Lembar Kerja Peserta Didik (LKPD)

“Penentuan Perubahan Entalpi Reaksi Berdasarkan Hukum Hess

dan Data Perubahan Entalpi Pembentukan Standar, ∆Hf⁰ ”

Kelas :
Namakelompok :
Anggotakelompok :

KompetensiDasar:
3.5 Menjelaskanjenisentalpireaksi, hukum Hess dankonsepenergiikatan

Indikator:
1. Menentukannilai ∆H reaksimenggunakanHukum Hess
2. Menentukannilai ∆H reaksimenggunakan data ∆H f⁰

A. Menentukannilai ∆H reaksimenggunakanHukum Hess

1. Tuliskan bunyi hukum Hess
…………………………………………………………………………………………………………………………….
………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………
………………………………………………………………………………………………………………………………………………………

2. Tentukan nilai △H dari diagram siklus dibawah ini :

∆H3 = -394 KJ

C(s) + ∆H=- CO2(g)

394kJ
O2(g)= ?
∆H ∆H2=-
1
CO(g) 283kJ
Jawab :
+½O2(g)
 3. Perhatikan diagram tingkat energi di bawah ini !

½ N2(g) + O2(g)

△H2= .....Kj

△H1
-57,05 KJ NO (g) + ½ O2 (g)

△H3= ..... kj

-90,25 KJ NO2 (g)

Berapakah/ tentukanlah nilai; △H1,△H2△H3?

Jawab :

4. Tentukanperubahanentalpireaksi:
2SO2(g) + O2(g) 2SO3(g) ……………..…… (1)

Jika diketahui:
S(g) + O2(g) SO2(g),H = -295 kJ …. (2)
2S(g) + O2(g) 2SO3(g),H = -785 kJ …... (3)

Jawab :2S(g) + O2(g) 2SO3(g),H = -785 kJ …... (3)

SO2(g) S(g) + O2(g) ,H = +295 kJ …. (2)+

....... +......  ......... , H=.......... ......(1)

Dari persoalan diatas(4), apa yang dapat kamu kemukakan untuk menetukan ∆H rx
,dengan data reaksi yang sudah diketahui ? diskusikan dengan kelompok mu !

.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................

B. Menentukannilai ∆H reaksimenggunakan data ∆H f⁰

5. Diketahuientalpipembentukanbeberapasenyawasebagaiberikut:
∆Hf⁰ C2H6(g) = -84,86 kJ/mol
∆Hf⁰ C3H8(g) = -103,85 kJ/mol
∆Hf⁰ CO2(g) = -393,5 kJ/mol
∆Hf⁰ H2O(l) = -285,5 kJ/mol
Denganmenggunakan data perubahanentalpidiatas, hitunglah
∆Hreaksiberikut!
a. 2C2H6(g) + 7O2 → 4CO2(g) + 6H2O(l)
b. C3H8(g) + 5O2 → 3CO2(g) + 4H2O(l)

Jawab :

a.H rx =4.HCO2+ 6.HH2O– 2.∆Hf⁰C2H6 + 7. ∆Hf⁰O2

=(..............+...............) - ( ...............+.............)
6. Dari kegiatan no 5 diatas apa yang dapat kamu simpulkan untuk menentukan
∆Hrx , bila diketahui harga ∆Hf⁰dari zat yang bereaksi ?
Jawab;.................................................................................................................
............................................................................................................................
............................................................................................................................
............................................................................................................................
............

7. Jikadiketahuientalpireaksi: NH4Cl(g) → NH3(g) +HCl(g)adalah 175,9 kJ.

∆Hf⁰ NH4Cl= -314,4Kj/moldan ∆Hf⁰ HCl = -92,3 Kj/mol.
Hitunglahentalpipembentukan NH3 !
Jawab :

KESIMPULAN : (kegiatan A dan B )

.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
.......................................................................................................................................
............................