Relative Volatility
Dalam larutan biner relative volatility didefinisikan
sebagai perbandingan konsentrasi A dan B dalam
fase uap dibanding perbandingan konsentrasi A
dan B dalam fase cairan.
y A / yB PA
atau
x A / xB PB
x A xB 1 x A
yA
y A yB 1 1 ( 1) x A
Q1 Q2
A,B
V1 , yA1 , Hv1
A,B
A,B A,B
A,B
to , Lo , tbp , Lo , xA0 t1 , Lo
xA0, Ho
A,B
L1 , xA1 , HL1
Lo = L1 + V1 yA1 > xAo > xA1
Lo(xAo) = L1 (xA1) + V1(yA1)
Lo Ho + Q1 + Q2 = L1 HL1 + V1Hv1
Q1 T vs xA tA
bubble point
CAIR curve
t0 (dingin)
a
UAP
λB CAIR-UAP
Saturated vapor
λAB
H t1 t2
Enthalpy (Btu/lb)
Tie line t3
t1 t4 λA
t2
t3
t4
Saturated liquid
CAIR
0 x x y
1.0
xA , yA
DIAGRAM ENTHALPY- KOMPOSISI
UAP
CAIR-UAP
Saturated vapor
Tie line t1
H b
H2 Tie line
Enthalpy (Btu/lb)
Q2 to
H1
Q1
Ho to Saturated liquid
a
CAIR
0 xA xAo yA y
1.0
xA , yA
V1
a
H
HM M
Q2 b
L1
Hbp
Q1
Ho Lo cair jenuh
y
y1
V1/L1 = b/a
x1 xo x
2
KURVE KESETIMBANGAN CAIR- UAP
3
y=x
y
AZEOTROP
2
y
y 1
y
x x x
x
3 2 1
KESETIMBANGAN UAP DAN CAIRAN (tie line)
KURVE
TIE LINE SETIMBANG x-y
KURVE
PA, PB, P SETIMBANG x-y
P = pA + pB
= XA PA + XB PB
= XA PA + (1 – XA) PB
= XA PA + PB – XA PB
= XA (PA – PB) + PB
XA = (P – PB) / (PA – PB)
yA = mol A / mol total
= pA / P
= XA PA / P
yA = (PA / P) XA
pA, pB = tekanan parsiel komponen A, B
(PA, PB) = tekanan uap murni komponen A, B
P = tekanan total
XA = fraksi komponen A dalam cairan
yA = fraksi komponen A dalam uap
TIE LINE KURVE SEIMBANG
V1
V2
H Vn
L1
L2
Ln
cair jenuh
yn
y
y2
y1
x1 x2 x xn
KURVE SEIMBANG TIE LINE (posisi V & L)
V1
V2
H Vn
L1
L2
Ln
cair jenuh
yn
y
y2
y1
x1 x2 x xn
L1 V1
L2 V2
dew point curve
T bubble point curve
Vn
Ln
yn
y
y2
y1
x1 x1 x xn
P1
P2
T y P1
P2
P1 > P2
x, y x
P2
P2
.
T
T P1 m2
M1
P1
m1
x, y x, y
. P2 P2
P1
y y
P1
(c)
x x