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Bateleur arms

A ballistic vest or bullet-proof vest is an item of armour that absorbs the impact from gun-
fired projectiles and explosive fragments fired at the torso. Soft vests made from layers of
tightly-woven fibres protect wearers from projectiles fired from handguns, shotguns, and
shrapnel from explosives such as hand grenades. When metal or ceramic plates are used with
a soft vest, it can also protect wearers from shots fired from rifles. Soft vests are commonly
worn by police forces, private citizens and private security guards, and hard-plate reinforced
vests are mainly worn by combat soldiers in the armies of various nations as well as armed
response police forces.

Modern body armour may combine a ballistic vest with other items of protective clothing,
such as a helmet. Vests intended for police and military use may also include ballistic
shoulder armour for more protection and leg armour for protection against grenade blasts.

Performance standards

Vests may be augmented with metal (steel or titanium), ceramic or polyethylene plates that
provide extra protection to vital areas. These hard armour plates have proven effective against
all handgun bullets and a range of rifles. These "tactical body armour" vests have become
standard in military use, as soft body armour vests are ineffective against most military rifle
rounds. The CRISAT NATO (Collaborative Research Into Small Arms Technology-North
Atlantic Treaty Organization) standard for body armour specifies the use of titanium backing.
This titanium plate may be removable or sewn in.

A vest does not protect the wearer by deflecting bullets. Instead, the layers of material catch
the bullet and spread its force over a larger portion of the body, absorbing energy more
quickly and hopefully bringing it to a stop before it can penetrate into the body. This tends to
deform the bullet, further reducing its ability to penetrate. While a vest can prevent bullet
wounds, the wearer still absorbs the bullet's energy, which can cause blunt force trauma. The
majority of users experience only bruising, but impacts can still cause severe internal injuries.

Most vests offer little protection against arrows, ice picks, stabbing knife blows, bullets with
their points sharpened or armour-piercing rounds. As the force is concentrated in a relatively
small area with bladed weapons and armour-piercing rounds, they can push through the
weave of most bullet-resistant fabrics. Specially-designed vests which protect against bladed
weapons and sharp objects are often used in vests for prison guards and other law
enforcement officers. Some materials like Dyneema offer considerable protection against
bladed weapons and slash attacks.
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Ballistic vests may provide little or no protection against rifle ammunition or even against
handgun ammunition fired from a pistol-calibre carbine. The exception is the common .22
LR ammunition, which can usually be stopped by these vests even when fired from a rifle.
These vests are usually protective against handgun ammunition fired from handguns of all
calibres, depending on the armour level of the vest.

History

Silk vests

The oldest bullet-resistant fabric vests were made from silk and they resembled medieval
padded jacks, which used 18 to 30 layers of cloth to protect wearers from arrow penetration.
In 1881 Dr. George Emery Goodfellow of Arizona witnessed a gunfight between two people.
When he examined one man who had been shot through his breast pocket, he found that the
bullet had been slowed by the layers of the man's silk handkerchief. Dr. Goodfellow
documented various other cases of silk fabric protecting people from gunshot wounds,
including a noted case where a man's bandanna saved his carotid artery from being severed.

Casimir Zeglen of Chicago, Illinois used Goodfellow's findings to develop a bullet-proof vest
made of silk fabric at the end of the 1800s. Zeglen's expensive vests could stop the relatively
slow rounds from black powder handguns. The vests cost $800 USD each in 1914, which is
equivalent to about $15,000 in 2005 dollars. On June 28, 1914, Franz Ferdinand, Archduke of
Austria, heir to the Austro-Hungarian throne was wearing a silk bullet-proof vest. However,
the vest did not protect him, because he was shot in the neck above the vest with a .32 ACP
bullet fired by Gavrilo Princip using a handgun.

During World War I, the United States developed several types of body armour, including the
chrome nickel steel Brewster Body Shield, which consisted of a breastplate and a headpiece
and could withstand Lewis Gun bullets at 2,700 ft/s (820 m/s), but was clumsy and heavy at
40 pounds (18 kg). Another type of body armour was designed in February 1918 by the
Metropolitan Museum of Art. This breastplate was based on armour of the 1400s, weighed 27
pounds (12 kg), and was considered too noisy and restricting. A scaled waistcoat of
overlapping steel scales fixed to a leather lining was also designed; this armour weighed 11
pounds (5 kg), fit close to the body, and was considered more comfortable.

During the late 1920s through the early 1930s, gunmen from criminal gangs in the United
States began wearing less-expensive vests made from thick layers of cotton padding and
cloth. These early vests could absorb the impact of handgun rounds such as .22, .25, S&W .
32 Long, S&W .32, .380 ACP, and .45 ACP travelling at slower speeds of up to
approximately 1000 ft/s (300 m/s). To overcome these vests, law enforcement agents such as
the FBI began using the new .357 Magnum cartridge.

World War II

In the early stages of World War II, the United States designed body armour for infantrymen,
but most models were too heavy and mobility-restricting. These armour vests were often
incompatible with existing equipment as well. The military diverted its research efforts to
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developing "flak jackets" for aircraft crews. These flak jackets were made of nylon fabric and
capable of stopping flak and shrapnel, but not bullets.

The Japanese army produced a few types of infantry body armour during World War II, but
they did not see much use. Near the middle of 1944, development of infantry body armour in
the United States restarted. Several vests were produced for the US military, including but not
limited to the T34, the T39, the T62E1, and the M12.

There were several models of body armour in the Red Army, called SN-38, SN-39, SN-40,
SN-40A, and SN-42 (The native Cyrillic abbreviation for the vest was СН, the Cyrillic letters
Es and En.) "Stalynoi Nagrudnik" is Russian for "steel breastplate", and the number denotes
the design year. All were combat tested, but only the SN-42 was put in production. It
consisted of two pressed steel plates that protected the front torso and groin. The plates were
2 mm and weighed 3.5 kg. This armour was supplied to SHISBr (assault engineers) and to
Tankodesantniki (infantry that rode on tanks) of some tank brigades. The SN armour
protected wearers from the German MP-40 9 mm bullet at around 100-125 meters, which
made it useful in urban battles (Stalingrad). However, the SN's weight made it impractical for
infantry on foot in an open outdoor setting, and the 7.92x57mm cartridges fired by the
Mauser Karabiner 98k and MG42 easily penetrated it.

During the Korean War several new vests were produced for the United States military,
including the M-1951 (Chriss Body, 2002), "a vast improvement on weight, but the armour
failed to stop bullets and fragments very successfully" (Military, 2004). The Vietnam war era
vests were simply various combinations of the nylon and were still not capable of stopping
Rifle rounds.

In 1969, American Body Armour was founded and began to produce a patented combination
of quilted nylon faced with multiple steel plates. This armour configuration was marketed to
American law enforcement agencies by the Smith & Wesson gun company under the trade
name "Barrier Vest". The "Barrier Vest" was the first police vest to gain wide use during high
threat police operations.

In the mid-1970s, the DuPont Corporation introduced (Kevlar) synthetic fibre, when woven
into a fabric and layered. Immediately Kevlar was incorporated into a National Institute of
Justice (NIJ) evaluation program to provide lightweight, concealable body armour to a test
pool of American law enforcement officers to ascertain if everyday concealable wearing was
possible. Lester Shubin, a program manager at the NIJ, managed this law enforcement
feasibility study within a few selected large police agencies, and quickly determined that
Kevlar body armour could be comfortably worn by police daily, and would save lives.

In 1975 Richard A. Armellino, the founder of American Body Armour marketed an all
Kevlar vest called the K-15, comprised of 15 layers of Kevlar that also included a 5" X 8"
ballistic steel "Shok Plate" positioned vertically over the heart and was issued U.S Patent
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#3,971,072 for this ballistic vest innovation. Similarly sized and positioned "trauma plates"
are still used today on the front ballistic panels of most concealable vests, reducing blunt
trauma and increasing ballistic protection in the centre-mass heart/sternum area.

In 1976, Richard Davis, founder of Second Chance Body Armor designed this company's
first all-Kevlar vest, named the Model Y. The lightweight, concealable vest industry was
launched and a new form of daily protection for the modern police officer was quickly
adapted. By the mid to late 1980s, an estimated 1/3 to 1/2 of police patrol officers wore
concealable vests daily. By the year 2006, more than 2,000 documented police vest "saves"
were recorded, validating the success and efficiency of lightweight concealable body armour
as a standard piece of everyday police equipment.

Kevlar soft armour had its shortcomings because if "large fragments or high velocity bullets
hit the vest, the energy could cause life-threatening, blunt trauma injuries" in selected, vital
areas (Military, 2004). So the Ranger Body Armor was developed for the American military
in 1994. Although it was the second modern US body armour that was able to stop rifle
calibre rounds and still be light enough to be worn by infantry soldiers in the field, it still had
its flaws: "it was still heavier than the concurrently issued PASGT (Personal Armor System
for Ground Troops) anti-fragmentation armour worn by regular infantry and ... did not have
the same degree of ballistic protection around the neck and shoulders" (Military, 2004). The
format of Ranger Body Armor (and more recent body armour issued to US special operations
units) highlights the tradeoffs between force protection and mobility that modern body
armour forces organizations to address.

The newer armour issued by the United States military to large numbers of troops is known
as Interceptor Multi-Threat Body Armor System. The Kevlar Interceptor vest is intended
mainly to provide shrapnel protection, but is rated for threats up to and including 9mm
submachine gun fire. Small Arms Protective Insert (SAPI) plates, made of ceramic materials,
are worn front and back and protect the vital organs from threats up to and including
7.62x51mm NATO rifle rounds.

Since the 1970s, several new fibers and construction methods for bullet-proof fabric have
been developed besides woven Kevlar, such as DSM's Dyneema, Honeywell's GoldFlex and
Spectra, Teijin Twaron's Twaron, Pinnacle Armor's Dragon Skin, and Toyobo's Zylon (now
controversial, as new studies report that it degrades rapidly, leaving wearers with
significantly less protection than expected). These newer materials are advertised as being
lighter, thinner and more resistant than Kevlar, although they are much more expensive.

Both the Underwriters Laboratories (UL Standard 752) and the United States National
Institute of Justice (NIJ Standard 0101.04) have specific performance standards for bullet
resistant vests used by law enforcement. The US NIJ rates vests on the following scale
against penetration and also blunt trauma protection (deformation) (Table from NIJ Standard
0101.04):
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Armour Level

Type I (.22 LR; .380 ACP)

This armour protects against 22 calibre Long Rifle Lead Round Nose (LR LRN) bullets, with
nominal masses of 2.6 g (40 gr) at a reference velocity of 329 m/s (1080 ft/s ± 30 ft/s) and .
380 ACP Full Metal Jacketed Round Nose (FMJ RN) bullets, with nominal masses of 6.2 g
(95 gr) at a reference velocity of 322 m/s (1055 ft/s ± 30 ft/s)

Type IIA (9 mm; .40 S&W)

This armour protects against 9 mm Full Metal Jacketed Round Nose (FMJ RN) bullets, with
nominal masses of 8.0 g (124 gr) at a reference velocity of 341 m/s (1120 ft/s ± 30 ft/s) and .
40 S&W calibre Full Metal Jacketed (FMJ) bullets, with nominal masses of 11.7 g (180 gr) at
a reference velocity of 322 m/s (1055 ft/s ± 30 ft/s). It also provides protection against the
threats mentioned in [Type I].

Type II (9 mm; .357 Magnum)

This armour protects against 9 mm Full Metal Jacketed Round Nose (FMJ RN) bullets, with
nominal masses of 8.0 g (124 gr) at a reference velocity of 367 m/s (1205 ft/s ± 30 ft/s) and
357 Magnum Jacketed Soft Point (JSP) bullets, with nominal masses of 10.2 g (158 gr) at a
reference velocity of 436 m/s (1430 ft/s ± 30 ft/s). It also provides protection against the
threats mentioned in [Types I and IIA].

Type IIIA (High Velocity 9 mm; .44 Magnum)

This armour protects against 9 mm Full Metal Jacketed Round Nose (FMJ RN) bullets, with
nominal masses of 8.0 g (124 gr) at a reference velocity of 436 m/s (1430 ft/s ± 30 ft/s) and .
44 Magnum Semi Jacketed Hollow Point (SJHP) bullets, with nominal masses of 15.6 g (240
gr) at a reference velocity of 436 m/s (1430 ft/s ± 30 ft/s). It also provides protection against
most handgun threats, as well as the threats mentioned in [Types I, IIA, and II].

Type III (Rifles)

This armour protects against 7.62 mm Full Metal Jacketed (FMJ) bullets (U.S. Military
designation M80), with nominal masses of 9.6 g (148 gr) at a reference velocity of 847 m/s
(2780 ft/s ± 30 ft/s) or less. It also provides protection against the threats mentioned in [Types
I, IIA, II, and IIIA].

Type IV (Armour Piercing Rifle)

This armour protects against .30 calibre armour piercing (AP) bullets (U.S. Military
designation M2 AP), with nominal masses of 10.8 g (166 gr) at a reference velocity of 878
m/s (2880 ft/s ± 30 ft/s). It also provides at least single hit protection against the threats
mentioned in [Types I, IIA, II, IIIA, and III].
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Bomb disposal officers often wear heavy armour designed to protect against most effects of a
moderate sized explosion, such as bombs encountered in terror threats. Full head helmet,
covering the face and some degree of protection for limbs is mandatory in addition to very
strong armour for the torso. An insert to protect the spine is usually applied to the back, in
case an explosion blasts the wearer. Visibility and mobility of the wearer may be severely
limited.

German standards allow for bullet impact depression of 20 millimetres on the mannequin's
wax body under the vest; US standards allow for more than twice that (44 millimetres), which
can be potentially lethal.

In addition, there are vests available for police dogs which offer a measure of protection for
the animals.An Aramid vest's material must not get wet, because it will lose its protective
capability until dry again, or in some cases be permanently degraded (water acts as a
lubricant, helping the bullet slip through between the fibres; it may also weaken the structure
of the fibre by breaking hydrogen bonds, see Kevlar for details). Most bullet-proof vests have
panels in sealed enclosures, but waterproofing is usually not perfect. Dyneema and Spectra
based vests do not have the same difficulties with water.

The future of bullet-proof vests

In recent years advances in material science have opened the door to the old idea of a literal
"bullet-proof vest" that will be able to stop handgun and rifle bullets without the assistance of
heavy and cumbersome extra metal or ceramic plating. Current soft body armour can stop
most handgun rounds. Plates are currently needed to stop rifle rounds and unique handgun
rounds such as 7.62x25. Research aims to develop artificial spider silk which could be super
strong, yet light and flexible. Other research has been done to harness nanotechnology to help
create super strong materials that could be used in future bullet-proof vests. Currently, there
are two methods by which nanomaterials are being implemented into body armour
production. The first is based on nanoparticles within the suit that become rigid enough to
protect the wearer as soon as a pressure threshold is surpassed, which the impact of a bullet
would register. These nano-infused suits are significantly lighter than alternative forms of
body armour because of the properties that govern them. The second was introduced in 2005
by American company ApNano. They developed a material that was always rigid, and
announced that this nanocomposite based on Tungsten Disulfide was able to withstand
shocks generated by a steel projectile travelling at velocities of up to 1.5 km/second. The
material was also reportedly able to withstand shock pressures generated by the impacts of up
to 250 tons per square centimetre. During the tests, the material proved to be so strong that
after the impact the samples remained essentially unmarred. Additionally, a recent study in
France tested the material under isostatic pressure and found it to be stable up to at least 350
tons/cm². As of mid-2006, spider silk bullet-proof vests and nano-based armours are being
developed for potential market release
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Legality

Body armour is legal in most countries. One exception is Australia, where body armour has
been prohibited for some time. This ban may have its origins in the late 19th century, when
the iconic Australian outlaw and folk hero Ned Kelly used home-made armour with mixed
results. While the steel armour worn by Kelly defeated the soft lead, low velocity bullets fired
by police Martini-Henry rifles, it greatly restricted his movement.

United States law restricts possession of body armour for convicted violent felons. Many US
states also have penalties for possession or use of body armour by felons. In February of
1999, the late Russell Jones a.k.a. "Ol' Dirty Bastard" was arrested in California for
possession of body armour by a convicted felon. In other states, such as Kentucky, they do
not prohibit possession, but deny probation or parole for a person convicted of certain violent
crimes while wearing body armour and carrying a deadly weapon.

Canadian legislation makes it legal to wear and to purchase body armour such as ballistic
vests. However, there are current proposals to the legislation to make it illegal to wear such
body armour during the commission of a criminal offence.

Blunt force trauma

In medical terminology, blunt trauma, blunt injury, non-penetrating trauma or blunt force
trauma refers to a type of physical trauma caused to a body part, either by impact, injury or
physical attack; the latter usually being referred to as blunt force trauma. The term itself is
used to refer to the precursory trauma, from which there is further development of more
specific types of trauma, such as contusions, abrasions, lacerations, and/or bone fracturing.

Variations

Abdominal Trauma (BAT)

Blunt abdominal trauma is often referred to as the most common type of trauma, representing
around 50 to 75 percent of blunt trauma. The majority of BAT is often attributed to car-to-car
collisions, in which rapid deceleration often propels the driver forwards into the steering
wheel or dashboard, causing contusions in less serious cases or rupturing of internal organs
due to briefly increased intraluminal pressure in more serious cases where speed or forward
force is greater.

Abdominal trauma caused by deceleration and impact shows a similar effect to trauma to any
other part of the body; namely the rupturing or damage of free and relatively fixed objects, a
classic example of such an injury would be a hepatic tear along the ligamentum teres
followed with injuries to the renal arteries.
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As with most trauma, blunt abdominal trauma is often the case of further injury, depending
upon the severity of the accident. In the majority of cases, the liver and spleen (see Blunt
splenic trauma) are most severely affected, followed by damage to the small intestine. Recent
studies utilizing CT scanning have suggested that hepatic and other concomitant injuries may
develop from blunt abdominal trauma.

In rare cases, BAT has been attributed to several medical techniques such as the heimlich
manoeuvre, attempts at cardiopulmonary resuscitation, and manual thrusts to a clear an
airway. Although these are rare causes of blunt abdominal trauma, it is often thought that
they are caused by applying unnecessary pressure when administering such techniques.

Diagnosis

Although blunt trauma is a condition in itself, the main emphasis on the diagnosis of blunt
trauma is to ascertain the cause of the accident, any further injury and its correlation with the
medical, dietary, and physiological history of the patient gathered from various sources, such
as family and friends, or previous physicians, in order to establish the most swift path to
recovery. This method is given the mnemonic "SITEMAP";

Social history and/or evidence of substance abuse

Usually, in the case of examination, areas such as the head or those linked with the
respiratory system have a higher priority, and are examined before the abdomen, so as to
administer, if necessary, medical treatments which will immediately limit the amount of
progressive damage which could be caused from such injuries. The amount of time spent on
diagnosing abdominal injury should be minimal, and expedited by using relatively quick
methods of determining the extent of such injury, such as by identifying free intra-abdominal
fluid through diagnostic peritoneal lavage (DPL) before recommending a laparotomy if the
situation requires one.

Treatment

Whenever any blunt trauma is sustained to the body, it is normal to ensure first that there is
no bleeding, internal or back injury, or breathing problems before administering any type of
rehabilitative care to the patient. In cases of car accidents, or where a patient has had some
form of accelerated impact, the likelihood is that there will be progressive damage to internal
organs, as well as the fracturing of bones, both of which are dealt with by splinting fractures
and controlling external hemorrhaging. Most cases require IV therapy along with other
methods of stabilisation such as securing the airway or providing a respirator.

Spider silk, also known as gossamer, is a fibre spun by spiders. Spider silk is a remarkably
strong material. Its tensile strength is comparable to that of high-grade steel — according to
Nature, spider dragline silk has a tensile strength of roughly 1.3 GPa, while one source lists a
tensile strength for one form of steel at 1.65 GPa. However, spider silk is much less dense
than steel; its tensile strength to density ratio is roughly five times higher than that of steel
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(i.e. it is five times as strong as steel of the same density — as strong as Aramid filaments,
such as Twaron or Kevlar.) In fact, a strand of spider silk long enough to circle the earth
would weigh less than 16 ounces (450 g).

Spiders normally use their silk to make structures, either for protection for their offspring, or
for predation on other creatures. They can also suspend themselves using their silk, normally
for the same reasons.

The trapdoor spider will burrow into the ground and weave a trapdoor-like structure with
spindles around so it can tell when prey arrives and take it by surprise.

Many small spiders use silk threads for ballooning. They extrude several threads into the air
and let themselves become carried away with upward winds. Although most rides will end a
few meters later, it seems to be a common way for spiders to invade islands. Many sailors
have reported that spiders have been caught in their ship's sails, even when far from land.

Structure of spider silk. Inside a typical fibre, one finds crystalline regions separated by
amorphous linkages. The crystals are beta-sheets that have assembled together.

Spider silk is also especially ductile, able to stretch up to 40% of its length without breaking.
This gives it a very high toughness (or work to fracture), which "equals that of commercial
polyaramid (aromatic nylon) filaments, which themselves are benchmarks of modern
polymer fibre technology."The notion that spider silk is stronger than any industrial fibre is a
common misconception as whilst some may be stronger, none are tougher (total energy to
break). Numerous artificial fibres are similar or stronger, notably aramids like Kevlar and
carbon fibre materials (see tensile strength for common comparisons). Nonetheless, there is
much interest in duplicating the silk process artificially, since spiders use renewable materials
as input and operate at room temperature, low pressures and using water as a solvent. Spider
silk can be harvested in large scale quantities if one has proper harvesting equipment. One
can also make near-indestructible spider silk threads by weaving the fine threads into thicker
and more durable weaves in the same fashion as other industrial threads.Spider silk is
composed of complex protein molecules. This, coupled with the isolation relating from the
spider's predatory nature, has made the study and replication of the substance quite
challenging. Because of the repetitive nature of the DNA encoding the silk protein, it is
difficult to determine its sequence and to date, silk-producing sequences have only been
decoded for fourteen species of spider. In 2005, independent researchers in the University of
Wyoming (Tian and Lewis), University of the Pacific (Hu and Vierra), the University of
California at Riverside (Garb and Hayashi) and Shinshu University (Zhao and Nakagaki)
have uncovered the molecular structure of the gene for the protein that various female spider
species use to make their silken egg cases.Although different species of spider, and different
types of silk, have different protein sequences, a general trend in spider silk structure is a
sequence of amino acids (usually alternating glycine and alanine, or alanine alone) that self-
assemble into a beta sheet conformation. These "Ala rich" blocks are separated by segments
of amino acids with bulky side-groups. The beta sheets stack to form crystals, whereas the
other segments form amorphous domains. It is the interplay between the hard crystalline
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segments, and the elastic semi amorphous regions, that gives spider silk its extraordinary
properties.

Synthesis

The unspun silk dope is pulled through silk glands, resulting in a transition from stored gel to
final solid fibre. Many species of spider have different glands for different jobs, such as
housing and web construction, defence, capturing and detaining prey, mobility and in
extreme cases even as food. Thus, different specialized silks have evolved with material
properties optimized for their intended use.

The gland's visible, or external, part is termed the spinneret. Depending on the species,
spiders will have anything from two to eight spinnerets, usually in pairs. The beginning of the
gland is rich in thiol and tyrosine groups. After this beginning process, the ampulla acts as a
storage sac for the newly created fibres. From there, the spinning duct effectively removes
water from the fibre and through fine channels also assists in its formation. Lipid secretions
take place just at the end of the distal limb of the duct, and proceeds to the valve. The valve is
believed to assist in rejoining broken fibres, acting much in the way of a helical pump.

Various compounds other than protein are used to enhance the fibre's properties. Pyrrolidine
has hygroscopic properties and helps to keep the thread moist. It occurs in especially high
concentration in glue threads. Potassium hydrogen phosphate releases protons in aqueous
solution, resulting in a pH of about 4, making the silk acidic and thus protecting it from
fungus and bacteria that would otherwise digest the protein. Potassium nitrate is believed to
prevent the protein from denaturating in the acidic milieu.

Human use

Peasants in the southern Carpathian Mountains used to cut up tubes built by Atypus and
cover wounds with the inner lining. It reportedly facilitated healing, and even connected with
the skin. This is believed to be due to antiseptic properties of spider silk (which is made of
protein) Some fishermen in the indo-pacific ocean use the web of Nephila to catch small fish.
Spider silk, normally that of the golden orb spider, is occasionally harvested and spun into
usable textiles. Due to the difficulty of the process, the resulting fabric is invariably
extremely expensive, and is generally utilized in medical applications.

Artificial spider silk

Spider silk's properties have made it the target of industrial research efforts. It is not generally
considered possible to use spiders themselves to produce industrially useful quantities of
spider silk, due to the difficulties of managing large quantities of small spiders (although it
was tried with Nephila silk). Compared with silkworms, spiders are aggressive and will eat
one another, making it inadvisable to keep many spiders together in the same space. Other
efforts have involved extracting the spider silk gene and using other organisms to produce the
required amount of spider silk. In 2000, Nexia, a Canadian biotechnology company, was
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successful in producing spider silk protein in transgenic goats. These goats carried the gene
for spider silk protein, and the milk produced by the goats contained significant quantities of
the protein. Attempts to spin the protein into a fibre similar to natural spider silk failed,
however. The spider's highly sophisticated spinneret is instrumental in organizing the silk
proteins into strong domains. Specifically, the spinneret creates a gradient of protein
concentration, pH, and pressure, which drive the protein solution through liquid crystalline
phase transitions, ultimately generating the required silk structure (which is a mixture of
crystalline and amorphous biopolymer regions). Replicating these complex conditions in lab
environment has proved difficult. Nexia attempted to press the protein solution through small
extrusion holes in order to simulate the behaviour of the spinneret, but this was insufficient to
properly organize the fibres. Ultimately, Nexia was forced to abandon research on artificial
spider silk, despite having successfully created the silk protein in genetically modified
organisms. Extrusion of protein fibres in an aqueous environment is known as 'wet-spinning'.
This process has so far produced silk fibres of diameters ranging from 10-60 μm, compared
to diameters of 2.5-4 μm seen in natural spider silk.

Nanocomposites are materials that are created by introducing nanoparticulates (often referred
to as filler) into a macroscopic sample material (often referred to as the matrix). This is part
of the growing field of nanotechnology. After adding nanoparticulates to the matrix material,
the resulting nanocomposite may exhibit drastically enhanced properties. For example,
adding carbon nanotubes tends to drastically add to the electrical and thermal conductivity.
Other kinds of nanoparticulates may result in enhanced optical properties, dielectric
properties or mechanical properties such as stiffness and strength. In general, the
nanosubstance is dispersed into the matrix during processing. The percentage by weight
(called mass fraction) of the nanoparticulates introduced is able to remain very low (on the
order of 0.5% to 5%) due to the incredibly high surface area to volume ratio of
nanoparticulates. Much research is going into developing more efficient combinations of
matrix and filler materials and into better controlling the production process.

Aramid

Aramid fibres are a class of heat-resistant and strong synthetic fibres. They are used in
aerospace and military applications, for ballistic rated body armour fabric, and as an asbestos
substitute. The name is a shortened form of "aromatic polyamide". They are fibres in which
the chain molecules are highly oriented along the fibre axis, so the strength of the chemical
bond can be exploited.

History

Aromatic polyamides were first introduced in commercial applications in the early 1960s,
with a meta-aramid fibre produced by DuPont under the trade name Nomex. This fibre,
which has the hand of normal textile apparel fibres, is characterised by its excellent resistance
to heat, as it neither melts nor ignites in normal levels of oxygen. It is used extensively in the
production of protective apparel, air filtration, thermal and electrical insulation as well as a
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substitute for asbestos. Meta-aramid is also produced in the Netherlands and Japan by Teijin
under the trade name Teijinconex, in China by Yantai under the trade name New Star and a
variant of meta-aramid in France by Kermel under the trade name Kermel.

Based on earlier research by Monsanto and Bayer, a fibre - para-aramid - with much higher
tenacity and elastic modulus was also developed in the 1960s-1970s by DuPont and Akzo
Nobel, both profiting from their knowledge of rayon, polyester and nylon processing.

Much work was done by Stephanie Kwolek in 1961 while working at DuPont, and that
company was the first to introduce a para-aramid called Kevlar in 1973. A similar fibre called
Twaron with roughly the same chemical structure was introduced by Akzo in 1978. Due to
earlier patents on the production process, Akzo and DuPont had a patent war in the 1980s.
Twaron is currently owned by the Teijin company (see Production).

Para-aramids are used in many high-tech applications, such as aerospace and military
applications, for "bullet-proof" body armour fabric.

The Federal Trade Commission definition for aramid fibre is:

A manufactured fibre in which the fibre-forming substance is a long-chain synthetic

polyamide in which at least 85% of the amide linkages, (-CO-NH-) are attached directly to
two aromatic rings.

Production

World capacity of para-aramid production is estimated at about 41.000 tons/yr in 2002 and
increases each year by 5-10%. In 2007 this means a total production capacity of around
55.000 tons/yr.

Polymer preparation

Aramids are generally prepared by the reaction between an amine group and a carboxylic
acid halide group. Simple AB homopolymers may look like:

nNH2-Ar-COCl → -(NH-Ar-CO)n- + nHCl

The most well-known aramids (Nomex, Kevlar and Twaron) are AABB polymers. Nomex or
Teijinconex contain predominantly the meta-linkage and are poly-metaphenylene
isophtalamides (MPIA). Kevlar and Twaron are both p-phenylene terephtalamides (PPTA),
the simplest form of the AABB para-polyaramide. PPTA is a product of p-phenylene diamine
(PPD) and terephtaloyl dichloride (TDC or TCl). Production of PPTA relies on a co-solvent
with an ionic component (calcium chloride (CaCl2)) to occupy the hydrogen bonds of the
amide groups, and an organic component (N-methyl pyrrolidone (NMP)) to dissolve the
aromatic polymer. Prior to the invention of this process by Leo Vollbracht, who worked at
the Dutch chemical firm Akzo, no practical means of dissolving the polymer was known. The
use of this system led to a patent war between Akzo and DuPont.
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Spinning

After production of the polymer, the aramid fibre is produced by spinning the solved polymer
to a solid fibre from a liquid chemical blend. Polymer solvent for spinning PPTA is generally
100% (water free) sulphuric acid (H2SO4).

Other types of aramids

Beside meta-aramids like Nomex, other variations belong to the aramid fibre range. These are
mainly of the copolyamide type, best known under the brand name Technora, as developed
by Teijin and introduced in 1976. The manufacturing process of Technora reacts PPD and
3,4'-diaminodiphenylether (3,4'-ODA) with terephtaloyl chloride (TCl). This relatively
simple process uses only one amide solvent and therefore spinning can be done directly after
the polymer production.

Aramid fibre characteristics

Aramids share a high degree of orientation with other fibres such as Ultra high molecular
weight polyethylene, a characteristic which dominates their properties.

General:

good resistance to abrasion

good resistance to organic solvents

nonconductive

no melting point, degradation starts from 500°C

low flammability

good fabric integrity at elevated temperatures

sensitive to acids and salts

sensitive to ultraviolet radiation

prone to static build-up unless finished

Para-aramids:

para-aramid fibres such as Kevlar and Twaron, provide outstanding strength-to-weight

properties

high Young's modulus

high tenacity
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low creep

low elongation at break (~3.5%)

difficult to dye - usually solution dyed

Ultra high molecular weight polyethylene (UHMWPE), also known as high modulus
polyethylene (HMPE) or high performance polyethylene (HPPE), is a thermoplastic. It has
extremely long chains, with molecular weight numbering in the millions, usually between 2
and 6 million. The longer chain serves to transfer load more effectively to the polymer
backbone by strengthening intermolecular interactions. This results in a very tough material,
with the highest impact strength of any thermoplastic presently made. It is highly resistant to
corrosive chemicals, with exception of oxidizing acids. It has extremely low moisture
absorption, very low coefficient of friction, is self lubricating and is highly resistant to
abrasion (15 times more resistant to abrasion than carbon steel). Its coefficient of friction is
significantly lower than that of nylon and acetal, and is comparable to teflon, but UHMWPE
has better abrasion resistance than teflon. It is odourless, tasteless, and non-
toxic.Polymerisation of UHMWPE was commercialised in the 1950s by Ruhrchemie AG,
which changed names over the years; today UHMWPE powder materials are produced by
Ticona. UHMWPE is available commercially either as consolidated forms, such as sheets or
rods, and as fibres. UHMWPE powder may also be directly moulded into the final shape of a
product. Because of its resistance to wear and impact, UHMWPE continues to find increasing
industrial applications, including the automotive and bottling sectors, for example. Since the
1960s, UHMWPE has also been the material of choice for total joint arthroplasty in
orthopaedic and spine implants .

UHMWPE fibres, commercialised in the late 1970s by the Dutch chemicals company DSM,
are widely used in ballistic protection, defence applications, and increasingly in medical
devices as well.

Structure and properties

Structure of UHMWPE, with n greater than 100,000

UHMWPE is a type of polyolefin and, despite relatively weak Van der Waals bonds between
its molecules, derives ample strength from the length of each individual molecule. It is made
up of extremely long chains of polyethylene, which all align in the same direction. Each
chain is bonded to the others with so many Van der Waals bonds that the whole can support
great tensile loads.

When formed to fibres, the polymer chains can attain a parallel orientation greater than 95%
and a level of crystallinity of up to 85%. In contrast, Kevlar derives its strength from strong
bonding between relatively short molecules.
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The weak bonding between olefin molecules allows local thermal excitations to disrupt the
crystalline order of a given chain piece-by-piece, giving it much poorer heat resistance than
other high-strength fibres. Its melting point is around 144 to 152 degrees Celsius, and
according to DSM, it is not advisable to use UHMWPE fibres at temperatures exceeding 80
to 100 °C for long periods of time. It becomes brittle at temperatures below -150 °C.

The simple structure of the molecule also gives rise to surface and chemical properties that
are rare in high-performance polymers. For example, the polar groups in most polymers
easily bond to water. Because olefins have no such groups, UHMWPE does not absorb water
readily, but it also does not get wet easily, which makes bonding it to other polymers
difficult. For the same reasons, skin does not interact with it strongly, making the UHMWPE
fibre surface feel slippery. Similarly, aromatic polymers are often susceptible to aromatic
solvents due to aromatic stacking interactions, an effect aliphatic polymers like Dyneema are
also immune to. Since Dyneema does not contain chemical groups (such as esters, amides or
hydroxylic groups) that are susceptible to attack from aggressive agents, it is very resistant to
water, moisture, most chemicals, UV radiation, and micro-organisms.

Under tensile load, UHMWPE will deform continually as long as the stress is present - an
effect called creep.

Annealing

To anneal UHMWPE the material should be heated to 135 °C to 138 °C in an oven or a liquid
bath of silicone oil or glycerine. The material must then be cooled down at a rate of 5 °C /
hour to at least 65 °C. Finally the material should be wrapped in an insulating blanket for 24
hours to bring to room temperature.

Production

UHMWPE is synthesized from monomers of ethylene, which are bonded together to form
what is called ultra high molecular weight polyethylene (or UHMWPE). These are molecules
of polyethylene which are several orders of magnitude longer than familiar high density
polyethylene due to a synthesis process based on metallocene catalysts. HDPE molecules
generally have between 700 and 1,800 monomer units per molecule, while UHMWPE
molecules tend to have 100,000 to 250,000 monomers each.

Finished UHMWPE is produced by 4 major methods: compression moulding, ram extrusion,

gel spinning, and sintering. The leading manufacturers of each process UHMWPE in
different ways:

compression moulding (Quadrant,PPD, Hutchinson, North American)

ram extrusion and fabrication (Quadrant, Garland Manufacturing, Artek)

gel spinning - armour and cordage (Dyneema)

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sintering - Medical (Quadrant, Solus, Perplas)

Dyneema fibres are made using a DSM patented (1979) method called gel spinning. A
precisely heated gel of UHMWPE is processed by an extruder through a spinneret. The
extruded is drawn through the air and then cooled in a water bath. The end result is a fibre
with a high degree of molecular orientation, and therefore exceptional tensile strength. Gel
spinning depends on isolating individual chain molecules in the solvent so that intermolecular
entanglements are minimal. Entanglements make chain orientation more difficult, and lower
the strength of the final product.

Capacity

Production capacity of DSM Dyneema is about 5000-6000 tons/yr by 2008 as the 10th
production line will be finished in 2008. 5 lines are located in Heerlen, The Netherlands and 5
in Greenville, North Carolina (USA).

Trade Names

Dyneema is a registered trademark of Royal DSM N.V. (The Netherlands). Dyneema was
invented by DSM in 1979. It has been in commercial production since 1990 at a plant in
Heerlen, the Netherlands. In the Far East, DSM has a cooperation agreement with Toyobo
Co. for commercial production in Japan. In the United States, DSM has a production facility
in Greenville, North Carolina which is the largest production facility in the United States for
UHMWPE fibre.

Honeywell developed a chemically identical product, which is sold under the brand name
Spectra. Though the production details are somewhat different, the resulting materials are
comparable in properties.

Other trade names for consolidated UHMWPE materials include TIVAR by Quadrant EPP
Inc., and Polystone-M by Röchling Engineering Plastics.

Usage

Fibre applications

Dyneema and Spectra are gel spun through a spinneret to form oriented-strand synthetic
fibres of UHMWPE which have yield strengths as high as 2.4 GPa and density as low as 0.97
kg/l (for Dyneema SK75). This gives a strength/weight ratio as much as 15 times stronger
than steel and up to 40% stronger than Aramid.

UHMWPE fibres are used in bullet-proof vests, bow strings, climbing equipment, fishing
line, spear lines for spear guns, high performance sails, suspension lines on sport parachutes,
rigging in yachting, kites and kites lines for kites sports. Spectra is also used as a high-end
Wakeboard line.
 drwerwolf7ARMOUR specifation level 1.

For body armour, the fibres are generally aligned and bonded into sheets, which are then
layered at various angles to give the resulting composite material strength in all directions.
Recently developed additions to the US Military's Interceptor body armour, designed to offer
arm and leg protection, are said to utilise a form of Spectra or Dyneema fabric.

Spun UHMWPE fibres excel as fishing line as they have less stretch, are more abrasion
resistant, and are thinner than traditional monofilament line.

Equipment used for climbing includes cord and webbing made of combinations of Dyneema
and nylon yarns. Dyneema "Slings", multi-purpose sewn loops of webbing, have gained
popularity for their low weight and bulk, though unlike their nylon counterparts they exhibit
very low elasticity, making them unsuitable for limiting forces in a fall. Also, low elasticity
translates to low toughness. Dyneema's very high lubricity leads to poor knot holding ability,
and has led to the recommendation to use the triple fisherman's knot rather than the
traditional double fisherman's knot in 6mm Dyneema core cord to avoid a particular failure
mechanism of the double fisherman's, where first the sheath fails at the knot, then the core
slips through.It is also used in both skis, and snowboards often in combination with carbon
fibre, reinforcing the fibreglass composite material, adding stiffness and improving its flex
characteristics. The UHMWPE is often used as the base layer, that contacts the snow and is
structured with abrasives to absorb and retain wax.High-performance ropes for sailing and
parasailing are made of Dyneema as well. Dyneema is the preferred material for sport kite
lines for two main reasons. First the low stretch means that control inputs to the kite are
transferred quickly and secondly the low friction allows the kite to remain controllable up to
about ten twists in the line.

Dyneema was used for the 30-kilometre space tether in the failed ESA/Russian Young
Engineers' Satellite 2 of September, 2007.

The extremely low friction coefficient of UHMWPE makes it a common top sheet for boxes
in terrain parks.