NAMA : ROSNA

NIM : F1C118058
1. Evaluasi integral berikut (Pertimbangkan semua huruf besar untuk menjadi konstanta):
a. ∫ 4𝑥 2 𝑑𝑥
1
b. ∫ 𝑥 2 𝑑𝑥
c. ∫ sin 3𝑥 𝑑𝑥
d. ∫(3𝑥 + 5)2 𝑥 𝑑𝑥
e. ∫ 4𝑒 𝑥 𝑑𝑥
f. ∫ 𝑃 𝑑𝑣
𝑅𝑇
g. ∫ 𝑑𝑝
𝑝
h. ∫ 𝑀𝑣 𝑑𝑣
𝑄2
i. ∫ 𝑟 2 𝑑𝑟
j. ∫ cos(2𝜋𝑊𝑡)𝑑𝑡

Solution

a) ∫ 4𝑥2

1
b) ∫ 𝑥 2 𝑑𝑥

c) ∫ 𝑠 in 3𝑥 𝑑𝑥
Misalnya : U = 3x

(3𝑥+5 )2+1
d) ∫( 3𝑥 + 5)2 𝑥 𝑑𝑥 = 3(2+1 )
+C
(3𝑥+5 )2+1
= (6+3 )
+ 𝐶
9 25
= 4 𝑥4 + 10x3 + 2 𝑥2 + C
e) ∫ 4𝑒 𝑥 𝑑𝑥
Misalkan : 𝑢 = 𝑥
𝑑𝑢 = 𝑑𝑥
𝑑𝑥 = 𝑑𝑢
Jadi, ∫ 4𝑒 𝑥 𝑑𝑥 = ∫ 4𝑒 𝑢 𝑑𝑥
= 4 ∫ 𝑒 𝑢 𝑑𝑢
= 4𝑒 𝑢 + 𝑐
Kembalikan ke bentuk semula , 𝑢 = 𝑥
∫ 4𝑒 𝑥 𝑑𝑥 = 4𝑒 𝑥 + 𝑐

f) ∫ 𝑃 𝑑𝑣 = pv + C

𝑅𝑇
g) ∫ 𝑃
𝑑𝑝 = RT ln P + C

1
h) ∫ 𝑀𝑣 𝑑𝑣 = 2 𝑀𝑣 2 + C

𝑄2
i) ∫ 𝑟 2 𝑑𝑟 = ∫ 𝑄 2 𝑟 −2 𝑑𝑟
1
= 𝑄 2 −1 𝑟 −1 + 𝐶
𝑄2
=− + 𝐶
𝑟

1
j) ∫ cos(2𝜋𝑊𝑡) 𝑑𝑡 = 2𝜋𝑤 sin(2πwt) + C

NAMA : RAHMAT LIA KADRINA

NIM : F1C118099
1. Evaluate the following integrals using the table of integrals faund in appendix II, as needed
(consider all uppercase letters to be constants):
a. ∫ 𝑒 −4𝑥 𝑑𝑥
b. ∫(𝑥 2 − 𝐴2 ) 𝑑𝑥
c. ∫(𝑥 2 − 𝐴2 )1⁄2 𝑑𝑥
d. ∫(𝑥 4 − 2𝑥 2 + 4) 𝑥 3 𝑑𝑥
𝑁𝜋𝑥
e. ∫ 𝑠𝑖𝑛2 ( 𝐴
) 𝑑𝑥
𝑁𝜋𝑥
f. ∫ 𝑠𝑖𝑛2 ( 𝐴 ) 𝑥 𝑑𝑥
−∆𝐻
g. ∫ ( 𝑅𝑡 2 ) 𝑑𝑡
𝑥
h. ∫ 𝑒 cos 𝑥 𝑑𝑥
i. ∫ 𝑠𝑖𝑛2 (2𝜋𝑊𝑡) 𝑑𝑡
j. ∫ 𝑐𝑜𝑠 3 ∅ sin ∅ 𝑑∅
k. ∫ 𝑐𝑜𝑠 4 𝜃 𝑑𝜃
 l. ∫ 𝑠𝑖𝑛6 (3𝑥 + 4)𝑑𝑥
m. ∫ 𝑥 2 cos 2𝑥 𝑑𝑥
𝑑𝑥
n. ∫ (4−𝑥) (3−𝑥)
∆𝐻 𝐴 𝐵 𝐶
o. ∫ ( 𝑡 2 + 𝑡
+ 2 + 3 𝑡) 𝑑𝑡
𝐶𝑝
p. ∫ 𝑑𝑡
𝑡
𝑑𝑥
q. ∫ (𝐴 − 𝑥)𝑛
−𝑎𝑟
r. ∫ 𝑟 𝑒 𝑑𝑟
s. ∫ 𝑒 ∈/𝐾𝑇 𝑑 ∈
𝑑(𝐴)
t. ∫ (𝐴)
= − ∫ 𝐾 𝑑𝑡

Solution
a) ∫ 𝑒 −4𝑥 𝑑𝑥
1
=− 4 𝑒 −4𝑥 + 𝐶

b) ∫(𝑥 2 − 𝐴2 ) 𝑑𝑥
1
= 3 𝑥 3 − 𝐴2 + 𝐶

c) ∫(𝑥 2 − 𝐴2 )1⁄2 𝑑𝑥
1
= [𝑥 √(𝑥 2 − 𝐴2 ) − 𝐴2 ln |𝑥 + √𝑥 2 − 𝐴2 | ] + 𝐶
2

d) ∫(𝑥 4 − 2𝑥 2 + 4) 𝑥 3 𝑑𝑥

= ∫ ( 𝑥7 – 2x5 + 4x3 )

= ∫ 𝑥 4 dx– ∫ 2𝑥 2 𝑑𝑥 + ∫ 4𝑥 3 dx

1 1
= X8 - X6 + X4 + C
8 3

𝑁𝜋𝑥
e) ∫ 𝑠𝑖𝑛2 ( ) 𝑑𝑥
𝐴
𝑥 𝐴 2𝑁𝜋𝑥
=2− sin
4𝜋𝑁 𝐴

𝑁𝜋𝑥 𝑥2 𝐴 2𝑁𝜋𝑥 𝐴2 2𝑁𝜋𝑥

f) ∫ 𝑠𝑖𝑛2 ( 𝐴
) 𝑥 𝑑𝑥 = 4
− 4𝜋𝑁
𝑥 sin 𝐴
− 8𝑁2𝜋2 cos ( 𝐴
)+𝐶
 −∆𝐻 −∆𝐻 𝑡
g) ∫ ( 𝑅𝑡 2 ) 𝑑𝑡 = ∫ 𝑡 2 𝑑𝑡
𝑅
−∆𝐻
= 𝑅
∫ 𝑡 −2 𝑑𝑡
∆𝐻
= 𝑇 −1+ C
𝑅
∆𝐻
= +𝐶
𝑅𝑇

1
h) ∫ 𝑒 𝑥 cos 𝑥 𝑑𝑥 = 2 𝑒 2 (cos 𝑥 + sin 𝑥 ) + 𝐶

𝑡 1
i) ∫ 𝑠𝑖𝑛2 (2𝜋𝑊𝑡) 𝑑𝑡 = 2 − sin(4𝜋𝑡) + 𝐶
8𝜋𝑊

sin ∅ 1
j) ∫ 𝑐𝑜𝑠 3 ∅ sin ∅ 𝑑∅ = − sin ∅ × 𝑠𝑖𝑛4 + 𝐶
4
1
= − 4 𝑐𝑜𝑠 4 ∅ + 𝐶

3𝜃 3 sin 2𝜃 𝑐𝑜𝑠 3 𝜃 sin 𝜃

k) ∫ 𝑐𝑜𝑠 4 𝜃 𝑑𝜃 = + + +𝐶
8 16 4

1 5𝑥 5
l) ∫ 𝑠𝑖𝑛6 (3𝑥 + 4)𝑑𝑥 =− 18 𝑠𝑖𝑛5 ( 3𝑥 + 4 ) cos( 3𝑥 + 4 ) + 16 − sin 2( 3𝑥 + 4 )
96
5
= − 72 𝑠𝑖𝑛3 ( 3𝑥 + 4) cos( 3x + 4 ) + 𝐶

𝑥2 1 𝑥
m) ∫ 𝑥 2 cos 2𝑥 𝑑𝑥 = sin 2𝑥 − 4 sin 2𝑥 + 𝑐𝑜𝑠2𝑥 + 𝐶
2 2

𝑑𝑥 1
n) ∫ (4−𝑥) (3−𝑥) = 3−4 [− 𝐼𝑛( 4 − 𝑥 ) + ( 3 − 𝑥)]
(4−𝑥)
= 𝐼𝑛 (3−𝑥) + 𝐶

∆𝐻 𝐴 𝐵 𝐶 𝑏 𝑐
o) ∫ ( 𝑡 2 + + 2 + 3 𝑡) 𝑑𝑡 = ∫ (∆𝐻𝑡 −2 + 𝐴𝑡 −1 + 2 + 3 𝑡) 𝑑𝑡
𝑡
∆𝐻 𝑏 𝑐
=− + 𝐴 ln 𝑡 + 2 𝑡 + 6 𝑡 2 + 𝐶
𝑡

𝐶𝑝 1
p) ∫ 𝑑𝑡 = 𝐶𝑝 ∫ 𝑡 𝑑𝑡
𝑡

= 𝐶𝑝 ln 𝑡 + 𝐶
 𝑑𝑥 1
q) ∫ = [(𝑛−1)(𝑎−𝑥)𝑛−1 ] + 𝐶
(𝐴 − 𝑥)𝑛

1
r) ∫ 𝑟 𝑒 −𝑎𝑟 𝑑𝑟 = − 2 𝑒 −𝑎𝑟 ( 𝑎𝑟 + 1 ) + 𝐶
𝑎

s) ∫ 𝑒 ∈/𝐾𝑇 𝑑 ∈ =− 𝑘𝑇𝑒 −𝜖⁄𝑘𝑇 + 𝐶

𝑑(𝐴)
t) ∫ = − ∫ 𝐾 𝑑𝑡
(𝐴)

. ∫ 𝑑(𝐴)(𝐴)−1 = − ∫ 𝐾 𝑑𝑡
. ln 𝐴 = −𝐾𝑡 + 𝐶

NAMA : AZRILLA AWALUDDIN

NIM : F1C118077
2. Mengevaluasi integral berikut menggunakan Tabel Integrasi yang ditemukan pada
Lampiran II, jika diperlukan (pertimbangkan semua huruf besar sebagai konstanta) :
a. ∫ 𝑒 −4𝑥 𝑑𝑥
b. ∫(𝑥 2 − 𝐴2 )𝑑𝑥
c. ∫(𝑥 2 − 𝐴2 )1/2 𝑑𝑥
d. ∫(𝑥 4 − 2𝑥 2 + 4)𝑥 3 𝑑𝑥
𝑁𝜋𝑥
e. ∫ sin2 ( ) 𝑑𝑥
𝐴
𝑁𝜋𝑥
f. ∫ sin2 ( 𝐴 ) 𝑥 𝑑𝑥
∆𝐻
g. ∫ (− 𝑅𝑡 2 ) 𝑑𝑡
h. ∫ 𝑒 𝑥 cos 𝑥 𝑑𝑥
i. ∫ sin2 (2𝜋𝑊𝑡)𝑑𝑡
j. ∫ cos 3 𝜑 sin 𝜑 𝑑𝜑
k. ∫ cos 4 𝜃 𝑑𝜃
l. ∫ sin6 (3𝑥 + 4)𝑑𝑥
m. ∫ 𝑥 2 cos 2𝑥 𝑑𝑥
𝑑𝑥
n. ∫ (4−𝑥)(3−𝑥)
∆𝐻 𝐴 𝐵 𝐶
o. ∫ ( 𝑟 2 + 𝑡 + 2 + 3 𝑡) 𝑑𝑡
𝐶𝑝
p. ∫ 𝑑𝑡
𝑡
𝑑𝑥
q. ∫ (𝐴−𝑥)𝑛
−𝑎𝑟
r. ∫ 𝑟𝑒 𝑑𝑟
−∈/𝐾𝑇
s. ∫ 𝑒 𝑑∈
 𝑑(𝐴)
t. ∫ = − ∫ 𝐾 𝑑𝑡
𝐴
Jawaban :
∫ 𝑒 𝑥 cos 𝑥 𝑑𝑥

Solution
𝑇 𝑑
∫𝑇 (𝑎 + 𝑏𝑇 + 𝑐𝑇 2 + 𝑇 ) 𝑑𝑇; 𝑎, 𝑏, 𝑐 𝑎𝑛𝑑 𝑑 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑠
2
a)
1

= ∫ 𝑎 dT+ ∫ 𝑏𝑇 𝑑𝑇 + ∫ 𝑐𝑇2 dT + ∫ 𝑑/𝑇

𝑏 𝑐
= ax + 2 𝑇𝑥 2 + 3 𝑇𝑥3 + d ln T

𝑏 𝑐
= a ( T2-T1) + 2 (𝑇22 − 𝑇12 ) + 3 (𝑇23 − 𝑇13 ) + d ln ( T2-T1)
𝑃 𝑅𝑇
b) ∫𝑃 2 𝑑𝑃; 𝑅 𝑑𝑎𝑛 𝑇 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
1 𝑃

= RT ln P
=RT ln (P2 – P1 )

2𝜋
c) ∫0 𝑑∅ = ]2π

= 2𝜋 − 0
= 2𝜋

𝑇 ∆𝐻 𝑇 ∆𝐻
d) ∫𝑇 2 2 𝑑𝑇 = ∫𝑇 2 𝑇 −2 𝑑𝑇
𝑅𝑇
1 1 𝑅
∆𝐻
= − 𝑇 −1 ]
𝑅
∆𝐻 1
= − ( )
𝑅 𝑇2 −𝑇1

𝑉 𝑛𝑅𝑇 𝑛𝑅𝑇 𝑛2 𝑎
e) ∫𝑉 2 𝑉−𝑛𝑏 − (𝑉−𝑛𝑏 − ) 𝑑𝑉; 𝑎, 𝑏, 𝑛, 𝑅, 𝑎𝑛𝑑 𝑇 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑠
1 𝑉2

𝑛𝑅𝑇 𝑛2 𝑎
= ∫ 𝑉−𝑛𝑏 𝑑𝑉 − ∫ 𝑣2
𝑑𝑉

= nRT ln V-nb – n2a ln V2

 =nRT ln (V2 – V1 ) –nb - n2a ln (V2 – V1 )

𝜋⁄2
f) ∫0 𝑠𝑖𝑛2 𝜃 cos 𝜃 𝑑𝜃
cos 𝜃 1
= cos 𝜃 × 𝑠𝑖𝑛3 𝜃 + 𝐶
3
1 𝜋
= 3 𝑠𝑖𝑛3 −0
2
1
=3

𝑎 𝑛𝜋𝑥
g) ∫0 𝑥 2 𝑠𝑖𝑛2 𝑎
𝑑𝑥; 𝑛, 𝜋, 𝑎𝑛𝑑 𝑎 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑠
𝑎
𝑛𝜋𝑥 𝑎3 𝑎3
∫ 𝑥 2 sin2 𝑑𝑥 = − 2 2
0 𝑎 6 4𝑛 𝜋

∞ 2
h) ∫0 𝑥 2 𝑒 −𝑎𝑥 𝑑𝑥; 𝑎 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
1⁄
1 𝜋 2
= ( )
4𝑎 𝑎

∞
i) ∫0 𝑒 −2𝑟⁄𝑎0 𝑟 𝑑𝑟; 𝑎0 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
1!
=
2 2
( )
𝑎0
𝑎02
=
4

∞ 2 ⁄2𝐾𝑇
j) ∫0 𝑒 −𝑚𝑉 𝑣 3 𝑑𝑣; 𝑚, 𝐾, 𝑎𝑛𝑑 𝑇 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡𝑠
1
= 𝑚 2
2( )
2𝑘𝑇
1
=
𝑚2
2 ( 2 2)
4𝑘 𝑇
2𝑘 2 𝑇 2
=
𝑚2

∞ 2 +𝐽)
k) ∫0 (2𝐽 + 1)𝑒 −𝑎(𝐽 𝑑𝐽; 𝑎 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
1
=2
2𝑎
1
=
𝑎
NAMA : SELVIA LAILA WAWE
NIM : F1C118071
4. Consider the ideal gas law equation P = nRT/V, where in this case n, R, and T are
assumed to be constant. Prepare a graph of P versus V, choosing suitable coordinates,
for n= 1 mole, R= 0,0821L.atm/mol. K, and T= 298 K from a volume of V = 1.00
liters to a volume of V= 10.0 liters. Consider now the area under the P versus V curve
from = 2.00 liters to V = 6.00 liters. Determine the approximate area graphically by
breaking up the area into four rectangles of equal width ΔV; compare your answer to
that found by analytically integraing the function between these limits of integration.

Solution
𝑛𝑅𝑇
P= 𝑉

𝑉2 𝑛𝑅𝑇
= ∫𝑉1 𝑉
𝜕𝑉

𝑉2 𝜕𝑉
= 𝑛𝑅𝑇 ∫𝑉1 𝑉

= 𝑛𝑅𝑇 (ln 𝑉2 − 𝑉1)

𝑉2
= 1 mol × 0.0821𝑙. 𝑎𝑡𝑚/𝑚𝑜𝑙. 𝐾 × 298𝐾 × 𝑙𝑛(𝑉1)

2𝑙
= 1 mol ×0.0821 l.atm/mol.K × 298𝐾× ln(1 𝑙)

= 1 𝑚𝑜𝑙 × 0.0821 𝑙. 𝑎𝑡𝑚/𝑚𝑜𝑙. 𝐾 × 298𝐾 × 𝑙𝑛(0.693𝑙)

= 16,955 atm

NAMA : DIAH FEBRYANA

NIM : F1C118090
5. Evaluate the following multiple integrals using the table of integrals, as needed :
a) ∫ ∫ yx2 dx dy
b) ∫ ∫ (x2 + y2) dx dy

c) ∫ ∫ y In x dx dy
 d) ∫ ∫ ∫ x2 In y e2x dx dy dz

𝜋/2 2
e) ∫0 ∫0 𝑟 cos 𝜃 𝑑𝑟 𝑑𝜃

2𝜋 𝜋 𝑟
f) ∫0 ∫0 ∫0 r 2 sinθ dr dθ d⏀

∞ ∞ ∞ 2 𝑛 2 𝑛𝑦2 𝑛𝑧2
- ℎ
∫0 ∫0 ∫0 𝑒 ( 𝑥 + + ) dnx dny dnz ; a, b, c, h, m, k, and tconstant.
𝐵𝑚𝑘𝑇 𝑎2 𝑏2 𝑐2

Solution:
a) ∫ ∫ yx2 dx dy =∫{∫(𝑦𝑥 2 ) 𝑑𝑥 } 𝑑𝑦
1
= ∫ (3 𝑦𝑥 3 ) 𝑑𝑦
11
= 2 3 𝑦2𝑥3 + 𝐶
1
=6 𝑦 2 𝑥 3 + 𝐶

b) ∫ ∫ (x2 + y2) dx dy =∫{∫( 𝑥 2 + 𝑦 2 ) dx} dy

1
=∫ (3 𝑥 3 + 𝑦 2 𝑥) 𝑑𝑦
1 1
= (3 𝑥 3 𝑦 + 3 𝑥𝑦 3 ) + 𝐶
1
= (𝑥 3 𝑦 + 𝑥𝑦 3 ) + 𝐶
3

c) ∫ ∫ y In x dx dy = ∫{∫( y ln 𝑥) dx} dy
= ∫ 𝑦(𝑥 ln 𝑥 − 𝑥)𝑑𝑦
1
= 𝑦 2 (𝑥 ln 𝑥 − 𝑥) + 𝐶
2
𝑦 2 ln 𝑥 𝑦2𝑥
= − +𝐶
2 2

𝑥 2 𝑒 2𝑥 𝑒 2𝑥
d) ∫ ∫ ∫ x2 In y e2x dx dy dz =[ − (2𝑥 − 1)] (𝑦 𝑙𝑛 𝑦 − 𝑦)𝑧 + 𝐶
2 4

𝜋
2 𝜋/2 2
e) ∫02 ∫0 𝑟 cos 𝜃 𝑑𝑟 𝑑𝜃 = ∫0 {∫0 (𝑟 cos 𝜃) 𝑑𝑟} 𝑑𝜃
𝜋⁄2
= ∫0 2 cos 𝜃 𝑑𝜃
= 2(sin 𝜋⁄2 − sin 0)
= 2(1-0)
=2
 2𝜋 𝜋 𝑟 2𝜋 π 1
f) ∫0 ∫0 ∫0 r 2 sinθ dr dθ d⏀ = ∫0 {∫0 (3 r 3 sin θ) dθ} 𝑑∅
2𝜋 1
=∫0 (− 3 𝑟 3 (cos 𝜋 − cos 0)) 𝑑∅
2𝜋 2 3
=∫0 𝑟 𝑑∅
3
2
= 3 𝑟 3 (2𝜋 − 0)
2
= 3 𝑟 3 2𝜋
4
= 3 𝜋𝑟 3

∞ ∞ ∞ 2 𝑛 2 𝑛𝑦2 𝑛𝑧2
- ℎ
g) ∫0 ∫0 ∫0 𝑒 ( 𝑥 + + ) dnx dny dnz ; a, b, c, h, m, k, and tconstant.
𝐵𝑚𝑘𝑇 𝑎2 𝑏2 𝑐2
2 2
∞ ∞ ∞ ℎ2 𝑛𝑘 𝑛𝑦 𝑛𝑧2
− ( 2+ 2 + 2 )
8𝑚𝑘𝑇 𝑎 𝑏 𝑐 𝑎𝑏𝑐
∫ ∫ ∫ 𝑒 𝑑𝑛𝑥 𝑑𝑛𝑦 𝑑𝑛𝑧 = (2𝜋𝑚𝑘𝑇)3/2
0 0 0 ℎ3

NAMA : ADINDA NUR FADILLAH

NIM : F1C1 18 065
6. The equation of a straight line passing through the origin of a Cartesian coordinate
system is y = mx where m is the slope of the line. Show that the area of a triangle
1
made up of this line and the x axis between x = 0 and x a is A = 2 ay

Solution:
Dik : y = mx , m = gradien

6
Dit .: Tunjukkan bahwa area segitiga yang terdiri dari garis ini dan sumbu x antara x = 0
1
dan x = a adalah 𝐴 = 2 𝑎𝑦 ?

y X

-m -
1

0 0

m 1
 2m 2

3m 3

Dengan sumbu –x, dimana x = 0 dan x = a. Misalkan titik potong y =mx dan x = a disebut titik p
maka terbentuk persegi OAPY (karena y = mx, akibatnya OA =OY).

Luas persegi OAPY = s x s

= a.y

1 1
Sehingga luas segitiga yang terbentuk yaitu: 2 luas persegi OAPY = 2 AY

NAMA : FESTI SRI SABANIA

NIM : F1C1180

7. The Kirchhoff equation for a chemical reaction relating the variation of ∆H of a

reaction with absolute temperature is

𝜕(∆𝐻)
[ ]p = ∆Cp
𝜕𝑇

Where ∆Cp represents the change in the heat capacity at constant pressure for the reaction.
Expressing ∆Cp as apower series in T,
 ∆Cp = a + bT + cT2

derive an equation for ∆H as a function of temperature. ( Hint: write the above derivative
in differential form).

Solution:

Persamaan Kirchhof

𝜕 (∆𝐻)
[ ]𝑝 = ∆𝐶𝑝
𝜕𝑇

𝜕(∆𝐻)
∆∆𝐶𝑝 =[ ]𝑝 = a + bT + cT2
𝜕𝑇

Tentukan persamaan ∆𝐻 = ⋯ … … . ?

Penyelesaian:

𝜕 (∆𝐻) = (a + bT + cT2) 𝜕𝑇

= ∫ 𝜕(∆𝐻) = ∫(𝑎 + 𝑏𝑇 +cT2)𝜕𝑇

𝑏 𝑏
H = aT + 2 𝑇 2 + 3 𝑇 3 + d
NAMA : MARDHATILLAH
NIM : F1C118038
8. The gibbs –helmholtz equation for a chemical reaction is
𝜕(∆𝐺⁄𝑇 ) ∆𝐻
[ ]p = − 𝑇 2
𝜕𝑇

Where ∆𝐺 is the Gibbs free energy change attending the reaction, ∆H is the enthalpy
change attending the reaction, and T is absolute temperature. Expressing ∆H in a
power series in T,
∆H= a +bT + cT2
 Where a, b,and c are experimentally determined constants, derive an expession for
∆G as a function of temperature.
Solution:

∆𝐺
𝜕( ) ∆𝐻
𝑇
[ ] = − 𝑇2
𝜕𝑇

Jika: ∆𝐻 = a + bT + c𝑇 2

Tentukan: ∆𝐺 = ⋯ … … … … ?

Penyelesaian:

∆𝐺
𝜕(
𝑇
) (𝑎+𝑏𝑇+𝑐𝑇 2 )
= −
𝜕𝑇 𝑇2

𝑎 𝑏
𝜕(∆G) = − 𝑇 2 − 𝑇 − 𝑐

∆𝐺 𝑎 𝑏
𝜕 ( 𝑇 ) = (− 𝑇 2 − 𝑇 − 𝑐) 𝜕𝑇

∆𝐺 𝑎 𝑏
∫ 𝜕 ( 𝑇 ) = − ∫(𝑇 2 + 𝑇 + c)𝜕𝑇

∆𝐺 𝑎
= −(− 𝑇 + 𝑏 ln 𝑇 + 𝑐𝑇) + d
𝑇

∆𝐺 = 𝑎 − 𝑏𝑇 ln 𝑇 − 𝑐𝑇 2 + dT

NAMA : SITTI HANAFIAH

NIM : F1C118031

9. Find the probability of finding a particle confined to field-free one-dimensional box in

the state n = 1 at x = L/2 in a range L/2 ± 0,05 L, where L is the widthof box, given
 2 𝐿/2+0,05𝑙 𝜋𝑥
Probability = 𝐿 ∫𝐿/2−0,05𝑙 𝑠𝑖𝑛2 𝑑𝑥
𝐿

1
2 +0.05𝐿 𝜋
Probability = ∫ 1
2
𝑠𝑖𝑛2 𝐿 𝑥 𝜕𝑥
𝐿 −0.05𝐿
2

1
2 +0.05𝐿 2𝜋
Jawab: = 𝐿 ∫12 (1 − cos x)𝜕𝑥
−0.05𝐿 𝐿
2

2 1 1 2𝜋
= 𝐿 (2 ∫ 𝜕𝑥 − 2 ∫ cos 𝑥 𝜕𝑥)
𝐿

1
2 𝑥 𝐿 2𝜋 +0.05𝐿
2
= 𝐿 (2 − 4𝜋 𝑠𝑖𝑛 𝑥)1/2−0.05𝐿
𝐿

𝐿 𝐿
+0.05𝐿 𝐿 2𝜋 𝐿 −0.05𝐿 𝐿 2𝜋
= 2 2
( − 2𝜋 sin (2 + 0.05𝐿)) − ( − 2𝜋sin 𝐿 (L/2-0.05L))
𝐿 𝐿 𝐿

1 1
=(0.05− 2𝜋sin 1.1𝜋) (0.45-2𝜋sin 0.9𝜋)

1 1
= 0.1− sin 1,1𝜋 + sin 0.9𝜋)
2𝜋 2𝜋

1
= 0.1− 2𝜋 (sin1.1𝜋 − sin 0.9𝜋)

1
= 0.1− 2𝜋 (sin 198o− sin 162o)
 1
= 0.1− (−0,31 − 0.31)
2𝜋

0.62
= 0.1 + 2(3,14)

= 0.198
10. Find the probability of finding an electron in the 1s-state of the hydrogen atom at r
=a0 in range a0 ± 0,05 a0, where a0 is the Bohr radius, given
1 𝑎 +0,005𝑎0 2
Probability = 4 (𝑎 )3 ∫𝑎 0 𝑒 −2𝑟/𝑎0 𝑟 dr
0 0−0,005𝑎0

Temukan kemungkinan menemukan elektron dalam keadaan 1s atom hidrogen pada 𝑟 =

𝑎0 dalam rentang 𝑎0 ± 0.005 𝑎0 , dimana 𝑎0 adalah radius Bohr, diberikan
𝑎0 +0.005𝑎0
1 3
Kemungkinan = 4 ( ) ∫ 𝑒 −2𝑟/𝑎0 𝑟 2 𝑑𝑟
𝑎0
𝑎0 −0.005𝑎0

Jawab : 0,0063

NAMA : NURUL FADILLAH

NIM :F1C118063
11. Find the expectation value (x) for an electron in the 1s-state of the hydrogen atom,
given that
1 ∞ 3
(x) = 4(𝑎 )3 ∫0 𝑒 −2𝑟/𝑎0 𝑟 dr
𝑜

∞
1 3
(𝑥) = 4 ( ) ∫ 𝑒 −2𝑟/𝑎0 𝑟 3 𝑑𝑟
𝑎0
0
3
1 3!
= 4( ) 𝑥
𝑎0 2 4
(𝑎 )
0
4 6
= 3𝑥
𝑎0 16
𝑎04
4 3𝑎04
= 𝑥
𝑎0 3 8
12𝑎04
=
8𝑎03
3
= 𝑎0
2
NAMA : NUR INTAN
NIM : F1C118032

12. The differential volume element in cylindrical coordinates is dV = r d𝜃 dr dz. Show

that if r goes from 0 to r, 𝜃 from 0 to 2π, and z from 0 to h, the volume of a cylinder is
V = πr2h
Dik : 𝑑𝑉 = 𝑟 𝑑𝜃 𝑑𝑟 𝑑𝑧
r = 0 sampai r
𝜃 = 0 sampai 2𝜋
z = 0 sampai h
Dit : persamaan V ?
𝑟 2𝜋 ℎ
Jawab: ∫ 𝑑 = ∫0 𝑟 𝑑𝑟 ∫0 𝑑𝜃 ∫0 𝑑𝑧
1 2 𝑟
𝑣 = [ 𝑟 ] [𝜃]2𝜋 ℎ
0 [𝑧]0
2 0
1
𝑣 = 𝑟 2 𝑥 2𝜋 𝑥 ℎ
2
𝑣 = 𝑟 2 𝜋ℎ