1.

How many right angles are there in XeF6

a) 4 b) 8 c) 12 d) 0

2. Chemical reactions of sulphuric acid results in

a) High volatility b) Weak acidic character c) Low volatility d) both a and b

3. 0.1gm mole of urea is dissolved in 100gm of water. The concentration of the solution is .

a) 1m b) 0.01M c) 0.01m d) 1M

4. ----------- of a reaction cannot be determined experimentally

a) Order b) Rate c) rate constant d) molecularity

5. At anode in the electrolysis of fused sodium chloride

a) Na+ is oxidized b) Cl- is oxidized c) Cl- is reduced d) Na+ is reduced

6. Which statement is correct about physical adsorption

a) It is highly specific b) It is unimolecular layer adsorption.

c) It depends on critical temperature of adsorbate.

d) It is irreversible.

7. In a first order reaction, 0.16 moles of reactant decreases to 0.02 moles in 144minutes, its
half life is

a) 24min b) 12 min c) 72 min d) 48 min

8. which of the following is/are independent of temperature?

a) Molality b) mole fraction c) Weight percentage d) all of these

9. Which is the second most abundant metal in the earth crust?

a) Aluminum b) Copper c) Zinc d) Iron

11. Two liquids A and B form non-ideal solution which shows a minimum boiling point. Can
the two liquids be completely separated by fractional distillation. What will be the change
in temperature on mixing A and B?

12. What is lanthanide contraction?

13. What is meant by critical micelle concentration?

14. Why physical adsorption is multilayered?

15. Why Zinc, Cadmium, mercury are not considered as transition elements?

SECTION B

21. (i) Name the device used to measure an unknown resistance accurately

(ii) What are fuel cells?

22. (a) Why is Cu+2 is more stable than Cu+?

(b) Why Ti+3 is coloured where as Sc+3 colourless?

23. What is the effect of reversibility and temperature on physical and chemical adsorption?

24.State Henry's law, write two applications.

25. Calculate the mass of ascorbic acid (C6H8O6) to be dissolved in 75gm of acetic acid to
lower its melting point by 1.50C, Given Kf = 3.9KKg/mol-1

(Or)

Show that t99.9% is 10 times t1/2 in a first order equation.

26. How much charge is required for the following reductions:

(a) 1 mole of Al+3 to Al?

(b) 1 mole of Cu+2 to Cu?

(Or)

The conductivity of 0.2M of KCl at 298k is 0.0248SCm-1 . Calculate its molar conductivity.

27. What is catalyst? How does it influence the rate of reaction?

SECTION C

28. An electrolyte AB 50% ionized in aqueous solution. Calculate the freezing point of 1
molal aqueous solution. Kf=1.86 K kg/mol

(Or)

Calculate the molality of sulphuric acid solution in which mole fraction of water is 0.8.
 30. The decomposition of ammonia on platinum surface is zero order reaction. If rate
constant is 4x10-3 MS-1 , how long it will take to reduce the initial concentration of
ammonia from 0.1M to 0.064M.

31. Explain how the phenomenon of adsorption finds application in each of the following
processes:

(a) production of vacuum (b) Heterogeneous catalysis (c) Froth flotation process

(Or)

What are the characteristic of the following colloids? Give one example each

(a) Multimolecular colloids (b) Lyophobic sols (c) Emulsions

32. (i) Name the method used for the refining of Zirconium

(ii) Define roasting with example.

(iii) Name the depressant used in the separation of sulphide ores in froth flotation process.

33. (i) Which form of sulphur shows paramagnetic behavior?

(ii) Why halogens are coloured?

(iii) write the order of enthalpy of dissociation in halogens ?

(Or)

Write the structures of the following :

a) H2SO3 b) HOCl c) H2S2O8

34.(a) List any four factors on which the colligative properties of a solution depend.

(b) Calculate the boiling point of one molar aqueous solution (density 1.06gm/lit) of KBr

given Kb for H2O = 0.52KKg/mol

( Or )

A solution contains 15gm urea per liter of solution in water has the same osmotic pressure as a
solution of glucose in water. calculate the mass of glucose present in one liter of its
solution.

SECTION D

35. (a) 30gm of urea is dissolved in 846 gm of water. calculate the vapour pressure of water for
this solution if vapour pressure of pure water at 298K is 23.8Hg.
 (b) Write two difference between ideal and non ideal solution.

Or

(a) calculate the mole fraction of ethylene glycol (C2H6O2) in a solution containing 20% of C2H6O2
by mass.

(b) Calculate the molarity of solution containing 5gm of NaOH in 450ml solution.

(c) Calculate the molality of 205gm of ethanoic acid in 75gm of benzene.

36. (a)The rate of reaction quadruples when the temperature changes from 293K to 313K.
Calculate the energy of activation of the reaction assuming that it does not change with
temperature.

(b) The decomposition of ammonia on platinum surface is a zero order reaction what are the
rates of production of N2 and H2 if K= 2.5x10-4 .

(Or)

(a)In a reaction between A and B, the initial rate of reaction was measured for different initial
concentration of A and B given below

A moles/liter 0.2 0.2 0.4

A moles/liter 0.3 0.1 0.5
R0moles/liter 5.07x10-5 5.07x10-5 1.43x10-4

What is order of reaction with respect A and B.

(b)A first order reaction takes 40minutes for 30% decomposition. Calculate its t 1/2 .