Please refer to the relevant chapter for more details. © IBID Press 2007
CHAPTER 4 BONDING
Please refer to the relevant chapter for more details. © IBID Press 2007
CHAPTER 4 BONDING
b) This would predict that one of the nitrogen oxygen bonds would be shorter
than the other two. Also with the charge all on one oxygen it is unlikely that it
would have the precise trigonal planar symmetry found.
c) The bonding is better described by considering the nitrogen and oxygen atoms
to be joined by three σ-bonds and for there also to be a delocalised π-bond that
connects all four atoms.
d) The σ-bonds would be formed between sp2 hybrid orbitals on the oxygen and
nitrogen atoms. The delocalised π-bond would be the result of the interaction of
the p-orbitals, on all of the atoms, that are at right angles to the sp2 hybrid
orbitals.
e) The bond between the nitrogen and the oxygens would be equivalent to 1 1--3-
1
bonds and each oxygen atom would carry a charge of – ---
3
f) It would be expected that the N–O bond length in the nitrate ion
1
(bond order 1 --3- ) would be longer than the N=O bond in nitric acid,
Please refer to the relevant chapter for more details. © IBID Press 2007
CHAPTER 4 BONDING
Please refer to the relevant chapter for more details. © IBID Press 2007
CHAPTER 4 BONDING
11. Ethanoic acid dissolves in water because its -OH group can form hydrogen bonds
to the water. Sodium ethanoate dissolves in water because it is an ionic solid and
the strong hydration interaction between the ions and the polar water molecules
enables the strong forces between the ions in the solid to be overcome. Ethyl
ethanoate has two hydrocarbon regions which cannot bond to the water and these
would disrupt the hydrogen bonding between water molecules if it were to
dissolve, hence it is not soluble.
12. Going from left to right, sodium oxide has an ionic structure. There are quite
strong electrostatic forces between the ions hence the melting point is quite high.
In magnesium oxide, the bonding is also ionic, but the fact that there are equal
numbers of the two ions and that these have double charges results in a very high
melting point. Aluminium oxide and silicon dioxide have a giant covalent
structures so that to melt them involves overcoming strong covalent bonds,
resulting in a high melting point. The remaining oxides, those of phosphorus,
sulfur and chlorine, have a molecular covalent structure, so that melting them
only depends on overcoming relatively weaker intermolecular forces. The lower
the molar mass of the compound, the lower the melting point and this accounts
for the decrease in melting point of these from phosphorus, through sulfur to
chlorine.
Please refer to the relevant chapter for more details. © IBID Press 2007