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ESAS

PART-4
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REFRESHER Sept:. 20:1..0 (ESAS - 4)


(9 What do you call the phenomenon whereby a short wavelength photon hitting an atom on
the surface of a substance causes an electron to be ejected?
A Quantum effect C. Peltier effect
CJY Photoelectric effect D. Skin effect - ~ .ftn d£11
~n -h> tr1(:Ve. of
E,.:pfal\t~fion: l.o~Atwcwcl ~~·face- 4 ~ ~duw
<9-~fum effi.d =- ~[f e[ecf [f)=- tJ <8/h} 'J::: fll:1~ fu~r 1

P€-1-b er effect =- ~ Cct[tnift-c e{te..ct of Qn elev\Yical CUV'f'e,nt aJ +h.t.


J~nchO'f\ of 'h.w di~ m.zta!.s:
2. Where must an object to be placed in the case of a converging lens of focal length f if the
ig1age is to be virtual and 3 times as large as the object?
Cf) (2/3}/ c. (1/4) f
B. (3/4)/ D. (1/2) f

Solution:

L1~r IYla._gnifiQ:<flbn =- m=
fOr Y\rfvta/ r~gt : ~ =8

t=~ + t -7 ~ = ~ t -~p = 1(~)


(3.'·i A meniscus lens has a convex surface whose radius of curvature is 20 em and concave
·-./ surface whose radius of curvature is 10 em. if the index of refraction is 1.52, what is the
focal length of the lens?
(A)-38.5cm C. +16.5 em
1:3. +48.5 em D. ..,-23.81 em
Solution:
L,,_ f r
tA.'j lefls IVtt:l(<..(IJ e~,

+l=-(h-r){
. 1
,.I f lll
rz.J (ConWKI
.
[ )=-:1?_
J

cu.vve
~·~- ~8
r_ ~ s-
l-=- (t.S2.-r)
f f _r t -
20 -10 ~()
----7
1~
tnwtll.rd
" Cvoncu.ve)
4. What color has the shortest wavelength of light? Cc! 1V'0rlJitl_g l.vls)
A. orange ' r ©blue
B. green D. red
shvrid- J:r, VIblet: .11 ~Ubnm ,
[(-0-Y-G-B-l-V
_,.-- Lon0d f:,. reA ~ /'i =- =1 w t\f'Yl h 19h~- - --®-- -
-7 Low
( 5) A metal string under a tension of 95 N has a length of 75 em and a mass of 0.60 gram.
·~· Determine the frequency in the second overtone.
(A.) 690Hz C. 460 Hz
'tf. 230Hz D. 920Hz
'

li

6. Curie temperature is the temperature above which a ferro-magnetic .material


becomes .
A. diamagnetic C. elt=~ctrOf!lagnetic
®paramagnetic D. superconductor

(!)_A cast i_ron that ~as been cooled quickly from molten state.
@ White cast tron C. Mottled cast iron
B. Malleable cast iron D. Gray 'cast iron
fxpluncthon'. __
IV\().\1-tablt CO.stivn -= pn:>cttAC£.d b~J fehtctkll_~ Whitt CC!St_\rllYl rS'D\) -IKOD'r)
Mottkcl ca.s.t 1\'lll'l :::. COi'l't"Ci!nS both GeMerrRft k 9H{p\ruk be;' whtk~gr7.11)
6rtt~ cast lhll\ =:. mos.-\--CAJYhWlOY\ ~p-t Cf{~t 11-Dn • .i:!
8. What element that improves the strength and ratigue properties of copper?
(!;) Beryllium C. Aluminum
B. Phosphorus D. Zinc

(9:\ Find the gray code of the four digit 2.


. A. 1010 @oo11
B. 1100 D. 1111

Solution;_ k.
6~L1 Cock =- re-Fle.dd c,o clt -1 2
\(.:::NJ2.o{ cltg\l ~ (2')HJ:: (ODIDJz. GY1Jtj0Jf~(001i)--/§)
10. Convert (DC.945) base 16 to base 2.
@101101.1001 c. 101001.1001
B. 101101.1011 D. 101001.1100

Solution: [ -[ -'2.. -:-.3

~·. (1b.94S)r 6 ~(N)~o=- 2.><lb + \3.;<!f"+9x\G+4x\G +~><16


(N)Io-:: (45·:s-~n4'S'"103.1) 1 b =- (!DtlO\ .\OOIJz
(11)What is ASCII means? ~
'~-·A. American Standard Code for Input Information
__.ft, American Standard Code for Information input t.,_ .I ,I
1r· n:.~eg•uphr C
r
(g) American Standard Code for information Interchange ---7 developed
D. American Standard Code for Interchange Information C.Ocle.s ( MDrSe CodeJ
12. All are basic operation in Boolean Algebra EXCEPT:
A. logic addition C. logic multiplication
@ logic subtraction D. logic complementation

13. What refers to the com~uter's use of hard disk storage to stimulate RAM?
A. Volatile memory @ VirtUal memory
8. ROM D. Cache memory

&pia Aatu711: _
':· ' \foi ctti\e M-eMO:l1 =- primo..t!1_.stvrct~e, _de.vrCt, .fh{X)- req~Airts f:bvVBtr- to
1"1/W rvta fn th..e. stu H'.cl mfD rmah t7YI ) (;II\\ i k:t non - vo l C!~ [-e .
il: Cctch-e memo~ :: -us-ectry__ CPU whi-Ch .s\-vres CbpleJ of vta+u 'fYom mort
freq~ u~ m~A!n metttovt1 Low~'ovt
14. A general-purpose computers used in large centralized applications in which several
programs are running simultaneously. . . S cw-t. lCH~ef" C(yfl~tetl U~
A. Supercomputers C. Mtmcomputers f [1'\ bu~~ cto.~ f1\'DCQ..SSin~
B. Microcomputers @Mainframe computers a\:; C\ ~~le... locei-h~
&p!C1111)-h-uru. r
SUpRA-eompvkn =are ex\-rernel~ f'VW~~~ mri~\A~ thcJ. hoVQ~I'!l·e-
~no11tin~1 .suvh· os en.~~· ~lgh 'k_ uholy~t.s. · . _ .
fVttOv comw~-Br-> "' are.- -.SYY\ctU .>10_9\.e- (;t~ CG'M~U~ wlo ex~\W ~rpMro\S
I

k s.~ (e.9. PC)


'

1/
I

I
I'
I ....... ~\

(15;~ost ofthing that are neither labor nor material is ...


"(E) Expenses C. Investment
B. Labor Cost D. Construction Cost

16. A type of bond where the corporation pledges securities which it owns such as the stocks
or bonds on one of its subsidiaries.
A. Common bond ~ Joint bond
B. Mortgage bond (_91 Collateral trust bond
(17)A newly-acquired equipment· requires an annual maintenance cost of P15,000. If the
·- annual maintenance cost is increased by 20% each year every year for 10 yrs. What is the
estimated present worth of the maintenance costs if money is worth 12%.

mT
A. P168,259.02 @P186,295.02
B. P186,925.20 D. P168,925.20

Appl~ Gtctdt~t ·. 0 1 ()
Solution: . G'WI'f\R,tric 2. .J --- n-\
P== _£__
ft i
{~}
f- X
~~v~- zc4,
f2-t
X= 1-+~
I tl
1 j G,
x-::. 1-0il12~ !o p 6(itr) r 1..

p-;: 1JI5sOOD J 1- (!.O:rl42~) l -::.f [26/2.9).02 G~_itr)


( [t0d2.) l [- 1.61-14'2-~ J ' L._jf) .
18. An ammeter has a selling price of P500. If its selling price is expected to decline at a rate
of 10% per annum due to obsolescence, what will be iis selling price after 7 yrs?
<E}P239.15 C. P236.20
B. P293.15 D. P326.20

Solution:

Sl~Q ~ ~~t of- aepr: ~ ~* ~ ~Wr ?tt tD~ at


book. VCi.I!Ae) us.e 1\A.C!~Y\ h1tt1toct : k:. ~ /- m ~ J
() ,[0:: 1- 1-
.- 1i ' (, ~1 co
~D lVl(\__g c1 ::: r SDD l o, 90 f 1.3~. [S -----ilJ
j:::
~ '

~,New generator has just been installed. It is expected that there will be no maintenance
charges until the end ofjhe sixth years, when P300 will be spent at the end of each
successive year until the ger.e-rotor is scrapped at the end of the fourteenth year of
service. What sum of money set a side at the time of instailation of the generator at 6%
..-Jnterest will take care of all maintenance expenses for the generator? Draw the cash flow•.
\A)P1,392.10 C. P2,392.10
B. P1,492.10 D. P1,592.10
Solution: CMH FL~W ~

'~

20. An applicant of Professional Electrical Engineer must submit how many certifications from
different Professional Electrical Engineers to effect that the experience record of the
applicant is factual and the technical paper submitted was actually prepared by the
applicant?
A. 2 .©3
B. 5 D. 4
21. What is Article Ill sec. 16 (c) of R.A. 7920? G)
·. A. He is a citizen of the Philippines ---7 ~ IG 0. r-nc.!G (b)·
B. He is of good reputation with high moral values --? ;,;.. .
C. He is a holder of the degree of Bachelor of Science in Electrical Engil']eering (BSEE)
from universities, school, colleges, academy or institute duly constitute, recognized by
, the Philippine Government --7 bee. lG ((;!.) · ··
(Q) turpitude
He has not
..
b~n finally convicted by the court of an offense involving moral
22. A Registered Master Electrician shall work under a supervision of a Professional EE or
Registered EE if the machinery is rated in excess o f _ kVA a n d _ Volts.
A.. 500, 500 respectively C. 600, 750 respectively
@soo,
----7 se-e. sec. 3.1 cc
600 respectively,) h 11 ""'" 1\
1'-11 17 '-V
D. 750, 1000respective!y

23. What is Article If! sec. 17 (c) of R.A. 7920? t:


A. He is a citizen of the Philippines -7 S€C. [9 \.0..)
B. He is at least twenty-one (21) years of age - t I't (b) s-ec. ·
C. He has not been finally convicted by the court of an offense involving moral turpitude.
D. He is of good reputation with high moral values
-1- re.c li- (d)
24. Refers to the power plant mounted on wheels as used in railroad transportation industry.
A. Electric train C. Railway rolling stack
B. LRT @ Electric locomotive
@what is Ruie 1i in R.A. 7920?
A. Action on Communication ~ l'l.Ale..-10 C. Program of Examination ---1 rtA..Le.- 12.
@ Places and Dates of Examinations
D. Publication of Examination - 7 fv<Lt- J'1
26. What limits the size of an induction motor that can be started across the line?
A. distribution system C. branch circuit protection
@horsepower rating D. frequency rating

,2_7: All switches and circuit breakers used as switches shall be so installed that the center of
the grip of the operating handle when in its highest position shall NOT be more than
1: _ _mm above the floor or working flatform.
,, A. 1,200 C. 2,200
l.l
I, B. 1,500 @ 2,000
~ PEe I (2.0oo~) se.c. J.&-D.l, ~(o.) PP46~
·j~ 28. In Indoor wet locations, the entire wiring system including all boxes, fittings, control boards
] and panelboards shall be installed on walls with a minimum clearance. What is this
clearance?
A. 15 mm
C. 25mm
,I @10mm D. 20 mm
,,·~
I ~
Set- Ftc I (z.ooo.ed) ~. .:1.i:\. [. 2. (!A) PP 4Si
~ut G.4 l'flllJ k. 1Dirlm (s ~~+·
~)In an industrial building, where the actual numbers of general purpose receptacle outlets
~ are unknown, an additional, load o f _ volt-amps per square meter shall be included
in the load calculation.
@o C. 8
B. 6 D. 2
~ PEC 1 (2ooo ed) Table, 2. 20. La Co.)

30. Under the optional method of a calculation for a single-family dwelling, all "other load"
beyond the initial10 kVA is to be assessed at percent.
A. 60 •· ~40
8. 50 D. 75
£:et ~ 1 (2.0ooed r sec. 2{ ?...0 3,1 (b)
1
il!J
"i

I·'
I

(31)Two pulleys 2 ft in diameter· are connected by a belt so that, each has the belt wrap
,. around half of its circumfell.ll'la!. The coefficient of friction between the belt and the pulley
is 0.17. If the tension in the tlght side is 250 lbs, determine the tension in the slack side
when the belt is about to slipc. ·
A. 1751bs C. 1571bs
~1471bs D. 1251bs

Solution: T

~!($) ~:

Solution: Nox : : . 200 em 3'1° =~ .:}'.) frs


GN?U)
'Vo~ -= 20D .cln :3.1° =12.0, .'1o fr-.5
@An automobile goes around a slippery curve of radius 55 m. If the road is banked at an
angle of 16 degrees with the horizontal, at what maximum speed in kph may the
automobile travel to avoid the tendency to skid?
A 47.79 C. 37.79
\.J!)44.79 D. 34.79

Solution:
v:: [2.4.1811 ( J600 %~ -,<-
% hr )

(1~o~h1) -=- 44.~ ~rh


)

I'

I
II
36. What diameter shaft is required to transmit 200 hp at 1850 rpm if the maximum shearing
stress is 10,000 ibf/in 2 and the maximum twist is 1 degree per foot of length? The shaft is
round steel.
A 3.338 inch
B. 3.833 inch
C. 1.145 inch
c:3J1.514 inch .
!j
I,
I
Sol~tion: T:: :n!.ooo liP :::. ~3rOOOJ!2lil ( 2Db 1
=Sl3i, z
i' \lv1+h rr =-- 10, ooo fbfJfil 'L :LJt N 2.:[_ 1<l ')o .rt11 ) lbf- f£
! ~ '

.1'Wtax = __ IG~I -7 cl- .11rr;::r-


~ -::~J [
. r; ~.8 - .J¥t1n
r
'ltcP - ~ '[ C'trnal\J tr(W1oDO lbf)(l2.1o/~)2 = Ot~Uft
d.=- L5l4 inche> -7® · · tn:
,, .o ofu Ch,co'>t-: d.:: I.SI4tr,dtes (qovert~)
i!'
With', v ~ 1I Tt . 'Z. ~

- o . r_:rr_ \ TL - (%1-~-ffi{ tfu( ~) -7 d- i 4'2. '


. -8= 1/ft(r&o·J=J~- !(d:t)(ll.Sx[DG~t) -. 8-rncht5
€J. cylinder of diameter 1.2500 em at 35°C is to slide into a hole on a steel plate. The hole
· has a diameter of 1.2497 em at 35°C. To what temperature the plate must be heated?
Coefficient of linear expansion for steel is 12 x1 0~ per °C.
A 50°C C 60°C
@ssoc D. 57°C

Solution:

dL:: d- D::' 1<1.') -l('Li9t:::. O.OOOJ.eftl


[L -= o( lo (Tf -To )
o,OOD?.>CIYl::: (r2.:x[oG)c)(L1Scm) (Tf-1Soc)
TF = ~OC --7®
38. The "SLENDERNESS RATIO" of a column is generally defined as the ratio of:
A. length to its minimum width . . · '2.
B. unsupported length to its maximum radius of gyration
_J4. length of its moment of inertia
6ct1tl
COl.\ ::
- ('l.
1f E
(_QJ unsupported length to its-ieast radius of gyration lfr)
1 ~ is CCtlled tlttco[utvln '\:{en~s m-Bo u
I
~A single boH is used to lap joint two steel bars together. Tensile force on the bar is 25 kN.
Determine the diameter of the boH required if the allowable shearing stress on it is 75
MPa.
A. 19.6 mm ©
20.6 mm
B. 21.6 mm D.. 18.6 mm

Solution: b H:.

l-} ~~
~.-1--plo-r-oh--~~ ~
F
"'\ (1'5t000~)
1l c:rs %ft1'2.)
40. Which of the following ratios describes Reynolds number?
CAJ Internal forcesNiscous forces C. Internal forces/Buoyant forces
B. Drag force/Buoyant forces D. Viscous forces/Drag forces

f;c~\an@ot\; ( .:L..)
[(£, =- rwlcls~~u ~~-=-- tnjerrta\ ii>r-a-s =- fL ::. fV L _ VL
I VISCoUS fortt) (f~tz.) }/'- -:- ))
@wate~ is flowing _through a pipe o!
0.60 m in diameter and 2_ k~ in len~th .. If the av~r~ge
velocity of water rs 2 m/sec, what rs the loss of head due to fnctton consrdenng that fnctton
factor is 0.005?
A. 12.6 m C. 11.7 m
@13.6m D. 9.71 m

Solution:

42. What is the reciprocal of absolute viscosity?


A. Viscosity index - ~Rigidity
B. Compressibility (Q) Fluidity
,. ...,,..
,~

\43JA floating cylinder 8 em in diameter and weighing 950 grams is placed in a cylindrical
-· container 20 em in diameter partially full of water. What is the increase in the depth of
water in the container due to placing a float? ;-;;..-)
A. 10cm ' ~3cm
B. Scm D. 2cm

Solution:
dV~hdh dV= mJp=
dh = cJ.V :: __::::9~SD:!....CCffl~:>_
At 1'! ('2D· Cfl'l).,..
4 '
·44. Enthalpy of an ideal gas is a function of:
J A. internal energy @temperature

I B. entropy · D. pressure

f:h>l ~"trti~n : H-= u+'fV : fV= n[T : cl.H .::Cp (c\T)', c\lk= Cv(c\T)
.j
I

l
l
'l
I
I:
I
@on a hot day, the temperature rises from 50°F eariy in the morning to 99°F in the
afternoon. What is the ratio of the concentration (in moieslff) of helium in a spherical
balloon in the afternoon to the concentration of helium in the balloon in the morning?
A. 0.51 . @0.91 ,
B. 0.69 D. 1.98

Solution:
-'f\1 = nrt T Ltt C ~ COY\CW~~·on ~ ~ -= /r
0. -= 1i : : . 5o t 46{) _ Dcwz. ~~ CI =~Wltrufl~: of He.
Ct Tt 99 +46o - t 1 .~ ll\ tht ~'~~ 0 !:"' 1~ ,
~ C:1. "'"' G6Y1~hrtfh011 of 1-le 1n Hu.
46. A weatherman carried an aneroid barometer from the ground floor of his office atop the Ci.t-l:u--
Sears tower in Chicago. On the ground level the barometer reads 765.81 mm of Hg abs. 1'\00rl
at the top it reads 726.62 mm of Hg abs. Assume that the average atmospheric density . ·
was 11,772 N/m3. Estimate the height of the building.
0 445 meters C. 345 meters
B. 545 meters D. 645 meters

~: h.~'. "( = \l.-=ti2 %~ .


- b.'P r (%S.gl- "'ll"'f',b'J..)Im~ :x \0\;:q.s;.~~-l
h- - :::. l T LO ~ · '(f -=tbo m~ J
ll.~iZ.¥/m~
7
0 ~
. h = 44'3. ~4 m
r;::, 44s m~ ----4@
G_!)shaft work of -15 BTU/ib and heat transfer of -10 BTU!Ib, the change of enthalpy of a
system by:
A. -25 c. -5
8. -15 @+5
Solution:
H~ ~-W~"haft -= -10-(-ls=) =- ts tml;'!~m
® ~ =-he crt 1n ·
\t> W~ work out of the .sy.i~ =- Lo~ of -entr]y -fo lh ..currvu{\oti~
48. A 3 hp refrigerator or the heat pump operates between 0°F and 100°F. The maximum
theoretical heat that can be transferred from the cold reservoir is nearest to:
A. 7,600 BTU/hr ~ 23,000 BTU/hr
8. 13,000 BTU/hr <EJ35,000 BTU/hr

Solution:. NDk~ 1hr =- <2>4s tmv'nr


c.o~ r. ~ 1L ---7 t1>r refr-,a~r
Tit- TL
C01P 1
: (Ot46t>Jol1_ f'l
U')L= C.O.P, ( W)
(:o0+46oYR.- r.o+46D)olt &v= 4, 6 (~(2S4S 1mA J
COd', =4.G ~
@Which of the following values
A. Cycle
c~cterize the(9
~teProperty
of the system?
~L =-
~
J'5 IDD f.l.TJA / r
1
~® /h
1

B. Process D. Entropy Change

50. The loss of zinc in the presence of some certain corrosive media or at high temperature is
known as. ·
A,. Graphitization C. Normalizing
UV Dezincification D. Cyaniding
~})At zero deg. C and under a pressure of 100 atm. The compressibility factor of oxygen is ·
0.927. Calculate the weight of the Oxygen in kg. necessary to fill a gas cylinder of 100-fiter
capacity under the given conditions? { l.ol.v 1'
(F) 15.42 · c. 13.4 >1 · h ~,.,
Z. T
B. 12.00 D. 9.0 t'g•1
Solution: ~< 1 { ~ f
2= CMnpwlbil~ .fucm·t--= wr-mDtHfyln.!3 th.tfctt.al ga~ law -h>
o.evoun{ w re(.:{l' ~a·s lctwl wl.
- ~
Z.::: ®IV _ 'PV . . ( 0 1~)
!cleat V - RT (too~ 101J:ns--$:) o:92:t •_
m-:: ¥V/ ILT - ·c~- ~.)/~ -;Jt!(o+2i-l k ):; .41 k.~ -:{A)
52. Sonic velocity (Mach 1) at 50,000 fti altitude tn the standard upper atmosphere ( -67 .6°F
and 1.68 psia) is nearest to: ·
A. 880ft/sec C. 995ft/sec
@ 971 ftlsec D. 1064 ftlsec

solution: Ltt C-=- sonic veloc1~ 1n ttj~~-


C-=- Jt ftc JLT : I< -= Vf _ _
C-:: ~ Vf ( "3'2.~ l~ft ~ )(-D.'J/tlf:j)( -G~.Gt46o):Jt-::. ~~. 91 ~c,
-sec/·
4l.-
@To determine the chemica formula of a compound, we need to know all of the following
EXCEPT the:
A. elements that compose the compound
B. atomic weights of the elements in the compound
C. molecular weight of the compound -.i d
....L • .l · ,
@ density of the compound __,. vJ TI-e ~1IO. h etUif-,1
lior ell ca~l
rtCrly t!pp h e'
~ on!~ Vtti'Oi deo.t11'1 mGt~ be u~ iu ~m1n-e MW ot _gases..
54. Heat is generated by electrical arcs from three electrodes (for the phase current)
extending the wall down into energy charge space in furnace known as...... _ .
A. Open hearth furnace ~Blast furnace =
U~t 1t; reduct
f'ro'fl OX\cle,
B. Bessemer process converter ~Electric arc furnace

txPietnahtKI '. Besse~ pto(1$.( crnverw =IA~e fo reck-ttt CC\rl>on C\mteni ~


open heG~r+h furt~ttU =fkxible. ~C6Y!-lvcl purl~ 1~n.
@A volumetric analysis of a gaseous mixture is as follows:
C02 = 12%, 0 2 = 4%, N2 = 82%, CO = 2%
What is the percentage of CO on a mass basis?
A. 1.0% _.k 1.5%
B. 1.2% (.1?.)1.9%

Solution:
~arne- t voi<J. · h'\(}lt hc-hin 14/\W MO.!'.~ I

CO'L t"L o, 12_ ;>( 44 ::: S1tl


Ot- ' _A o,04 x :11 -- lc'U
Nt V- o, ~1. ){ ~ '«' 22,96
co 2. 0.01"' 2~ :. o.sb
rnr -= 3o,o&
1mass of CO : l,~cl].. --7(£)
I
!

56. In a titration experiment, a student finds that 23.38 mL of NaOH solution are needed to
neutralize 0.5468 g of KHP. What is the concentration (in molarity) of the NaOH
solution?
A. 0.1441 M C. 0.4141 M
B. 0.4411 M @o.114SM

Solution: ( masS"\
Molar:1"N (rv1) = n of .s;ol<.tft; _ Mw -1 l<ltP
· U o.f soln. - Li ofsolr;,
bltl mw bf. l(ftf (t•o-bsnCim Ht-tctrvBf-n Phtha/'*) ='204.2. B/mol
~)~6~ ~ 'y+
. '
Molan~ of Nt~OH rom.::
. r (-
=o .tL3,0g
'L~.--1 [cHp/ .:: o.II4S mol NqOH
,q 0<J Ll sol'1 u ~10

57.
* \ tv~ol ~'.Iff~ 1 mof NaDH = D. 1!45 M~
How many milliliters (mL) of a 0.600 M NaOH solution are needed to neutralized 20.0
mL of a 0.245 M H2 S04?
A. 121 mL C. 141 mL
@ 16 mL D. 131 mL

Solution:
Mo\.e.s H2S04 -= 0.'2.4> mDI H'2S04 "" 2..0~.2/ih".::: .if,9D:<Ib.!t11ol rk.Stkf
1Dl ~oln.
S'~t1u IV' sll>lchfo~+r-i 1 mol H-z.W4 c. 2.mo! NaOtt fht6 N nt.m-
l?er-of rvt9les o.t NaNt Mt-d- b.e 1(4a xlv")-= 9.&:x-lo ~r~ol~.
1

U crt Sl;!n',-= 1\llol.esof.rol~k - 9. ~x-\b'-3":<>1 ~aOH. -=-0,0163 L!


I
!
rvrole<rt~ (M) O.GOD IV'l.oi/Lr Q>l11 w \G.SmL

58. Given that 3.50 moles of NH3 occupy 5.20 L at 47°C, Calculate the pressure of the gas ~
(in atm) using the ideal gas equation.
!1.
1.' A. 16.6 atm @17.7atm
B. 15.5 atm D 18.8 atm

Solution:

.tpy: nrtT
(:!..5 ~ol )(0.0&21 afwl-Li~oi-T<) (4"Tt2.q.~) k
-'P =- nltL= s-~10 Lj
v
f-::: l:t. =t Vti"WJ ~
59. Given that 3.50 moles of NH3 occupy 5.20 L at 47°C, Calculate the pressure of the gas
)in_atm) using the van der waals equation.
l&)16.2 atm C. 15.2 atm
B. 12.6 atm D. 17.6 atm

Solution: J)vm Van der Waals Wl.sh!nt tor- Nl:b


o..-::: .t.k_H· a+m-tl.'7tvtol'l- ~ b : :. o.o:.HI L1/Mol : nb = J.> (o.0311) == 0,13 L(
. . ~ ~

Q!]_'l.- (4. r:t·o+m-.li;fuof)(1.)0 ~. :: lc~9 cdvn .


V'- - (S'Ro .k() z.. ·
( f-t U~~) (S'.'L Ll- o, ~~ LJ)-:: (:l.S"mo~)( 0.0<&-LI Ll ~-fyn )(:."Z.oJ:.)
t -:: [6, 2Sqfwl ~® fiitOl I<
if
il
I
l,i
I

I,

60. How many grams of potassium dichromate (K2 Cr2 0 7) are required to prepare a 200-mL
solution whose concentration is 2.16M?
A. 195 g c. 79.43 g
@12.:zrg D. 74.93 g

Solution: (- rvta~.s j
· I 1, ( ) rn~s o£ Joluft =- MW kz.Crz.07
ffib Clrl"1 M ~ Li of soln . l; ot .rolri.
MolLS of k.<tCnO~ -= 0.2.D~( 2,1G tv~ol k:illl-0-=f) = DA12. mo/
~olt). k:z_Cn. O:r
gf"ZU'Y\S of l::.zCr-z.01'-= (1110le.s K.tCrl-D:t)CfVlw) =(0.43'2)(~94.'2.}= 12.~ j
61. In a biochemical essay, a chemist needs to add 3. 81 g of glucose to a reaction mixture. ~
!f Calculate the volume in milliliters. of a 2.5 ·M glucose solution she should use for the
~~~ addition.
I!,j
A. S.~b ml soln C. 3.86 mL sol.n
~
!
It @ 8.46 mL soln D. 3.68 mL soln
!~
:l Solution: / CH O
1
:!
n of CGH11.0G ::: ~-g~6) ( r~;~~
1
)= '21.14'1x!o
3
'I lz... b Yho!e>
S\na·. V-= J:L :: '2.!. llf<!, k'lo-~~1-Df> -~c, H1z...06
,I
l
t M Q.S Mol ,.. l- 6 = gAG><!£> ""LI
l ,, U 0 So/r{ fir ~A6 ml ~
1: 62. Describe how you would prepare 5,)0 X 102mL of a 1.75 M H2so4 solution, starting
II
with an 8.61 M stock soiution of H2S04
I
l A. 120 mL @ 11'2. ml.
li B. 201 mL D. 210 mL

I !
I
Solution:

Mt~ 8,GJ M n :.(MolCiri~)(VoL ofSotn.J


I•
I Mf:: l.':fSM
l
'~ Vi :? Yf :: s.s-o ~<lo2 fi1L n::. c.cvtst.
i.
l'
I'
:: VC-:. 0:1-5" M) ( s-. 'W,x 1b'l. WI L) == 111 8 tn L"' 112 mL -49
IIi
ji
g, Gf t'v1 I . -v . '

1:
63. A 0.5662-g sample of an ionrc compound containing chloride ions and a unknown metal

·~· is dissolved in water and treated with an excess of AgN03 . If 1.099 2 g of AgCI
~ecipitate forms, what is the percent by mass of Cl in the original compound?
\A) 47/¥}% c. 57.45%
B. 45.17% D. 54.75%
64. Sulfur hexafluoride (SFs) is a colorless, odorless, very unreactive gas. Calculate the
in
pressure (in atm) exerted by 1.82 moles of the gas a steel vessel of volume f.43 L at
45°C.
@ 10.::1 atm . C. 6.55 atm
B. 5.75 atm D. 4.55 atm

Solution:

1'-':: nil.T = Cl.&2.~)(o.o&2t).=t-otm~(4rtZ73}X


y 4(~~~
1' = 10.::}l ot/-m -.:;(£)

~ Slna no cht~l)9e.s Jh Ph>Joef>hts of ._ga~ ocwrs, wt CrAn u~ the !dull


9/H €lf Ltll~·lir'l tv ca Ioulet te fM p~we.
65. Calculate the volume (in liters) GCCupied by 7.45 g of NH3 at STP.
A. 7.93 L C. 3.97 L
@9.SOL D, 4.57 L

Solution:
-7 ~ll)(t 1 /VIol of IdeDI ga) OCLL•pies Z!L4 Li at STf a11d Ltsi'!9 1h.e
IYlblt~r rvttm I>F NH~ =17:.D3 g I ih! J'€Cji.AU\ct rrf CcllVU"-nMs as:
grams Df NH~ -:--+Mol£.) of NHl ~ U~ c;f NH.1~Sf/l'
~t : () h.l!:r. "" 1MOI-=ttlh x 21,4 l1 _ n :ul L. ~IJ3'
VOI• ::: 7 ,15'.?-r""~ l"=t.OJ.~.1 1 M~> - ;~,
1:1_ I \!:::/
66. A small bubble rises from the bottom of a lake, where the temperature and pressure are
ace and 6.4 atm, to the water's surface, where the temperature is 25°C and the pressure
is 1.0 atm. Calculate the final volume (in mL) of the bubble if its initial volume was 2.1
ml.
0 14mL C. 12 mL
B. 17mL D. 15ml

Solution:

~rnl~ -that ru arno(.,(n+ of a1r i\1 fh.t bubHt rerna,Y,.s ~k11+J


\.e.. rt1=ht ,so-thttt 'fW1 : tfJz.Vz_
T, r..
V2-=Y1 x ft x T1: :(2-,fML)(~.'f~ \( 1~+2.1-'11:):: 14\'l..)ml
Pt T1 f,o aftvt) \ g +'l.:t~ k 4
67. A chemist has synthesized a greenish-yellow gaseous compound of chloride and oxygen
and finds its density is 7.71 giL at 36°C and 2.80 atm. Calculate the molar mass of the
compound.
A. 79.6 g/mol @&9.9g/mol
B. 69.7 g/mol D. 76.9 g/mol
68. A flammable gas made up only of carbon and hydrogen is found to effuse through a
porous barrier in 1.50 min. Under the same conditions of temperature and presSure, it
takes an equal' volume of bromine vapor 4.73 min to effuse through the same barrier.
Calculate the molar mass of the unknown gas.
A. 18.1 g/mol C. 12.1 g/mol
@ 16.1g/mol D. 28.1 g/mol

Solution:
lAsing b'rtAhcur1~ Lo.w o.f d[{WI~ : n ~ 12. -= ~ MW-z
\,Sb IYii'riS- j I'A\'Jz r l. -t, MWJ
4c1<lMltlS: 1s9.gg:(M11{ Ltt tv\Wt-::.moi~I'"IV\CA~of-theun~owh
3rA.> 1n !1fM,o\.
MWt. -= 16, I ~Anol --;-?;® sia tvtolo.r-rntt~S ~ cathon {s l2.tOl !J ~r
h~ tl.t~>9€AI ~ I· Ol>& 9 , thegro ts. IV\£.,1-h~l\t.. LGI4)
69. The pressure outside-11 jet plane flying at high altitude falls considerably below standard
atmospheric pressure. Therefore, the air inside the cabin must pressurize to protect the
passengers. What is the pressure in atmospheres in the cabin if the barometer reading
is68S mmHg?
@ 0.90\ atm C. 0.959 atm
B. 0.859 atm D. 0.895 atm

Solution:
$ln (L 1 cclm {!'; fLJV1et I to ~GCHYIIYL ~
f:: 6&S ~ '!{
1crlvv1 : o. 901 cxlwl --7@
:YdJ~
4
70. The concentration of W ions in the bottle of table wine was 3.2 x10 M right after the
cork was removed. Only half of the wine was consumed. The other half, after it had been
standing open to the air for a month, was found to have hydrogen ion concentration
equal to 1.\ · x1 0-2 M. Calculate the pH of the wine on these two occasions.
A. 3.94 & 3.20 resp. C. 4.49 & 3.94 resp.
@ 3.49 &2.96 resp. D. 4.94 & 3.84 resp.

Solution:
pH~ -J,o9 [tl+] ~·. [H+J = !on eohc.err\-r<Atton
4
Wh.udiu botlie.wa~~~sf op~~ [H+]::J,'2XIo M
tts pti ~- J.o; (J.z.x lo4) :::: J,4!jS ---7@ 1
01\ fu ~tum~ OcC4Sion·. [ Hf J= 1,1 :><;lo ~
3
it~ p~: -k_g (!,\ :XIo ) = 2/36
7i. The Ph of rainwater collected in a certain region of northeastern Luzon on a particular
day is 4.92. Calculate the W ion concentration of t~~inwater.
LiJJ
A. 1.5 x10-s M '-...0' 1.2 x10..s M
8. 2.5 x10..s M D. 2.4 x10-<> M

Solution:

~\i"' - ,Lj ( 1-l+J :. 4,92


Mj [H+J = -4.~1. -bk:in.9 antiloB hvih-'ICUs:
LH+] :: 10- 4,'3 2 :: II'L><ID-S'M ~
72. Sodium azide (NaN3) is used in some automobile air bags. The impact of a collision
triggers the decomposition of NaN3 as follows: 2NaN 3 (s) ~ 2Na(s) + 3N 2 (g)
The nitrogen gas produced quickly inflates the bag between the driver and the
windshield and dashboard. Calculate the volume of N2 generated at 80°C and 833
mmHg by the decomposition of 60.0g of NaN 3 .
(10 36Ji L C. 46.8 L
R 39.6 L D. 48.61

Solution: •
t-J u 1'>1. 3mol NL.
'from H11 be.Ian C4l e%1o'·. 1. rno I N~ N3 .~ 3 MOl 2. SOri\.W 2. h1 o[ Na N'J
MJ>lu <>fNl=b'D~~>< 16),~,.;
D'L
~;:;N 1 ~ 1.~& mo\N2
Nl '2..
lli ICttal gb\~ ee· )J~nrLI :. (u& Wt)(o,DR'll u-c4m/JM1-J0(00-f2~J)t"
V= 3G,G U ~· 1' (83V%D)¢vi1
73. A mixture of gases contains 4.46 moles of neon (Ne), 0.7 4 mole of argon (Ar), and 2.15
moles of xenon (Xe). Calculate the partial pressure of xenon gas if the total pressure is
2.00 atm at a certain temperature.
A. 0.656 atm C. 1.21 atm
@ 0.585 atm D. 0.20 atm

Solution: (
U>fr19 DCAiton's Lll.w of f>~rh'al pressure·. fxe = X;xe 'Pr)
,.J _ nx-e _ '2.,1) ~
'X)<~= molt tach"Gvl vr Xeno~ - .fiNe t nwtnx-e- 4,4GtD.1-~H'2..1)
Xx~-=- Q,192S == 2H.'2!fL
fh\(;.:t'xe = (0/2.9'2.)')('2,0D~)-= O,S"&.S trtm ---4@)
74. Oxygen gas generated by the decomposition of potassium chlorate by an apparatus.
i:!I The volume of oxygen collected as 24°C and atmospheric pressure of 762 mmHg is 128
i mL. Calculate the mass (in grams) of oxygen gas obtained. The pressure of ihe water
!
vapor at 24°C is 22.4 mmHg.
@o.1s.a 9 c. o.146 g
B. 0.641 g D. 0.461 g

Solution:
USin3 D£Aittms lrAw of- padicd pre.s.stArt: fr = 1h t 'rK2-0
f'ot :: fr- fH"~-O =%'2. -1!2..4 = q.:a9rG mm ~
, , ,r,.l: 'h·T mn·r
I{) rM
_lASihj tcuetl @CAS e'V. ( r v= lit<.. ::: ~'W --7 ~ RT
flV (IVI\Y)
t'l

M- ~:lq,G/-,.6())~(o.12ili) :i'2.ct>D M =- Q,IG3.)~---IJ)


- co,ox2.1 v-
v~-J4'C1-4 +~-:r~w
75. Calculate the root-mean-square speeds of helium atoms and nitrogen molecules in m/s
at 25°C.
@515rnlsec C.415mfsec
B. 551 m/sec D. 451 m/sec

..
II.··.·
Solution:

!
l·!ll·.

.'

I
I

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