Apéndice

METODO DE COMPRESION ISOTERMICA

N° H(mm) H(mm)
0 1575 0
1 1420 215
2 1395 310
3 1365 400
4 1335 506
5 1305 655
6 1290 770
7 1255 925
8 1240 1120

CALCULAMOS PRESIONES A DIFERENTES ALTURAS

P1= 486.4 (mmHg)

Densidad de Hg =13.56g/ml

Densidad de H2O = 1g/ml

PvH2O= 14.401 (mmHg) A 17°C

P=486.4 (mmHg)+
g
1(
)
ml
∗h (mm)−P v H 2O
gg
13.56 (1( ) )
mlml
P1=486.4 (mmHg)+ ∗0 (mm)−14.401(mm) =471.9
g
13.56 ( )
ml
g
1(
)
ml
P=486.4 (mmHg)+ ∗215(mm)−14.401(mm) =487.85
g
13.56 ( )
ml
g
)1(
ml
P=486.4 (mmHg)+ ∗310 ( mm )−14.401 ( mm )=¿ 494.86
g
13.56 ( )
ml
 g
1( )
ml
P=486.4 (mmHg)+ ∗400 ( mm )−14.401 ( mm ) =¿ 501.49
g
13.56 ( )
ml
g
1( )
ml
P=486.4 (mmHg)+ ∗506 (mm)−14.401(mm) =503.31
g
13.56 ( )
ml
g
1( )
ml
P=486.4 (mmHg)+ ∗655 (mm)−14.401(mm) =520.30
g
13.56 ( )
ml
g
1( )
ml
P=486.4 (mmHg)+ ∗770(mm)−14.401(mm) =528.78
g
13.56 ( )
ml
g
1( )
ml
P=486.4 (mmHg)+ ∗925 ( mm )−14.401 ( mm )=540.21
g
13.56 ( )
ml
g
1()
ml
P=486.4 (mmHg)+ ∗1120 ( mm )−14.401 ( mm )=¿ 554.59
g
13.56 ( )
ml
PARA EL VOLUMEN UTILIZAMOS LA SGT FORMULA

π
V= ∗D2∗h
4
Diámetro 1.12cm

π π
V= ∗1.122∗1575 =1551.69 V= ∗1.122∗1335 =1315.25
4 4
π π
V= ∗1.122∗1420=¿ 1398.98 V= ∗1.122∗1305=¿ 1285.69
4 4
π π
V= ∗1.122∗1395=¿ 1374.36 V= ∗1.122∗1290 =1270.91
4 4
π π
V= ∗1.122∗1365=¿ 1344.80 V= ∗1.122∗1255=1236.43
4 4
 π 2
V= ∗1.12 ∗1240=1221.65
4
 N° V(ml) P(mmHg) K (P*V)
1 1551.69 0 0
2 1398.98 471.9 660178.6
3 1374.36 487.85 670481.5
4 1344.80 494.86 665487.7
5 1315.25 501.49 659584.7
6 1285.69 503.31 646759.3
7 1270.91 520.30 661254.5
8 1236.43 528.78 653799.4
9 1221.65 554.59 677514.8

∑ 5222960.05

12
10
8
presion

6
4 Li near ()
2
0
1200 1250
f(x) = 1300 1350 1400 1450 1500 1550 1600
R² = 0 volumen

DIBUJAMOS LA ISOTERMA PARA HALLAR W, Q, ∆U, ∆H

P=(atm)

P2

P1 T2

V2 V1 TV=(Lt)
1
Inicialmente se comprime isobáricamente al disminuir la temperatura seguido de una compresión
adiabática pára finalizar con una expansión isotérmica para cerrar el ciclo de la transformación
termodinámica

T1 = 17+273.15=290.15

T2=?

P1=471.99mmHg a 0.62atm

P2=?

V1= 1551.63ml a 1.55L

V2=1221.65ml a 1.22L

DE A-B COMPESION ISOBARICA A P=CTE

V 1 V2
=
T1 T 2
T 1∗V 1 290.15∗1.55
T 2= = =368.63° K
V2 1.22

ω= -n*R*(T2-T1)

ω= -1mol*8.314 ( mol∗°J K ) *(368.63-290.15)°K

ω= -652.48(J)
∆U= n*Cv (T2-T1)
 3 J
∆U=1(mol)*
2
∗8.314 (
mol∗° K )
( 368.63−290.15 ) ° K

∆U=978.72 (J)

∆H=n*Cp*(T2-T1)

5 J
∆H=1(mol)*
2
∗8.314 (
mol∗° K )
( 368.63−290.15 ) ° K

∆H=1631.21 (J)=Q

DE B-C COMPRESION ADIABATICA

5
γ=
CP
=
( 2)
=1.66
CV 3
(2)
P1* V 1 γ =P 2∗V 2γ
1.283
P2= 1.391 =0.92(atm)

Q=0
∆U= ω

∆U=n*Cv*(T2-T1)

3 J
∆U=1(mol)*
2
∗8.314 (
° K∗mol )
∗( 368.63−290.15 ) ° K

∆U=978.72 (J) = ω

5 J
∆H=1(mol)*
2
∗8.314 (
mol∗° K )
( 368.63−290.15 ) ° K

∆H=1631.21 (J)

DE C-D EXPANSIÓN ISOTERMICA T=CTE

∆U=0

∆H=0

Q=0

atm∗L 1.22
ω= 1mol*0.0821 ( mol∗° K) ( )
* ln 1.55
ω=-0.019