Safety data sheet

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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A
(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019

1. Substance/preparation and manufacturer/supplier identification

ELASTOPAN* CS 9530 C-A

Recommended use: polyurethane component

Manufacturer/supplier:
BASF Polyurethanes GmbH
Postfach 1140
49440 Lemfoerde, GERMANY
Telephone: +49 5443 12-2121
Telefax number: +49 5443 12-2090
E-mail address: Product-Safety-Polyurethanes@basf.com

Emergency information:
International emergency number:
Telephone: +49 180 2273-112

2. Hazard identification

Classification of the substance and mixture:

Serious eye damage/eye irritation: Cat. 2A

Label elements and precautionary statement:

Pictogram:

Signal Word:
Warning
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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A

(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019
Hazard Statement:
H319 Causes serious eye irritation.

Precautionary Statements (Prevention):

P264 Wash with plenty of water and soap thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face
protection.

Precautionary Statements (Response):

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/attention.

Other hazards which do not result in classification:

See section 12 - Results of PBT and vPvB assessment.

3. Composition/information on ingredients
Chemical nature

Preparation based on: polyol, catalyst, additives

Hazardous ingredients

Diethanolamine
Content (W/W): >= 1 % - < 3 % Acute Tox.: Cat. 4 (oral)
CAS Number: 111-42-2 Skin Corr./Irrit.: Cat. 2
Eye Dam./Irrit.: Cat. 1
Repr.: Cat. 2 (fertility, unborn child)
STOT RE (Blood, Liver, Kidney, Central
nervous system): Cat. 2 (oral)

4. First-Aid Measures

General advice:
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Note to physician:
Symptoms: Eye irritation
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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A

(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019
Hazards: Symptoms can appear later.
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

5. Fire-Fighting Measures

Suitable extinguishing media:

water spray, dry powder, foam, carbon dioxide

Specific hazards:
carbon monoxide, carbon dioxide, nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire.

Special protective equipment:

Wear a self-contained breathing apparatus.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

6. Accidental Release Measures

Personal precautions:
Use personal protective clothing.

Environmental precautions:
Do not empty into drains. Do not discharge into the subsoil/soil.

Methods for cleaning up or taking up:

For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of contaminated material as prescribed.

Additional information: High risk of slipping due to leakage/spillage of product.

7. Handling and Storage

Handling
Ensure thorough ventilation of stores and work areas.

Protection against fire and explosion:

No special precautions necessary.

Storage
Segregate from foods and animal feeds. Segregate from acids. Segregate from oxidants.

Suitable materials for containers: Carbon steel (Iron), High density polyethylene (HDPE), Low
density polyethylene (LDPE), tinned carbon steel (Tinplate), Stainless steel 1.4301 (V2)
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A

(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019

8. Exposure controls and personal protection

Components with occupational exposure limits

2,2'-iminodiethanol, 111-42-2;
TWA value 1 mg/m3 (ACGIHTLV), Inhalable fraction and vapor
Skin Designation (ACGIHTLV), Inhalable fraction and vapor
The substance can be absorbed through the skin.

Personal protective equipment

Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Particle filter with medium efficiency for solid
and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)

Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures:

Wearing of closed work clothing is required additionally to the stated personal protection equipment.
When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at
the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied.

9. Physical and Chemical Properties

Form: liquid
Colour: yellowish
Odour: amine-like
Odour threshold: not applicable

pH value: 7-9
(20 °C)

solidification temperature: < 0 °C

Boiling point: > 140 °C
(1,013 hPa)

Flash point: > 110 °C (DIN 51758)

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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A

(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019
Evaporation rate:
Value can be approximated from
Henry's Law Constant or vapor
pressure.

Flammability (solid/gas): not flammable (derived from flash point)

Lower explosion limit:
For liquids not relevant for
classification and labelling., The
lower explosion point may be 5 - 15
°C below the flash point.
Upper explosion limit:
For liquids not relevant for
classification and labelling.
Ignition temperature: > 250 °C

Thermal decomposition: No decomposition if stored and

handled as prescribed/indicated.
Explosion hazard: not explosive
Fire promoting properties: not fire-propagating

Vapour pressure: 10 mbar

(20 °C)

Density: > 1.0 g/cm3 (DIN 51757)

(20 °C)
Relative density: > 1.0
(20 °C)
Relative vapour density (air):
not applicable

Solubility in water: partly soluble

Miscibility with water:
partly miscible
Partitioning coefficient n-octanol/water (log Pow):
not applicable for mixtures, Study
scientifically not justified.

Viscosity, dynamic:
not determined

Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.

10. Stability and Reactivity

Conditions to avoid:
Temperature: < 0 °C

Thermal decomposition: No decomposition if stored and handled as

prescribed/indicated.
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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A

(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019
Substances to avoid:
acids, oxidizing agents, isocyanates

Corrosion to metals: No corrosive effect on metal.

Hazardous reactions:
No hazardous reactions if stored and handled as prescribed/indicated.
The product is chemically stable.

No hazardous decomposition products if stored and handled as prescribed/indicated.

11. Toxicological Information

Acute toxicity

Assessment of acute toxicity:

Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. Virtually nontoxic after a
single ingestion.

Information on: Diethanolamine

Experimental/calculated data:
LD50 rat (oral): approx. 1,600 mg/kg (BASF-Test)
----------------------------------

Information on: Diethanolamine

Experimental/calculated data:
rat (by inhalation): 8 h (BASF-Test)
Inhalation-risk test (IRT): No mortality within 8 hours as shown in animal studies. The inhalation of a
highly saturated vapor-air mixture represents no acute hazard.
----------------------------------

Information on: Diethanolamine

Experimental/calculated data:
LD50 rabbit (dermal): 13,079 mg/kg
----------------------------------

Irritation

Assessment of irritating effects:

Eye contact causes irritation. Not irritating to the skin.

Information on: Diethanolamine

Experimental/calculated data:
Serious eye damage/irritation rabbit: irreversible damage (BASF-Test)
----------------------------------

Respiratory/Skin sensitization

Assessment of sensitization:
The chemical structure does not suggest a sensitizing effect.

Information on: Diethanolamine

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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A

(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019
Experimental/calculated data:
Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406)
----------------------------------

Germ cell mutagenicity

Assessment of mutagenicity:
The chemical structure does not suggest a specific alert for such an effect.

Carcinogenicity

Assessment of carcinogenicity:
The chemical structure does not suggest a specific alert for such an effect.

Reproductive toxicity

Assessment of reproduction toxicity:

The chemical structure does not suggest a specific alert for such an effect.

Developmental toxicity

Assessment of teratogenicity:
The chemical structure does not suggest a specific alert for such an effect.

Specific target organ toxicity (single exposure):

Assessment of STOT single:

Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

Repeated dermal uptake of the substance did not cause substance-related effects. Repeated
inhalative uptake of the substance did not cause substance-related effects. Repeated oral uptake of
the substance did not cause substance-related effects.

Aspiration hazard

No aspiration hazard expected.

Other relevant toxicity information

The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.

12. Ecological Information

Ecotoxicity

Assessment of aquatic toxicity:

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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A

(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019
There is a high probability that the product is not acutely harmful to aquatic organisms.

Information on: Diethanolamine

Toxicity to fish:
LC50 (96 h) 460 mg/l, Oncorhynchus mykiss (Fish test acute, static)
Nominal values (confirmed by concentration control analytics)

LC50 (96 h) 1,460 mg/l, Pimephales promelas (Fish test acute, static)
Nominal concentration. Literature data.
----------------------------------

Mobility

Assessment transport between environmental compartments:

Adsorption to solid soil phase is not expected.

Persistence and degradability

Assessment biodegradation and elimination (H2O):

Poorly biodegradable.

Elimination information:
Poorly biodegradable.

Bioaccumulation potential

Assessment bioaccumulation potential:

Does not significantly accumulate in organisms.

Other adverse effects

Adsorbable organically-bound halogen (AOX):

This product contains no organically-bound halogen.

Additional information

Other ecotoxicological advice:

Do not allow to enter soil, waterways or waste water channels. Inhibition of degradation activity in
activated sludge is not to be anticipated during correct introduction of low concentrations. The
product has not been tested. The statement has been derived from substances/products of a similar
structure or composition.

13. Disposal Considerations

Incinerate in suitable incineration plant, observing local authority regulations.

Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for
recycling after being thoroughly cleaned.
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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A

(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019
14. Transport Information
Domestic transport:
Not classified as a dangerous good under transport regulations

Sea transport
IMDG
Not classified as a dangerous good under transport regulations

Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations

15. Regulatory Information

For the classification of the mixture the following methods have been applied: extrapolation on the
concentration levels of the hazardous substances, on basis of test results and after evaluation of
experts.
The methodologies used are mentioned at the respective test results.

Other regulations

If it is intended to use materials for the manufacture of consumer goods (e. g. products which will
come into contact with foodstuffs or with the skin, toys) or medical products, national and
international regulations have to be observed. Where no regulations exist, consumer goods or
medical products must at least comply with European legislation. We recommend contacting our
Sales and our Product Safety departments.

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

16. Other Information

For the classification of the mixture the following methods have been applied: extrapolation on the
concentration levels of the hazardous substances, on basis of test results and after evaluation of
experts.
The methodologies used are mentioned at the respective test results.

Vertical lines in the left hand margin indicate an amendment from the previous version.
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BASF Safety data sheet
Date / Revised: 15.07.2019 Version: 5.0
Product: ELASTOPAN* CS 9530 C-A

(30187478/SDS_GEN_VN/EN)
Date of print 16.07.2019
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. This safety data sheet is neither a
Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification
agreement. Identified uses in this safety data sheet do neither represent an agreement on the
corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the
responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.