PAPRE NO.

Paper Chemistry Part- I(2019)

Question No.1: Select the suitable answer
(i) The volume occupied by 1.4g of N₂ at STP is
(a) 2.24dm³ (b) 22.4dm³ (c) 1.12dm³ (d) 112cm³
(ii) In combustion analysis, water vapours are absorbed by
(a) 50% KOH (b) Mg(ClO₄)2 (c) 50% NaOH (d) MgCl₂
(iii) Which one of the following substances does not undergo sublimation
(a) Naphthalene (b) Iodine (c) KMnO₄ (d) NH₄Cl
(iv) Which gas will diffuse more rapidly?
(a) CO₂ (b) HCl (c) NH₃ (d) SO₂
(v) Which of the following is a Pseudo Solid?
(a) CaF2 (b) Glass (c) NaCl (d) All of these
(vi) Ice occupies more space than liquid water
(a) 9% (b) 10% (c) 11% (d) 12%
(vii) Properties of waves are
(a) wave lenght (b) Wave number (c) Frequency (d) All of these
(viii) When 6d orbital is complete, the entering electron goes into
(a) 7f (b) 7s (c) 7p (d) 7d
(ix) Which of the following molecules has coordinate covalent bond?
(a) NH₄Cl (b) NaCl (c) HCl (d) AlCl₃
(x) Measurement of the degree of polarity is
(a) Electron affinity (b) Ionic character (c) Ionization energy (d) All of these
(xi) The total heat contents of a system is called
(a) Enthalpy (b) Temperature (c) Internal energy (d) All of these
(xii) Law of mass action was given by C.M Guldberg and P Waage in
(a) 1564 (b) 1664 (c) 1164 (d) 1864
(xiii) Equilibrium state is achieved quickly by addition of
(a) Reactants (b) Acid (c) Base (d) Catalyst
(xiv) Aqueous Solution of Na₂SO₄ will be
(a) Basic (b) Acidic (c) Neutral (d) None
(xv) The electode potential of SHE is
(a) 0.1 V (b) 0.20V (c) 0.02 V (d) 0.0 Volts
(xvi) The electrolyte used in fuel cells is
(a) NaOH (b) Ca(OH)₂ (c) PbO₂ (d) KOH
(xvii) A substance that promotes the activity of a catalyst is called
(a) Promoter (b) Inhibitor (c) Radiator (d) Auto catalyst

Prof. Iftikhar Hussain

Govt. Dyal Singh College, Lahore
E. Mail: iftikharhussain1084@gmail.com
PAPRE NO.1

Paper Chemistry Part- I (2019) Section -I

Question No. 2: Attempt any Eight short questions: (8x2)
(i) Define Stoichiometry. Write its assumptions.
(ii) Why actual yield is less than theoretical yield?
(iii) What is limiting reactant? How it helps to control the amount of product?
(iv) What are main features of an ideal solution for crystallization of compound?
(v) (v) Why Rf value is always less than one?
(vi) State Boyle’ law. Give its mathematical expression?
(vii) What is Absolute Zero? Write its value.
(viii) Define Joule Thomson’ effect. Give its significance?
(ix) Light gases diffuse rapidly than heavier gases. Give reason
(x) Why colligative properties are obeyed when the solutions are dilute?
(xi) What is conjugate solution and critical solution temperature?
(xii) Why NaCl and KNO3 are used to form freezing mixture?
Question No.3: Attempt any Eight short questions: (8x2)
(i) Why ice floats on water?
(ii) Why boiling point of H₂O is greater than that of HF?
(iii) Why sodium is softer than copper but both are very good conductor?
(iv) Define anisotropy. Give example.
(v) How cathode says are termed as material particles with negative charge on them?
(vi) What is function of Azimuthal quantum number?
(vii) What is Moseley’ law. Write mathematical form.
(viii) Differentiate between Stark effect and Zeeman effect?
(ix) What are buffer solutions? Why do we need buffers?
(x) What do you mean by ionization constant of acids?
(xi) What are auto and negative catalysis
(xii) What is rate of reaction? Write its unit
Question No. 4: Attempt any six short questions: (6x2)
(i) Explain that ionization energy is the index of metallic character?
(ii) Why 2nd ionization energy value is greater than that of 1st value?
(iii) Why lone pair occupies more space than bond pair?
(iv) Why He₂ molecule does not exist? Discuss by M.O.T
(v) State Hess’ law. Give its mathematical form.
(vi) State first law of Thermodynamics. Give its mathematical form..
(vii) What is function of salt bridge?
(viii) What is SHE? What is its use?
(ix) Na and K can displace hydrogen from acids but Pt, Pd and Cu cannot?

Prof. Iftikhar Hussain

Govt. Dyal Singh College, Lahore
E. Mail: iftikharhussain1084@gmail.com
PAPRE NO.1

Section -II
Note: Attempt any Three question. (3x8)
No. 5: (a) what is vapour pressure? Describe its measurement by Manometric method? (4)
(b) What is combustion analysis? How is it used to calculate the %age of carbon, hydrogen and oxygen?

Q. No.6: (a)Derive the equation for the radius of nth orbit of H-atom by Bohr’ Model? (4)
3
(b) Calculate the mass of 1 dm of NH3 gas at 30 °C and 1000 mmHg pressure, considering that NH3 is
behaving an ideal gas. (4)

Q. No.7 :(a) Write down the postulates of VSEPR theory.Discuss the structure of NH3 and BF3 by VSEPR
theory. (4)
(b)What is Lattice energy? How does Born-Haber Cycle help to calculate the lattic energy of NaCl.

Q. No. 8: (a) The solubility of PbF2 in water at 25oC is 0.64 g dm-3. Calculate Ksp of PbF2 ?
(b) What is Enzyme Catalysis? Write any four characteristics of enzyme catalysis. (4).

Q. No. 9:(a) Give the graphical explanation for elevation of boiling point of solution (4)
(b) ) Balance the following equation by oxidation number method.
K₂Cr₂O7 +HCl → KCl+CrCl₃ +Cl₂+H₂O (4)

Prof. Iftikhar Hussain

Govt. Dyal Singh College, Lahore
E. Mail: iftikharhussain1084@gmail.com