7.
8. Explains the meaning of the designation D and L as used to specific the
configuration of carbohyrdrates? D- and L- notation provides a quick shorthand
for designating enantiomers. D-Glucose is the enantiomer of L-Glucose, for
example. As L-Alanine is the enantiomer of D-Alanine.It is assigned as follows.
For a sugar drawn in the Fischer projection with the most oxidized carbon at the
top (i.e. aldehyde or ketone).
9. which carbon determine whether the sugar has a D and L configuration?:
Emil Fischer began studying carbohydrates in the late 1880’s. It was known by
that time ( Van’t Hoff, 2001) that carbon was tetrahedral, and it was also known
that molecules containing a carbon with four different substituents could rotate
plane-polarized light ( Pasteur, 2009). What wasn’t known was the absolute
configuration of any of the chiral molecules – what we’d refer to today as their “R”
and “S” configurations.
11.Plants store carbohydrates in the form of starch granules as primary metabolism that
consists of two parts which are, amylose and amylopectin by accumolation of the
glucose unit during the photsynthesis. While in the Animal, glycogen is the storage form
of glucose which is analogous to the starch in plants. Glycogen is synthesized and
stored mainly in the liver and the muscles. Structurally, glycogen is very similar to
amylopectin with alpha acetal linkages, however, it has even more branching and more
glucose units are present than in amylopectin. (Ophardt, 2003)
14. Glycosidic bonds are covalent chemical bonds that hold together a glycoside. A
glucoside is simply a ring shaped sugar molecule that is attached to another molecule.
The sugar ring maybe either a 5-membered ring or a 6 membered ring, and the other
molecule can be — and after is — another sugar. It is formed by a condensation
reaction, which means that one water molecule is produce during formation of a
glycoside (George,2019). While Glucosidic bond are chemical linkages formed between
two monosaccharides or polysaccharides. They form through hydrolysis on the
anomeric carbon’s hydroxyl group of the conjoined saccharide. H2O is removed from
the molecules and they become joined by an oxygen atom. Glucoside bond are
important to the formation of complex polysaccharide. (Izubachi,2002)