Arrhenius Definition!!
1.An acid is a chemical substance which ionises in water to produce hydrogen ion,H+.
2. A base is a chemical substance which ionises in water to produce hydroxide ion, OH-
7.4 7.3
Analysing
Analysing Concentration of
Neutralization acids and alkalis
1. Define
neutralization reaction. 1. Define molarity
2. Write ionic equation 2. Describe methods for
for neutralization preparing standard
reaction. solutions.
3. State relationship
between the numbers of
moles with molarity.
Chemistry Module 2009 1
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T. 7.1
Substance produced
hydrogen ion H+ when Substance with opposite
dissolved/ionise in properties to acid and may react
water. with acid to form salt and water.
Water dissociated acid to
form H+ ion
H2O
Base that H2SO4 2H+ + SO42-
dissolved in
Base water is called
Acid
alkali
Uses of acids
and alkalis
The difference between
Properties of base and alkali
acid and alkali
Base Alkali
Acid Alkali Water Water soluble
1. Sour Bitter insoluble base forming
2. Electricity Electricity conductor metal OH-
Oxide or ion
conductor
hydroxide.
3. React with base to React with acid to
form salt and water. form salt and water.
4. React with metal to React with ammonium
form salt and hydrogen salt to form ammonia
gas. gas.
5. React with React with halogen to
carbonate to form salt, form 2 types of salt.
water and CO2
Chemistry Module 2009 2
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T.7.2
H+ H+ H+ CH3COOH
Cl-
Cl- H +
Cl- CH3COO-
- CH3COOH
Cl Cl-
H+ - + CH3COOH H+
Cl H H+ -
CH3COO CH3COOH
Acid that completely ionise in water Acid that partially ionise in water to
to produce H+ produce H+
Definition of Definition of
strong acid Strong acid weak acid
and weak acid
Definition of Definition of
weak alkali Strong alkalis strong alkali
and weak alkalis
+
Na+ - Na+ OH- NH4 NH4OH
- OH NH4OH NH4OH
OH Na OH-
+
1 2 3 4 5 6 7 8 9 10 11 12 13 14
Scale pH
Relationship To determine
pH of acids and
between pH and alkali
molarity of acids
and alkalis
Universal
indicator
Explanation
Acid or
alkali
PH scale
Molarities H2SO4 HCl NaOH
CH3COOH NH4OH
(M) (Strong (Strong (strong
(weak acid) (weak alkali)
acid) acid) alkali)
0.1 M 1.0 1.0 3.0 14.0 11.0
0.01 M Module 1.2
Chemistry 2009 2.0 3.5 13.0 10.5 4
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0.001M 1.5 3.0 4.0 11.0 10.0
5|Page
T. 7.3
÷ Molar mass
Concentration in g dm-3 Concentration in mole dm-3 (M)
X Molar mass
Concentration
The molarity of an acid
decreased the pH value Calculation
increase. The molarity of exercise for
an alkali decreased, the concentration
pH value decreased CONCENTRATION
OF ACIDS AND
ALKALIS Preparation of
standard solution
Relationship Preparation of
between pH and a solution
molarity of acid
and alkali
Dilution Method
pipette
*T.7.3.1
Exercise 1
Volume and
Molarity Concentration No. of. Mole Volume Mass
concentration of (n = MV/1000)
(mol dm-3) -3
(g dm ) (cm 3 ) (g)
substance.
0.05 x 1000
100 cm3 sulphuric 0.5 x 100/1000
49/98 = 0.5 49.0 0.5 0.05 x 98
acid 49.0 g dm-3 = 0.05
50 cm3 hydrochloric
acid 0.2 mol dm-3
2 mole copper(II)
sulphate 1.5 mole
dm-3
50 cm3 aluminium
chloride 0.5 mol dm-3
*T.7.3.2
Exercise 2. Complete the table below.
[RAM.: H,1; S,32; O,16; Cl 35.5; Cu,64; Al,27; Na,23; N,14; K,39; Pb,207]
Amount and
No. of moles Formula No. mol Molarity
No. molarity of Formula Mass
(n=MV/1000) of ion of ion ion
chemicals.
2 x 100 H+ 2 x 0.2 4.0
3
100 cm sulphuric H2SO4 1000 0.2 x 98 = 0.4
1
acid 2.0 mol dm-3 = 0.2 mol SO42- 1 x 0.2 2.0
= 0.2
H+
50 cm3
2 hydrochloric acid
0.2 mol dm-3
1.5 x 25
25 cm3 copper(II)
1000
3 sulphate solution
= SO42-
1.5 mol dm-3
50 cm3 aluminium
4 chloride 0.5 mol
1.5
dm-3
Na+
150 cm3 sodium
5 hydroxide 0.1 mol
dm-3
25 cm3 copper(II)
8 nitrate 0.025 mol
dm-3
T. 7.4
Application of
Calculation using formula: neutralization in every
NEUTRALISATION day life
Va Ma = na
Vb Mb nb
Experiment:
Titration method
Neutralisation between
sulphuric acid and
sodium hydroxide
H2O
HCl H + (aq) + Cl-(aq)
H2O
H2SO4 2H+(aq) + SO42-(aq)
Chemical properties
(i) Reaction with metals that are more electropositive than hydrogen
in the electrochemical series produces salt and hydrogen gas :
Mg + 2HNO3 Mg(NO3)2+ H2
Observation :…………………………………………………………
Observation :…………………………………………………………
Chemical properties
(i) Reaction with acids and alkalis / bases produces salt and
water.
Activity 1
b.
c. Role of water in determining properties of alkali :
7.4 pH Concept
a. pH is a scale of numbers to measure the degree of acidity and alkalinity
of an aqueous solution based on the concentration of hydrogen ions, H+ .
b. pH scale: 0-14:
pH value : 1 2 3 4 5 6 7 8 9 10 11 12 13 14
b) Strong acid :
Acid which dissociates completely in water to produce hydrogen ions.
Weak acid :
Acid which ionises / dissociates partially in water to produce hydrogen ions.
Example:
H+ H+ CH3 COOH
Cl- Cl- CH3 COOH H+
H+ H+ H+
Cl- Cl- CH3 COO- CH3 COO-
c) Strong alkali :
Alkali which ionises completely in water to produce hydroxide ions.
Weak alkali :
Alkali which ionises partially in water to produce hydroxide ions.
a. Concentration –
The measurement of substance dissolved in an amount of solvent.
e. Dilution of acid/alkali :
e. g : Find the volume of 2.0 mol dm3 sulphuric acid, H 2SO4 needed
to prepare 100 cm3 of 1.0 mol dm3 sulphuric acid
Before dilution After dilution
M1 V1 M2 V2
(mol dm )
-3
(cm )
3
( mol dm )
-3
(cm3)
2.0 ? 1.0 100
V1 = M 2 V 2
M1
= 1 x 100
2
=50 cm3
Try these yourself:
Calculate the volume needed to prepare each of the
following dilute solutions
2 ? 0.1 50
7. 7 Neutralisation :
a. Neutralisation is the reaction between an acid and a base to form salt and water.
Example :
b. At end point, all H+ ions from the acid are neutralised by OH- ions from the alkali or
vice-versa .
pH of the titration product is 7 (neutral).
M1xV1=M2xV2
Calculate the volume of a concentrated solution needed to prepare each of the following
dilute solutions:
2. 100 cm 3 of 0.5 mol dm -3 potassium manganate(VII), KMnO4 solution from 1.0 mol
dm -3 potassium manganate(VII), KMnO4 solution.
3 5 .0 dm -3 of 1.0 mol dm -3 nitric acid, HNO3 from 18.0 mol dm -3 nitric acid, HNO3 .
Definition !!
1.Concentration – Quantity of solute in a given volume of solution usually in dm3
• Concentration = mass(g)
(g / dm3 ) volume (dm3)
2. Unit
Molarity (mol dm3 ) @ M
7. 50 cm 3 of hydrochloric acid, HCl, 2 mol dm -3, reacted with excess zinc powder.
Calculate the volume of hydrogen gas released under room conditions.
[ Molar volume: 24 dm 3 at room condition ]
9. 3.25g of zinc, Zn, reacted completely with hydrochloric acid, HCl, with molarity of
0.5 mol dm -3. Calculate the volume of acid used.
[ Relative atomic mass: Zn,65]
1. The equation shows the reaction between sulphuric acid and sodium
hydroxide.
Persamaan menunjukkan tindak balas antara asid sulfurik dan natrium
hidroksida.
What is the volume of 1.0 mol dm-3 sodium hydroxide solution which can
be neutralise 25.0 cm 3 of 1.0 mol dm -3 sulphuric acid ?
Berapakah isipadu larutan natrium hidroksida 1.0 mol dm -3 yang boleh
meneutralkan 25.0 cm 3 asid sulfurik 1.0 mol dm -3 .
A. 12.5 cm3
B. 25.0 cm3
C. 50.0 cm3
D. 75.0 cm3
A. Ammonia
B. Potassium oxide
C. Carbon dioxide
D. Sodium hydroxide
4. A dibase acid ,H 2J has the concentration of 0.5 mol dm -3 . Letter J is not the
actual symbol of the element . What is the volume of potassium
hydroxide,KOH 1.0 mol dm-3 that can neutralise 25.0 cm-3 of the H 2J acid
solution ?
Satu dwibes ,H 2J mempunyai kepekatan 0.5 mol dm-3
Huruf J bukan symbol sebenar unsure itu. Berapakah 1.0 mol dm-3 yang
dapat meneutralkan 25.0 cm3 larutan asid H2 J itu?
A. 6.25 cm3
B. 12.50 cm3
C. 25.00 cm3
D. 50.00 cm3
STRUCTURAL QUESTION
SPM 2006
1. (a) 8g of solid sodium hydroxide, NaOH, is dissolved in distilled
water to produce a solution of 1000 cm 3.
The NaOH solution produced has the concentration of 8.0 g dm -3 and
molarity of 0.2 mol dm -3.
(i) State the meaning of the concentration for the solution produced.
[ 1 mark ]
(ii) State the meaning of the molarity for the solution produced.
[ 1 mark ]
(iii) Write the formula that represents the relationship between the
number of mole (n), molarity (M) and volume (V) for the solution.
[ 1 mark ]
(iv) Substitute the actual values of the number of mole, molarity and
volume of the NaOH solution into the formula in 4(a)(iii).
[Relative molecular mass of NaOH = 40 ]
[ 1 mark ]
(b) Diagram 4.1 shows the preparation of the standard solution of NaOH, 0.2
mol dm -3 .
DIAGRAM 4.1
(i) What are the two parameters that shoulb be measured accurately
to prepare the standard solution.
Parameter I _________________________
Parameter II _________________________
[ 2 marks]
(ii) After all the NaOH solution is poured into the volumetric flask, the
beaker and the filter must be rinsed several times with distilled
water.
After each rinse, all of this water is transferred into the volumetric
flask.
Give one reason for doing this.
[ 1 mark ]
(iii) What step should be taken to ensure that the meniscus level of the
standard solution is exactly in line with the graduation mark on the
volumetric flask ?
[ 1 mark ]
[ 1 mark ]
(v) Why is the volumetric flask stoppered after the standard solution is
prepared ?
[ 1 mark ]
2. Figure 1 shows the apparatus arrangement of an experiment in the laboratory to
determine the end point of the reaction between nitric acid, 2 mol dm-3 with 25 cm3
of potassium hydroxide solution.
Nitric acid
Figure 1
Table 2
[ 1 mark ]
b. Name the type of reaction occurred in this experiment.
[1 mark ]
c. Write the balance chemical equation for the reaction between nitric acid and
potassium hydroxide.
[ 3 marks ]
d. What is the colour of the potassium hydroxide solution when added with a few
drops of phenolphthalein?
[ 1 mark ]
e. State the change on the colour of the solution in potassium hydroxide solution
when the end point is reached.
[ 1 mark ]
[ 1 mark ]
(iii) Calculate the concentration of the potassium hydroxide solution.
[ 1 mark ]