309 18.066 7.048 7.809
46.00 24.224 10.087 2.401 28.506 18.070 7.040 7.814
48.00 26.730 11.163 2.394 28.708 18.075 7.033 7.820
50.00 29.453 12.337 2.387 28.916 18.079 7.025 7.826
52.00 32.407 13.614 2.380 29.130 18.084 7.018 7.832
54.00 35.608 15.004 2.373 29.349 18.088 7.010 7.837
56.00 39.073 16.513 2.366 29.574 18.093 7.002 7.843
58.00 42.818 18.150 2.359 29.804 18.097 6.995 7.849
60.00 46.861 19.924 2.352 30.040 18.102 6.987 7.855
62.00 51.222 21.844 2.345 30.282 18.106 6.979 7.861
64.00 55.918 23.920 2.338 30.528 18.111 6.970 7.866
66.00 60.971 26.161 2.331 30.781 18.115 6.962 7.872
68.00 66.401 28.578 2.323 31.039 18.120 6.954 7.878
70.00 72.230 31.182 2.316 31.303 18.124 6.945 7.884
72.00 78.482 33.986 2.309 31.572 18.129 6.937 7.889
74.00 85.180 37.000 2.302 31.847 18.133 6.928 7.895
76.00 92.347 40.237 2.295 32.127 18.138 6.920 7.901
78.00 100.010 43.710 2.288 32.413 18.142 6.911 7.907
 80.00 108.195 47.434 2.281 32.704 18.147 6.902 7.912
82.00 116.929 51.422 2.274 33.001 18.151 6.893 7.918
84.00 126.240 55.688 2.267 33.303 18.156 6.884 7.924
86.00 136.158 60.249 2.260 33.612 18.160 6.875 7.930
88.00 146.711 65.119 2.253 33.925 18.165 6.865 7.935
90.00 157.932 70.317 2.246 34.244 18.169 6.856 7.941
92.00 169.851 75.857 2.239 34.569 18.174 6.847 7.947
94.00 182.503 81.759 2.232 34.899 18.178 6.837 7.953
96.00 195.919 88.040 2.225 35.235 18.183 6.827 7.958
98.00 210.137 94.719 2.219 35.576 18.187 6.818 7.964
100.00 225.190 101.817 2.212 35.923 18.191 6.808 7.970
2.384 29.518 18.079 7.015 7.826
esión.
l 25% mol de etanol.
n el 5% mol de etanol.
ntación es de: y el

Destilado
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h

kgmol agua/h

Kcal/Kg mol K
28.777 9921.665
Kcal/Kg mol
18.065 10410.868
Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h
kgmol agua/h

Kcal/Kg mol K

Kcal/h
DHVap,EtOH DHVap,H2O
10714.866 10918.897
10681.717 10896.973 Constantes de Antoine (T °C, P mmHg)
10648.395 10874.975 P° = 10^(A- (B/(C+T)))
10614.899 10852.903 Compuesto A B C
10581.226 10830.755 Etanol 8.04494 1554.3 222.65
10547.373 10808.532 Agua 8.10765 1750.286 235
10513.338 10786.233
10479.118 10763.856
10444.712 10741.402 Constantes de Cp (liq) (T °K)

10410.115 10718.869 (Cp/R) = A + BT + CT2

10375.325 10696.257 Compuesto A B C
10340.340 10673.565 Etanol 33.866 -1.73E-01 3.49E-04
10305.157 10650.792 Agua 8.712 1.26E-03 -1.80E-07
10269.772 10627.938
10234.183 10605.002 Constantes de Cp (vap) (T °K)
10198.386 10581.982 (Cp/R) = A + BT + CT2
10162.379 10558.879 Compuesto A B C
10126.158 10535.691 Etanol 3.518 2.00E-03 -6.02E-06
10089.720 10512.418 Agua 3.47 1.45E-03 0.00E+00
10053.061 10489.059
10016.177 10465.613 D Hvap (T °K)
9979.066 10442.079 D Hv,2 = D Hv,1 ((1-Tr2)/(1-Tr1))0.375
9941.724 10418.456 Compuesto Tc Tb D Hvap,Tb
9904.146 10394.743 Etanol 516.20 351.50 9260.00
9866.330 10370.940 Agua 647.3 373.15 9717.00
9828.270 10347.046
9789.962 10323.059
9751.404 10298.979
9712.589 10274.805
9673.515 10250.535
9634.175 10226.170
9594.566 10201.707
9554.682 10177.147
9514.520 10152.487
9474.072 10127.726
9433.335 10102.865
9392.302 10077.901
9350.968 10052.833
9309.328 10027.661
9267.374 10002.384
9225.102 9976.999
9182.505 9951.506
9139.575 9925.904
9096.307 9900.191
9052.693 9874.367
9008.726 9848.430
8964.399 9822.378
8919.703 9796.210
8874.630 9769.926
8829.173 9743.523
8783.323 9717.000
9801.076 10336.991
 Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

1.00

0.90

0.80

0.70

0.60
y, fracción mol del etanol en el vapor

0.50

0.40

0.30

0.20

0.10

0.00
1.00
0.00

x, Fracción mol del etanol en el líquido

Diagonal L.Op.Enr. q L.Op.Emp Etapas
RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA
Se desea destilar una mezcla líquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presión.
La alimentación es de 100 kg mol/h y está en estado líquido, a una temperatura de 40°C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relación de reflujo a usar en este proceso es de 3:1. La capacidad calorífica promedio de la alimentación es de: y el
calor latente promedio es de kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Número de platos y Plato de alimentación.

Datos Inciales del problema

F* = 100.00 kg mol/h

xF = 0.1500 Kg mol EtOH/kg mol tot

PF = 101.33 kPa Destilado

TF = 90.00 °C D* = 11.76
yV = 0.9000 Kg mol EtOH/kg mol tot yD = 0.9000
xL = 0.0500 Kg mol EtOH/kg mol tot TD = 87.80
R= 0.5000 PD = 101.33
Cp*F,prom = 19.79 Kcal/ kg mol K H*D = 12403.13
DH*Vap = 10297.25 Kcal/ kg mol (1- yD) = 0.10000
9861.828 10374.085 D* yD = 10.59
Alimentación D*(1-yD) = 1.18
F* = 100.00 kgmol/h Cp*D,L = 27.71
xF = 0.1500 frac mol EtOH DH*Vap = 9970.59
TF = 90.00 °C L* = 5.88
PF = 101.33 kPa

H*F = 1772.26 Kcal/Kg mol D* H*D = 145919.15

(1- xF) = 0.8500 frac mol agua

F* xF = 15.00 kgmol EtOH/h

F* (1-xF) = 85.00 kgmol agua/h

Cp*F = 19.69 Kcal/Kg mol K

28.895
18.068 Fondo
L* = 88.24
TB,F = 94.05 °C xL = 0.0500
F* H*F = 177226.45 Kcal/h TL = 87.80
Cp*F,TB = 19.73 Kcal/Kg mol K Q = -F* H*F + L* H*L + V* H*V PL = 101.33
29.139 112084.52 H*L = 1633.16
18.072 (1- xL) = 0.95000
SOLUCION DEL PROBLEMA L* xL = 4.41
 1. Cálculo del valor TB : 94.05 °C L* (1-xL) = 83.82
2. Cálculo del valor H*F,Lsat: 1973.215 Kcal/kg mol Cp*L = 18.60
3. Cálculo del valor q : 1.02414 Adimens.

4. Pendiente de q : 42.423 Adimens. L* H*L = 143391.83

5. Pendiente de L.Op. Enriquec.: 0.3333
6. Interc. de L.Op. Enriquec.: 0.6000

Eje X Eje Y
7. Trazado de L.Op. Enriquec.: 0.900 0.900
0.100 0.633

Eje X Eje Y
8. Trazado de Linea "q" : 0.150 0.150
0.163 0.680

Eje X Eje Y
9. Calc. Interc. L.Op.E. y L. "q" : 0.1619 0.6540

Eje X Eje Y
9. Trazado de L.Op. Empobrecim. : 0.050 0.050
0.162 0.654

Eje X Eje Y
10. Trazado de las etapas : 0.9000 0.9000
0.7450 0.9000
0.7450 0.8480
0.4450 0.8480
0.4450 0.7480
0.2300 0.7480
0.2300 0.6760
0.1570 0.6760
0.1570 0.6250
0.1270 0.6250
0.1270 0.4650
0.0690 0.4650
0.0690 0.1500
0.0170 0.1500
0.0170 0.0000

11. Cálculo del V* y de L* : 11.765 kgmol/h

88.235 kgmol/h
 .

Kcal/Kg mol K
T P°EtOH (kPa) P°H2O (kPa) a CpEtOH (l) CpH2O (l) CpEtOH (v) CpH2O (v)
0.00 1.545 0.609 2.537 25.378 17.965 7.183 7.682
2.00 1.783 0.704 2.533 25.453 17.970 7.178 7.688
4.00 2.052 0.811 2.529 25.534 17.974 7.173 7.693
6.00 2.356 0.933 2.524 25.620 17.979 7.168 7.699
8.00 2.698 1.071 2.520 25.711 17.984 7.162 7.705
10.00 3.083 1.226 2.515 25.808 17.988 7.157 7.711
12.00 3.515 1.401 2.509 25.911 17.993 7.151 7.716
14.00 3.999 1.597 2.504 26.019 17.997 7.145 7.722
16.00 4.539 1.817 2.498 26.133 18.002 7.139 7.728
18.00 5.141 2.063 2.493 26.252 18.006 7.133 7.734
20.00 5.812 2.337 2.487 26.377 18.011 7.127 7.739
22.00 6.557 2.643 2.481 26.508 18.016 7.121 7.745
24.00 7.382 2.983 2.475 26.644 18.020 7.115 7.751
26.00 8.296 3.361 2.468 26.785 18.025 7.109 7.757
28.00 9.306 3.780 2.462 26.932 18.029 7.102 7.763
30.00 10.420 4.243 2.456 27.085 18.034 7.096 7.768
32.00 11.646 4.755 2.449 27.243 18.038 7.089 7.774
34.00 12.994 5.320 2.442 27.407 18.043 7.082 7.780
36.00 14.473 5.942 2.436 27.576 18.047 7.076 7.786
38.00 16.094 6.626 2.429 27.751 18.052 7.069 7.791
40.00 17.868 7.377 2.422 27.931 18.057 7.062 7.797
42.00 19.806 8.200 2.415 28.117 18.061 7.055 7.803
44.00 21.921 9.102 2.408 28.309 18.066 7.048 7.809
46.00 24.224 10.087 2.401 28.506 18.070 7.040 7.814
48.00 26.730 11.163 2.394 28.708 18.075 7.033 7.820
50.00 29.453 12.337 2.387 28.916 18.079 7.025 7.826
52.00 32.407 13.614 2.380 29.130 18.084 7.018 7.832
54.00 35.608 15.004 2.373 29.349 18.088 7.010 7.837
56.00 39.073 16.513 2.366 29.574 18.093 7.002 7.843
58.00 42.818 18.150 2.359 29.804 18.097 6.995 7.849
60.00 46.861 19.924 2.352 30.040 18.102 6.987 7.855
62.00 51.222 21.844 2.345 30.282 18.106 6.979 7.861
64.00 55.918 23.920 2.338 30.528 18.111 6.970 7.866
66.00 60.971 26.161 2.331 30.781 18.115 6.962 7.872
68.00 66.401 28.578 2.323 31.039 18.120 6.954 7.878
70.00 72.230 31.182 2.316 31.303 18.124 6.945 7.884
 72.00 78.482 33.986 2.309 31.572 18.129 6.937 7.889
74.00 85.180 37.000 2.302 31.847 18.133 6.928 7.895
76.00 92.347 40.237 2.295 32.127 18.138 6.920 7.901
78.00 100.010 43.710 2.288 32.413 18.142 6.911 7.907
80.00 108.195 47.434 2.281 32.704 18.147 6.902 7.912
82.00 116.929 51.422 2.274 33.001 18.151 6.893 7.918
84.00 126.240 55.688 2.267 33.303 18.156 6.884 7.924
86.00 136.158 60.249 2.260 33.612 18.160 6.875 7.930
88.00 146.711 65.119 2.253 33.925 18.165 6.865 7.935
90.00 157.932 70.317 2.246 34.244 18.169 6.856 7.941
92.00 169.851 75.857 2.239 34.569 18.174 6.847 7.947
94.00 182.503 81.759 2.232 34.899 18.178 6.837 7.953
96.00 195.919 88.040 2.225 35.235 18.183 6.827 7.958
98.00 210.137 94.719 2.219 35.576 18.187 6.818 7.964
100.00 225.190 101.817 2.212 35.923 18.191 6.808 7.970
2.384 29.518 18.079 7.015 7.826
esión.
l 25% mol de etanol.
n el 5% mol de etanol.
ntación es de: y el

Destilado
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h

kgmol agua/h

Kcal/Kg mol K
28.777 9921.665
Kcal/Kg mol
18.065 10410.868
Kcal/Kg mol K

Kcal/h

Fondo
kgmol/h

frac mol EtOH

°C

kPa

Kcal/Kg mol

frac mol agua

kgmol EtOH/h
kgmol agua/h

Kcal/Kg mol K

Kcal/h
DHVap,EtOH DHVap,H2O
10714.866 10918.897
10681.717 10896.973 Constantes de Antoine (T °C, P mmHg)
10648.395 10874.975 P° = 10^(A- (B/(C+T)))
10614.899 10852.903 Compuesto A B C
10581.226 10830.755 Etanol 8.04494 1554.3 222.65
10547.373 10808.532 Agua 8.10765 1750.286 235
10513.338 10786.233
10479.118 10763.856
10444.712 10741.402 Constantes de Cp (liq) (T °K)

10410.115 10718.869 (Cp/R) = A + BT + CT 2

10375.325 10696.257 Compuesto A B C

10340.340 10673.565 Etanol 33.866 -1.73E-01 3.49E-04
10305.157 10650.792 Agua 8.712 1.26E-03 -1.80E-07
10269.772 10627.938
10234.183 10605.002 Constantes de Cp (vap) (T °K)
10198.386 10581.982 (Cp/R) = A + BT + CT2
10162.379 10558.879 Compuesto A B C
10126.158 10535.691 Etanol 3.518 2.00E-03 -6.02E-06
10089.720 10512.418 Agua 3.47 1.45E-03 0.00E+00
10053.061 10489.059
10016.177 10465.613 D Hvap (T °K)
9979.066 10442.079 D Hv,2 = D Hv,1 ((1-Tr2)/(1-Tr1))0.375
9941.724 10418.456 Compuesto Tc Tb D Hvap,Tb
9904.146 10394.743 Etanol 516.20 351.50 9260.00
9866.330 10370.940 Agua 647.3 373.15 9717.00
9828.270 10347.046
9789.962 10323.059
9751.404 10298.979
9712.589 10274.805
9673.515 10250.535
9634.175 10226.170
9594.566 10201.707
9554.682 10177.147
9514.520 10152.487
9474.072 10127.726
9433.335 10102.865
9392.302 10077.901
9350.968 10052.833
9309.328 10027.661
9267.374 10002.384
9225.102 9976.999
9182.505 9951.506
9139.575 9925.904
9096.307 9900.191
9052.693 9874.367
9008.726 9848.430
8964.399 9822.378
8919.703 9796.210
8874.630 9769.926
8829.173 9743.523
8783.323 9717.000
9801.076 10336.991
 Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

1.00

0.90

0.80

0.70

0.60
y, fracción mol del etanol en el vapor

0.50

0.40

0.30

0.20

0.10

0.00
1.00
0.00

x, Fracción mol del etanol en el líquido

Diagonal L.Op.Enr. q L.Op.Emp Etapas
RECTIFICACION DE UNA MEZCLA DE ETANOL-AGUA
Se desea destilar una mezcla líquida de etanol-agua en una torre fraccionadora a 101.325 kPa de presión.
La alimentación es de 100 kg mol/h y está en estado líquido, a una temperatura de 40°C y contiene el 25% mol de etanol.
Para este proceso se desea obtener un destilado que contenga el 86% mol de etanol y un residuo con el 5% mol de etanol.
La relación de reflujo a usar en este proceso es de 3:1. La capacidad calorífica promedio de la alimentación es de: y el
calor latente promedio es de kJ/kg mol.
Calcular: (1) Flujo de destilado, (2) Flujo de residuos, (3) Número de platos y Plato de alimentación.

Datos Inciales del problema

F* = 100.00 kg mol/h

xF = 0.1500 Kg mol EtOH/kg mol tot

PF = 101.33 kPa Destilado

TF = 90.00 °C D* = 11.76 kgmol/h

yV = 0.9000 Kg mol EtOH/kg mol tot yD = 0.9000 frac mol EtOH

xL = 0.0500 Kg mol EtOH/kg mol tot TD = 87.80 °C

R= 0.47 0.47 PD = 101.33 kPa

Cp*F,prom = 19.79 Kcal/ kg mol K H*D = 12407.60 Kcal/Kg mol

DH*Vap = 10317.63 Kcal/ kg mol (1- yD) = 0.1000 frac mol agua

9892.321 10392.688 D* yD = 10.59 kgmol EtOH/h

Alimentación D*(1-yD) = 1.18 kgmol agua/h

F* = 100.00 kgmol/h Cp*D,L = 27.64 Kcal/Kg mol K 28.708 9931.99

xF = 0.1500 frac mol EtOH DH*Vap = 9980.50 Kcal/Kg mol 18.064 10417.13
TF = 90.00 °C L* = 5.53 kgmol/h

PF = 101.33 kPa

H*F = 1770.35 Kcal/Kg mol D* H*D = 145971.72 Kcal/h

(1- xF) = 0.8500 frac mol agua

F* xF = 15.00 kgmol EtOH/h

F* (1-xF) = 85.00 kgmol agua/h

Cp*F = 19.67 Kcal/Kg mol K

28.766
18.065
Fondo
W* = 88.24 kgmol/h
 TB,F = 94.05 °C xw = 0.0500 frac mol EtOH

F* H*F = 177035.04 Kcal/h TW = 87.80 °C

Cp*F,TB = 19.70 Kcal/Kg mol K Q = -F* H*F + L* H*L + V* H*V PW = 101.33 kPa

28.945 112293.77 H*W = 1632.77 Kcal/Kg mol

18.069 (1- xW) = 0.9500 frac mol agua

SOLUCION DEL PROBLEMA W* xW = 4.41 kgmol EtOH/h

1. Cálculo del valor TB,R : 94.05 °C W*(1-xW) = 83.82 kgmol agua/h

Cálculo del valor TR,F : 99.10 °C Cp*W = 18.60 Kcal/Kg mol K

2. Cálculo del valor H*F,Lsat: 1970.023 Kcal/kg mol y = -44.101x4 + 20.522x3 + 2.4092x2 - 6.6426x + 100
3. Cálculo del valor q : 1.02392 Adimens.
4. Pendiente de q : 42.806 Adimens. W* H*W = 143357.09 Kcal/h

5. Pendiente de L.Op. Enriquec.: 0.3197

5'. Pendiente Mínima de L.Op.
6. Interc. de L.Op. Enriquec.: 0.6122 0.3160
Enriquec.:
5b. Valor mínimo de reflujo.: 0.4620
Eje X Eje Y y*xF = 0.6630
7. Trazado de L.Op. Enriquec.: 0.900 0.900 6. Interc. de L.Op. Enriquec.: 0.6156
0.100 0.644
Eje X Eje Y
8. Trazado de Linea "q" : 0.150 0.150
0.163 0.685
Eje X Eje Y
9. Calc. Interc. L.Op.E. y L. "q" : 0.1620 0.6640
Eje X Eje Y
9. Trazado de L.Op. Empobrecim. : 0.050 0.050
0.162 0.664
Eje X Eje Y
10. Trazado de las etapas : 0.9000 0.9000
0.7450 0.9000
0.7450 0.8480
0.4450 0.8480
 0.4450 0.7480
0.2300 0.7480
0.2300 0.6760
0.1570 0.6760
0.1570 0.6250
0.1270 0.6250
0.1270 0.4650
0.0690 0.4650
0.0690 0.1500
0.0170 0.1500
0.0170 0.0000
11. Cálculo del V* y de L* : 11.765 kgmol/h

88.235 kgmol/h

Kcal/Kg mol K
T P°EtOH (kPa) P°H2O (kPa) a a Prom CpEtOH (l) CpH2O (l) CpEtOH,Pr (l) CpH2O,Pr (l) DH*V,EtOH DH*V,H2O DH*V,EtOH,Pr
0.00 1.545 0.609 2.537 25.378 17.965 10714.87 10918.90
1.00 1.660 0.655 2.535 2.536 25.415 17.968 25.397 17.966 10698.31 10907.94 10706.59
2.00 1.783 0.704 2.533 2.535 25.453 17.970 25.416 17.968 10681.72 10896.97 10698.30
3.00 1.913 0.756 2.531 2.534 25.493 17.972 25.435 17.969 10665.08 10885.98 10689.99
4.00 2.052 0.811 2.529 2.533 25.534 17.974 25.455 17.970 10648.40 10874.97 10681.67
5.00 2.199 0.870 2.527 2.532 25.576 17.977 25.475 17.971 10631.67 10863.95 10673.34
6.00 2.356 0.933 2.524 2.531 25.620 17.979 25.496 17.972 10614.90 10852.90 10664.99
7.00 2.522 1.000 2.522 2.530 25.665 17.981 25.517 17.973 10598.08 10841.84 10656.63
8.00 2.698 1.071 2.520 2.529 25.711 17.984 25.538 17.974 10581.23 10830.76 10648.25
9.00 2.885 1.146 2.517 2.528 25.759 17.986 25.560 17.976 10564.32 10819.65 10639.86
10.00 3.083 1.226 2.515 2.526 25.808 17.988 25.583 17.977 10547.37 10808.53 10631.45
11.00 3.293 1.311 2.512 2.525 25.859 17.990 25.606 17.978 10530.38 10797.39 10623.03
12.00 3.515 1.401 2.509 2.524 25.911 17.993 25.629 17.979 10513.34 10786.23 10614.59
13.00 3.750 1.496 2.507 2.523 25.964 17.995 25.653 17.980 10496.25 10775.05 10606.14
14.00 3.999 1.597 2.504 2.522 26.019 17.997 25.678 17.981 10479.12 10763.86 10597.67
15.00 4.261 1.704 2.501 2.520 26.075 18.000 25.703 17.982 10461.94 10752.64 10589.19
16.00 4.539 1.817 2.498 2.519 26.133 18.002 25.728 17.984 10444.71 10741.40 10580.69
17.00 4.832 1.936 2.496 2.518 26.192 18.004 25.754 17.985 10427.44 10730.15 10572.17
18.00 5.141 2.063 2.493 2.516 26.252 18.006 25.780 17.986 10410.11 10718.87 10563.64
19.00 5.468 2.196 2.490 2.515 26.314 18.009 25.807 17.987 10392.74 10707.57 10555.10
20.00 5.812 2.337 2.487 2.514 26.377 18.011 25.834 17.988 10375.33 10696.26 10546.54
21.00 6.175 2.486 2.484 2.512 26.442 18.013 25.861 17.989 10357.86 10684.92 10537.96
22.00 6.557 2.643 2.481 2.511 26.508 18.016 25.890 17.990 10340.34 10673.56 10529.37
23.00 6.959 2.809 2.478 2.510 26.575 18.018 25.918 17.992 10322.77 10662.19 10520.76
24.00 7.382 2.983 2.475 2.508 26.644 18.020 25.947 17.993 10305.16 10650.79 10512.14
25.00 7.828 3.167 2.472 2.507 26.714 18.022 25.977 17.994 10287.49 10639.38 10503.50
26.00 8.296 3.361 2.468 2.505 26.785 18.025 26.007 17.995 10269.77 10627.94 10494.84
27.00 8.789 3.565 2.465 2.504 26.858 18.027 26.037 17.996 10252.00 10616.48 10486.17
28.00 9.306 3.780 2.462 2.502 26.932 18.029 26.068 17.997 10234.18 10605.00 10477.48
29.00 9.849 4.006 2.459 2.501 27.008 18.032 26.099 17.998 10216.31 10593.50 10468.77
30.00 10.420 4.243 2.456 2.500 27.085 18.034 26.131 18.000 10198.39 10581.98 10460.05
31.00 11.018 4.493 2.452 2.498 27.163 18.036 26.163 18.001 10180.41 10570.44 10451.31
32.00 11.646 4.755 2.449 2.497 27.243 18.038 26.196 18.002 10162.38 10558.88 10442.56
33.00 12.304 5.031 2.446 2.495 27.324 18.041 26.229 18.003 10144.30 10547.30 10433.78
34.00 12.994 5.320 2.442 2.494 27.407 18.043 26.263 18.004 10126.16 10535.69 10424.99
35.00 13.716 5.624 2.439 2.492 27.491 18.045 26.297 18.005 10107.97 10524.07 10416.19
36.00 14.473 5.942 2.436 2.491 27.576 18.047 26.331 18.006 10089.72 10512.42 10407.36
37.00 15.265 6.276 2.432 2.489 27.663 18.050 26.366 18.008 10071.42 10500.75 10398.52
38.00 16.094 6.626 2.429 2.487 27.751 18.052 26.402 18.009 10053.06 10489.06 10389.67
39.00 16.962 6.993 2.426 2.486 27.840 18.054 26.438 18.010 10034.65 10477.35 10380.79
40.00 17.868 7.377 2.422 2.484 27.931 18.057 26.474 18.011 10016.18 10465.61 10371.90
41.00 18.816 7.779 2.419 2.483 28.023 18.059 26.511 18.012 9997.65 10453.86 10362.99
42.00 19.806 8.200 2.415 2.481 28.117 18.061 26.549 18.013 9979.07 10442.08 10354.06
43.00 20.841 8.641 2.412 2.480 28.212 18.063 26.586 18.014 9960.42 10430.28 10345.11
44.00 21.921 9.102 2.408 2.478 28.309 18.066 26.625 18.016 9941.72 10418.46 10336.15
45.00 23.048 9.584 2.405 2.476 28.406 18.068 26.663 18.017 9922.96 10406.61 10327.17
46.00 24.224 10.087 2.401 2.475 28.506 18.070 26.703 18.018 9904.15 10394.74 10318.17
47.00 25.451 10.614 2.398 2.473 28.606 18.072 26.742 18.019 9885.27 10382.85 10309.15
48.00 26.730 11.163 2.394 2.472 28.708 18.075 26.782 18.020 9866.33 10370.94 10300.11
49.00 28.064 11.737 2.391 2.470 28.811 18.077 26.823 18.021 9847.33 10359.00 10291.05
50.00 29.453 12.337 2.387 2.468 28.916 18.079 26.864 18.022 9828.27 10347.05 10281.98
51.00 30.900 12.962 2.384 2.467 29.022 18.081 26.906 18.024 9809.15 10335.06 10272.89
52.00 32.407 13.614 2.380 2.465 29.130 18.084 26.947 18.025 9789.96 10323.06 10263.78
53.00 33.976 14.295 2.377 2.464 29.239 18.086 26.990 18.026 9770.71 10311.03 10254.64
54.00 35.608 15.004 2.373 2.462 29.349 18.088 27.033 18.027 9751.40 10298.98 10245.49
55.00 37.307 15.743 2.370 2.460 29.461 18.091 27.076 18.028 9732.03 10286.90 10236.33
56.00 39.073 16.513 2.366 2.459 29.574 18.093 27.120 18.029 9712.59 10274.80 10227.14
57.00 40.909 17.315 2.363 2.457 29.688 18.095 27.164 18.030 9693.08 10262.68 10217.93
58.00 42.818 18.150 2.359 2.455 29.804 18.097 27.209 18.031 9673.51 10250.54 10208.70
59.00 44.801 19.020 2.356 2.454 29.921 18.100 27.254 18.033 9653.88 10238.36 10199.46
60.00 46.861 19.924 2.352 2.452 30.040 18.102 27.300 18.034 9634.18 10226.17 10190.19
61.00 49.001 20.865 2.348 2.450 30.160 18.104 27.346 18.035 9614.40 10213.95 10180.90
62.00 51.222 21.844 2.345 2.449 30.282 18.106 27.393 18.036 9594.57 10201.71 10171.59
63.00 53.526 22.862 2.341 2.447 30.404 18.109 27.440 18.037 9574.66 10189.44 10162.27
64.00 55.918 23.920 2.338 2.445 30.528 18.111 27.487 18.038 9554.68 10177.15 10152.92
65.00 58.398 25.019 2.334 2.444 30.654 18.113 27.535 18.039 9534.64 10164.83 10143.55
66.00 60.971 26.161 2.331 2.442 30.781 18.115 27.584 18.041 9514.52 10152.49 10134.16
67.00 63.637 27.347 2.327 2.440 30.909 18.118 27.633 18.042 9494.33 10140.12 10124.75
68.00 66.401 28.578 2.323 2.439 31.039 18.120 27.682 18.043 9474.07 10127.73 10115.32
69.00 69.264 29.856 2.320 2.437 31.170 18.122 27.732 18.044 9453.74 10115.31 10105.87
70.00 72.230 31.182 2.316 2.435 31.303 18.124 27.782 18.045 9433.33 10102.86 10096.40
71.00 75.302 32.558 2.313 2.433 31.437 18.127 27.833 18.046 9412.86 10090.40 10086.91
72.00 78.482 33.986 2.309 2.432 31.572 18.129 27.884 18.047 9392.30 10077.90 10077.39
73.00 81.774 35.466 2.306 2.430 31.709 18.131 27.936 18.048 9371.67 10065.38 10067.85
74.00 85.180 37.000 2.302 2.428 31.847 18.133 27.988 18.050 9350.97 10052.83 10058.30
75.00 88.703 38.589 2.299 2.427 31.986 18.136 28.040 18.051 9330.19 10040.26 10048.72
76.00 92.347 40.237 2.295 2.425 32.127 18.138 28.094 18.052 9309.33 10027.66 10039.11
77.00 96.115 41.943 2.292 2.423 32.269 18.140 28.147 18.053 9288.39 10015.04 10029.49
78.00 100.010 43.710 2.288 2.421 32.413 18.142 28.201 18.054 9267.37 10002.38 10019.84
79.00 104.036 45.540 2.284 2.420 32.558 18.145 28.255 18.055 9246.28 9989.70 10010.17
80.00 108.195 47.434 2.281 2.418 32.704 18.147 28.310 18.056 9225.10 9977.00 10000.48
81.00 112.492 49.394 2.277 2.416 32.852 18.149 28.366 18.058 9203.84 9964.27 9990.76
82.00 116.929 51.422 2.274 2.415 33.001 18.151 28.422 18.059 9182.50 9951.51 9981.03
83.00 121.511 53.519 2.270 2.413 33.152 18.154 28.478 18.060 9161.08 9938.72 9971.27
84.00 126.240 55.688 2.267 2.411 33.303 18.156 28.535 18.061 9139.58 9925.90 9961.48
85.00 131.121 57.931 2.263 2.409 33.457 18.158 28.592 18.062 9117.98 9913.06 9951.67
86.00 136.158 60.249 2.260 2.408 33.612 18.160 28.650 18.063 9096.31 9900.19 9941.84
87.00 141.353 62.644 2.256 2.406 33.768 18.162 28.708 18.064 9074.54 9887.29 9931.99
 88.00 146.711 65.119 2.253 2.404 33.925 18.165 28.766 18.065 9052.69 9874.37 9922.11
89.00 152.236 67.676 2.249 2.403 34.084 18.167 28.826 18.067 9030.75 9861.41 9912.20
90.00 157.932 70.317 2.246 2.401 34.244 18.169 28.885 18.068 9008.73 9848.43 9902.27
91.00 163.802 73.043 2.243 2.399 34.406 18.171 28.945 18.069 8986.61 9835.42 9892.32
92.00 169.851 75.857 2.239 2.397 34.569 18.174 29.006 18.070 8964.40 9822.38 9882.34
93.00 176.083 78.762 2.236 2.396 34.733 18.176 29.066 18.071 8942.10 9809.31 9872.34
94.00 182.503 81.759 2.232 2.394 34.899 18.178 29.128 18.072 8919.70 9796.21 9862.31
95.00 189.113 84.851 2.229 2.392 35.066 18.180 29.190 18.073 8897.21 9783.08 9852.26
96.00 195.919 88.040 2.225 2.391 35.235 18.183 29.252 18.074 8874.63 9769.93 9842.18
97.00 202.926 91.329 2.222 2.389 35.405 18.185 29.315 18.076 8851.95 9756.74 9832.08
98.00 210.137 94.719 2.219 2.387 35.576 18.187 29.378 18.077 8829.17 9743.52 9821.95
99.00 217.556 98.215 2.215 2.385 35.749 18.189 29.442 18.078 8806.30 9730.28 9811.79
100.00 225.190 101.817 2.212 2.384 35.923 18.191 29.506 18.079 8783.32 9717.00 9801.61
2.384 29.506 18.079 9801.61 10337.19
DH*V,H2O,Pr

10913.42
10907.94 Constantes de Antoine (T °C, P mmHg)
10902.45 P° = 10^(A- (B/(C+T)))
10896.95 Compuesto A B C
10891.45 Etanol 8.04494 1554.3 222.65
10885.95
10880.43 Agua 8.10765 1750.286 235
10874.91
10869.39 Constantes de Cp (liq) (T °K)
10863.85 (Cp/R) = A + BT + CT2
10858.32 Compuesto A B C
10852.77 Etanol 33.866 -1.73E-01 3.49E-04
10847.22 Agua 8.712 1.26E-03 -1.80E-07
10841.66
10836.10 Constantes de Cp (vap) (T °K)
10830.53 (Cp/R) = A + BT + CT2
10824.95 Compuesto A B C
10819.37 Etanol 3.518 2.00E-03 -6.02E-06
10813.78 Agua 3.47 1.45E-03 0.00E+00
10808.18
10802.58 D Hvap (T °K)
10796.97 D Hv,2 = D Hv,1 ((1-Tr2)/(1-Tr1))0.375
10791.35 Compuesto Tc Tb D Hvap,Tb
10785.73 Etanol 516.20 351.50 9260.00
10780.10 Agua 647.3 373.15 9717.00
10774.47
10768.82
10763.18
10757.52
10751.86
10746.19
10740.51
10734.83
10729.14
10723.44
10717.74
10712.03
10706.31
10700.59
10694.86
10689.12
10683.37
10677.62
10671.86
10666.10
10660.32
10654.54
10648.75
10642.96
10637.16
10631.35
10625.53
10619.71
10613.88
10608.04
10602.19
10596.34
10590.48
10584.61
10578.73
10572.85
10566.96
10561.06
10555.15
10549.24
10543.32
10537.39
10531.45
10525.50
10519.55
10513.59
10507.62
10501.65
10495.66
10489.67
10483.67
10477.66
10471.65
10465.62
10459.59
10453.55
10447.50
10441.44
10435.38
10429.30
10423.22
10417.13
10411.03
10404.93
10398.81
10392.69
10386.56
10380.41
10374.27
10368.11
10361.94
10355.76
10349.58
10343.39
10337.19
 Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa

1.00

0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.55
0.00

x, Fracción mol del etanol en el líquido

Diagonal L.Op.Enr. q L.Op.Emp Etapas
 DATOS
PAREJA xF yV (xD) xW R TF
1 0.25 0.88 0.08 4 60
2 0.25 0.88 0.08 2 91 Andrea + Veronica
3 0.25 0.88 0.08 1 95 Tzitzijani + Yadira
4 0.35 0.94 0.12 4 85 Diana + Alejandro
5 0.35 0.94 0.12 2 88.3 Gaby + Maricruz
6 0.35 0.94 0.12 1 93 Alexandra + Mariela
7 0.4 0.95 0.15 4 80 Carolina + Martha
8 0.4 0.95 0.15 2 87.05 Maricarmen + Lorena
9 0.45 0.96 0.18 4 80 Nayeli + Ricardo
10 0.45 0.96 0.18 2 85.9 Silvia Yol + Manuel Ale
11 0.45 0.96 0.18 1 90 Oscar

H F ,V  L  H F , L  sat  H L ,  TB ...TF Z L  (1  Z L )DHVap,T   T F

B

PAREJA 1 PAREJA 2
Valor de la pendiente de L.Op.Enr. 0.800 L. Op. De la zona de Enr. 0.667 L. Op. De la zona de Enr.
Valor del Intercepto de L.Op.Enr. 0.1760 Eje X Eje Y 0.2933 Eje X

0.880 0.880 0.880

0.200 0.336 0.200

Valor de q = 1.066 Linea "q" 1.000 Linea "q"

Valor de la pendiente de Linea "q" 16.25617 Eje X Eje Y Eje X

Valor del Intercepto de Linea "q" -3.814044 0.250 0.250000 0.250

0.260 0.412562 0.250

Soluc. De la Ec. L.Op.Enr. Y Lìnea "q" Valor x Valor y Valor x

0.258 0.382522 0.250
L.Op. Z. Empobrec. L.Op. Z. Empobrec.
Valor de la pendiente de L.Op.Empobr. 1.698 Eje X Eje Y 2.235 Eje X

Valor del Intercepto de L.Op.Empobr. -0.0558 0.080 0.080000 -0.0988 0.080

0.258 0.382522 0.250

Trazado de las etapas: Eje X Eje Y Eje X

0.880 0.880000 0.880
0.617 0.880000 0.617
0.617 0.669600 0.617
0.155 0.669600 0.184
0.155 0.207358 0.184
0.025 0.207358 0.039
0.025 -0.013396 0.039

Cálculo de la fracción de etapa:

Area de la última etapa total 0.01434902 0.02349853
Area de la frac. De etapa última 0.01178063 0.01656094
Fracción de etapa última 0.82100592 0.704765
 TB TR HF HL HV q ZL NTeo
91 98.8 1221.016 1891.695 12123.7 1.066 2.821
91 98.8 1891.695 1891.695 12123.7 1.000 2.705
91 98.8 4344.656 1891.695 12123.7 0.7603 0.7500 2.377
88.3 98.8 1848.537 1925.891 12123.7 1.008 4.089
88.3 98.35 1925.891 1925.891 12123.7 1.000 4.862
88.3 98.35 5047.199 1925.891 12123.7 0.6939 0.6790 5.974
87.05 97.9 1772.639 1943.103 12123.7 1.017 4.964
87.05 97.9 1943.103 1943.103 12123.7 1 5.575
85.9 97.4 1813.655 1960.846 12123.7 1.014 6.966
85.9 97.4 1960.846 1960.846 12123.7 1 8.547
85.9 97.4 5231.765 1960.846 12123.7 0.6781 0.6593

PAREJA 2 PAREJA 3 PAREJA 4 PAREJA 5

. Op. De la zona de Enr. 0.500 L. Op. De la zona de Enr. 0.800 L. Op. De la zona de Enr. 0.667
Eje Y 0.4400 Eje X Eje Y 0.1880 Eje X Eje Y 0.3133
0.880 0.880 0.880 0.940 0.940
0.427 0.150 0.515 0.150 0.308

Linea "q" 0.760 Linea "q" 1.008 Linea "q" 1.000

Eje Y -3.171285 Eje X Eje Y 132.8343 Eje X Eje Y

0.250000 1.042821 0.250 0.250000 -46.142 0.3500 0.350000

0.500000 0.150 0.567129 0.3515 0.549251
Valor y Valor x Valor y Valor x Valor y
0.460000 0.164 0.522099 0.35089 0.468715
L.Op. Z. Empobrec. L.Op. Z. Empobrec. L.Op. Z. Empobrec.
Eje Y 5.251 Eje X Eje Y 1.510 Eje X Eje Y 1.855
0.080000 -0.3401 0.080 0.080000 -0.0612 0.12000 0.120000 -0.1026
0.460000 0.164 0.522099 0.35089 0.468715

Eje Y Eje X Eje Y Eje X Eje Y

0.880000 0.880 0.880000 0.940 0.940000
0.880000 0.617 0.880000 0.915 0.940000
0.704667 0.617 0.748500 0.915 0.920000
0.704667 0.232 0.748500 0.850 0.920000
0.312471 0.232 0.556000 0.850 0.868000
0.312471 0.096 0.556000 0.545 0.868000
-0.011647 0.096 0.164010 0.545 0.624000
0.020 0.164010 0.125 0.624000
0.020 -0.235039 0.125 0.127551
0.015 0.127551
 0.015 -0.038580

0.01516388 0.00913722 0.03784719

0.00571271 0.00081178 0.0326298
0.3767313 0.08884298 0.86214587
 NReal

PAREJA 5 PAREJA 6 PAREJA 7

L. Op. De la zona de Enr. 0.500 L. Op. De la zona de Enr. 0.800 L. Op. De la zona de Enr.
Eje X Eje Y 0.4700 Eje X Eje Y 0.1900 Eje X Eje Y

0.940 0.940 0.940 0.940 0.950 0.950

0.150 0.413 0.150 0.545 0.150 0.310

Linea "q" 0.694 Linea "q" 1.017 Linea "q"

Eje X Eje Y -2.267157 Eje X Eje Y 60.72283 Eje X Eje Y

0.350 0.350000 1.143505 0.350 0.350000 -23.88913 0.400 0.400000

0.350 0.546667 0.220 0.644730 0.402 0.521446
Valor x Valor y Valor x Valor y Valor x Valor y
0.350 0.546667 0.243 0.591696 0.402 0.511469
L.Op. Z. Empobrec. L.Op. Z. Empobrec. L.Op. Z. Empobrec.
Eje X Eje Y 3.823 Eje X Eje Y 1.435 Eje X Eje Y

0.120 0.120000 -0.3387 0.120 0.120000 -0.0653 0.150 0.150000

0.350 0.546667 0.243 0.591696 0.402 0.511469

Eje X Eje Y Eje X Eje Y Eje X Eje Y

0.940 0.940000 0.940 0.940000 0.950 0.950000
0.915 0.940000 0.915 0.940000 0.933 0.950000
0.915 0.923333 0.915 0.927500 0.933 0.936400
0.862 0.923333 0.878 0.927500 0.905 0.936400
0.862 0.888000 0.878 0.909000 0.905 0.914000
0.668 0.888000 0.802 0.909000 0.823 0.914000
0.668 0.758667 0.802 0.871000 0.823 0.848400
0.247 0.758667 0.558 0.871000 0.450 0.848400
0.247 0.355594 0.558 0.749000 0.450 0.550000
0.045 0.355594 0.235 0.749000 0.094 0.550000
0.045 -0.019130 0.235 0.559614 0.094 0.069621
0.098 0.559614
0.03587444 0.098 0.035900 0.08550742
0.03494934 0.0824
0.9742128 0.96365908
 PAREJA 8 PAREJA 9 PAREJA 10
0.667 L. Op. De la zona de Enr. 0.800 L. Op. De la zona de Enr. 0.667 L. Op. De la zona de Enr.
0.3167 Eje X Eje Y 0.1920 Eje X Eje Y 0.3200 Eje X

0.950 0.950 0.960 0.960 0.960

0.150 0.417 0.150 0.312 0.150

1.000 Linea "q" 1.014 Linea "q" 1.000 Linea "q"

Eje X Eje Y 70.04559 Eje X Eje Y Eje X

0.400 0.400000 -31.07051 0.450 0.450000 0.450

0.400 0.583333 0.452 0.590091 0.450
Valor x Valor y Valor x Valor y Valor x
0.400 0.583333 0.451 0.553178 0.450
L.Op. Z. Empobrec. L.Op. Z. Empobrec. L.Op. Z. Empobrec.
1.733 Eje X Eje Y 1.375 Eje X Eje Y 1.630 Eje X

-0.1100 0.150 0.150000 -0.0674 0.180 0.180000 -0.1133 0.180

0.400 0.583333 0.451 0.553178 0.450

Eje X Eje Y Eje X Eje Y Eje X

0.950 0.950000 0.960 0.960000 0.960
0.933 0.950000 0.955 0.960000 0.955
0.933 0.938667 0.955 0.956000 0.955
0.905 0.938667 0.945 0.956000 0.947
0.905 0.920000 0.945 0.948000 0.947
0.845 0.920000 0.931 0.948000 0.936
0.845 0.880000 0.931 0.936800 0.936
0.624 0.880000 0.906 0.936800 0.922
0.624 0.732667 0.906 0.916800 0.922
0.214 0.732667 0.8415 0.916800 0.9000
 0.214 0.260933 0.8415 0.865200 0.9000
0.030 0.260933 0.5300 0.865200 0.8500
0.02934187 0.030 -0.058000 0.10467117 0.5300 0.616000 0.03731526 0.8500
0.01686187 0.101152 0.1230 0.616000 0.02041926 0.6600
0.57466919 0.96637882 0.1230 0.101645 0.54720936 0.6600
0.2500
0.2500
0.0360
0.0360
AREJA 10 PAREJA 11
. Op. De la zona de Enr. 0.500 L. Op. De la zona de Enr.
Eje Y 0.4800 Eje X Eje Y

0.960 0.960 0.960

0.420 0.150 0.555

Linea "q" 0.678 Linea "q"

Eje Y -2.107032 Eje X Eje Y

0.450000 1.398164 0.450 0.450000

0.620000 0.330 0.702844
Valor y Valor x Valor y
0.620000 0.352 0.656094
L.Op. Z. Empobrec. L.Op. Z. Empobrec.
Eje Y 2.765 Eje X Eje Y

0.180000 -0.3177 0.180 0.180000

0.620000 0.352 0.656094

Eje Y Eje X Eje Y

0.960000 0.960 0.960000
0.960000 0.955 0.960000
0.956667 0.955 0.957500
0.956667 0.947 0.957500
0.951333 0.947 0.953500
0.951333 0.936 0.953500
0.944000 0.936 0.948000
0.944000 0.922 0.948000
0.934667 0.922 0.941000
0.934667 0.9000 0.941000
0.920000 0.9000 0.930000
0.920000 0.8500 0.930000
0.886667 0.000049 0.8500 0.905000
0.886667 -0.430392 0.6600 0.905000
0.760000 -8783.5102 0.6600 0.810000
0.760000 0.2500 0.810000
0.294074 0.2500 0.373548
0.294074 0.0360 0.373548
-0.054667 0.0360 -0.218156
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

x, FracciónDiagonal
mol del etanol en el líquido
L.Op. Enr.
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

x, FracciónDiagonal
mol del etanol en el líquido
L.Op. Enr.
 1.00 Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

x, Fracción mol del etanol en el líquido

Diagonal
L.Op. Enr.
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

x, FracciónDiagonal
mol del etanol en el líquido
L.Op. Enr.
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

x, FracciónDiagonal
mol del etanol en el líquido
L.Op. Enr.
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

x, FracciónDiagonal
mol del etanol en el líquido
L.Op. Enr.
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

x, Fracción mol del etanol en el líquido

Diagonal
L.Op. Enr.
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

-0.10

x, FracciónDiagonal
mol del etanol en el líquido
L.Op. Enr.
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

x, Fracción mol del etanol en el líquido

Diagonal
L.Op. Enr.
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

-0.10

x, FracciónDiagonal
mol del etanol en el líquido
L.Op. Enr.
 1.00
Diagrama de equilibrio del sistema Etanol-Agua, P = 101.325 kPa
0.95

0.90

0.85

0.80

0.75

0.70

0.65

0.60
y, fracción mol del etanol en el vapor

0.55

0.50

0.45

0.40

0.35

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.00

-0.05

-0.10

x, Fracción mol del etanol en el líquido

Diagonal
L.Op. Enr.