Background of Provisions
Related to DEF Cracking
Reference Material 1 p.113
Reference Material 2 p.115
Reference Material 4 p.129
Shunsuke HANEHARA
Iwate University
Ettringite
One of the cementitious hydrates
formula: 3CaO・Al2O3・3CaSO4・32H2O
It is called and written as AFt
Formation of Ettringite(AFt)
3CaO・Al2O3 3[CaSO4・2H2O]
(Aluminate phase) + (Gypsum or Calcium sulfate) + H2O
In a day
Decomposition of 3CaO・Al2O3・3CaSO4・32H2O
Ettringite formed (Ettringite: AFt)
×
at early age by
heat treatment at The reaction is irreversible
high temperature
3CaO・Al2O3・CaSO4・12H2O After 1 day
(Monosulfate hydrate :AFm)
(Ettrengite:AFt)
formed again:DEF
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Role of C-S-H
JCI Guidelines for Control of Cracking of Mass Concrete 2016
Expantion by DEF
2.5
90℃
2.0 80℃
Expansion(%)
70℃
1.5 60℃
55℃
1.0 50℃
20℃
0.5
0.0
0 50 100 150 200 250
Age(days)
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JCI Guidelines for Control of Cracking of Mass Concrete 2016
・Water contact:
Water plays a fundamental role in the reaction progress of DEF
・High temperature:
When the maximum temperature reaches or exceeds 70°C at
early stage, DEF is more likely to occur.
・Sulfate and alumina content in cement:
The sulfate and aluminate content in cement directly contributes
to the reaction mechanism of ettringite generation.
It is necessary to investigate
the influence of the behavior of water in the ettringite
crystal structure, temperature and relative humidity around
ettringite deposition locations,
the influence of coexistent materials such as C-S-H, and
the interaction between C-S-H and sulfate.
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JCI Guidelines for Control of Cracking of Mass Concrete 2016
Effects図of1.3.2
temperature on SO42- concentration
エトリンガイトと水酸化カルシウム
Effects of temperature on SO42- concentration
図 1.3.3 モノサルフェートと水酸化カルシ
which が安定となる
enable ettringite and calcium hydroxide which enable mono-sulfate hydrate and
SO42-濃度に及ぼす温度の影響 ウムが安定となる SO42-濃度に及ぼす温度
to be stable (solid lines show stable ranges) calcium hydroxide to be stable (solid lines
(実線は両者が安定な範囲を示す) の影響(実線は両者が安定な範囲を示す)
show stable ranges)
Mono sulfate hydrate is stable and easily formed as the result
of ettringite decomposition under high temperature and high
alkali concentration
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JCI Guidelines for Control of Cracking of Mass Concrete 2016
Examples of Deteriorated
Structures Due to DEF around
the World
(referred from Reference
materials 2)
•Size:1.5×8.2×2.7m
•Cracking state: Map and network cracking 0.1mm-several mm
•27years after construction and cast in August.
•at 70°C or higher during about 70 hours by FEM
•Water contact: directly exposed to rainfall and water dripping from the footpaths.
• Cement:CEM I、W/C:50%、content of cement:430kg/m3
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JCI Guidelines for Control of Cracking of Mass Concrete 2016
(2) Main tower foundation (Bridge B)
•Size:11.9×3.0×6.5m
•Cracking state: Cracking 0.1mm-1mm on water level part
• 6 years after construction
• easy contaction to water
•CEM I 52.5N, the cement content 350 kg/m3, W/C: 0.45
•Remained at 70°C or higher during 6 days and cast in August and September
Aggregate
AFt: Ettringite
コアの反射電⼦像
AFt
Aggregate
AFt
60μm 90μm
DEF
DEF and ASR
低熱,高炉B,低熱高炉,フライアッシュB,
C3A:8%
Expansion(%)
TypeⅠ,TypeⅢ,CEMⅠ,CEMⅡ
3.0
膨張量 (%)
C4AF:7%
C3A/C4AF:1.1 2.5
R2O:3.63kg/m3 2.0
SO3:11.8kg/m3 1.5
1.0
0.5
Age (days)
0.0
Fig. Influence of maximum temperature
20 30 40 50 60 70 80 90 100 110
on expansion by DEF
最高温度 (℃)
Maximum temperature of concrete (℃)
ACI 301 committee reported that the long term durability of only
certain concretes can be affected by deleterious chemical reactions
if the concrete temperatures exceed 70°C (it seems to be DEF
while DEF is rare).
Maximum temperature for preventing DEF cracking is specified under 65℃ or 70℃.
The larger the amount of alkali sulfate added, the larger the expansion amount.
It suggests that the promotion of decomposition of ettringite by alkali and the
increase in the amount of initial ettringite produced by SO3 have a large effect on
DEF expansion.
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JCI Guidelines for Control of Cracking of Mass Concrete 2016
Effects図of1.3.2
temperature on SO42- concentration
エトリンガイトと水酸化カルシウム
Effects of temperature on SO42- concentration
図 1.3.3 モノサルフェートと水酸化カルシ
which が安定となる
enable ettringite and calcium hydroxide which enable mono-sulfate hydrate and
SO42-濃度に及ぼす温度の影響 ウムが安定となる SO42-濃度に及ぼす温度
to be stable (solid lines show stable ranges) calcium hydroxide to be stable (solid lines
(実線は両者が安定な範囲を示す) の影響(実線は両者が安定な範囲を示す)
show stable ranges)
Mono sulfate hydrate is stable and easily formed as
the result of ettringite decomposition under high
JCI-RILEM International Workshop, CONCRACK5, April 24-26, 2017, Japan
temperature and high alkali concentration 33
JCI Guidelines for Control of Cracking of Mass Concrete 2016
Expansion (mm/m)
(SO3)2/Al2O3(activ)
(SO3)2/Al2O3(activ)
Reference[14] Reference[2]
DEFindex≧1.1 Some Risk of DEF cracking (SO3)2/Al2O3(activ)≧2 Some Risk of DEF cracking
DEF expansions of mortar prepared with HPC, WPC and OPC with
much amount of C3A to form AFt at early hydration stage are
observed. Mortar prepared with MPC which has less content of C3A
and FA C and BFS C may not expand.
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JCI Guidelines for Control of Cracking of Mass Concrete 2016
Influence of blastfurnace slag and fly ash on preventing
DEF cracking
Blank
Expansion(%)
Packed
Wet air
In water
Packed
Packed
Age (days) In water
Blank
Expansion(%)
Expansion(%)
Reference[13]
TypeⅠ,CEMⅠ
5 HPC, NPC, TypeI, (0.20%)
5.0
R2O量 (kg/m3)
TypeIII,CEMI
(0.80%)
4 4.0 【%】 expansion
( )は膨張量 (0.66%)
3 3.0
2 2.0
セメント種類:
Type of cement:
1 早強・普通・Type I・III・CEM I・IR
HPC, NPC, TypeI, TypeIII,CEMI 1.0
最高温度:80℃~90℃
Max Temp: 80-90℃
0 0.0
0 5 10 15 20 25 30 35 0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0
SO3 量 (kg/m3) Reference[1]-[9] SO3量 (kg/m3) Reference[1]-[9]
In case of concrete prepared with more than 3kg/m3 of R2O or more than 9kg/m3of
SO3may expand by DEF⇒Limitation of maximum temperature must be less than 70℃
In case of concrete prepared with more than 4kg/m3 of R2O and more than 17kg/m3of
SO3may expand by DEF⇒Limitation of maximum temperature must be less than 65℃
(in case of less than 3kg/m3 of R2O and less than 9kg/m3of SO3, Limitation of
maximum temperature may be less than 80℃)
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JCI Guidelines for Control of Cracking of Mass Concrete 2016
Proposal of maximum temperature of concrete to
prevent DEF cracking (II)
65-80℃ of maximum temperature 80-90℃ of maximum temperature
8 8
less than 0.1%
膨張量<0.1% 65℃以上~80℃以下 less than 0.1%
膨張量<0.1%
80℃超~90℃以下
7 More than 0.1% 7 膨張量≧0.1%
More than 0.1%
膨張量≧0.1%
6 6
R2O量 (kg/m3)
R2O量 (kg/m3)
5 5
4 4
3 3
2 2
1 1
Reference[1]-[10] Reference[1]-[10]
0 0
0 5 10 15 20 25 30 0 5 10 15 20 25 30
SO3量 (kg/m )
3
SO3量 (kg/m )
3
In case of less than 3kg/m3 of R2O and less than 9kg/m3of SO3 and less than 80℃ of
maximum temperature, all of concrete may not expand. In case of less than 3kg/m3 of
R2O and less than 9kg/m3of SO3 and 80-90℃ of maximum temperature, some
concrete may expand.
⇒It is difficult to raise the limitation of maximum temperature to 90℃.
39
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JCI Guidelines for Control of Cracking of Mass Concrete 2016
Proposal of limitation of maximum temperature
of concrete at early age to prevent DEF cracking
(1)In case of using HPC and OPC
Ø Concrete prepared with more than 4kg/m3 of R2O and more than
17kg/m3of SO3may expand by DEF⇒less than 65℃
Ø Concrete prepared with more than 3kg/m3 of R2O or more than
9kg/m3of SO3may expand by DEF⇒less than 70℃
Ø In case of less than 3kg/m3 of R2O and less than 9kg/m3of
SO3⇒less than 80℃
6
25
R2O (kg/m3)
SO3 (kg/m3)
5
20
4
15
3
2 10
1 5
0 0
0 5 10 15 20 25 30 35 0 5 10 15
SO3 (kg/m3) C3A (%)
8
less than 0.1% HPC , Type III, CEM IR
In the range of 2% - 12% C3A, Concrete
膨張量<0.1% 早強・Type III・CEM IR
7 More than 0.1%
膨張量≧0.1% with 2% of C3A cement may be expanded
6 more than 0.1%.
Since Concrete expands even below 8% of
R2O (kg/m3)
5
4 C3A in cement, which is the threshold
3
value in France, it is difficult to propose
2
C3A content threshold at this stage.
1
0
0 5 10 15
JCI-RILEM International Workshop, CONCRACK5, April 24-26, 2017, Japan
C3A (%) 41
JCI Guidelines for Control of Cracking of Mass Concrete 2016