Hasil Pengukuran

1. Pengukuran Deret Standar 2. Pengukuran Sampel

con cd abs ulangan
0 0.0004 1
0.1 0.0226 2
0.2 0.0546 3
0.4 0.1099 4
0.8 0.2350 5
1.4 0.4142 6
1.8 0.5352 7
slope 0.2996 rata-rata
intersep -0.0052
regresi 0.9998

3. Hasil uji akurasi metode spiking

sampel dispike dengan menanmbahkan 0.5 mg/L cd 20 mg/L
ulangan bobot sampel abs
1 10.001 0.0745
2 10.001 0.0695
3 10.001 0.0725
4 10.001 0.0745
5 10.000 0.0715
6 10.001 0.0685
7 10.000 0.0745

ketidakpastian penimbangan 0.0004

labu takar 50 0.03
suhu ruang 25

1. KETIDAKPASTIAN KURVA KALIBRASI

deret xi yi yc yi-yc
1 0 0.0004 -0.0052 0.0056
2 0.1 0.0226 0.0248 -0.0022
3 0.2 0.0546 0.0547 -0.0001
4 0.4 0.1099 0.1147 -0.0048
5 0.8 0.2350 0.2345 0.0005
6 1.4 0.4142 0.4143 -0.0001
7 1.8 0.5352 0.5342 0.0010
rata-rata 0.6714 0.1960 0.1960 0.0000
jumlah 4.7 1.3719 1.3719 0.0000
n-2 5
rsd 0.003464807842577
slope 0.299641164856861
1+1/n 1.14285714285714
yo-yr -0.1528
yo-yr2 0.0233609
b2(xi-xr)2 0.259862944104499
yo-yr2/b2.. 0.089897153517193
1+1/n+(yo-yr 1.23275429637434
akar 1.11029468897871
miu reg 0.012838548894918

2. KETIDAKPASTIAN ASAL LABU TAKAR

koef muai air vlt variasis suhu
Ketidakpastian asal temperatur
0.00021 50 5
data spek pabrik
ketidakpastian asal kalibrasi
0.03
3. KETIDAKPASTIAN PENIMBANGAN
data spek k miu kal miu w
0.0004 2 0.0002 0.00028284271

4. KETIDAKPASTIAN PRESISI METODE

ulangan bobot sampel abs v lt (L) c terukur
1 10.0005 0.0441 0.05 0.16454
2 10.0005 0.0421 0.05 0.15786
3 10.0003 0.0464 0.05 0.17221
4 10.0002 0.0414 0.05 0.15553
5 10.0005 0.0397 0.05 0.14985
6 10.0001 0.0400 0.05 0.15085
7 10.0004 0.0483 0.05 0.17855
rata-rata 10.0004 0.0431 0.0500 0.1613
jumlah 70.0025 0.302 0.35 1.1293958058
sd/ miu pm

5. KETIDAKPASTIAN RECOVERY
ulangan bobot sampel abs kon dispike v lt (l)
1 10.001 0.0745 0.2660 0.05
2 10.001 0.0695 0.2493 0.05
3 10.001 0.0725 0.2593 0.05
4 10.001 0.0745 0.2660 0.05
5 10.000 0.0715 0.2560 0.05
6 10.001 0.0685 0.2460 0.05
7 10.000 0.0745 0.2660 0.05
Rata-rata
sd

KETIDAKPASTIAN GABUNGAN
nilai xi satuan miu miu/xi
Kurva kalibrasi 0.1613 mg/l 0.01283854889 0.079573
pm 0.8067 mg/kg 0.05448413404 0.067541
vlt 50 ml 0.03491060011 0.000698
penimbangan 10.0004 g 0.00028284271 0.000028
rec 48.50753866 % 4.16898298172 0.085945
jumlah
miu csx
diperluas
pelaporan
engukuran Sampel kur
bobot sampel abs
0.6
10.0005 0.0441
10.0005 0.0421 0.5 f(x) = 0.299641164856861 x − 0.0052019249
10.0003 0.0464 R² = 0.999769068246412
10.0002 0.0414 0.4
10.0005 0.0397
0.3
10.0001 0.0400
10.0004 0.0483 0.2
10.0004 0.0431
0.1

0
0 0.2 0.4 0.6 0.8 1

yi-yc2 xi-xr xi-xr2

0.0000 -0.6714 0.4508
4.67507212749559E-06 -0.5714 0.3265
1.59537098665065E-08 -0.4714 0.2222
2.26056598109084E-05 -0.2714 0.0737
2.39114241903605E-07 0.1286 0.0165
9.15960480193902E-09 0.7286 0.5308
1.09794400581184E-06 1.1286 1.2737
8.57492384713016E-06 0.0000 0.4135
6.00244669299111E-05 0.0000 2.8943
k miu tem miu tem 2 miu LT
1.73 0.0303108891325 0.00091875
miu kal miu kal 2 0.034910600109422
1.73 0.0173205080757 0.0003

kadar cd
0.8226
0.7893
0.8610
0.7776
0.7492
0.7543
0.8927
0.8067
5.64677633689958
0.054484134042922

kadar fe (c3) kadar spike (c2) kadar sampel (c1) c3-c1/c2*100 c3-c1
1.32982321734453 0.999900009999 0.8067 52.31931976 0.52314088
1.24639843069375 0.999900009999 0.8067 43.97600685 0.43971610
1.29645330268422 0.999900009999 0.8067 48.98199459 0.48977097
1.32982321734453 0.999900009999 0.8067 52.31931976 0.52314088
1.2798963221886 1 0.8067 47.32139883 0.47321399
1.2297134733636 0.999900009999 0.8067 42.30734426 0.42303114
1.32995619966627 1 0.8067 52.32738658 0.52327387
1.29172345 0.99992858 0.80668233 48.50753866 0.48504112
0.04168688 0.00004879 0.00000000 4.16852923 0.04168688

miu/xi2
 0.0063319229
0.0045617871
0.0000004875
0.0000000008
0.0073865521
0.0182808
0.1090686
0.218137108299602
(0.81 ± 0.22 )mg/kg
 kurva kalibrasi

1164856861 x − 0.005201924975321
068246412

abs
Linear (abs)

0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2

Miu c3-c1 miu c2/c2 miu reg

0.0073865498 2.380816E-09 0.085945053 4.16898298