The first few days of stoichiometry are often frustrating for both the students and teacher
because quite often the students do not known how to think about or go about solving a
simple problem. Though they have the required mathematical skills, the concepts elude
them, at least temporarily. Here are some example problems that I have either gone over
step by step on the board, or overhead, or I have given them out in the form of worksheets.
Both questions have been used successfully to overcome the anxiety of the first day of
stoichiometry.
You are the cook at a northern mining town. It is your job to keep the miners fed, which
usually means the food had better be good and there had better be lots of it. Remember,
mine shafts are deep and tempers can be short!!
Your basic breakfast menu consists of 2 eggs, 4 strips of bacon, a glass of orange juice and
2 pieces of toast. We won't include the coffee because it works as a catalyst!
If you feed all 600 miners the first day what supplies from your stock do you use up?
we can get the amount of each food from the equation as follows:
Eggs 1 complete breakfast = 2 eggs
600 miners x
x = 1200 eggs
From the above information you can see that in order to feed these ravenous miner type
persons you must cook
Question #2: How much of each food type do you have left in your larder? The results can
be found by using the following calculations.
Question #3 On the second day you again need to make breakfast. Because your first day
was so successful you party all night long. So you didn't go shopping. Bad move. You will
have to make breakfast using the existing stock in your larder.
Your stock on hand from the question above is: 1200 eggs, 1800 strips of bacon, 120 L of
juice, 1800 slices of bread
You will continue to make full breakfasts. It's really the only thing you know how to do.
Nobody said you were a Cordon Bleu chef, did they! You'll keep this up until you run out
of one of the ingredients. Which one of the ingredients do you run out of first?
Let's answer this by seeing how much of each ingredient will go around.
You have enough eggs on hand to feed the 600 miners. Boy are you lucky.
You can only give 450 out of the 600 miners bacon!
Juice 120 L of juice = 120 000 mL of juice = 400 miners get
300 mL of juice/miner juice!
Only 400 of the 600 miners get their morning's dose of vitamin C. How fast can you run?
Bread 1800 slices = 900 miners get bread!
2 slices/miner
You can give all 600 miners their bread. You suddenly realize that each miner can have 3
pieces of bread. You blurt out that instead of bacon and juice you'll gladly give each miner
an extra piece of toast. They just as gladly pick you up, carry you to the shaft and throw
you in as a sacrifice to incompetence.
From the information above you can see that you run out of juice first. You are only going
to feed 400 miners their full breakfasts. The other 250 are going to give you the shaft.
The thing we have the least of is the orange juice so it is called the limiting reagent. i.e.
Once it runs out you are limited in your ability to make full breakfasts.
Once you've feed the 400 miners you stop making full breakfasts.
You used 400 miners in the equation above because they are all you can feed.
You have been assigned the task of building a concrete sidewalk by your boss. The boss has
left you at a secluded, out of the way spot with 900 bags of cement, 160 m3 of premixed
gravel and sand, and 1000 L of water. You've got to mix and pour enough concrete to fill a
sidewalk that is 1 m wide x 60 m long by 20 cm thick. (The carpenters have already been
there and laid the forms.)
Your boss has left you, in addition to the above materials, a concrete mixer, (55 dm3
capacity), and a wheelbarrow that can hold 60 L and a shovel. Lucky you!
The boss tells you to mix 1 shovelful of cement with 6 shovelfuls of the gravel/sand premix,
then add enough water to just mix it into a smooth mass!
The equation is: 1 cement + 6 premix + water ----> 1 load of mixed concrete
After a little experimenting you discover that an average shovelful of cement is 1 dm3. The
sand/gravel premix is about the same. Okay, I know, it's a small shovel.
You can now find out how many shovelfuls of cement you have on hand!
Question #2 How any shovelfuls of gravel/sand premix do you have on hand?
Again after a little experimentation you discover that you need 5 L of water for each mix so
that the concrete has the right consistency.
Question #3 You mix a few more loads and find that you are averaging about 8 dm3 of
concrete mixture per load, if you use the 1:6 cement:premix ratio the boss gave you. How
many loads will you have to mix in order to fill the sidewalk?
Question #4 How many loads of 8 dm3 can you do at one time?
Since we can't overfill the cement mixer, we will only make up 6 full loads at any one time.
Question #5 If we use the boss's mix recipe and do 6 loads at a time, how much of each
ingredient do we need?
x = 6 shovelfuls of cement
x = 30 L of water
x = 48 dm3 of mix
You do not have enough water to complete the job. When you run out of water you must
stop, so it is the limiting reagent. It limits you in your ability to complete the mixing of any
further cement and premix.
We are looking at H2O as the limiting reagent and we are looking at how many loads of
concrete we can mix therefore ignore the other two components in the equation.
x = 200 loads
= 33.3 bags
Question #8 If you fill the mixer each time with 6 full loads and let it mix, how many times
do you have to walk back and forth from the mixer to the sidewalk forms?
= 33.3 times.
= 1.3%
Only 1.3% of the sidewalk gets completed. Are you in trouble? What solution can you
come up with to resolve your dilemma?