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Very Similar

MODEL TEST PAPER


for AIEEE-2006
Time : 3 hrs. (Based on new pattern) Maximum Marks : 540
Instructions:
1. This question paper contains 180 questions: 1-60 Physics, 61-120 Chemistry, 121-180 Mathematics.
2. For every correct answer 3 marks will be credited to your account, 1 mark will be deducted for every wrong answer and no marks
will be awarded for unattempted questions.
3. Use of Trigonometric table, Calculator or any other helping device is restricted.
4. Useful data : At.wt./ Mol.wt. : KMnO4 : 158; Cu : 63.5; NaOH : 40; HCl : 36.5; Mg : 24; H : 1; He : 4; C : 12; N : 14;
O : 16; Na : 23; P : 31; S : 32; Cl : 35.5; Ca : 40; Zn : 65; Ag : 108.
Atomic No : H : 1; He : 2; Li : 3; Be : 4; B : 5, C : 6; N : 7; O : 8; F : 9; Na : 11; Mg : 12; Al : 13; Si : 14; Fe : 26; Co : 27;
Ni : 28; Cu : 29; Zn : 30; Rb : 37
Constants : g = 10 m/s 2 , R = 8.3 JK -1 mol -1 or 0.0821 atm litre K -1 mol -1 , e = 1.6 × 10 -19 C, N 0 = 6.023 × 10 23 ,
mp = 1.6 × 10-27 kg, me = 9.11 × 10-31 kg, h = 6.6 × 10–34 Js.

PHYSICS (a) 1 m/s (b) 0.5 m/s


(c) 0.01 m/s (d) 0.005 m/s.
1. The velocity of a particle is given by
v = at2 + bt + c, where v is measured in m/s and t is 6. The increase in energy of a brass rod of length
measured in second. The unit of 0.2 m and cross-sectional area 1 cm2 when compressed
(a) a is m/s (b) b is m/s with a load of 5 kg-wt. along its length is
(c) c is m/s (Y of brass = 1.0 × 1011 N/m2, g = 9.8 ms–2).
(d) a and b is same but that of c is different. (a) 2.4 × 105 joule (b) 4.2 × 10–5 joule
–5
(c) 2.4 × 10 joule (d) none of these.
2. The percentage errors in the measurement of mass
and speed are 1% and 2% respectively. What is the 7. Smoothing the surface is contact beyond a certain
percentage error in the kinetic energy? limit raises friction because
(a) 5% (b) 2.5% (a) irregularities are increased
(c) 3% (d) 1.5%. (b) surface projections are sharpened
(c) area of actual contact increases
3. A boat crosses the river in shortest possible time.
(d) none of these.
The speed of the boat in still water is 13 m/s. The average
speed of the boat while crossing the river comes out to 8. A body of mass M is raised from the surface of the
be 12 m/s. What is the velocity of flow of river? earth to an altitude equal to the radius of the earth. The
(a) 25 m/s (b) 1 m/s potential energy gained by the body will be
(c) (12/13) m/s (d) none of these. (a) MgR/2 (b) MgR
(c) 2MgR (d) none of these.
4. The angular speed of the minute hand of a clock
in degrees per second is 9. A neutron is moving with a velocity u. It collides
(a) 0.01 (b) 0.1 head on and elastically with an atom of mass number
(c) 1.0 (d) none of these. A. If the initial kinetic energy of the neutron be E, how
much energy will be retained by the neutron after
5. Two boys are left in the middle of a frictionless
collision?
floor. One boy of mass 20 kg gives a blow lasting one 2
milli-second and of 100 N to the other. He himself will  A  A
E
(a)   E (b)
( A + 1) 2
move with a velocity of  A +1
A −1 putting soap solution on one side of the stick, the surface
2
 A −1 E.
(c)   E (d)
( A + 1) 2 tension is reduced to 0.06 N/m. The net force on the
 A +1
stick will be
10. The centre of mass of system of particles does not (a) 0.01 N (b) 0.02 N
depend on the (c) 0.06 N (d) 0.07 N.
(a) masses of the particles
18. A cylinder of radius R made of material of thermal
(b) forces on the particles
conductivity K1 is surrounded by cylindrical shell of
(c) position of the particles
inner radius R and outer radius 2R made of a material
(d) relative separation of the particles.
of thermal conductivity K2. The two ends of the combined
11. A disc rolls down an inclined plane having system are maintained at two different temperatures.
inclination 30° without slipping. What will be its There is no loss of heat across the cylindrical surface
acceleration down the inclined plane? and the system is in the steady state. The effective thermal
(a) g/2 (b) g/3 conductivity of the system is
(c) 2g/3 (d) none of these. K1K2
(a) K1 + K2 (b)
12. Assuming the earth as a sphere of uniform density, (K1 + K2 )
the acceleration due to gravity half way towards the K1 + 3K2 (3K1 + K2 )
(c) (d)
centre of the earth will be 4 4
(a) 0.75g (b) 0.50 g
19. The temperature of the source of a Carnot heat
(c) 0.25g (d) 0.125g.
engine is 0°C and that of sink is –39°C. The efficiency
13. A projectile is fired vertically upwards. It escapes of a heat engine is
from the earth when fired with velocity v. If it is to be (a) zero (b) 14.3%
fired at 45° with the horizontal, what should be its velocity (c) 39% (d) none of these.
to enable it escape from the gravitational pull of the
20. A current carrying wire is placed along east-west
earth?
in a magnetic field directed northwards. If the current
(a) 2v (b) v / 2 in the wire is directed eastwards, what will be the direction
(c) v (d) some other velocity. of force on the wire?
14. The modulus of rigidity of a liquid is (a) due west (b) due south
(a) zero (b) 1 (c) vertically upwards (d) vertically downwards.
(c) infinity 21. If the average velocity of the molecules of a gas
(d) a value not one of those mentioned above. is doubled, then what happens to their root mean square
15. A person is carrying a bucket in one hand and a velocity?
fish in the other hand. If he puts fish in the bucket, how (a) doubled (b) halved
will the load carried by the person change? (c) becomes 2 times (d) becomes 1/ 2 times.
(a) no change (b) it will be more
22. A monoatomic ideal gas initially at 17°C is suddenly
(c) it will be less
compressed to one eighth of its original volume. The
(d) it will depend on the mass of the fish.
temperature after compression is
16. Eight drops of water, each of radius 2 mm are falling (a) 17°C (b) 136°C
through air at a terminal velocity of 8 cm/s. If they (c) 887°C (d) none of these.
coalesce to form a single drop, the terminal velocity of
23. The cause of Fraunhofer lines is
the combined drop will be
(a) reflection of radiations by chromosphere
(a) 8 cm/s (b) 16 cm/s
(b) absorption of radiation by chromosphere
(c) 24 cm/s (d) 32 cm/s.
(c) emission of radiations by chromosphere
17. A wooden stick 2 m long is floating on the surface (d) transmission of radiations by chromosphere.
of water, the surface tension of water is 0.07 N/m. By
24. What happens when a sound wave is reflected from
the boundary of a denser medium? The compression of 1 1
the incident wave is returned as
(a) V∝ (b) V ∝
R2 R
(a) crest (b) trough (c) V µ R (d) V µ R2.
(c) compression (d) rarefaction.
32. An infinite long straight wire is bent into a semicircle
25. A transverse wave is given by y = Asinp(ft – x/ of radius R, as shown in the figure. A current I is sent
l). The maximum particle velocity is 4 times the wave through the I
velocity, when c o n d u c t o r.
πA πA The magnetic
(a) λ = (b) λ =
R
4 2 field at the I I
(c) λ = π A (d) λ = 2π A centre of the
semicircle is
26. What causes reverberation?
(a) infinite (b) zero
(a) reflection (b) refraction
µ0 I µ0 I (π + 1)
(c) diffraction (d) interference. (c) (d)
4 R 4πR
27. A tunnel is made along a chord inside the earth
33. A proton enters a magnetic field with velocity parallel
and a ball is released in it. What will be the time period
to the magnetic field. The nature of the path followed
of oscillation of the ball?
by the proton will be
R R (a) straight line (b) circle
(a) 2π (b) 2π
2g g (c) helix (d) parabola.
2R R 34. A magnetised straight wire of length l and dipole
(c) 2π (d) π .
g g moment pm is bent into a semicircle. The dipole moment
of the bent wire will be
28. The masses of the three wires of copper are in the pm
ratio of 1 : 3 : 5 and their lengths are in the ratio of (a) p m (b)
π
5 : 3 : 1. The ratio of their electrical resistances is pm 2 pm
(a) 1 : 3 : 5 (b) 5 : 3 : 1 (c) (d) .
2π π
(c) 1 : 15 : 25 (d) 125 : 15 : 1
35. Which of the following is most suitable as the core
29. Two small spheres each carrying a charge q are of transformers?
placed 1 m apart. The electric force between them is F. (a) steel (b) alnico
If one sphere is taken around the other, the work done (c) soft iron (d) none of these.
is
(a) F (b) 2pF 36. In a transformer the voltage is stepped up from
220 volt to 440 volt. If the current in the primary was
(c) F/2p (d) zero.
1.0 ampere, that in the secondary should be
30. A parallel plate capacitor is connected across a (a) 0.5 A (b) between 0.5 and 1 A
2 volt battery and charged. The battery is then disconnected (c) 1 A (d) more than 1 A.
and a glass slab is introduced between the plates. Which
37. In an a.c. circuit capacitive reactance = inductive
of the following pairs of quantities decrease?
reactance. The phase difference between the current and
(a) charge and potential difference
the voltage will be
(b) potential difference and energy stored
π
(c) energy stored and capacitance (a) zero (b)
(d) capacitance and charge. 4
π
31. How does the maximum voltage (V) that can (c) (d) p.
2
be given to a spherical conductor vary with its
38. The refractive index is equal to the tangent of the
radius R?
angle of polarisation. It is called
(a) Brewster’s law (b) Malus law 47. The frequency of the incident light falling on a
(b) Bragg’s law (d) Grimald’s law. photosensitive metal plate is doubled, the kinetic energy
of the emitted photoelectrons is
39. The amplitude of the light waves emerging from
(a) double the earlier value
the two slits in Young’s experiment is in the ratio 2 : 3.
(b) unchanged
The intensity of the minimum to that of the consecutive
(c) more than doubled
maximum will be in the ratio of
(d) less than doubled.
(a) 2 : 3 (b) 4 : 9
(c) 1 : 9 (d) none of these. 48. The current gain a of a transistor in common base
40. The critical angle of water with respect to air is q. mode is 0.995. Its gain b in the common emitter mode
What is the angular range in which the fish just below is
the surface of water can see objects outside? (a) 99.5 (b) 1.005
(a) q/2 (b) q (c) 200 (d) 100.
(c) 2q (d) none of these. 49. The ratio of momentum of an electron and an alpha
41. We have a right angled isosceles prism. Its refractive particle which are accelerated from rest by a potential
index is 1.5. If we incident a ray normally on one of the difference of 100 V is
two perpendicular surfaces, which of the following 2me
phenomenon will take place? (a) 1 (b)

(a) dispersion (b) total internal reflection
(c) refraction (d) reflection. me me
(c) (d)
mα 2 mα
42. A far sighted person can see clearly beyond
100 cm distance. If he wants to see clearly an object at 50. If the binding energies per nucleon in Li7 and He4
40 cm distance, then the power of the lens he shall nuclei are respectively 5.60 MeV and 7.06 MeV, then
require is the energy of the reaction : Li7 + p ® 2 2He4 is
(a) + 1.5 D (b) – 1.5 D (a) 19.6 MeV (b) 2.4 MeV
(c) + 3.0 D (d) – 3.0 D. (c) 8.4 MeV (d) 17.3 MeV.
43. The rest mass of photon is 51. What is the name of the semiconductor material
(a) zero (b) 1.67 × 1035 kg having high negative coefficient of resistivity?
(c) infinite (d) 1 amu. (a) thermistor (b) transistor
(c) resistor (d) thyristor.
44. A particle of mass 10–30 kg is moving with velocity
equal to 106 m/s. The wavelength of the particle is equal 52. A motor boat covers the distance between two spots
to on the river in t1 = 8 hr and t2 = 12 hr down stream and
(a) 6.6 m (b) 6.6 cm upstream respectively. The time required for the boat
(c) 0.66 mm (d) 0.66 nm. to cover this distance in still water is
45. An electron moving with a velocity 8 × 107 enters (a) 4.3 hr (b) 9.6 hr
a parallel plate capacitor. The electric intensity is (c) 0.21 hr (d) 0.42 hr.
4 × 108 volt/metre. To keep the beam undeflected in its A
53. In figure,
path its magnetic field applied is ABCD is a channel D
(a) 0.5 T (b) 5 T in a vertical plane, E
r
(c) 50 T (d) 500 T. part BCDE being h
C
circular with r
46. The ionisation potential of hydrogen atom is r
13.6 volt. The energy required to remove an electron in radius r. A ball is
the n = 4 state of the hydrogen atom is released from A B
(a) 27.2 eV (b) 13.6 eV and slides without friction and without rolling. It will
(c) 1.5 eV (d) 0.85 eV. complete the loop path if
(a) h is greater than 5r/2 to increasing values of energy i.e. EA < EB < EC. If l1,
(b) h is less than 5r/2 l2, l3 are the wavelengths of the radiation corresponding
(c) it will not complete the loop to the transition C to B, B to A and C to A respectively,
(d) h is equal to 7r/5. which of the following relations is correct?
λ1λ 2
54. A uniform chain is held on a frictionless table with (a) l3 = l1 + l2 (b) λ 3 =
one fifth of its length hanging over the edge. If the λ1 + λ 2
chain has a length l and mass m, then the work required (c) l1 + l2 + l3 = 0 (d) λ 32 = λ12 + λ 22 .
to pull the hanging part back on the table is
CHEMISTRY
mg 50ml
(a) (b) 61. When a copper sulphate solution is treated with
50l g
50mg mgl potassium iodide and excess of hypo solution is added
(c) (d) in resulting solution, a white precipitate is formed. The
l 50
white precipitate is due to
55. A man is travelling along a straight line joining (a) Na2S4O6 (b) CuI2
two sources each of 1000 vib/sec. How fast should he (c) CuI (d) NaI.
move, so that he may hear 15 beats per second?
(velocity of sound = 330 m/s) 62. An organic compound has 4% sulphur. The
(a) 1.46 m/s (b) 2.48 m/s molecular weight of the compound will be
(c) 3.93 m/s (d) 0.53 m/s. (a) 100 (b) 200
(c) 400 (d) 800.
56. Find the potential 30 9
difference between the 63. Sodium carbonate reacts with SO2 gas to give
plates of the capacitor C 1V
C (a) Na2SO4 (b) NaHSO4
in the circuit shown. The (c) Na2SO3 (d) NaHSO3.
internal resistance of the 20 9 10 9 64. The wax which is used in the manufacture of candles,
sources are negligible. contains
(a) –2 volt (a) saturated hydrocarbons
(b) + 1 volt 4V (b) esters (c) alcohols
(c) + 2 volt (d) –1 volt. (d) higher ethers.
57. An intrinsic semiconductor at absolute zero of 65. Which of the following statement is correct about
temperature behaves as thepositive catalyst?
(a) an insulator (b) a semiconductor (a) it increases the energy of activation
(c) a metallic conductor (b) it increases the amount of products
(d) a superconductor. (c) it increases the rate of forward and backward
reactions
58. Four independent waves are expressed as
(i) y1 = a1sinwt (ii) y2 = a2sin2wt (d) it initiates a chemical reaction.
(iii) y3 = a3coswt (iv) y4 = a4sin(wt + p/3) 66. When two gases hydrogen and helium are filled in
The interference is possible between two different containers whose volumes and weights
(a) (i) and (iii) (b) (i) and (iv) are same, which of the following statements is correct
(c) (iii) and (iv) (d) not possible at all. about two gases?
59. The nuclear radius of a nucleus with nucleon number (a) both the gases have same pressure
10 is 3 × 10–15 metre. Then the nuclear radius of a nucleus (b) both the gases have equal number of molecules
with nucleon number 80 is (c) molecules of H2 will be more
(a) 3 × 10–15 metre (b) 1.5 × 10–15 metre (d) molecules of He will be more.
(c) 6 × 10–15 metre (d) 4.5 × 10–15 metre. 67. In manufacture of caustic soda which of the
60. Energy levels A, B, C of a certain atom correspond following is obtained as a by-product?
(a) oxygen (b) nitrogen 77. Reduction potentials of some half reactions are
(c) chlorine (d) common salt. given as :
Fe2+ + 2e ® Fe ; E° = – 0.47 volts
68. Which of the following compounds does not react
Fe3+ + 3e ® Fe ; E° = – 0.057 volts
with iodine and sodium hydroxide?
Fe3+ + e ® Fe2+ ; E° = + 0.77 volts
(a) propanal (b) ethyl alcohol
FeO42– + 3e + 8H+ ® Fe3+ + 4H2O ; E° = + 2.20 volts
(c) acetaldehyde (d) acetone.
Which of the following statements is correct?
69. Benzaldehyde is converted into benzyl alcohol by (a) neither Fe3+ nor Fe2+ have any tendency to reduce Fe
(a) Fittig reaction (b) Wurtz reaction (b) FeO42– is the weakest oxidising agent
(c) Cannizzaro reaction (d) Wurtz-Fittig reaction. (c) DG value for FeO42– ® Fe3+ will be large and positive
(d) reactions with negative values for E° are more
70. Which of the following is conjugate base of
strongly oxidising than oxygen.
[C2H5NH3]+ ?
(a) [C2H5NH]– (b) [C2H5NH3]OH 78. Which of the following metals has the lowest
(c) C2H5NH2 (d) all of these. metallic conductivity?
(a) silver (b) copper
71. At 227°C the enthalpy of the reaction
(c) sodium (d) zinc.
N2 (g) + 3H2 (g) S 2NH3 (g)
is found to be –22.40 K cal. The enthalpy at constant 79. When ammonia (NH 3) reacts with calcium
volume will be (given R = 1.98 × 10–3 Kcal K–1 mol–1) hypochlorite, which of the following is main product
(a) –22.40 (b) 22.40 of the reaction?
(c) –20.42 (d) 20.42 (a) Ca3N2 (b) NH4Cl
(c) N2 (d) CaO.
72. Which one of the following reactions is said to be
a Friedel Craft’s reaction? 80. Which of the following species has the lowest value
AlCl3
(a) C6H5CH3 + CH3CH2Cl → of pKa?
C6H5C2H5 + CH3Cl (a) H3PO4 (b) H2PO4–
AlCl (c) HPO42– (d) all have equal value.
(b) C6H5Cl + CH3CH2Cl 3

C6H5C2H5 + Cl2 81. When cupric oxide (CuO) is heated in the current
AlCl3 of ammonia, which of the following is not the product
(c) C H + CH CH Cl 
→ C6H5C2H5 + HCl
6 6 3 2 formed?
(d) none of these. (a) Cu (b) N2
73. The pH of 10–10 M Mg(OH)2 solution will be (c) H2O (d) Cu3N2.
(a) 10 (b) 6 82. Which of the following oxyacids of phosphorus is
(c) 4` (d) 7.001 monobasic and reducing in nature?
74. If uncertainty in position of an electron is zero, (a) metaphosphoric acid
the uncertainty in its momentum will be (b) pyrophosphoric acid
(a) less than h/4p (b) greater than h/4p (c) hypophosphoric acid
(c) zero (d) infinite. (d) hypophosphorous acid.

75. Half-life of a radioactive disintegration (A ® B) 83. Which of the following compounds is not reduced
having rate constant 231 sec–1, will be by ozone?
(a) 3.0 × 10–2 sec (b) 3.0 × 10–3 sec (a) BaO2 (b) Ag2O
–2
(c) 2.31 × 10 sec (d) 2.31 × 10–3 sec. (c) Na2O2 (d) K4[Fe(CN)]6.

76. Didymium catayst is 84. When the vapours of benzene are passed through
(a) neodymium (b) praseodymium a red hot tube
(c) both (a) and (b) (d) none of these. (a) diphenyl is formed
(b) diphenyl benzene is formed
(c) both (a) and (b) are correct (c) supercooled liquids
(d) both (a) and (b) are wrong. (d) substances with definite melting point.
CO + HCl 94. In a crystal the atoms are located at the position of
85. The reaction, C6H6  → C 6H5CHO is
AlCl3 (a) maximum potential energy
known as (b) minimum potential energy
(a) Reimer-Tiemann reaction (c) zero potential energy
(b) Perkin’s reaction (d) infinite potential energy.
(c) Gattermann Koch reaction
(d) Gattermann aldehyde synthesis. 95. Sodium metal crystallises in bcc lattice with the
cell edge, a = 4.29 Å. The radius of sodium atom is
86. The product formed by heating sodium phenoxide (a) 4.29 Å (b) 2.145 Å
with CO2 at 140°C on treatment with HCl gives (c) 1.86 Å (d) 2.86 Å.
(a) phenyl acetic acid (b) cinnamic acid
(c) benzoic acid (d) salicylic acid. 96. The enzyme which can catalyse the conversion of
glucose to ethanol is
87. The reaction of benzaldehyde with ammonia (NH3)
(a) invertase (b) maltase
gives
(c) zymase (d) diastase.
(a) benzaldehyde ammonia
(b) benzaldimine (c) hydrobenzamide 97. The rate constants for the forward and backward
(d) benzamide. reactions of hydrolysis of ester are 1.1 × 10 –2 and
1.5 × 10–3 per minute respectively. The equilibrium
88. The energy required to send hydrogen electron from
constant of the reaction will be
n= 1 to n = 2 will be
(a) 1.1 × 10–2 (b) 1.5 × 10–3
(a) 13.6 eV (b) 27.2 eV –5
(c) 1.65 × 10 (d) 7.33
(c) 10.2 eV (d) 1.02 eV.
98. Naturally occurring boron consists of two isotopes
89. The ionization energy of hydrogen atom is
having atomic weights 10.01 and 11.01. The atomic
13.6 eV. The ionization energy of Li2+ ion will be
(a) 13.6 eV (b) 40.8 eV weight of naturally occurring boron is 10.81. The
(c) 122.4 eV (d) 84.6 eV. percentage of each isotope in natural boron is
(a) 20% and 80% respectively
90. When the value of n + l is not more than three (b) 80% and 20% respectively
which of the following sub shells is not possible to (c) 30% and 70% respectively
exist? (d) 70% and 30% respectively.
(a) 2s (b) 3s –
(c) 3p (d) 2p. 99. The substances which produce NH 2 in liquid
ammonia are
91. Hypnotic chloretone is obtained by (a) acids (b) bases
(a) condensation of acetone with chloroform (c) both (a) and (b) (d) none of these.
(b) condensation of acetaldehyde with carbon
tetrachloride 100. Which of the following substances are formed when
(c) condensation of acetone with bleaching powder lithium is heated in air?
(d) condensation of acetaldehyde with bleaching (a) Li2O + LiO2 (b) Li2O2
powder. (c) LiO2 (d) Li2O + Li3N.

92. The conversion of aliphatic compounds into aromatic 101. Which of the following compounds is most stable?
compounds is known as (a) LiF (b) LiCl
(a) aromatisation (b) hydroforming (c) LiBr (d) LiI.
(c) catalytic reforming (d) conformation. 102. The name hydrargyrum stands for
93. Amorphous solids are (a) Ag (b) Hg
(a) solids in true sense (b) liquids in true sense (c) He (d) Ho.
103. Ketones R – C – R1 , where R and R1 are alkyl 110. Which one of the following is correct order of
basic strength?
O (a) NH3 > CH3NH2 > NF3
groups, can be obtained in one step by (b) CH3NH2 > NH3 > NF3
(a) hydrolysis of esters (c) NF3 > CH3NH2 > NH3
(b) oxidation of primary alcohols (d) NH3 > NF3 > CH3NH2.
(c) oxidation of tertiary alcohols
(d) reaction of acid halides with alcohols. 111. Which of the following expressions does not
represent the equilibrium constant (Ke) of water?
104. Which one of the following chemical units is
[H3O+ ] [OH − ] Kw
essentially found in enzymes? (a) 2
(b) 2
O [H 2O] (55.5)
N
(a) –C–O– (b) 10−14
(c) (d) [H3O+] [OH–]
N (55.5)2
O 112. Which one of the following is correct statement?
H
–C (a) a strong acid must be stronger than H3O+
(c) .... N – C .... (d) O (b) a weak acid must be stronger than H3O+
–C (c) weak acids are weaker than H2O
O –
O (d) weak bases are stronger than OH .
105. Which of the following substances is used to make 113. Which of the following species is not amphoteric?
non-stick cookware? (a) NH3 (b) HCO3–
(a) polystyrene (b) PVC (c) NH4+ (d) HF.
(c) polytetrafluoroethylene 114. Mercury acts as a superconductor at
(d) poly (ethylene terephthalate). (a) 4 K (b) 8 K
106. Which of the following substances is not a (c) 6 K (d) 10 K.
organophosphorus insecticide? 115. In which of the following interactions H2SO4 acts
(a) malathion (b) parathion as a base?
(c) phosdrin (d) rotenone. (a) H2SO4 + HNO2 (b) H2SO4 + HNO3
107. The number of conformations possible for ethane (c) H2SO4 + HClO4 (d) none of these.
is 116. Which of the following compounds actually exists?
(a) two (b) four (a) BF3 (b) BH3
(c) eight (d) infinite. (c) BF5 (d) all of these.
108. Which one of the following is incorrect? 117. Which of the following reactive carbon intermediates
(a) at equilibrium DG = 0 is called triplet carbene?
(b) at equilibrium, DG = DG° + RT logKe
(c) at equilibrium, DG° = –RT logKe – C ..

(a) (b) – C .
(d) DG° = DH° – TDS°.
. Å
109. Which of the following reactions has negative DS (c) – C. – (d) – C
value?
(a) H2 + CH3CH CH2 ® CH3CH2 – CH3 118. The reverse of heterolytic cleavage of covalent bond
(b) CH2 – CH2 is known as
CH3CH CH2
(a) covalent bonding
CH2 (b) co-ordinate covalent bonding
(c) CH3COO– (aq) + H3O+ (aq) ® CH3COOH + H2O (c) dipole-dipole interaction
(d) all of these. (d) van der Waal’s forces.
119. Which of the following pairs has both the species 129. Minimum value of tan2q + cot2q is
having nearly same ionization energy? (a) –2 (b) 2
(a) O2 and F (b) O2 and Xe (c) 1 (d) 3.
(c) O2+ and F– (d) O and N.
130. The expression
120. Which of the following compounds can oxidise (1 – x)–2 = 1 + 2x + 3x2 + 4x3 + .... + ¥
the molecular oxygen? is not valid for
(a) PtF6 (b) XeF6 (a) x = 1/2 (b) x = –1/2
(c) SiF4 (d) HClO. (c) x = 1/ 3 (d) x = 2 / 3 .
MATHEMATICS 131. The conditions x ³ 0, y ³ 0 in a linear programming
problem are called
121. If secq – tanq = –2/3, then q lies in the
(a) structural constraints
(a) first quadrant (b) second quadrant
(b) redundant constraints
(c) third quadrant (d) fourth quadrant. (c) non-negativity constraints
122. If Tp , Tq , Tr are the pth, qth and rth terms of an (d) none of these.
Tp Tq Tr  132. If p and q are the coefficients of xn in (1 + x)2n and
A.P., then det  p q r  is equal to (1 – 4x)–1/2, |x| < 1/4, then
 1 1 1  (a) p = q (b) p = 2q
(c) q = 2p (d) p + q = 2nCn.
(a) 1 (b) –1
(c) 0 (d) pqr. 133. The arithmetic mean between the roots of
1/3 –1/3 x2 + bx + c = 0 is 5, while the geometric mean between
123. If 2x + 2x = 5, then x is equal to
them is 4. The values of b and c are
(a) 1 or –1 (b) 2 or 1/2
(a) 5, 4 (b) –10, 16
(c) 8 or 1/8 (d) 4 or 1/4.
(c) –5, 4 (d) 10, 16.
124. The number of common tangents to the circles
134. If the roots of the equation,
x2 + y2 + 2x + 8y – 23 = 0
px2 + 2qx + r = 0 and
x2 + y2 – 4x – 10y + 19 = 0 are
(a) one (b) two qx 2 − 2 pr x + q = 0
(c) three (d) four. are simultaneously real, then
(a) p = q, r ¹ 0 (b) 2q = ± pr
125. The distance of the point (a, b) from X-axis is
(c) p/q = q/r (d) q = r ¹ 0.
(a) a (b) b
(c) |a| (d) |b|. 135. A train travelling at a speed of 72 km/hr is brought
to rest by application of brakes. If the distance travelled
126. The nth term of the sequence 5 + 55 + 555 + ... is
by the train before coming to rest is 200 m, the acceleration
(a) 5 × 10n – 1 (b) 5 × 11n – 1
produced by the breaks is
5 n
(c) (10 − 1) (d) none of these. (a) 1 m/sec2 (b) 1 m/sec
9 (c) –1 m/sec (d) –1 m/sec2.
127. The number of real solutions of the equation 136. If z1 and z2 be any two complex numbers, then
x2 + 3 | x | + 2 = 0 is which one of the following is not true?
(a) 0 (b) 1 (a) |z1 – z2| £ |z1| + |z2|
(c) 3 (d) 2. (b) |z1 – z2| £ |z1| – |z2|
128. In a triangle ABC, (c) |z1 + z2| £ |z1| + |z2|
(a) sin(A + B) + sinC = 0 (d) |z1 – z2| ³ |z1| – |z2|.
(b) cos(A + B) + cosC = 0 137. If the first term of an infinite G.P. is equal to twice
A+ B C the sum of all the terms that follows it, then the common
(c) A + B + C = p/2 (d) sin + cos = 0.
2 2 ratio is
(a) 2 (b) 1 (a) |x| £ 1 (b) x £ 1
(c) 1/2 (d) 1/3. (c) |x| ³ 1 (d) x ³ 1.

∫|x
3
an + bn 147. | dx is equal to
138. If n −1 n −1 be the arithmetic mean between a
a +b x 4
x4
and b, then the value of n is (a) ± +C (b) +C
4 4
(a) 1 (b) 0 x3 | x |
(c) –1/2 (d) –1. (c) +C (d) none of these.
4
2 2 − (sin x + cos x )3 e x − e− x
139. lim is equal to 148. lim is equal to
x→π / 4 1 − sin 2 x x →∞ e x + e− x
3 (a) 1 (b) –1
(a) (b) 3 2 (c) 0 (d) none of these.
2 2
−3 3 1 1
(c) (d) . 149. If A =   , then A is equal to
n
2 2 1 1
(a) nA (b) 2n A
 1 − x2  (c) 2 n–1
A (d) none of these.
140. The relation cos −1  2 
= 2 tan −1 x holds for all
 1 + x 
x in 150. If r (x, y) = 0.6 and byx = – 0.9, then bxy is equal
(a) [–1, 1] (b) [0, 1] to
(c) [0, ¥) (d) (–1, 1). (a) 0.4 (b) – 0.4
(c) 0.36 (d) none of these.
141. 51/2 · 51/4 · 51/8 .... to ¥ is equal to
sin(π[ x])
(a) log105 (b) 5 151. The range of the function f (x) = is
x4 + 1
(c) 5 (d) 1. (a) (–1, 1) (b) [–1, 1]
e 2 (c) {–1, 1} (d) {0}.
log e x
142. ∫ x
dx is
2ˆ 3 ˆ 6 ˆ
1/ e 152. The vector i + j − k is a
(a) 3/2 (b) 5/2 7 7 7
(c) 3 (d) 5. (a) null vector (b) unit vector
(c) vector whose components are (2, 3, –6)
143. lim [cos x] is equal to (d) vector which is equally inclined to the axes.
x →0
(a) 1 (b) 0 153. If the normal to the curve y = f (x) at the point
(c) does not exist (d) none of these. (3, 4) makes an angle 3p/4 with positive x-axis, then
f ¢(3) is
144. A person travels from his house to his office at a
(a) –1 (b) –3/4
speed of 30 km/hour and returns at a speed of
(c) 4/3 (d) 1.
20 km/hour. His average speed of the two trips taken H H H H
together is 154. If a and b be two vectors such that a ⋅ b = 0 and
H H H
(a) 25 km/hour (b) 24.5 km/hour a × b = 0 , then
H H
(c) 24 km/hour (d) none of these. (a) a is parallel to b
H H
145. For a discrete bivariate data b yx = –0.9 and (b) a is perpendicular to b
H
bxy = –0.4, coefficient of correlation r (X, Y) for this (c) a is a nullHvector
H
data is (d) either a or b is a null vector.
(a) 0.6 (b) 0.06 155. 5 tickets are drawn successively with replacement
(c) – 0.06 (d) – 0.6 from a box containing 100 tickets, numbered from 1 to
100. The probability that all the tickets bear numbers
 2x 
146. The statement 2cot −1 x = sin −1  2 
holds only if divisible by 10, is
1+ x 
 9
5
 1
5 these forces passes through the
(a)   (b)   (a) incentre (b) centroid
 10   10 
5 (c) orthocentre (d) none of these.
 9 
(c)   (d) none of these. n −1
 100  ∞
 a 
165. If a > 0, then ∑  equals
156. The probability of throwing an ace in a single throw n =1  a +1
of an unbiased dice is (a) a (b) a + 1
(a) 1/6 (b) 0 a a +1
(c) (d) .
(c) 1 (d) 2/3. 2a + 1 2a + 1

 tan x − x  1  x, x > 0
157. lim   cos 
x →0
 x  x 166. Let y =  0, x = −0 , then at x = 0, y is
 − x, x < 0
(a) does not exist (b) equals 0 
(c) equals 1 (a) derivable (b) not continuous
(d) exists and is different from 0 and 1. (c) continuous but not derivable
(d) none of these.
158. tan75° + cot75° is equal to
(a) 2 3 (b) 2+ 3 1 + 2 + 3 + .... + n
167. lim is equal to
(c) 2− 3 (d) 4.
n →∞ n3 / 2
(a) 0 (b) 1
1
159. If det A = 3 and A is of order 2 × 2, then det 4A
is equal to (c) 3/2 (d) ∫ xdx.
0
(a) 3 (b) 12
(c) 48 (d) 36. G( x) − G(1)
168. If G ( x) = − 25 − x 2 , then lim has the
x →1 x −1
160. The system of equations, value
x + y + z = 6, x + 2y + 3z = 14 (a) 1/24 (b) 1/5
x + 3y + 5z = 20 has (c) − 24 (d) 1/ 24 .
(a) a unique solution
(b) only finitely many solutions 169. The equation of the curve which passes through
(c) infinitely many solutions dy
the point (1, 1) and for which = 2 x + 2 is
(d) no solution. dx
(a) y = x2 + 2x (b) y = x2 + 2x – 3
161. If In is identity matrix of order n, then (In)–1 (c) y = x2 + 2x – 2 (d) y = x2 + x – 3.
(a) does not exist (b) = In
(c) = 0 (d) = nIn. 170. If Z is any complex number, then AmpZ + Amp Z =
(a) 0 or 2p (b) 0
162. Equation of the sphere which passes through the (c) 2p (d) none of these.
points (a, 0, 0), (0, b, 0), (0, 0, c) and (0, 0, 0) is
2
(a) x2 + y2 + z2 – ax – by – cz = 0
∫ ( px + qx + r )dx
3
171. To find the numerical value of
(b) x2 + y2 + z2 – ax + by + cz = 0 −2

(c) x2 + y2 + z2 + ax – by – cz = 0 it is necessary to known the values of the constants


(d) x2 + y2 + z2 – ax + by – cz = 0. (a) p (b) q
(c) r (d) p and r.
163. Octal representation of the number 0.1875 is
(a) (0.15)8 (b) (0.41)8 172. Let P(x) = a0 + a1x2 + a2x4 + ... + anx2n be a poly-
nomial in a real variable x with 0 < a0 < a1 < a2 < ... < an.
(c) (0.14)8 (d) none of these.
The function P(x) has
164. Three like parallel forces, each of magnitude P, (a) neither a maximum nor a minimum
act at the vertices of a triangle ABC. The resultant of (b) only one maximum (c) only one minimum
2n 2n
(d) only one maximum and only one minimum. (a) Cn (b) Cn n!
173. There exists a triangle ABC satisfying the
2 n!
(c) (d) none of these.
conditions n!
(a) b sin A = a, a > b (b) b sin A > a, a > b 178. The number of ways in which 2n persons can be
(c) b sin A < a, a = b, A = p/2 divided into n couples is
(d) b sin A < a. 2n ! 2n !
(a) (b)
174. (0, 0) is a vertex of a square and 5x – 12y + 26 = 0 n! n! n! 2n
is the equation of one of its sides. The area of the square
2 n!
is (c) (d) none of these.
(a) 4 sq. units (b) 676 sq. units 2n
169 179. The number of ways in which 52 cards can be
(c) 169 sq. units (d) sq. units.
4 divided equally amongst four players is
175. The lengths of the sides of a triangle are 3, 4 and 52! 52!
(a) (b)
5. Its circumradius is (13!) 4
(13!) 4 × 4!
(a) 1 (b) 5 52!
(c) (d) none of these.
(c) 5/2 (d) none of these. (13!) 4 × 4
H H H H
176. Let the vectors a , b , c and d be such that
H H H H H 1 2 
( a × b ) × (c × d ) = 0 . Let P 1 and P 2 be the planes 180. If A =   , then adj(adj A) is equal to
H H H H 3 4 
determined by the pairs of vectors a , b , and c , d
respectively, then the angle between P1 and P2 is  1 −2  1 2 
(a)  −3 4  (b) 3 4 
(a) 0 (b) p/4    
(c) p/3 (d) p/2.
 1 −3
177. Coefficient of xn in the expansion of (c)  −2 4  (d) none of these.
(1 – 2x + 3x2 + 4x3 + ...)–n is  

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