1.

Pada suatu reaksi kimia diperoleh data hubungan antara temperatur

(T) dengan harga konstanta kecepatan reaksi (k) sebagai berikut :

no T (K) k (1/menit) x=1/T y=ln k xy x^2

1 300 0.0012 0.003333 -6.72543 -0.02242 1.11E-05
2 330 0.0017 0.00303 -6.37713 -0.01932 9.18E-06
3 360 0.0025 0.002778 -5.99146 -0.01664 7.72E-06
4 390 0.0036 0.002564 -5.62682 -0.01443 6.57E-06
5 420 0.0042 0.002381 -5.47267 -0.01303 5.67E-06
0.014086 -30.1935 -0.08584 0.000198

Model Isotherm Arhenius y = -1373.2x - 2.17 R² = 0.9927

a = -1373.2 , b = -2.1 R = 0.99634

E = a*R b = ln A
E = 1368.174 A = 0.114178

2. Data kesetimbangan biosorpsi Cu dengan saccharomyces

cereviacae adalah sebagai berikut :
Berat biomassa (m) = 0.2 gram
Volume larutan CuSO4 (V) = 100 ml

no Co(mg/l) Cs (mg/l) Qs (mg/g)%penyerapan1/Cs (x) 1/Qs (y)

1 20 9.5325 5.23 52.34 0.104904 0.191205
2 40 22.2425 8.88 44.39 0.044959 0.112613
3 60 34.9525 12.52 41.75 0.02861 0.079872
4 80 47.6625 16.17 40.42 0.020981 0.061843
5 100 63.55 18.23 36.45 0.015736 0.054855

Model Isotherm Langmuir y = 1.5236x + 0.0345

a = 1.5236 , b = 0.0345

1/qs=(1/qsmax*b*Cs)+1/qsmax 1/qmax*b = a
1/qsmax = b 1/qmax*b = 1.5236
1/qsmax = 0.0345 b = 0.022668
qsmax = 28.98551

no Co(mg/l) Cs (mg/l) Qs (mg/g)%penyerapan

1/Qs modelQs model%kesalahan
1 20 9.5325 5.23 52.34 0.194164 5.150277 1.524336
2 40 22.2425 8.88 44.39 0.102928 9.715571 9.409581
3 60 34.9525 12.52 41.75 0.078045 12.81315 2.341467
4 80 47.6625 16.17 40.42 0.066433 15.05279 6.909144
5 100 63.55 18.23 36.45 0.05845 17.10874 6.150612
3. Data kesetimbangan biosorpsi Cu dengan saccharomyces cereviacae
adalah sebagai berikut :
Berat biomassa (m) = 0.2 gram Qs = (V/m)*(Co – Cs)
Volume larutan CuSO4 (V) = 100 ml

no Co Cs Qs data%penyerapanlog Cs (x) log Qs (y)

1 20 9.53 5.235 52.350 0.979093 0.718917
2 40 22.24 8.880 44.400 1.347135 0.948413
3 60 34.95 12.525 41.750 1.543447 1.097778
4 80 47.66 16.170 40.425 1.678154 1.20871
5 100 63.55 18.225 36.450 1.803116 1.260668

Model Isotherm Freundlich

no Co Cs Qs datalog Qs modelQs model%kesalahan
1 20 9.53 5.235 0.7157 5.1723 1.1976
2 40 22.24 8.880 0.9652 9.1812 3.3921
3 60 34.95 12.525 1.0983 12.4690 0.4471
4 80 47.66 16.170 1.1896 15.3832 4.8658
5 100 63.55 18.225 1.2743 18.6923 2.5641

Konstanta F reundlich y = 0.6776x + 0.0507 log Kf = b

a = 0.6776 , b = 0.05 Kf = 10^0.0507
1/a = a Kf = 1.123828
n = 1/a
n = 1/0.6776 Rumus Qs Model = Kf x Cs^1/n
n = 1.476797 Rumus Kesalahan Dat[(Qs - Qs Model)/Qs] * 100%
 Isotherm Arrhenius
0
0.0022 0.0024 0.0026 0.0028 0.003 0.0032 0.0034
-1

-2

-3

-4

-5

-6 f(x) = - 1373.1901102467x - 2.1700234893

R² = 0.9927133241
-7

-8
Is otherm Arrheni us Li near (Is otherm Arrheni us )

Isotherm Langmuir
0.25

0.2
f(x) = 1.5236174961x + 0.0345039414
0.15 R² = 0.9887003479
1/Qs

0.1

0.05

0
0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.1 0.11
1/Cs

Is otherm Langmui r Li near (Is otherm Langmui r)

%kesalahan
 Isotherm Freundlich
1.4
1.2 f(x) = 0.6776216859x + 0.0506651136
R² = 0.9956769757
1
0.8
log Qs

0.6
0.4
0.2
0
0.9 1 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9
log Cs

Li near ()