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EQUILIBRIO AGUA Y 1-BUTANOL

Se trabajó para un proceso


isobárico
Vapor-Liquid Equilibrium Data
The experimental data shown in these pages are freely available and have been published
already in the DDB Explorer Edition. The data represent a small sub list of all available data in
the Dortmund Data Bank. For more data or any further information please search the
DDB or contact DDBST.

Vapor-Liquid Equilibrium Data Set 1133


Components

No. Formula Molar Mass CAS Registry Number Name


1 H2O 18.015 7732-18-5 Water
2 C4H10O 74.123 71-36-3 1-Butanol

Constant Value

Pressure 101.33 kPa

Data Table

T [K] x1 [mol/mol] y1 [mol/mol]


384.65 0.03900 0.26700
383.75 0.04700 0.29900
382.75 0.05500 0.32300
381.95 0.07000 0.35200
371.05 0.25700 0.62900
370.35 0.27500 0.64100
369.85 0.29200 0.65500
369.45 0.30500 0.66200
366.65 0.49600 0.73600
366.55 0.50600 0.74000
366.05 0.55200 0.75000
366.05 0.56400 0.75200
366.05 0.57100 0.74800
365.95 0.57700 0.75000
365.85 0.97500 0.75200
366.15 0.98000 0.75600
365.95 0.98200 0.75800
366.55 0.98500 0.77500
366.55 0.98600 0.78400
366.85 0.98800 0.80800
368.55 0.99200 0.84300
369.95 0.99400 0.88400
371.45 0.99700 0.92900
371.55 0.99800 0.95100
372.55 0.99900 0.98100

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
Hull C.M.: Vapor-Liquid Equilibria and Boiling-Point Composition Relations for Systems n-
Butanol-Water and Isobutanol-Water. Ind.Eng.Chem. Ind.Ed. 23 (1931) 1438-1440

Vapor-Liquid Equilibrium Data Set 1134


Components

No. Formula Molar Mass CAS Registry Number Name


1 H2O 18.015 7732-18-5 Water
2 C4H10O 74.123 71-36-3 1-Butanol

Constant Value

Temperature 298.15 K

Data Table

P [kPa] x1 [mol/mol] y1 [mol/mol]


0.928 0.00000 0.00000
2.557 0.15000 0.68820
3.409 0.30000 0.79000
3.716 0.51240 0.82530
3.716 0.98120 0.82530
3.516 0.99000 0.88740
(P - pressure, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source
MacLennan W.N.: Part III. The Theory of Binary Solutions, and its Application to Aqueous-
Alcoholic Solutions.. J.Chem.Soc.London (1933) 674-686

Vapor-Liquid Equilibrium Data Set 1135


Components

No. Formula Molar Mass CAS Registry Number Name


1 H2O 18.015 7732-18-5 Water
2 C4H10O 74.123 71-36-3 1-Butanol

Constant Value

Pressure 102.26 kPa

Data Table

T [K] x1 [mol/mol] y1 [mol/mol]


384.10 0.05000 0.25300
380.00 0.09200 0.38800
379.55 0.09700 0.40200
374.00 0.18100 0.55600
369.80 0.29100 0.66000
369.50 0.30300 0.66600
367.15 0.41700 0.72400
366.17 0.54600 0.75000
366.15 0.55000 0.75300
365.85 0.75200 0.75400
365.91 0.90200 0.75400
365.95 0.98000 0.76000
366.00 0.98100 0.76300
368.55 0.99100 0.83900
368.95 0.99200 0.85000

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference
Source
Bonner R.F.: Vapor-Liquid Equilibrium Still for Partially Miscible Liquids. Ind.Eng.Chem. 41
(1949) 2867-2871

Diagrams

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Tomado de la pagina web:

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EQUILIBRIO ACETONA Y 2-
PROPANOL
Se trabajo para un proceso
isotérmico
Vapor-Liquid Equilibrium Data
The experimental data shown in these pages are freely available and have been published
already in the DDB Explorer Edition. The data represent a small sub list of all available data in
the Dortmund Data Bank. For more data or any further information please search the
DDB or contact DDBST.

Vapor-Liquid Equilibrium Data Set 591


Components

No. Formula Molar Mass CAS Registry Number Name

1 C3H6O 58.080 67-64-1 Acetone

2 C3H8O 60.096 67-63-0 2-Propanol

Constant Value

Temperature 298.15 K

Data Table

P [kPa] x1 [mol/mol] y1 [mol/mol]

5.906 0.00000 0.00000

13.332 0.17500 0.59900

18.612 0.33900 0.73500

22.291 0.51400 0.79800

25.331 0.66900 0.85500

29.544 0.83900 0.91000

30.198 1.00000 1.00000

(P - pressure, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source

Chaffee C.S.: Some Physical-Chemical Properties of Mixtures of Acetone and Iso-Propyl Alcohol.
J.Phys.Chem. 31 (1927) 439-447

Vapor-Liquid Equilibrium Data Set 1522


Components

No. Formula Molar Mass CAS Registry Number Name

1 C3H6O 58.080 67-64-1 Acetone

2 C3H8O 60.096 67-63-0 2-Propanol

Constant Value

Temperature 328.15 K

Data Table

P [kPa] x1 [mol/mol] y1 [mol/mol]

34.393 0.02370 0.11660

39.930 0.06420 0.27770

44.208 0.09710 0.36250

52.026 0.15910 0.47620

59.050 0.23530 0.57220

60.848 0.26870 0.60240

69.000 0.38790 0.69950

71.177 0.43140 0.72840

75.068 0.52340 0.76550

80.287 0.60840 0.80980

85.038 0.72160 0.86170

85.942 0.73380 0.87290

91.220 0.85690 0.92400


94.308 0.92140 0.96290

(P - pressure, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source

Pike K.A.: Vapor-Liquid Equilibrium Data for Systems of Acetone-Methanol Isopropanol.


J.Chem.Eng.Data 12 (1967) 179-183

Vapor-Liquid Equilibrium Data Set 1524


Components

No. Formula Molar Mass CAS Registry Number Name

1 C3H6O 58.080 67-64-1 Acetone

2 C3H8O 60.096 67-63-0 2-Propanol

Constant Value

Pressure 101.33 kPa

Data Table

T [K] x1 [mol/mol] y1 [mol/mol]

352.93 0.03590 0.11350

348.56 0.10800 0.30180

346.56 0.14680 0.37930

344.78 0.19270 0.45250

342.47 0.24860 0.52610

338.16 0.39970 0.68600

337.75 0.42150 0.69740


336.95 0.46290 0.72420

334.34 0.60770 0.80810

331.90 0.76910 0.88730

329.93 0.92490 0.96140

(T - temperature, x - liquid mole fraction, y - vapor mole fraction)

Reference

Source

Pike K.A.: Vapor-Liquid Equilibrium Data for Systems of Acetone-Methanol Isopropanol.


J.Chem.Eng.Data 12 (1967) 179-183

Diagrams

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Sacado de la página web:

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