1. Complete the table for the reaction that take place in the test tubes below.
Bromine
water
Iron(III) chloride
solution
Iron(II) solution
sulphate zinc
solution
Observation
Half-equation
oxidation
Half equation
reduction
Overall equation
Confirmatory test
1
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
2.
Bromine water
Iron(II) sulphate
solution
Diagram 1
A few drops of bromine water is added into iron(II) sulphate solution. The mixture is shaken
and heated slowly as shown in diagram 1.
…………………………………………………………………………………………………………..
c) State the substance that is oxidized and the substance that is reduced.
…………………………………………………………………………………………………………..
…………………………………………………………………………………………………………..
f) State the observation occur when sodium hydroxide solution is added into the mixture.
…………………………………………………………………………………………………………..
2
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
3. Excess of zinc is added into iron(III) chloride solution. The mixture is then heated
slowly.
Zinc
a) Write the half equation for
c) State the substance that is oxidized and the substance that is reduced.
1. Rusting occur in the presence of water droplets on the surface of iron metal and oxygen
in air . The centre of water droplet serves as …………….. , where iron metal undergoes
.................... . Iron .......................... electrons and change into........................... .
3
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
The iron surface at the surrounding of water droplet acts as……… ….. . The electrons
are received by the dissolved ……………………. . Oxygen is reduced into …………….. .
Agarl
+
Potassium hexacynoferrate(III) solution
+
Phenolphtalein
Test Metal pairing Intensity of dark blue Intensity of the pink colour.
tube spot
A Iron nail only A few number of dark
None
blue spot
B Iron nail and No dark blue spot
Very high
magnesium ribbon
C Iron nail and copper Many dark blue spot
None
strip
a) Write the formula of the metal ion that is formed when iron nail rusts.
…………………………………………………………………………………………………………..
b) Write the ionic equation of the rusting process.
…………………………………………………………………………………………………………..
4
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
…………………………………………………………………………………………………………..
d) Why does potassium hexacynoferrate(III) solution used in this investigation?
…………………………………………………………………………………………………………..
e) Based on the observation, which test tube shows that rusting has not occured?
…………………………………………………………………………………………………………..
f) Name the metal that can prevent rusting of iron. Explain your answer.
…………………………………………………………………………………………………………..
…………………………………………………………………………………………………………..
…………………………………………………………………………………………………………..
h) Name the ion that causes the pink colour to form in the mixture.
…………………………………………………………………………………………………………..
Electrolytic cell
1. An electrolytic cell is prepared as shown in diagram 2 by using carbon electrodes that are
immersed in copper(II) sulphate solution 0.1 moldm-3 .
Carbon
electrodes
Copper(II)
sulphate solution
i) anode :
ii) cathode :
b) Name the product that is formed at
i) anode :
ii) cathode :
c) Write the half equation of anode and cathode.
5
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
i) anode :
ii) cathode :
d) Determine the type of reactions that occur at anode and cathode.
i) anode :
ii) cathode :
e) State the electron transfer in this experiment.
i) oxidising agent :
Chemical cell
A Daniel cell is prepared as shown in diagram 3. Zinc plate and copper plate are dipped into
zinc sulphate solution and copper(II) sulphate solution respectively. The zinc and copper
plate is connected to an ammeter with connecting wires. The solutions are separated by
porous pot.
V
Porous pot
berliang
Zinc plate
Copper plate
Zinc sulphate
solution
Copper(II) sulphate
solution
i) negative terminal :
6
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
i) negative terminal :
i) negative terminal :
i) negative terminal :
h) State what happen to the ammeter reading if zinc plate and zinc sulphate solution are
replaced with magnesium ribbon and magnesium sulphate solution?
1. Figure 1 shows the set-up apparatus to investigate redox reaction between potassium
iodide solution and chlorine water.
M N
Dilute sulphuric
acid
7
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
b) What is expected to be observed around electrode M after ½ hour the experiment has
taken place?
i) reduction :
ii) oxidation :
e) Write the ionic equation for the reaction that occurs in this experiment.
g) Name one substance that can replace chlorine water in order to get the same products at
electrode M.
h) If potassium iodide is replaced with iron(II) sulphate solution, what will be observed at
electrode M. Explain your answer.
…………..……………………………………………………………………………………..
…..……………………………………………………………………………………………..
iii) Explain the difference between the names of the two compounds based on the
IUPAC nomenclature system.
…….……………………………………………………………………………………………..
…….……………………………………………………………………………………………..
8
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
Dilute sulphuric
acid, H2SO4
……………………………………………………………………………………………………..
ii) Write the half equation for the reaction that occur at the negative and positive
terminals.
……………………………………………………………………………………………………..
iii) Based on your answer in 2(b)(ii), describe the oxidation and reduction process in
terms of the electron transfer that occurs at the negative and positive terminals.
State also the changes that can be observed after 10 minutes.
9
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
Figure 1 shows an experiment to investigate the reactivity of metals P, Q and R with oxygen.
P Q R
Heat
Hydrogen peroxide
Manganese(IV)
oxide
The observations of the experiment are shown in Table 1.
Metal Observation
P Burns brightly and produces a yellow powder
when hot and becomes white when cooled.
Q Burns with clear luminous flame and produces
white powder
R Glows faintly. The residue is black
i) manipulated variable :
i) metal P :
ii) metal Q :
e) Chemical formula of R oxide is RO. This oxide can be reduced by hydrogen gas to form
metal R.
10
TUISYEN IBNU SINA CHEMISTRY MODULE 17
OXIDATION AND REDUCTION
ii) Write the chemical equation for the reaction between RO and hydrogen gas.
iii)) Name the oxidising agent and the reducing agent in this experiment.
Oxidising agent :
Reducing agent :
Mixture of
Crucible
substances
ribbon
ii) Based on the observation, arrange lead, zinc and iron according to the reactivity of the
metals in decreasing order.
……………………………………………………………………………………………..
11