R ###

P
D
A B
Reaktor Kondensor
F
###

Pr

Diketahui :
F : 0.280 CO2 A : Xco2a Pr : 0.500 CH3OH
0.700 H2 xh2a 0.500 H2O
0.020 I 0.004 I
Xh2 = 0.600
1. Mencari komposisi F & D berdasarkan reaksi REAL
CO2 + ### H2O = CH3OH + H2O
m : 320.000 800.000 - -
r : 160.000 480.000 160.000 160.000
s : 160.000 320.000 160.000 160.000

Komp F (kmol) D (kmol) x di D

CO2 320.000 160.000 0.318 Komp D = Komp P = Komp R
H2 800.000 320.000 0.636
I 22.857 22.857 0.045
1142.857 502.857 1.000

2. Mencari F berdasarkan basis

Basis = 100.000 kmol F
Komp F (kmol)
CO2 28.000
H2 70.000
I 2.000
100.000

3. Reaction balance berdasarkan basis

CO2 + ### H2O = CH3OH + H2O
m : 28.000 70.000 - -
r : 14.000 42.000 14.000 14.000
s : 14.000 28.000 14.000 14.000

4. Mol balance
Sistem 1 Sistem Kondensor
H2 : Xh2a A + 0.636 R = 70.000 Xh2b B = 0.636 D
CO2 : Xco2a A + 0.318 R = 28.000 Xco2b B = 0.318 D
I : 0.004 A + 0.045 R = 2.000 Xib B = 0.045 D
 Sistem Reaktor
in - out + gen - kons = acc
H2 : 70.000 - xh2b B - 42.000 = 0.000
Xh2b B = 28.000 ...(1)

5. Mencari D berdasarkan basis

Xh2b B = 0.636 D
28.000 = 0.636 D
D = 44.000 kmol

6. Mencari R berdasarkan basis

A + R = 100.000
A = ### - R

0.004 A + 0.045 R = 2.000

0.004 (100 - R) + 0.045 R = 2.000
0.400 -0.004 R + 0.045 R = 2.000
0.041 R = 1.600
R = 38.596 kmol

7. Mencari A berdasarkan basis

A + R = 100.000
A = ### - R
= ### - 38.596
= 61.404 kmol

8. Mencari komposisi A berdasarkan basis

Xh2a A + 0.636 R = 70.000
61.404 Xh2a + 24.561 = 70.000
Xh2a = 0.740

Xco2a A + 0.318 R = 28.000

61.404 Xco2a + 12.281 = 28.000
Xco2a = 0.256
Xia = 0.004

9. Mencari P berdasarkan basis

Sistem 2
H2 : Xh2d D = Xh2p P + Xh2r R
28.000 = 0.636 P + 24.561
P = 5.404 kmol

Fresh Feed (A) Recycle (R) Purge (P)

Komponen
Xi kmol Xi kmol Xi kmol
CO2 0.256 15.719 0.318 12.281 0.318 1.719
H2 0.740 45.439 0.636 24.561 0.636 3.439
I 0.004 0.246 0.045 1.754 0.045 0.246
1.000 61.404 1.000 38.596 1.000 5.404

701.781
Basis awal : 100 kmol menghasilkan 14 kmol CH3OH.
Diinginkan 160 kmol CH3OH sehingga:
100.000 = 14.000
x = 160.000 11.429
x = 1142.857
Maka F dikali : 11.429

R 2.000
P
D
A B
Reaktor Kondensor
F
###

Pr

Diketahui :
F : 0.280 CO2 A : Xco2a Pr : 0.500 CH3OH
0.700 H2 xh2a 0.500 H2O
0.020 I 0.004 I
Xh2 = 0.600
1. Mencari komposisi F & D berdasarkan reaksi REAL
CO2 + ### H2O = CH3OH + H2O
m : 320.000 800.000 - -
r : 160.000 480.000 160.000 160.000
s : 160.000 320.000 160.000 160.000

Komp F (kmol) D (kmol) x di D

CO2 320.000 160.000 0.318 Komp D = Komp P = Komp R
H2 800.000 320.000 0.636
I 22.857 22.857 0.045
1142.857 502.857 1.000

2. Mencari F
Basis = 1142.857 kmol F
Komp F (kmol)
CO2 320.000
H2 800.000
I 22.857
1142.857

3. Reaction balance
CO2 + ### H2O = CH3OH + H2O
m : 320.000 800.000 - -
r : 160.000 480.000 160.000 160.000
s : 160.000 320.000 160.000 160.000
4. Mol balance
Sistem 1 Sistem Kondensor
H2 : Xh2a A + 0.636 R = ### Xh2b B = 0.636 D
CO2 : Xco2a A + 0.318 R = ### Xco2b B = 0.318 D
I : 0.004 A + 0.045 R = 22.857 Xib B = 0.045 D

Sistem Reaktor
in - out + gen - kons = acc
H2 : 800.000 - xh2b B - 480.000 = 0.000
Xh2b B = ### ...(1)
5. Mencari D
Xh2b B = 0.636 D
### = 0.636 D
D = 502.857 kmol

6. Mencari R
A + R = 1142.857
A = ### - R

0.004 A + 0.045 R = 22.857

0.004 (100 - R) + 0.045 R = 22.857
4.571 -0.004 R + 0.045 R = 22.857
0.041 R = 18.286
R = 441.103 kmol

7. Mencari A
A + R = 1142.857
A = ### - R
= ### - 441.103
= 701.754 kmol

8. Mencari komposisi A
Xh2a A + 0.636 R = ###
701.754 Xh2a + 280.702 = ###
Xh2a = 0.740

Xco2a A + 0.318 R = ###

701.754 Xco2a + 140.351 = ###
Xco2a = 0.256
Xia = 0.004

9. Mencari P
Sistem 2
H2 : Xh2d D = Xh2p P + Xh2r R
320.000 = 0.636 P + 280.702
P = 61.754 kmol

Fresh Feed (A) Recycle (R) Purge (P)

Komponen
Xi kmol Xi kmol Xi kmol
CO2 0.256 179.649 0.318 140.351 0.318 19.649
H2 0.740 519.298 0.636 280.702 0.636 39.298
I 0.004 2.807 0.045 20.050 0.045 2.807
1.000 701.754 1.000 441.103 1.000 61.754
CH3OH
H2O