Hope Wilcox
Student Advisor
Alberto M. Carvalho
Superintendent of Schools
Milagros R. Fornell
Associate Superintendent
Curriculum and Instruction
Beatriz Zarraluqui
Administrative Director
Division of Mathematics, Science, and Advanced Academic Program
Table of Contents
Introduction ...............................................................................................................................4
Next Generation Sunshine State Standards ..................................................................5
Resources
Materials ......................................................................................................................10
Laboratory Safety and Contract...................................................................................14
Lab Roles and Descriptions ........................................................................................15
Writing in Science........................................................................................................16
Hands-on Activities
The purpose of this document is to provide Chemistry teachers with a list of basic laboratories
and hands-on activities that students in a Chemistry class should experience. Each activity is
aligned with the Chemistry Curriculum Pacing Guide and the Next Generation Sunshine State
Standards.
All the information within this document provides the teacher an essential method of integrating
the Science Next Generation Sunshine State Standards with the instructional requirements
delineated by the Course Description published by the Florida Department of Education
(FLDOE). The information is distributed in three parts:
(1) A list of the course specific benchmarks as described by the FLDOE. The Nature of
Science Body of Knowledge and related standards are infused throughout the
activities. Specific Nature of Science benchmarks may have been explicitly cited in
each activity; however, it is expected that teachers infuse them frequently in every
laboratory activity.
(2) The Interim Assessment Schedule to assist teachers with content assessed leading to
the science FCAT 1.0.
(3) Basic resources to assist with laboratory safety, organization of groups during lab
activities, and scientific writing of reports.
(4) Hands-on activities that include a teacher-friendly introduction and a student handout.
The teacher introduction in each activity is designed to provide guidelines to facilitate
the overall connection of the activity with course specific benchmarks through the
integration of the scientific process and/or inquiry with appropriate questioning
strategies addressing Norman Webb‘s Depth of Knowledge Levels in Science.
All the hands-on activities included in this packet were designed to cover the most important
concepts found in the Chemistry course and to provide the teacher with sufficient resources to
help the student develop critical thinking skills in order to reach a comprehensive understanding
of the course objectives. In some cases, more than one lab was included to cover a specific
standard, benchmark, or concept. In most cases, the activities were designed to be simple and
without the use of advanced technological equipment to make it possible for all teachers to use.
However, it is highly recommended that technology, such as Explorelearning Gizmos and hand-
held data collection equipment from Vernier, Texas Instruments, and Pasco, is implemented in
the science classrooms.
This document is intended to bring uniformity among the science teachers that are teaching this
course so that all can work together, plan together, and rotate lab materials among classrooms.
Through this practice, all students and teachers will have the same opportunities to participate in
these experiences and promote discourse among learners, which are the building blocks of
authentic learning communities.
Acknowledgement
M-DCPS Curriculum and Instruction Division of Mathematics, Science, and Advanced Academic
Programs would like to acknowledge the efforts of the teachers who worked arduously and
diligently on the preparation of this document.
3. Density
100-ml graduated cylinder can of non-diet soft drink
2-L graduated cylinder (plastic) can of diet soft drink
balance (50g capacity) dropper
distilled water 2000 ml graduated cylinder (or large
rubber stopper (#2 solid) container)
7. Periodic Trends
96 –well microplate or Playdough Ruler (cm)
36 plastic straws or coffee stirrers Graph paper
Scissors Table of atomic radii and ionization
Calculator energies
20. Half-Life
100 pennies (include a mixture of pre large box top
and post 1982 pennies) 2 plastic cups
Zip loc bag
balance
Rules:
Know the primary and secondary exit routes from the classroom.
Know the location of and how to use the safety equipment in the classroom.
Remove all unnecessary materials from the work area and completely clean up the work
area after the experiment.
Safety Contract:
I will:
Follow all instructions given by the teacher.
Protect eyes, face and hands, and body while conducting class activities.
Carry out good housekeeping practices.
Know where to get help fast.
Know the location of the first aid and firefighting equipment.
Conduct myself in a responsible manner at all times in a laboratory situation.
I, _______________________, have read and agree to abide by the safety regulations as set
forth above and also any additional printed instructions provided by the teacher. I further agree
to follow all other written and verbal instructions given in class.
Cooperative learning activities are made up of four parts: group accountability, positive
interdependence, individual responsibility, and face-to-face interaction. The key to making
cooperative learning activities work successfully in the classroom is to have clearly defined
tasks for all members of the group. An individual science experiment can be transformed into a
cooperative learning activity by using these lab roles and responsibilities:
A report is a recap of what a scientist investigated and may contain various sections and
information specific to the investigation. Below is a comprehensive guideline that students can
follow as they prepare their lab/activity reports. Additional writing templates can be found in the
District Science website.
Benchmarks Covered:
A summary of the main concepts that you will learn by carrying out the experiment.
Problem Statement:
Identify the research question/problem and state it clearly.
Hypothesis(es):
State the hypothesis carefully, logically, and, if appropriate, with a calculation.
1. Write your prediction as to how the independent variable will affect the dependent
variable using an IF-THEN-BECAUSE statement:
i. If (state the independent variable) is (choose an action), then (state the dependent
variable) will (choose an action), because (describe reason for event).
Procedures:
Do not copy the procedures from the lab manual or handout.
Summarize the procedures that you implemented. Be sure to include critical steps.
Give accurate and concise details about the apparatus (diagram) and materials used.
Data:
Ensure that all observations and/or data are recorded.
1. Use a table and write your observations clearly. (e.g., color, solubility changes, etc.)
2. Pay particular attention to significant figures and make sure that all units are stated.
Chemistry HSL Page 16
Curriculum and Instruction
Data Analysis:
Analyze data and specify method used.
If graphing data to look for a common trend, be sure to properly format and label all aspects
of the graph (i.e., name of axes, numerical scales, etc.)
Results:
Ensure that you have used your data correctly to produce the required result.
Include any errors or uncertainties that may affect the validity of your result.
NGSSS:
SC.912.N.1. Describe and explain what characterizes science and its methods.
SC.912.N.1.6 Describe how scientific inferences are drawn from scientific observations and
provide examples from the content being studied.
(Also addresses SC.912.N.1.1, SC.912.N.2.1, SC.912.N.3.1 and SC.912.N.3.4).
Purpose of Lab/Activity:
To practice working safely in a laboratory.
Learn how to interpret chemical hazard labels.
To become familiar with ―Material Safety and Data Sheets.‖
Extension: Ask the students for homework to write down the chemical substances found in
detergents at home. Then, they should look up the MSDS at http://www.ehso.com/msds.php.
For each chemical substance they most record their toxicity and precautions in the event of
ingestion.
NGSSS:
SC.912.N.1. Describe and explain what characterizes science and its methods..
SC.912.N.1.6 Describe how scientific inferences are drawn from scientific observations and
provide examples from the content being studied.
(Also addresses SC.912.N.1.1, SC.912.N.2.1, SC.912.N.3.1 and SC.912.N.3.4).
Background:
Chemistry has been developed largely through experimentation. Chemistry courses use
laboratory experiences to demonstrate, clarify, and develop principles of chemistry.
Behavior in the laboratory is more structured than in the classroom. Certain rules of conduct
pertaining to safety and keeping a clean work environment must be followed at all times. You
must also adopt correct procedures for using glassware and other pieces of equipment. General
safety rules are summarized at the beginning of this lab manual. However, there often will be
more specific safety rules or special procedures to follow when performing an experiment. Your
teacher will provide these added instructions before you perform any lab activity. If you are
unsure of any procedure, always ask your teacher before proceeding. In this activity, you will
practice some laboratory techniques and apply laboratory safety rules.
Safety:
There should be no eating or drinking in the lab.
Goggles and aprons must be worn at all times.
Procedures:
Complete the activities in each station and investigate each of the following questions. The
investigations do not need to be done in order. The write-up for each will follow this basic lab
report format:
4. Results and Conclusions: Write one safety rule that follows from your observations.
What to do:
1) Cut two strips of yarn about 8 cm long. Coat one with hairspray and let it dry.
2) One at a time, hold the un-covered yarn with the tong and light one end for less than 5
seconds. Repeat with the hairspray covered yarn and make observations.
3) Clean up: put out the flame by smothering the fire with a lid; throw yarn in trash;
return other materials to station.
Lab Station F. Where are the fire extinguisher and the fire blanket located and how do
you use it?
Materials: paper, pencil, and common sense
Safety: none, but don‘t actually discharge the fire extinguisher
What to do:
1) Make a map that locates the fire extinguishers that are available to you.
2) Take one off the wall and read the label; describe the types of fires it can put out and
how to use it
3) Clean up: put the fire extinguisher back
Procedures: Use the documents listed above to answer the following questions.
1. Interpret the following colors on a chemical hazard label:
a. red; b. yellow; c. blue; and d. white
2. Interpret numbers on a chemical hazard label.
a. A number ____ is the most serious, and a number ____ is the least serious.
b. What does the number four on a red background indicate to the user?
c. What does the number zero on a yellow background mean?
3. Complete the following for acetone:
a. Fill in the appropriate NFPA hazard coding colors and numbers on the label above.
b. Complete the missing information on the MSDS on the back of this page.
4. What does MSDS stand for?
5. What information is found in an MSDS sheet?
6. What information do the chemical hazard label and MSDS have in common?
7. Why should an individual working with chemicals understand the hazard coding system
on a chemical label?
8. What additional information provided on an MSDS might be of use to an individual
working with chemicals?
9. What does the physical data include?
10. What are the Fire Hazards associated with this product?
11. Is this substance stable or reactive?
12. Can this substance be considered toxic? How?
13. Write the safety precautions for its handling.
Chemical Labels: Lay out different chemicals for students to analyze the information
provided in the labels.
1. What is the information contained in a label of any chemical?
2. What does a lower number indicate? A higher number?
3. What is the storage code for your chemical?
4. Look on page 14 (p18) of the Modern Chemistry book, according to the table, what are
the different grades of chemicals?
Procedures: Distribute students in group to perform the disaster scripts for the class. Discuss
what was observed and write the rules that should have been followed in each scenario.
NGSSS:
SC.912.N.1.1 Define a problem based on a specific body of knowledge, for example: biology,
chemistry, physics, and earth/space science, and do the following: 1) pose questions about the
natural world, 2) conduct systematic observations, 3) examine books and other sources of
information to see what is already known, 4) review what is known in light of empirical evidence,
5) plan investigations, 6) use tools to gather, analyze, and interpret data (this includes the use of
measurement in metric and other systems, and also the generation and interpretation of
graphical representations of data, including data tables and graphs), 7) pose answers,
explanations, or descriptions of events, 8) generate explanations that explicate or describe
natural phenomena (inferences), 9) use appropriate evidence and reasoning to justify these
explanations to others, 10) communicate results of scientific investigations, and 11) evaluate the
merits of the explanations produced by others.
(Also addresses: SC.912.N.1.2 to N.1.7, SC.912.N.2.2 and SC.912.N.2.4)
Purpose of Lab/Activity: Use scientific inquiry to explore the effectiveness of different methods
to contain a simulated salt water oil spill.
c. Provide students with a copy of the handout: Power Writing and the Art of
Scientific Conclusions. Discuss and clarify with the class each section of
the write up.
d. Divide students into groups of 4 and have them brainstorm possible
methods of cleaning the simulated oil spill based on the possible materials
available for the lab.
e. Ask students what is the importance of including a control group? Also have
students discuss why more than one trial is necessary when performing an
experiment.
f. Have each lab group propose a plan that includes a hypothesis, the
experimental design, a detailed list of materials, and the step by step
procedures. The procedure should include a method to measure the
amount of oil before and after the clean up. Review each plan and clarify
any errors with each lab group before they test their hypothesis.
g. Provide students with a translucent container with 400 ml of the prepared
simulated ocean water and access to the materials that they will need for
their test.
What the teacher will do:
a. Discuss with each group the distribution of roles for the lab.
b. Monitor each group as they perform their experiment.
During
c. Review their data collection instruments and ASK PROBING QUESTIONS
activity:
about the qualitative and quantitative observations made by each group.
d. Make sure that students document any changes that they make to their
original plan.
What the teacher will do:
a. Have students present their findings to the class including a summary of
their plan, and any pictures and data that document their results.
b. Ask students how the use of the scientific method was instrumental in
helping them propose a plan to contain the simulated oil spill.
After c. Have students evaluate the results provided by each team and judge which
activity: would be the best method to contain the oil spill.
d. Each student should write a complete report for their lab using the “Power
Writing Model 2009”
1. In their conclusions, students should refer to the magnitude of the Exxon
Valdez and the BP Gulf of Mexico oil spills and explain the advantages
and limitations of using models in scientific inquiry.
Extension:
Gizmo: Mystery Powder Analysis
NGSSS:
SC.912.N.1.1 Define a problem based on a specific body of knowledge, for example: biology,
chemistry, physics, and earth/space science, and do the following: 1) pose questions about the
natural world, 2) conduct systematic observations, 3) examine books and other sources of
information to see what is already known, 4) review what is known in light of empirical evidence,
5) plan investigations, 6) use tools to gather, analyze, and interpret data (this includes the use of
measurement in metric and other systems, and also the generation and interpretation of
graphical representations of data, including data tables and graphs), 7) pose answers,
explanations, or descriptions of events, 8) generate explanations that explicate or describe
natural phenomena (inferences), 9) use appropriate evidence and reasoning to justify these
explanations to others, 10) communicate results of scientific investigations, and 11) evaluate the
merits of the explanations produced by others.
(Also addresses: SC.912.N.1.2 to N.1.7, SC.912.N.2.2 and SC.912.N.2.4)
Background:
Accidental oil spills are not common; but when they occur, they can cause huge environment
damage, affecting wildlife and inhabits of the area. Two of the major oil spills are the Exxon
Valdez oil spill in Prince William Sound, off the coast of Alaska in the mid 80‘s, and recently the
BP Gulf of Mexico oil spill, off the coast of Louisiana, Alabama and Florida. As the oil spreads
over the surface of the water, it forms a large oil slick which is particularly challenging to contain
and clean. Generally, the process involves the physical containment of slick and then the
breaking up of the large slick into clumps which are easier to clean. Natural processes such as
evaporation, wave action, and biological breakdown work to clean up the oil but at a very slow
rate. In this lab, you will act as scientists to test the most effective physical and chemical
methods to contain remove or dissolve the oil, to prevent major damages, and restore a safe
environment for all living organisms.
Purpose of activity:
Use scientific inquiry to explore the effectiveness of different methods to contain a
simulated salt water oil spill.
Safety:
Always wear safety goggles and a lab apron.
Do not eat or drink anything in a laboratory.
Follow appropriate disposal of excess oil, waste oil and water mixtures, and any oil
soaked materials. Do not pour down the drain.
Graduated cylinder
Cleaning supplies: paper towels, fabric, coffee filters, string, sponges, scrap construction
paper, sand, string and various brands of detergent
Instrument to measure: rulers (cm), pipettes, graduated cylinder.
Optional: blank acetate or tracing paper and markers.
Procedures:
1. Brainstorm different methods for containing and cleaning an oil spill within your lab group.
Propose and write up a treatment plan that includes a problem statement, hypothesis, the
experimental design, a detailed list of materials, and a method to quantify the amount of
oil slick before and after clean up.
2. Obtain the materials required to test your treatment plan.
3. Create your simulated oil spill using the translucent container to which you will add the
ocean water prepared by your teacher and using a graduated cylinder add 20 ml of
simulated oil to represent the slick.
4. Measure the initial oil slick and record in a data table.
5. Follow your proposed plan to contain and clean the slick. Record your observations in
your table.
6. Measure the remaining oil slick and record in table.
Observations/Data:
1. Create a data table to record your observations and measurements for each trial of your
oil containment and cleaning tests.
2. If possible, take photographs and try to visually document the size of your slick using
trace paper or acetate.
Data Analysis:
1. Use data generated in all trials and compare the surface area of the initial oil slick and the
oil slick after the proposed treatment.
2. Compare your group data with the data presented by other groups‘ containment and
clean up treatment.
Results:
1. How would oil floating between the surface and the bottom or oil stuck in the ocean floor
impact the method of cleanup?
2. Did time affect the oil spill?
3. Based on the results presented by each group, which cleanup treatment tested in this
investigation was the most effective. Explain.
4. Did trying several treatments make a difference in the cleanup? Would combining several
methods be effective?
5. What problems could be encountered in reclaiming and reusing the oil removed?
6. What effect did the detergent have on the oil spill? Hint: Research surfactants.
7. What were some of the limitations of this oil spill simulation?
Conclusion:
Write a report, using the ―Power Writing Model‖ provided by your teacher.
Density
NGSSS:
MA.912.S.1.2 Determine appropriate and consistent standards of measurement for the data to
be collected in a survey or experiment.
MA.912.S.3.2 Collects, organizes, and analyzes data sets, determine the best format for the
data and present visual summaries for the following: bar graphs, line graphs, stem and leaf
plots, circle graphs, histogram, box and whisker plots, scatter plots and cumulative frequency
(ogive) graphs.
Purpose of Lab/Activity:
Measure the mass and volume of several different objects.
Calculate the density of objects by using their measured mass and volume.
Compare the densities of various objects.
Learn how to calculate experimental percentage error.
Extension:
Gizmo: Density Laboratory
Density
NGSSS:
MA.912.S.1.2 Determine appropriate and consistent standards of measurement for the data to
be collected in a survey or experiment.
MA.912.S.3.2 Collects, organizes, and analyzes data sets, determine the best format for the
data and present visual summaries for the following: bar graphs, line graphs, stem and leaf
plots, circle graphs, histogram, box and whisker plots, scatter plots and cumulative frequency
(ogive) graphs.
Background:
Density is a physical property of a substance and is often used to identify what the substance is.
Density is a ratio that represents how much mass (amount of matter) there is in a unit of volume
(amount of space something occupies) of a substance. Density can be computed by using the
equation - . Mass is usually expressed in grams and volume in milliliters (ml), which are
equivalent to cubic centimeters (cm3).
Mass and volume measurements can be made in the laboratory. Mass can be determined by
using a balance. If the object has a regular shape, such as a cube or a cylinder, volume can be
calculated from length measurements. However, most objects have irregular shapes, and the
volume must be determined indirectly. One way to measure the volume of an irregularly shaped
item that does not dissolve in or react with water is by water displacement. An item that is
entirely submerged in water will displace a volume of water equal to its volume. It is necessary
to use the proper units when calculating the density of a substance. Densities of liquids and
solids are usually expressed in terms of g/ml or g/cm 3. Densities of gases are usually expressed
in g/L.
The accuracy of your methods can be reported in terms of percent error. The percent error of
measurements is a comparison of the differences between experimental results and theoretical
or standard values, expressed as a percentage. The equation for percent error is:
Purpose of Lab/Activity:
Measure the mass and volume of several different objects.
Calculate the density of objects by using their measured mass and volume.
Compare the densities of various objects.
Calculate percentage error
Safety:
Always wear safety goggles and a lab apron.
Clean up any spills immediately.
Do not eat or drink anything in a laboratory.
Procedures:
Part A: Density of Water
1. Find the mass of a clean, dry 100-ml graduated cylinder. Record this mass in Data Table
1.
2. Fill the cylinder with distilled water. Use a dropper to adjust the bottom of the meniscus
exactly to the 100.0-ml mark.
3. Find and record the mass of the graduated cylinder and water.
4. Calculate and record the mass of the water.
17. Use the mass and volume data to calculate the densities of water, the rubber stopper, a
can of non-diet soft drink, and a can of diet soft drink. Show work and then record the
answers in the data tables.
Observations/Data:
Data Table 1
Part A: Density of Water
Mass of empty graduated cylinder (g)
Mass of graduated cylinder and water (g)
Mass of water (g)
Volume of water (ml)
Density of water (g/ml)
Data Table 2
Part B: Density of Rubber Stopper
Mass of rubber stopper (g)
Initial volume of water in graduated cylinder (ml)
Final volume of water in graduated cylinder (ml)
Volume of rubber stopper (ml)
Density of rubber stopper (g/ml)
Data Table 3
Part C: Density of a Can of Non-Diet Soft Drink
Mass of can of non-diet soft drink (g)
Initial volume of water in graduated cylinder (ml)
Final volume of water in graduated cylinder (ml)
Volume of can of can of non-diet soft drink (ml)
Density of can of non-diet soft drink (g/ml)
Data Table 4
Part D: Density of a Can of Diet Soft Drink
Mass of can of diet soft drink (g)
Initial volume of water in graduated cylinder (ml)
Final volume of water in graduated cylinder (ml)
Volume of can of diet soft drink (ml)
Density of can of diet soft drink (g/ml)
Observation/Data Analysis:
1. What is the density determined for your water sample?
2. Using 1g/ml or 1 g/cm3 as the theoretical density of distilled water, calculate the percent
error of your measurement (see formula in Background Information section). Show work.
3. What could you do to improve the accuracy of your measurements?
4. How does the density of the rubber stopper compare to the density of water?
5. Compare the densities of the soft drinks tested? Which soda is denser? How can you
explain this result?
Conclusion:
1. When you use the terms heavier or lighter to compare different objects with the same
volume (such as the two soda cans), what property of the objects are you actually
comparing?
2. Would you expect the densities of various fruit juices in the same container to all be the
same? Explain.
3. How can the concept of density be used to differentiate between a genuine diamond and
an imitation diamond?
4. Explain why a tractor-trailer can be completely filled with one type of merchandise, such
as butter, but only partially filled with a second type of material, such as steel.
5. The density of aluminum is 2.70 g/cm3. What volume will 13.5 grams of aluminum
occupy?
NGSSS:
SC.912.P.8.1 Differentiate among the four states of matter.
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes of matter.
Purpose of Lab/Activity:
To learn to operate a balance as a tool to measure mass.
To establish the law of conservation of mass from experimental evidence
To understand and represent the following changes of a system at the particle level:
o Part 1: Expansion of matter by pulling steel wool strands apart
o Part 2: Melting of ice
o Part 3: Combining solutions to form a precipitate
o Part 4: Burning steel wool which adds oxygen particles to the iron wool
o Part 5: Dissolving sugar
o Part 6: Dissolving Alka-Seltzer
To be able to conclude that despite observable changes in a closed system the mass
does not change. The changes occur due to a rearrangement of the atoms, but as long
as the amount of atoms remains constant, so will the mass.
Experiment Overview: The lab activity consists of 6 parts. For every part, the students will first
predict what will happen to the system as the change is performed. Then they will measure the
mass of the system before and after an observable change has occurred. By using the initial
and final mass, students will calculate the change of mass using the formula: ∆m = m f - mi. The
use of an analog balance is preferred but digital balances are also acceptable.
Part 2:
Small vial and chip of ice
Part 3:
Small vials
Solutions of calcium nitrate Ca(NO3)2 and sodium carbonate Na2CO3
Part 4:
Small tuft of steel wool
Crucible tongs
Evaporating dish
Bunsen burner (a lighter will also work)
Part 5:
Vial with cap
Sugar
Part 6:
Vial with cap
¼ tablet of Alka-Seltzer
NGSSS:
SC.912.P.8.1 Differentiate among the four states of matter.
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes of matter.
Background: It is possible to imagine all matter as composed of very small particles called
atoms. Mass is a property of matter which accounts for the amount of ―stuff‖ in an object. The
heavier an object, the more mass it has, which means the more matter or atoms. A balance is a
piece of equipment which can measure the amount of mass, in grams, of an object.
Purpose of Lab/Activity: In this lab you will perform 6 experiments and in each one an object,
called the system, will undergo a visible change. The question to be answered is how this
change will affect the mass of the system.
Safety: All parts require minimal safety precautions except for part 4. In part 4 you will be
working with a Bunsen burner or a lighter. Remember to wear goggles and pull all hair back
while operating a burner.
Part 2:
Small vial and chip of ice
Part 3:
Small vials
Solutions of calcium nitrate Ca(NO3)2 and sodium carbonate Na2CO3
Part 4:
Small tuft of steel wool
Crucible tongs
Evaporating dish
Bunsen burner (a lighter will also work)
Part 5:
Vial with cap
Sugar
Part 6:
Vial with cap
¼ tablet of Alka-Seltzer
Procedures:
Part 1 – Pulling Steel wool apart
1. Obtain a small wad of steel wool which is tightly rolled in a ball.
2. Measure the mass of the small tuft of steel wool
3. Separate the strands of steel wool until it reaches twice the size
4. Measure the mass of the expanded steel wool.
5. Keep the steel wool around as you will use it again in part 4
6. Calculate ∆m and represent the change you observed at the particle level
3. Measure the mass of the vial with water and the cap with the Alka-Seltzer
4. Place the Alka-Seltzer in the water and wait until it all dissolves and stops bubbling
5. Measure the mass of the dissolved Alka-Seltzer and cap
6. Calculate ∆m and represent the change you observed at the particle level
Observations/Data Analysis:
Answer the following questions on a separate sheet for each of the six parts:
1. Explain this experiment and predict how the mass of the system will be affected by the
change you perform?
Results/Conclusion:
1. How do your results compare to your predictions? Why?
2. From the post-lab class discussion, what is the understanding you have gained from this
experiment?
Isotopes
NGSSS:
SC.912.P.8.3 Explore the scientific theory of atoms (also known as atomic theory) by describing
changes in the atomic model over time and why those changes were necessitated by
experimental evidence.
SC.912.P.8.4 Explore the scientific theory of atoms (also known as atomic theory) by describing
the structure of atoms in terms of protons, neutrons and electrons, and differentiate among
these particles in terms of their mass, electrical charges and locations within the atom.
Purpose of Lab/Activity:
To determine the isotopic composition of 100 pennies
To apply the lessons of the penny-isotope analogy to isotopic data.
*This activity can be done with a smaller amount of pennies as long as the amount used by all
groups is consistent. Also, to facilitate obtaining the pennies, teachers should ask students to
bring pennies from home the day before the activity.
f. How is the ―average‖ atomic mass of an element derived from its relative
isotopes?
g. Model deriving the weighted average value of 4 quarters, 5 dimes, and 9
pennies. (In a weighted average, the value of each type of item is multiplied
by the number of that type of item. The products are added, and the sum is
divided by the total number of items). Have the students describe the steps
and calculate their answers.
h. Have students read the entire laboratory activity and make a flow chart of
the procedure the students will follow.
What the teacher will do:
a. Ensure that students are completing the data tables correctly.
b. Probe the thinking behind the experimental design: ―Why are we using 100
pennies for this activity?‖ Have you noticed any differences in the mass of
During
the pennies? Why are these differences found?
activity:
c. Ask the students, what further analogies can they describe in the
experiment?
d. Have students brainstorm the parts of the experiment that may not mimic
the natural properties of isotopes.
What the teacher will do:
a. Ask the students, ―How are the different types of pennies analogous to the
isotopes of an element?
b. How could the design of this experiment be improved?
c. Which step of the calculations is analogous to the relative mass of an
After
isotope?
activity:
d. Which step of the calculations is analogous to the relative weighted mass of
an isotope?
e. Have students explain which calculation is comparable to the average
weighted mass of the element, in this case an imaginary element called
―Pennium‖
Extension: Ask students to research online the existence, properties, and use of naturally
occurring and man-made isotopes of various elements.
Isotopes
NGSSS:
SC.912.P.8.3 Explore the scientific theory of atoms (also known as atomic theory) by describing
changes in the atomic model over time and why those changes were necessitated by
experimental evidence.
SC.912.P.8.4 Explore the scientific theory of atoms (also known as atomic theory) by describing
the structure of atoms in terms of protons, neutrons and electrons, and differentiate among
these particles in terms of their mass, electrical charges and locations within the atom.
Background:
The defining characteristic of an atom of a chemical element is the number of protons in its
nucleus. A given element may have a natural of different isotopes, which are nuclei with the
same numbers of protons but different numbers of neutrons. For example, 12C and 14C are two
isotopes of carbon. The nuclei of both isotopes contain six protons. However, 12C has six
neutrons, whereas 14C has eight neutrons. In general, it is the number of protons and electrons
that determines chemical properties of an element. Thus, the different isotopes of an element
are usually chemically indistinguishable. These isotopes, however, have different masses.
Between 1962 and 1982, pennies were made of brass, which is an alloy composed of 95%
copper and 5% zinc. In 1982, the rising price of copper led to a change in the composition of the
penny. Beginning in 1982, pennies have been made of zinc plated with copper. These pennies
contain 2.5% copper and 97.5% zinc. In this experiment, the two different types of pennies will
represent two isotopes of an element.
Purpose of Lab/Activity:
To determine the isotopic composition of 100 pennies
To apply the lessons of the penny-isotope analogy to isotopic data.
Safety: Always wear safety goggles and a lab apron in the lab.
Vocabulary: “Average” atomic mass, relative and weighted atomic mass, Isotopes
Procedures:
1. Use the plastic cups and large box top to contain pennies so they do not get lost.
2. Measure the mass of ten pre-1982 pennies to the nearest 0.01 g. Record your
measurement in Data Table 1. Repeat for post-1982 pennies.
3. Using your data from step 1, calculate the average mass of one pre-1982 penny. Record
this average mass in Data Table 1. Repeat for a post-1982 penny.
4. Obtain 100 pennies. Find the mass of the sample to the nearest 0.01 g. Record your
measurement in Data Table 2.
5. Divide the sample of 100 pennies into pre-1982 and post-1982 pennies. Record the
numbers of each in Data Table 2.
6. Cleanup and Disposal- Follow your teacher's instructions for returning the coins.
Observations/Data:
Data Table 1
Mass of Pennies (g)
Pennies Mass (g)
10 pre-1982
10 post-1982
Avg. pre-1982 penny
Avg.post-1982 penny
Data Table 2
Data for 100-penny sample
Mass of 100 pennies (g)
Number of pre-1982 pennies in 100-penny
sample
Number of post-1982 pennies in 100-penny
sample
Ave mass of a penny in 100-penny sample (g)
Data Analysis/Results:
1. In procedure step 1, why did you measure the mass of 10 pennies instead of the mass of
1 penny?
2. Using the mass of pre-1982 and post-1982 pennies from data table 1 and the number of
each type of penny calculate the relative mass (RM) of each type of penny and list as
average pre-1982 and post-1982 mass.
3. Calculate the relative abundance (RA) for each type of penny by dividing the amount of
each type of penny by the total amount of pennies.
4. Derive the relative weighted mass (RWM) of each penny by multiplying the relative
abundance by the relative mass for each type of penny.
5. Derive the weighted average mass (WAM) of Pennium by adding the two values from the
previous step.
Conclusions:
1. The density of copper is 8.96 g/cm3, and that of zinc is 7.13 g/cm3. Using the
compositions given in the introduction, the density of a pre-1982 penny is (0.95) (8.96
g/cm3) + (0.05)(7.13 g/cm3) = 8.87 g/cm3. Calculate the density of a post-1982 penny.
2. A typical penny has a diameter of 1.905 cm and a thickness of 0.124 cm. What is the
volume in cm3 of a typical penny? Hint: V = (π x r2)(thickness of penny).
3. Using the density and volume values from questions 1 and 2, calculate the theoretical
mass of a pre-1982 penny and the mass of a post-1982 penny.
4. Data Table 3 shows the isotopic mass and relative abundance for the most common
isotopes of copper and zinc.
a. How many protons and neutrons are there in a 64-Cu nucleus?
b. How many protons and neutrons are there in a nucleus of 64-Zn?
Data Table 3
Atomic Mass Isotopic mass Relative
Isotope
number number (amu) abundance (%)
Copper-63 29 63 62.9298 69.09
Copper-64 29 64 64.9278 30.91
Zinc-64 30 64 63.9291 48.89
Zinc-66 30 66 65.9260 27.81
Zinc-67 30 67 66.9271 4.73
Zinc-68 30 68 67.9249 18.57
Flame Tests
NGSSS:
SC.912.P.10.9 Describe the quantization of energy at the atomic level.
SC.912.P.10.18 Explore the theory of electromagnetism by comparing and contrasting the
different parts of the electromagnetic spectrum in terms of wavelength, frequency, and energy,
and relate them to phenomena and applications.
Purpose of Lab/Activity:
Observe the spectra emitted by different ions.
Identify the metallic ions by the color emitted
Extension:
Gizmo: Star Spectra
Using Planck‘s equation : Energy = Planck‘s constant (h) X frequency (√), ask the
students to calculate the energy of one photon or one packet of energy.
Flame Tests
NGSSS:
SC.912.P.10.9 Describe the quantization of energy at the atomic level.
SC.912.P.10.18 Explore the theory of electromagnetism by comparing and contrasting the
different parts of the electromagnetic spectrum in terms of wavelength, frequency, and energy,
and relate them to phenomena and applications.
Background:
Flame tests provide a way to test for the presence of specific metallic ions. The heat of the
flame excites the loosely-held electrons in the metal ion prompting the electrons to jump from a
ground level to a higher energy level in the atom. As the electrons fall back to their ground state,
energy is released from the excited electrons and can be seen as a colored flame. The color is a
combination of the wavelengths of each transition and can be used to determine the identity of
an unknown ion. Although white light produces a continuous spectrum in which all wavelengths
of visible light are present (400-700nm), an excited electron produces one or more specific lines
in the spectrum. This unique spectrum corresponds to an element‘s distinct electron
configuration.
Purpose of Lab/Activity:
Observe the spectra emitted by different ions.
Identify the metallic ions by the color emitted
Safety:
Always wear safety goggles and a lab apron in the lab.
Tie back hair and secure loose bulky clothing while working near a flame.
All of the salt solutions (except NaCl) are toxic, if any of the solutions splash on your skin,
wash affected area with large amounts of water and notify your teacher.
Handle carefully the heated nichrome wire. Make sure to hold only from the handle.
Hydrochloric acid is corrosive to the skin and clothing and the vapors are irritating to the
lungs and the eyes. Avoid contact with the solution and inhalation of its vapors. If acid
splashes on your skin or clothing wash immediately with soap and plenty of water and
notify your teacher.
Vocabulary: atoms, electrons protons, continuous spectra, emission spectra, line spectra, wave
length, frequency, energy, ground state (or level), excited state (or level).
Procedures:
1. Put on your goggles and lab apron, and secure your hair.
2. Obtain a well plate and place it on a white sheet of paper. Label each well with the name
of the solutions to be tested including a well for the unknown solution. Put a dropperful of
each known solution into its corresponding well.
3. Clean the nichrome wire before testing each solution. Rinse the loop with distilled water
followed by rinsing with the 6.0 M HCl. Place the loop into the flame for about a minute.
4. Following your teacher‘s discussion, make sure that the wire is inserted in the appropriate
region of the flame.
5. Observe the color of the clean nichrome wire in the flame; this is the color you should see
after you clean the wire for each new test. Briefly allow the wire to briefly cool down
between tests.
6. Dip the nichrome wire into the well with the calcium nitrate (Ca(NO3)2) solution and
immediately place the loop into the flame. Observe and record the color of the flame in
the Data Table. Repeat each test 2 or 3 times before trying a new solution. Clean the
nichrome wire between each test (see step 3). Continue testing and recording the flame
colors produced by the metallic ions of each solution.
7. Sodium has a very strong color which could affect the color results of your other tests. To
prevent this from happening follow proper nichrome wire cleaning procedure and leave
the sodium test for last.
8. Obtain an unknown from your teacher and repeat steps 3 and 4.
Observations/Data:
Data Analysis/Results:
1. Is the color of the flame, a chemical or a physical property of these metals? Explain.
2. What particles are found in the chemicals that may be responsible for the production of
colored light in the metallic salts you tested?
3. What color did your unknown produce in the flame? What is your unknown?
4. What would have been another way of exciting the electrons without using a Bunsen
burner?
Conclusion:
1. Why do different metals have different characteristic flame test colors?
2. The majority of the known compounds tested contain nitrate, yet the colors of the flames
were different. What effect would you expect on the flame colors if these compounds
were chlorides instead of nitrates?
3. A firework contains copper chloride and strontium sulfate. What colors would you expect
to be produced?
4. When a pan of milk boils over onto the stove the flame turns red-orange. Explain why.
Periodic Trends
NGSSS:
SC.912.P.8.5 Relate properties of atoms and their position in the periodic table to the
arrangement of their electrons.
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
Purpose of Lab/Activity:
Determine the periodic trends per group of main elements.
Relate the reactivity of elements to their electron structure.
Dough. The 3D model should include the elements‘ symbol that they
represent and the scale used.
Extension:
Gizmo: Element Builder, Electron Configuration
Periodic Trends
NGSSS:
SC.912.P.8.5 Relate properties of atoms and their position in the periodic table to the
arrangement of their electrons.
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
Background:
Elements within the same family in the Periodic Table have similar properties and in many
cases, one element can be replaced by another element with similar properties. This knowledge
is presently being widely used in medicine with radioactive tracers that are being used more
frequently to locate tumors in the body and deliver medications for their treatment. This
knowledge is also being widely studied in external pollutants and contaminants that replace
essential elements within the human body, such as the replacement of calcium in bones by
radioactive strontium
Safety: Non-applicable
Procedures:
Part 1- Making a 3D Model of Atomic Radius
1. Copy the values of Atomic Radii in Angstroms given in the first column of Table 1 into
your Periodic Table. Describe any patterns you find as you from top to bottom and from
left to right.
2. To create a 3-D model of the Atomic Radius trend, first measure a plastic straw to find
the total length in cm.
3. Choose a conversion factor to change the radius of the first 35 elements listed in Table 1
from Angstroms into centimeters (Add the conversion factor to column 3 of Table 1) .
Using the conversion factor, estimate the centimeters for each of the 35 elements, round
each value to the nearest tenth and fill in the fourth column of Table 1.
4. Using the derived centimeters measure a straw for each element and cut and place each
straw securely into the 96-well microplate to model the arrangement of the first 35
elements found in the Periodic Table.
2. Plot the points of the ionization energy (y axis) vs. the atomic number (x axis) and label
each point with the element symbol in the graph provided below.
3. Connect with different color lines the points corresponding to the elements within the
same family or group.
Observations/Data Analysis:
1. For Part 1, analyze the 3-D model you created for the atomic radii for the first 35
elements. What pattern does this data show?
2. For Part 2, analyze your graph, what pattern does your graph show?
Conclusion:
1. Provide an explanation for the pattern of the elements as you go across a group? Provide
an explanation for the pattern of the elements as you go down the group
2. Which group has the least reactive elements? How does this relate to their electronic
structure?
3. Which group of elements are the most reactive? Where are they found in the periodic
table?
4. Would you predict the second ionization energy to be higher or lower than the first?
Explain.
5. What patterns would you expect for reactivity of the Transition elements? Explain.
6. Provide students with a blank Periodic Table and have them summarize the pattern found
for both Atomic Radii and for Ionization energy.
7. Which elements are most likely to lose electrons? Explain.
Chemistry HSL Page 58
Curriculum and Instruction
Student
NGSSS:
SC.912.P.8.3 Explore the scientific theory of atoms (also known as atomic theory) by describing
changes in the atomic model over time and why those changes were necessitated by
experimental evidence.
SC.912.P.8.4 Explore the scientific theory of atoms (also known as atomic theory) by describing
the structure of atoms in terms of protons, neutrons and electrons, and differentiate among
these particles in terms of their mass, electrical charges and locations within the atom.
Prerequisite:
Students should have a solid understanding that matter is composed of tiny particles
called atoms. It is not necessary for students to know that these particles have internal
structure.
One of the goals of this activity is for them to develop a model which includes oppositely
charged particles as the atomic constituents.
Students should also recognize that there is some natural force of attraction which keeps
particles of a solid together and that make atoms stick to form compounds.
h. In the student version there is a diagram of tapes being pulled apart for
them to add dots to represent electrons. An ideal representation is
presented below:
The bottom tape has gained electrons from the top and is now negative.
The top tape lost electrons and it is now positive. This diagram assumes
that having 4 electrons (dots) makes the atom neutral which is the case
when the tapes are stuck together.
i. It is now possible to relate this activity with electricity. Students are familiar
with the shock they feel when they walk on a carpet wearing socks and
touch a grounded object. Make sure students understand that this
movement of electrons is called electricity. If you have a Van de Graaff
generator it is possible to show students a series of fun demonstrations of
electricity in action.
j. Students should also connect their newly developed model of the atom to
the forces which holds solids together and that make atoms stick as
compounds. This atomic glue is called electrostatic force.
k. Conclusion questions address everyday instances where students
experience static electricity. One important hazard students must be aware
of is static spark hazard at gas stations. This link
http://www.esdjournal.com/static/refuelfr.htm has a video of a girl
inadvertently starting a fire while pumping gas. Instruct students that they
should touch the car before nearing the gas pump to discharge themselves
and prevent a hazardous spark.
Extension:
Gizmo: Pith Ball Lab, Coulomb Force (Static)
Background: A solid is able to hold its shape because the particles that make it up are strongly
attracted to each other. Also a chemical compound such as water is composed of separate
atoms, H2O. There is a force which holds the hydrogens to the oxygens so that they form a
molecule. Some property inside the atom is responsible for the existence of this force.
Materials:
Roll of scotch tape (shared between two groups)
Piece of PVC pipe (about a foot in length)
Piece of natural fur, or wool, or a cotton tube sock
Procedures:
Part 1 - Preparing the tapes
1. Take a 15 cm piece of transparent tape and make a handle on the end by folding under the
first cm of tape, sticky side to sticky side. Place this tape on the lab table. This is the base
tape.
2. Take a second 15 cm piece of transparent tape, make a handle as before, and place this
tape on top of the base tape. Label this tape ―B‖ for bottom.
3. Attach a third similarly prepared strip of tape onto the bottom tape. Label this tape ―T‖ for
top.
4. Repeat steps 1 through 3 above. You now have two sets of 3-layer tapes.
Observations/Data:
1. What happens when you bring two top tapes near each other?
2. What happens when you bring two bottom tapes near each other?
3. What happens when you bring a top and a bottom tape near each other?
4. What happens when you bring the tapes near a recently rubbed PVC rod?
5. List the behavior of the tapes as you approach them to three objects of your choice.
Conclusion:
1. You should have noticed that when the tapes were in the roll there was no difference
between them but after they were separated they behaved differently. Similarly, before
rubbing the plastic rod, the rod is not able to attract anything but after rubbing, the rod
becomes attractive. Based on a number of observations scientists have assigned the
label of negative (–) to the charge of a rubber or plastic rod rubbed with fur or wool. The
fur or wool becomes positively charged (+). Based on your observations from using the
rod, label the T and B tapes as either a (+) or (–). Explain your reasoning.
2. Below you will find a diagram of two tapes being pulled apart. The circles in the tape
represent atoms of the tape. Based on your observations and class discussion, draw
electrons inside of the atoms (as black dots) to show the difference between the top tape
and bottom tape before and after the tapes were separated. Explain your reasoning for
each case.
3. Both bottom and top tapes are able to attract a piece of paper. Knowing that objects of
opposite charge attract each other, is the piece of paper negative or positive? Explain
your reasoning
4. On a dry day you walk on carpet wearing socks. As you grab the door knob to open the
door you feel a small shock. Explain what is happening at the particle level
5. Many gas stations have a warning for spark hazard. It is possible to ignite a dangerous
fire at a gas station just by getting in and out of your car once you start fueling. Why
does this occur and how can you prevent it?
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes of matter.
SC.912.P.8.8 Characterize types of chemical reaction, for example: redox, acid-base, synthesis
and single and double replacement reaction.
Purpose of Lab/Activity:
Observe the changes associated with a chemical reaction including heat changes,
changes in an indicator, bubble of gas released.
Determine which compounds are reactants and which are products through the use of a
chemical equation.
Use indicators in order to identify whether a solution is acidic or basic.
Extension:
Gizmo: Limiting Reactants
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes of matter.
SC.912.P.8.8 Characterize types of chemical reaction, for example: redox, acid-base, synthesis
and single and double replacement reaction.
Background:
Chemical reactions occur when molecules come together to form new products. In our bodies
and environments, chemical reactions occur continuously to help run our lives. During a
reaction, chemical bonds are broken and remade. Usually, color changes, gases being
released, changes in temperature, and/or formation of solute characterize chemical reactions.
These events describe changes in energy or solubility of the compound, meaning new products
were produced.
Chemical reactions can be defined by a chemical equation in which reactants and products are
characterized by chemical symbols. All chemical reactions are accompanied by a change in
energy. Some reactions release energy to their surroundings (usually in the form of heat) and
are called exothermic. For example, sodium and chlorine react so violently that flames can be
seen as the exothermic reaction gives off heat. On the other hand, some reactions need to
absorb heat from their surroundings to proceed. These reactions are called endothermic. A
good example of an endothermic reaction is that which takes place inside of an instant '"cold
pack." Commercial cold packs usually consist of two compounds - urea and ammonium chloride
in separate containers within a plastic bag. When the bag is bent and the inside containers are
broken, the two compounds mix together and begin to react. Because the reaction is
endothermic, it absorbs heat from the surrounding environment and the bag gets cold.
Purpose of Lab/Activity:
Observe the changes associated with a chemical reaction including heat changes,
changes in an indicator, bubble of gas released.
Determine which compounds are reactants and which are products through the use of a
chemical equation.
Use indicators in order to identify whether a solution is acidic or basic.
Safety:
Remind students that there is NO eating or drinking during the lab.
CO2 is produced in the bags. Make sure the area is well-ventilated before releasing all
the gas.
Do not let students ingest baking soda or calcium chloride. Avoid contact with eyes or
mouth. If ingested in small amounts neither compounds are toxic, but if ingested in larger
amounts give student a full glass of water and contact a medical facility.
Watch for bags exploding. Ensure the students shake the bag away from their faces and
clothes.
Once bags get tightly filled with gas, release the CO2. If the bag does explode, all the
products are non-toxic and can be washed off.
The bags can be disposed of in the trash because all products are non-toxic.
Procedures:
1. In a Ziploc type of bag, place 2 tablespoons of sodium bicarbonate (sodium hydrogen
carbonate) and a film-canister or vial (1/3 full of water or 30 ml) with 3 drops of the phenol
red indicator added to the water. Place canister/vial in the bag in the upright position.
Squeeze the excess air and seal the bag. Spill the water into the bag and record
observations. Record observations in Table 1.
2. To a second Ziploc type bag add 1 tablespoon of calcium chloride and add the same
amount of water as in the previous step but without the phenol red indicator. Repeat
procedure in step 1. Record observations in Table 1.
3. To a third Ziploc bag, add 2 tablespoons of calcium chloride into one corner of the bag,
twist off the corner to separate chemical from the rest of the bag and tie with a rubber
band or twist tie.
4. Into the opposite corner of the third bag, add 2 tablespoons of sodium bicarbonate and
twist off the corner to separate from the rest of the bag and tie with a rubber band or twist
tie.
5. Place the canister/vial with 30 ml of water in the middle of the bag in the upright position.
6. Squeeze the excess air and seal the bag.
7. Carefully untwist the 2 corners (if using rubber bands, use scissors to cut them careful
not to cut the bag) while the partner holds both corners apart.
8. Release both corners and allow all three chemicals to mix. Quickly observe any
immediate changes in the corners. Record all your observations in Table 1.
9. In a fourth bag repeat steps #3-8 but this time with 3 drops of the phenol red indicator to
the water. Record all your observations in Table 1.
Observations/Data
CaCl2 in water
NaHCO3 +
CaCl2 in water
NaHCO3 +
CaCl2 with water
+ indicator
solution
Observation/Data Analysis:
1. Which steps could be characterized as physical or chemical change? Justify your
reasoning
2. What observations confirm the presence of a chemical change?
3. Which process(es) would you characterize as exothermic? Explain.
4. Which process(es) would you characterize as endothermic? Explain.
Conclusion:
1. What was the function of the phenol red in the experiment?
2. During this reaction, baking soda (NaHCO3) is combined with calcium chloride (CaCl2) in
water. Write the balanced chemical equation for the reaction that occurred.
3. Give the names of all the compounds present in the chemical reaction you observed.
4. What type of gas is in your bags? How can you verify?
5. Propose an explanation for where the energy change originated.
6. Which general chemical principles or laws can you confirm in this investigation?
A Mole Ratio
NGSSS:
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
SC.912.P.8.9 Apply the mole concept and the law of conservation of mass to calculate
quantities of chemicals participating in reactions.
Purpose of Lab/Activity:
To examine the qualitative properties of chemical processes.
To relate macroscopic observations to changes on an atomic scale.
To quantify the amount of mass and moles of chemical species
To determine % yield and limiting reactants.
To develop a sound model for oxidation reduction reactions
h. Help students identify which reactant ―ran out‖ first. They should observe
that no iron remains. Introduce the concept of limiting and excess reagent.
i. Discuss the process of calculating theoretical, actual and percent yield.
j. A few enrichment questions that could be addressed at the end of this activity
include:
1. Could the reaction be forced backwards? Why or why not?
2. What are the factors that affect the percentage yield?
3. Is there a way to increase the yield in the reaction?
4. What do the color change of the supernatant solution tells you?
5. What other reactions follow this same pattern?
Extension:
Gizmo: Chemical Equations
A Mole Ratio
NGSSS:
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
SC.912.P.8.9 Apply the mole concept and the law of conservation of mass to calculate
quantities of chemicals participating in reactions.
Background:
Chemicals react with each other in fixed proportions based on various bonding principles. The
valence electrons in the reacting atoms are responsible for the nature of these reactions. For
these reactions to occur, the atoms must collide in the appropriate set of conditions. In this
Safety:
Safety goggles and aprons must always be worn!
No eating or drinking
Hot objects will not appear to be hot
Do not handle or heat broken, chipped, or cracked glassware
Turn off the hot plate when not in use.
Vocabulary: Chemical reactions, moles, limiting reagent, excess reagent, actual, theoretical
and percentage yield, valence electrons, compounds, ions, atoms, molecules, elements,
oxidation-reduction, spectator ions.
Procedures:
1. Measure and record the mass of a clean, dry 150-ml beaker.
2. Place approximately 12.00-grams of copper (II) pentahydrate into the 150-ml beaker and
measure and record the combined mass.
3. Add 50.00-ml of distilled water to the copper (II) pentahydrate and heat the mixture on the
hot plate at a medium setting. Stir until the solid is dissolved, but do not boil. Using
tongs, remove the beaker from the hot plate.
4. Measure approximately 2.00-grams of iron metal filings onto a piece of weighing paper.
Measure and record the exact mass of the filings.
Chemistry HSL Page 75
Curriculum and Instruction
Student
5. While stirring, slowly add the iron filings to the hot copper (II) sulfate solution.
6. Allow the reaction mixture to stand, without stirring, for 5 minutes to ensure complete
reaction. A new solid product will settle to the bottom of the beaker.
7. Use the stirring rod to decant (pour off) the liquid into a 400-ml beaker. Be careful to
decant only the liquid.
8. Add 15.00-ml of distilled water to the solid and carefully swirl the beaker to wash the
product. Decant the liquid into the 400-ml beaker.
9. Repeat step 8 two more times.
10. Place the 150-ml beaker containing the wet solid on the hot plate. Use low heat to dry
the solid.
11. Remove the beaker from the hot plate and allow it to cool.
12. Measure and record the mass of the cooled 150-ml beaker and the solid.
13. Cleanup and Disposal:
a. Make sure the hot plate is off and cool.
b. The dry solid can be placed in a waste container. Wet any residue that sticks to the
beaker and wipe it out using a paper towel. Pour the supernatant solution into a large
beaker in the fume hood.
c. Return all lab equipment to its proper place.
d. Wash your hands thoroughly after all lab work and cleanup is complete.
Observations/Data:
Data Table
Mass of empty 150-ml beaker (g)
Mass of 150-ml beaker + CuSO4 5H2O
(g)
Mass of CuSO4 ·5H2O (g)
Mass of iron filings (g)
Mass of 150-ml beaker and dried product
(g)
Mass of dried product (g)
Observations:
Data Analysis/Results:
1. List all the observations that serve as evidence that a chemical reaction occurred?
2. From your data, determine the mass of the copper produced.
3. Use the mass of copper to calculate the moles of copper produced.
4. Calculate the moles of iron used in the reaction.
5. Determine the whole number ratio of moles of iron to the moles of copper from your data
in steps 3 and 4.
6. Based on your result from part 5, write a chemical equation for the reaction that took
place.
7. Use the balanced chemical equation to calculate the mass of copper that should have
been produced from the sample of iron used: theoretical yield.
8. Use this number and the mass of copper you actually obtained (actual yield) to calculate
the percentage yield.
9. What was the source of any deviation from the mole ratio calculated?
10. How could the yield have been improved?
Conclusions:
1. Using mole ratios, determine the expected yield of copper metal if all the CuSO4.5H2O
had been consumed.
2. Use this answer and that of #7 to explain what reagent was the limiting reagent.
3. Using the terms oxidation and reduction to explain at the particle level the process that
occurred in the reaction.
4. How could reactions which involve the spontaneous transfer of electrons be used in a
practical way?
5. An internal combustion engine relies primarily on the efficient production of energy by the
combination of oxygen (O2) and gasoline (assume this is primarily octane, C8H18). Write
the chemical equation for this reaction and derive the exact ratio of oxygen to octane for
100% efficiency.
6. Automobile air bags inflate on impact because a series of gas-producing chemical
reactions are triggered. To be effective in saving lives, the bags must not overinflate or
underinflate. What factors must automotive engineers take into account in the design of
air bags?
Hydrated Crystals
NGSSS:
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
SC.912.P.8.9 Apply the mole concept and the law of conservation of mass to calculate
quantities of chemicals participating in reactions.
Purpose of Lab/Activity:
To evaluate the relationship between mass and chemical change.
To derive the empirical formula of a hydrated salt using gravimetric analysis.
c. Ask students to explain, ―What is the phase of the water molecules being
lost‖?
d. What part of the process is chemical? What part is physical?
e. Help the students evaluate and minimize the sources of error as they are
conducting the experiment.
What the teacher will do:
a. Have students work in groups to answers the analysis questions.
b. Supervise the mathematical manipulations of data to ensure that students
understand the steps.
After
c. Help the students relate their observations to the calculated results.
activity:
d. As a whole class discussion format discuss all the analysis questions in the
student results.
e. Have students describe the energy changes taking place between the
atoms during the experiment.
Extension:
Gizmo: Stoichiometry
Hydrated Crystals
NGSSS:
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
SC.912.P.8.9 Apply the mole concept and the law of conservation of mass to calculate
quantities of chemicals participating in reactions.
Background:
Hydrates are crystalline compounds with water molecules incorporated in their structure. The
ratio of moles of water to one mole of the compound is a whole number which can be
determined experimentally by heating the hydrate to remove the water. For example, in the
hydrated compound copper (II) sulfate pentahydrate (CuSO 4·5H2O), the ratio is 5:1. There are 5
molecules of water for each formula unit of copper (II) sulfate. Once the water has been
removed from a hydrated compound, it has become anhydrous. The ions in the compound are
associated via ionic bonding. The atoms in water molecules are associated covalently. The ionic
compound and the covalent compound are associated by a coordinate covalent bond. The
overall structure can be viewed as an ionic compound. It can be thought that water is trapped
inside the ionic crystal lattice and heating the substance can provide the energy necessary to
liberate the water molecules.
The percentage error between the experimental and theoretical percentages of water in a
hydrate can be calculated using the following equation:
Safety:
Always wear safety goggles and a lab apron
Hot objects will not appear to be hot.
Procedure:
1. Allow hot plate to warm up on the high setting.
2. Measure to the nearest 0.01 g the mass of a clean, dry crucible and record.
3. Add provided hydrated MgSO4 to the crucible and measure the mass of the crucible plus
hydrate to the nearest 0.01 g. Record the mass.
4. Observe and describe the properties of the solid hydrate before heating
5. Place the crucible with hydrate on the hot plate and cover with the large beaker.
6. After a few minutes write down what you observe happening inside the large beaker, and
then carefully remove the large beaker while wearing a hot mitt or with beaker tongs.
7. Continue heating the crucible and contents for a total of about 10 minutes.
8. Use the crucible tongs to remove the crucible from the hot plate, allow it to cool, and
determine the mass of crucible plus the anhydrous contents. Record this mass.
9. Reheat the crucible and contents for about 5 minutes, cool, and mass it again.
10. If these last two masses do not agree within 0.02g, you should reheat the crucible and
contents a third time.
11. Dispose of the MgSO4 according to your teacher‘s directions, and then clean the beakers
and crucible.
Observations/Data:
Table 1
Observations
Solid Hydrated MgSO4
Large beaker during initial heating
Solid Anhydrous MgSO4
Table 2
Mass Data
Mass of crucible
Mass of crucible + MgSO4 hydrate
Mass MgSO4 hydrate
Mass of crucible + anhydrous
MgSO4
Mass anhydrous MgSO4
Mass of water in MgSO4 hydrate
Data Analysis/Results:
Percentage of Water
1. Calculate the percentage of water in the hydrated crystals of MgSO4 using your
experimental data.
2. Assuming that the correct formula for the hydrate is MgSO4 • 7H2O, calculate the
theoretical percentage of water in the hydrated crystals.
Hydrate Formula
1. Calculate the moles of anhydrous MgSO4.
2. Calculate the moles of water removed from the hydrate by heating.
3. Determine the ratio of moles of water to moles of anhydrous MgSO4.
4. Using this ratio, give the experimentally determined, predicted formula for hydrated
MgSO4.
Conclusions:
1. Compare your observations of the hydrated and anhydrous crystals.
2. The method used in this experiment is not suitable for determining the percentage of
water in all hydrates. Explain why this may be so.
3. What might you observe if the anhydrous crystals were left uncovered overnight?
4. If you were to repeat this experiment, what would you change in order to decrease your
% error?
5. What if the hydrate was added to water, would this be a physical or chemical change?
Explain and represent the change in an equation.
6. If energy was added (endothermic change) to remove the water from the salt, then what
would happen energetically if water was added to the anhydrous salt? Explain.
7. Packets of the anhydrous form of a hydrate are sometimes used to keep cellars from
being damp. Is there a limit to how long a packet could be used?
8. Gypsum (CaSO4·2H2O) is a mineral used for making wallboard for construction. The
mineral is stripped of three-quarters of its water of hydration in a process called
calcinning. Then, after mixing with water, it hardens to a white substance called plaster of
Paris. Infer what happens as calcinned gypsum becomes plaster of Paris.
9. How could the energetic processes involving a hydrate be used in a heat exchange
process?
Changes of State
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.10.5 Relate temperature to the average molecular kinetic energy.
Purpose of Lab/Activity:
Determine how the temperature changes as water changes state.
Understand the role of energy as an agent of change at the particle level.
Given a heating/ cooling curve for a substance, name each phase corresponding to the
curve.
Extension:
Gizmo: Phase Changes
Changes of State
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.10.5 Relate temperature to the average molecular kinetic energy.
Background: Matter can be found in three different states, solids, liquids, and gases. (There
are other states of matter that will not be addressed in this lab). In a solid, the particles are
attracted to each other strongly which makes them keep their shape and be rigid. In a liquid,
particles are attracted more loosely and this allows them to move pass one another and be fluid.
In a gas, the attraction between particles is very small and particles move around bouncing into
one another and into the walls of the container. Temperature is a measure of the kinetic energy
of the particles in a system. The higher the temperature, the more energy of motion the particles
have.
Purpose of Lab/Activity:
Determine how the temperature changes as water changes state.
Understand the role of energy as an agent of change at the particle level.
Given a heating/ cooling curve for a substance name each phase corresponding to the
curve.
Safety:
Always wear safety goggles and a lab apron.
Use hot mitts to handle hot plates.
Do not eat or drink anything in a laboratory.
Vocabulary: temperature, states of matter, kinetic energy, potential energy , melting (fusion),
freezing, evaporation, condensation, temperature change (ΔT), heating/cooling curve
Procedures:
1. Turn your hot plate to medium setting (or as recommended by your teacher) and allow a
few minutes for the plate to heat up.
2. Add ice (preferably crushed) to the 400ml beaker (half filled is enough).
3. Measure the initial temperature of the water in ºC and record in Table 1.
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4. Place the beaker on the hot plate and record the temperature every 30s. Carefully stir the
ice 5 seconds before taking temperature readings. Do not allow the thermometer to touch
the bottom of the beaker when recording the temperature.
5. When the water starts boiling, continue recording the temperature every 30 seconds for
an additional three minutes. Extend Table 1 as needed to record your data.
Observations/Data Analysis: As you perform the experiment, make your observations and
analyze your data completing the ―Student Lab Guide‖.
Conclusion: Summarize the scientific principles that you discovered in this lab using the
following terms:
temperature
states of matter
kinetic energy
potential energy
melting (fusion)
freezing
evaporation
condensation
temperature change (ΔT)
heating/cooling curve
1. In the following graph sketch your prediction of what will happen to the temperature of the
system as you start heating it. Include any relevant temperatures.
4. Start heating the beaker. As you heat the beaker while stirring constantly, what is
happening to the temperature of the system?
5. What phase(s) are present in the beaker?
6. Using the boxes below, draw at the particle level the changes occurring as the ice melts
7. What happens to the kinetic energy of the system as the ice is melting? Why?
8. When all the ice has melted, what happens to the temperature of the system? What
phase (s) is (are) present in the beaker?
9. Using the boxes below, draw at the particle level the changes occurring as the water
heats up
10. What happens to the kinetic energy of the system as the water is heating? Why?
11. When the water starts boiling, what happens to the temperature of the system? What
phase (s) is (are) present in the beaker?
12. Using the boxes below, draw at the particle level the changes occurring as the water boils
13. What happens to the kinetic energy of the system as the water is boiling? Why?
14. After 4 minutes of boiling, sketch the graph that you obtained as you collected data.
15. How is the curve you obtained different from your prediction?
16. On the graph above, divide your heating curve into three sections. For each section, of
the graph, state what phases were present in:
a. a low temperature plateau?
b. an area of temperature change?
c. a high temperature plateau?
Conclusion: Summarize the scientific principles that you discovered in this lab using the
following terms:
temperature
states of matter
kinetic energy
potential energy
melting (fusion)
freezing
evaporation
condensation
temperature change (ΔT)
heating/cooling curve
NGSSS:
SC.912.L.18.12 Discuss the special properties of water that contribute to Earth's suitability as
an environment for life: cohesive behavior, ability to moderate temperature, expansion upon
freezing, and versatility as a solvent.
SC.912.P.8.5 Relate properties of atoms and their position in the periodic table to the
arrangement of their electrons.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
Purpose of Lab/Activity:
Identify the types of bonding (ionic, covalent, metallic) by investigating conductivity and
solubility of substances.
Visualize how atoms, ions and molecules interact with each other at the particle level to
account for the behavior at the macro level.
Prerequisite:
Students should have a basic model of atomic structure which includes the electrical
nature of atoms. The existence of a negative mobile particle, the electron, and a positive
stationary particle, the proton, is necessary for this activity. When the amount of protons
and electrons is equal, the atom is neutral.
Students should be able to visualize that there is a force of attraction between unlike
charges and repulsion between like charges.
Students know that electricity is the flow of the mobile negative particles through a
medium which will allow this flow.
Students should have a view of the dissolving process such as water being able separate
the molecules of a solid by overcoming the attractions the molecules feel towards each
other
Materials:
small beakers or cups (100 ml or less)
distilled water (~100 ml)
wash bottle filled with distilled water
stirring rod
1 cm2 of Aluminum foil
a penny
rubbing alcohol (isopropyl alcohol - 10ml)
Approximately 1 g of the following:
o sucrose (table sugar)
o NaCl (table salt)
o SiO2 (sand)
o Candle wax
o CaCl2 (calcium chloride)
o CuSO4 (copper II sulfate)
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http://www.sciencenter.org/chemistry/d/carryingcharges.pdf
o tape
o 9-V battery
o battery clip
o bare wire leads
o resistor
o LED or buzzer
o wood backing.(tongue depressor)
Note: Teacher may opt to use commercially available conductivity testers. Materials for
construction of student-made apparatus can be obtained at local hobby/electrical supply
stores.
c. Pose the question to students if they think that electricity can flow through a
liquid. Most of them are aware that it is dangerous to be in water when
electrical equipment is around. However, pure water is actually a poor
conductor. Tap water on the other hand is a better conductor due to the
presence of dissolved solids.
d. Tell students that they will be testing solubility and conductivity of different
materials and writing down their observations.
e. Give each group a set of materials, a conductivity tester and tell them to
test for solubility and conductivity. The solids should be tested for
conductivity before and after dissolving them.
f. Review the data table students are to complete and answer any questions
students may have on the procedure
What the teacher will do:
a. Supervise students as they perform their investigation. As you visit
separate groups, engage their thinking with some of the following
questions: (Resist giving them the answer until the whole class discussion
During at the end of the lab)
activity: 1. why they think that some solids dissolve and some do not.
2. why some substances conduct electricity once they dissolve but not
when solid
3. why some substances do not conduct as a solid or in solution
b. Make sure students collect data and fill out their data table correctly
What the teacher will do:
a. Once students have collected all their data, bring the class together for
class discussion
b. Address the fact that substances that are not soluble in water have particles
which are attracting to each other so strongly that water cannot break them
apart. In this experiment, the only substances that will do this are the two
metals (Al and Cu), the sand and the wax.
c. Distinguish the wax and sand from the metals with the conductivity test.
The wax and sand do not conduct while the metals do. Conclude that
metals are insoluble (strong bonds) and conduct electricity. They are also
shiny and good conductors of heat. These are the characteristics of
metallic bonding. Because metals can conduct it implies that the atoms
After allow electrons to flow through them easily. Explain to the class that metals
activity: tend to have high melting and boiling points thanks to the strength of the
metallic bonds.
d. Sugar, salt, copper sulfate, and calcium chloride all dissolved which means
that water is able to break their structure apart. After testing the
conductivity, sugar does not conduct while the three other do. In the
conductivity tester there are electrons on one lead trying to flow to the other
lead (forced by the difference in potential in the battery). Copper sulfate,
calcium chloride and sodium chloride are able to ―ferry‖ the electrons from
one lead to the other. This happens because these solids break up into
oppositely charged particles or ions. These substances are considered
ionic. In the solid state these substances do not conduct because the ions
are locked in place in the crystal lattice. In solution, the ions can flow freely
and take electrons back and forth. Sugar is not able to conduct electricity
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Extension:
Gizmo: Solubility and Temperature
NGSSS:
SC.912.L.18.12 Discuss the special properties of water that contribute to Earth's suitability as
an environment for life: cohesive behavior, ability to moderate temperature, expansion upon
freezing, and versatility as a solvent.
SC.912.P.8.5 Relate properties of atoms and their position in the periodic table to the
arrangement of their electrons.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
Background: Recall that solids are able to keep their shape due to the force of attraction
between the particles that compose it. This attraction comes from the internal structure of the
atom which includes positive protons and negative electrons. Opposite charges attract and like
charges repel. Electricity occurs when electrons are able to flow through a substance. Materials
which allow electrons to flow are called conductors and those that do not insulators. If a solid
can dissolve in water it is said to be soluble and this occurs because the solvent (water in this
case) can separate the particles of the solid.
Purpose:
To classify substances based on their properties of solubility and conductivity.
To develop a particle level model to account for the differences in properties of solubility
and conductivity.
Safety:
Always wear safety goggles.
Use conductivity tester only for described activities.
Procedure:
1. Conductivity- Use conductivity apparatus to test the conductivity of all substances
before making any solutions. Be sure to keep the wire test probes apart. Record your
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results in the second column of Table 1. Rinse and dry the paper clip probes with distilled
water between each test.
2. Solubility- Take ~1 g of each solid substance, place it in the small beaker or cup and try
to dissolve it with ~10 ml of distilled water. Record your results in the third column of
Table 1.
3. Conducts when dissolved- If the substance dissolves in water, test the solution with the
conductivity apparatus. Make sure to keep the probes apart. Enter your results in the final
column of Table 1. If a substance did not dissolve enter NO in this column.
Observations/Data:
Table 1: Test Results
Original
Substance Solution
substance
Substances dissolves? conducts?
conducts?
Yes/No Yes/No
Yes/No
Al (s) - Aluminum foil
C12H22O11(s)
Sucrose (sugar)
C20H42 (s) candle (wax)
Cu (s) -- Copper
Data Analysis/Results:
1. Group the substances that have the same characteristics. Which groups did you form?
2. From each group that you assembled, look at the similarities and differences between
atoms that make up the substances. Describe the similarities and differences that you
detected.
Conclusion:
1. Explain at the particle level why some substances dissolve in water while others do not.
2. Some substances dissolved and conducted electricity while others dissolved but did not
conduct electricity. What are solutions that conduct electricity called?
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3. Explain at the particle level how some solutions can conduct electricity while others
cannot.
4. Based on the 3 types of bonding discussed (metallic, ionic, covalent) assign the
appropriate one to each substance tested.
5. Using a 3 column chart, compare and contrast ionic, covalent and metallic bonding.
6. What is a covalent network? What substance in this experiment is considered a covalent
network? Name at least another substance that exhibits this type of arrangement.
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.10.5 Relate temperature to the average molecular kinetic energy.
SC.912.P.12.11 Describe phase transitions in terms of kinetic molecular theory.
Purpose of Lab/Activity:
To study the effect of temperature on solubility
To understand the process of solubility and saturation at the particle level
To experimentally construct a solubility curve
To use a solubility curve to find the solubility of a solute at different temperatures
Prerequisite: Students should have clear model on how the solution process works. Most
important is for them to realize that solids dissolve and disappear from view as the particles of
the solid are separated by the solvent. Students should also know that temperature is a
measure of the kinetic energy of the particles in a system. Basic laboratory safety and
techniques are expected due to the nature of this experiment.
b. The most difficult part of this lab is to keep the temperature of the water
bath constant. Assist students with this task and make sure that they are
reading the thermometers correctly.
c. Visit each group individually and ask them questions about what steps they
are completing and why.
d. Point out to students that given the initial amount of KCl added (about 10
grams) they should not expect all the salt to ever dissolve. Ask them if they
expect the amount of solute dissolved in the solvent to be constant at
different temperatures and why.
e. Set up a space in the room for groups to post their results. The quality of
the graph will depend on the individual group results so great care must be
taken if good results are desired.
What the teacher will do:
a. Students should gather data from the whole class and construct their
solubility curve
b. After all groups build their graph, bring them together for a whole class
discussion and analysis of results
c. The class discussion should have two main goals: First, to help students
develop a particle level model of solubility and how temperature affects it.
Second, for students to know how to read their chart and answer questions
such as the ones in the conclusion section of the student procedure.
d. Have students explain orally how water dissolves KCl. They should say that
in the solid state, the ions of potassium and chlorine are attracting each
other in a crystal lattice structure. All the ions together amount to a visible
quantity of salt. When water is added the water molecules surround the
ions and separate them from the lattice. Now the ions are in the aqueous
state and invisible.
e. Once this is established, ask why temperature affects this process. Lead
students to see that at higher temperatures the water molecules have more
After energy and are moving faster. At the same time, the potassium chloride
activity: lattice has more energy as well. The extra energy makes is easier for the
water molecules to separate the potassium and chloride ions. Therefore,
fewer water molecules are needed to separate the particles and the amount
of solute dissolved increases.
f. Turn now to the analysis of the solubility curve that the students produced.
Ask students what the solubility line represents. This is the combination of
temperature and amount of solute at saturation. Below the line the solution
is unsaturated. Above the line the solution is saturated and there are visible
undissolved solids. One of the conclusion questions addresses
extrapolation of the curve by asking students for solubility at temperatures
outside of the range of data collected. Students may have difficulty
understanding how the units in the vertical axis in the chart. The units are
grams of solute (KCl) per 100 grams of solvent (water). A question in the
student section addresses this understanding by checking on other
amounts of solvent. Another question in the conclusion section addresses
calculating how much solute precipitates if a solution is cooled down. Feel
free to add more questions such as this which enforce graphical analysis.
g. Two extension questions are given at the end for students to apply their
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understanding of the situation to real life applications. One deals with the
solubility of gases - carbon dioxide in soda. The question begins by telling
students that the opposite trend is observed when dealing with the solubility
of gases. Explain to students that gases would rather escape the liquid and
they are lightly attracted to the solvent particles. Increasing the temperature
will help the particles escape the attraction and leave the liquid phase.
Extension:
Gizmo: Solubility and Temperature
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.10.5 Relate temperature to the average molecular kinetic energy.
SC.912.P.12.11 Describe phase transitions in terms of kinetic molecular theory.
Purpose of Lab/Activity:
To determine the solubility of a solute, potassium chloride (KCl), in water as the
temperature of the solution is changed.
Safety:
Always wear safety goggles and a lab apron.
Never taste any substance used in the lab.
Test tube and evaporating dish may be cause burns
Use caution around hot items.
Procedures:
1. Your teacher will assign your group a temperature between 20ºC and 90ºC.
2. Determine the mass of a clean, dry evaporating dish (or 100 ml beaker) with watch glass
cover. Set aside.
3. Fill the large 250 or 400 ml beaker with water ½ way and place on hot plate to heat.
4. Put 15 ml of distilled water in the test tube and add about 10 g of KCl. Immerse the test
tube in the large (250 ml) beaker.
5. Place the thermometer in the large beaker and heat the water until it reaches your
assigned temperature. Maintain this temperature for 10 minutes, stirring every few
minutes and rechecking the temperature.
6. Set up a funnel for filtering the solution, using a small wad of cotton instead of filter paper,
placing the previously weighed evaporating dish (or 100 ml beaker) below the funnel.
7. Remove the test tube from the water bath, being careful that any solid at the bottom of
the test tube is undisturbed. Decant about half of the solution into the funnel.
8. Weigh the evaporating dish, watch glass, cover and contents when filtering is complete.
9. Evaporate the water from the solution by heating rapidly at first and then more slowly.
Start the evaporation without the watch glass and then cover the evaporating dish with
the watch glass to prevent loss of KCl by spattering.
10. After the evaporating dish has cooled, measure the mass again. Reheat until the mass
changes by less than 0.02 g.
11. Cleanup and Disposal:
a. Turn off the hot plate and allow it to cool.
b. Make sure all glassware is cool before emptying the contents.
c. Dissolve all the KCl with plenty of water and flush down the drain
d. Return all lab equipment to its proper place.
e. Clean up your work area.
Observations/Data:
1. Record your data calculation answers in Table 1.
2. Record class data in Table 2
3. Make a line graph of the solubility of KCl in grams KCl/100 g water (Y-axis) versus the
temperature in ºC (X-axis).
Conclusion:
1. Describe your findings on the effect of temperature on the solubility of KCl.
2. Explain, at the particle level, why changes in temperature affect solubility?
3. Using the plot you made, predict the solubility of KCl in water at 15°C and 95°C
4. A saturated solution of potassium chloride in 50 g of water at 70°C is cooled to 30°C.
How much solute will precipitate out of the solution?
5. If you wish to fully dissolve 500 grams of KCl in a liter of water, at what temperature
should the solution be?
6. In a dishwasher, the temperature of the water is very hot. Explain why it is better to use
hot water in a dishwasher rather than cold water.
7. Unlike solids for which solubility in a liquid generally increases with increasing
temperature, the solubility of a gas in a liquid usually decreases as the temperature
increases. Knowing this, explain why you should never heat a can containing a
carbonated soft drink.
NGSSS:
SC.912.P.8.8 Characterize types of chemical reactions, for example: redox, acid-base,
synthesis, and single and double replacement reactions.
SC.912.P.8.11 Relate acidity and basicity to hydronium and hydroxyl ion concentration and pH.
Purpose of Lab/Activity
Determine the end point of an acid-base titration
Calculate the molarity of acetic acid in vinegar
Calculate the percentage of acetic acid in vinegar.
Extension:
Gizmo: pH Analysis, pH Analysis: Quad Color Indicator
NGSSS:
SC.912.P.8.8 Characterize types of chemical reactions, for example: redox, acid-base,
synthesis, and single and double replacement reactions.
SC.912.P.8.11 Relate acidity and basicity to hydronium and hydroxyl ion concentration and pH.
Background Information:
Vinegar, which is naturally produced from the fermentation of apple cider in the absence of
oxygen, contains acetic acid (CH3COOH) at a concentration 4.0 to 5.5 %. The exact
concentration of acetic acid can be determined by titration with a standard base such as sodium
hydroxide. This can be done on a microscale as described below by counting drops of base
needed to neutralize the acid in vinegar, or on a larger scale with a standard 50 ml buret setup.
Purpose of Lab/Activity
Determine the end point of an acid-base titration
Calculate the molarity of acetic acid in vinegar
Calculate the percentage of acetic acid in vinegar.
Safety Precautions:
Wear safety goggles and a lab apron.
Do not touch chemicals
Vocabulary: titration, concentration, molarity, mol per liter, solution, solvent, solute, acid, base,
pH scale, hydronium and hydroxide ions.
Procedures:
Calibrate pipet droppers:
1. Put about 5 ml of water in the 10 ml graduated cylinder and read the exact volume.
Record this reading in Data Table 1- Calibration Data.
2. Fill the pipet with water. Holding the pipet in a vertical position, transfer exactly 20 drops
of water to the graduated cylinder. Record the new volume in the graduated cylinder as
the final volume for trial 1.
3. The final volume for trial 1 will then be the Initial volume for trial 2 as 20 more drops are
added to the graduated cylinder.
4. Record the new final volume and repeat for a third trial.
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Titration:
1. Drain the water from the Acid pipet, rinse the Acid pipet with vinegar, and discard this
vinegar. Then fill the pipet with fresh vinegar.
2. Hold the pipet vertically and add 20 drops of vinegar and 1 drop of phenolphthalein to 3
wells of the well plate or to the 3 small beakers.
3. Drain the water from the Base pipet, rinse the Base pipet with NaOH solution, and
discard this rinse solution. Then fill the pipet with fresh NaOH solution.
4. Hold the Base pipet vertically and add NaOH solution drop by drop to one well or beaker
with gentle swirling after each drop is added. Continue adding drops of NaOH solution
until the pink phenolphthalein color remains for 30 s. Record the number of drops of
NaOH added in the Titration Data Table.
5. Repeat step 4 with the 2 other 20-drop vinegar samples refilling the NaOH pipet if
necessary. Record the observed number of drops in the Data Table 2- Titration.
6. Cleanup: Clean all equipment used and dispose of the chemicals as directed by your
teacher. Wash your hands.
Data Analysis/Results:
1. Calculate the volumes of vinegar and NaOH for each trial and record in Data Table 2-
Titration. Show your calculations.
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2. From the molarity of the standardized NaOH solution (provided by your teacher) calculate
the number of moles of NaOH used to neutralize the acetic acid in each trial. Show work.
3. Write the balanced equation for the neutralization of acetic acid by sodium hydroxide.
4. From the calculations in steps 2 and 3, and the mole ratio from the balanced equation of
#3 above, calculate the number of moles of acetic acid neutralized by NaOH each trial.
Show work.
5. From the moles of acetic calculated in #4 and the volumes of vinegar used in each trial,
calculate the molarities of acetic acid in each trial, then average your results.
6. Calculate the molar mass of acetic acid, CH3COOH.
7. Using your average molarity of acetic acid in vinegar (#5), calculate the mass of acetic
acid in 100 ml (0.100 L) of vinegar. Hint: Find the mass of acetic acid in 1L and then the
mass in 100 ml.
8. Assume that the density of vinegar is close to 1.00 g/ml, so that the mass of 100 ml of
vinegar will be 100.g. Determine the percentage of acetic acid in your sample of vinegar.
Conclusion:
1. Why was phenolphthalein used in each titration? Could you have done your titrations
without phenolphthalein?
2. How could the end point have been determined more accurately?
3. Why does the titrated mixture have to be stirred vigorously to ensure greater accuracy?
4. Why were you instructed to hold the pipets in a vertical position when you used them?
5. What if the pipet was not rinsed with the standard, NaOH before it was used to titrate the
acid solution, what effect would it have had on the % by volume?
6. How does a company producing vinegar solution ensure that the concentration is
accurate enough?
7. How does fermentation of apple cider result in the production of an acid?
8. Describe some other fermentation processes that are useful biochemically?
NGSSS:
SC.912.P.10.1 Differentiate among the various forms of energy and recognize that they can be
transformed from one form to others.
SC.912.P.10.2 Explore the Law of Conservation of Energy by differentiating among open,
closed, and isolated systems and explain that the total energy in an isolated system is a
conserved quantity.
SC.912.P.10.7 Distinguish between endothermic and exothermic chemical processes.
Purpose of Lab/Activity:
Determine the energy content of foods and fuels and compare to standard values.
Understand how energy is produced from chemical reactions that take place all around
us.
To evaluate the efficacy of experimental set ups for energy measurements
they eat.
b. Ask the class how the energy is stored in food. They should conclude that
energy is stored as chemical potential in the molecules of food. Bring to
their attention that a chemical reaction needs to occur for that energy to
become useful in our bodies. Remind them that a chemical reaction means
a rearranging of the atoms of reactants to form products.
c. Ask students what the food we eat react with in our bodies? The idea is for
them to realize that the oxygen we breathe is also use in this process of
respiration. If the food reacts with oxygen in our bodies, it can also react
with oxygen outside. Demonstrate how food can catch on fire and release
energy.
d. Have students briefly distinguish the caloric differences between various
food groups.
e. Familiarize the students with the proper use of the technology used for this
lab and with the overall procedure.
What the teacher will do:
a. Monitor the proper use of the technology
b. Supervise the construction of the food holder and the set up used.
During
c. Ask the students to discuss the change in potential energy and kinetic
activity:
energy and how they are related to each other.
d. Ask students if they feel that all the energy of the reaction is going into
heating the water or if some is going somewhere else.
What the teacher will do:
a. Summarize the differences between the fuel values of the various chemical
groups.
b. Make sure the students have manipulated their calculations correctly.
c. Help the students interpret their data properly
d. Students should compare the values obtained from their experiment with
After the values in the food labels. They should be greatly smaller. This is
activity: because of the low quality of the experimental setup which allows for a high
percentage of the energy to be dissipated. Discuss with them how the
results are going to be tied to how much energy is received by the water in
the can. Ask students to come up with ideas on how this problem can be
eliminated. If no good ideas come up, explain to them the concept of a
bomb calorimeter which submerges the reaction in water so that all the
energy released goes into the water as opposed to the air around it.
Extension:
Gizmo: Calorimetry Lab
NGSSS:
SC.912.P.10.1 Differentiate among the various forms of energy and recognize that they can be
transformed from one form to others.
SC.912.P.10.2 Explore the Law of Conservation of Energy by differentiating among open,
closed, and isolated systems and explain that the total energy in an isolated system is a
conserved quantity.
SC.912.P.10.7 Distinguish between endothermic and exothermic chemical processes.
Background: All human activity requires ―burning‖ food and fuel for energy. The energy is
originally stored in the food as chemical potential energy. This energy is released when atoms
rearrange in chemical reactions. In this experiment, you will determine the energy released (in
kJ/g) as various foods and fuels burn such as cashews, marshmallows, peanuts, popcorn,
paraffin wax, and ethanol. You will look for patterns in the amounts of energy released during
burning of the different foods and fuels.
Purpose of Lab/Activity:
Determine the energy content of foods and fuels and compare to standard values.
Understand how energy is produced from chemical reactions that take place all around
us.
Safety:
Always wear safety goggles and a lab apron.
Do not eat or drink anything in a laboratory.
Tie back hair and secure loose bulky clothing while working near a flame.
Note: If anyone is allergic to nuts, you can substitute with potato chips or other snack
food
11. If using a thermometer, record a temperature every 15 seconds. At first, the temperature
will increase until it reaches a maximum and then it will decrease. The most important
data points are the initial (T1) and highest temperature (T2)
12. Continue stirring the water until the temperature stops rising. Record this maximum
temperature, T2. Data collection will stop after 10 minutes (or press the STO key to stop
before 10 minutes has elapsed).
13. Determine and record the final mass of the food sample and food holder.
14. To confirm the initial (T1) and final (T2) values you recorded earlier, examine the data
points along the curve on the displayed graph. As you move the cursor right or left, the
time (X) and temperature (Y) values of each data point are displayed below the graph.
15. Press ENTER to return to the main screen. Select START to repeat the data collection for
the second food sample. Use a new 50-ml portion of cold water. Repeat Steps 7-14.
16. When you are done, place burned food, used matches, and partially-burned wooden
splints in the container provided by the teacher.
Figure 1
Observations/Data:
1. Find the mass of water heated for each sample and record in Data Table 1.
2. Find the change in temperature of the water, ∆T, for each sample and record in Data
Table 1.
Data Analysis/Results:
1. Calculate the heat absorbed by the water, q, using the equation q = Cp•m•∆t where q is
heat, Cp is the specific heat capacity, m is the mass of water, and ∆T is the change in
temperature. For water, Cp is 4.18 J/g °C. Change your final answer to kJ.
2. Find the mass (in g) of each food sample burned.
3. Use the results of Steps 3 and 4 to calculate the energy content (in kJ/g) of each food
sample.
4. Record your results and the results of other groups in Data Table 2.
Conclusion:
1. Which food had the highest energy content? The lowest energy content?
2. Food energy is often expressed in a unit called a Calorie. There are 4.18 kJ in one
Calorie. Based on the class average for peanuts, calculate the number of Calories in a
50-g package of peanuts.
3. Using the food label determine the caloric content of each food and compare with your
results. Explain what factors in the experimental design account for this difference.
4. Two of the foods in the experiment have a high fat content (peanuts and cashews) and
two have high carbohydrate content (marshmallows and popcorn). From your results,
what generalization can you make about the relative energy content of fats and
carbohydrates?
can. Remember: The Temperature Probe must be in the water for at least 30 seconds
before you do Step 11.
Figure 2
11. Select START on the calculator to begin collecting data. Monitor temperature (in °C) on
the calculator screen for about 30 seconds and record the initial temperature of the water,
t1, in your data table. Light the candle and heat the water until its temperature reaches
40°C and then extinguish the flame. CAUTION: Keep hair and clothing away from an
open flame.
12. If using a thermometer, record a temperature every 15 seconds. At first, the temperature
will increase until it reaches a maximum and then it will decrease. The most important
data points are the initial (T1) and highest temperature (T2)
13. Continue stirring the water until the temperature stops rising. Record this maximum
temperature, T2. Data collection will stop after 10 minutes (or press the STO key to stop
before 10 minutes has elapsed).
14. Determine and record in Table 1 Part 1, the final mass of the cooled candle and foil,
including all drippings.
15. To confirm the initial (T1) and final (T2) values you recorded earlier, examine the data
points along the curve on the displayed graph. As you move the cursor right or left, the
time (X) and temperature (Y) values of each data point are displayed below the graph.
16. Press ENTER to return to the main screen. Select START to repeat the data collection
using ethanol in an alcohol burner. Repeat Steps 8-15. Be sure to use 200 ml of chilled
water in Step 9.
Observations/Data:
1. Find the mass of water heated.
2. Find the change in temperature of the water, ΔT.
Data Analysis/Results:
1. Calculate the heat absorbed by the water, q, using the formula in the introduction of this
experiment. For water, Cp is 4.18 J/g°C. Change your final answer to kJ.
2. Calculate the heat absorbed by the water, q, using the equation q = Cp•m•ΔT, where q is
heat, Cp is the specific heat capacity, m is the mass of water, and Δt is the change in
temperature. For water, Cp is 4.18 J/g°C. Change your final answer to kJ.
3. Find the mass of paraffin burned.
4. Calculate the heat of combustion for paraffin in kJ/g. Use your Step 3 and Step 4
answers.
5. Calculate the % efficiency in both trials of the experiment. Divide your experimental value
(in kJ/g) by the accepted value, and multiply the answer by 100. The accepted heat of
combustion of paraffin is 41.5 kJ/g, and for ethanol the value is 30.0 kJ/g. Record in Data
Table 2.
% efficiency %
Conclusion:
1. Based on your results, which fuel produces more energy per gram burned? Give an
explanation for the difference. (Hint: Ethanol, C2H5OH, is an oxygenated molecule;
paraffin, C25H52, does not contain oxygen.)
2. Suggest some advantages of using ethanol (or paraffin) as a fuel.
3. Discuss heat loss factors that contribute to the inefficiency of the experiment.
Chemistry HSL Page 116
Curriculum and Instruction
Student
Rates of Evaporation
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.10.5 Relate temperature to the average molecular kinetic energy.
Purpose of Lab/Activity:
Measure and compare the rates of evaporation for different liquids.
Classify liquids based on their rates of evaporation.
if you used heavier balls such as baseballs, which balls would require
more energy to evaporate or escape from the surface. (Note: make sure
students do not isolate these factors as attractive forces and molecular
weight occurs simultaneously).
f. Have students predict which factors could affect the evaporation rate of
different substances.
g. Make sure students understand that the rate of evaporation of a substance
is always compared to the rate of vaporization of a specific known material
and hence it is stated as a ratio. For this reason, there are no units for rate
of evaporation. You may wish to tell them that the general reference
material for evaporation rates is n-butyl acetate (commonly abbreviated
BuAc) which has a relative evaporation rate of 1.0.
h. Explain to the students that during this lab, the rate of evaporation will be
defined as the time in seconds for the drop to evaporate assuming that the
volume of the drop is comparable in each case.
What the teacher will do:
a. Review with students the basic lab procedures and data collection that
should take place during the experiment. They should discuss how they
During will identify when the liquid has completely evaporated and how to
activity: standardize this observation.
b. Make sure that students draw the shape of the drop. Try to get them to
express the direction of the attractions using arrows. Also if possible urge
them to use the terms cohesion and adhesion.
What the teacher will do:
a. Review with students their results. Refer back to the Changes of State lab
to discuss energy changes that took place as the substance evaporated.
They should explain that thermal energy must be sufficient to overcome
After the surface tension or the cohesion of the liquid in order to evaporate.
activity: b. For advanced students provide the boiling and melting points of the
substances tested. Have students identify the pattern and compare these
trends with evaporation rate.
c. You may want to copy the diagrams from the following pages to review
with students the differences between intra and intermolecular forces.
Extension:
Gizmo: Phase Changes
Intermolecular
Rates of Evaporation
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.10.5 Relate temperature to the average molecular kinetic energy.
Background:
A puddle of water formed after it rains, will evaporate after some time. The process of
evaporation describes how liquids change to gases as the molecular kinetic energy is increased
allowing some of the molecules to separate from the liquid. Several factors determine how fast a
sample of liquid evaporates. The volume of the sample is a key factor. A drop of water takes
less time to evaporate than a liter of water. The amount of energy supplied to the sample is
another factor.
In order to understand the process of evaporation you need to be familiar with properties of
liquids such as viscosity, surface tension, and polarity. The ability of a substance to resist
flowing is called viscosity. Highly viscous liquids have strong intermolecular forces that hold the
liquid from flowing freely. Surface tension refers to the force on the molecules at the surface of
the liquid. Substances with high surface tension have stronger forces of attraction between
molecules. Polarity is a property that refers to a molecule with one end slightly positive and the
other slightly negative. The attraction of polar molecules to other polar molecules occurs through
dipole-dipole forces. The attraction of nonpolar molecules to other nonpolar molecules occurs
through London dispersion forces.
Purpose of Lab/Activity:
Measure and compare the rates of evaporation for different liquids.
Classify liquids based on their rates of evaporation.
Predict which intermolecular forces exist between the particles of each liquid.
Safety:
Always wear safety goggles and a lab apron.
Wear gloves because some of the liquids can dry out your skin.
Avoid inhaling any of the vapors, especially ammonia.
There should be no open flames in the lab; some of the liquids are flammable.
Vocabulary:
Intermolecular forces of attraction, viscosity, evaporation, surface tension, polarity, volatile
substances, cohesive and adhesive
household
ammonia
droppers (5)
small plastic cups (5)
grease pencil or marking pen
masking tape
paper towel
square of waxed paper
stopwatch
Procedures:
1. Use a grease pencil or masking tape to label each of five small plastic cups. Use A for
distilled water, B for ethanol, C for isopropyl alcohol, D for acetone, and E for household
ammonia.
2. Place the plastic cups on a paper towel.
3. Use a dropper to collect about 1 ml of distilled water and add to cup labeled A.
4. Place the dropper on the paper towel directly in front of the cup. Repeat with the other
liquids.
5. Place a square of waxed paper on your lab surface.
6. Plan where on the waxed paper you will place each of the 5 drops that you will test. The
drops must be as far apart as possible to avoid mixing.
7. Have your stopwatch ready. Collect some water in your water dropper and place a single
drop on the waxed paper. Begin timing. Time how long it takes for the drop to completely
evaporate. While you wait, calculate the molecular weight for each substance and record
your answer in Table 1 along with the time for the liquid to evaporate. Also while you are
waiting make two drawings of each drop, the first should show the shape of the drop as
viewed from above and the second should be a side view at eye level. If possible use
arrows to show attraction of molecules to each other or to the paper and try to label with
the terms: ―cohesion and adhesion‖.
8. Note: If drops take longer than 5 min to evaporate, record 300 s in your data table.
9. Repeat step 5 with the four other liquids.
10. Use the above procedure to design an experiment in which you can observe the effect of
temperature on the rate of evaporation of ethanol. Your teacher will provide a sample of
warm ethanol. Record your observations.
Observations/Data:
Data Table 1- Evaporation Rate
Liquid Formula Molecular Weight Evaporation time (s)
Distilled water H2O
Ethanol C2H5OH
Isopropyl alcohol (2-
C3H8O
propanol)
Acetone (CH3)2CO
Household ammonia NH3
Distilled water
Ethanol
Acetone
Household ammonia
Data Analysis/Results:
1. Which liquids evaporated quickly? Rate them in order of speed of evaporation.
2. Based on your data, in which liquid(s) are the attractive forces between molecules most
likely to be solely dispersion forces?
3. Make a generalization about the molecular weight and the evaporation rate of the liquid.
4. What is the relationship between surface tension and the shape of a liquid drop? What
are the attractive forces that increase surface tension?
5. Which liquid is more efficient (water ethanol, alcohol, acetone, or ammonia) at cooling
down an object as a result of evaporation? Is there a relationship between the rate of
evaporation and the cooling effect that a liquid exhibits? Explain.
6. The isopropyl alcohol you used is a mixture of isopropyl alcohol and water. Would pure
isopropyl alcohol evaporate more quickly or more slowly compared to the alcohol and
water mixture? Give a reason for your answer.
7. Household ammonia is a mixture of ammonia and water. Based on the data you
collected, is there more ammonia or more water in the mixture? Use what you learned
about the relative strengths of the attractive forces in ammonia and water to support your
conclusion.
Conclusion:
1. Should rate of evaporation be directly or inversely related to the strength of
intermolecular attraction? Give clear reasons for your choice.
2. Make a generalization about the shape of a liquid drop and the evaporation rate of the
liquid.
3. The vapor phases of liquids such as acetone and alcohol are more flammable than their
liquid phases. For flammable liquids, what is the relationship between evaporation rate
and the likelihood that the liquid will burn?
4. Suggest why a person who has a higher than normal temperature might be given a
rubdown with rubbing alcohol (70% isopropyl alcohol).
5. Table salt can be collected from salt water by evaporation. The water is placed in large,
shallow containers. What advantage do these shallow containers have over deep
containers with the same overall volumes?
6. Is there a relationship between the boiling point of these liquids and their rate of
evaporation?
7. How does the rate of evaporation of warm ethanol compare to ethanol at room
temperature? Use kinetic-molecular theory to explain your observations.
Purpose of Lab/Activity:
To determine the factors that affect the rate of a chemical reaction {e.g., temperature, pH,
concentration (pressure), and catalyst.}
To determine the percentage yield and limiting reagent in chemical process.
To evaluate Le Chatelier‘s principle. (for advanced students)
To quantify the enthalpy change of a process (for advanced students)
Observations/Data Analysis :
1. Active Ingredients from package of ―original formula‖ fast relief Antacid and pain
medicine-Alka-Seltzer:
325 mg of Aspirin, Acetylsalicylic acid, or 2-acetoxybenzoic acid (C9H8O4)
1000 mg of Citric acid (H3C6H5O7)
1916 mg of sodium bicarbonate (NaHCO3)
Chemistry HSL Page 126
Curriculum and Instruction
Teacher
To simplify calculations use mmols (the ratio in g/mol is equivalent to mg/mmols, make
sure that students understand that all you are doing is working in a smaller unit which will
keep the numbers larger and easier to manipulate) see example below:
Net Ionic Equation: - -
If you do not want to use milimoles the alternative calculation in moles is as follows:
Then, the total theoretical yield would be 0.07939 g CO2 + 0.06872g CO2 = 0.7666 g
To find the percentage yield use the data generated in the experiment. (A typical percent
yield could be approximately 83.0%). Note: this value could be affected by binders,
sugar, food coloring (not applicable here} and human error (most likely).
Extension:
Gizmo: Limiting Reactants, Collision Theory
Background: Students must be very familiar with the kinetic molecular theory and how it relates
to the collision theory. The idea of concentration, pressure, temperature, kinetic energy must be
discussed. The role of catalysts and their properties must be reviewed and perhaps related to
the biological role of enzymes. The rate of a chemical reaction depends on the frequency of the
collisions between the atoms or ions of the reactants. The concentration or pressure has an
effect on the frequency of the collisions of the particles. The manipulation of concentration,
temperature and/or pressure/volume can also affect direction of a reaction. Temperature will
―drive‖ the extent of a reaction in either direction.
Purpose of Lab/Activity:
To examine the factors that affect the rates of reactions.
Extended: To quantify the energy change of the process.
Extended: To determine the percentage yield of the chemical process.
Extended to examine Le Chatelier‘s principle as it relates to the yield in a chemical
process
Safety:
Safety goggles,
Aprons.
No eating or drinking
Vocabulary: reaction rates, reaction order, rate constant, temperature, kinetic energy, catalysts,
pressure, concentration, surface area, collision theory, frequency of collisions enzymes. For
those considering the extended part of the lab these should also be presented: moles as it
relates to mass, volume of liquid and gas phases, limiting reactant, excess reactant, theoretical
and actual yield, the percentage yield, molar enthalpy change, endothermic and exothermic
reactions. Le Chatelier‘s principle.
Observations/Data:
Data Table 1
Time (seconds) for Temperature (degrees
Trials #
dissolving tablet. Celsius)
#1
#2
#3
Data Analysis/Results:
1. Graph the Water Temperature vs Time for Tablet to Dissolve.
2. Using the hot water, the rate was how many times faster than at 0 degrees Celsius?
3. Estimate the time it would take to dissolve an Alka-Seltzer tablet at 10 oC.
4. What if the temperature is doubled from 20 to 40 oC, by how much will the reaction rate
change?
Observations/Data:
Data Table 2
Time (seconds) for
Trial # Tablet
dissolving tablet.
#1 ―Whole‖ tablet
#2 ―8-piece‖ tablet
#3 ―Crushed‖ tablet
Data Analysis/Results:
1. What is the effect of particle size on the rate of the reaction?
2. The rate of the reaction for the crushed tablet was how many times faster than that of the
whole tablet?
3. As the particle size decreases, what is the effect on the total surface area and the
probability of interactions between atoms/ions/rate of the reactions?
4. Compare the results of particle size to the effect of temperature on the rate of the
reaction (Hint: Use data from Experiment 1.) Explain.
Observations/Data:
Data Table 3
Time (sec.) for
Trials # pH of solution
dissolving tablet
#1
Neutral H2O pH = 7
(from Data Table 2)
Slightly acidic
#2 5% by Vol.
Vinegar pH = 3
Strongly acidic
#3
1.00 Molar HCl pH = 0
Data Analysis/Results:
1. Compare the results and analyze the pH difference in the 3 trials and its effect on the rate
of the reaction.
2. Evaluate the effect of a decreased pH on the rate of the dissolving process; does it
increase or decrease the rate of the reaction?
3. What if the pH was increased? What effect would this have on the rate of the reaction?
Explain.
Observations/Data:
Data Table 4
Time (seconds) for
Trial # Pressure (atm)
dissolving tablet.
Normal sea level
Part A
pressure (1 atm)
Part B Increased pressure
Data Analysis/Results:
1. How does the increased pressure affect the time for the production of the gas?
2. When the gas bubbles are no longer visible in the liquid the reaction will be at equilibrium
(at equal rates represented by 2 arrows of the same size but in opposite direction). What
other factors could have been used to shift the direction of the arrows toward the product
besides the pressure?
3. In step 8 you were asked to again slightly release the pressure on the cork once. What
did you observe? Propose an explanation what occurred.
Extended discussion:
A known process in chemistry is the Bon-Haber process for synthesizing ammonia which is
widely used in the production of fertilizers and explosives. Research this process in the following
sites and answer the following questions.
Consider the need to optimize the % yield in the process for (the precursor for producing
fertilizers and explosives!) under ideal circumstances.
Experiment V: Determining the percentage yield, limiting reagent, and the molar enthalpy
of the reaction
Procedures:
1. Obtain the mass of an Alka-Seltzer tablet.
2. Obtain the mass of an empty clear plastic cup.
3. Using a graduated cylinder measure 250 ml of the water and add to the cup.
4. Measure the initial temperature (Ti) of the water in degree Celsius.
5. Add the tablet to the water.
6. After the tablet completely dissolves, record the final temperature(Tf) in degree Celsius
7. Mass the cup of water and ―reacted‖ tablet at the end of the process.
Observations/Data:
Data Table 5A
Measurements
Initial Mass of Alka- Seltzer tablet g
Mass of Empty Cup g
Volume of water ml
Initial Total mass of tablet, water and cup g
Final Mass of water, cup and reacted tablet g
Mass of gas produced g
o
Initial temp of Water C
o
Final temp of Solution C
o
Δ T of Solution C
Data Analysis:
1. Record the mass and the type of active ingredients from the package of an original
formula Alka-Seltzer (bright blue packet).
2. To find the mass of gas produced, subtract the initial mass of tablet, water and cup from
the final mass of water, cup and reacted tablet and record in the corresponding space in
Data Table 5A and in 5B (under mass of CO2).
3. The answer in step 2 is the mass of the gas evolved but the tablet includes additional
substances such as excess baking soda which must be considered in the calculations.
To find the actual mass of the CO2 gas, complete the following calculation:
a. Answer from #2 – 0.4529g of baking soda* = CO2 gas
4. Write the balanced chemical equation between the baking soda and the citric acid.
5. Write the balanced equation between the baking soda and the acetylsalicylic acid
6. Derive the molar masses for each reactant and product and derive the moles of each of
the reactants and record in Table 5B.
Data Table 5B
Chemical substances Molar masses Actual Mass # of Mols
Aspirin
Baking Soda
Citric Acid
Water
Carbon dioxide
Results:
1. Determine the limiting reagent. Show all your work
2. Determine the expected or theoretical mass of the gas evolved.
3. Calculate the excess mass of the reactant left over (already given in Experiment V step
3) but you need to show the work of how this value was derived.
4. Derive the percentage yield of the reactions. Hint: use CO2 answer from Data Table 5A
divided by the answer in step 2 above X 100.
5. Derive the enthalpy of the ―solution‖ and the ―reaction‖ in kilojoules per mol of reaction by
the following: [Q = mc T] / limiting reagent in moles; where the m is given by the Final
Mass of water + cup + reacted tablet, C is the specific heat capacity of water: 4.184J/g-K,
and ΔT is the final temperature minus the initial temperature in Celsius or Kelvin.
Data Table 5C
o
Initial Temperature (Ti) C
o
Final Temperature (Tf) C
Mass of system (m) g
Specific heat (C) J/g-K
Energy (Q) - {Q = m C ΔT} J
Energy ―gained‖ by the
kJ
reaction/dissolution process
moles of limiting reactant (citric acid) mol
Conclusions:
1. Explain the role of aspirin, baking soda and citric acid chemically?
2. Why was the baking soda ―chosen‖ to be the excess reagent?
3. Evaluate the sources of error in deriving the enthalpy of the reaction. Outline the specific
effects of the errors identified.
NGSSS:
SC.912.P.10.5 Relate temperature to the average molecular kinetic energy.
SC.912.P.12.10 Interpret the behavior of ideal gases in terms of kinetic molecular theory.
SC.912.P.12.11 Describe phase transitions in terms of kinetic molecular theory.
Purpose of Lab/Activity: To examine the idea of pressure and its relationship to volume.
Extension:
Interactive Boyle‘s Law Apparatus
Gizmo: Boyle's Law and Charles' Law
Boyle’s Law
NGSSS:
SC.912.P.10.5 Relate temperature to the average molecular kinetic energy.
SC.912.P.12.10 Interpret the behavior of ideal gases in terms of kinetic molecular theory.
SC.912.P.12.11 Describe phase transitions in terms of kinetic molecular theory.
Background Information:
In this investigation, you will observe the behavior of a gas, using a device called a Boyle‘s law
apparatus. The apparatus consists of a graduated syringe with a movable piston. Initially, the
syringe is adjusted to trap a volume of gas at the same pressure as its surroundings. The piston
then does not move because the pressure exerted by the gas in the syringe equals the pressure
of the atmosphere pushing on the piston. If the piston is pushed downward, it compresses the
gas trapped in the syringe. If the pressure on the piston is then decreased, the pressure of the
trapped gas will push the piston up.
In order to read the volume of trapped gas correctly, you must always read the measurement on
the side of the piston that is in contact with the gas. Because air is a mixture of gases-mostly
nitrogen and oxygen-that behaves physically as a single gas, the data from this lab can be
treated as data for a single gas. As the pressure of the air changes, you will monitor and collect
data on the resulting changes in volume. You can then use your data to find the atmospheric
pressure and determine how closely your results agree with Boyle‘s law
Safety Precautions:
Wear appropriate safety goggles.
Don‘t let the students aim the pressurized syringe at anyone as the syringe tip cap could
shoot off.
Note: The increasing load of books on the piston may become unsteady. Falling books
can injure the person measuring the gas volumes and damage the Boyle’s law
apparatus. Steady the books by resting them slightly against the ring or by nudging them
into balance as you would with wooden building blocks.
Vocabulary: Force, area, pressure, barometer, manometer, gases, altitude, elevation, density,
torr, psi (pounds per square inch- Ibs/in2), N/m2, mmHg, atm, volume
Procedures:
1. Work with a partner so that one person operates the apparatus (see figure below) while
the other steadies the books and keeps track of the procedural steps.
2. Put on your safety goggles. Secure the Boyle‘s law apparatus with a ring stand and
clamp. Adjust the initial volume (about 30 ml) to atmospheric pressure as directed by
your teacher.
3. Test the apparatus by pushing down on the piston with your hand slowly and steadily
until the volume of the trapped gas is reduced to 15 ml. Release the piston and note
whether it returns to initial volume. If not, check and adjust the seal at the syringe
opening.(Note: if red tip seals are too loose try replacing it with a small rubber stop with a
small indentation).
4. Place the apparatus on a flat, steady surface, such as a sturdy table or the floor. Record
the initial volume at 0 books of pressure in the data table.
5. Place one book on the piston and record the resulting volume of trapped gas in the data
table. Add a second book and record the gas volume. Continue adding books and
recording the resulting volumes until all 5 books are resting on the piston. Remember to
steady the books, especially when the apparatus is being read.
6. Remove all the books from the piston and reset the apparatus to the initial volume
recorded in Step 2.
7. Repeat Step 5 and 6 two more times, remembering to reset the apparatus between sets
of trials.
8. Clean up your work area.
Observations/Data:
8. Calculate the product of Ptotal x Vavg for each trial and record these values in the data
table.
Chemistry HSL Page 140
Curriculum and Instruction
Student
Conclusions:
1. What is the benefit of repeating the measurements 3 times?
2. Explain the relationship between pressure and volume shown in Graph#1.
3. Describe the results shown in Graph #2.
4. Look at the values you calculated in the last column of the data table. How do they
compare?
5. State Boyle‘s Law.
6. How do the pressure and volume values relate in terms of Boyle‘s law?
7. Will this pressure/volume relationship hold true for solids and liquids? Why or why not?
8. When the plunger was compressed, it got more and more difficult to push the plunger in.
Explain, using the kinetic molecular theory, why this happens.
9. Solve the following problems: 1) For an initial volume of 5.20-L and a pressure of 103
kilopascals, at what pressure in atmospheres will the volume of the gas expand to 12.00-
L? 2) A gas at 700.0 milimeters mercury occupies volume of 200.0 milliliters, at how
many atmospheres will it occupy 0.950-Liter?
Sample Graph
Half-Life
NGSSS:
SC.912.P.10.10 Compare the magnitude and range of the four fundamental forces
(gravitational, electromagnetic, weak nuclear, strong nuclear).
SC.912.P.10.11 Explain and compare nuclear reactions (radioactive decay, fission and fusion),
the energy changes associated with them and their associated safety issues.
SC.912.P.10.12 Differentiate between chemical and nuclear reactions.
.
Purpose of Lab/Activity:
To graph and interpret data of the isotope‘s half-life.
To model the half-life of an imaginary isotope.
isotopes? Explain.
c. As students collect data, ask them to describe patterns that are emerging
and what is the meaning of those patterns?
d. Direct the students to write their group data on the Group Data Table
displayed on the board.
What the teacher will do:
a. Ask student to explain why two trials of tossing the coins are needed and
how the calculated average minimizes any statistical deviations?
b. Looking at Table 2. Group Data on the board, ask the students: How does
After
each group‘s data compare to the class average data? Explain the
activity:
discrepancies.
c. How does this experimental design model the natural occurrence of
isotopes?
d. What are the limitations of this model?
Extension:
Gizmo: Half–life
Half-Life
NGSSS:
SC.912.P.10.10 Compare the magnitude and range of the four fundamental forces
(gravitational, electromagnetic, weak nuclear, strong nuclear).
SC.912.P.10.11 Explain and compare nuclear reactions (radioactive decay, fission and fusion),
the energy changes associated with them and their associated safety issues.
SC.912.P.10.12 Differentiate between chemical and nuclear reactions.
Background:
Isotopes are atoms of the same element with different atomic masses. These different masses
are a result of having different numbers of neutrons in their nuclei. Isotopes can be stable or
unstable (radioactive). Radioactive isotopes have unstable nuclei that break down in a process
called radioactive decay. During this process, the radioactive isotope is transformed into
another, usually more stable, element. The amount of time it takes half the atoms of a
radioactive isotope in a particular sample to change into another element is its half-life. A half-
life can be a fraction of a second for one isotope or more than a billion years for another isotope,
but it is always the same for any particular isotope.
Purpose of Lab/Activity:
To graph and interpret data of the isotope‘s half-life.
To model the half-life of an imaginary isotope.
Vocabulary: Spontaneous decay, radioactivity, alpha, beta, gamma emission, half-life, protons,
neutrons, electrons, nucleus, energy, potential energy, stability, elements, atom.
Procedures:
1. Place 100 pennies, each head-side up, into the container. Each penny represents an
atom (parent nuclei) of an unstable isotope.
2. Place the lid securely on the container. Holding the container level, shake it vigorously for
20 seconds.
3. Set the container on the table and remove the lid. Remove only pennies that are now in a
tails-up position (decayed nuclei or daughter nuclei).
4. Count the pennies you removed and record this number in Table 1 under Trial 1. Also
record the number of heads-up pennies that are left (undecayed parent nuclei).
5. Repeat steps 2 through 4 until there are no pennies left in the container.
6. Repeat steps 1 through 5 and record your data in Table 1 under Trial 2.
Observations/Data:
1. Calculate the averages for each time period and record these numbers in Table 1. The
first row is done for you.
2. Graph the average data from Table 1. Graph the number of heads-up pennies remaining
on the Y-axis (undecayed atoms or nuclei) against time in seconds (on X-axis) using a
symbol such as X,O, Δ, or different colors to represent the trials and the average values.
3. Record the averages for each time trial per group in your class in Table 2. The first row is
done for you.
4. Determine the totals and then the averages for the combined data from all groups and
record in Table 2.
5. Create a second graph for the average class data for undecayed nuclei. Use a different
symbol or color for each group and the class‘ average in the same way as you graphed
your individual group‘s data.
6. Be sure to include a symbol key for each graph.
Data Analysis:
Trial 1 Trial 2
Averages
A B C D
Number of Number of Number of Number of Columns Columns
Shaking
Heads-up Tails-up Heads-up Tails-up A and C B and D
Time
Remaining Removed Remaining Removed (H) (T)
After 20 s
After 40 s
After 60 s
After 80 s
After 100 s
After 120 s
After 140 s
H 100 100 100 100 100 100 100 100 800 100
0s
T 0 0 0 0 0 0 0 0 0 0
H
20 s
T
H
40 s
T
H
60 s
T
H
80 s
T
H
100 s
T
H
120 s
T
H
140 s
T
H = Heads; T = Tails
Results:
1. In this model, what represented the process of radioactive decay?
2. Which side of the penny represented the decayed isotope? Which side represented the
undecayed atoms?
3. In this model, what was the half-life of the pennies? Explain
4. Why were more accurate results obtained when the data from all groups was combined
and graphed?
Conclusions:
1. What can you conclude about the total number of atoms that decay during any half- life
period of the pennies?
2. If your half-life model had decayed perfectly, how many atoms of the radioactive isotope
should have been left after 80 seconds of shaking? (Hint: extrapolate the graph).
3. If you started with 256 radioactive pennies, how many would have remained undecayed
after 60 seconds of shaking? (Hint: interpolate the graph).
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes of matter.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
SC.912.P.8.8 Characterize types of chemical reaction, for example: redox, acid-base, synthesis
and single and double replacement reaction.
SC.912.P.8.9 Apply the mole concept and the law of conservation of mass to calculate
quantities of chemicals participating in reactions.
Purpose of Lab/Activity:
To introduce students to precipitation reactions, a type of double displacement reactions
To practice nomenclature of ionic compounds and formula writing
To create a particle level model to explain precipitation reactions
To identify the parts of a chemical equation and the state subscripts
Prerequisite: Students should already be familiar with ionic compounds and electrolytes. They
should have a clear model of how a solid dissolves in a solvent to produce an aqueous solution.
They should also be aware of basic nomenclature of ionic compounds including polyatomic ions.
Materials:
0.1M solutions of the following in Beral pipettes or bottles with droppers
NiCl2 NaOH AgNO3
Na2S Na2CO3 Pb(NO3)2
Co(NO3)2 CaCl2 Glass spot plate or
Ba(NO3)2 KI well plate
K2CrO4
CuSO4
enough for them to see what the chemical looks like in the solid state and
then show them the solutions they will be using.
d. Explain students the procedure and stress that they don‘t use more than
two drops of reactant. Some of these chemicals such as the chromates
and lead salts are toxic and harmful for the environment. So to reduce
waste the amounts must be small.
e. Warn students not to mix anything other than what is described in the
activity.
f. This activity works best when students work in pairs.
g. Groups can work in any order they prefer. If all groups work in order they
will all need the same bottles at the same time. Working out of order will
minimize this delay. Another solution is to make enough solutions for every
group.
What the teacher will do:
a. Students will be very surprised to see what happens when they start
combining the solutions. Some precipitates are white and others are black
or colored. Therefore, student should have a white piece of paper under the
glass spot plate and a dark surface to see the colors well.
b. Students may not realize that the color change occurs because a solid is
During forming. You may need to point out that at the bottom they can see some
activity: flecks of solid collecting as the mixture settles.
c. Ask the students what they think it is happening or where the solid is
coming from.
d. Watch students write some of the formulas for the products and reactants.
Correct mistakes in nomenclature as you observe them
e. Follow appropriate disposal procedure for the chemicals used in this
experiment.
What the teacher will do:
a. Bring the students together for class discussion.
b. Ask students to explain what they think is happening at the particle level
that makes a solid form out of two clear solutions
c. Lead students to conclude that each solution has an ion that when they
finally combine they attach to each other very strongly and water cannot
break the lattice apart.
d. Ask students what is the role of the ions that do not precipitate. Introduce
After
the concept of spectator ions. These ions do not participate in the reaction,
activity:
they just watch as spectators in a show do.
e. This time you can choose to cover the concept of total ionic equations and
net ionic equations if you deem this appropriate for your course. Also you
can introduce solubility rules.
f. Mention that this type of reactions is called precipitation reactions and they
are also part of the type of reaction called double displacement.
g. Discuss the conclusion questions in the student procedure after students
have had time to work through them.
Extension:
Gizmo: Limiting Reactants, Collision Theory
NGSSS:
SC.912.P.8.2 Differentiate between physical and chemical properties and physical and chemical
changes of matter.
SC.912.P.8.6 Distinguish between bonding forces holding compounds together and other
attractive forces, including hydrogen bonding and van der Waals forces.
SC.912.P.8.7 Interpret formula representations of molecules and compounds in terms of
composition and structure.
SC.912.P.8.8 Characterize types of chemical reaction, for example: redox, acid-base, synthesis
and single and double replacement reaction.
SC.912.P.8.9 Apply the mole concept and the law of conservation of mass to calculate
quantities of chemicals participating in reactions.
Background: It is common to see a solid in water dissolve until it disappears. The water
molecules are able to dismantle the lattice structure of the solid and separate it into ions too
small to see. In this case, the force between the water and the ions is stronger than the forces
between the ions and dissolution occurs. Is it possible for this process to happen in reverse?
The following activity will answer that question.
Purpose or Problem Statement: In the following activity you will combine solutions of ionic
compounds to form precipitates. You will learn how these precipitates form at the particle level.
Safety:
Use only the amount of chemical described in the procedure
Use goggles at all times
You will be handling small amounts of toxic chemicals. Do not touch or ingest the
chemicals in any way.
Dispose the chemicals as instructed by your teacher
Vocabulary: Precipitate, Lattice, solution, ions, solute, solvent, precipitation reactions, double
displacement reactions, spectator ions.
Procedures:
Using the following chemical reactions:
1. Combine two drops of each reactant (left of the arrow, ––>) on the glass plate. The
products are right of the arrow. [(ppt) means precipitate, flecks of solid formed and (aq)
means aqueous, or in solution, no solid formed.
2. Write the chemical formula for each compound in the reaction.
Chemistry HSL Page 149
Curriculum and Instruction
Student
3. Under the chemical formula for the precipitate (ppt), write the color of the precipitate.
2) Barium nitrate(aq) + copper(II) sulfate(aq) ––> barium sulfate(ppt) + copper(II) nitrate (aq)
7) Potassium iodide(aq) and lead(II) nitrate(aq) ––> lead(ll) iodide(ppt) + potassium nitrate(aq)
4. Disposal and cleaning: Follow your teacher‘s instructions for the cleaning and
disposal. Do not flush the chemicals down the drain. This lab involves heavy metals
such as lead, barium, and silver which are toxic and harmful to the environment.
These chemicals should be disposed the appropriate way.
Conclusion:
1. In your own words, define precipitate
2. Explain how precipitation reactions occur at the particle level
3. What are spectator ions?
4. Tap water involves many dissolved solids including calcium and magnesium. In some
areas of high mineral concentration pipes clog overtime just from the water running
through them. Based on your knowledge of precipitation reactions, explain how the
pipes clog.
5. Based on the reactions that you produced above, what chemical could you add to a
solution containing chloride ions if you wish to separate the chloride out of the
solution?
6. Heavy metals such as lead, silver, and barium are toxic and sometimes present in the
water. Based on your knowledge of precipitation reactions, how can water treatment
plants get rid of these toxic ions?
7. Kidney stones, a very painful condition, are composed of solid calcium oxalate.
Provide an explanation on how these stones can originate in your body.
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