WATER TECHNOLOGY-II
Q.No.1: Write a brief account of lime soda process.
Answer: Water used for industrial purposes such as for steam generation, should be sufficiently pure.
It should, therefore be freed from hardness-producing salts before put to use.
The process of removing hardness-producing salts from water is known as softening of water.
In industry main three external methods employed for softening of water are.
1. Lime-Soda process
2. Zeolite process
3. Ion-Exchange process
LIME-SODA PROCESS: In this method, the soluble calcium and magnesium salts in water
are chemically converted in to insoluble compounds, by adding calculated amount of Lime and Soda.
CaCO3 and Mg(OH)2 so precipitated, these precipitates are filtered off.
Lime soda process mainly two types, they are
1. Cold Lime-soda process
2. Hot Lime-soda process.
COLD LIME SODA PROCESS: In this method, calculated quantity of chemical like lime and soda
are mixed with water at Room temperature. At room temperature, the precipitates formed are finely
divided, so they do not settle down easily and cannot be filtered easily.
Consequently, it is essential to add small amounts of coagulants like alum, aluminum sulphate,
sodium aluminate, etc. Which hydrolyze to flocculent, gelatinousprecipitate of aluminum hydroxide,
and entraps fine precipitates.
Use of sodium aluminate as coagulant also helps the removal of silica as well as oil,
If present in water. Cold L-S process provides water, containing a residual hardness of 50 to 60 ppm.
NaAlO2 + 2H2O NaOH + Al(OH)3
Al2(SO4)3 + 3Ca(HCO3)2 2Al(OH)3 + 3CaSO4 + 6CO2
.
METHOD: Raw water and calculated quantities of chemicals ( Lime + soda + Coagulants) are fed
from the top into the inner vertical circular chamber, fitted with a vertical rotating shat carrying a
number of paddles. As the raw water and chemicals flow down, there is a vigorous stirring and
continuous mixing, whereby softening of water reaches up. The softened water comes into the outer
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co-axial chamber, it rises upwards. The heavy sludge or precipitated floc settles down the outer
chamber by the time the softened water reaches up. The softened water then passes through a filtering
media this is usually made of wood fibres to ensure complete removal of sludge. Filtered soft water
finally flows out continuously through the outlet at the top. Sludge settling at the bottom of the outer
chamber is drawn of occasionally
HOT LIME-SODA PROCESS:
a. The reaction proceeds faster
b. The softening capacity f hot process is increased to many fold
c. The precipitate and sludge formed settle down rapidly and hence, no coagulants are needed
d. Much of the dissolved gases such as CO2 and air driven out of the water
e. Viscosity of softened water is lower, so filtration of water becomes much easier. this in-turn
increases the filtering capacity of filters, and
f. Hot lime-soda process produces water of comparatively lower residual hardness of 15 to 30
ppm.
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2. Anion Exchange Resins: Anion exchange resins are styrene-divinyl benzene or amine-
formaldehyde copolymers, which contains amino, quaternary ammonium or quaternary
phosphonium or tertiary sulphonium groups as an internal parts of the resin matrix. These
after treatment with dilute NaOH solution. Become capable of exchanging their OH- ions
with anions in water.
In ion-exchange process, hard water is allowed to pass through cation exchange resins, which
remove Ca+2 and Mg+2 ions and exchange equivalent amount of H+ ions. Anions exchange resins
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remove bicarbonates, chlorides and sulphates from water exchange equivalent amount of Oh ions.
Thus by passing hard water through cation hardness is observed by the following reactions.
H- And OH- ions, thus released in water from respective cation and anion exchange columns, get
combined to produce water molecules.
H+ + OH- H2O
The water coming out from the exchanger is ion free i.e., free from anions and cations. Thus water of
zero hardness is obtained.
REGENERATION: When cation exchanger losses capacity of producing H+ ions and exchanger
losses capacity of producing OH- ions, they are said to be exhausted. The exhausted cation exchanger
is regenerated by passing it through dilute sulphruric acid.
R2Ca+2 + 2H+ 2RH+ + Ca+2
The exhausted anion exchanger is regenerated by passing a dilute solution of NaOH.
R2SO4-2 + 2OH 2R’OH- + SO
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b. If water contains turbidity, the output of the process is reduced. The turbidity must be below 10
ppm; else it has to be removed by coagulation and filtration.
Q.No.3: Write a brief account of Zeolite process.
Answer: Zeolites are also known as Permutits;
Zeolites are mainly 2 types:
1. Natural zeolites are non-porous, eg. Natrolite- Na2O.Al2O3.4SiO2.2H2O.
2. Synthetic Zeolites are porous and possess gel structure. Sodium zeolites are generally used for
softening of water and are simply represented as Na2Ze, where ‘Ze’ stands for insoluble zeolite. In
the process, when hard water is passed through a bed of zeolite placed in an closed cylinder, the
hardness causing ions like Ca+2 and Mg+2 ions are taken up by the zeolite. Sodium salts are
released during the reaction, as byproduct.
Process: For softening of water by zeolite process, hard water is percolated at a specified rate
through a bed of zeolite, kept in a cylinder. The hardness causing ions like Ca+2, Mg+2 are
retained by the zeolite as CaZe and MgZe; while the outgoing water contains sodium salts.
The various reactions taking place may be
Na2Ze + Ca(HCO3)2 CaZe + 2NaHCO3
Na2Ze + Mg(HCO3)2 MgZe + 2NaHCO3
Na2Ze + MgCl2 MgZe + 2NaCl
Na2Ze + CaCl2 CaZe + 2NaCl
Q.No.4 : What are Boiler troubles? Write short notes on scale & sludge
formation and caustic embrittlement?
Answer: BOILER TROUBLES: In treatment of water complete elimination of all the
impurities is not possible. The impurity that gives rise to certain troubles will be removed to certain
extent. In modern pressure boilers and laboratories, water purer than the distilled water is required.
Some of the boiler troubles caused by the use of unsuitable water are..
1. Carryover – Priming and Foaming
2. Scale formation
3. Boiler corrosion and
4. Caustic embrittlement
Carryover – Priming and Foaming
a. Priming: it may defined as the violent or rapid boiling of water occurring in the boiler which
results in carrying out of water with steam in in the form of a spray.
When a boiler is producing steam rapidly, some particles of liquid water are carried along with
the steam. This process of wet steam formation is called priming.
Priming mainly caused due to very high water level. The presence of large amount of dissolved
solids, high steam velocities, sudden increase in steam production rate. Sudden steam demand
which leads to sudden boiling, presence of excessive foam filling the foam spare, and due to faulty
boiler design.
priming can be controlled by proper boiler design, fitting mechanical steam purifier, avoiding
rapid change in steam-rate, proper evaporation and adequate heating surfaces, uniform distribution
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of fuel and providing anti priming pipes, keeping the water level low and avoid sudden steam
demands. Efficient softening and filtration of the boiler feed water.
b. Foaming: Foaming is the formation of small but stable bubbles above the surface. The main
reason for foaming is being presence of fatty acids and other impurities.
Foaming can be controlled by using anti-foaming chemicals, removal of concentrated boiler
water and replacing it by fresh feed water. Removing oil from boiler water by adding
compounds like sodium aluminate.
DIS-ADVANTAGES:
a. As the sludge’s are poor conductor of heat they cause loss of heat.
b. The working of the boiler is disturbed because of chocking of pipes by the sludge.
PREVENTION:
a. By using well softened water.
b. By drawing off a portion of concentrated water frequently.
SCALES: Scales are hard, adhering precipitates formed on the inner walls of the boilers. They
stick very firmly on to the inner wall surface and are difficult to remove with chisel and hammer.
1. Caustic Embrittlement: The formation of brittle and incrystalline cracks in the boiler
shell is called caustic embrittlement.
It is a type of boiler corrosion and the main reason for this, is the presence of alkali-metal
carbonates and bicarbonates in feed water and also the presence of sodium sulphate.
In lime-soda process, it is likely that, some residual Na2CO3 is still present in the softened water.
This Na2CO3 decomposes to give NaOH and CO2, due to which the boiler water becomes
“Caustic”.
Na2CO3+ H2O NaOH + CO2
This caustic water flows inside the boiler and causes some minutes hair-cracks, by capillary action.
On evaporation of water, the dissolved caustic soda increases its concentration which attacks the
surrounding area, thereby dissolving Iron of boiler as Sodium ferroate.
This causes embrittlement of boiler parts such as bends, joints, reverts etc, due to which the boiler
gets fail. Caustic cracking can be explained by considering the following concentration cell:
Iron at bends,
+
| Concentrated | Dilute NaOH solution | -
Iron at plane surfaces
joints, reverts etc, NaOH solution
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1. Calculate the quantities of lime and soda required in kgs for softening 10,000 lit of water using 82 ppm of
NaAlO2 as coagulant. Analysis of water was as follows:
Cacl2 = 111 ppm; Mg(HCO3)2 = 146ppm; NaCl = 58.5ppm; KCl = 74.5ppm; Dissolved CO2 = 44ppm. (At. Wt
of Na = 23, Mg = 24, K = 39, Ca = 40 and Al = 27)
Ans.
S.No. Constituent Amount(ppm) MF * CaCO3 equivalent
1. CaCl2 111 100/111 100
2. Mg(HCO3)2 146 100/146 100
3. NaCl 58.5
4. KCl 74.5 Do not contribute
5. CO2 44 100/44 100
6. NaAlO2 82 100/164 50
We have to consider atomic weight of metal ion.
74
Lime required = ---- [Mg2+ + CO2 + NaAlO2]
100
74
= ---- [100 + 100 + 50] = 185 mg/lit.
100
So for 10000 lit = 1.85 kg/10000lit.
106 106
Soda required = ---- [Ca2+ + Mg2+] = ---- [100 + 100] = 212 mg/lit
100 100
Calculate the lime and soda needed for softening 50,000 litres of water containing the
following salts: CaSO4 = 136 mg/lit; MgCl2 = 95 mg/lit; Mg(HCO3)2 = 73 mg/lit;
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Ca(HCO3)2= 162 mg/lit. Given that the molar mass of Ca(HCO 3)2 is 162 and that of MgCl2
is 95.
Ans:
74 400
= --- x ---- = 296 mg/l
100 1
106 200
= ---- x ---- = 212 mg/l
100 1
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S.NO
LIME-SODA PROCESS PERMUTIT/ZEOLITE
1 Water treatment plant occupies more area Water treatment plant occupies less area.
or place.
2 Water after treatment has lesser dissolved Water after treatment has much more dissolved
solids. solids.
3 This method of water treatment plants is This method of water treatment plants is more
not much expensive and material used is expensive and material used for softening is
cheap. expensive.
5 The cost incurred on softening of water is The cost incurred on softening of water is low.
high.
6 It cannot operate in under pressure. It can even operate in under pressure.
7 It can be used for treating acidic water This method of softening the water is not used for
also. treating acidic water.
8 There is a problem of settling, coagulation There is no problem of settling, coagulation and
and removal of sludge. removal of sludge.
10 In order to meet the changing hardness of Control test comprises only in checking the
incoming water, frequent control and hardness of treated-water.
adjustment of reagents is needed.
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S.NO
LIME-SODA PROCESS ION-EXCHANGE/RESIN
1 Water treatment plant occupies more area Water treatment plant occupies less area.
or place.
2 Water after treatment has lesser dissolved Water after treatment free from dissolved
solids. solids
3 This method of water treatment plants is This method of water treatment plants is more
not much expensive and material used is expensive and material used for softening is
cheap. expensive.
5 The cost incurred on softening of water is The cost incurred on softening of water is high
high.
6 It cannot operate in under pressure. It can even operate in under pressure.
7 It can be used for treating acidic water It can be used for treating acidic and alkaline
also. water also.
8 There is a problem of settling, coagulation There is problem of turbidity.
and removal of sludge.
10 In order to meet the changing hardness of Control test comprises only in checking the
incoming water, frequent control and hardness of treated-water.
adjustment of reagents is needed.
12 It is not good for boilers It is very good for treating water for use in high
pressure boilers.
13 Skilled persons required It required less skill for maintenance as well as
operation
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