Lampiran Panas Intan

LAMPIRAN 2
PERHITUNGAN NERACA PANAS

Basis : 1 Hari Operasi
Satuan Operasi : kg/h
Temperatur Basis : 250C ( 298 K )
Neraca panas ini menggunakan rumus-rumus perhitungan sebagai berikut:
Persamaan untuk menghitung kapasitas panas (Reklaitis, 1983)
Cp = a + bT + cT2 + dT3
Perhitungan panas :
Jika harga Cp maka = m x Cp x ΔT
Tabel . Kapasitas Panas Gas, Cpg = a + bT + cT2 + dT3 + eT4 [kJ/kmol.K]
Komponen A B c d E
S 2.462.E+01 -5.040.E-03 2.424.E-06 -4.220.E-10 2.518.E-14
CH4 3.99E+01 -3.996.E-02 1.918.E-04 -1.530.E-07 3.932.E-11
CS2 2.046.E+01 1.230E-01 1.618.E-04 1.020.E-07 -2.444.E-11
H2S 3.4523.E+01 -1.765.E-02 6.767.E-05 -5.325.E-08 1.407.E-11
N2 2.934.E+01 -3.540E-03 1.008.E-05 -4.312.E-09 2.594.E-13
CO2 2.744.E+01 4.232E-02 -1.956.E-05 3.997.E-09 -2.987.E-13
C 2.107E+01 -7.912E-04 5.090.E-07 -6.913.E-11 -2.702.E-15
H2O 3.39E+01 -8.419.E-03 2.991.E-05 -1.783.E-08 3.693.E-12
-3.0828E-
Oil -64.055 7.92E-01 -6.630E-04 2.4423E-07 11
(Yaws, 2005 & Reklaitis,1983)

Tabel . Kapasitas Panas Liquid, Cpl = a + bT + cT2 + dT3 [kJ/kmol.K]
Komponen A B c d
S 1.081E+02 -2.374E-01 2.273E-04 -5.996E-08
CS2 3.99E+01 2.36E-01 -7.21E-04 1.0443E-06
H2S 2.182E+01 7.74E-01 -4.20E-03 7.38677E-06
CO2 -3.981E+03 5.251E+01 -2.271E-01 3.287E-04
Oil -1.9242E+02 2.7211E+00 -6.1900E-03 5.1736E-06
H2O 9.2053E+01 -3.9953E-02 -2.1103E-04 5.3469E-07
(Yaws, 2005 & Reklaitis,1983)
148
Tabel. Panas Laten
Komponen ∆HVL (kJ/kmol) Normal BP (K)

CH4 8.179,5 111,671
CS2 26.334,4 319,400
H2S 18.678,3 212,820
H2O 40.656,2 373,161
Sx 9.875,2 473,150
(Reklaitis,1983)
Tabel . Panas Reaksi Pembentukan
Komponen ∆H°f (kcal/mol)

CH4 –17,89
CS2 27,98
H2S –4,82
H2O -57,80
(Reklaitis,1983)
Data Air Pemanas dan Air pendingin yang digunakan
T (°C) H (kJ/kg) λ (kJ/kg)
Air 29 121,5 -
33 138,2 -
Saturated Steam 143,6 - 2133,0
184,1 - 1998,5
(Reklaitis,1983)
149
1.1 Neraca Panas Furnace (A-200)
Q1
Q3
FURNACE
Q2
Keterangan:
Q1 : Aliran panas sulfur masuk
Q2 : Aliran panas metana masuk
Q3 : Aliran panas Produk
Panas bahan masuk
1. Airan panas sulfur
(Q1) Kondisi operasi :
a. Suhu reference 250C/298K
b. Suhu sulfur masuk = 435,21°C = 708,210 K
Massa sulfur masuk = 135.622,436
Imp (C) = 13,564
2. Aliran panas metana
(Q2) Kondisi operasi :
a. Suhu reference = 25°C = 298 K
b. Suhu masuk metana = 238,80°C = 511,80 K
Imp (CO2) = 547,704
Imp (N2) = 365,136
Panas bahan masuk
Cpg metana = a + bT + cT2 + dT3 + eT4
Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Q1 S2 135.622,436 0,1217 708,210 6.768.458,904
C 13,564 0,4128 708,210 2.296,675
Q2 CH4 14.301,160 0,7751 511,800 2.370.030,261
CO2 547,704 0,2415 511,800 28.278,162
N2 365,136 0,25326 511,800 19.717,611
Total 9.188.781,612
150
Panas bahan keluar : ( T = 923 K )

Q3 CS2 64.873,637 1,0507 923,000 42.599.735,333
H2S 58.044,833 0,3107 923,000 11.270.459,054
S2 26.361,574 0,0811 923,000 1.335.748,408
CH4 643,552 1,1151 923000 448.533,270
C 13,564 0,4123 923,000 3.495,406
CO2 547,704 0,2864 923,000 98.038,862
N2 365,136 0,2683 923,000 61.236,656
Total 55.817.246,988
Menentukan Panas Reaksi

Reaksi yang berlangsung : CH4(g) + 2S2(g) CS2(g) +2H2S(g)
∆Hf pada suhu = 298 K (250C)
CH4 bereaksi = 853,600 kmoll
∆Hf CH4(g) = -17,890 kkal/kmol
∆Hf S2(g) = 30,740 kkal/kmol
∆Hf CS2(g) = -27,980 kkal/kmol
∆Hf H2S(g) = -4,820 kkal/kmol
∆Hr = {(∆Hf CS2 + ∆Hf H2S) - (∆Hf CH4 + ∆Hf S2)}
= {(- 27,980 x 853,600 + ( 2x-4,820) x 853,600) – (-17,890 x 853,600 + (2x30,740) x
853,600)}
= - 69.320,856 kkal
Q yang dibutuhkan = 46.559.144,520 kkal
Menghitung kebutuhan bahan bakar
dQ/dT = (Qout - Qin) + Panas reaksi total
dQ/dT = (55.817.246,988 -9.188.781,612) +(- 69.320,856)
= 46.559.144,520 kkal
I kkal = 4,2 kj
46.559.144,520 kkal =195.548.406,982 KJ
Nilai bakar natural gas = 425.000 kJ/kg
Densitas natural gas = 0.7 kg/m3
Massa natural gas yang dibutuhkan :
M = 195.548.406,982 Kj
425.000 kJ/kg
= 460,114 kg
Volume natural gas yang dibutuhkan :
151
V = 460,114 kg
0.7 kg/m3
= 657,306 m3
1.2 Neraca Panas pada Reaktor (R-202)
Q3 Q4
REAKTOR
Keterangan :
Q3 : Panas umpan reaktor dari Furnace
Q4 : Panas hasil reaksi / keluaran reaktor
Suhu Reference = 250C = 298 k
Panas bahan masuk

Q3 CS2 64.873,637 1,0507 923,000 42.599.735,333
H2S 58.044,833 0,3107 923,000 11.270.459,054
S2 26.361,574 0,0811 923,000 1.335.748,408
CH4 643,552 1,1151 923,000 448.533,270
C 13,564 0,4123 923,000 3.495,406
CO2 547,704 0,2864 923,000 98.038,862
N2 365,136 0,2683 923,000 61.236,656
Total 55.817.246,988
Panas bahan Keluar

Q4 CS2 67.915,226 1,0130 903,00 41.622.558,179
H2S 60.766,255 0,3085 903,00 11.340.784,655
S2 21.238,898 0,0812 903,00 1.043.269,927
CH4 3,218 1,1010 903,00 2.143,375
C 13,564 0,4123 903,00 3.383,693
CO2 547,704 0,2847 903,00 94.337,056
N2 365,136 0,2675 903,00 59.093,679
Total 54.165.570,565
152
Menentukan Panas Reaksi
Reaksi yang berlangsung : CH4(g) + 2S2(g) CS2(g) +2H2S(g)
∆Hf pada suhu = 298 K (250C)
Konversi reaksi = 99,5%
Mol CH4 Bereaksi = 40,021 kmol
∆Hf CH4(g) = -17,890 kkal/kmol
∆Hf S2(g) = 30,740 kkal/kmol
∆Hf CS2(g) = -27,980 kkal/kmol
∆Hf H2S(g) = -4,820 kkal/kmol
∆Hr = {(∆Hf CS2 + ∆Hf H2S) - (∆Hf CH4 + ∆Hf S2)}
= {(- 27,980 x 40,021 + ( 2x-4,820) x 40,021) – (-17,890 x 40,021 + (2x30,740) x 40,021)}
= -388.666,763 kkal
Q Yang hilang = 2.040.343,166 kkal
2. Proses Sulfur Removal
2.1 Neraca Panas pada Sulfur Condenser (H-207)
Q4 Q5
Sulfur Condenser (H-
207)
Keterangan :
Q4 : Panas masuk ke Sulfur Condenser dari Reaktor
Q5 : Panas keluar Sulfur Condenser / input Recycle Sulfur Vessel
Panas bahan masuk
Q4 CS2 67.915,226 1,0130 903,00 41.622.558,179
H2S 60.766,255 0,3085 903,00 11.340.784,655
S2 21.238,898 0,0812 903,00 1.043.269,927
CH4 3,218 1,1010 903,00 2.143,375
C 13,564 0,4123 903,00 3.383,693
CO2 547,704 0,2847 903,00 94.337,056
N2 365,136 0,2675 903,00 59.093,679
Total 54.165.570,565
153
Panas bahan keluar
Uap

Q5 CS2 67.915,226 0,3653 448,00 3.721.127,605
H2S 60.766,255 0,2527 448,00 2.303.665,265
S2 4.247,780 0,0851 448,00 54.253,044
CH4 3,218 0,7220 448,00 348,502
C 13,564 0,4142 448,00 842,719
CO2 547,704 0,2324 448,00 19.094,821
N2 365,136 0,2508 448,00 13.736,413
Total 6.113.068,371
Liquid
Aliran Komponen massa (kg) Cp (kkal/kgoK) Suhu (oK) Q (kkal)

Q5 S 16.991,119 0,1564 448,00 398.606,990
Total 398.606,990
Total panas keluar sulfur condenser

Q out = Q uap + Q liquid
= 6.113.068,371 + 398.606,990 = 6.511.675,361 kkal
Panas pengembunan uap
Komponen massa (kg) Hv kkal/kg Q (kkal)

S 21.238,899 148,128 3.146.075,600
Total 3.146.075,600
Panas masuk sulfur condenser = Q masuk + Q HV
= 54.165.570,565 + 3.146.075,600 = 57.311.646,165 kkal
Panas yang diserap pendingin = 57.311.646,165 - 6.511.675,361 = 50.799.970,804 kkal
Menentukan Jumlah Air Pendingin
Media pendingin yang digunakan adalah air yang masuk pada suhu =290C dan keluar pada suhu
143,60C
𝑑𝑄
= Q out –Q in
𝑑𝑇
= 6.511.675,361 + 57.311.646,165 = -50.799.970,804 kkal

I kkal = 4,2 kj
-50.799.970,804 kkal = -213.359.877,377 kj
M= Q out – Q in
H (143,60C) – H (290C)
154
= - (-213.359.877,377) kj
(1.507,155 – 302,032) kj/kg
= - (-213.359.877,377) kj
1,205.12 kj/kg
= 177.044,067 kg
2.2 Neraca Panas pada Recyle Sulfur Vessel (V-270)
Q7
Q5
Recycle Sulfur Vessel
Q8
Q6
Keterangan:
Q5 : Panas keluaran Sulfur Condenser
Q8 : Panas dari hasil bawah CS2 Scrubber
Q7 : Panas fase uap dari V-270 / Umpan CS2 Scrubber
Q6 : Panas Sulfur excess
Suhu reference = 250C / 298 K
Panas bahan masuk :
Panas masuk V-270 = Q5 + Q8
Uap

Q5 CS2 67.915,226 0,3653 448,00 3.721.127,605
H2S 60.766,255 0,2527 448,00 2.303.665,265
S2 4.247,780 0,0851 448,00 54.253,044
CH4 3,218 0,7220 448,00 348,502
C 13,564 0,4142 448,00 842,719
CO2 547,704 0,2324 448,00 19.094,821
N2 365,136 0,2508 448,00 13.736,413
Total 6.113.068,371
155
Liquid

Q5 S 16.991,119 0,1564 448,00 398.606,990
Q8 S 2.548,668 0,1901 343,00 21.799,981
Total 420.406,971
Panas masuk V-270 = Q5 +Q7

= 6.113.068,371 + 420.406,971
= 6.533.475,342
Panas bahan keluar
Q7 CS2 67.915,226 0,2970 376,00 1.573.558,481
H2S 60.766,255 0,2452 376,00 1.162.205,862
S2 4.247,780 0,0860 376,00 28.500,998
CH4 3,218 0,6671 376,00 167,443
C 13,564 0,4148 376,00 438,832
CO2 547,704 0,2214 376,00 9.459,154
N2 365,136 0,2492 376,00 7.096,843
Q6 Sl 19.539,786 0,1321 376,00 201.269,578
Total 2.982.697,190
Q yang hilang = Qin – Qout

= 6.533.475,342 - 2.982.697,190
= 3.550.778,152 Kkal
2.3 Neraca Panas pada CS2 Scrubber (C-280)
Q9
C-280 QLO
Q7
q
q
Q8
156
Keterangan :
Q7 : Panas dari umpan Recycle Sulfur Vessel
Q9 : Panas fraksi atas CS2 Scrubber
Q8 : Panas fraksi bawah/sulfur cair excess
QLO : Panas dari refluk
Suhu reference = 250C = 298
Panas bahan masuk
Uap
Q7 CS2 67.915,226 0,2970 376,00 1.573.558,481
H2S 60.766,255 0,2452 376,00 1.162.205,862
S2 4.247,780 0,0860 376,00 28.500,998
CH4 3,218 0,6671 376,00 167,443
C 13,564 0,4148 376,00 438,832
CO2 547,704 0,2214 376,00 9.459,154
N2 365,136 0,2492 376,00 7.096,843
Total 2.982.697,190
Liquid/Reflus QLO

QLO CS2 41.128,000 0,2374 318,000 195.297,554
Total 195.297,554
Total panas bahan masuk = 2.982.697,190 + 195.297,554 =2.976.725,166

Panas bahan keluar
Q8 S 2.548,668 0,1901 343,00 21.799,981
Q9 H2S 60.766,255 0,2417 337,00 572.770,058
CS2 109.043,226 0,2636 337,00 1.121.010,091
S 1.699,112 0,0865 337,00 5.733,648
CH4 3,218 0,6406 337,00 80,392
CO2 547,704 0,2151 337,00 4.594,622
N2 365,136 0,2485 337,00 3.538,727
C 13,564 0,4151 337,00 219,603
Total 1.729.747,122
Panas yang hilang = Q masuk – Q keluar

= 2.976.725,166 - 1.729.747,122
= 1.246.978,044
157
2.4 Primarry CS2 Condenser (H-282)
Q9 Primarry CS2 Q10

Condenser (H-282)
Keterangan :
Q9 : Panas masuk ke Primarry CS2 Condenser dari CS2 Scrubber
Q10 : Panas keluar dari CS2 Condenser
Suhu reference = 250C/298 K
Panas bahan masuk
Q9 H2S 60.766,255 0,2417 337,00 572.770,058
CS2 109.043,226 0,2636 337,00 1.121.010,091
S 1.699,112 0,0865 337,00 5.733,648
CH4 3,218 0,6406 337,00 80,392
CO2 547,704 0,2151 337,00 4.594,622
N2 365,136 0,2485 337,00 3.538,727
C 13,564 0,4151 337,00 219,603
Total 1.729.747,122
Panas bahan keluar

Uap
Q10 H2S 60.766,255 0,2402 318,00 291.860,454
CS2 67.915,226 0,2482 318,00 337.093,133
S 1.699,112 0,0868 318,00 2.948,970
CH4 3,218 0,6287 318,00 40,461
CO2 547,704 0,2119 318,00 2.321,475
N2 365,136 0,2482 318,00 1.812,709
C 13,564 0,4153 318,00 112,666
Total 636.189,867
Liquid
Q10 CS2 41.128,000 0,2374 318.00 195.297,554
Total 195.297,554
Total panas yang keluar Primarry CS2 Condenser

Qout = Quap + Qliquid
158
= 636.189,867 kkal + 195.297,554 kkal
= 831.487,422 kkal
Panas pengembunan uap :
Komponen massa (kg) HV kkal/kg Q kkal

CS2 109.043,226 82,761 9.024.569,587
Total 9.024.569,587
Panas masuk Primary CS2 Condenser :

Q = Qmasuk + QHV
= 1.729.747,122 kkal + 9.024.569,587 kkal
= 10.732.516,729 kkal
Q dibawa pendingin = Total panas masuk – total panas keluar
= 10.732.516,729 kkal – 831.487,422 kkal
= 9.901.029,307
143,60C
𝑑𝑄
= Q out –Q in
𝑑𝑇
= 831.487,422 kkal - 10.732.516,729 kkal = -9.901.029,307 kkal

I kkal = 4,2 kj
-9.901.029,307 kkal = -41.584.323,089 kj
M= Q out – Q in
H (143,60C) – H (290C)
= - (-41.584.323,089) kj
(1.507,155 – 302,032) kj/kg
= - (-41.584.323,089) kj
1,205.12 kj/kg
= 3.450,289 kg
159
2.5 Primary CS2 Separator (V-285)
Q10
Primary CS2 Q11
Separator (V-285)
Keterangan :
Q10 : Panas masuk Primarry CS2 Separator V-285 dari Primarry CS2 Condenser
Q11 : Panas keluar CS2 Separator V-285
Suhu reference = 250C/298 K
Panas bahan masuk
Uap
Q10 H2S 60.766,255 02402 318,00 291.860,454
CS2 67.915,226 0.2482 318,00 337.093,133
S 1.699,112 0,0868 318,00 2.948,970
CH4 3,218 0,6287 318,00 40,461
CO2 547,704 0,2119 318,00 2.321,475
N2 365,136 0,2482 318,00 1.812,709
C 13,564 0,4153 318,00 112,666
Total 636.189,867
Liquid

Q10 CS2 41.128,000 0,2374 318.00 195.297,554
195.297,554
Total panas masuk
Qin = Quap + Qliquid
= 636.189,867 kkal + 195.297,554 kkal
= 831.487,422 kkal
160
Panas bahan keluar
Uap

Q11 H2S 60.766,255 02402 318,00 291.860,454
CS2 67.915,226 0.2482 318,00 337.093,133
S 1.699,112 0,0868 318,00 2.948,970
CH4 3,218 0,6287 318,00 40,461
CO2 547,704 0,2119 318,00 2.321,475
N2 365,136 0,2482 318,00 1.812,709
C 13,564 0,4153 318,00 112,666
Total 636.189,867
Liquid
QLO CS2 41.128,000 0,2374 318.00 195.297,554
195.297,554
Total panas keluar

= 636.189,867 kkal + 195.297,554 kkal
= 831.487,422 kkal
2.6 Neraca Panas pada Secondary CS2 Condenser (H-302)
Q11 Q12
Secondary CS2
Condenser
Keterangan :
Q11 : Panas masuk Secondary CS2 Condenser dari Primary CS2 Separator
Q12 : Panas keluar dari Secondary CS2 Condenser
161
Panas bahan masuk
Q11 H2S 60.766,255 02402 318,00 291.860,454
CS2 67.915,226 0.2482 318,00 337.093,133
S 1.699,112 0,0868 318,00 2.948,970
CH4 3,218 0,6287 318,00 40,461
CO2 547,704 0,2119 318,00 2.321,475
N2 365,136 0,2482 318,00 1.812,709
C 13,564 0,4153 318,00 112,666
Total 636.189,867
Panas bahan Keluar

Uap

Q12 H2S 60.158,592 0,2394 308,00 144.015,071
CS2 10.187,284 0,2403 308,00 24.477,492
CH4 3,218 0,6227 308,00 20,038
N2 365,136 0,2481 308,00 905,877
C 13,564 0,4154 308,00 56,346
Total 169.474,825
Liquid
Komponen Massa (kg) Cp (kkal/kgk) Suhu (K) Q (Kkal)

Q12 CS2 57.727,942 0,2346 308,00 135.405,605
H2S 607,663 0,5444 308,00 3.307,845
S 1.699,112 0,2043 308,00 3.470,521
CO2 547,704 1,3759 308,00 7.536,112
Total TOTAL 149.720,083
Total panas keluar

= 169.474,825 + 149.720,083 = 319.194,907
Q dibawa pendingin = Total panas masuk – total panas keluar

= 636.189,867 + 319.194,907 kkal
= 316.994,960 Kkal
143,60C
162
𝑑𝑄
= Q out –Q in
𝑑𝑇
= 319.194,907 - 636.189,867 kkal = -316.994,960 kkal

I kkal = 4,2 kj
-316.994,960 kkal = -1.331.378,831 kj
M= Q out – Q in
H (143,60C) – H (290C)
= - (-1.331.378,831) kj
(1.507,155 – 302,032) kj/kg
= - (-1.331.378,831) kj
1,205.12 kj/kg
= 1.104,766 kg
3. Proses Pemurnian H2S
3.1 Neraca Panas pada Secondary CS2 Separator (S-305)
Q13
Q12 CS2 Separator

(S-305)
Q14
3
Keterangan :
Q12 : Panas umpan dari Secondary CS2 Separator
Q13 : Panas fraksi atas secondary CS2 Separator/input Absorber
Q14 : Panas fraksi bawah secondary CS2 Separator/input Stabilizer Feed Drum
Suhu reference : 250C /298 K
163
Panas masuk
Uap

Q12 H2S 60.158,592 0,2394 308,00 144.015,071
CS2 10.187,284 0,2403 308,00 24.477,492
CH4 3,218 0,6227 308,00 20,038
N2 365,136 0,2481 308,00 905,877
C 13,564 0,4154 308,00 56,346
Total 169.474,825
Liquid
Q12 CS2 57.727,942 0,2346 308,00 135.405,605
H2S 607,663 0,5444 308,00 3.307,845
S 1.699,112 0,2043 308,00 3.470,521
CO2 547,704 1,3759 308,00 7.536,112
Total 149.720,083
Panas Keluar
Uap
Q13 H2S 60.158,592 0,2394 308,00 144.015,071
CS2 10.187,284 0,2403 308,00 24.477,492
CH4 3,218 0,6227 308,00 20,038
N2 365,136 0,2481 308,00 905,877
C 13,564 0,4154 308,00 56,346
Total 169.474,825
Liquid
Q14 CS2 57.727,942 0,2346 308,00 135.405,605
H2S 607,663 0,5444 308,00 3.307,845
S 1.699,112 0,2043 308,00 3.470,521
CO2 547,704 1,3759 308,00 7.536,112
Total 149.720,083
Total panas masuk = Total panas keluar

Qout = 169.474,825 + 149.720,083 = 319.194,907 Kkal
164
3.2 Neraca Panas pada Absorber (C-320)
Q 15
Q26 Q34
Qoil
Q13
Absorber C-320
Qv
H-330
Q16
Qv’
Keterangan :
Q13 : Panas fraksi atas Secondary Separator (S-305 )/input ke Absorber (C-320)
Q26 : Panas Fraksi atas CS2 Stripper Separator (S-306)/input ke Absorber (C320)
Q34 : Panas dari Stabilizer Condenser H-402 /input ke Absorber (C320)
Qoil : Feed absorbtion oil (Pella oil)/input ke ke Absorber (C-320)
Qv : Panas dari Absorber Intercooler (H-330)/input ke Absorber
Q15 : Panas fraksi atas dari Absorber (C-320)/gas menuju SRU
Q16 : Panas fraksi bawah dari Absorber (C-320)/input ke Oil Interchanger (H351)
Qv’ : Panas dari Absorber /input ke Absorber Intercooler (H-330)
H-330 : Absorber Intercooler
Suhu reference : 250C / 298K
165
1. Absorber
Panas masuk
Q13 H2S 60.158,592 0,2394 308,00 144.015,071
CS2 10.187,284 0,2403 308,00 24.477,492
CH4 3,218 0,6227 308,00 20,038
N2 365,136 0,2481 308,00 905,877
C 13,564 0,4154 308,00 56,346
Q26 CS2 1.600,533 0,2418 310.00 4.644,916
Q34 H2S 486,130 0,2394 308,00 1.163,758
QOIL Oil 157.172,875 0,5812 307,00 822.077,225
QV CS2 10.085,411 0,2346 308,00 23.656,156
Oil 157.172,875 0,58 308,00 915.085,920
Total 1.936.102,799
Panas Bahan Keluar

Fraksi Atas
Aliran Komponen massa (kg) Cp (kkal/kgk) Suhu (K) Q (kkal)
Q15 H2 S 60.644,722 0,1466 311,00 115.562,118
CS2 1.702,406 0,1220 311,00 2.699,706
CH4 3,218 0,4341 311,00 434,460
N2 365,136 0,2875 311,00 1.364,514
C 13,564 1,4906 311,00 262,831
Total 120.323,628
Panas yang keluar dari absorber masuk ke Absorber Intercooler

QV' CS2 10.085,411 0,2354 311,00 30.863,595
Oil 157.172,875 0,5854 311,00 1.196.016,858
Total 1.226.880,453
Fraksi Bawah

Q16 CS2 10085,411 0,2421 333,00 85.444,472
Oil 157172,875 0,6064 333,00 3.335.878,881
Total 3.421.323,353
Total panas keluar = 120.323,628 +1.226.880,453 + 3.421.323,353

= 4.768.527,434 Kkal
Q yang dibutuhkan = 4.768.527,434 - 1.936.102,799
= 2.832.424,635 Kkal
166
2. Absorber Intercooler (H-330)
QV’ Absorber Intercooler QV

(H-330)
Keterangan :
Qv : Panas keluar dari Absorber Intercooler (H-330)/input ke Absorber
Qv’ : Panas dari Absorber /input ke Absorber Intercooler (H-330)
Suhu Reference : 250C / 298 K
Panas Masuk

QV' CS2 10.085,411 0,2354 311,00 30.863,595
Oil 157.172,875 0,5854 311,00 1.196.016,858
Total 1.226.880,453
Panas Keluar

QV CS2 10.085,411 0,2346 308,00 23.656,156
Oil 157.172,875 0,58 308,00 915.085,920
Total 938.742,076
Q dibawa Pendingin = Q in – Q out

= 1.226.880,453 - 938.742,076
= 288.138,377
143,60C
𝑑𝑄
= Q out –Q in
𝑑𝑇
= 938.742,076 - 1.226.880,453 = - 288.138,377 kkal

I kkal = 4,2 kj
- 288.138,377 kkal = -1.210.181,183 kj
M= Q out – Q in
H (143,60C) – H (290C)
167
= - (-1.210.181,183) kj
(1.507,155 – 302,032) kj/kg
= - (-1.210.181,183) kj
1.205,123 kj/kg
= 1.004,197 kg
3.3 Oil Interchanger (H-351)
Q16 Oil Interchanger Q23

(H-351)
Q17
Q18
Keterangan :
Q16 : Panas masuk H-351 dari fraksi bawah Absorber
Q23 : Panas masuk H-351 dari fraksi bawah Stripper
Q17 : Panas Keluaran H-351/input ke Rich Oil Heater
Q18 : Panas Keluaran H-351/input ke Lean Oil Cooler
Panas Masuk

Q16 CS2 10.085,411 0,2421 333,00 85.444,472
Oil 157.172,875 0,6064 333,00 3.335.878,881
Q23 Oil 156.887,724 0,6969 453.00 16.947.185,021
H2O 3,267 1,0662 453,00 539.923,070
Total 20.908.431,444
Panas Keluar
Q17 CS2 10.085,411 0,2734 408,00 303.298,424
Oil 157.172,875 0,6631 408,00 11.464.192,054
Q18 Oil 156.887,724 0,6309 363,00 6.433.469,711
H2O 3,267 0,9994 363,00 212.230,601
Total 18.413.190,789
Q yang hilang = 20.908.431,444 - 18.413.190,789 = 2.495.240,654
168
3.4 Lean Oil Cooler (H-361)
Q18 Lean Oil Cooler Q19

(H-361)
Keterangan :
Q18: Panas masuk Lean Oil Cooler dari Oil Interchanger
Q19 : Panas keluar Lean Oil Cooler / input Lean Oil Tank
Suhu Reference : 250C / 298K
Panas Masuk

Q18 Oil 156.887,724 0,6309 363,00 6.433.469,711
H2O 3.267 0,9994 363,00 212.230,601
Total 6.645.700,312
Panas Keluar

Q19 Oil 156.887,724 0,5812 307,00 820.585,770
H2O 3.267 1,0001 307,00 29.405,595
Total 849.991,366
Q diserap pendingin = 6.645.700,312 - 849.991,366

=5.795.708,946
143,60C
𝑑𝑄
= Q out –Q in
𝑑𝑇
= 849.991,366 - 6.645.700,312 = - 5.795.708,946 kkal

I kkal = 4,2 kj
- 5.795.708,946 kkal = -24.341.977,574 kj
M= Q out – Q in
H (143,60C) – H (290C)
169
= - (-24.341.977,574) kj
(1.507,155 – 302,032) kj/kg

= - (-24.341.977,574) kj
1.205,123 kj/kg
= 20.198,749 kg
3.5 Neraca Panas pada Lean Oil Tank (T-350)
Q19
Lean Oil Tank Q20
(T-350)
Dumping
Keterangan :
Q19: Panas masuk Lean Oil Tank dari Lean Oil Cooler
Q20 : Panas keluar Lean Oil Tank / input Absorber
Panas Masuk

Q19 Oil 156.887,724 0,5812 307,00 820.585,770
H2O 3.267 1,0001 307,00 29.405,595
Total 849.991,366
Panas Keluar

Q20 Oil 156.887,724 0,5812 307,00 820.585,770
Dumping H2O 3.267 1,0001 307,00 29.405,595
Total 849.991,366
170
3.6 Neraca Panas pada Rich Oil Heater (H-341)
Rich Oil Heater Q21

Q17 (H-341)
Keterangan :
Q17: Panas masuk Rich Oil Heater dari Oil Interchanger
Q20 : Panas keluar Rich Oil Heater / input Stripper
Panas Masuk

Q17 CS2 10.085,411 0,2734 408,00 303.298,424
Oil 157.172,875 0,6631 408,00 11.464.192,054
Total 11.767.490,478
Panas Keluar
Q21 Oil 157.172,875 0,6986 455,00 17.238.132,508
CS2 10.085,411 0,3025 455,00 479.044,329
Total 17.717.176,837
Panas yang dibutuhkan = panas keluar - panas masuk

= 17.717.176,837 - 11.767.490,478
= 5.949.686,359 Kkal
1 kj = 4,2 kj
5.949.686,359 Kkal = 24.988.682,708 Kj
Kondisi operasi Rich Oil heater pada :
P = 1 atm = 101,325 Kpa; T = 2500C / 523 K
Maka steam yang digunakan adalah : saturated steam pada 2000C, P = 618,06 kPa
λ = 66.646,692 kj/kg
M=Q
λ
M = 24.988.682,708 Kj
66.646,692 kj/kg
= 374,943 Kg
171
3.7 Neraca pada Panas Stripper (C-340)
Q22
Q21
Stripper (C-340)
Q28
Qs
Q23
Keterangan :
Q21: Panas masuk Stripper dari Rich Oil Heater
Q28 : Panas masuk Stripper dari Stabilizer Feed Drum
Qs : Panas Steam masuk ke Stripper
Q22 : Fraksi atas dari Stripper / input ke Stripper Condenser
Q23: Fraksi bawah dari Stripper / Input ke Oil Interchanger
Panas Masuk :

Q21 CS2 10.085,411 0,3025 455,00 479.044,329
Oil 157.172,875 0,6986 455,00 17.238.132,508
Q28 CS2 584,808 0,2346 308,00 1.371,715
Oil 1.299,573 0,5822 308,00 7.566,326
Qs H2O 3.300,000 0,4617 457,10 242.388,642
Total 17.968.503,519
Panas Keluar

Q22 CS2 10.670,219 0,2953 374,00 239.445,456
Oil 1.584,724 0,4207 374,00 50.674,656
H2O 33,000 0,4526 374,00 1.135,066
Q23 Oil 156.887,724 0,6969 453,00 16.947.185,021
H2O 3.267,000 1,066 453,00 539.923,070
Total 17.778.363,269
172
Panas yang hilang = 17.968.503,519- 17.778.363,269
= 190.140,251
3.8 Neraca Panas pada Stripper Condenser (H-342)
Q22 Q25
Stripper Condenser
(H-342)
Keterangan :
Q22 : Panas dari Stripper (C-340) /input ke Stripper Condenser
Q25 : Panas dari Stripper Condenser/input ke Stripper Separator
Panas Masuk
Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu () Q (kkal)

Q22 CS2 10.670,219 0,2953 374,00 239.445,456
Oil 1.584,724 0,4207 374,00 50.674,656
H2O 33,000 0,4526 K 374,00 1.135,066
Total 291.255,178
Panas Keluar

Q25 CS2 10.670,219 0,2354 311,00 32.653,237
Oil 1.584,724 0,5854 311,00 12.059,060
H2O 33,000 0,9992 311,00 428,646
Total 45.140,944
Panas yang diserap pendingin :

Q = Qin – Qot
= 291.255,178 - 45.140,944
= 246.114,235
143,60C
𝑑𝑄
= Q out –Q in
𝑑𝑇
= 45.140,944 - 219.255,178 = -246.114,235 Kkal
173
I kkal = 4,2 kj
-246.114,235 kkal = -1.033.679,785 kj
M= Q out – Q in
H (143,60C) – H (290C)
= - (-1.033.679,785) kj
(1.507,155 – 302,032) kj/kg
= - (-1.033.679,785) kj
1.205,123 kj/kg
= 857,738 kg
3.9 Neraca Panas pada CS2 Stripper Separator (S-306)
Q26
Q25
CS2 Stripper
Separator (S-306)
Q27
Keterangan :
Q25 : Panas dari Stripper Condenser/input ke CS2 Stripper Separator
Q26 : Fraksi atas dari CS2 Stripper Separator /input ke Absorber (C-320)
Q27 : Fraksi bawah CS2 Stripper Separator /input ke Stabilizer feed Drum (V-300)
Panas Masuk
Q25 CS2 10.670,219 0,2354 311,00 32.653,237
Oil 1.584,724 0,5854 311,00 12.059,060
H2O 33,000 0,9992 311,00 428,646
Total 45.140,944
174
Panas Keluar
Uap

Q26 CS2 1.600,533 0,2418 310,00 4.644,916
Total 4.644,916
Liquid
Q27 CS2 9.069,686 0,2351 310,00 25.589,460
Oil 1.584,724 0,5843 310,00 11.111,715
H2O 33,000 0,9994 310,00 395,759
Total 37.096,935
Total Q keluar = 4.644,916 + 37.096,935

= 41.741,851
Q yang hilang = 45.140,944 – 41.741,851
= 3.399,093
3.10 Neraca Panas pada Stablizer Feed Drum (V-300)
Q14 Q27
Q28
7 Stablizer Feed7
Drum (V-300)
7
Q29
Condensat
7
Q2 7
Keterangan :
Q14 : Panas masuk Stabilizer Feed Drum V-300 dari fraksi bawah Secondary CS2 Separator
Q27 : Panas masuk Stabilizer Feed Drum V-300 dari fraksi bawah CS2 Stripper Separator
Q28 : Panas Keluar Stabilizer Feed Drum V-300/Input Stripper
Q29 : Panas Keluar Stabilizer Feed Drum V-300/Input Kolom Stabilizer
175
Panas Masuk
Q27 CS2 9.069,686 0,2351 310,00 25.589,460
Oil 1.584,724 0,5843 310,00 11.111,715
H2O 33,000 0,9994 310,00 395,759
Q14 CS2 57.727,941 0,2346 308,00 135.405,605
H2S 607,663 0,5444 308,00 3.307,845
S 1.699,112 0,2043 308,00 3.470,521
CO2 547,704 1,3759 308,00 7.536,106
Total 186.817,012
Panas Keluar
Q28 CS2 584,808 0,2346 308,00 1.371,715
Oil 1.299,573 0,5822 308,00 7.566,326
Q29 CS2 66.212,820 0,2346 308,00 155.307,581
S 1.699,112 0,2043 308,00 3.470,521
H2S 607,663 0,5444 308,00 3.307,845
Oil 114,060 0,5822 308,00 664,078
H2O 0,330 0,9994 308,00 3,298
CO2 219,081 1,3759 308,00 3.014,442
Condensat Oil 171,091 0,5822 307,00 896,506
H2O 32,670 0,9994 307,00 293,851
CO2 328,622 1,3759 307,00 4.069,497
Total 179.965,661
Q yang hilang = 186.817,012 - 179.965,661

= 6.851,351
176
4 Proses Pemurnian CS2
4.1 Neraca Panas pada Stabilizer (C-400)
Q34
Q31 H-402
LO
Q29 Stabilizer (C-
7
400)
7
Q32 7
7
H-401
Q30 Q33
7
Keterangan :
Q29 : Panas masuk C-400 dari Stabilizer Feed Drum
7 7
Q30 : Panas masuk Stabilizer Reboiler (H-401) dari Stabilizer C-400
Q31 : Panas Fraksi atas C-400 / input ke Stabilizer Condenser
Q32 : Panas masuk (Steam) ke C-400 dari H-401
QLO : Panas masuk (refluks) ke C-400 dari H-402
Q33 : Panas keluar Stabilizer Reboiler (H-401)/Input Still (C-420)
Q34 : Panas keluar Stabilizer Condenser (H-402) / input ke Absorber (C320)
H-401 : Stabilizer Reboiler
H-402 : Stabilizer Condenser
Suhu Reference : 25OC/298K
1. Stabilizer
Suhu Masuk

Q29 CS2 66.212,820 0,2346 308,00 155.307,581
S 1.699,112 0,2043 308,00 3.470,521
H2S 607,663 0,5444 308,00 3.307,845
Oil 114,060 0,5822 308,00 664,078
H2O 0,330 0,9998 308,00 3,300
CO2 219,081 1,3759 308,00 3.014,442
QLO CS2 34.426,533 0,2346 308,00 80.750,247
Q32 CS2 20.127,871 0,2953 374,00 451.680,248
Total 698.198,262
177
Suhu Keluar

Q30 CS2 86.340,691 0.2360 313.00 305.609,712
H2S 121,533 0.5549 313.00 1.011,645
Oil 114,060 0.5874 313.00 1.004,992
S 1.699,112 0.2021 313.00 5.151,743
H2O 0,330 0.9988 313.00 4,944
CO2 219,081 1.5539 313.00 5.106,321
Q31 CS2 34.426,533 0.2653 339.00 374.407,273
H2S 486,130 0.2419 339.00 4.820,509
Total 697.117,139
Q yang hilang = 698.198,262 - 697.117,139

= 1.081,123
2. Stabilizer Condenser (H-402)
Panas Masuk

Q31 CS2 34.426,533 0.2653 339.00 374.407,273
H2S 486,130 0.2419 339.00 4.820,509
Total 379.227,782
Panas Keluar

QLO CS2 34.426,533 0,2346 308,00 80.750,247
Q34 H2S 486,130 0,2394 308,00 1.163,758
Total 81.914,005
Q yang diserap pendingin = 379.227,782 -81.914,005

= 297.313,777
143,60C
𝑑𝑄
= Q out –Q in
𝑑𝑇
= 81.914,005 - 379.227,782 = -297.313,776 Kkal

I kkal = 4,2 kj
-297.313,776 kkal = -1.248.717,859 kj
178
M= Q out – Q in
H (143,60C) – H (290C)
= - (-1.248.717,859) kj
(1.507,155 – 302,032) kj/kg

= - (-1.248.717,859) kj
1.205,123 kj/kg
= 1.036,175 kg
3.Stabilizer Reboiler (H-401)

Panas Masuk

Q30 CS2 86.340,691 0.2360 313.00 305.609,712
H2S 121,533 0.5549 313.00 1.011,645
Oil 114,060 0.5874 313.00 1.004,992
S 1.699,112 0.2021 313.00 5.151,743
H2O 0,330 0.9988 313.00 4,944
CO2 219,081 1.5539 313.00 5.106,321
Total 317.889,357
Panas Keluar
Q32 CS2 20.127,871 0,2953 374,00 451.680,248
Q33 CS2 66.212,820 0,2572 374,00 1.294.500,396
H2S 121,533 0,7731 374,00 7.140,436
Oil 114,060 0,6390 374,00 5.539,459
S 1.699,112 0,1788 374,00 23.087,107
H2O 0,330 1,0027 374,00 25,147
CO2 219,081 5,9084 374,00 98.376,642
Total 1.880.349,435
Jumlah panas yang dibutuhkan = 1.880.349,435 - 317.889,357

= 1.562.460,077 Kkal
I kkal = 4,2 kj
1.562.460,077 Kkal = 6.562.332,325 kj
Data steam yang digunakan :
179
Steam (180°C), 1 atm, H = 2.777,914 kJ/kg
Kondensat (100°C), H = 419,1 kJ/kg
Panas sensible steam dari temperature 180°C - 100°C, Hs = 2.358,814 kJ/kg
Panas laten penguapan steam pada temperatur 100°C, HI = 2.256,9 kJ/kg
(Reklaitis, 1983)
H = Hs + HI = (2.358,814 + 2.256,9) kJ/kg = 4.615,714 kJ/kg
Steam yang diperlukan :
M= Q
λ pada 1800C
= 6.562.332,325 kj
4.615,714 kJ/kg
= 1.421,737 Kg
4.2 Neraca Panas pada Still ( C-420)
QF
H-422 Q38
7 Q35
Q33
7
QLO
Still (C-420)
7
Q37
7
7
H-421
QD
Q36
dD 7
um
Keterangan : pin
g 7
Q33 : Panas masuk C-420 dari Stabilizer Reboiler
QLO : Panas masuk (refluks) ke C-420 dari Still Refluks Vessel
Q37 : Panas masuk ke C-420 dari Still Reboiler
7
QD : Panas fraksi bawah C-420 / input Portable Tank
Q36 : Panas Fraksi bawah C-420 / input ke Still Reboiler
Q35 : Panas Fraksi atas C-420 / input ke Still Condenser
QF : Panas fraksi atas C-40 / input ke Flare
H-421 : Still Reboiler
180
H-422 : Still Condenser
Suhu Reference : 25OC/298K
1. Still C-420
Panas Masuk

Q33 CS2 66.212,820 0,2572 374,000 1.294.500,396
QF H2S 121,533 0,7731 374,000 7.140,436
Oil 114,060 0,6390 374,000 5.539,459
S 1699,112 0,1788 374,000 23.087,107
H2O 0,330 1,0027 374,000 25,147
CO2 219,081 5,9084 374,000 98.376,642
QLO CS2 34.800,000 0,2332 303,000 40.573,796
Q37 CS2 20.202,564 0,2856 363,000 375.077,028
Total 1.844.320,011
Panas Keluar
Q35 CS2 101.012,820 0,2762 352,000 1.506.468,222
QF H2S 121,533 0,2430 352,000 1.594,649
QD S 1.699,112 0,2047 333,000 11.535,251
Oil 114,060 0,5812 333,000 2.420,850
H2O 0,330 1,0001 333,000 11,509
CO2 219,081 1,3429 333,000 19.170,975
Q36 CS2 20.202,564 0,2389 323,000 120.672,107
Total 1.661.873,562
Q yang hilang = 1.844.320,011 - 1.661.873,562

= 182.446,448
2. Still Reboiler (H-421)
Panas Masuk

Q36 CS2 20.202,564 0,2389 323,00 120.672,107
Total 120.672,107
Panas Keluar

Q37 CS2 20202,564 0,2856 363,00 375.077,028
Total 375.077,028
Jumlah panas yang dibutuhkan = 375.077,028 - 120.672,107
181
= 254.404,921 Kkal
I kkal = 4,2 kj
254.404,921 Kkal = 1.068.500,669 Kj
Data steam yang digunakan :
Steam (180°C), 1 atm, H = 2.777,914 kJ/kg
Kondensat (100°C), H = 419,1 kJ/kg
Panas sensible steam dari temperature 180°C - 100°C, Hs = 2.358,814 kJ/kg
Panas laten penguapan steam pada temperatur 100°C, HI = 2.256,9 kJ/kg
(Reklaitis, 1983)
H = Hs + HI = (2.358,814 + 2.256,9) kJ/kg = 4.615,714 kJ/kg
Steam yang diperlukan :
M= Q
λ pada 1800C
= 1.068.500,669 kj
4.615,714 kj/kg
= 231,492 Kg
3. Still Condenser (H-422)
Suhu masuk

Q35 CS2 101012.820 0,2762 352,00 1.506.468,222
1.506.468,222
Panas Keluar

Q38 CS2 101.012,820 0,2332 303,00 117.772,227
Total 117.772,227
Panas yang diserap pendingin :

Q = Qin – Qot
Q = 1.506.468,222 - 117.772,227
= 1.388.695,995 Kkal
143,60C
𝑑𝑄
= Q out –Q in
𝑑𝑇
182
= 117.772,227 - 1.506.468,222
= -1.388.695,995 Kkal
I kkal = 4,2 kj
-1.388.695,996 kkal = -5.832.523,181 Kj
M= Q out – Q in
H (143,60C) – H (290C)
= - (-5.832.523,181) kj
(1.507,155 – 302,032) kj/kg
= - (-5.832.523,181) kj
1.205,123 kj/kg
= 4.839,774 kg
4.3 Neraca Panas Pada Still Refluks Vessel (V-430)
Still Refluks Vessel

(V-430)
Q38 Q39
QLO
Keterangan :
Q38 : Panas masuk ke V-430 dari Still Condenser
Q39 : Panas Produk akhir
QLO : panas keluar V-430 / input ke Still
Panas bahan masuk

Q38 CS2 101.012,820 0,2332 303,00 117.772,227
Total 117.772,227
183
Panas bahan Keluar
Q39 CS2 66.212,820 0,2332 303,00 77.198,431
QLO CS2 34.800,000 0,2332 303,00 40.573,796
Total 117.772,227
4.4 Panas pada Stack Flare

Panas bahan masuk
Suhu reference = 250C / 298K

QF H2 S 121,533 0,2430 352,00 1.594,649
Total 1.594,649
Panas bahan keluar

QF’ H2 S 121,533 0,2430 352,00 1.594,649
Total 1.594,649
184
4.5 Neraca Panas Overall
NO Komponen Input (kkal) Output (kkal)

1 Furnace
S 6.567.189,325 -
C 2.296,675 -
CH4 2.370.030,261 -
CO2 28.278,162 -
N2 19.717,611 -
Q Reaksi 69.320,856 -
Q yang dibutuhkan 46.559.144,520 -
2 Reaktor
Q Reaksi 388.666,743 -
Q lost - 2.040.343,166
3 Sulfur Condenser
Q Pengembunan 3.146.075,600 -
Q dibawa Pendingin - 50.799.970,804
4 Recycle Sulfur
Q lost - 3.550.778,152
5 CS2 Scrubber
Q lost - 1.246.978,044
6 Primary CS2 Condenser
Q Pengembunan 9.024.569,587 -
7 Secondary CS2 Cndenser
Q dibawa Pendingin - 316.994,960
8 Absorber
Oil 822.077,225 -
Panas ke SRU
CS2 - 2.699,706
H2S - 115.562,118
CH4 - 434,460
N2 - 1.364,514
C - 262,831
9 Absorber Intercooler
10 Lean Oil Cooler
11 Lean Oil Tank
H2O - 29.405,595
Oil - 820.585,770
12 Rich Oil Heather
13 Stripper
Q lost - 190.140,251
H2O 242.388,642 -
185
14 Stripper Condenser
15 Separator S-306
Q lost - 3.399,093
16 Stabilizer Feed Drum
Oil - 896,506
H2O - 293,851
CO2 - 4.069,497
Q lost - 6.851,351
17 Kolom Stabilizer
Q lost - 1.081,123
18 Stabilizer Reboiler
19 Stabilizer Condenser
20 Kolom Still
S - 11.535,251
Oil - 2.420,850
H2O - 11,509
CO2 - 19.170,975
Q lost - 182.446,448
21 Still Reboiler
Q yang dibutuhkan 254.404,921 -
22 Still Condenser
23 Still Refluks Vessel
CS2 - 77.198,431
24 Flare Stack
Q Gas Buang - 1.594,649
Total 80.040.000,778 80.040.000,778
Efisiensi Panas Total

Efisiensi = (jumlah panas output ) – (jumlah panas yang hilang) x 100%
Jumlah panas input
Efisiensi = 80.040.000,778- 7.222.017,628 x 100%
80.040.000,778
Efisiensi = 90,977%
% HEATLOSS
Heatloss = jumlah panas yang hilang x 100%
Jumlah panas input
Heatloss = 7.222.017,628 x 100%
80.040.000,778
= 9,023%
186
187

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LAMPIRAN 2

PERHITUNGAN NERACA PANAS

(Yaws, 2005 & Reklaitis,1983)

(Yaws, 2005 & Reklaitis,1983)

Komponen ∆HVL (kJ/kmol) Normal BP (K)

Komponen ∆H°f (kcal/mol)

Cpg metana = a + bT + cT2 + dT3 + eT4

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Menentukan Panas Reaksi

Volume natural gas yang dibutuhkan :

1.2 Neraca Panas pada Reaktor (R-202)

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Panas bahan Keluar

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Aliran Komponen massa (kg) Cp (kkal/kgoK) Suhu (oK) Q (kkal)

Total panas keluar sulfur condenser

Komponen massa (kg) Hv kkal/kg Q (kkal)

= 6.511.675,361 + 57.311.646,165 = -50.799.970,804 kkal

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Panas masuk V-270 = Q5 +Q7

Q yang hilang = Qin – Qout

2.3 Neraca Panas pada CS2 Scrubber (C-280)

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Total panas bahan masuk = 2.982.697,190 + 195.297,554 =2.976.725,166

Panas yang hilang = Q masuk – Q keluar

Q9 Primarry CS2 Q10

Panas bahan keluar

Total panas yang keluar Primarry CS2 Condenser

Komponen massa (kg) HV kkal/kg Q kkal

Panas masuk Primary CS2 Condenser :

= 831.487,422 kkal - 10.732.516,729 kkal = -9.901.029,307 kkal

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Total panas keluar

Panas bahan Keluar

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Komponen Massa (kg) Cp (kkal/kgk) Suhu (K) Q (Kkal)

Total panas keluar

Q dibawa pendingin = Total panas masuk – total panas keluar

= 319.194,907 - 636.189,867 kkal = -316.994,960 kkal

Q12 CS2 Separator

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Total panas masuk = Total panas keluar

Panas Bahan Keluar

Panas yang keluar dari absorber masuk ke Absorber Intercooler

Aliran Komponen massa (kg) Cp (kkal/kgk) Suhu (K) Q (kkal)

Aliran Komponen massa (kg) Cp (kkal/kgk) Suhu (K) Q (kkal)

Total panas keluar = 120.323,628 +1.226.880,453 + 3.421.323,353

QV’ Absorber Intercooler QV

Aliran Komponen massa (kg) Cp (kkal/kgk) Suhu (K) Q (kkal)

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Q dibawa Pendingin = Q in – Q out

= 938.742,076 - 1.226.880,453 = - 288.138,377 kkal

Q16 Oil Interchanger Q23

Aliran Komponen massa (kg) Cp (kkal/kgoK) Suhu (oK) Q (kkal)

Q yang hilang = 20.908.431,444 - 18.413.190,789 = 2.495.240,654

Q18 Lean Oil Cooler Q19

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Aliran Komponen massa (kg) Cp (kkal/kgK) Suhu (K) Q (kkal)

Q diserap pendingin = 6.645.700,312 - 849.991,366