Horton E. Newsom
somewhat better. Agreement between the averaged Mainz C1’~0(%0 relative to SMOW)
data and UCLA data, and the Anders and Grevesse [4] data
for most of the elements is generally better than plus or
minus 3%. Earlier compilations of CI data include Anders
and Ebihara [3], and Palme et al. [Sl].
The isotopic composition of the solar system reported by
Clark [ 181 has also been updated by Anders and Grevesse
[4, Table 31. Some solar system material contains elements
whose isotopic systems exhibit anomalies or evidence of
extinct radionuclides, which have been interpreted in terms
of different presolar contributions to the solar nebula [e.g.
391. The origin by nuclear or chemical processes of the
most widespread of the isotopic anomalies, the variations in
oxygen isotopes, is still in doubt [71]. Clayton et al. [20]
argued that two gaseous reservoirs, one “terrestrial”, one IhO
rich, are required to explain the O-isotope variations in
meteorites. Whatever their origin, the variations in the
ratios of ‘70/‘h0 and ‘sO/lhO (Figure 2) is the most useful
system for distinguishing different planetary materials. The
terrestrial fractionation line is due to mass fractionation of Fig. 2. The relationship between &I70 and 6”O for the
the 0 isotopes in terrestrial materials. The carbonaceous Earth, Moon, and meteorites from [69] with permission.
chondrite anhydrous minerals line may represent mixing be- The terms aI70 (%o relative to SMOW) and 6”O (%OO
tween different components. The Earth and Moon fall on relative to SMOW) refer to the ratios of ‘70/1h0 and “O/‘“O,
the same fractionation line, possibly indicating a close expressed in parts per thousand relative to Standard Mean
relationship between the two bodies. Ocean Water.
During the formation of the solar system, the material
now in the terrestrial planets and meteorites lost substantial
amounts of the gaseous elements, such as H and He. Great other chemical variations. Much of the material was also
diversity in different meteorite types was established due to thermally processed, resulting in chemical signatures of
variable oxidation states in different nebula reservoirs, and evaporation and condensation that are recorded in the
because fractionations of different solid components led to meteorites and planets. Some of the thermal events were of
a transient nature, resulting in the formation of the round
.PI
- - silicate chondrules characteristic of most chondritic meteor-
ites. Surprisingly, the CI chondrites do not contain chon-
drules, but they do contain fragments of what are interpreted
(
.
to have originally been chondrules. The thermal events
resulted in chemical fractionations that can be best char-
..
.
” 4
. acterized by the calculated condensation temperature, which
.
. 4 is a measure of volatility. These condensation temperatures
+ . “@
1
.
.
. represent the temperature at which 50% of the element
’ :
0. would be condensed from a system with a bulk solar system
,I .
I.
, composition at a given pressure (Table 1).
.
. The chemical elements can be classified based on their
. condensation temperature [50, Table 11: 1. The refractory
elements (Ca, Al, Ti, Zr, REE, Ir, OS, etc.) make up about
5% of the total condensible matter. 2. Mg-silicates (forster-
0 10 20 30 40 50 60 70 80 90 100
ite Mg,SiO,, enstatite MgSiO,) and metal (FeNi) represent
the major fraction of condensible matter. 3. Moderately
Atomic Number, Z
volatile elements (Na, K, Cu, Zn, etc.) have condensation
Fig. 1. Comparison of photospheric (“solar”) and solar- temperatures, from below Mg-silicate and FeNi, down to S
system (“meteoritic”) abundances from [4] with permission. (as FeS). 4. Highly volatile elements (In, Cd, Pb, etc) have
NEWSOM 161
condensation temperatures below FeS. Variations in the siderophile elements (elements with an affinity for iron
abundances of these different groups of elements are also metal) are enriched or depleted by a factor of two between
characteristic of the different meteorite groups. the metal-depleted LL chondrites and the metal-enriched CH
Meteorites can be divided into two major types, chon- chondrites [ 131. Siderophile element abundances are often
drites, which never experienced wholesale melting after depleted in differentiated bodies because of core formation.
accretion from the solar nebula, and achondrites, which are Figure 3 illustrates the depletions of volatile elements in the
igneous rocks that are thought to be the result of melting CM chondrites and the Bulk Silicate Earth (BSE) composi-
and crystallization on their parent asteroids. Classification tion. The additional depletion of siderophile elements (both
schemes from Wasson [79] are shown in Tables 4 and 5, refractory and volatile) in the BSE due to core formation is
and also discussed by Sears and Dodd [62]. Data for some evident in Figure 3.
types of chondritic meteorites other than CI are listed in
Table 6. [80]. The CI, CM, CO, CK and CV chondrites are 3. ASTEROIDS
called carbonaceous chondrites, because of their dark
appearance and high C content. These meteorites are also Meteorites are thought to come from parent bodies in the
highly oxidized, The CI chondrites contain essentially no asteroid belt between Mars and Jupiter (exceptions include
iron metal. The H, L and LL chondrites are called the the SNC meteorites, probably from Mars, see below, and
ordinary chondrites because they are the most abundant lunar meteorites). Spectrophotometry of asteroids has
types of meteorites in the world’s collections; they are also resulted in the development of classification schemes which
intermediate in oxidation state. The EH and EL chondrites reflect the chemical and mineralogical nature of the aster-
are highly reduced enstatite chondrites, which contain oids. The possible connection between known meteorite
essentially no oxidized iron. Several new types of chond- types and asteroid spectral types is described in Table 7.
ritic meteorites are in the process of being characterized. An unanswered question is whether these meteorites
Data for a limited number of elements for the CK (Karoon- originally accreted in the asteroid belt, or whether their
da-type) carbonaceous chondrites are listed in Table 6 [36]. parent asteroids were transported from other parts of the
The CK meteorites have refractory enrichments intermediate solar system to the asteroid belt and stored in their present
between the CV and CO, CM classes. Their oxygen iso- location? The regular distribution of asteroid types in the
topes are similar to CO chondrites, and the olivine composi- asteroid belt (Figure 4) suggests that the asteroids have not
tions range from Fa 29-33 [36]. Other groups of chondrites
are the CR (Renazzo-type) carbonaceous chondrites [83, 131,
the R (Carlisle Lakes) chondrites, which have more affini-
ties with ordinary and enstatite chondrites [61], the Kakan-
gari-type chondrites [84] and the Bencubbin-Weatherford
chondrites [85]. The CH chondrites (ALH85085, ACFER
182, and paired samples ACFER 207 and ACFER 214) are
enriched in Fe metal and siderophile elements [ 131. CM chondritcs
Chondritic meteorites provide information about the Cithophlles Bulk
chemical fractionations and processes that occurred in the S~lmte Earth
solar nebula, and the nature of the building blocks for the Siderophiles Bulk
SIllcab Earlh
planets [37, part 71. Solar system material has been affected
by different fractionation processes during the formation of
0001 i : / : I
the solar system, and within the terrestrial planets [50]. 400 900 1400 1900
These fractionations were caused by variations in the Condensation Temperature(K)
abundance of refractory components, olivine, iron metal, and
loss of volatile elements during condensation or heating. Fig. 3 Plot of the log ratio of the abundance of all elements
Refractory elements vary by a factor of two within chond- in CM chondrites (Table 2) and in the Bulk Silicate Earth
ritic meteorites due to variations in high temperature [56, Table 71, normalized to CI chondrites [4, Table 11, and
condensates, such as Ca, Al-rich inclusions in carbonaceous plotted versus the 50% condensation temperature of the ele-
chondrites. Variations of MglSi ratios by 30% in chondrites ments at 10e4atm total pressure, a measure of the volatility
are ascribed to fractionation of olivine. The depletion of of the elements [80]. The figure illustrates the depletion of
volatile elements relative to CI chondrite abundances is volatile elements in the CM chondrites and the Bulk Silicate
observed in chondritic meteorites, and in the compositions Earth, as well as the additional depletion of siderophile ele-
of differentiated planets and asteroids. The abundances of ments in the Bulk Silicate Earth.
162 COMPOSITION OF THE SOLAR SYSTEM
been widely transported, which implies that the meteorites reflectivity are similar to C-type asteroids, although their
in our collections are probably originally derived from a origin as captured asteroids is not completely certain [16].
limited portion of the solar system. The relationship between the esitimated compositions of the
The achondrite meteorites are igneous rocks and include planets and the solar system composition, provide clues to
several varieties. The Howardite, Eucrite and Diogenite the formation of the planets. For example, the high me-
clan, which are thought to come from the same parent body, tal/silicate ratio for Mercury and the low ratio for the Moon
called either the HED parent body, or the Eucrite Parent suggests the role of giant impacts.
Body (EPB). The Eucrite meteorites are basalts containing 4.1. Mercury, Venus
plagioclase and pyroxene, the Diogenites are ultramafic The compositions of Mercury and Venus are not well
rocks containing pyroxene and olivine, while the Howardites known (Table 9). For Mercury the available data includes
are brecciated mixtures of material similar to Eucrites and density information and very limited spectroscopic informa-
Diogenites. Thus the EPB meteorites represent portions of tion suggesting a low Fe0 content (< 5.5 wt%) [26]. The
the parent bodies’ crust. The EPB meteorites record high mean density of Mercury (5.43 g cmm3)sets this planet
evidence of core formation and igneous processes that apart from the other terrestrial planets, and implies an iron
occurred soon after the formation of the solar system [30]. rich core making up 65 wt% to 68 wt% of the planet [7].
Lead isotope data suggest that the EPB samples crystallized Based on this information and cosmochemical constraints,
shortly after the formation of the most primitive meteorites. several authors have come to the conclusion that the high
For example, data for the Juvinas eucrite suggests a melting density probably cannot’have been produced by a simple
age of 4.539 Z!Z0.004 Ga, only 20 Ma after the formation of
the Allende carbonaceous chondrite.
The bulk composition of the Eucrite Parent Body has
been estimated (Table S), although the lack of mantle rocks
from the EPB is a great handicap. Dreibus and Wanke [23] b
estimated the bulk composition by using mixing diagrams
for EPB meteorites to obtain a composition with chondritic
ratios of the refractory elements, which was then added to
an olivine composition. The Vizgirda and Anders [74] and
Hertogen et al. [29], and Morgan et al. [45] compositions
were obtained by using fractionation factors from the Moon
and Earth, which relate the composition of basalts to the
bulk composition by the processes of core and crust forma-
tion. Consolmagno and Drake [21] calculated a metal free
bulk composition based on trace element constraints for the
mode of the eucrite source regions and mineral compositions
from the work of Stolper [66]. Jones [33] modeled the bulk
composition as a mixture of 25% eucrite and 75% olivine.
Estimates of the amount of metal in the parent body, based
on the depletions of siderophile elements in eucrites,
include: 8% Hertogen et al. [29], 12.9% Morgan et al. [45],
and 20% - 40% Hewins and Newsom [30].
accretion model [e.g. 40, 2.51. This has led to giant impact 350-500 km radius [35]. Constraints due to the lunar
models, such as the vaporization model of Fegley and properties mentioned above, and the angular momentum of
Cameron [25] which involves a giant impact that strips off the Earth-Moon system have led to a theory for the origin
much of the silicate mantle of Mercury. of the Moon by a giant impact of a Mars-sized planet into
An estimate of the bulk composition of Venus based on the Earth [48]. Table 11 contains estimates of the bulk
cosmochemical grounds [44] is also listed in Table 9. silicate composition of the Moon, and an estimate of the
Chemical analyses of the Venus surface have been obtained composition of the lunar highlands crust. Anders [2] used
by spacecraft of the former Soviet Union and the chemistry a cosmochemical approach involving 6 components to
of the surface has been considered at length [8, 241, but this estimate the bulk Moon composition, and estimated a metal
data has not yet been incorporated into models of the bulk content of 6.1% and a troilite content of 1.l%. The O’Neill
planetary composition. Goettel [26] has also estimated the [49] composition consists of 82.5% of the present Earth’s
composition of the core of Mercury as 88-91 wt% Fe, 6.5 mantle, 0.2% of “Hadean matte” (Fe-Ni-S-O liquid), 13.3%
7.5 wt% Ni, and 0.5-5 wt% S. volatile free CI material, and 4% H chondrite material. The
Taylor [68] composition is based on heat flow, density data,
4.2. Mars (SNC parent body) the composition of the highland crust, and elemental ratios
Information on the composition of the silicate portion of in lunar samples. Taylor [68] also estimated a metal content
Mars is based on cosmochemical models, and on the of 2.3%. Wanke et al. [78] used a mixing model for lunar
composition of the Shergottite, Nakhlite and Chassignite highlands samples between lunar anorthosites and a “prima-
meteorites (SNC’s) (Table 10). The martian origin of the ry component”. The primary component consists of a
SNC’s is strongly supported by their young ages (about 1.3 refractory and non-refractory component in the ratio of 21
B.Y.), and the similarity of their trapped Ar and Xe isotopic to 79. For the bulk Moon, a composition was derived
compositions to measurements of the martian atmosphere by consisting of a 50-50 mixture (constrained by the lunar K/La
Viking [52]. The composition of Wanke and Dreibus [76] ratio) of the refractory and non-refractory portions. The
is based on element ratios in the SNC meteorites. Ander- metal content was also estimated at 1.5%. The bulk silicate
son’s model [5] is based on a mixture of 75% type 3 carbo- composition estimated by Jones and Delano [34] is based on
naceous chondrites and 25% ordinary chondrites, which was a mixture of an early olivine residuum, a later olivine
chosen in order to obtain a metal core composition consis- cumulate, and a primitive liquid composition from pristine
tent with geophysical parameters for Mars. Morgan and lunar glasses. Ringwood et al. [57] used a mixture of a
Anders [55] used the abundances of index elements obtained komatiite component (essentially the primary component of
from orbital gamma-ray observations, Viking observations, Wanke et al. [78]), and its liquidus olivine composition.
and geophysical constraints, in order to relate the composi-
tion of the planet to chondrites via four nebular fractionation 4.4. Earth
processes. The composition of Ringwood [55] consists of The Earth is the best studied planet, although the compo-
a mixture of 30% of a low-temperature condensate, repre- sition of the bulk Earth, and its major parts are still uncer-
sented by the Orgeuil CI chondrite, and 70% of a high- tain for many elements. The bulk composition of the
temperature devolatilized metal-rich component. For silicate portion of the Earth is broadly chondritic in compo-
additional data on Mars, including mineralogical models, see sition, but no presently identified chondrite type represents
Longhi et al. [41]. an exact match [69]. The Earth is divided into several
major parts, including the core (32 wt%), lower mantle (48
4.3. Moon wt%), upper mantle (20 wt%), and continental crust (0.4
The chemistry of the Moon has been extensively studied wt%). The composition of the Bulk Silicate Earth is based
based on remote sensing and on the lunar samples returned on samples available for chemical analysis from the upper
from the Moon by the Apollo astronauts, the unmanned mantle and crust. The continental crust can also be divided
Luna probes by the former U.S.S.R. and from lunar meteor- into upper and lower parts. The composition of the ancient
ites. Detailed chemical information for a large number of continental crust has also been investigated in order to study
different types of lunar material is summarized in the Lunar the chemical evolution of the crust with time. The composi-
Source Book [28]. Compared to the Earth, the Moon has a tions of the different reservoirs in the Earth provides clues
very low volatile element content and a higher Fe0 content. to the major processes involved in the evolution of the
The Moon has a low mean density of 3.34 g cm.3 implying Earth, such as core formation and the formation of the
a low iron content. The existence of a lunar metal core has continental crust. The composition of the continental crust
not been conclusively proven, although substantial indirect is also important for determining the bulk abundance in the
geophysical data supports the presence of a small core of Earth because many incompatible elements, which are
164 COMPOSITION OF THE SOLAR SYSTEM
concentrated in the continental crust. The continental crust, element data. The Ringwood [56] “pyrolite” primitive
for example, may contain more than 80% of the highly mantle composition is based on complementary composi-
mobile elements Cs, Cl, and Br [77]. This type of data has tions of melts and residual mantle material. A similar
even been extended by some authors to include estimates of approach was used by Sun [67]. Wanke et al. [77], updat-
the enrichment of some elements in ore deposits relative to ing Jagoutz et al. [32] have used the composition of mantle
the continental crust [ 15,421. nodules to represent the depleted upper mantle, combined
4.4.1. Core. The Earth’s core consists largely of Fe- with a continental crust composition. Zindler and Hart [89]
metal, along with Ni and Co, in the same ratio to Fe as used ratios of refractory elements in lherzolites together with
observed in solar system material, such as the CI chondrites cosmochemical constraints. The bulk Earth composition of
(approximately 5.8 wt% Ni, 0.3 wt% Co, Table 12). These Morgan and Anders [44] used 7 cosmochemical components
compositions are observed in iron meteorites, which are constrained by the mass of the core, the U and Fe abun-
thought to be the cores of melted asteroids that formed at dance, and the ratios K/U, Tl/U, FeO/MnO.
relatively low pressures. However, geophysical evidence
4.4.3. Bulk Continental Crust. Estimates of the compo-
indicates that the Earth’s metal core is 10% less dense than
sition of the continental crust are listed in Table 14. The
pure Fe-Ni-Co, indicating the presence of a significant
bulk continental crustal composition of Taylor and McLen-
amount of a light element which is not observed in iron
nan [70] (their Table 3.5) is comprised of 75% of their
meteorites. The presence of the light element may be due
Archean crustal composition (Table 9) and 25% of their
to processes that only occur at very high pressures within
Andesite model (Table 9), to represent the relative contribu-
the Earth. The nature of this light element is currently
tions of Archean and Post-Archean crustal growth processes.
controversial, with the main candidates being oxygen or
A similar approach was taken by Weaver and Tarney [81],
sulfur. A recent estimate of Ahrens and Jeanloz [l] assum-
who combined composition estimates for the upper crust,
ing sulfur is the light element, gives a sulfur content of 11
Archean middle crust, Archean lower crust and post-Arch-
+ 2%, based on experimental evidence. Experimental work
ean middle and lower crust in the proportions 8:3:9:4.
at pressures approximating the core mantle boundary has
Other estimates of the composition of the continental crust
shown that high pressure mantle minerals, such as (Mg,
include those of Holland and Lambert [3 11,Poldevaart [53],
Fe)SiO, perovskite, will react chemically with iron to form
Ronov and Yaroshevsky [59], Ronov and Migdisov [60],
alloys [38]. This experimental result may explain the light
and Wedepohl [82]. For a summary of other major element
element component, and the existence of the D” (D-double-
estimates of the composition of the bulk continental crust
prime) layer at the core mantle boundary observed in
see Table 3.4 in Taylor and McLennan [70].
seismic studies. Such reactions could be changing the
composition of the core over time. 4.4.4 Other crustal abundances. The continental crust
4.42 Bulk Silicate Earth (primitive mantle). The can be broken down into other divisions that provide useful
composition of the silicate portion of the Earth (the mantle constraints in terms of the formation of the continental crust
plus .crust) has been estimated based on measurements of (Table 15). The composition of the upper continental crust
upper mantle and crustal rocks (Table 13). The composition estimated by Taylor and McLennan [70] is based on
of the upper mantle is surprisingly homogeneous for many sampling programs in the Canadian shield for major
elements. Elements that are compatible in mantle minerals, elements, and analyses of sedimentary rocks for trace
such as Co and Ni, have abundances in primitive mantle elements. Rare-earth distributions of a composite of 40
nodules that do not vary by more than plus or minus 10% North American shales were compiled by Haskin et al. [27]
[6.5]. The abundances of poorly known incompatible to approximate the composition of the upper continental
elements can be determined relative to well known incom- crust. The lower continental crust composition of Taylor
patible elements. For example, MO is constant within plus and McLennan [70] is based on their bulk continental
or minus a factor of two relative to the light rare earth crustal composition, from which their upper continental
element Ce in terrestrial basalts [47]. The composition of crustal composition (Table 15) has been subtracted. The
Anderson [6] is a mixture of five components, ultramafic composition of the bulk Archean continental crust estimated
rocks, orthopyroxene, Mid-ocean Ridge Basalt (MORB), the by Taylor and McLennan 1701, is based on a mixture of
continental crust, and kimberlite, combined to achieve basic and felsic rocks consistent with the observed heat
chondritic relative abundances of refractory elements. flow. Taylor and McLennan [70] present a composition for
Taylor and McLennan [70] used a mixture of cosmochemi- the post-Archean continental crust, the “Andesite model”,
cal components for refractory elements, crustal data for which is based on the average composition of erupted
volatile elements and mantle nodule data for siderophile material at island arcs.
NEWSOM 165
TABLE 1. Solar-System abundances of the Elements Based on Meteorites and Condensation Temperatures
TABLE 1. (Continued)
TABLE 2. (Continued)
TABLE 3. (Continued)
TABLE 3. (Continued)
TABLE 3. (Continued)
*Assignments to nucleosynthetic processes are from Cameron [1982]17, Schramm (private communication, 1982) Walter et al. [1986]75, Woosley and
Hoffman [1986, 1989]87p8s, and Beer and Penzhom [19871g. Processes are listed in the order of importance, with minor processes (lo-30% for r-and s-
processes) shown in lower case. See above references for details. U = cosmological nucleosynthesis, H = hydrogen burning, N = hot or explosive hydrogen
burning, He = helium burning, C = carbon burning, 0 = oxygen burning, Ne = neon burning, Ex = explosive nucleosynthesis, E = nuclear statistical
equilibrium, S = s-process, R = r-process, RA = r-process producing actinides, P = p-process, X = cosmic-ray spallation. thalicizcd values refer to
abundances 4.55 x 10’ yr ago.
NEWSOM 173
IAB IAB -0.7 -0.70 6 -50 Fs 4-8 5.0 5.0 ____ ____ 0.95
inclusion
Enstatite EL 0.60 0.76 0.05 47-57 Fs -0.05 5.6 0.0 51 .o 112 0.84
EHg 0.59 1.13 0.05 68-72 5.3 0.0 0.5 20 0.72
a As fraction of silicates
b Ibitira is an unbrecciated eucrite
’ Pallastic silicates monomict; metal and silicates probably originally separate in core and mantle, repectively.
174 COMPOSITION OF THE SOLAR SYSTEM
Element CM co CK cv H L LL EH EL
TABLE 6. (Continued)
Element CM co CK cv H L LL EH EL
Data from Wasson and Kallemeyn [1988]80, & Kallemeyn et al. [1991]36 (CK). Values in parentheses for Nb and Ta are inferred by assuming they
are unfractionated relative to well-determined refractory lithophiles.
TABLE 7. (Continued)
TABLE 8. Estimated Composition of the Silicate Portion of the Parent Body of the Eucrite Meteorites
TABLE 8. (Continued)
1 H wm 0.4 35
3 Li PPm 0.87 1.94
4 Be wb 34 47
5 B ppb 0.11 10.0
6 C % 0.0005 1 0.0
7 N wm 0.046 4.3
8 0 % 14.44 30.9
9 F ppm 2.2 15
11 Na wm 0.1-0.7 200 1390
12 Mg % 25.5 19-23 6.5 14.54
13 Al wm 8.99 1.9-3.7 10,800 14,800
14 Si % 12.1 18-22 7.05 15.82
15 P ppm 390 1860
16 S % 0.24 1.62
17 Cl 0.23 20.9
19 K wm 0 ____ 22 150
20 Ca 9.80 2.4-5.0 11,800 16,610
21 SC ____ 7.4 10.1
22 Ti wm 0.479 0.09-O. 18 630 850
23 V ppm 63 86
24 Cr PPm 7180 4060
2.5 Mn wm ____ 150 460
26 Fe % 64.47 31.17
27 Co mm 1690 820
28 Ni % 3.66 1.77
29 Cu wm 5.1 35
30 Zn PPm
____ 12.1 82
31 Ga -__- 0.50 3.4
32 Ge PPm 1.24 8.4
33 As ppm 6.4 3.1
34 Se mm 0.79 5.4
35 Br wm 0.0012 0.111
37 Rb wm 0.075 0.509
38 Sr wm ____ 1.11 15.2
178 COMPOSITION OF THE SOLAR SYSTEM
TABLE 9. (Continued)
Mantle + Crust
MgO % 27.4 29.8 29.9 30.2
Al203 % 3.1 6.4 3.1 3.02
SiO2 % 40.0 41.6 36.8 44.4
CaO % 2.5 5.2 2.4 2.45
TiO2 % 0.1 0.3 0.2 0.14
Fe0 % 24.3 15.8 26.8 17.9
Na20 % 0.8 0.1 0.2 0.50
p205 % -_- ___ -_- 0.16
Cr203 % 0.6 0.6 0.4 0.76
MnO % 0.2 0.15 0.1 0.46
K ppm 573 77 218 305
Rb mm _--- 0.258 1.06
CS ppm ---- 0.026 0.07
F wm ____ 24 32
Cl ppm ---_ 0.88 38
Br ppb -___ 4.7 ____ 145
I wb ____ 0.59 ---_ 32
co mm ____ ---- ---- 68
Ni % ____ ____ --__ 0.04
CU mm _-_- -___ -_-_ 5.5
Zn mm ____ 42 ____ 62
Ga wm -___ 2.4 _-_- 6.6
MO ppb ---- _-_- 118
In wb -___ 0.095 -___ 14
TI ppb _--- 0.17 3.6
W ppb ---- ---- --_- 105
Th ppb 77 113 60 56
U ppb 17 33 17 16
Core
Fe % 72 88.1 63.7 77.8
Ni % 9.3 8.0 8.2 7.6
co % ---_ ---- ____ 0.36
S % 18.6 3.5 9.3 14.24
0 % ---- ____ 18.7 -_--
Core Mass % 11.9 19.0 18.2 21.7
180 COMPOSITION OF THE SOLAR SYSTEM
Ringwood
[ 1977154, Morgan
Ringwood & WPnke
8~ Kesson Anders et al.
[1977]58 [ 1980]44 [ 1984]77
TABLE 13. Composition of Bulk Silicate Earth (Primitive Mantle), Depleted Mantle and the Bulk Earth (Core + Mantle + Crust)
Element Anderson Ringwood Sun Taylor & W&r&e Zindler & Wanke Morgan
[ 198317 [1991’J5’ [1982]67 McLennan et al. et al. & Anders
[ 198517 [ 1984]77 [ 1984]77 [ 1980]44
Depleted Bulk Earth
mantle
Element Anderson Ringwood Sun Taylor & Wtike Zindler & W&e Morgan
[ 198317 [1991]56 [1982]67 McLennan et al. Hart et al. & Anders
[ 198517 [1984]77 [ 1986]89 [ 1984177 [ 1980144
Depleted Bulk Earth
mantle
30 Zn mm 37 56 56 50 48.5 ---- 48 74
31 Ga ppm 4 3.9 4.5 - 5.0 3 3.8 ---- 3.7 3.1
32 Ge ppm 1.13 1.1 ____ 1.2 1.32 --__ 1.31 7.6
33 As ppm ---- 0.13 _--_ 0.10 0.152 ---- 0.14 3.2
34 Se ppm 0.02 0.05 -_-_ 0.041 0.0135 --__ 0.0126 9.6
35 Br ppm --_- 0.075 0.060-0.090 ---- 0.0456 ---_ 0.0046 0.106
37 Rb ppm 0.39 0.635 0.66 0.55 0.742 ---- 0.276 0.458
38 Sr ppm 16.2 21.05 _-_- 17.8 27.7 19.6 26.0 14.5
39 Y mm 3.26 4.55 ____ 3.4 -__- --__ ____ 2.62
40 Zr mm 13 11.22 __-- 8.3 ---- --__ __-- 7.2
41 Nb ppb 970 713 -_-- 560 ---- ---_ ---- 800
42 Moppm ---_ 0.065 ---- 0.059 __-_ --__ ____ 2.35
44 Ru ppm ---_ 0.0042 __-- 0.0043 ____ ---- ---- 1.18
45 Rh ppb ---_ 1 ___- 1.7 1.18 --__ ---- 252
46 Pd ppb ---_ 5 _-_- 3.9 ___- ---- ---- 890
47 Ag ppb 3 8 5-10 19 2.92 --__ 2.51 44
48 Cd ppb 20 40 --_- 40 26.1 -_-- 25.5 16.4
49 In ppb 6 13 10-15 18 18.5 -_-- 18.1 2.14
50 Sn ppb 600 175 _-_- 600 ---- --__ ___- 390
51 Sb ppb ---- 5 3-6 25 5.7 --__ 4.5 35
52 Te ppb --__ 13 -_-_ 22 19.9 -___ 19.9 1490
53 Ippb ---- 11 ____ __-_ 13.3 ____ 4.2 13.6
55 Cs ppb 20 33 8-17 18 9.14 ____ 1.44 15.3
56 Ba ppb 5220 6989 ____ 5100 5600 -___ 2400 4000
57 La ppb 570 708 ____ 551 520 -___ 350 379
58 Ce ppb 1400 1833 ____ 1436 1730 -__- 1410 1010
--_- 278 -__- 206 ---- --_- ____ 129
59 Pr ppb
60 Nd ppb 1020 1366 ____ 1067 1430 1170 1280 690
62 Smppb 320 444 _--- 347 520 380 490 208
63 Eu ppb 130 168 -__- 131 188 -___ 180 79
64 Gd ppb ---- 595 ___- 459 740 -_-- 690 286
65 Tb ppb 90 108 ____ 87 126 -___ 120 54
66 “Y mb --__ 737 ___- 572 766 -_-- 730 364
67 Ho ppb --__ 163 __-- 128 181 -__- 170 80
68 Er ppb --__ 479 ____ 374 460 -___ 440 231
69 Tmppb --__ 74 ____ 54 ____ -__- _-_- 35
70 Yb ppb 320 481 ____ 372 490 420 470 229
71 Lu ppb 60 73.7 ____ 57 74 -___ 71 386
72 Hf ppb 330 309 -_-- 270 280 -___ 260 230
73 Ta ppb 40 41 ---- 40 25.6 -___ 12.6 23.3
74 w ppb --__ 21 (21) 16 24.1 -___ 16.4 180
75 Re ppb 0.21 0.28 ____ 0.25 0.236 -_-- 0.23 60
76 OS wb 2.90 3.4 ---- 3.8 3.106 --_- 3.1 880
77 Ir ppb 2.97 3.3 ____ 3.2 2.81 ---- 2.8 840
78 Pt wb --__ 6.8 -_-- 8.7 ____ -___ __-- 1670
79 Au ppb 0.50 0.75 __-- 1.3 0.524 -__- 0.50 257
80 Hg ppb --__ 10 ____ ____ ____ -__- _--- 7.9
184 COMPOSITION OF THE SOLAR SYSTEM
Element Anderson Ringwood Sun Taylor & Wanke Zindler & Wanke Morgan
[198317 [1991]56 [1982]67 McLennan et al. Hart et al. & Anders
[ 198517 [1984]77 [ 19861gg [1984]77 [1980]44
Depleted Bulk Earth
mantle
TABLE 15. Compositions of the Upper Continental Crust, Lower Continental Crust and Archean Continental Crusts
TABLE 15 (continued)
Element Upper
_- Continental North Lower Archean Continental Post-Archean
crust American Continental crust Continental
Shale crust Upper Total crust
(1) (2) (3) (1) (1) (1) (1)
Acknowledgments. I wish to th,ank S. Maehr for assistance with the ments. This work was supported by NSF grants EAR 9005199, EAR
tables, and T.J. Ahrens, A.J. Brearley, and R.H. Jones for helpful com- 9209641, and the Institute of Meteoritics, Univ. of New Mexico.
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