Q

S A Material safety data sheet

D Therminol 55

Química Delta
S.A. de C.V.
1. PRODUCT AND COMPANY IDENTIFICATION
MSDS: Therminol 55

Sinonyms:
Heat transfer fluid

CAS No.: 68855-24-3

UN No.: N/A

supplier:
Química Delta S.A. de C.V.
Teoloyucan – Huehuetoca No. 259
Sta. Ma. Caliacac, Teoloyucan
phone: 58-99-94-00
Emergency phone: 01-800-00-214-00

2. HAZARDS IDENTIFICATION
Emergency Overview

GHS Classification
Acute toxicity, Aspiration (Category 1)
Skin irritation (Category 3)

GHS Label elements, including precautionary statements

Pictogram

Signal word Warning

Hazard statement(s)
H304 May be fatal if swallowed and enters airways.
H316 Causes mild skin irritation.

Precautionary statement(s)
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P331 - Do NOT induce vomiting

Storage
P405 - Store locked up

Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant

Potential Health Effects

Inhalation High processing temperatures may cause release of vapors that irritate if inhaled.
Skin Causes mild skin irritation. Fully reversible in 7 days or less.
Eyes Causes mild skin irritation. Fully reversible in 7 days or less.
Ingestion Aspiration hazard. May be fatal if swallowed and enters pathways respiratory.

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Chronic Effects Repeated exposure may cause skin dryness or cracking skin.
Danger to the environment See section 12: ECOLOGICAL INFORMATION.

Other information

Other hazards
Hot liquid can cause severe burns.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical name No. CAS Concentration [%]

Benzene, C14-30-alkyl derivs. 68855-24-3 100 %

4. FIRST AID MEASURES

General advice
When symptoms persist or in all cases of doubt seek medical advice. If unconscious, place in recovery position and get
medical attention immediately. Show this material safety data sheet to the doctor in attendance.

If inhaled
Remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Keep victim
warm and quiet. Loosen tight clothing such as a collar, tie, belt or waistband. Maintain an open airway. Persons who have
inhaled vapors or smoke fumes have to be put under medical observation for at least 48 hours, due to the delayed
appearance of poisoning.

In case of skin contact

Wash off immediately with soap and plenty of water. Remove contaminated clothing and shoes. Get medical attention if
irritation develops and persists. In case of burns, immediately cool affected skin for as long as possible with cold water. For
severe burns, immediate medical attention is required. Wash contaminated clothing before reuse. Discard contaminated
shoes.

In case of eye contact

Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15
minutes. Get medical attention immediately if symptoms occur.

If swallowed
If swallowed, rinse mouth with water (only if the person is conscious). Call a physician or poison control center immediately.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Loosen tight clothing such as a collar, tie,
belt or waistband. Never give anything by mouth to an unconscious person. Do NOT induce vomiting unless directed to do so
by a physician. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Maintain an open airway. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen.

Notes to physician
Treat symptomatically. Contact with hot material: Treat for thermal burns. Persons who have inhaled vapors or smoke fumes
have to be put under medical observation for at least 48 hours, due to the delayed appearance of poisoning.

5. FIREFIGHTING MEASURES
Conditions of flammability
This product is not classified as a transfer fluid heat fire resistant. Caution should beto avoid ignition sources.

Suitable extinguishing media

Water spray, Foam, Dry extinguishing powder, Carbon dioxide (CO2).

Special protective equipment for firefighters

Special protective equipment for fire – fighters. As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA / NIOSH (approved or equivalent) and protective clothing tota

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Hazardous combustion products
Fire will produce dense black acrid smoke. Thermal decomposition can lead to release of toxic and corrosive gases/vapors.
Decomposition products: Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). Container may explode in
heat of fire. Runoff may pollute waterways.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions
No action shall be taken involving any personal risk or without suitable training. Do not touch or walk through spilled material.
Avoid contact with skin, eyes and clothing. Wear personal protective equipment.

Environmental precautions
Prevent further leakage or spillage if safe to do so. Clean up spill immediately. Try to prevent the material from entering drains
or water courses.

Methods and materials for containment and cleaning up

Containment methods.
Prevent further leakage or spillage if you can do so safely. Dike to collect large liquid spills size.

Methods for containment

Prevent further leakage or spillage if safe to do so. Dike to collect large liquid spills. Contain and collect spillage with non-
combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local / national regulations

Methods for cleaning up

Take up with sand or other noncombustible absorbent material and place into containers for later disposal. Clean
contaminated surface thoroughly. Try to prevent the material from entering drains or water courses.

7. HANDLING AND STORAGE

Precautions for safe handling
Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Use in well ventilated areas. Carrying equipment
individual protection. Do not eat, drink or smoke during use. Handle in accordance with good industrial practice health and
safety. This product is not classified as a transfer fluid heat fire resistant. Should take precautions to avoid ignition sources.

Conditions for safe storage

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from direct sunlight. Keep away from
contact with oxidizing materials. Keep in properly labeled containers. Use appropriate containment to avoid environmental
contamination. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Store in
accordance with local regulations.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the
region specific regulatory bodies.

Engineering measures
Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Apply technical measures
to comply with the occupational exposure limits. If this product contains ingredients with exposure limits, personal, workplace
atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective equipment.

Individual protection measures, such as personal protective equipment

Respiratory protection
Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is
necessary Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator. If exposure limits are exceeded or irritation is experienced, use respiratory
protection must be approved by the NIOSH / MSHA. When the concentration of airborne contaminants is high, the use of it
may be necessary.

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Hand protection
Handle with gloves. Gloves must be inspected prior to use .Use the correct removal technique gloves (without touching glove's
outer surface) to avoid skin contact with this product. Discard gloves contaminated after use in accordance with applicable
laws and good laboratory practices laws. Wash and dry hands.

Eye protection
Face shield and safety glasses. Use equipment eye protection tested and approved under the rules governmental
authorities, such as NIOSH (U.S.) or EN 166 (EU).

Protecting the Skin

Lightweight protective clothing: Long sleeved clothing Chemical resistant apron, impervious gloves. Wear impervious rubber
clothing if needed to prevent contact with liquid material Work clothing that becomes wet or significantly contaminated should
be removed and replaced. Wear rubber boots if needed to prevent skin contact with liquid material Wash contaminated
clothing before reuse, discard contaminated shoes. Wear protective gloves and additional protective clothing as necessary to
prevent exposures.

Hygiene measures
Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Liquid

Appearance Yellow
Odor Characteristic
Odor threshold No information available

Property Values Remarks • Method

pH No information available Not applicable
Melting point/freezing point -54 °C / -65°F Pour point
Boiling point/boiling range 351 °C/664°F 1013 hPa

Flash point 166 ° C / 330 ° F Pensky-Martens Closed Cup, ASTM D-93

Evaporation There is no information available
Specific gravity 0.876 15 ° C
Flammability (solid, gas)

Flammability Limits in Air

Upper Flammable Limit No information available
Lower Flammable Limit No information available
Steam Pressure 0.0228 kPa 93 ° C

Vapor Density No information available

Solubility in water
Solubility in other solvents
Partition Coefficient
n-octanol/water
Autoignition temperatura
Decomposition temperature
0.001 g /l 25 ° C
There is no information available
There any information available
There any information available
343 °C ASTM E-659
There is no information available

Kinematic viscosity 19.0 mm ² / s 40 ° C

3.5 mm ² / s 100 ° C
Viscosity, dynamic There is no information available
Explosive properties Not explosive
Oxidant properties No oxidant

Density 868 kg / m³ 25 ° C

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10. STABILITY AND REACTIVITY
Chemical stability
Stable under recommended storage and handling conditions (see section 7).

Incompatible products
Strong oxidizing agents.

Possibility of hazardous reactions

Hazardous polymerization Hazardous polymerization does not occur.

Hazardous reactions Under normal conditions of storage and use, hazardous reactions will not occur.

Conditions to avoid
This product is not classified as a transfer fluid heat fire resistant. Caution should be
to avoid ignition sources. Heating in air.

11. TOXICOLOGICAL INFORMATION

Product Info

Inhalation High processing temperatures may cause release of vapors irritating if inhaled.
Eyes May cause slight irritation. Fully reversible in 7 days or less.
Skin Causes mild skin irritation. Fully reversible in 7 days or less.
Ingestion Aspiration hazard. May be fatal if swallowed and enters airways.

Acute toxicity

Chemical name LD50 Oral LD50 Dermal LC50 Inhalation

DERIVADOS C14-30- > 15800 mg/kg ( Rat ) > 7940 mg/kg ( Rabbit ) No data available
ALQUILAROMATICOS

Chronic Toxicity
Repeated exposure may cause skin dryness or cracking skin.

Carcinogenicity
This product contains no carcinogen or potential carcinogen as classified by OSHA, IARC or NTP.

Sensitization
No caused sensitization in laboratory animals: Guinea Pigs.

Germ cell mutagenicity

No genetic effects were observed in standard tests using bacterial cells and animal cells.

Teratogenicity No data available.

Specific target organ toxicity - single exposure (Globally Harmonized System)

No data available

Specific target organ toxicity - repeated exposure (Globally Harmonized System)

No data available.

Aspiration hazard
Liquid hydrocarbons of low viscosity. Potential for aspiration if swallowed. Aspiration into lungs can produce severe lung
damage.

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12. ECOLOGICAL INFORMATION
Acute aquatic toxicity
EL50 method of the water accommodated fraction (W.A.F.).

Property Result Species

96-hour LC50 – Fish > 1 000 mg/l Oncorhynchus mykiss (rainbow trout)
48-hour EC50 - Aquatic invertebrates > 600 mg/l Daphnia magna (Water flea)
72-hour EC50 - Algae/aquatic plants > 1 000 mg/l Selenastrum capricornutum

Chronic aquatic toxicity

Persistence and degradability
OECD Test No. 301A:. Easy Biodegradability: test loss of dissolved organic carbon (DOC) (TG 301 A): None
readily biodegradable

Bioaccumulative potential
Product has a low potential to bioconcentrate.

Toxicity
Chemical name log Pow

Benzene, C14-30-alkyl derive 6.6

Bioaccumulative potential:
No data available

Mobility in soil
No data available

PBT and vPvB assessment

No data available. This substance is not considered to be persistent, bioaccumulating nor toxic (PBT)
This substance is not considered to be very persistent nor very bioaccumulating (vPvB)

Other adverse effects

No data available

13. DISPOSAL CONSIDERATIONS

Methods of waste disposal.
This material when discarded may be hazardous waste as that term is defined by the Conservation Resource and Recovery
Act (RCRA), 40 CFR 261.24, due to its characteristic toxicity. This material should be analyzed as method 1311 for D018
benzene compound. See 40 CFR 268.40 or appropriate local regulations standards for the concentration of base.

Contaminated packaging
Empty containers should be taken to an approved waste management for recycling or disposal.
Product Offer surplus and non-recyclable solutions to a licensed disposal company.

Other Information
This product meets the criteria for synthetic oil under the standards of the U.S. EPA for the management
Used Oil (40 CFR 279). These rules govern recycling and disposal instead of 40 CFR 260-272 residues
Federal hazardous program in states that have adopted these used oil regulations. Consult your attorney or appropriate
regulatory official to ensure that these standards have been adopted in your state.
Recycle or burn under the applicable rules. It should not be dumped, spilled, rinsed or washed product so that enters sewers
or public waterways.

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14. TRANSPORT INFORMATION
DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods

15. REGULATORY INFORMATION

OSHA Hazards
Flammable liquid, Target Organ Effect, Harmful if swallowed.

SARA 302 Components

SARA 302: This material contains no chemicals subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA for short
English). This product contains no chemical subject to the reporting requirements of the Act and
Title 40 Code of Federal Regulations, part 372

SARA 311/312 Hazards

Acute Health Hazard

Clean Water Act

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40
CFR 122.21 and 40 CFR 122.42)

CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Act
Response, Compensation, and Comprehensive Environmental Liability (CERCLA for its acronym in English) (40 CFR 302) or
Amendments and Reauthorization Act Superfund (SARA) (40 CFR 355). There may be reporting requirements
specific local, regional or state level pertaining to releases of this material.

State regulations of right to information from the U.S.

This product does not contain any substances regulated under state regulations right to information.

International regulations

Hazard Class WHMIS

D2B Toxic materials
Materials causing other toxic effects

International Inventories

TSCA comply
DSL/NDSL comply
EINECS/ELINCS comply
ENCS (Japan) comply
IECSC comply
KECL comply
PICCS comply
AICS comply

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16. OTHER INFORMATION

Clasificacion HMIS
Health hazard: 1
Flammability: 1
Physical hazards: 0

Clasificación NFPA
Peligro para la salud: 1
Fuego: 1
Peligro de Reactividad: 0

Further information
The information above is based on available data which is believed to be correct. However, no guarantee merchantability,
fitness for any purpose or any other warranty is expressed or implied regarding the accuracy of this information, the results
obtained from the use, risks related to the use of materials or any other use not infringe any patent, since the information
contained herein will be applied under conditions beyond our control and with which we may be unfamiliar, we assume no
liability resulting from its use. this information is set on the conditions that the person receiving it shall make their own
determinations under the suitability of the material for your particular job.