9

LAMPIRAN

A. Pembuatan Larutan
1. Pembuatan Larutan Sukrosa ±1 molal
massa terlarut 1000
molal = ×
BM massa pelarut
massa sukrosa 1000
×
1 molal = g 10 g
342
gmol
g
1molal ×342 ×10 g
Massa sukrosa = gmol
1000
Massa sukrosa = 3,4200 gram
Toleransi penimbangan:
 Batas atas : 3,4200 + (3,4200 x 10%) = 3,7620 g
 Batas bawah : 3,4200 – (3,4200 x 10%) = 3,0780 g

2. Pembuatan Larutan Sukrosa ±0,5 molal

massa terlarut 1000
molal = ×
BM massa pelarut
massa sukrosa 1000
×
0,5 molal = g 10 g
342
gmol
g
0,5 molal× 342 ×10 g
Massa sukrosa = gmol
1000
Massa sukrosa = 1,7000 gram
Toleransi penimbangan:
 Batas atas : 1,7000 + (1,7000 x 10%) = 1,8700 g
 Batas bawah : 1,7000 – (1,7000 x 10%) = 1,5300 g

3. Pembuatan Larutan Urea ±1 molal

massa terlarut 1000
molal = ×
BM massa pelarut
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massa urea 1000

×
1 molal = g 10 g
60
gmol
g
1molal ×60 ×10 g
Massa urea = gmol
1000
Massa urea = 0,6000 gram
Toleransi penimbangan:
 Batas atas : 0,6000 + (0,6000 x 10%) = 0,6600 g
 Batas bawah : 0,6000 – (0,6000 x 10%) = 0,5400 g

4. Pembuatan Larutan Urea ±0,5 molal

massa terlarut 1000
molal = ×
BM massa pelarut
massa urea 1000
×
0,5 molal = g 10 g
60
gmol
g
0,5 molal× 60 × 10 g
Massa urea = gmol
1000
Massa urea = 0,3000 gram
Toleransi penimbangan:
 Batas atas : 0,3000 + (0,3000 x 10%) = 0,3300 g
 Batas bawah : 0,3000 – (0,3000 x 10%) = 0,2700 g

5. Pembuatan Larutan NaCl ±0,5 molal

massa terlarut 1000
molal = ×
BM massa pelarut
massa NaCl 1000
×
0,5 molal = g 10 g
58,44
gmol
g
0,5 molal×58,44 ×10 g
Massa NaCl = gmol
1000
Massa NaCl = 0,2922 gram
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Toleransi penimbangan:
 Batas atas : 0,2922 + (0,2922 x 10%) = 0,3214 g
 Batas bawah : 0,2922 – (0,2922 x 10%) = 0,2630 g

6. Pembuatan Larutan KCl ±0,5 molal

massa terlarut 1000
molal = ×
BM massa pelarut
massa KCl 1000
×
0,5 molal = g 10 g
74,56
gmol

g
0,5 molal×74,56 × 10 g
Massa KCl = gmol
1000
Massa KCl = 0,3728 gram
Toleransi penimbangan:
 Batas atas : 0,3728 + (0,3728 x 10%) = 0,4101 g
 Batas bawah : 0,3728 – (0,3728 x 10%) = 0,3355 g

B. Data Mentah Hasil Percobaan

 Penentuan Berat Molekul Larutan Non-Elektrolit
Nama BM teoritis Massa Massa
Molalitas Tb (oC)
Zat (g/mol) pelarut (g) terlarut (g)
1 10,1994 3,4272 -3
Sukrosa 342
0,5 10,0635 1,7239 -2
1 10,1946 0,6393 -2
Urea 60
0,5 10,0639 0,2991 -1

 Penentuan Faktor van’t Hoff Larutan Elektrolit

Nama BM teoritis Massa Massa
Molalitas Tb (°C)
Zat (g/mol) pelarut (g) terlarut (g)
NaCl 58,44 0,5 10,0112 0,2959 -2
KCl 74,56 0,5 10,0262 0,3700 -2

C. Pengolahan Data
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1. Penentuan Berat Molekul Larutan Sukrosa

 Larutan Sukrosa ±1 molal
∆ Tb = molal × Kb
massaterlarut 1000
∆ Tb= × × Kb
BM massa pelarut
g
1000
3,4272 g kg ℃
3 ℃= × ×1,86
BM 10,1994 g molal
BM = 208,3323 g/mol
 Larutan Sukrosa ±0,5 molal
∆ Tb = molal × Kb
massaterlarut 1000
∆ Tb= × × Kb
BM massa pelarut
g
1000
1,7239 g kg ℃
2 ℃= × ×1,86
BM 10,0635 g molal
BM = 159,3111 g/mol

BM percobaan 1+ BM percobaan 2
BM percobaan rata-rata =
2
g g
208,3323 +159,3111
= mol gmol
2
= 183,8217 g/mol
BM percobaan−BM teoritis
Ralat = × 100%
BM teoritis
183,8217−342
= × 100%
342
= 46,25 %

2. Penentuan Berat Molekul Larutan Urea

 Larutan Urea ±1 molal
∆ Tb = molal × Kb
massaterlarut 1000
∆ Tb= × × Kb
BM massa pelarut
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g
1000
0,6393 g kg ℃
2 ℃= × ×1,86
BM 10,1946 g molal
BM = 58,3200 g/mol
 Larutan Urea ±0,5 molal
∆ Tb = molal × Kb
massaterlarut 1000
∆ Tb= × × Kb
BM massa pelarut
g
1000
0,2991 g kg ℃
1 ℃= × × 1,86
BM 10,0639 g molal
BM = 55,2794 g/mol

BM percobaan 1+ BM percobaan 2
BM percobaan rata-rata =
2
g g
58,3200 +55,2794
= mol gmol
2
= 56,7997 g/mol
BM percobaan−BM teoritis
Ralat = × 100%
BM teoritis
56,7997−60
= × 100%
60
= 5,33 %

3. Penentuan Faktor van’t Hoff Larutan NaCl ±0,5 molal

∆ Tb = molal × Kb × i
massaterlarut 1000
∆ Tb= × × Kb × i
BM massa pelarut
g
1000
0,2959 g kg ℃
2 ℃= × ×1,86 ×i
g 10,0112 g molal
58,44
mol
i = 2,1260
Perhitungan faktor van’t Hoff NaCl Teoritis
NaCl Na+ + Cl-
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n = 1+1 =2
i =1+ (n-1)α
i = 1 + ( 2-1) × 1
i=2
i percobaan−iteoritis
Ralat = × 100%
i teoritis
2,1260−2
= × 100%
2
= 6,30 %

4. Penentuan Faktor van’t Hoff Larutan KCl ±0,5 molal

∆ Tb = molal × Kb × i
massaterlarut 1000
∆ Tb= × × Kb × i
BM massa pelarut
g
1000
0,3700 g kg ℃
2 ℃= × ×1,86 ×i
g 10,0262 g molal
74,56
mol
i = 2,1725
Perhitungan faktor van’t Hoff KCl Teoritis
KCl K+ + Cl-
n = 1+1 =2

i =1+ (n-1)α
i = 1 + ( 2-1) × 1
i=2
i percobaan−iteoritis
Ralat = × 100%
i teoritis
2,1725−2
= × 100%
2
= 8,62 %