This page contains a collection of facts and rules, necessary for making ecological estimates and
calculations. Print it out for your convenience when studying the topics on this web site.
Jerrard H G (1963-1992): Dictionary of scientific units, including dimensionless numbers and scales.
Chapman&Hall
Rowlett, Russ (Internet): A dictionary of unitsof Measurements. www.unc.edu/~rowlett/units/ very extensive
and accessible
Harte, John (1939,1988): Consider a spherical cow, a course in environmental problem solving. Univ Science
Books.
Physics Fact Book: http://hypertextbook.com/facts/index-topics.shtml use of formula in sample problems, and
interesting dimensions.
The international system of units (SI units) defines how physical properties are measured,
previously known as the MKS (Metre, Kilogram mass and Seconds) system. Units consist of two
parts, a prefix coding for magnitude (multiplication or division) and a unit of measure. The unit
kg consists of the prefix k for 1000x and g for gram. As a rule, prefixes above 1000 are spelled
with capital letters (M=mega=1,000,000x), and so are units derived from a person's name
(W=Watt, J=Joule), but kilo k, hecto h and deka da are spelled in lower case.
Units are always singular: An elephant has four feet. John is six foot tall. Mary travels to work
about 20 kilometre. The bag contained 5 kilogram.
Prefixes
power of ten 24 21 18 15 12 9 6 3 2 1
prefix Y Z E P T G M k h da
name yotta zetta exa peta tera giga mega kilo hecto deka
In computing, the K unit is used for 210=1024 instead of 1000. Here are the new conventions:
power of two 10 20 30 40 50 60
approximate
3 6 9 12 15 18
power of ten
prefix Ki Mi Gi Ti Pi Ei
name kibi mebi gibi tebi pebi exbi
Basic SI units
Derived SI units
Russ Rowlett of the University of Carolina has a very extensive web site about this.
The International Bureau of Standards in Paris also has an extensive web site. Bureau
International des Poids et Mesure.
A very precise unit converter converts one unit into another.
Note! On the Seafriends web site, the powers of ten are often written as 1E6 rather than 10^6 or
106. 15000 = 15E3 = 1.5E4
Units are spelled the English way: metres rather than meters. Formulas are spelled out like e = m
x c x c, rather than e=mc2.
In scientific literature it is conventional to spell m/s as m s-1 , but this is not followed in this web
site.
Dimension-less quantities
Ratios
1 order of magnitude = 10 x
to decimate originally means, to take 10% (= x 0.9), but is often used as meaning to leave 10%
(= x 0.1).
Square root of two: The international paper size A0, A1, A2, A3, A4, A5, ... series was
designed such that an A0 sized sheet cut in half, would produce two A1 sheets of equal size and
equal ratio between height and width (=aspect). There is only one mathematical number that has
this property: the square root of 2. SQR(2) = 1.4142. In this series of paper sizes, the
height/width ratio is SQR(2). When cut in half, becomes SQR(2) / 2 = SQR(2) / (SQR(2) * SQR
(2)) = 1 / SQR(2). Thus the ratio remains identical, although the cut sheets need to be turned
ninety degrees.
This is the only number/ratio which inverses when divided by two: 1 / n = n / 2 thus n x n = 2
or n = SQR( 2 )
Golden section: the division of a number so that the whole is to the greater part as that part is to
the smaller part. It is also called the divine proportion, first defined by Euclid, and is used by
architects in designing buildings (first used for the Parthenon). 1.61803 to 1 or 1 to 0.61803. A
rectangle with these proportions is called a golden rectangle and is thought to be more pleasing
to the eye. It is calculated by solving the equation 1 / n = n + 1 or n2 + n - 1 = 0
The golden section can directly be calculated as: (1 + SQR(5)) / 2 (see mathematics refresher
below)
Graphically it is drawn as follows: First draw a square ABCD. Then, find the midpoint M of side
AB. Next, use a compass to extend AB to a point E so that ME = MC. Rectangle AEFD is a
golden rectangle. To divide AB according to the golden section, use a compass to find a point G
on AE so that EF = EG.
Fibonacci series
The Italian mathematician Leonardo Fibonacci defined the Fibonacci series
0,1,1,2,3,5,8,13,21,34,55,89,144, ..... where each following number is the sum of the two
previous (2=1+1, 3=2+1, 144=89+55, ..). It is a series that has a constant progression as found in
things that grow in nature. In fact, each following number can be calculated from the previous by
multiplying with 1.618033988 (dividing by 0.618033988) and rounding the result. Note the
remarkable mathematical quality 1 / n = 1 + n or the Golden Section above.
Two (2): The lowest number that makes counting and arithmetic possible. The only number for
which n x n = n + n = nn . It is the number that stands for duplication, replication and
redundancy. A rectangle with aspect of two, becomes a smaller rectangle with the same ratio
when folded or halved twice.
Pi: the ratio of circumference to the diameter of a circle 3.14159... The number obtained by
dividing 22 by 7 22/7=3.1428571.. is almost the same, but slightly larger. Pi can be calculated
exactly as follows:
pi / 2 = 2/1 x 2/3 x 4/3 x 4/5 x 6/5 x 6/7 x ..... x (n+1)/n x n/(n+1) . (John Wallis series), or by a
shorter series, which converges more slowly:
pi / 4 = 1/1 - 1/3 + 1/5 - 1/7 + 1/9 - 1/11 .... (Leibniz series (1673), also discovered by James
Gregory (1671))
Perfect numbers
A number is called perfect, if the sum of its factors adds up to the number itself, like: 6 = 1 + 2 +
3 and 28 = 1 + 2 + 4 + 7 + 14. There are only four such perfect numbers: 6; 28; 496; 8128.
(Nichomachus Gerasa, 100 AD). The 6th and 7th are: 8,859,869,056 and 137,438,691,328
(Pietro Cataldi, 1603) What is the fifth perfect number?
Angles
A circle is 360 degrees = 2 x pi radians
One degree = 60 minutes = 60 arcminutes
One minute = 1 arcminute = 60 secondes = 60 arcseconds
1 minute over a meridian = 1 nautical mile = 1.852 km
Density
Density or specific weight is a ratio between weight and volume. Traditionally gram / cubic
centimetre = kg / litre
or ton/m3. Multiply by 27.7 to get lb/in3, and by 1.33 to get ton/yd3.
The density of clean water is defined as 1.000. A rock with density 2.80 weighs 2800 kg / cubic
metre = 2.8 t / m3
Density of air at the surface is 0.00013
Densest substance on Earth is iridium 22.5, followed by osmium 22.4, platinum 21.4, rhenium
21.0, neptunium 20.4, plutonium 19.8, gold 19.3, tungsten 19.3, uranium 18.9, ... mercury
13.53, ... lead 11.4, ... iron 7.86, ....
Averages
The arithmetic average of a, b, c = (a + b + c ) / 3
The geometric average of a,b,c = (a x b x c ) / 3
An arithmetic series is: a + (a+d) + (a+2d) + (a+3d) + ....
A geometric series is: a + (a x r) + (a x r x r) + ...
An exponential series is: ex = 1 + x + ( x2 ) / ( 1 x 2 ) + ( x3 )/ (1 x 2 x 3 ) + ... ( xn ) / n!
A logarithmic series is: ln(1+x) = x - (x2) / 2 + (x3) / 4 - (x4) / 4 + ...
Attenuation
The difference between Beer and Lambert is that the first was concerned with the
density of the medium, whereas the second was concerned with the distance travelled
through the medium. Both concerns are captured in the same formula:
Id = I0 x e x x d or ln( Id / I0 ) = x x d
Where I0 = starting intensity, Id = intensity at distance d and ex = rate of change for a
distance equal to d = 1, and x = the decay constant. If x is larger than 0, there is
exponential growth, but if it is less than zero, there is logarithmic decay.
For absorption by a medium, x can be written as a constant times concentration : k x c
To convert from the natural logarithm ln( to the decimal logarithm log(, correct by:
e= 2.71828
Id = I0 x 10 ( x x d ) / e or log( Id / I0) = ( x x d ) / log( e ) = 2.3029 x x x d
If the rate of change is known for a unit distance, then the exponent x can be
calculated as:
x = ln( unit rate of change)
For the 1,2,4,8 series above, x can be calculated from the rate of change = 2: 2 = 1 x e
x x 1
or x = ln(2) = 0.693. Likewise, x = -0.693 for the 256,128,64,.. series.
Mathematical series
This section contains the various mathematical series important to nature.
Scaling / allometrics
Allometrics (Gk: allo=other; metron= measure) is the ability to scale size up and down according
to the relationship between size and some other measure. Many of these relationships appear
throughout all chapters of this page. For instance, the volume of a sphere is related to its radius
as 4/3 x pi x r x r x r. With this formula, the volume of any sphere can be calculated. It is an
exact and mathematically provable formula. However, a number of relationships have been
established empirically (by experiment), and these are listed here. Note that empirical formulas
are subject to some uncertainty.
Impact damage
Nuclear weapon (power in Mt) area of destruction = 400 x (Mt) ^ 0.67 (km2). (Steel, 1995)
Thus a bomb of 10 Mt TNT destroys 1870 km2, equal to an asteroid of 25m radius, density 3
and speed 20,000m/s.
Asteroid impact energy for radius r (m), speed v (m/s), density d = (5.0E-13) x r ^3 x v ^2 x d
(Mt TNT)
Time, frequency
1 day = 1440 minutes = 86400 sec. The day lengthens by 1 second every 62500 years.
exact duration of a year = 365.25 days
1 yr = 8760 hr = 31,560,000 sec = 3.156E7 s
1 eon = 1E9 years. Life started 3.6 eons ago (3,600,000,000 years). The Big Bang 15 eons ago.
Earth = 4.6 eons
Geological time
See Geologic Time Table.
Frequency
1 hertz = 1 Hz = 1/s (per second) = 1 c/s (cycles/second) = 2 x pi rad/s = 6.28318 rad/s
1 revolution per minute (rpm) = 0.105 rad/s
unit of (radioactive) activity = Becquerel = 1 Bq = 1/s (per second)
1 Curie = 1 Ci = 3.7E10 Bq
Temperature
Length
1 m = 39.37 inches (in) = 3.281 feet (ft) = 1.094 yards (yd)
1 inch = 2.5400 cm
1 ft = 0.3048 m
1 km = 1000 m = 0.6214 statute mile (mi) = 0.5400 nautical mile
1 statute mile = 1.6093 km =1609.3 m
1 fathom = 6 ft = 1.829 m
1 furlong (fur) = 201 m
1 league = 1 nautical mile (n mile) = 1.852 km
1 chain = 66 ft = 20.1168m
1 Aengstrom (AE) = 1E-8 m = 0.1 nm = 100 pm (pico metre)
Book printing: 1 inch = 6 pica = 72 point
Area
1 m2 = 10.76 ft2 = 1.196 yd2
1 km2 = 1000000 m2 = 100 hectares (ha) = 247.1 acres = 0.3861 mi2
1 square nautical mile = 3.4299 km2
1 square mile = 2.59 km2
1 are = 100 m2
1 hectare (ha) = 10,000 m2 = 0.01 km2
1 square inch (in2) = 6.45 cm2
1 square foot (ft2) = 929 cm2 = 0.0929 m2
1 perch = 25.3 m2
1 acre = 0.405 ha = 4050 m2
1 rood (rd) = 0.101 ha
Volume
1 litre (l) = 1000 cm3 = 33.81 fluid ounces = 1.057 US quarts
1 fluid ounce = 29.57353 ml (USA) = 28.4 ml (Imperial)
1 cu ft = 0.0283 m3; 1 in3 = 16.4 cm3; 1 yd3= 0.765 m3
1 Imperial pint = 0.5682 l
1 Imperial gallon = 1.2009 US gallons = 4.5461 litre
1 US gallon = 0.8327 Imperial gallon = 3.7854 litre
1 m3 = 1000 l = 35.31 ft3 = 264.2 US gallons = 6.290 barrels
1 acre foot = 1230 m3 =43,560 cu ft
1 bushel (US) = 1 bu = 8 (Imperial?) gallon = 35.23907 litre
1 wheat bushel (US) = 60 pound = 27.216 kg. Barley bushel = 48 pound = 21.772 kg. Oats bu =
32 pound = 14.515 kg
1 rye bu = 56 pound = 25.401 kg.
Volume of one mole of a chemical substance at surface temp & pressure = 22.414 litre/mol =
6.0249E23 molecules
Oil quantities and measurements
1 m3 = 6.29 barrels
(6.7 barrels/tonne for crude oil; 8.5 for motor spirits; avg 7.3)
1 tonne crude oil = 7.3 barrels average = 256 Imp gall = 301 US gall
1 barrel per day = 50 tonnes oil / yr (average)
1 barrel = 34.97 Imperial gallons = 42.00 US gallons = 159.0 l
1 km3 = 1E9 m3 = 0.2399 mi3 = 810600 acre-feet
1 mile-per-gallon US (mpg) = 0.4251 km/l kilometres-per-litre. 50mpg = 21.26 km/l
1 mile-per-gallon IMPERIAL (mpg) = 0.3541 km/l kilometres-per-litre. 50mpg =
17.71 km/l
Sulfur content of gasoline is approximately 350 ppm.
Geometry
pi = 3.14159
Circumference of a circle = 2 x pi x r, where pi = 3.14159 and r = radius
Area of a circle = pi x r x r.
Area of an ellipse with axes a and b = pi x a x b
Surface area of a sphere = 4 x pi x r x r
Volume of a sphere = 4/3 x pi x r x r x r
Volume of a cone with height h and base radius r = pi x h x r x r / 3
Volume of a pyramid with base area b and height h: = h x b / 3
Surface area of a triangle with base b and height h = b x h / 2
Area of a regular pentagon with side a, = 1.721 x a x a. Hexagon = 2.598 x a x a. Octagon =
4.828 x a x a
Area of a trapezium with parallel sides a and b and height h = 0.5 x ( a + b ) x h
The distance between two points (x1,y1) and (x2,y2) = SQR( (x2 - x1)2 + (y2 - y1)2 )
Equation or formula for a parabola: y2 = 4 x a x x, where a = focus
Equation for an ellipse: x2 / a2 + y2 / b2 = 1
Equation for a hyperbola: x2 / a2- y2 / b2 = 1
World dimensions
Radius: equatorial = 6378.163 km. polar = 6356.177 km
Circumference: equatorial = 40074 km. polar = 39942 km
Mean elevation of continents = 800 m (840m). Mean depth of oceans = 3800m (3729m*, 3730m,
3795m). Contains 97% of all water (not ice).
Total surface = 510.1E6 km2. Surface of oceans = 361.3E6 km2 (70.8%)
Mixed surface layer avg depth= 75m. Mixed layer volume=
Surface area of ice-free land = 133E6 km2 Productive land 88E6 km2 = 8.8 Gha.(66%). Sea
ice= 33E6km2.
Continents & Islands: 148.8E6 km2. Eurasia= 0.536E14 m2. Africa= 0.298E14 m2. N-America
+ Central= 0.238E14 m2. S America= 0.179E14 m2. Antarctica= 0.149E14 m2. Oceania=
0.089E14m2.
Cosmic dimensions
Mean distance to sun = 149.6E6 km = 497 s = 8.28 minutes
Mean distance to moon = 384,000 km = 3.84E8 m = 1.3 light-seconds
Geostationary orbit = 35,900 km from surface = 42,200 km from earth's centre (?)
Mass of moon = 7.4E22 kg
Mass of Earth = 600E22 kg.
Velocity of light in vacuum (Einstein's constant), c = 2.9979E8 m/s (approx 300,000 km/s)
1 light year = 9.454E12 km
Escape velocity from Earth = 11.2 km/s. For orbital velocities see oceans/currents/atmosphere
velocity
radius time to fall to
microns ocean bottom 4000m
cm/s
1 0.00025 51 years
10 0.025 185 days
100 (Stokes) 2.5 1.8 days
100 (Oseen's) 1.7 2.7 days
See also Heezen& Hollister's diagram of current velocities for erosion, transportation and
sedimentation, oceano/soil51.gif
For particles larger than 1mm their speed increases ten fold for a hundred fold increase in diameter thus
following a square root function. A 1mm particle sinks at about 20cm/s. A one metre boulder would
sink at 6.3 m/s or 22.7 km/h, at fast bicycling speed.
1 bar = 100 kPa = 1E5 Pa = 1E5 N/m2 = 10.20 t/m2 = 0.9869 atmosphere = 750 torr
1 atmosphere = 1.013 bar = 14.7 lb/in2 = 76.0 cm of mercury = 1.013E6 dyne/cm/cm = 1013 kPa
1 inch of mercury (inHg) = 33.9 mb = 3.390 Pa
1 torr = 1mm mercury = 1.333 mbar
1 ton/in2 = 15.4 MPa
1 pound/acre = 1.12085 kg/ha
1 pound/in2 (psi) = 1 lbf/in2 = 6895 Pa =6.805E-2 atm = 51.71 mm Hg = 6.859E-2 bar
Atmosphere at sea level: mass density = 1.225 kg/m3. Pressure = 1.01325 bar
Molecules/litre = 2.547E22. Average temperature = 15.0 ºC
Molecular weight of air = 28.96 g/mole. Oxygen = 2 x 16 = 32. Nitrogen = 2 x 14 = 28.
1 Joule (J) = 1 N m = 2 kg m/s = 1E7 ergs = 1 watt-second (Ws) = 0.2390 calories (cal)
One joule is the amount of energy used when a force of 1 newton moves an object 1 metre in the
direction of the force.
1 erg = 1 g cm cm = 1E-7 J
1 food calorie = 1 kcal = 4184 J
1 kilojoule (kJ) = 1000 J = 0.9484 Btu (British thermal units) = 737.6 foot pounds (ft lb) = 2390
cal = 0.2778E-3 kWhr
1 Btu is the quantity of heat needed to raise the temperature of 1 pound of water by 1 °F.
1 British thermal unit (Btu) = 1055.056 J
1 therm = 100,000 Btu = 106 MJ
1 horsepower (hp) = 0.746 kW; 1 kW = 1.34 hp
1 kilowatt-hour = 3600 kJ = 3.6 MJ = 3413 Btu = 859.845 kilocalories (kcal) = 1.98E6 foot-
pounds = 0.034 therms
1 kilowatt-year = 31.56E9 J
1 kilowatt (kW) - 1 kJ/s = 1.341 horsepower (Hp)
1 quad = 1 quadrillion BTU = 1E15 Btu = 1.055E18 J = 1.055 EJ = 2.930E11 kWh = 0.001 Q
1 langley = 1 cal/cm2; 1 Langley/minute = 0.6974 kW/m2
1 electronvolt = 1.602E-19 J (1.502???)
A small car example: a small motor car's engine is about 40 kW energy output = 40 kJ/s = 40 x 1.341 =
53.6 Hp
In one hour (=3600 s), this car can produce 3600 x 40 kJ = 144000 kJ = 144E6 J = 144/4.2E6, equal to
34.2 kg of TNT explosives.
An internal combustion motor of this capacity uses about 10 litre fuel per hour (352E6 J), travelling at
120 km/hr (at 32 KW):
An internal combustion motor runs at near 30% efficiency, requiring an amount of fuel equal to 3x its
energy output. The energy content of gasoline is about 46 MJ/kg or about 37 MJ/litre. The car above
would have consumed 144 x 3 MJ = 11.7 litres.
Energy statistics relating to the airplane attack on the World Trade Centre in New York, 11
September 2001:
Towers: 410m tall; total weight 1.25 Mt; Collapse energy = 0.5 x 410 x 1.25E9 x 9.8= 2.5E12 J = 597 t
TNT (Sci-Am: 500t ).
Fuel: Boeing 767 fuel capaciry 23,980 Gall (USA) = 90,800 litres = 2.7E12 J = 640 t TNT; Together
1280t TNT (Sci-Am: 1170 t)
Impact: direct explosion 3000 gall = 180 t TNT; fire afterwards 990 t TNT.
Takeoff weight of airplane 412,000 lb = 187 t. Typical cruising speed: 530 mph = 853 km/h = 237 m/s.
Kinetic energy of each plane : 0.5 x 187000 x 237 x 237 = 5.2E9 J = 1.24t TNT; Together 2.5 ton TNT
(Sci-Am: 2 t).
By comparison: Tomahawk cruise missile = 0.5 t TNT; Hiroshima bomb = 20,000 t TNT; a typical
tornado = 5,100 t TNT.
(Source: Scientific American Nov 2001 p 10) Note that Sci-Am arrives at slightly different values for
energy equivalents.
Solar energy striking top of atmosphere = 1.72E17 W. Solar energy reaching surface = 8.6E16
W
Solar energy per m2 on outside of atmosphere: average 1.360 kW/m2; 1.406 in June solstice and
1.314 in December solstice.
Ultraviolet 0-380nm = 10.0%; visible 380 - 760 nm = 44.8%; infrared > 760nm = 45.2%.
Evaporation of water = 4.13E15 W. Gross photosynthesis = 2E14 W.
Global gross primary production (V Smil) 1E14 W.
Theoretical amount of energy from uranium U-235 burner-type fission = 79E12 J/kg (2,700,000
x coal), but these reactors run at 1-2% fuel utilisation (50,000 x coal). A breeder-type of fission
can run at 40-70% fuel utilisation (1,500,000 x coal).
Because Uranium ore contains about 0.2% U3O8 ore, 1 kg of uranium-containing ore produces
as much energy as 100 kg of coal in a standard fission reactor.
Energy conversion
Potential energy E = m x h x g (J) where m = mass (kg) and h = height (m) and g= 9.81 =
acceleration of gravity
Kinetic energy E = 0.5 x m x v x v where m= mass and v = velocity
Converting mass to energy: E = m x c x c where m = mass and c = speed of light
1 g of matter = 9E13 J = 25 GWh
1 atomic unit of mass = 1 u = 1.49E-10 J= 931 MeV
1 electron = 0.000549 u = 0.510 MeV
Electrical noise power P = k x T x B watt, where k = Boltzman's constant, T = temperature ºK
and B = bandwidth (hz)
To photosynthesise 1 kg of carbon, 4.77E8 J in potential energy is obtained, = 1.14E8 cal.
per gram of carbohydrate: 15.9kJ= 3.8 kcal.
To electrolyse 1 mole of a substance, 96,500 Coulombs of electricity are required for each of its
valence.
e.g. 96,500 Coulombs to electrolyse 1 mole of copper (Cu++) = 63.54 deposits 31.77 gram.
Heat
Heat is the energy passed from one substance to another. Heat capacity = specific heat = heat
storage (per kg per degree)
Energy radiation
1 Gray (Gy) = 1 J/kg
1 rad = 10 mGy = 1E-7 J absorbed per gram of material.
Q = Quality factor: 1 for X-ray and gamma radiation; 10 for beta and 20 for alpha radiation
RBE = Relative Biological Effectiveness=
1 rem = 1 rad x Q (above). Maximum permissible human dosage = 0.1 - 0.2 rem/yr = 1 - 2
mSv/yr (??)
A sudden dose of 350 rem gives 50% mortality in 30 days.
1 Sievert = 1 Sv = 100 rem; 1 mSv = 0.1 rem.
1 Curie = 3.7E10 Becquerel (Bq) = 3.7E10 disintegrations/s = 1 gram of pure radium
One flight from New York to HongKong = 0.1 mSv; Watching TV = 0.01 mSv/yr.
Maximum occupational exposure per year: 50 mSv (equals 500 flights as above). Max for pregnant
women: 5 mSv.
Radiation hazard of 3.6 mSv equals a loss of life expectancy of 1.5 minutes or fewer than 2 cigarette
puffs.
(Source: Sci-Am Jan 2002 p 20)
Thermodynamics
First law, conservation of energy: Energy can neither be created nor destroyed. If energy in one
form or one place disappers, it must show up in another form or another place. Energy can be
converted from one form to another, but its total amount remains the same.
Decrease in internal energy = heat produced + work done: dE = Q + W
Second law, all forms of energy ultimately reduce to heat: All physical processes lead to a
decrease in the availability of the energy involved. Processes involving energy transformations
will not occur spontaneously unless there is a degradation of energy from a non-random to a
random form. All spontaneous (natural) events act to increase the entropy within a system. Until
a system reaches its maximum entropy, it can do useful work. But as a system does work, its
entropy increases until the system can no longer perform work.
Ideal gases
An 'ideal' gas is a conceptual one, behaving contrary to the second law, by not losing energy
during expansion or compression.
The volume of one mole of a substance, produces 22.4 litres of an ideal gas at OºC, 1 At, and
24.5 @ 25ºC
Thus 1 mole of oxygen, O2 = 2 x 16 = 32 g, produces 22.4 litres of gas with a density of 32/22,400 = 1.43E-3
g/cm3 @0ºC
which is 700 times lighter than water. Air averages 28.96 g/mol = 1.29E-3 g/cm3 @0ºC = 773 times lighter than
water.
The abve laws are derived from the more universal equation P x V = R x T
Where R = Gas constant = 8.317 J/mol/ºK, amount of heat to warm up one mole of a gas
Henry's law: at a constant temperature, the amount of a given gas dissolved in a given type and
volume of liquid is directly proportional to the partial pressure of that gas in equilibrium with
that liquid (for small concentrations, not saturated).
e^p = e^{kc} or e p = e k c
p = the partial pressure of the gaseous solute above the solution in atmospheres (approx kg/cm2)
c = the concentration of the gaseous solute in the solution in mol/Litre or mol/kg for water
k = the Henry's Law constant, which various with the kind of solvent and temperature. solubility
decreases with increasing temperatures.
Examples of the value for k at 26ºC: O2=769.2 ; CO2= 29.4; H2= 1282.1 L·atm/mol See
http://www.henrys-law.org/
Stephan-Boltzman equation
Defines the radiation emitting from an object of temperature T ºK: I = emissivity x 5.6704E-8 x
T^4 W/m2
where emissivity = 1.00 for a black body; 0.997 for water; 0.969 for snow; desert sand 0.993.
Electricity
Coulomb's law constant = 1 / (4 x pi x e0) = 9.0E9 N m2 C-2
Permittivity constant ( in vacuum) e0 = 8.8541853E-12 C2 N-1 m-2
Permeability constant (in vacuum) m0 = 4 x pi x 1E-7 Wb A-1 m-1
Faraday's constant = 9.64867E4 C/mol
1 Ampere = 1 Coulomb/second.
Physical constants
Pi = 3.14159265
Natural logarithm e = 2.71828. ln(x) = 2.3026 log(x)
Standard acceleration of gravity, g =0.98066 m/s/s
Perfect gas constant, R = 8.3143 J/(g mol)/ºK. [Amount of energy needed to heat a gas]
Avogadro's number, N = 6.022169E23 molecules/(g mol) [Number of molecules in a mole]
Faraday constant, F = 9.648670E-4 C/mol
Stefan-Boltzmann constant, sigma = 5.6697E-8 W/m2/ºK4 Also quoted as 5.6704E-8
Planck's constant, h = 6.6255E-34 Js [Amount of energy in an electro-magnetic wave; quantum
theory]
Boltzmann constant, k = 1.380622E-23 J/ºK. [Amount of radiated energy of a black body;
entropy]
Biology
Humans
Mean human mass worldwide = 50 kg, contains 1.9 kg nitrogen, which is 15% of body mass.
Nitrogen content of proteins = 25%
The mean human body contains 0.9 kg phosphorus, most of it in bones.
Food energy per day = 2400 kcal = 10 MJ
Maximum daily output of a manual worker = 0.5 kWh = 1.8 MJ
Plants
Dry weight (DM) of a crop is about 25% of wet weight.
Carbon content of dried matter (DM) = 45% (containing carbohydrates CH2O chains)
Nitrogen content of DM is 1.1 - 1.6%
Biomass calculations
The ratios shown are not by weight but by the numbers of atoms.
Average composition of terrestrial life: H:O:C:N:P:S = 2960:1480:1480:16:1.8:1 (E S
Deevey Jr)
Average composition of land plants: H:O:C:N:P:S = 1600:800:800:9:5:1
Average composition of marine plants: H:O:C:N:P:S = 212:106:106:16:2:1
Average composition of plant biomass: C:H:O= 1:(1.3-1.8):(0.5-0.6)
(McDermitt&Loomis 1981)
1 kg dry organic matter (DM) = 0.45 kg C = 1.5 kg CO2 (with 15% variation) = 4200
kcal energy
Rule of thumb: 4kcal per gram of dry organic matter
1 kg C corresponds to 2.2 kg dry organid matter. Wet weight (plants) = 4 x dry weight.
Animals
1 kg of beef requires 50,000 kg of water.
A general equation to estimate the food requirement of marine mammal species (Innes et al
1987)
Daily food cunsumption (kg biomass) Y = 0.123 x M ^ 0.80 or log(Y) = log(0.123) + 0.8 x
log(M)
Biochemical productivity
Plant productivity increases 100% with 12ºC temperature increase
Soil [note that facts relating to soil are traditionally expressed per hectare ha]
Natural erosion before farming: 9E9 tonnes worldwide. In 1984: 25E9 tonnes
Tennessee: losing 14 t/acre/yr = 35t/ha/yr.
Nature puts back 5 t/acre/yr= 10t/ha/yr: Loss= 25t/ha/yr = 15m3/10,000m2/yr = 1.5mm /yr
Conservation farming reduced soil loss from 14 to 10 t/acre/yr
tropical rainforest = 180 t/acre in dry matter
sediment yield from erosion by water 20-2600 t/sqkm/yr avg 30-92 m3/sqkm/yr
=9 km3/yr particles + 9.4E9 ton dissolved = 6 cm/1000yr= 0.06 mm/yr (Last Frontier p367)
Natural rate of weathering = 0.1mm/yr = 0.1 x 0.001 x 10,000 m3/ha/yr = 1m3/ha/yr = 100
m3/km2/yr = 1.5t/ha/yr
Water
Capillary rise of height h in a tube with diameter d : h = 0.3 / d (in cm) (approximately)
A hair-thin capillary of 0.1 mm = 0.01 cm causes water to rise by 30 cm.
NZ vital statistics
NZ soil erosion: 270Mt/yr = 1000 t/km2/yr = 10 t/ha/yr = 6 m3/ha/yr is about six times the
sustainable rate, which is severely underestimated. But most erosion by far comes from the
13Mha of agricultural land (about 50% of the land), which makes erosion 12 times the
sustainable rate. But NZ has always had very low natural erosion and in recent years erosion has
accelerated due to more torrential rains. so, NZ erosion may well top 400Mt/yr or over 20 times
of what was natural.
loss of Carbon by soil erosion, estimated at between 3 and 10 Mt C per year (AgResearch)
Mathematics refresher