2.1 INTRODUCTION
Phase:
Atoms are similar to a bunch of balls, and these balls can be arranged in
many different ways. A simple example is that the billiard balls are arranged
in a hexagonal close-packed fashion to start with, whereas the keyboards you
are using are arranged in another way. Although both of these examples are
two dimensional, atoms can certainly also be arranged in many different ways
three dimensionally.
The reason that atoms have a regular or homogeneous way to stack
themselves is because such arrangement results in a stable or low energy
configuration. The homogeneous arranged portion of atoms is called a phase.
A phase may be defined as a homogeneous portion of a system that has
uniform physical and chemical characteristics. Every pure material is
considered to be a phase; so also is every solid, liquid, and gaseous solution.
The graph below is the phase diagram for pure H2O. Parameters
plotted are external pressure (vertical axis, scaled logarithmically) versus
temperature. In a sense this diagram is a map wherein regions for the three
familiar phases—solid (ice), liquid (water), and vapor (steam) are described.
The three curves represent phase boundaries that define the regions. A
photograph located in each region shows an example of its phase—ice cubes,
liquid water being poured into a glass, and steam that is spewing forth from a
kettle.
The following are the main objects of the heat treatment of steel.
1. To soften the steel that has been hardened by the previous heat
treatment or mechanical working.
2. To harden the steel and increase its strength.
3. To adjust its other mechanical and physical properties like ductility,
malleability, permeability corrosion resistance, etc.
4. To stabilize the dimensions of the steel instruments so that they do not
expand or contract with time.
5. To refine the grain size of the steel.
6. To reduce the internal stresses. To eliminate gases.
7. To produce a hard surface on a ductile interior.
8. To improve electrical and magnetic properties.
1. Annealing
(i) Full annealing
(ii) Process annealing
(iii) Isothermal annealing
(iv)Spheroidize annealing
(v) Homogenizing
2. Normalizing
3. Hardening
4. Tempering
5. Surface hardening
ANNEALING
The annealing operation is carried out mainly to obtain the following
properties.
1. To soften the steels.
2. To improve machinability.
3. To relieve internal stress induced by some previous treatment (rolling,
forging, extrusion, uneven cooling).
4. To remove coarseness of grains.
5. To produce a completely stable structure.
Annealing treatment is applied to castings, forgings, cold worked sheets and
wires. The operation consists of (i) heating the steel to- a certain
predetermined temperature (ii) soaking at a constant temperature for a
sufficient time to allow the necessary changes to occur and (iii) cooling at a
predetermined very slow rate.
1. Full Annealing:
Purpose:
(i) To reduce internal stresses produced due to cold working, welding etc.
(ii) To reduce hardness and increase ductility.
(iii) To refine the grain size.
(iv) To increase machinability.
(v) To make the steel suitable for further heat treatment.
Process:
Hypoeutectoid steel (steel containing less than 0.8 % C) is heated to
30-50 °C above the upper critical temperature and hypereutectoid steel (steel
containing more than 0.8 % C) is heated to 50°C above the lower critical
temperature. The steel is soaked at the annealing temperature (soaking time
depend upon the thickness of steel parts). Then these steel parts are slowly
cooled at the rate of 20 to 40°C per hour. The cooling is carried out in the
furnace.
2. Process Annealing:
It is also known as sub- critical annealing or recrystalization.
Purpose:
(i) To soften the component to restore the ductility.
(ii) To remove the internal stresses produced in the casting by welding or
by previous heat treatment.
Process:
Steel is heated to a temperature from 600 to 650 °C, holding at that
temperature, and then cooling in air or in furnace. By this process, high
degree of softening takes place due to removal of stress from pearlite. No
phase change takes place and the ferrite & pearlite simply rearrange
themselves to induce softening in materials.
3. Isothermal Annealing:
This process is suitable for small rolled and forged components and not for
large components. It is faster than full annealing and saves much time.
Purpose:
(i) To obtain stable structure
(ii) To save the time required for heat treatment
Process:
The process is similar to ordinary annealing but it is first cooled rapidly in air
or by blast in furnace to temperature 600-700 °C. The steel is held
isothermally at this temperature for certain duration then it is rapidly cooled in
air.
4. Spheroidize Annealing:
The process of producing a structure of globular pearlite is known as
Spheroidizing or spheroidizes annealing.
Purpose:
(i) To improve machinability of the steel
(ii) To reduce hardness
(iii) To prevent chances of cracking during cold working.
Process:
This operation is generally applied to the hypereutectoid steels. Steel is
heated just above the lower critical temperature (740 to 770 0C), held for the
required time and cooled very slowly upto 600 0C in furnace. Further cooling
is conducted in still air. The cooling rate varies from 20 to 25 0C per hour. It
should be noted that heating much above Acm will produce lamellar pearlite
instead of granular cementite.
5. Homogenizing:
It is also known as diffusion annealing.
Purpose:
(i) To remove non uniformity of castings this is caused by coring. Coring
means variation in the composition from centre to surface of a
grain.
(ii) To improve the structure of steel.
Process:
The steel is heated as rapidly as possible up to 1150 °C and is held at this
temperature for sufficient time so that diffusion takes place. It is then cooled
in 6 to 8 hours to a temperature of 800 to 850 °C and then further cooled in
air. After homogenizing, the full annealing is done to refine the grain
structure.
NORMALIZING
Purpose:
1. To eliminate coarse-grained structure.
2. To remove internal stresses that may have been caused by working.
3. To improve the mechanical properties of the steel.
4. To increase the strength of medium carbon steels to a certain extent
(in comparison with annealed steels)
5. To improve the machinability of low carbon steels
6. To improve the structure of welds
Normalizing is frequently applied as a final heat treatment for items
which are to operate at relatively high stresses.
Process:
1. Heating the metal to temperatures within the normalizing range usually
40°C to 50°C above Ac3 (for Hypoeutectoid steels) and Acm (for
hypereutectoid steels)
2. Holding at this temperature for a short time (about 15 minutes).
3. Cooling in air.
Normalized steels have a higher yield points, tensile strength and
impact strength than if they were annealed, but ductility and machinability
obtained by normalizing will be somewhat lower.
Difference between annealing and normalizing
Annealing Normalizing
Less hardness, toughness. Slightly more hardness, toughness.
For plain carbon steel the Microstructure shows more pearlite.
microstructure shows pearlite. Pearlite is fine and appears
Pearlite is coarse and usually gets unresolved with optical microscope.
resolved by the optical microscope. Grain size distribution is slightly less
Grain size distribution is more uniform. uniform.
Internal stresses are least. Internal stresses are slightly more
Process:
The process consists of heating the metal to a temperature above
critical point. The metal is held at this temperature for a considerable time
and then it is rapidly cooled. The cooling media used varies between water,
oil or molten salt.
Hardening is applied to tools and machine parts to perform the
operations more efficiently.
Quenching:
The rapid cooling of a metal in a bath of liquid during heat
treatment is known as quenching, e.g. Steel is heated above its critical
temperature and plunged into water to cool it, an extremely hard, needle
shaped structure known as ‘martensite’ is formed. The rapidity with which
heat is absorbed by the quenching bath has different effects on the hardness
of the metal. Cold clean water is used as quenching media, while addition of
salt increases the hardness considerably. Oil gives the best balance between
hardness, toughness and distortion. Special soluble oils are used as quenching
media.
The parts which are subjected to hardening have good tensile
strength, but poor ductility, toughness and impact strength.
TEMPERING
Objectives:
(i) To reduce internal stresses developed during previous heating,
(ii) To reduce the hardness developed during hardening,
(iii) To give the metal a right structural condition (To stabilize the
structure).
Why tempering is done after hardening?
After hardening, when a metal is removed from the quenching media,
it is very hard and brittle and there are several other inequalities in the
structure of the metal. Tempering is done to restore ductility and reduce
hardness. The process involves re-heating of the metal below critical point,
then holding it for a considerable time and then slowly cooling it. Tempering
should be done immediately after quenching in order to relieve hardening
strains. The temperature at which tempering is done varies with the carbon
content of the metal and mechanical properties desired in the finished article.
Lathe tools, chisels in which only the cutting ends need hardening
may be hardened and tempered in one operation only. The whole tool
is heated to the hardening temperature and the cutting end is quenched.
When the cold end is rubbed bright and the heat from unquenched portion
causes tempering, when the colour is satisfactory, the whole tool is quenched.
Three types of tempering processes are classified as:
(i) Low temperature tempering: This type of tempering is done in the range
of 200 - 250° C. At this range, hardness changes to a very small extent.
Tensile strength is increased. Internal stresses are reduced comparatively.
(ii) Medium temperature tempering: Tempering done in this case at a range
of 350° to 450° C. In this case, the properties of the structure are improved,
mostly employed for coil and laminated springs. Highest elastic limit and
toughness are achieved.
(iii) High temperature tempering: This tempering is performed in the range of
550° C to 600° C. Eliminates the internal stresses completely. Comparatively
high strength and toughness are achieved.
2.2.1 CASE HARDENING OF STEELS
A large number of industrial components like cams, change-over switch
shafts, drive worms brake drums, gears, etc. require a hard wear resistant
surface (also called case) and a soft core, so that it is tough and shock
resistant too. No plain carbon steel and even alloy steels possess both the
requirements, i.e. hard surface and tough core to resist shock. It is noticed
that steel containing 0.1% carbon is tough whereas the steel containing 0.8
%C is very hard and brittle. Both these properties are obtained by the case
hardening process. The heat treatment process of producing a hard wear-
resistant carbon rich case (surface layers) on a tough and soft core of steel
part is known as case hardening. Low carbon steel is used for the case
hardening processes except in induction, hardening, where medium carbon
steel or high carbon steel is used. The processes generally employed for case
hardening are as follows.
1. Carburising
2. Cyaniding
3. Nitriding
4. Carbonitriding
5. Flame hardening
6. Induction hardening.
1. Carburising
Process: Curburising is a method of enriching in carbon the surface
layer of low carbon steel in order to produce a hard case. Carburising is also
known as cementation. Roughly, the machined parts of the low carbon steel
are packed with carburising mixture in a steel box as shown in Fig. The
carburising mixture contains 50 to 70% charcoal, 5 to 15% barium carbonate,
2 to 15% calcium carbonate and 3 to 13% sodium carbonate. A layer of the
carburising mixture of nearly 25 mm thickness is placed at the bottom. Then
the components are so placed that no component touches one another or
even the sides of the box. The box is covered and the lid tightly sealed with
fireclay to avoid the entry or escape of gases.
3. Nitriding
The heat treatment process which produces a hard-wear
resistant layer of nitrides on a tough core of low carbon steel is
known as nitriding.
Process: The process is suitable for the steels containing 1%
aluminium, 1.5% chromium and 0.2 per cent molybdenum. The percentage of
carbon in these steels varies from 0.2 to 0.5.
The process consists of heating machined and heat treated components to a
temperature of 500°C for 40 to 90 hours in a gas tight box through which
ammonia gas is circulated. The essential requirement of the operation is close
adherence to a temperature of 500°C. The component is allowed to cool in
the furnace after switching of the supply of ammonia.
When ammonia vapours come in contact with the steel, they get dissociated
NH3 = 3H +N and nascent nitrogen so produced diffuses into the surface of
the workpiece forming hard nitrides.
Carburizing Nitriding
1) Carburizing is a method of heat 1) Nitriding is a case hardening
treatment by which carbon content at process by which nitrogen content at
the surface of a ferrous material is the surface of steel is increased.
increased.
2) High temperature (930°C). 2) Temperature employed ≤=600°C.
Quenching is done. Quenching is not required.
3) Hardening and tempering is 3) No need of hardening and
needed. tempering.
4) This process is very simple and 4) This process is complex and
inexpensive. expensive.
5) Grain refinement is not necessary. 5) Before nitriding, grain refinement
is necessary.
4. Carbonitriding
The process of producing a hard case by the addition of carbon and
nitrogen on the surface of the steel.
Process: Hydrocarbons, carbon monoxide and ammonia gases are used for
Carbonitriding. Carbonitriding is carried out at a temperature of 800 to 875°C
for 6 to 10 hours and the case depth obtained is 0.5 mm. Carbonitriding is
applied to the low carbon steels (steels used for carburising). Nitrogen in the
surface layer of the steel increases its hardenability and permits hardening in
oil quenching. Thus, chances of distortion and cracking are eliminated. The
portion of components which is not to be carbonitrided is protected by copper
plating.
SURFACE HARDENING
Surface hardening involves the following two methods.
1. Flame hardening:
The process of heating the metal with a flame of an oxyacetylene torch and is
then almost immediately quenched is called as flame hardening.
surface material effect the heat required. When the surface, to be hardened,
is heated upto a proper length of time, the circuit is opened and water is
sprayed immediately on the surface for quenching. It is extensively used for
hardening of crank shaft, cam shafts, axles and gears.
Advantages:
(i) Time required for this process is less
(ii) Deformation is reduced.
(iii) Hardening can be controlled by controlling the current
(iv) Depth of hardening can be controlled.
Disadvantages:
(i) High equipment cost
(ii) High maintenance cost
(iii) Method is suitable only for large scale production.