Researchers:
Salvo, Isabella
Tuazon, Bea
in Investigatory Project
At
Presented to:
Acknowledgement………………………………………………………………………..3
Abstract…………………………………………………………………………………...5
Introduction……………………………………………………………………………….5
Background………………….……………………………………………………………5
Hypotheses……………………………..…………………………………………………7
Materials………………………………………………………………………………….11
Methodology……………………...………………………………………………………13
Results……………………………………………………………….……………………17
Data………………………………………………………………………….……………17
Summary………………………………………………………………….………………19
Conclusion………………………………………………………………………..………19
Recommendation……………………………………………………….…………………19
References…………………………………………………………...……………………20
ACKNOWLEDGEMENT
We, the researchers, would like to extend our deepest gratitude and appreciation to the
following people who helped and contributed for the completion of this study. We are grateful
for your help and effort which made this research a success.
To our Investigatory Project teacher, Mr. Jerby Salazar, for his continuous support,
encouragement and for helping us improve our paper, proponent and research paper. In addition,
for teaching and guiding us in the fundamentals of an Investigatory Project and for being very
To our friends and classmates on 12-STEM, for being considerate and helpful towards
our experiment and for being the source of our laughter which makes everything lighter. We
Mikkaela Guzman and Aaron Arevalo, for extending their help at any given time, may it
Aingeal Ocampo, for helping us in editing the research paper and for contributing in
Ghenrae Dela Cruz, Paul Vincent Borabon, A-z Closkey Lopez, Rocel Alonso and Angelo
Arsolon, for being enthusiastic in helping powderize the green mussel shells (Perna viridis) even
To our Physics teacher, Mrs. Ruby Pineda, for letting us borrow the apparatuses in the
Chemistry Laboratory.
To our Adviser, Mr. Andrew Guarin, for encouraging, supporting and inspiring us to
To our parents and family, for the love and for being very supportive in our research,
Most importantly, praises to God, the Almighty Father, for His abundant showers of
courage, knowledge, patience, strength and wisdom. Without His guidance, this research would
Lastly, to each and everyone who took part in making this research possible.
ABSTRACT
composed of three layers; the inner iridescent layer made of calcium carbonate (CaCO3 )
, the prismatic layer made of chalky white crystals of calcium carbonate in a protein
matrix and the periostracum, the outer layer which resembles a skin based from its
pigment. This study is about using green mussel shells (Perna viridis) as an additive in
making more durable and sustainable cement bricks since it is often thrown away and
regarded as wastes. According to a study of Gil-Lim et. al., (2002), The experimental
construction material; which proves that shells can be an effective additive to making
bricks and can be a replacement to sand, which is often added in the mixture in making
bricks. The study only focuses on adding the powderized, burned and coarse-grained
green mussel shells (Perna viridis) in to pure cement mixture and conduct a drop test
from 20 inches (50.8 centimeters) to 169 inches (429.26 centimeters) height to compare
the durability of each mixtures. It came up with a positive result that the adding of green
mussel shells (Perna viridis) is indeed a great help in consolidating a brick. This could
cause a radical change in the production of bricks since the discovery could make better
improvement to the architecture of every infrastructure and establishments that every city
have.
CHAPTER I: THE STUDY AND ITS BACKGROUND
I. Introduction
Green Mussels or “Tahong” as we know is a delicious Filipino food that can be served in
our dining table. After we finished eating, we just throw the shells away not knowing what it can
do and what can be the better purpose of those shells. We think of a way that this garbage will
lessen and those shell will be beneficial to us. We conducted a project in which the waste of our
so called “Tahong” shells will be used as an additive to cement brick to make it even stronger.
We conducted this project to help reduce the green mussel shells (Perna viridis) waste that can
A. Background
to the family Mytilidae which consists of small to large saltwater mussels and marine
bivalve mollusks in the order Mytiloida. These can be found worldwide but it is usually
abundant in colder parts of the seas in the Asian-Pacific region. The shell is mainly
composed of three layers; the inner iridescent layer made of calcium carbonate (CaCO3 )
, the prismatic layer made of chalky white crystals of calcium carbonate in a protein
matrix and the periostracum, the outer layer which resembles a skin based from its
pigment.
On the other hand, brick is a type of building material that is commonly used in
making walls, pavements and also used in architectural projects and designs. It is more of
an old material that was commonly used back then. Bricks are made of clay, but other
elements can be used as well, such as⎼sand, lime or concrete materials. Calcium
carbonate ( CaCO3 ) is a chemical compound that is found in rocks just like in Calcite,
Aragonite and most importantly, Limestone. Since bricks need a little amount of
finely-powdered limestone, it enables silica (of a required portion) which makes the
particles of the brick stick together resulting in a strong and durable brick that can now be
The foundation of the infrastructures around us should be stable and sturdy. The
physique of every house should be the primary concern since weak foundations could be
a danger for the people inside and around. The green mussel shells (Perna viridis) or
commonly known as 'Tahong’ are often disposed and regarded as wastes. We have come
up to an idea to recycle the shells and innovate more durable cement bricks. Moreover,
1. What are the effects when green mussel shells (Perna viridis) are added to
cement?
4. What is the difference between powdered and burned/heated green mussel shells
(Perna viridis)?
5. What height will the brick made of green mussel shells (Perna viridis) and pure
C. Hypotheses
The alternative hypothesis is the g reen mussel shell (Perna Viridis) is found to be
an effective compound in making more durable and sustainable cement bricks; green
mussel shells, when powderized and mixed with the cement mixture create a strong and
compact brick.
The null hypothesis would be the green mussel shell (Perna Viridis) is found to be a less
effective and less efficient additive compound in making cement bricks. The green
mussel shells did not mix well with the mixture which resulted into an unsteady and weak
cement brick. This made the rupturing of the brick easier compared to pure cement
bricks.
This would contribute to more effective, durable and cost efficient product. The
rise of demand in concrete bricks or hollow blocks because of government projects, mall
expansions, and other commercialized buildings justifies the need of budget-friendly and
improving this product and can hopefully give others an idea to innovate
limited, this study could help them in creating an idea to further improve
the product which they could use for building houses, architectures, etc.
family that recycling wastes is essential and beneficial to the world. They
could teach their students and inspire them to innovate more products that
This study mainly focuses on the effects of adding different types of green mussel
shells (Perna Viridis) ; namely coarse-grained, burned and powderized in a pure cement
mixture in attempting to make the cement bricks stronger. The data that will be collected
will come from testing and comparing the durability of the brick with the added green
mussel shells (Perna viridis) against ordinary (pure cement) bricks by conducting a drop
test. The results would determine if the null hypothesis should be accepted.
Arroyo et al. (2005), conducted a study on the feasibility of mollusk shell based
powdered mollusk shell, and tackifier in an elastomer and toluene mixture. (DOST
In Southern coast of Korea, oyster shell had been illegally disposed on the oyster
farm near the sea shore. To seek for the possibility of the wastes to recycled, the
mechanical and chemical property of the crushed oyster shell had been investigated. The
research project to produce structural lightweight concrete using solid waste, namely the
oil palm shell, as a coarse aggregate. Reported in this paper are the compressive strength,
bond strength, modulus of elasticity and flexural behavior of oil palm shell concrete. It
was found that although oil palm shell concrete has a low modulus of elasticity, full-scale
mussel, and mollusk) when transformed into powder can be utilized as partial substitute
for Portland cement in masonry cement mortar as evidenced by its similar physical,
chemical and mechanical properties, especially its workability, specific gravity, and
compressive strength.
Characterization of calcium carbonate obtained from oyster and mussel shells and
incorporation in polypropylene
Hamester, Rosa, Balzer, Santos, & Becker (2012) explains in their study that
oyster shells and mussels-where green mussel shells (Perna viridis) classify, contains
high content of calcium carbonate (CaCO3 ) . With this compound, the shells could be
making construction materials. Their main objective in this study was to obtain or extract
calcium carbonate (CaCO3 ) from oyster and mussel shells which they will use as filler
MATERIALS
additive to cement bricks. The approach used on this study is experimental. The null
hypothesis of this study would be accepted if the results from the test shows that the brick
made from both cement and green mussel shells (Perna Viridis) is more prone to
The green mussel shells (Perna Viridis) used in this study weighed one and
one-half (1½) kilograms and were bought and collected in Bagong Pagasa Wet Market,
The cement powder used weighed two (2) kilograms and was bought from R.C
Talucod Hardware located at 149, 1105 Ilocos Sur, Bago Bantay, Quezon City.
1. Pure cement,
4. Cement with burned and crushed green mussel shells (Perna Viridis) .
The green mussel shells (Perna Viridis) were pounded using mortar and pestle.
The shells were categorized into three (3): powderized, burned and coarse-grained. The
powderized green mussel shells (Perna Viridis) were extracted using the strainer to
prevent coarse-grained green mussel shells (Perna Viridis) from getting mixed.
Figure A. Pounding of green mussel shells (Perna viridis) using mortar and pestle
Figure B. Pouring small portions (10mL) of distilled water from beaker to beaker
Figure C. Putting fixed amounts of cement and green mussel shells (Perna viridis) on the
mould
There are four (4) moulds for each mixture. The moulds have a dimension of 6
cm x 10 cm x 3.4 cm. The first mould was used for the mixture of pure cement. It
The second mould was used for the mixture of cement and powderized green
mussel shells (Perna Viridis). It consists of four (4) - ⅛ cups or 30 mL of cement powder,
two (2) - ⅛ cups or 30 mL of powderized green mussel shells (Perna Viridis) and 60 mL
of distilled water.
The third mould was used for the mixture of cement and burned green mussel
shells (Perna Viridis) . It consists of two (2) - ⅛ cups or 30 mL of cement powder, two (2)
water.
Lastly, the fourth mould was used for the mixture of cement powder and
coarse-grained green mussel shells (Perna Viridis). The mixture is made up of two (2) -
Figure E and Figure F. The final products; mixture of cement with coarse-grained, crushed and burned
Figure G, Figure H, and Figure I. Burned, Coarse-grained and Powderized green mussel shells (Perna
viridis)
CHAPTER IV: Presentation, Analysis and Interpretation of Data
Results
Given the data below, pure cement (4:4) shows no fragments or shattered pieces between
the given height of 40 in up to 60 in. While in the height of 20 in. there were only one shattered
fragments. Slightly crushed (1:1) shows no shattered fragments in the given height of 20 in. but
in the given height of 40 in. and 50 in. shows few shattered pieces and were recorded, while in
the given height of 60 in. there were visible cracks that were found. Slightly crushed (1:2) shows
no shattered pieces or fragments within the given height of 20 in. to 60 in. Slightly crushed (1:4)
with the given height of 20 in. shows no shattered pieces or fragments. While with the given
height of 40 in. to 60 in. shows that there were shattered pieces or fragments recorded during the
drop test. Powderized (1:1) shows no shattered pieces or fragments were recorded during the
drop test. Powderized (1:4) only the 20 in height shows no shattered pieces were recorded during
the drop test, while in the given height of 40 in. too 60 in, there were shattered pieces or
Based on the video documentation of the second drop test and its results, the mixture of
powdered green mussel shells (Perna viridis) and cement showed great results which made this
mixture rank 1st or the most durable. The mixture of pure cement brick ranked 2nd most durable
in the four (4) mixtures. Due to the fact that the fragments or pieces of the broken cement brick
still remained compact and there was no powder shown. The 3rd was the slightly crushed green
mussel shells (Perna viridis) mixed with cement, which showed traces of powder from the
fragments of the brick; and lastly, the burned green mussel shells (Perna viridis) which
Slightly Crushed
Green Mussel Shells x few shattered pieces few shattered pieces some shattered
(1:1) pieces; visible cracks
found
Slightly Crushed
Green Mussel Shells x x x x
(1:2)
Slightly Crushed
Green Mussel Shells x few shattered pieces some shattered few shattered pieces
(1:4) pieces; visible cracks
found
Powderized Green
Mussel Shells (1:1) x x x x
Powderized Green
Mussel Shells (1:2) x x x little to no amount of
shattered pieces
Powderized Green
Mussel Shells (1:4) x few shattered pieces few shattered pieces few shattered pieces
Slightly Crushed Green some shattered pieces; huge cleavage formed; completely
Mussel Shells (1:1) visible cracks found susceptible to breakage broken/damaged
Slightly Crushed Green very little amount of very little amount of few shattered pieces
Mussel Shells (1:2) shattered pieces shattered pieces
Powderized Green Mussel few shattered pieces few shattered pieces few shattered pieces
Shells (1:2)
Powdered Green Mussel some shattered pieces; huge cleavage formed; few shattered pieces
Shells (1:4) visible cracks found susceptible to breakage
Slightly Crushed Green Mussel Shells Broken in fragments varying to small and large;
some powder are visible
Powdered Green Mussel Shells Most parts still compact; broken in half; could be
because of the fracture formed in the middle
Burned Green Mussel Shells Broken; in powder form; few small chunks of
cement are visible
Summary
The first drop test, which consists of green mussel shells (Perna viridis) in different types
and ratios mixed with cement showed a variety of results. The mixture made of green mussel
shells (Perna viridis) and cement (1:1) performed well in a drop test with a height starting from
50.8 cm (20 in) to 429.26 cm (169 in) showing little to no fragments compared to pure cement
brick (4:4). This only proves that even the pure cement brick, originally made of more cement (4
spoonfuls) is expected to perform better than the mixture of powdered green mussel shells
(Perna viridis) [1 spoonful cement:1 spoonful green mussel shells (Perna viridis) ]
On the second drop test, with rectangular bricks being tested, the powdered green mussel
shells (Perna viridis) still showed a remarkable performance among other bricks due to its
Conclusions
Based on the results gathered from the data of the two (2) drop tests, the brick made of
powdered green mussel shell (Perna viridis) and cement is found to be more durable than pure
Recommendations
For future studies and for improvements, the researchers would suggest to find a better
way of powderizing the green mussel shell (Perna viridis) since it is time-consuming; Moreover,
find a way to eliminate the odor of the bricks made of cement and green mussel shells (Perna
viridis); Test the durability of the green mussel shells (Perna viridis) in other ways such as in
wet areas; prolonged exposure to sun; its capability to withhold pressure and/or mass; and make
larger bricks made of green mussel shells (Perna viridis) to further test its durability.
References
1. https://www.ijert.org/research/powdered-shell-wastes-as-partial-substitute-for-masonry-c
ement-mortar-in-binder-tiles-and-bricks-production-IJERTV5IS070063.pdf
2. https://ejournals.ph/article.php?id=9170
3. https://www.science.gov/topicpages/g/green+shell+mussel
4. http://shodhganga.inflibnet.ac.in/bitstream/10603/23015/7/07_chapter2.pdf
5. Hamester, Michele Regina Rosa, Balzer, Palova Santos, & Becker, Daniela. (2012).
Characterization of calcium carbonate obtained from oyster and mussel shells and
2012.https://dx.doi.org/10.1590/S1516-14392012005000014