Application
Refinery feedstock
Fuel blending component
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Hydrogen sulphide (H2S), an extremely toxic and highly flammable gas, and other flammable light hydrocarbon gases
may collect in vapour spaces where product is stored.
Polycyclic aromatic hydrocarbons will be present, some of which have been shown by experimental studies to induce
skin cancer.
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Contact with hot product may cause burns.
May cause cancer, classified as a category 2 carcinogen.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Repeated exposure may cause skin dryness or cracking.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
If hot material enters the eye, flood immediately with cold water to dissipate the heat, if possible, ensuring eyelids are
held open. Take the casualty to hospital for examination and treatment without delay.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
If hot product causes burns, the affected area should be flooded immediately with, or immersed in cold water for 10
minutes, or longer if pain persists. Burns should be covered with clean cotton or gauze, and the casualty taken to
hospital as soon as possible for examination and treatment.
Never use gasoline, kerosine or other solvents to remove fuel oil from skin or clothing.
Medical advice must be obtained urgently if product under high pressure has been injected through the skin.
Ingestion
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
If ingested, do not induce vomiting.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Ensure good ventilation.
Evacuate all non essential personnel from the immediate area.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Depending upon its temperature the product may be liquid, semi-solid or solid.
Protect drains from spills and prevent entry of product, since this may result in blockage on cooling. Should blockage
occur, notify the appropriate authority immediately.
Scrape up bulk of solid material and remove liquid with sand or other suitable inert absorbent material. If necessary,
clean the contaminated area using hot water and detergent: absorb the washings - do not wash into drains.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Avoid inhalation of dust from combustion/exhaust spaces.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
mists generated will create a flammability or explosion hazard.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
When handling heated material suitable protective clothing of an appropriate standard should be worn to prevent
thermal burns.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Will cause burns if hot material contacts skin
As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may
eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Ingestion
Unlikely to be swallowed in view of the high handling temperatures.
Inhalation
May be irritating to eyes, nose and throat at high vapour concentrations.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin
cancer. The inhalation of vapour, mists or fumes over long periods may therefore be hazardous.
Dusts generated during the removal of ash deposits from engine/boiler combustion surfaces or exhaust spaces, will be
harmful if inhaled and may cause nausea and eye, nose and throat irritation. Repeated contact may result in serious
irreversible disorders.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
This material may accumulate in sediments.
Aquatic toxicity
Harmful to aquatic organisms, may cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: Light fuel oil 2; Heavy fuel oil 1
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed
waste disposal contractor.
At sea, used or unwanted product should be stored for eventual discharge into port approved waste oil disposal
facilities.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
Not classified as hazardous for transport (ADR, RID, UN , IMO, IATA/ICAO).
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Carcinogenic category 2
Dangerous for the environment
EU Labelling
Symbol:
Skull and crossbones
Indication of danger:
None
Risk ( R ) Phrases:
R45 May cause cancer
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance Name: Heavy Fuel Oil, EINECS No: 265-045-2, 265-058-3, 269-777-3
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
02/09/98 1, 4, 8, 11, 12, 15
17/07/2000 2, 3, 11, 8, 9, 13, 15
Application
Refinery stream
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil UK Ltd, Coryton Refinery, The Manorway, Stanford-le-Hope, Essex SS17 9LL
BP Oil Grangemouth Refinery Ltd, Bo'Ness Road, Grangemouth, Stirlingshire FK3 9XQ
__________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Cold product - Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical
advice if any pain or redness develops or persists.
Hot product - Flood with water to dissipate heat. In the event of any product remaining, do not try to remove it other than
by continued irrigation with water. Obtain medical attention immediately.
Skin
Where skin burns occur the area should be immediately immersed in cold water until the bitumen is thoroughly cooled. Do
not attempt to remove the bitumen from the skin as it provides an airtight sterile covering over the burn which will
eventually fall away with the scab as the burn heals. If for any reason the bitumen must be removed, this can be done using
a slightly warmed medicinal liquid paraffin. Kerosene and other solvents should never be used. All burns should receive
medical attention. It should be noted that bitumen contracts on cooling and where a limb is encased care should be taken to
avoid the development of a tourniquet effect.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce vomiting;
obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If symptoms
persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air and
medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be delayed
for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and consider
administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema develops.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
Use foam, dry powder or water fog. DO NOT USE water jets.
FIRES IN CONFINED SPACES SHOULD BE DEALT WITH BY TRAINED PERSONNEL WEARING APPROVED
BREATHING APPARATUS.
Water may be used to cool nearby heat exposed areas/objects/packages. Avoid spraying directly into storage containers
because of the danger of boil-over.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Depending upon its temperature the product may be liquid, semi-solid or solid.
Protect drains from spills and prevent entry of product, since this may result in blockage on cooling. Should blockage
occur, notify the appropriate authority immediately.
Scrape up bulk of solid material and remove liquid with sand or other suitable inert absorbent material. If necessary, clean
the contaminated area using hot water and detergent: absorb the washings - do not wash into drains.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage which
may be reasonably anticipated.
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable atmosphere is
present before entry.
In the case of large spills contact the appropriate authorities. If spillage occurs call the Environment Agency Emergency
Hotline on 0800 807060 (24 hours a day, 7 days a week).
In the case of spillage on water, the product will sink and recovery may be difficult.
__________________________________________________________________________________
7. HANDLING AND STORAGE
Handling Precautions
Contact with hot product may cause burns.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Avoid skin contact.
Good working practices, high standards of personal hygiene and plant cleanliness must be maintained at all times.
Wash hands thoroughly after contact.
When product is heated to high temperatures, vapour, mists or fumes will be given off and may condense, contaminating
the skin or clothing of operatives. Prolonged or repeated contact with this condensate may give rise to dermatitis or other
skin conditions of a serious or irreversible nature.
Regular periodic self inspection of the skin is recommended, especially those areas subject to contamination. In the event
of any localised changes in appearance or texture of the skin being noticed, medical advice should be sought without delay.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at
temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential
flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care
should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from
storage tanks.
Product should not be over heated in storage because of the risk of fire. For advice on storage temperatures please contact
the local BP office.
Storage Conditions
Store under cover away from moisture and sources of ignition. Do not overheat in storage.
Under no circumstances should water be allowed to contact hot product because of the danger of boil-over. Particular care
should be taken to ensure that bulk storage tanks are watertight and that any steam heating coils are regularly checked for
leaks.
For bulk product, the storage temperature should not fluctuate above and below 100 deg C as this increases the risk of
water condensation leading to boil-over. Care must always be exercised when heating bitumen through 100 deg C.
Highly toxic hydrogen sulphide gas may be emitted from hot product and accumulate in enclosed spaces or tanks. Extreme
care must therefore be taken during venting of tanks and enclosed spaces which have at any time contained hot product.
Under no circumstances should entry be made into small enclosures without taking full precautions.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when no
alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved type and
following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see the comments
in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to effect a
quick rescue.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Pyrophoric (self-heating) deposits, which may cause fire or explosion, may be formed in storage. Avoid exposure of tank
vapour space to fresh air, and maintain stable storage temperatures. Regular inspection for such deposits will indicate when
tank cleaning is necessary.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
Ensure good ventilation.
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
If vapour, mists or fumes are generated, their concentration in the workplace air should be controlled to the lowest
reasonably practicable level.
Comply with current local occupational exposure limit. Where not established, the following limits are recommended.
Asphalt, petroleum fumes
UK publication EH40 (Occupational Exposure Limits):
Occupational Exposure Standard: Long-term exposure limit (8-hour TWA) 5 mg m-3
Short-term exposure limit (15 minute) 10 mg m-3
Protective Clothing
When handling hot product, suitable protective clothing of an appropriate standard should be worn. Depending on the type
of operation this may include:
- Visor to protect the face and head covering with neck flap.
- Gauntlets (heat resistant and impervious to bitumen)
- Overalls, impervious to bitumen, covering full body and limbs with legs worn over boots.
- Protective boots.
- Protective clothing should be regularly dry cleaned and laundered.
Change heavily contaminated clothing as soon as reasonably practicable; dry clean, launder and preferably starch before re-
use. Wash any contaminated underlying skin with soap and water.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators may
unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-supplied
breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas
__________________________________________________________________________________
Typical Values
Grades:Bitumen or Vacuum
residue
Test Method Units
Physical state solid
Colour black
Odour bituminous
Density @ 15°C ASTM D 1298 kg/m3 >1000
Flash point (COC) ASTM D 92 °C >200
Solubility in water g/l <0.1
10. STABILITY AND REACTIVITY
Products of this type are stable and unlikely to react in a hazardous manner under normal conditions of use.
Hazardous polymerisation reactions will not occur.
This material is combustible.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Will cause burns if hot material contacts skin
When product is heated to high temperatures, vapour, mists or fumes will be given off and may condense, contaminating
the skin or clothing of operatives. Prolonged or repeated contact with this condensate may give rise to dermatitis or other
skin conditions of a serious or irreversible nature.
Ingestion
Unlikely to be swallowed in view of the high handling temperatures.
Inhalation
At normal ambient temperatures this product will be unlikely to present an inhalation hazard because of its low volatility.
Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.
The inhalation of vapour, mists or fumes over long periods may therefore be hazardous.
__________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages are unlikely to penetrate the soil.
Bioaccumulative potential
This material is not expected to bioaccumulate.
Aquatic toxicity
Unlikely to cause long term effects in the aquatic environment.
__________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Where possible, arrange for product to be recycled.
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed waste
disposal contractor.
__________________________________________________________________________________
14. TRANSPORT INFORMATION
COLD - Not classified as hazardous for transport (ADR, RID, UN, IATA/ICAO).
Note
Under ADR emptied uncleaned tankers are classified as follows :-
Emptied container class 9, item 71 ADR Latest cargo 3257 Liquid elevated temperature NOS, item 20(c).
__________________________________________________________________________________
15. REGULATORY INFORMATION
Not classified as hazardous for supply.Not classified as hazardous for supply. No Statutory label required.
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
hazards inherent in the nature of the material.
Crude Oil
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Crude Oil
Application
Refinery feedstock
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Polycyclic aromatic hydrocarbons will be present, some of which have been shown by experimental studies to induce
skin cancer.
The following components, considered by various legislative authorities to be hazardous, may be present:
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2
Hydrogen sulphide CAS No. 7783-06-4, EINECS No. 231-977-3
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
Harmful if swallowed - aspiration hazard. (If viscosity <7 cSt at 40°C)
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Product can be removed from the skin using warmed medicinal paraffin. Never use gasoline or kerosine to remove
product from skin or clothing.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
If ingested, do not induce vomiting. Drinking milk or medicinal paraffin may be beneficial.
Aspiration of the product is unlikely to occur except as the result of ingestion, followed by vomiting or regurgitation in a
partially or totally unconscious individual, when immediate effects are most likely to result from the aspiration of acidic
stomach contents. If it should occur, transport casualty immediately to hospital.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Isolate spillage from all ignition sources including road traffic.
Ensure good ventilation.
Evacuate all non essential personnel from the immediate area.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable
atmosphere is present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Any spillage which results in pollution at sea must be treated in accordance with the guidelines in MARPOL 73/78
Annex 1.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Explosive air/vapour mixtures may form at ambient temperature.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to
dermatitis.
As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may
eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Lower viscosity crude oils may injure the lungs if aspiration occurs, eg. during vomiting
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Harmful to aquatic organisms.
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
May cause long term effects in the aquatic environment
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
This information is provided for guidance only. The current legislative text for each mode of transport should be
referred to for definitive information.
** NOTE**, Transport Requirements depend on flash point, initial boiling point and vapour pressure.
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable or Highly Flammable or Flammable or unclassified for flammability (dependent on flash point and
initial boiling point)
Carcinogenic category 2
Harmful (If viscosity <7 cSt at 40°C)
Dangerous for the environment
EU Labelling
Symbol:
Flame (for extremely flammable or highly flammable only)
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE, or HIGHLY FLAMMABLE, or no indication of danger for flammability (dependent on flash
point and initial boiling point)
Risk ( R ) Phrases:
R12 Extremely flammable, or R11 Highly flammable, or R10 Flammable, or no risk phrase for flammability (dependent
on flash point and initial boiling point)
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed. (If viscosity <7 cSt at 50°C)
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance Name: Crude oil , EINECS No: 232-298-5
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
25/09/98 1, 3, 8, 14, 15
______________________________________________________________________________
Heating Oil
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Heating Oil
Alternative Names: No. 2 Fuel Oil, Extra Light Fuel Oil (ELFO), Light Heating Oil, Furnace Oil, Domestic Fuel Oil
Application
Fuel for industrial or domestic boilers; fuel for compression ignition diesel engines.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Cracked components containing polycyclic aromatic hydrocarbon compounds may be present.
Fuels, diesel. EINECS No: 269-822-7, CAS No: 68334-30-5, Xn, R40 Possible risks of irreversible effects, R65
Harmful: may cause lung damage if swallowed, R66 Repeated exposure may cause skin dryness or cracking
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Harmful if swallowed - aspiration hazard.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Repeated exposure may cause skin dryness or cracking.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage, remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable
atmosphere is present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
mists generated will create a flammability or explosion hazard.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to
dermatitis.
As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may
eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
This material may accumulate in sediments.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Harmful to aquatic organisms, may cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
EU Labelling
Symbol:
St. Andrew's Cross
Indication of danger:
HARMFUL
Contains:
Fuels, Diesel
Risk ( R ) Phrases:
R40 Possible risks of irreversible effects
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking
Safety ( S ) Phrases:
S2 Keep out of reach of children
S24 Avoid contact with skin
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
07/05/98 1, 2, 12, 15
02/11/98 1
17/07/2000 2, 3, 4, 9, 12, 15
IMPORTANT: Read this MSDS before handling and disposing of this product and pass this information on to employees,
customers, and users of this product.
Trade Name(s) Thums, OCS (Outer Continental Shelf) Crude, Maya Crude
Exposure Limits
ACGIH OSHA
1 2 3
Component CAS No. % Composition By Volume TLV PEL Units Type
CRUDE OIL, PETROLEUM
8002-05-9 EQ 100 N/AP N/AP
Other applicable exposure guidelines:
(4)
COAL TAR PITCH VOLATILES, AS BENZENE SOLUBLES
65996-93-2 0.2 0.2 mg/m3 TWA
OIL MIST, MINERAL
8012-95-1 10 N/AP mg/m3 STEL
5 5 mg/m3 TWA
STODDARD SOLVENT
8052-41-3 100 100 ppm TWA
Stoddard Solvent exposure limits are listed as an exposure guideline for hydrocarbon vapors that may be similar
to those derived from crude oil.
Since specific exposure standards or control limits have not been established for this material, the exposure limits
shown here are suggested as minimum control guidelines.
1 (1) (2) (3) (4)
Carcinogen displayed after Component Name. Listed by NTP, IARC, OSHA, Other
2
See Abbreviations on last page
3
The OSHA exposure limits were changed in 1993 due to a federal court ruling. ARCO has chosen to list the 1989 OSHA exposure limits in this document as they are generally more
stringent and therefore more protective than the current exposure limits. (Refer to 29 CFR 1910.1000).
3. HAZARD IDENTIFICATION
IMMEDIATE HAZARDS
DANGER
HIGHLY FLAMMABLE! OSHA/NFPA Class 1B flammable liquid. KEEP AWAY FROM HEAT, SPARKS, AND
OPEN FLAME! CONTAINS PETROLEUM DISTILLATES! Avoid breathing vapors or mists. Use only with
adequate ventilation.
Print Date: 12/07/00 ***FOR “DISCLAIMER OF LIABILITY”, SEE THE STATEMENT ON LAST PAGE*** Page 1 of 6
HEAVY CRUDE OIL MSDS No. RS294 Ver. 3
If swallowed, do not induce vomiting since aspiration into the lungs may cause chemical pneumonia. Obtain
prompt medical attention.
May cause irritation or more serious skin disorders! May be harmful if inhaled! May cause irritation of the nose,
throat, and lungs, headache, dizziness, drowsiness, loss of coordination, fatigue, nausea and labored breathing.
May cause irregular heartbeats. Avoid prolonged or repeated liquid, mist, and vapor contact with eyes, skin, and
respiratory tract.
Wash hands thoroughly after handling.
Sulfur compounds in this material may decompose to release hydrogen sulfide gas which may accumulate to
potentially lethal concentrations in enclosed air spaces. Vapor concentrations of hydrogen sulfide above 50 ppm,
or prolonged exposure at lower concentrations, may saturate human odor perceptions so that the smell of gas
may not be apparent. DO NOT DEPEND ON THE SENSE OF SMELL TO DETECT HYDROGEN SULFIDE!
Long-term tests show that similar crude oils have produced skin tumors on laboratory animals.
Crude oils contain some polycyclic aromatic hydrocarbons which have been shown to be carcinogenic after
prolonged or repeated skin contact in laboratory animals.
Summary of Personnel with preexisting central nervous system disease, skin disorders, or chronic
Chronic Hazards respiratory diseases should be evaluated by an appropriate health professional before
and Special exposure to this material.
Health Effects
Prolonged/repeated skin exposure, inhalation or ingestion of this material may result in
adverse dermal or systemic effects. Avoid prolonged or repeated exposure.
May be harmful if absorbed through the skin. Prolonged or repeated contact may create
cancer risk, organ damage, and adversely affect reproduction, fetal development and fetal
survival. Avoid all skin contact.
See Section 11 for Additional Toxicological Information.
Inhalation Immediately remove personnel to area of fresh air. For respiratory distress, give oxygen,
rescue breathing, or administer CPR (cardiopulmonary resuscitation) if necessary. Obtain
prompt medical attention.
Eye Contact Flush eyes with clean, low-pressure water for at least 15 minutes, occasionally lifting the
eyelids. If pain or redness persists after flushing, obtain medical attention.
Skin Contact Immediately remove contaminated clothing. Wash affected skin thoroughly with soap and
water. If irritation persists, obtain medical attention.
Ingestion Do not induce vomiting since aspiration into the lungs may cause lipoid pneumonia. Obtain
prompt medical attention.
Emergency See above procedures. Personnel with pre-existing central nervous system disease, skin
Medical disorders, chronic respiratory diseases, or impaired liver of kidney function should avoid
Treatment exposure to this product.
Procedures
Flash Point (Method) * Based on NFPA Petroleum, Crude AP 20°F to 90°F NFPA Hazard Rating:
Autoignition Temperature (Method)* N/DA + Health: 2 = Moderate
Flammable Limits (% Vol. in Air) Lower AP 1 + Fire: 3 = High
* At Normal Atmospheric Temperature and Pressure Upper AP 8 Reactivity: 0 = Insignificant
+
Based on NFPA 325 Special: = ---
Fire and HIGHLY FLAMMABLE! This material releases flammable vapors at or below ambient
Explosion temperatures. When mixed with air in certain proportions and exposed to an ignition source,
Hazards these vapors can burn in the open or explode in confined spaces.
Flammable vapors may travel long distances along the ground before reaching a point of
ignition and flashing back.
Open top tanks involved in a fire have a potential for "boil-over" if water or water-in-oil
emulsion is at the bottom of the tank. Boil-over may result in a large expulsion of burning oil
from the tank, greatly increasing the fire area.
Precautions if Contain spill, evacuate non-essential personnel, and safely stop flow. On hard surfaces,
Material is Spilled spilled material may create a slipping hazard. Equip cleanup crews with proper protective
or Released equipment (as specified in Section 8) and advise of hazards. Clean up by recovering as
much spilled or contaminated materials as possible and placing into closed containers.
Consult with an environmental professional for the federal, state and local cleanup and
reporting requirements for spills and releases.
Handling, Store and transport in accordance with all applicable laws. KEEP AWAY FROM HEAT,
Storage and SPARKS, AND OPEN FLAME! KEEP CONTAINERS CLOSED, PLAINLY LABELED AND
Decontamination OUT OF CLOSED VEHICLES! Containers should be able to withstand pressures expected
Procedures from warming orocooling in storage. Ground all drums and transfer vessels when handling.
Store in cool (80 F or below), well-ventilated location. All electrical equipment in storage
and/or handling areas should be installed in accordance with applicable requirements of the
National Electrical Code (NEC).
KEEP OUT OF REACH OF CHILDREN!
Empty containers retain some liquid and vapor residues, and hazard precautions must be
observed when handling empty containers.
For determining National Electrical Code (NEC) Hazardous (Classified) location
requirements for electrical installations, consider this material Class 1, Group D.
Engineering Where possible, use adequate ventilation to keep vapor and mist concentrations of this
Controls material below the Occupational Exposure Limits shown in Section 2. Electrical equipment
should comply with National Electrical Code (NEC) standards (see Section 7).
Respiratory Where there is potential for exposure to hydrogen sulfide gas in excess of the permissible
exposure limit, a NIOSH/MSHA-approved supplied-air respirator operated in positive
pressure mode should be worn.
If hydrogen sulfide gas is not present in excess of permissible exposure limits, a
NIOSH/MSHA-approved air-purifying respirator with an organic vapor cartridge may be
permissible under certain circumstances where airborne concentrations of hydrocarbon
vapor may exceed the exposure limits in Section 2. Where work conditions may generate
airborne mists of the material, also use a high-efficiency particulate pre-filter. Consult a
health and safety professional for guidance in respirator selection. Respirator use should
comply with OSHA 29 CFR 910.134.
CAUTION: The protection provided by air-purifying respirators is limited. Use a positive
pressure air-supplied respirator if there is any potential for an uncontrolled release, if
exposure levels are not known, or if concentrations exceed the protection limits of the air-
purifying respirator.
Eyes Eye protection should be worn. If there is potential for splashing or spraying, chemical
protective goggles and/or a face shield should be worn. If contact lenses are worn, consult
an eye specialist or a safety professional for additional precautions. Suitable eye wash water
should be available in case of eye contact with this material.
Skin Avoid all skin contact with this material. If conditions of use present any potential for skin
contact, clean and impervious clothing such as gloves, apron, boots, and facial protection
should be worn. Neoprene, Nitrile, Butyl Rubber or Viton glove material is recommended.
When working around equipment or processes which may create the potential for skin
contact, full body coverage should be worn, which consist of impervious boots and oil-
resistant coated Tyvek suit or other impervious jacket and pants.
Non-impervious clothing which accidentally becomes contaminated with this material should
be removed promptly and not reworn until the clothing is washed thoroughly and the
contamination is effectively removed. Discard soaked leather goods.
Other Hygienic Use good personal hygiene practices. If skin contact should occur, material should be
and Work removed from the skin with a waterless hand cleaner, and the affected area should then be
Practices washed with a mild soap and water. Wash hands and other exposed areas thoroughly
before eating, drinking, smoking or using toilet facilities.
Stability Stable
Hazardous Polymerization Not expected to occur.
Other Chemical Reactivity N/AP
Toxicological The information found in this section is written for medical, toxicology, occupational health
Information and safety professionals. This section provides technical information on the toxicity testing
of this or similar materials or its components. If clarification of the technical content is
needed, consult a professional in the areas of expertise listed above.
Prolonged/ IARC has determined there is "limited evidence for the carcinogenicity in experimental
Repeated animals of crude oil" and "inadequate evidence for the carcinogenicity in humans of crude
Exposures oil." IARC concludes that "crude oil is not classifiable as to its carcinogenicity to humans
(Group 3)."
Crude oil administered orally to pregnant rats during gestation produced increased number
of resorptions and decrease in fetal weight and length.
Not Available
Waste Disposal Consult environmental professional to determine if state or federal regulations would classify
Methods spilled or contaminated materials as a hazardous waste. Use only approved transporters,
recyclers, treatment, storage or disposal facilities. Comply with all federal, state and local
laws pertaining to waste management.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 - PROPOSITION 65
PROP 65 WARNING LABEL:
Chemicals known to the State to cause cancer, birth defects, or other reproductive harm are found in gasoline,
crude oil, and many other petroleum products and their vapors, or result from their use. Read and follow label
directions and use care when handling or using all petroleum products.
This product contains the following chemical(s) listed by the state of California as known to cause cancer or birth
defects or other reproductive harm.
(C)
MINERAL OILS, UNTREATED
Other Prop 65 chemicals will result under certain conditions from the use of this material. For example, burning
fuels produces combustion products including carbon monoxide, a Prop 65 reproductive toxin.
(C)
= Carcinogen
General The information and conclusions herein reflect normal operating conditions and may be from
Comments sources other than direct test data on the mixture itself.
Disclaimer of Liability
The information in this MSDS was obtained from sources which we believe are reliable. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY
WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS.
The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. FOR THIS AND
OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS DAMAGE OR EXPENSE ARISING OUT OF
OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be
applicable.
Application
Fuel for industrial or domestic boilers; fuel for compression ignition diesel engines.
Company Identification
Singapore Refining Company Pte. Ltd.
Pulau Merlimau
Jurong
Singapore
Hazardous Components
Cracked components containing polycyclic aromatic hydrocarbon compounds may be present.
__________________________________________________________________________________
3. HAZARDS IDENTIFICATION
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Harmful if swallowed - aspiration hazard.
_______________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any pain
or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing and
wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water. If larger amounts are swallowed, do not induce
vomiting; transport casualty together with the product container, its label or the safety data sheet urgently to hospital.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If symptoms
persist obtain medical advice.
Medical Advice
Note: High Pressure Applications
Injections through the skin resulting from contact with the product at high pressure constitute a major medical emergency.
Injuries may not appear serious at first but within a few hours tissue becomes swollen, discoloured and extremely painful
with extensive subcutaneous necrosis.
Surgical exploration should be undertaken without delay. Thorough and extensive debridement of the wound and
underlying tissue is necessary to minimise tissue loss and prevent or limit permanent damage. Note that high pressure may
force the product considerable distances along tissue planes.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of
vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotrachael intubation.
Monitor for cardiac disrhythmias.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
FIRES IN CONFINED SPACES SHOULD BE DEALT WITH BY TRAINED PERSONNEL WEARING APPROVED
BREATHING APPARATUS.
Combustion Products
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
Isolate spillage from all ignition sources including road traffic.
Ensure good ventilation.
Evacuate all non essential personnel from the immediate area.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable atmosphere is
present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover product
from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate government/regulatory
authorities.
__________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to the
safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere
has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an
oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to effect a
quick rescue.
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even
at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential
flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care
should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from
storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product soaked rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to
accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never cut,
weld, solder or braze empty containers.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
Comply with current local occupational exposure limit.
If vapour, mists or fumes are generated, their concentration in the workplace air should be controlled to the lowest
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and preferably
starched after use.
Respiratory Protection
The use of approved breathing apparatus in confined spaces, by trained personnel, must only be undertaken strictly in
accordance with Statutory Regulations governing such entry.
Typical Values
Grades:Low Sulphur Fuel Oil
Test Method Units
Physical state liquid
Colour amber
Odour oily
Density @ 15°C ASTM D 1298 kg/m3 805-890
Flash point (PMC) ASTM D 93 °C 55 - 70
Kinematic viscosity @ 20°C ASTM D 445 mm2/s 2-7
Vapour pressure °C ASTM D 323 kPa 4
Boiling point/range ASTM D 86 °C 160 -
385
10. STABILITY AND REACTIVITY
Stable at ambient temperatures.
Hazardous polymerisation reactions will not occur.
Conditions to Avoid
Avoid temperatures at or near flash point.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to
dermatitis.
This material contains significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which has been shown
by experimental studies to induce skin cancer.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
May be harmful to aquatic organisms.
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
__________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed waste
disposal contractor.
__________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Gas oil, Flammable Liquid Class 3, Item 31(c) Hazard Identification No 30
UN: GAS OIL, Flammable liquid, Class 3, Packing Group III, UN Number 1202
IATA/ICAO: Gas oil, Flammable liquid, Class 3, Packing group III
IMO: GAS OIL, Flammable liquid, Class 3.3, Packing group III
EMERGENCY ACTION CODE: Flammable liquid, 3[Z]
__________________________________________________________________________________
15. REGULATORY INFORMATION
EC Labelling
Risk ( R ) Phrases:
R40 - Possible risks of irreversible effects
Safety ( S ) Phrases:
S24 - Avoid contact with skin
S36/37 - Wear suitable protective clothing and gloves
S43 - In case of fire, use foam/dry powder/CO2/halon. Never use water.
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-On-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed the information contained herein which we received from sources outside SRC .
However, no warranty or representation, expressed or implied is made as to the accuracy or completeness of the data and
information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. SRC shall not be responsible for any damage or
injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any hazards
inherent in the nature of the material
Application
Fuel for diesel engines or heating/boiler plant
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Complex mixture of mainly middle distillate hydrocarbons in the C10-C30 range. The resulting fuel can be paraffinic,
naphthenic or aromatic in nature. Performance additives may be added.
DDO may contain trace amounts of residual fuel oil. BDO will typically contain about 20% by volume of residual fuel oil.
Hazardous Components
Hydrogen sulphide (H2S), an extremely toxic and highly flammable gas, and other flammable light hydrocarbon gases
may collect in vapour spaces where product is stored.
Polycyclic aromatic hydrocarbons will be present, some of which have been shown by experimental studies to induce
skin cancer.
Fuels, diesel. EINECS No: 269-822-7, CAS No: 68334-30-5, Xn, R40 Possible risks of irreversible effects, R65
Harmful: may cause lung damage if swallowed, R66 Repeated exposure may cause skin dryness or cracking
(>70%)
Fuel oil, residual. EINECS No: 270-675-6, CAS No: 68476-33-5, T, R45 May cause cancer, R66 Repeated exposure
may cause skin dryness or cracking, R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
May cause cancer, classified as a category 2 carcinogen.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Repeated exposure may cause skin dryness or cracking.
Harmful if swallowed - aspiration hazard.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Medical advice must be obtained urgently if product under high pressure has been injected through the skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
Ash from combustion may contain potentially harmful components such as vanadium and other heavy metal oxides.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
In the event of spillages contact the appropriate authorities.
Any spillage should be regarded as a potential fire risk.
Isolate spillage from all ignition sources including road traffic.
Ensure good ventilation.
Evacuate all non essential personnel from the immediate area.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Recovery of large spillages should be effected by specialist personnel.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Do not siphon product by mouth.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Avoid inhalation of dust from combustion/exhaust spaces.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
mists generated will create a flammability or explosion hazard.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
_________________________________________________________________________________
Conditions to Avoid
Avoid storage at or near flash point.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to
dermatitis.
As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may
eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
Dusts generated during the removal of ash deposits from engine/boiler combustion surfaces or exhaust spaces, will be
harmful if inhaled and may cause nausea and eye, nose and throat irritation. Repeated contact may result in serious
irreversible disorders.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Harmful to aquatic organisms, may cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: 2
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed
waste disposal contractor.
At sea, used or unwanted product should be stored for eventual discharge into port approved waste oil disposal
facilities.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Gas oil, Flammable Liquid Class 3, UN 1202, Item 31(c) Hazard Identification No 30,
EMERGENCY ACTION CODE: 3[Z]
Not classified as hazardous for transport ( UN , IMO, IATA/ICAO).
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Carcinogenic category 2
Harmful
EU Labelling
Symbol:
Skull and crossbones
Indication of danger:
None
Contains:
Fuels, Diesel
Heavy fuel oil
Risk ( R ) Phrases:
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking
Safety ( S ) Phrases:
S24 Avoid contact with skin
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
02/11/98 1, 2, 8, 12, 15
17/07/2000 2, 3, 4, 7, 8, 12, 14, 15
Application
Fuel for diesel engines or heating/boiler plant
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Cracked components containing polycyclic aromatic hydrocarbon compounds may be present.
Fuels, diesel. EINECS No: 269-822-7, CAS No: 68334-30-5, Xn, R40 Possible risks of irreversible effects, R65
Harmful: may cause lung damage if swallowed, R66 Repeated exposure may cause skin dryness or cracking
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Harmful if swallowed - aspiration hazard.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Repeated exposure may cause skin dryness or cracking.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage, remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable
atmosphere is present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
mists generated will create a flammability or explosion hazard.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to
dermatitis.
As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may
eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
This material may accumulate in sediments.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Harmful to aquatic organisms, may cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
EU Labelling
Symbol:
St. Andrew's Cross
Indication of danger:
HARMFUL
Contains:
Fuels, Diesel
Risk ( R ) Phrases:
R40 Possible risks of irreversible effects
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking
Safety ( S ) Phrases:
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
02/11/98 1, 2, 12, 15
17/07/2000 2, 3, 4, 9, 12, 14, 15
Application
Fuel for industrial, marine and commercial boilers and furnaces; fuel for low and medium speed diesel engines.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Hydrogen sulphide (H2S), an extremely toxic and highly flammable gas, and other flammable light hydrocarbon gases
may collect in vapour spaces where product is stored.
Polycyclic aromatic hydrocarbons will be present, some of which have been shown by experimental studies to induce
skin cancer.
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Contact with hot product may cause burns.
May cause cancer, classified as a category 2 carcinogen.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Repeated exposure may cause skin dryness or cracking.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
If hot material enters the eye, flood immediately with cold water to dissipate the heat, if possible, ensuring eyelids are
held open. Take the casualty to hospital for examination and treatment without delay.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
If hot product causes burns, the affected area should be flooded immediately with, or immersed in cold water for 10
minutes, or longer if pain persists. Burns should be covered with clean cotton or gauze, and the casualty taken to
hospital as soon as possible for examination and treatment.
Never use gasoline, kerosine or other solvents to remove fuel oil from skin or clothing.
Medical advice must be obtained urgently if product under high pressure has been injected through the skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
If ingested, do not induce vomiting.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Ensure good ventilation.
Evacuate all non essential personnel from the immediate area.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Depending upon its temperature the product may be liquid, semi-solid or solid.
Protect drains from spills and prevent entry of product, since this may result in blockage on cooling. Should blockage
occur, notify the appropriate authority immediately.
Scrape up bulk of solid material and remove liquid with sand or other suitable inert absorbent material. If necessary,
clean the contaminated area using hot water and detergent: absorb the washings - do not wash into drains.
Spilled material may make surfaces slippery.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Spillages of hot product in confined spaces may be especially hazardous because highly toxic hydrogen sulphide gas
may be present. For spillages in such confined spaces the use of approved breathing apparatus by personnel specially
trained in its use may be required.
Vapour may collect in any confined space.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
The product may sink making recovery difficult.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Avoid inhalation of dust from combustion/exhaust spaces.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
mists generated will create a flammability or explosion hazard.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
When handling heated material suitable protective clothing of an appropriate standard should be worn to prevent
thermal burns.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Will cause burns if hot material contacts skin
As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may
eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Ingestion
Unlikely to be swallowed in view of the high handling temperatures.
Inhalation
May be irritating to eyes, nose and throat at high vapour concentrations.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin
cancer. The inhalation of vapour, mists or fumes over long periods may therefore be hazardous.
Dusts generated during the removal of ash deposits from engine/boiler combustion surfaces or exhaust spaces, will be
harmful if inhaled and may cause nausea and eye, nose and throat irritation. Repeated contact may result in serious
irreversible disorders.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
This material may accumulate in sediments.
Aquatic toxicity
Harmful to aquatic organisms, may cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: Light fuel oil 2; Heavy fuel oil 1
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed
waste disposal contractor.
At sea, used or unwanted product should be stored for eventual discharge into port approved waste oil disposal
facilities.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
Not classified as hazardous for transport (ADR, RID, UN , IMO, IATA/ICAO).
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Carcinogenic category 2
Dangerous for the environment
EU Labelling
Symbol:
Skull and crossbones
Indication of danger:
None
Risk ( R ) Phrases:
R45 May cause cancer
R66 Repeated exposure may cause skin dryness or cracking
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Fuel oil, residual, EINECS No: 270-675-6
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
08/05/98 2, 3, 4, 8, 12, 15
02/11/98 1
17/07/2000 3, 8, 11, 15
Ashland(R)
000075
ATI
ATTN: MICHELLE BRIGGS
1 PARK CENTRE PRODUCT:
SUITE 10 INVOICE: REQST
WADSWORTH OH 44281 INVOICE DATE: 09/11/93
TO:
SECTION II - COMPONENTS
IF PRESENT IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN
THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION
Notes:
Specific Gravity
.713 @ 60.00 Deg F (15.55 Deg C)
Percent Volatiles
100.00%
MATERIAL IS HIGHLY VOLATILE AND READILY GIVES OFF VAPORS WHICH MAY TRAVEL
ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY PILOT LIGHTS,
OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC MOTORS, STATIC DISCHARGE,
OR OTHER IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL HANDLING
POINT.
NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE
PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY.
ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS INCLUDING TANK CARS AND
TANK TRUCKS SHOULD BE GROUNDED AND/OR BONDED WHEN MATERIAL IS TRANSFERRED.
SEE SECTION II
EYES - EXPOSURE TO LIQUID OR VAPOR MAY CAUSE MILD EYE IRRITATION. SYMPTOMS
MAY INCLUDE STINGING, TEARING, AND REDNESS.
FIRST AID:
IF ON SKIN: REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND
WATER. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. IF SYMPTOMS PERSIST,
SEEK MEDICAL ATTENTION.
IF SWALLOWED: DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET, AND GET
MEDICAL ATTENTION. ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING
CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.
SMALL SPILL:
SMALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
LARGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND
FEDERAL REGULATIONS.
PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:, NITRILE RUBBER, NATURAL
RUBBER
DEFINITIONS
This definition page is intended for use with Material Safety Data Sheets
supplied by the Ashland Chemical Company. Recipients of these data sheets
should consult the OSHA Safety and Health Standards (29 CFR 1910),
particularly subpart G - Occupational Health and Environmental Control,
and subpart I - Personal Protective Equipment, for general guidance on
control of potential Occupational Health and Safety Hazards.
SECTION I
PRODUCT IDENTIFICATION
DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed.
SECTION II
COMPONENTS
SECTION III
PHYSICAL DATA
SECTION IV
FIRE AND EXPLOSION DATA
criteria.
SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other
sections.
SECTION V
HEALTH HAZARD DATA
SECTION VI
REACTIVITY DATA
SECTION VII
SPILL OR LEAK PROCEDURES
and disposal. Consult federal, state and local regulations for accepted
procedures and any reporting or notification requirements.
SECTION VIII
PROTECTIVE EQUIPMENT TO BE USED
SECTION IX
SPECIAL PRECAUTIONS OR OTHER COMMENTS
ADDITIONAL COMMENTS
Containers should be either reconditioned by CERTIFIED firms or properly
disposed of by APPROVED firms. Disposal of containers should be in
accordance with applicable laws and regulations. "EMPTY" drums should not
be given to individuals. Serious accidents have resulted from the misuse
of "EMPTIED" containers (drums, pails, etc.). Refer to Sections IV and IX.
TRADE NAMES/SYNONYMS:
CRUDE OIL; SOUR CRUDE OIL; ROCK OIL; SENECA OIL; PROCESS STREAM; CONDENSATE;
S-041; CE2; AA3; 1037
COMPONENT: BENZENE
CAS NUMBER: 71-43-2
EC NUMBER (EINECS): 200-753-7
PERCENTAGE: 0-2
EMERGENCY OVERVIEW:
COLOR: brown to black
PHYSICAL FORM: oil
ODOR: petroleum odor
SIGNAL WORD: DANGER!
MAJOR HEALTH HAZARDS: Extremely flammable. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness, and nausea, and may lead to unconsciousness or death. Harmful or
fatal if liquid is aspirated into the lungs. Contains Benzene. Cancer hazard.
Can cause blood disorders. Harmful when absorbed through the skin. Prolonged or
repeated contact can defat the skin and lead to irritation and/or dermatitis.
May release hydrogen sulfide which can be harmful or fatal.
PHYSICAL HAZARDS: Extremely flammable liquid and vapor. Vapor may cause flash
fire.
SKIN CONTACT: Wash exposed skin with soap and water. Remove contaminated
clothing and thoroughly clean and dry before reuse. Get medical attention if
irritation develops.
EYE CONTACT: Flush eyes with plenty of water. Get medical attention if
irritation persists.
FIRE AND EXPLOSION HAZARDS: Severe fire hazard. Vapor/air mixtures are explosive
above flash point. The vapor is heavier than air. Vapors or gases may ignite at
distant ignition sources and flash back.
EXTINGUISHING MEDIA: regular dry chemical, carbon dioxide, water, regular foam
Large fires: Use regular foam or flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. For fires in cargo or storage area: Cool containers with
water from unmanned hose holder or monitor nozzles until well after fire is out.
If this is impossible then take the following precautions: Keep unnecessary
people away, isolate hazard area and deny entry. Let the fire burn. Withdraw
immediately in case of rising sound from venting safety device or any
discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation
radius: 800 meters (1/2 mile). Water may be ineffective. Water or foam may cause
frothing.
FIRE FIGHTING PROTECTIVE EQUIPMENT: Firefighters should wear full bunker gear,
including a positive pressure self contained breathing apparatus.
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible
without personal risk. Reduce vapors with water spray. Small spills: Absorb with
sand or other non-combustible material. Collect spilled material in appropriate
container for disposal. Large spills: Dike for later disposal. Remove sources of
ignition. Keep unnecessary people away, isolate hazard area and deny entry.
Notify Local Emergency Planning Committee and State Emergency Response
Commission for release greater than or equal to RQ (U.S. SARA Section 304). If
release occurs in the U.S. and is reportable under CERCLA Section 103, notify
the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
STORAGE: Avoid heat, flames, sparks and other sources of ignition. Grounding and
bonding required. Keep container tightly closed. Store in a well-ventilated
area.
HANDLING: Keep away from all ignition sources. Keep container tightly closed.
Use only with adequate ventilation. Ground and bond containers when transferring
materials. After this container has been emptied, it may contain product
residue; observe all warnings and precautions listed for this product. SPECIAL
PRECAUTIONS: Empty containers may contain toxic, flammable/combustible or
explosive residue or vapors. Do not cut, grind, drill, weld, reuse or dispose of
containers unless adequate precautions are taken against these hazards. Do not
eat, drink or smoke in areas of use or storage. Use good personal hygiene
practices. Wash hands before eating, drinking, smoking or using toilet
facilities. Remove contaminated clothing and thoroughly clean and dry before
reuse. Wash thoroughly after work using soap and water.
EXPOSURE LIMITS:
PETROLEUM CRUDE OIL-SOUR:
MINERAL OIL MIST:
5 mg/m3 OSHA TWA
5 mg/m3 ACGIH TWA
10 mg/m3 ACGIH STEL
5 mg/m3 MEXICO TWA
10 mg/m3 MEXICO STEL
BENZENE:
1 ppm OSHA TWA
5 ppm OSHA STEL 15 minute(s)
0.5 ppm OSHA action level
0.5 ppm ACGIH TWA (skin)
2.5 ppm ACGIH STEL (skin)
10 ppm (30 mg/m3) MEXICO TWA
25 ppm (75 mg/m3) MEXICO STEL
HYDROGEN SULFIDE:
20 ppm OSHA ceiling
50 ppm OSHA peak 10 minute(s) (once if no other measurable exposure occurs)
10 ppm (14 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30, 1993)
15 ppm (21 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30, 1993)
10 ppm ACGIH TWA
15 ppm ACGIH STEL
10 ppm (14 mg/m3) MEXICO TWA
15 ppm (21 mg/m3) MEXICO STEL
EYE PROTECTION: None required; however, use of eye protection is good industrial
practice.
RESPIRATOR: Use with adequate ventilation. Avoid breathing vapor and/or mist. If
ventilation is inadequate, use a NIOSH certified respirator with an organic
vapor cartridge and P95 particulate filter.
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition.
Containers may rupture or explode if exposed to heat. Keep out of water supplies
and sewers. Dangerous gases may accumulate in confined spaces.
HAZARDOUS DECOMPOSITION:
Thermal decomposition products or combustion: hydrocarbons, hydrogen sulfide,
oxides of carbon, oxides of sulfur
SKIN: Repeated or prolonged contact may result in defatting, oil acne, redness,
itching, inflammation, cracking and possible secondary infections.
Hydrogen sulfide (H2S) gas may accumulate in storage tanks of bulk transport
compartments containing this material. Contact with eyes causes painful
Aspiration of this product into the lungs can cause chemical pneumonia and can
be fatal. Aspiration into the lungs can occur while vomiting after ingestion of
this product.
Crude oils contain small, variable amounts of Benzene. Acute toxicity of benzene
results primarily from depression of the central nervous system (CNS).
Inhalation of concentrations over 50 ppm can produce headache,
lassitude,weariness, dizziness, drowsiness, or excitation. Exposure to very high
levels can result in unconsciousness and death. Long-term overexposure to
benzene has been associated with certain types of leukemia in humans. In
addition, the International Agency for Research on Cancer (IARC), the National
Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic
exposures to benzene at levels of 100 ppm and below have been reported to cause
adverse blood effects including anemia. Benzene exposure can occur by inhalation
and absorption through the skin. Inhalation and forced feeding studies of
benzene in laboratory animals have produced a carcinogenic response in a variety
of organs, including possibly leukemia, other adverse effects on the
blood,chromosomal changes and some effects on the immune system. Exposure to
benzene at levels up to 300 ppm did not produce birth defects in animal studies;
however, exposure to the higher dosage levels (greater than 100 ppm) resulted in
a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes
have been observed in mice exposed to benzene at 300 ppm, but reproductive
performance was not altered in rats exposed to benzene at the same level.
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR Part 302.4): This product
is reportable under 40 CFR Part 302.4 because it contains the following
substance(s):
HYDROGEN SULFIDE: 100 LBS RQ
Benzene: 10 LBS RQ
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR Part 355):
HYDROGEN SULFIDE: 500 LBS TPQ
SARA TITLE III SECTION 311/312 HAZARDOUS CATEGORIZATION (40 CFR Part 370):
ACUTE: Y
CHRONIC: Y
FIRE: Y
REACTIVE: N
SUDDEN RELEASE: N
SARA TITLE III SECTION 313 (40 CFR Part 372): This product contains the
following substance(s), which is on the Toxic Chemicals List in 40 CFR Part 372:
HYDROGEN SULFIDE
Benzene
STATE REGULATIONS:
California Proposition 65: Y
Known to the state of California to cause the following:
Benzene
Cancer (Feb 27, 1987)
Developmental toxicity (Dec 26, 1997)
Male reproductive toxicity (Dec 26, 1997)
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
NOTICE: The information presented herein is based on data considered to be
accurate as of the date of preparation of this Material Safety Data Sheet.
However, no warranty or representation, express or implied, is made as to the
accuracy or completeness of the foregoing data and safety information, nor is
any authorization given or implied to practice any patented invention without a
license. In addition, no responsibility can be assumed by vendor for any damage
or injury resulting from abnormal use, from any failure to adhere to recommended
practices, or from any hazards inherent in the nature of the product.
Application
Fuel blending component
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
_________________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
Complex hydrocarbon substance, one of the following:
Gas oils (petroleum), straight-run. EINECS No: 265-043-1, CAS No: 64741-43-1
Gas oils (petroleum), light vacuum, EINECS No: 265-059-9, CAS No: 64741-58-8
3. HAZARDS IDENTIFICATION
Harmful if swallowed - aspiration hazard.
Repeated exposure may cause skin dryness or cracking.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage, remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable
atmosphere is present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when
no alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved
type and following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see
the comments in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
mists generated will create a flammability or explosion hazard.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to
dermatitis.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
This material may accumulate in sediments.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed
waste disposal contractor.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Gas oil, Flammable Liquid Class 3, Item 31(c) Hazard Identification No 30
UN: GAS OIL, Flammable liquid, Class 3, Packing Group III, UN Number 1202
IATA/ICAO: Gas oil, Flammable liquid, Class 3, Packing group III
IMO: GAS OIL, Flammable liquid, Class 3.3, Packing group III
EMERGENCY ACTION CODE: 3[Z]
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Harmful
Dangerous for the environment
EU Labelling
Symbol:
St. Andrew's Cross
Dead tree and fish
Indication of danger:
HARMFUL
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S24 Avoid contact with skin
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
TRADE NAMES/SYNONYMS:
CRUDE OIL; SWEET CRUDE OIL; ROCK OIL; SENECA OIL; PROCESS STREAM; CONDENSATE;
S-041; CE2; AA3; 1037
COMPONENT: BENZENE
CAS NUMBER: 71-43-2
EC NUMBER (EINECS): 200-753-7
PERCENTAGE: 0-2
EMERGENCY OVERVIEW:
COLOR: brown to black
PHYSICAL FORM: oil
ODOR: petroleum odor
SIGNAL WORD: DANGER!
MAJOR HEALTH HAZARDS: Extremely flammable. Inhalation of vapor/aerosol
concentrations above the recommended exposure limits causes headaches,
drowsiness, and nausea, and may lead to unconsciousness or death. Harmful or
fatal if liquid is aspirated into the lungs. Prolonged or repeated contact can
defat the skin and lead to irritation and/or dermatitis. Contains Benzene.
Cancer hazard. Can cause blood disorders. Harmful when absorbed through the
skin. May release hydrogen sulfide which can be harmful or fatal.
PHYSICAL HAZARDS: Extremely flammable liquid and vapor. Vapor may cause flash
fire.
SKIN CONTACT: Wash exposed skin with soap and water. Remove contaminated
clothing and thoroughly clean and dry before reuse. Get medical attention if
irritation develops.
EYE CONTACT: Flush eyes with plenty of water. Get medical attention if
irritation persists.
FIRE AND EXPLOSION HAZARDS: Severe fire hazard. Vapor/air mixtures are explosive
above flash point. The vapor is heavier than air. Vapors or gases may ignite at
distant ignition sources and flash back.
EXTINGUISHING MEDIA: regular dry chemical, carbon dioxide, water, regular foam
Large fires: Use regular foam or flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk.
Cool containers with water spray until well after the fire is out. Stay away
from the ends of tanks. For fires in cargo or storage area: Cool containers with
water from unmanned hose holder or monitor nozzles until well after fire is out.
If this is impossible then take the following precautions: Keep unnecessary
people away, isolate hazard area and deny entry. Let the fire burn. Withdraw
immediately in case of rising sound from venting safety device or any
discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation
radius: 800 meters (1/2 mile). Water may be ineffective. Water or foam may cause
frothing.
FIRE FIGHTING PROTECTIVE EQUIPMENT: Firefighters should wear full bunker gear,
including a positive pressure self contained breathing apparatus.
Avoid heat, flames, sparks and other sources of ignition. Stop leak if possible
without personal risk. Reduce vapors with water spray. Small spills: Absorb with
sand or other non-combustible material. Collect spilled material in appropriate
container for disposal. Large spills: Dike for later disposal. Remove sources of
ignition. Keep unnecessary people away, isolate hazard area and deny entry.
Notify Local Emergency Planning Committee and State Emergency Response
Commission for release greater than or equal to RQ (U.S. SARA Section 304). If
release occurs in the U.S. and is reportable under CERCLA Section 103, notify
the National Response Center at (800)424-8802 (USA) or (202)426-2675 (USA).
STORAGE: Avoid heat, flames, sparks and other sources of ignition. Grounding and
bonding required. Keep container tightly closed. Store in a well-ventilated
area.
HANDLING: Keep away from all ignition sources. Keep container tightly closed.
Use only with adequate ventilation. Ground and bond containers when transferring
materials. After this container has been emptied, it may contain product
residue; observe all warnings and precautions listed for this product. SPECIAL
PRECAUTIONS: Empty containers may contain toxic, flammable/combustible or
explosive residue or vapors. Do not cut, grind, drill, weld, reuse or dispose of
containers unless adequate precautions are taken against these hazards. Do not
eat, drink or smoke in areas of use or storage. Use good personal hygiene
practices. Wash hands before eating, drinking, smoking or using toilet
facilities. Remove contaminated clothing and thoroughly clean and dry before
reuse. Wash thoroughly after work using soap and water.
EXPOSURE LIMITS:
BENZENE:
1 ppm OSHA TWA
5 ppm OSHA STEL 15 minute(s)
0.5 ppm OSHA action level
0.5 ppm ACGIH TWA (skin)
2.5 ppm ACGIH STEL (skin)
10 ppm (30 mg/m3) MEXICO TWA
25 ppm (75 mg/m3) MEXICO STEL
HYDROGEN SULFIDE:
20 ppm OSHA ceiling
50 ppm OSHA peak 10 minute(s) (once if no other measurable exposure occurs)
10 ppm (14 mg/m3) OSHA TWA (vacated by 58 FR 35338, June 30, 1993)
15 ppm (21 mg/m3) OSHA STEL (vacated by 58 FR 35338, June 30, 1993)
10 ppm ACGIH TWA
15 ppm ACGIH STEL
10 ppm (14 mg/m3) MEXICO TWA
15 ppm (21 mg/m3) MEXICO STEL
EYE PROTECTION: None required; however, use of eye protection is good industrial
practice.
RESPIRATOR: Use with adequate ventilation. Avoid breathing vapor and/or mist. If
ventilation is inadequate, use a NIOSH certified respirator with an organic
vapor cartridge and P95 particulate filter.
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition.
Containers may rupture or explode if exposed to heat. Keep out of water supplies
and sewers. Dangerous gases may accumulate in confined spaces.
HAZARDOUS DECOMPOSITION:
Thermal decomposition products or combustion: hydrocarbons, hydrogen sulfide,
oxides of carbon, oxides of sulfur
SKIN: Repeated or prolonged contact may result in defatting, oil acne, redness,
itching, inflammation, cracking and possible secondary infections.
Hydrogen sulfide (H2S) gas may accumulate in storage tanks of bulk transport
compartments containing this material. Contact with eyes causes painful
conjunctivitis, sensitivity to light, tearing and clouding of vision. Inhalation
of low concentrations causes a runny nose with a loss of sense of smell, labored
breathing and shortness of breath. Direct contact with skin causes pain and
redness. Other symptoms of exposure include profuse salivation, nausea,
vomiting, diarrhea, giddiness, headache, dizziness, confusion, rapid breathing,
rapid heart rate, sweating, weakness, sudden collapse, unconsciousness and death
due to respiratory paralysis.Cardiac neurological effects have also been
reported. Prolonged breathing (greater than one hour) of concentrations of H2S
around 50 ppm can produce eye and respiratory tract irritation. Levels of 250 to
600 ppm will result in fluid in the lungs, and concentrations around 1,000 ppm
will cause unconsciousness and death in a short period oftime. Since the sense
of smell rapidly becomes insensitive to this toxic, colorless gas, odor cannot
be relied upon as an indicator of concentrations of the gas. Always exercise
caution when working around closed containers.
Aspiration of this product into the lungs can cause chemical pneumonia and can
be fatal. Aspiration into the lungs can occur while vomiting after ingestion of
this product.
Crude oils contain small, variable amounts of Benzene. Acute toxicity of benzene
results primarily from depression of the central nervous system (CNS).
Inhalation of concentrations over 50 ppm can produce headache,
lassitude,weariness, dizziness, drowsiness, or excitation. Exposure to very high
levels can result in unconsciousness and death. Long-term overexposure to
benzene has been associated with certain types of leukemia in humans. In
addition, the International Agency for Research on Cancer (IARC), the National
Toxicology Program, and OSHA consider benzene to be a human carcinogen. Chronic
exposures to benzene at levels of 100 ppm and below have been reported to cause
adverse blood effects including anemia. Benzene exposure can occur by inhalation
and absorption through the skin. Inhalation and forced feeding studies of
benzene in laboratory animals have produced a carcinogenic response in a variety
of organs, including possibly leukemia, other adverse effects on the
blood,chromosomal changes and some effects on the immune system. Exposure to
benzene at levels up to 300 ppm did not produce birth defects in animal studies;
however, exposure to the higher dosage levels (greater than 100 ppm) resulted in
a reduction of body weight of the rat pups (fetotoxicity). Changes in the testes
have been observed in mice exposed to benzene at 300 ppm, but reproductive
performance was not altered in rats exposed to benzene at the same level.
II
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR Part 302.4): This product
is reportable under 40 CFR Part 302.4 because it contains the following
substance(s):
HYDROGEN SULFIDE: 100 LBS RQ
Benzene: 10 LBS RQ
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR Part 355):
HYDROGEN SULFIDE: 500 LBS TPQ
SARA TITLE III SECTION 311/312 HAZARDOUS CATEGORIZATION (40 CFR Part 370):
ACUTE: Y
CHRONIC: Y
FIRE: Y
REACTIVE: N
SUDDEN RELEASE: N
SARA TITLE III SECTION 313 (40 CFR Part 372): This product contains the
following substance(s), which is on the Toxic Chemicals List in 40 CFR Part 372:
HYDROGEN SULFIDE
Benzene
STATE REGULATIONS:
California Proposition 65: Y
Known to the state of California to cause the following:
Benzene
Cancer (Feb 27, 1987)
Developmental toxicity (Dec 26, 1997)
Male reproductive toxicity (Dec 26, 1997)
TThis Material Safety Data Sheet conforms to the requirements of ANSI Z400.1.
NOTICE: The information presented herein is based on data considered to be
accurate as of the date of preparation of this Material Safety Data Sheet.
However, no warranty or representation, express or implied, is made as to the
accuracy or completeness of the foregoing data and safety information, nor is
any authorization given or implied to practice any patented invention without a
license. In addition, no responsibility can be assumed by vendor for any damage
or injury resulting from abnormal use, from any failure to adhere to recommended
practices, or from any hazards inherent in the nature of the product.
CITGO
Health: Cancer suspect agent. Similar products have been shown to cause
cancer in laboratory animals.
HMIS Rating(1):
Health 0
Flammability 1
Reactivity 0
NA - Not Applicable
ND - No Data
NE - Not Established
Boiling Point, 760 mmHg, Deg. C (Deg. F): > 249 (> 480) (Wide Range)
pH of Undiluted Product: NA
Molecular Wt.: ND
NFPA Rating(2)
Health: 0
Flammability: 1
Reactivity: 0
Flammability Class
IIIB
Extinguishing Media
CO2, dry chemical, foam
Stability: Stable
* Large spills: Control spill in earthen dikes for later recovery. Control
ignition sources around spill area.
Waste Disposal:
No Carcinogen
No Corrosive
Yes Animal Carcinogen*
No Irritant
No Suspect Carcinogen
No Sensitizer
No Mutagen
No Teratogen
No Highly Toxic
No Target Organ
No Toxic
Dermal Contact: The dermal toxicity of this product has not been
determined. However, based upon the toxicology of similar products this
Eye Contact: The eye irritation potential of this product has not been
determined. However, based upon the toxicology of similar products this
product is not expected to cause prolonged or significant eye irritation.
Ingestion: The oral toxicity of this product has not been determined.
However, based on the toxicology of similar products, this product may be
slightly toxic to internal organs if swallowed. The severity of injury
will depend upon the amount absorbed from the gut. Typical signs and
symptoms from ingestion include gastro-intestinal disturbances, vomiting
and diarrhea, headache, and tiredness. This product may present a moderate
aspiration hazard.
Injection: NA
Eye Contact: Wash the eyes with large amounts of water for 15 minutes,
occasionally lifting upper and lower eyelids. Remove contact lenses if
worn. If irritation persists, seek medical advice.
Storage:
DOT Information
Product Name
Vacuum Gas Oil
This product does not contain toxic chemicals of Section 313 of Title III,
Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR
Part 372.
Components CAS # %
None NA NA
None - - - -
NA - - -
Petroleum and petroleum fractions are excluded from the list of CERCLA
hazardous substances by Section 101(14) of CERCLA.
Federal Regulations
CALIFORNIA Proposition 65
Tradename: Vacuum Gas Oil
Contains components that occur on lists of:
Carcinogenic Materials [ ] Yes [X] No
Teratogenic Materials [ ] Yes [X] No
10.0 Labeling
Vacuum Residue
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Vacuum Residue
Application
Refinery stream
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
3. HAZARDS IDENTIFICATION
This product can be delivered, stored and used at temperatures above 100°C.
Contact with hot product may cause burns.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Cold product - Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical
advice if any pain or redness develops or persists.
Hot product - Flood with water to dissipate heat. In the event of any product remaining, do not try to remove it other
than by continued irrigation with water. Obtain medical attention immediately.
Skin
Cold Product - Wash contaminated skin with soap and water. Remove contaminated clothing and wash underlying skin
as soon as reasonably practicable.
Hot Product - Flood skin with cold water to dissipate heat, cover with clean cotton or gauze, obtain medical advice
immediately.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Where skin burns occur the area should be immediately immersed in cold water until the bitumen is thoroughly cooled.
Do not attempt to remove the bitumen from the skin as it provides an airtight sterile covering over the burn which will
eventually fall away with the scab as the burn heals. If for any reason the bitumen must be removed, this can be done
using a slightly warmed medicinal liquid paraffin. Kerosene and other solvents should never be used. All burns should
receive medical attention. It should be noted that bitumen contracts on cooling and where a limb is encased care
should be taken to avoid the development of a tourniquet effect.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Water may be used to cool nearby heat exposed areas/objects/packages. Avoid spraying directly into storage
containers because of the danger of boil-over.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Depending upon its temperature the product may be liquid, semi-solid or solid.
Protect drains from spills and prevent entry of product, since this may result in blockage on cooling. Should blockage
occur, notify the appropriate authority immediately.
Scrape up bulk of material and remove remainder with sand or other suitable inert absorbent material.
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable
atmosphere is present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
The product may sink making recovery difficult.
In the case of large spills contact the appropriate authorities.
_________________________________________________________________________________
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Product should not be over heated in storage because of the risk of fire.
Storage Conditions
Store under cover away from moisture and sources of ignition. Do not overheat in storage.
Under no circumstances should water be allowed to contact hot product because of the danger of boil-over. Particular
care should be taken to ensure that bulk storage tanks are watertight and that any steam heating coils are regularly
checked for leaks.
For bulk product, the storage temperature should not fluctuate above and below 100 deg C as this increases the risk of
water condensation leading to boil-over. Care must always be exercised when heating product through 100 deg C.
Highly toxic hydrogen sulphide gas may be emitted from hot product and accumulate in enclosed spaces or tanks.
Extreme care must therefore be taken during venting of tanks and enclosed spaces which have at any time contained
hot product. Under no circumstances should entry be made into small enclosures without taking full precautions.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when
no alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved
type and following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see
the comments in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Pyrophoric (self-heating) deposits, which may cause fire or explosion, may be formed in storage. Avoid exposure of
tank vapour space to fresh air, and maintain stable storage temperatures. Regular inspection for such deposits will
indicate when tank cleaning is necessary.
_________________________________________________________________________________
Protective Clothing
When handling hot product, suitable protective clothing of an appropriate standard should be worn. Depending on the
type of operation this may include:
- Visor to protect the face and head covering with neck flap.
- Gauntlets (heat resistant and impervious to bitumen)
- Overalls, impervious to bitumen, covering full body and limbs with legs worn over boots.
- Protective boots.
Protective clothing should be regularly dry cleaned. Change heavily contaminated clothing as soon as reasonably
practicable; dry clean, launder and preferably starch before re-use. Wash any contaminated underlying skin with soap
and water.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Will cause burns if hot material contacts skin
When product is heated to high temperatures, vapour, mists or fumes will be given off and may condense,
contaminating the skin or clothing of operatives. Prolonged or repeated contact with this condensate may give rise to
dermatitis or other skin conditions of a serious or irreversible nature.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Inhalation
At normal ambient temperatures this product will be unlikely to present an inhalation hazard because of its low
volatility.
Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of which are known to produce skin
cancer. The inhalation of vapour, mists or fumes over long periods may therefore be hazardous.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages are unlikely to penetrate the soil.
Bioaccumulative potential
This material is not expected to bioaccumulate.
Aquatic toxicity
Unlikely to cause long term effects in the aquatic environment.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Where possible, arrange for product to be recycled.
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed
waste disposal contractor.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
COLD - Not classified as hazardous for transport (ADR, RID, UN, IATA/ICAO).
Note
Under ADR emptied uncleaned tankers are classified as follows : Emptied container class 9, item 71 ADR Latest cargo
3257 Liquid elevated temperature NOS, item 20(c).
_________________________________________________________________________________
15. REGULATORY INFORMATION
Not classified as hazardous for supply.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
02/09/98 1, 6, 7, 8
17/07/2000 1, 4, 8
BP Butane
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING
Identification of substance/preparation
BP Commercial Butane, BP Butane Export Quality
Application
Multi-purpose product with applications including gaseous fuel for domestic, commercial and industrial uses; internal
combustion engine fuel; aerosol propellant; Chemical feedstock.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil UK Limited,
Witan Gate House
500-600 Witan Gate
Central Milton Keynes
MK9 1ES
Hazardous Components
Hydrocarbon, C3-4-rich, petroleum distillate. EINECS No: 270-990-9, CAS No: 68512-91-4, F+, R12 Extremely
flammable (>90%)
__________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Abuse involving wilful inhalation of very high concentrations of vapour, even for short periods, can produce
unconsciousness or might prove fatal.
__________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water. Obtain IMMEDIATE medical attention.
Skin
If cold burns are present drench with water and obtain immediate medical advice.
Keep contaminated clothes away from ignition sources.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat,
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
These materials are delivered, stored and used at temperatures above their flash point. Avoid all naked flames, sparks,
cigarettes, etc.
IN CASE OF FIRE, IMMEDIATELY ALERT THE FIRE BRIGADE.
Ensure an escape path is always available from any fire.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
If gas has ignited, do not attempt to extinguish but stop gas flow and allow to burn out. Use water spray to cool heat-
exposed containers, and to protect surrounding areas and personnel effecting shut-off.
Every precaution must be taken to keep containers cool to avoid the possibility of a boiling liquid expanding vapour
explosion (BLEVE).
Pressurised containers are liable to explode violently when subjected to high temperatures.
Combustion Products
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
If a leak has not ignited, stop gas flow, isolate sources of ignition and evacuate personnel.
Ensure good ventilation.
Liquid leaks generate large volumes of flammable vapour, heavier than air, which may travel to remote sources of ignition
(eg. along drainage systems).
Where appropriate, use water spray to disperse the gas or vapour and to protect personnel attempting to stop leakage.
Vapour may collect in any confined space.
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable atmosphere is
present before entry.
Do not enter a vapour cloud except for rescue; self-contained breathing apparatus must be worn.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
In the event of a leak, contact the appropriate authorities.
Small quantities of spilled liquid may be allowed to evaporate. Vapour should be dispersed by effective ventilation.
__________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and use only in equipment/containers designed for use with this product.
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Do not enter storage tanks. If entry to tanks is necessary, contact the supplier.
Containers must be properly labelled.
Do not remove warning labels from containers.
Handling Precautions
Ensure good ventilation.
Avoid inhalation of vapour.
Avoid contact with liquid and cold storage containers.
When handling cylinders wear protective footwear and suitable gloves.
Avoid contact with the eyes.
Fire Prevention
Ensure equipment is electrically bonded and earthed to prevent static accumulation.
Explosive air/vapour mixtures may form at ambient temperature.
Note: Product spilt on clothing may give rise to delayed evaporation and subsequent fire hazard.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
Comply with current local occupational exposure limit. Where not established, the following limits are recommended.
Butane
UK publication EH40 (Occupational Exposure Limits):
Occupational Exposure Standard: Long-term exposure limit (8hr TWA) 600ppm, 1450 mg/m3
Short-term exposure limit (15 min) 750ppm, 1810mg/m3
Protective Clothing
Wear suitable gloves and overalls to prevent cold burns and frostbite.
In filling operations wear protective clothing including impervious gloves, safety goggles or face shield.
When handling cylinders wear protective footwear.
Respiratory Protection
If operations are such that significant exposure to vapour, mist or fume may be anticipated, then suitable approved
respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
__________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Note: National specifications may apply.
Typical Values
Grades:BP Butane UK
Test Method Units
Physical state gas
Colour colourless
Odour Distinctive when stenched
Density @ 15°C ASTM D 1657 kg/m3 580
Gauge vapour pressure 40°C BS3324 kPa <505
Vapour density rel. to air ASTM 1.9 -
D2463/D2421 2.1
Flammability Limits % 1.9 -
9.0
Flash point (PMC) ASTM D 93 °C <-50
Boiling point/range ASTM D 86 °C <-2
10. STABILITY AND REACTIVITY
Stable at ambient temperatures.
Hazardous polymerisation reactions will not occur.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Will cause cold burns and frostbite if skin contact with liquid occurs.
Inhalation
Low vapour concentrations may cause nausea, dizziness, headaches and drowsiness.
May have a narcotic effect if high concentrations of vapour are inhaled.
High vapour concentrations may produce symptoms of oxygen deficiency which, coupled with central nervous system
depression, may lead to rapid loss of consciousness.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very high
concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
__________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages are unlikely to penetrate the soil.
Bioaccumulative potential
This material is not expected to bioaccumulate.
Aquatic toxicity
Unlikely to cause long term effects in the aquatic environment.
__________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Do not dispose of any LPG container. Return all cylinders/vessels to your supplier.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty
packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld, solder
or braze empty containers.
__________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Butane, Flammable gases, Class 2, Item 2°F, Hazard Identification Number 23.
UN: Butane, Flammable Gases, Class 2.1, UN Number 1011
IATA/ICAO: Butane, Flammable gas, Class 2.1. Forbidden for transport on passenger aircraft.
IMO: Butane, Flammable gas, Class 2.1.
Emergency Action Code: Flammable gas, 2WE
__________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
EU Labelling
Symbol: Flame
Indication of danger: EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
R12 Extremely flammable
Safety ( S ) Phrases:
S2 Keep out of reach of children
S3/9 Keep in a cool, well ventilated place.
S16 Keep away from sources of ignition - No smoking
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
hazards inherent in the nature of the material.
BP Propane
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING
Identification of substance/preparation
BP Commercial Propane, BP Premium Propane, BP Propane Export Quality
Application
Multi-purpose product with applications including gaseous fuel for domestic, commercial and industrial uses; internal
combustion engine fuel; aerosol propellant; Chemical feedstock.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil UK Limited,
Witan Gate House
500-600 Witan Gate
Central Milton Keynes
MK9 1ES
Hazardous Components
Hydrocarbon, C3-4-rich, petroleum distillate. EINECS No: 270-990-9, CAS No: 68512-91-4, F+, R12 Extremely
flammable (>90%)
__________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Abuse involving wilful inhalation of very high concentrations of vapour, even for short periods, can produce
unconsciousness or might prove fatal.
__________________________________________________________________________________
4. FIRST-AID MEASURES
file:///C|/Documents%20and%20Settings/lanewg/...ATA/QA%20Amendments/MSDS/Gas/BP%20Propane.htm (1 of 6) [29/01/2002 08:47:17]
Sheet No: SUK2107 Date: 09/01/98 Revision of Sheet Dated: 01/09/94 (FLPR01) Name of Product: BP Propane
Eyes
Wash eye thoroughly with copious quantities of water. Obtain IMMEDIATE medical attention.
Skin
If cold burns are present drench with water and obtain immediate medical advice.
Keep contaminated clothes away from ignition sources.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat,
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
These materials are delivered, stored and used at temperatures above their flash point. Avoid all naked flames, sparks,
cigarettes, etc.
IN CASE OF FIRE, IMMEDIATELY ALERT THE FIRE BRIGADE.
Ensure an escape path is always available from any fire.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
If gas has ignited, do not attempt to extinguish but stop gas flow and allow to burn out. Use water spray to cool heat-
exposed containers, and to protect surrounding areas and personnel effecting shut-off.
Every precaution must be taken to keep containers cool to avoid the possibility of a boiling liquid expanding vapour
explosion (BLEVE).
Pressurised containers are liable to explode violently when subjected to high temperatures.
Combustion Products
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
If a leak has not ignited, stop gas flow, isolate sources of ignition and evacuate personnel.
Ensure good ventilation.
Liquid leaks generate large volumes of flammable vapour, heavier than air, which may travel to remote sources of ignition
(eg. along drainage systems).
Where appropriate, use water spray to disperse the gas or vapour and to protect personnel attempting to stop leakage.
Vapour may collect in any confined space.
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable atmosphere is
present before entry.
Do not enter a vapour cloud except for rescue; self-contained breathing apparatus must be worn.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
In the event of a leak, contact the appropriate authorities.
Small quantities of spilled liquid may be allowed to evaporate. Vapour should be dispersed by effective ventilation.
__________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and use only in equipment/containers designed for use with this product.
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Do not enter storage tanks. If entry to tanks is necessary, contact the supplier.
Containers must be properly labelled.
Do not remove warning labels from containers.
Handling Precautions
Ensure good ventilation.
Avoid inhalation of vapour.
Avoid contact with liquid and cold storage containers.
When handling cylinders wear protective footwear and suitable gloves.
Avoid contact with the eyes.
Fire Prevention
Ensure equipment is electrically bonded and earthed to prevent static accumulation.
Explosive air/vapour mixtures may form at ambient temperature.
Note: Product spilt on clothing may give rise to delayed evaporation and subsequent fire hazard.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
Comply with current local occupational exposure limit. Where not established, the following limits are recommended.
Propane
UK publication EH40 (Occupational Exposure Limits):
Simple asphyxiant.
Protective Clothing
Wear suitable gloves and overalls to prevent cold burns and frostbite.
In filling operations wear protective clothing including impervious gloves, safety goggles or face shield.
When handling cylinders wear protective footwear.
Respiratory Protection
If operations are such that significant exposure to vapour, mist or fume may be anticipated, then suitable approved
respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
__________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Note: National specifications may apply.
Typical Values
Grades:BP Propane
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Will cause cold burns and frostbite if skin contact with liquid occurs.
Inhalation
Low vapour concentrations may cause nausea, dizziness, headaches and drowsiness.
May have a narcotic effect if high concentrations of vapour are inhaled.
High vapour concentrations may produce symptoms of oxygen deficiency which, coupled with central nervous system
depression, may lead to rapid loss of consciousness.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very high
concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
__________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages are unlikely to penetrate the soil.
Bioaccumulative potential
Aquatic toxicity
Unlikely to cause long term effects in the aquatic environment.
__________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Do not dispose of any LPG container. Return all cylinders/vessels to your supplier.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty
packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld, solder
or braze empty containers.
__________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Propane, Flammable gases, Class 2, Item 2°F, Hazard Identification Number 23.
UN: Propane, Flammable Gases, Class 2.1, UN Number 1978
IATA/ICAO: Propane, Flammable gas, Class 2.1. Forbidden for transport on passenger aircraft.
IMO: Propane, Flammable gas, Class 2.1.
Emergency Action Code: Flammable gas, 2WE
__________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
EU Labelling
Symbol: Flame
Indication of danger: EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
R12 Extremely flammable
Safety ( S ) Phrases:
S2 Keep out of reach of children
S3/9 Keep in a cool, well ventilated place.
S16 Keep away from sources of ignition - No smoking
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
hazards inherent in the nature of the material.
Natural Gas
Application
Refinery stream
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil UK Ltd, Coryton Refinery, The Manorway, Stanford-le-Hope, Essex SS17 9LL
BP Oil Grangemouth Refinery Ltd, Bo'Ness Road, Grangemouth, Stirlingshire FK3 9XQ
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat,
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air and
medical assistance obtained without delay.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be delayed
for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and consider
administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema develops.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
These materials are delivered, stored and used at temperatures above their flash point. Avoid all naked flames, sparks,
cigarettes, etc.
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
FIRES IN CONFINED SPACES SHOULD BE DEALT WITH BY TRAINED PERSONNEL WEARING APPROVED
BREATHING APPARATUS.
If gas has ignited, do not attempt to extinguish but stop gas flow and allow to burn out. Use water spray to cool heat-
exposed containers, and to protect surrounding areas and personnel effecting shut-off.
Combustion Products
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Ensure good ventilation.
Vapour may collect in any confined space.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
In the event of a leak, contact the appropriate authorities.
If a leak has not ignited, stop gas flow, isolate sources of ignition and evacuate personnel.
In confined or poorly ventilated spaces the use of self-contained breathing apparatus may be necessary. See Exposure
Controls/ Personal Protection, Section 8 of this Safety Data Sheet.
Evacuate all non essential personnel from the immediate area.
Explosive air/vapour mixtures can occur, particularly in unventilated or confined spaces.
_________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and use only in equipment/containers designed for use with this product.
Do not enter storage tanks. If entry to tanks is necessary, contact the supplier.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when no
alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved type and
following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see the comments
in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Handling Precautions
Ensure good ventilation.
Fire Prevention
Ensure equipment is electrically bonded and earthed to prevent static accumulation.
Explosive air/vapour mixtures may form at ambient temperature.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
There is no appropriate occupational exposure limit for this material.
Comply with current local occupational exposure limit. Where not established, the following limits are recommended.
Methane / Ethane
UK publication EH40 (Occupational Exposure Standard):
Simple asphyxiant.
Hydrogen Sulphide
UK publication EH40 (Occupational Exposure Limits):
Occupational Exposure Standard: Long-term exposure limit (8hr TWA) 10 ppm, 14 mg/m3
Short-term exposure limit (15 min) 15ppm, 21 mg/m3
Respiratory Protection
Respiratory protection is unnecessary, provided the concentration of vapour, mists or fumes is adequately controlled.
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators may
unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-supplied
breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas
__________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Typical Values
Grades:Natural Gas
Test Method Units
Physical state gas
Colour colourless
Odour odourless -> pungent
Boiling point/range °C -161.5
Vapour density rel. to air ASTM 0.6
D2463/D2421
Flash point °C -187.8
Explosion limits % 15/5.3
Solubility in water g/l Slight
10. STABILITY AND REACTIVITY
Stable at ambient temperatures.
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Avoid halogens
Skin
Unlikely to cause harm to the skin on accidental contact.
Inhalation
May have a narcotic effect if high concentrations of vapour are inhaled.
High vapour concentrations may produce symptoms of oxygen deficiency which, coupled with central nervous system
depression, may lead to rapid loss of consciousness.
__________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
The product is volatile/gaseous and will partition to the air phase.
EU Labelling
Symbol: Flame
Indication of danger: EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
R12 Extremely flammable
Safety ( S ) Phrases:
S3/9 Keep in a cool, well ventilated place.
S16 Keep away from sources of ignition - No smoking
S33 Take precautionary measures against static discharges
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
The label must carry the following additional information: "EC Label", Substance name, EINECS No. Natural gas, dried,
EINECS No. 270-085-9, CAS No. 68410-63-9
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
hazards inherent in the nature of the material.
Petroleum Gas
Common refinery name: LPG
Application
Refinery stream
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil UK Ltd, Coryton Refinery, The Manorway, Stanford-le-Hope, Essex SS17 9LL
BP Oil Grangemouth Refinery Ltd, Bo'Ness Road, Grangemouth, Stirlingshire FK3 9XQ
Extremely flammable.
Carcinogenic, category 2 ; contains 1,3 butadiene at > 0.1%.
Explosive air/vapour mixtures may form at ambient temperature.
Abuse involving wilful inhalation of very high concentrations of vapour, even for short periods, can produce
unconsciousness or might prove fatal.
__________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water. Obtain IMMEDIATE medical attention.
Skin
If cold burns are present drench with water and obtain immediate medical advice.
Keep contaminated clothes away from ignition sources.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat,
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
These materials are delivered, stored and used at temperatures above their flash point. Avoid all naked flames, sparks,
cigarettes, etc.
IN CASE OF FIRE, IMMEDIATELY ALERT THE FIRE BRIGADE.
Ensure an escape path is always available from any fire.
FIRES IN CONFINED SPACES SHOULD BE DEALT WITH BY TRAINED PERSONNEL WEARING APPROVED
BREATHING APPARATUS.
If gas has ignited, do not attempt to extinguish but stop gas flow and allow to burn out. Use water spray to cool heat-
exposed containers, and to protect surrounding areas and personnel effecting shut-off.
Every precaution must be taken to keep containers cool to avoid the possibility of a boiling liquid expanding vapour
explosion (BLEVE).
Pressurised containers are liable to explode violently when subjected to high temperatures.
Combustion Products
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
If a leak has not ignited, stop gas flow, isolate sources of ignition and evacuate personnel.
Ensure good ventilation.
Liquid leaks generate large volumes of flammable vapour, heavier than air, which may travel to remote sources of ignition
(eg. along drainage systems).
Where appropriate, use water spray to disperse the gas or vapour and to protect personnel attempting to stop leakage.
Vapour may collect in any confined space.
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable atmosphere is
present before entry.
Do not enter a vapour cloud except for rescue; self-contained breathing apparatus must be worn.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
In the event of a leak, contact the appropriate authorities.
Small quantities of spilled liquid may be allowed to evaporate. Vapour should be dispersed by effective ventilation.
__________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and use only in equipment/containers designed for use with this product.
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Do not enter storage tanks. If entry to tanks is necessary, contact the supplier.
Containers must be properly labelled.
Do not remove warning labels from containers.
Handling Precautions
Ensure good ventilation.
Avoid inhalation of vapour.
Avoid contact with liquid and cold storage containers.
When handling cylinders wear protective footwear and suitable gloves.
Avoid contact with the eyes.
Whilst using do not eat, drink or smoke.
Fire Prevention
Ensure equipment is electrically bonded and earthed to prevent static accumulation.
Explosive air/vapour mixtures may form at ambient temperature.
Note: Product spilt on clothing may give rise to delayed evaporation and subsequent fire hazard.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
Comply with current local occupational exposure limit. Where not established, the following limits are recommended.
Liquefied Petroleum Gas (LPG)
UK publication EH40 (Occupational Exposure Limits):
Occupational Exposure Standard: Long-term exposure limit (8hr TWA) 1000ppm, 1750 mg/m3
Short-term exposure limit (15 min) 1250ppm, 2180 mg/m3
Propane
UK publication EH40 (Occupational Exposure Limits):
Simple asphyxiant.
Butane
UK publication EH40 (Occupational Exposure Limits):
Occupational Exposure Standard: Long-term exposure limit (8hr TWA) 600ppm, 1450 mg/m3
Short-term exposure limit (15 min) 750ppm, 1810mg/m3
Protective Clothing
Wear suitable gloves and overalls to prevent cold burns and frostbite.
In filling operations wear protective clothing including impervious gloves, safety goggles or face shield.
When handling cylinders wear protective footwear.
Respiratory Protection
If operations are such that significant exposure to vapour, mist or fume may be anticipated, then suitable approved
respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
__________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Typical Values
Grades:Petroleum Gas
Test Method Units
Physical state gas
Colour colourless
Odour Distinctive when stenched
Density @ 15°C ASTM D 1657 kg/m3 500 - 580
Gauge vapour pressure 40°C BS3324 kPa 300 -
1550
Vapour density rel. to air ASTM 1.5 - 2.1
D2463/D2421
Flammability Limits % 1.9 - 11.1
Flash point (PMC) ASTM D 93 °C <-50
Boiling point/range °C <-2
Materials to Avoid
Avoid contact with strong oxidizing agents.
Eyes
Will present a risk of serious damage to the eyes if contact with liquid occurs.
Skin
Will cause cold burns and frostbite if skin contact with liquid occurs.
Inhalation
Low vapour concentrations may cause nausea, dizziness, headaches and drowsiness.
May have a narcotic effect if high concentrations of vapour are inhaled.
High vapour concentrations may produce symptoms of oxygen deficiency which, coupled with central nervous system
depression, may lead to rapid loss of consciousness.
Contains > 0.1% 1,3-butadiene; animal studies have shown that 1,3 butadiene has a potential to cause cancer.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very high
concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
__________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages are unlikely to penetrate the soil.
Bioaccumulative potential
This material is not expected to bioaccumulate.
Aquatic toxicity
Unlikely to cause long term effects in the aquatic environment.
__________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Do not dispose of any LPG container. Return all cylinders/vessels to your supplier.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty
packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld, solder
or braze empty containers.
__________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Hydrocarbon gas mixture, liquefied, N.O.S. (technical name). Flammable gases, Class 2, Item 2°F,
Hazard Identification Number 23.
UN: Hydrocarbon gas mixture, liquefied, N.O.S. (technical name). Flammable Gases, Class 2.1, UN Number 1965.
IATA/ICAO: Hydrocarbon gas mixtures liquefied N.O.S. (technical name). Flammable gas, Class 2.1.
Forbidden for transport on passenger aircraft.
IMO: Hydrocarbon gas mixture, liquefied, N.O.S (technical name). Flammable gas, Class 2.1.
Emergency Action Code: Flammable gas, 2WE
NOTE: More specific technical name required in brackets e.g. (butane, propane)
__________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
Carcinogenic category 2
EU Labelling
Symbol: Flame, Skull and crossbones
Indication of danger: EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S3/9 Keep in a cool, well ventilated place.
S16 Keep away from sources of ignition - No smoking
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
The label must carry the following additional information: "EC Label", Substance name, EINECS No. (as appropriate)
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
Application
Refinery stream
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil UK Ltd, Coryton Refinery, The Manorway, Stanford-le-Hope, Essex SS17 9LL
BP Oil Grangemouth Refinery Ltd, Bo'Ness Road, Grangemouth, Stirlingshire FK3 9XQ
Eyes
Not hazardous under normal conditions of use. Obtain medical advice if any pain or redness develops or persists.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat,
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air and
medical assistance obtained without delay.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be delayed
for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and consider
administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema develops.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
These materials are delivered, stored and used at temperatures above their flash point. Avoid all naked flames, sparks,
cigarettes, etc.
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
FIRES IN CONFINED SPACES SHOULD BE DEALT WITH BY TRAINED PERSONNEL WEARING APPROVED
BREATHING APPARATUS.
If gas has ignited, do not attempt to extinguish but stop gas flow and allow to burn out. Use water spray to cool heat-
exposed containers, and to protect surrounding areas and personnel effecting shut-off.
Combustion Products
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Ensure good ventilation.
Vapour may collect in any confined space.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
In the event of a leak, contact the appropriate authorities.
If a leak has not ignited, stop gas flow, isolate sources of ignition and evacuate personnel.
In confined or poorly ventilated spaces the use of self-contained breathing apparatus may be necessary. See Exposure
Controls/ Personal Protection, Section 8 of this Safety Data Sheet.
Evacuate all non essential personnel from the immediate area.
Explosive air/vapour mixtures can occur, particularly in unventilated or confined spaces.
_________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and use only in equipment/containers designed for use with this product.
Do not enter storage tanks. If entry to tanks is necessary, contact the supplier.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when no
alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved type and
following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see the comments
in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Handling Precautions
Ensure good ventilation.
Fire Prevention
Ensure equipment is electrically bonded and earthed to prevent static accumulation.
Explosive air/vapour mixtures may form at ambient temperature.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
There is no appropriate occupational exposure limit for this material.
Comply with current local occupational exposure limit. Where not established, the following limits are recommended.
Hydrogen / Methane / Ethane / Ethylene / Propylene
UK publication EH40 (Occupational Exposure Limits):
Simple asphyxiant.
Propane
UK publication EH40 (Occupational Exposure Limits):
Simple asphyxiant.
Hydrogen Sulphide
UK publication EH40 (Occupational Exposure Limits):
Occupational Exposure Standard: Long-term exposure limit (8hr TWA) 10 ppm, 14 mg/m3
Short-term exposure limit (15 min) 15ppm, 21 mg/m3
Respiratory Protection
Respiratory protection is unnecessary, provided the concentration of vapour, mists or fumes is adequately controlled.
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators may
unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-supplied
breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas
__________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Typical Values
Grades:Refinery Fuel Gas
Test Method Units
Physical state gas
Colour colourless
Odour pungent
Boiling point/range ASTM D 86 °C < -73
Vapour density rel. to air ASTM <1
D2463/D2421
Flash point (COC) ASTM D 92 °C < -73
Explosion limits % 75.0/4.0
Solubility in water g/l Slight
10. STABILITY AND REACTIVITY
Stable at ambient temperatures.
Hazardous polymerisation reactions will not occur.
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Avoid halogens
Skin
Unlikely to cause harm to the skin on accidental contact.
Inhalation
Low vapour concentrations may cause nausea, dizziness, headaches and drowsiness.
May have a narcotic effect if high concentrations of vapour are inhaled.
High vapour concentrations may produce symptoms of oxygen deficiency which, coupled with central nervous system
depression, may lead to rapid loss of consciousness.
Contains > 0.1% 1,3-butadiene; animal studies have shown that 1,3 butadiene has a potential to cause cancer.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very high
concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
__________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
The product is volatile/gaseous and will partition to the air phase.
EU Labelling
Symbol: Flame, Skull and crossbones
Indication of danger: EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S3/9 Keep in a cool, well ventilated place.
S16 Keep away from sources of ignition - No smoking
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
The label must carry the following additional information: "EC Label", Substance name, EINECS No. (271-750-6)
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
hazards inherent in the nature of the material.
Application
Chemical Feedstock
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
A complex combination of hydrocarbons produced by the distillation of products from the gas and gasoline fractions of
a catalytic cracking process. It consists predominantly of propylene with some ethane and propane.
EINECS No: 270-772-3, CAS No: 68477-90-7
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Abuse involving wilful inhalation of very high concentrations of vapour, even for short periods, can produce
unconsciousness or might prove fatal.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water. Obtain IMMEDIATE medical attention.
Skin
If cold burns are present drench with water and obtain immediate medical advice.
Keep contaminated clothes away from ignition sources.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
These materials are delivered, stored and used at temperatures above their flash point. Avoid all naked flames,
sparks, cigarettes, etc.
IN CASE OF FIRE, IMMEDIATELY ALERT THE FIRE BRIGADE.
Ensure an escape path is always available from any fire.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
If gas has ignited, do not attempt to extinguish but stop gas flow and allow to burn out. Use water spray to cool heat-
exposed containers, and to protect surrounding areas and personnel effecting shut-off.
Every precaution must be taken to keep containers cool to avoid the possibility of a boiling liquid expanding vapour
explosion (BLEVE).
Pressurised containers are liable to explode violently when subjected to high temperatures.
Combustion Products
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
If a leak has not ignited, stop gas flow, isolate sources of ignition and evacuate personnel.
Ensure good ventilation.
Liquid leaks generate large volumes of flammable vapour, heavier than air, which may travel to remote sources of
Handling Precautions
Ensure good ventilation.
Avoid inhalation of vapour.
Avoid contact with liquid and cold storage containers.
When handling cylinders wear protective footwear and suitable gloves.
Avoid contact with the eyes.
Fire Prevention
Ensure equipment is electrically bonded and earthed to prevent static accumulation.
Explosive air/vapour mixtures may form at ambient temperature.
Note: Product spilt on clothing may give rise to delayed evaporation and subsequent fire hazard.
_________________________________________________________________________________
Propylene
ACGIH (USA):
Simple asphyxiant.
Propane
ACGIH (USA): TLV 2500ppm (8 hr TWA)
Protective Clothing
Wear suitable gloves and overalls to prevent cold burns and frostbite.
In filling operations wear protective clothing including impervious gloves, safety goggles or face shield.
When handling cylinders wear protective footwear.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Will cause cold burns and frostbite if skin contact with liquid occurs.
Inhalation
Low vapour concentrations may cause nausea, dizziness, headaches and drowsiness.
May have a narcotic effect if high concentrations of vapour are inhaled.
High vapour concentrations may produce symptoms of oxygen deficiency which, coupled with central nervous system
depression, may lead to rapid loss of consciousness.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages are unlikely to penetrate the soil.
The product is volatile/gaseous and will partition to the air phase.
Bioaccumulative potential
This material is not expected to bioaccumulate.
Aquatic toxicity
Unlikely to cause long term effects in the aquatic environment.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Do not dispose of any LPG container. Return all cylinders/vessels to your supplier.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld,
solder or braze empty containers.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Propylene. Flammable gases, Class 2, Item 2°F, Hazard Identification Number 23.
UN: Propylene. Flammable Gases, Class 2.1, UN Number 1077
IATA/ICAO: Propylene. Flammable gas, Class 2.1. Forbidden for transport on passenger aircraft.
IMO: Propylene. Flammable gas, Class 2.1.
Emergency Action Code: Flammable gas, 2WE
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
EU Labelling
Symbol:
Flame
Indication of danger:
EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
R12 Extremely flammable
Safety ( S ) Phrases:
S3/9 Keep in a cool, well ventilated place.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Gases (petroleum), depropanizer dry, propene-rich, EINECS No: 270-772-3
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
06/01/99 2, 15
17/07/2000 8, 9
Alkylate
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Alkylate
Alternative Names: Low boiling point modified naphtha
Application
Refinery feedstock
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Gasoline
ACGIH (USA) : TLV 300 ppm (8hr TWA); 500 ppm (15min STEL)
A3 - Animal Carcinogen
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Grades: Alkylate
Test Method Units
Physical state low viscosity
liquid
Colour colourless ->
amber
Odour gasoline-like
Density @ 15°C ASTM D 1298 kg/m³ 680 - 740
Flash point (PMC) ASTM D 93 °C below -18
Boiling point/range °C 25 - 220
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name:Naphtha (petroleum), full-range alkylate, EINECS No: 265-066-7
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Application
Fuel for compression ignition diesel engines
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Cracked components containing polycyclic aromatic hydrocarbon compounds may be present.
Fuels, diesel. EINECS No: 269-822-7, CAS No: 68334-30-5, Xn, R40 Possible risks of irreversible effects, R65
Harmful: may cause lung damage if swallowed, R66 Repeated exposure may cause skin dryness or cracking
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Harmful if swallowed - aspiration hazard.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Repeated exposure may cause skin dryness or cracking.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage, remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable
atmosphere is present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
mists generated will create a flammability or explosion hazard.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to
dermatitis.
As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may
eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
This material may accumulate in sediments.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Harmful to aquatic organisms, may cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
EU Labelling
Symbol:
St. Andrew's Cross
Indication of danger:
HARMFUL
Contains:
Fuels, Diesel
Risk ( R ) Phrases:
R40 Possible risks of irreversible effects
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking
Safety ( S ) Phrases:
S2 Keep out of reach of children
S24 Avoid contact with skin
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
07/05/98 1, 2, 12, 15
02/11/98 1
17/07/2000 2, 3, 4, 9, 12, 15
AVCAT
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
AVCAT
Alternative Names: (Synonyms F-44, AVCAT/FSII, JP5)
Application
Jet fuel
do not use for other purposes
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL
Hazardous Components
Kerosine - unspecified
Xn R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Harmful if swallowed - aspiration hazard.
Likely to cause skin irritation.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water
ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs
wash out thoroughly with water.
Except as a deliberate act
the ingestion of large amounts of product is unlikely. If it should occur
do not induce vomiting
obtain medical advice.
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate
medical assistance must be called without delay. If breathing has failed respiration must be assisted
preferably by mouth to mouth method.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents
and can cause severe and potentially fatal chemical pneumonitis
which will require urgent treatment. Because of the risk of aspiration
induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after
endotracheal intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam
dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity
Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage
remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection
section 8
of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems
in basements etc.).
If spillage has occurred in a confined space
ensure adequate ventilation and check that a safe
breathable atmosphere is present before entry.
In the case of spillage on water
prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect
environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Handling Precautions
Avoid
as far as reasonably practicable
inhalation of vapour
mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat
drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling
discharge or ullaging) and when sampling
there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags
paper or material used to absorb spillages
represent a fire hazard
and should not be allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut
weld
solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely
wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained
Respiratory Protection
If operations are such that exposure to vapour
mist or fume may be anticipated
then suitable approved respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses
though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs
eg. during vomiting.
Inhalation
May cause irritation to eyes
nose and throat due to exposure to vapour
mists or fumes.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms.
May cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Dispose of product and container carefully and responsibly. Do not dispose of near ponds
ditches
down drains or onto soil.
At sea
used or unwanted product should be stored for eventual discharge into port approved waste oil disposal facilities.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Kerosene
Flammable Liquid
Class 3
Item 31 (c)
Hazard Identification No 30
UN: KEROSENE
Flammable liquid
Class 3
Packing Group III
UN Number 1223
IATA/ICAO: Kerosene
Flammable liquid
Class 3
Packing Group III
IMO: KEROSENE
Flammable liquid
Class 3.3
Packing Group III
EMERGENCY ACTION CODE: Flammable liquid
3[Y]
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Harmful
Irritant
EU Labelling
Symbol: St. Andrew's Cross
Indication of danger: HARMFUL (Xn)
Contains:
Kerosine - unspecified
Risk ( R ) Phrases:
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
Safety ( S ) Phrases:
S24 Avoid contact with skin
S23 Do not breathe vapour
S43 - In case of fire use foam or dry powder. Never use water jets
S62 If swallowed
do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission
recommendation or authorization given or implied to practise any patented invention without a valid licence. The BP
Amoco Group shall not be responsible for any damage or injury resulting from abnormal use of the material
from any failure to adhere to recommendations
or from any hazards inherent in the nature of the material.
______________________________________________________________________________
Application
Use only as a motor fuel for aviation. Should NOT be used as a solvent nor cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
A complex mixture of volatile hydrocarbons containing paraffins
naphthenes
olefins and aromatics with carbon numbers predominantly between C4 and C12.
May contain oxygenates. May also contain small quantities of proprietary performance additives.
Contains lead compounds.
Hazardous Components
Lead alkyls
T+
N
R61 May cause harm to the unborn child.
R62 Possible risk of impaired fertility
R26/27/28 Very toxic by inhalation
in contact with skin and if swallowed
R33 Danger of cumulative effects
R50/53 Very toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
(>0.1 - <0.5% Pb)
Benzene
EINECS No. 200-753-7
CAS No. 71-43-2 F
T
R45 May cause cancer
R11 Highly flammable
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation
in contact with skin and if swallowed
Gasoline
EINECS No: 289-220-8
CAS No: 86290-81-5 F+
T
N
R12 Extremely flammable
R45 May cause cancer
R65 Harmful: may cause lung damage if swallowed
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness
R51/53 Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer
classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases
including leukaemia.
Toxic by inhalation
in contact with skin and if swallowed.
Harmful if swallowed - aspiration hazard.
Danger of cumulative effects
May cause harm to the unborn child
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water
ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product
drench with water
remove clothing as soon as possible and wash skin with soap and water. Seek medical advice if skin becomes red
swollen or painful.
Ingestion
If contamination of the mouth occurs
wash out thoroughly with water.
Except as a deliberate act
the ingestion of large amounts of product is unlikely. If it should occur
do not induce vomiting
obtain medical advice.
Inhalation
If exposure to vapour
mists or fumes causes drowsiness
headache
blurred vision or irritation of the eyes
nose or throat
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents
and can cause severe and potentially fatal chemical pneumonitis
which will require urgent treatment. Because of the risk of aspiration
induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after
endotracheal intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam
dry powder or water fog. DO NOT use water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity
Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems
in basements etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water
prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect
environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Special health precautions must be taken during cleaning or maintenance operations on storage tanks which may
have contained leaded product at any time.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours
mists or fumes which may be generated during use. If such vapour
mists or fumes are generated
their concentration in the workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Do not siphon product by mouth.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling
discharge or ullaging) and when sampling
there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces
or leaks occur from pressurised fuel pipes
the vapour or mists generated will create a flammability or explosion hazard.
Product contaminated rags
paper or material used to absorb spillages
represent a fire hazard
and should not be allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut
weld
solder or braze empty containers.
_________________________________________________________________________________
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA)
2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely
wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained
overalls should be dry-cleaned
laundered and preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour
mist or fume may be anticipated
then suitable approved respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Toxic in contact with skin - contains lead.
Ingestion
Toxic if swallowed - contains lead.
Will injure the lungs if aspiration occurs
eg. during vomiting.
Inhalation
Toxic by inhalation - contains lead
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea
dizziness
headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous
however
abuse involving deliberate inhalation of very high concentrations of vapour
even for short periods
can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
Lead is a cumulative poison. It can cause anaemia
central nervous system effects
gastro-intestinal symptoms and kidney damage.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
When cleaning storage tanks
sludges which may be contaminated with lead must be disposed of via a licensed waste disposal contractor
in accordance with local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Motor spirit
Flammable liquid
Class 3
Item 3(b)
Hazard Identification No 33
ADNR/ADN: Motor Spirit
Class 3
Item 3(b)
UN: MOTOR SPIRIT
Flammable liquid
Class 3. Packing Group II
UN Number 1203
IATA/ICAO: Motor spirit
Flammable liquid
Class 3
Packing group II
IMO: MOTOR SPIRIT
Flammable liquid
Class 3.1
Packing group II
MARINE POLLUTANT (Leaded Petrol)
EMERGENCY ACTION CODE: Flammable liquid
3[Y]E
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
Carcinogenic category 2
Toxic to reproduction category 3
Toxic
Irritant
Harmful
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
TOXIC
Contains:
Low boiling point naphtha - unspecified
Lead alkyls
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R23/24/25 Also Toxic by inhalation
in contact with skin
and if swallowed
R65 Also Harmful: may cause lung damage if swallowed.
R61 May cause harm to the unborn child.
R33 Danger of cumulative effects.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell
seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire
use foam/dry powder/CO2. Never use water jets.
S62 If swallowed
do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission
recommendation or authorization given or implied to practise any patented invention without a valid licence. The BP
Amoco Group shall not be responsible for any damage or injury resulting from abnormal use of the material
from any failure to adhere to recommendations
or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
07/04/97 1
2
3
8
12
15
19/06/2000 1
2
3
4
7
8
10
12
15
SHEET NO: SAV2104
ISSUE DATE: 19/06/2000
REVISION OF SHEET DATED: 30/03/98
______________________________________________________________________________
Application
Use only as a motor fuel for aviation. Should NOT be used as a solvent nor cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
A complex mixture of volatile hydrocarbons containing paraffins
naphthenes
olefins and aromatics with carbon numbers predominantly between C4 and C12.
May contain oxygenates. May also contain small quantities of proprietary performance additives.
Contains lead compounds.
Hazardous Components
Lead alkyls
T+
N
R61 May cause harm to the unborn child.
R62 Possible risk of impaired fertility
R26/27/28 Very toxic by inhalation
in contact with skin and if swallowed
R33 Danger of cumulative effects
R50/53 Very toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
(0.05 - <0.1% Pb)
Benzene
EINECS No. 200-753-7
CAS No. 71-43-2 F
T
R45 May cause cancer
R11 Highly flammable
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation
in contact with skin and if swallowed
Gasoline
EINECS No: 289-220-8
CAS No: 86290-81-5 F+
T
N
R12 Extremely flammable
R45 May cause cancer
R65 Harmful: may cause lung damage if swallowed
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness
R51/53 Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer
classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases
including leukaemia.
Harmful by inhalation
in contact with skin and if swallowed.
Harmful if swallowed - aspiration hazard.
Danger of cumulative effects
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water
ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product
drench with water
remove clothing as soon as possible and wash skin with soap and water. Seek medical advice if skin becomes red
swollen or painful.
Ingestion
If contamination of the mouth occurs
wash out thoroughly with water.
Except as a deliberate act
the ingestion of large amounts of product is unlikely. If it should occur
do not induce vomiting
obtain medical advice.
Inhalation
If exposure to vapour
mists or fumes causes drowsiness
headache
blurred vision or irritation of the eyes
nose or throat
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents
and can cause severe and potentially fatal chemical pneumonitis
which will require urgent treatment. Because of the risk of aspiration
induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after
endotracheal intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity
Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems
in basements etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water
prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect
environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours
mists or fumes which may be generated during use. If such vapour
mists or fumes are generated
their concentration in the workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Do not siphon product by mouth.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling
discharge or ullaging) and when sampling
there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces
or leaks occur from pressurised fuel pipes
the vapour or mists generated will create a flammability or explosion hazard.
Product contaminated rags
paper or material used to absorb spillages
represent a fire hazard
and should not be allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut
weld
solder or braze empty containers.
_________________________________________________________________________________
Benzene
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely
wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained
overalls should be dry-cleaned
laundered and preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour
mist or fume may be anticipated
then suitable approved respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Harmful in contact with skin - contains lead.
Ingestion
Harmful if swallowed - contains lead.
Will injure the lungs if aspiration occurs
eg. during vomiting.
Inhalation
Harmful by inhalation - contains lead
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea
dizziness
headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous
however
abuse involving deliberate inhalation of very high concentrations of vapour
even for short periods
can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
Lead is a cumulative poison. It can cause anaemia
central nervous system effects
gastro-intestinal symptoms and kidney damage.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
Aquatic toxicity
Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
When cleaning storage tanks
sludges which may be contaminated with lead must be disposed of via a licensed waste disposal contractor
in accordance with local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Motor spirit
Flammable liquid
Class 3
Item 3(b)
Hazard Identification No 33
ADNR/ADN: Motor Spirit
Class 3
Item 3(b)
UN: MOTOR SPIRIT
Flammable liquid
Class 3. Packing Group II
UN Number 1203
IATA/ICAO: Motor spirit
Flammable liquid
Class 3
Packing group II
IMO: MOTOR SPIRIT
Flammable liquid
Class 3.1
Packing group II
MARINE POLLUTANT (Leaded Petrol)
EMERGENCY ACTION CODE: Flammable liquid
3[Y]E
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
Carcinogenic category 2
Irritant
Harmful
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
Contains:
Low boiling point naphtha - unspecified
Lead alkyls
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R20/21/22 Also Harmful by inhalation
in contact with the skin and if swallowed.
R65 Also Harmful: may cause lung damage if swallowed.
R33 Danger of cumulative effects.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell
seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S43 In case of fire
use foam/dry powder/CO2. Never use water jets.
S62 If swallowed
do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN
reviewed any information contained herein which we received from sources outside the BP Amoco Group of
Companies. However
no warranty or representation
express or implied is made as to the accuracy or completeness of the data and information contained in this data
sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission
recommendation or authorization given or implied to practise any patented invention without a valid licence. The BP
Amoco Group shall not be responsible for any damage or injury resulting from abnormal use of the material
from any failure to adhere to recommendations
or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
11/11/97 1
2
3
8
12
15
19/06/2000 1
2
3
4
7
8
10
15
SHEET NO: SAV2103A
ISSUE DATE: 19/06/2000
REVISION OF SHEET DATED: 11/03/98
______________________________________________________________________________
Application
Use only as a motor fuel for aviation. Should NOT be used as a solvent nor cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL
_________________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
A complex mixture of volatile hydrocarbons containing paraffins
naphthenes
olefins and aromatics with carbon numbers predominantly between C4 and C12.
May contain oxygenates. May also contain small quantities of proprietary performance additives.
Contains lead compounds.
Hazardous Components
Lead alkyls
T+
N
R61 May cause harm to the unborn child.
R62 Possible risk of impaired fertility
R26/27/28 Very toxic by inhalation
in contact with skin and if swallowed
R33 Danger of cumulative effects
R50/53 Very toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
(0.05 - <0.1% Pb)
Gasoline
EINECS No: 289-220-8
CAS No: 86290-81-5 F+
Xn
N
R12 Extremely flammable
R65 Harmful: may cause lung damage if swallowed
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness
R51/53 Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
Harmful by inhalation
in contact with skin and if swallowed.
Harmful if swallowed - aspiration hazard.
Danger of cumulative effects
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water
ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product
drench with water
remove clothing as soon as possible and wash skin with soap and water. Seek medical advice if skin becomes red
swollen or painful.
Ingestion
If contamination of the mouth occurs
wash out thoroughly with water.
Except as a deliberate act
the ingestion of large amounts of product is unlikely. If it should occur
do not induce vomiting
obtain medical advice.
Inhalation
If exposure to vapour
mists or fumes causes drowsiness
headache
blurred vision or irritation of the eyes
nose or throat
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents
and can cause severe and potentially fatal chemical pneumonitis
which will require urgent treatment. Because of the risk of aspiration
induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after
endotracheal intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam
dry powder or water fog. DO NOT use water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity
Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems
in basements etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water
prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect
environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours
mists or fumes which may be generated during use. If such vapour
mists or fumes are generated
their concentration in the workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling
discharge or ullaging) and when sampling
there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces
or leaks occur from pressurised fuel pipes
the vapour or mists generated will create a flammability or explosion hazard.
Product contaminated rags
paper or material used to absorb spillages
represent a fire hazard
and should not be allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut
weld
solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely
wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained
overalls should be dry-cleaned
laundered and preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour
mist or fume may be anticipated
then suitable approved respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Harmful in contact with skin - contains lead.
Ingestion
Harmful if swallowed - contains lead.
Will injure the lungs if aspiration occurs
eg. during vomiting.
Inhalation
Harmful by inhalation - contains lead
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea
dizziness
headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous
however
abuse involving deliberate inhalation of very high concentrations of vapour
even for short periods
can produce unconsciousness and/or result in a sudden fatality.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
When cleaning storage tanks
sludges which may be contaminated with lead must be disposed of via a licensed waste disposal contractor
in accordance with local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Motor spirit
Flammable liquid
Class 3
Item 3(b)
Hazard Identification No 33
ADNR/ADN: Motor Spirit
Class 3
Item 3(b)
UN: MOTOR SPIRIT
Flammable liquid
Class 3. Packing Group II
UN Number 1203
IATA/ICAO: Motor spirit
Flammable liquid
Class 3
Packing group II
IMO: MOTOR SPIRIT
Flammable liquid
Class 3.1
Packing group II
MARINE POLLUTANT (Leaded Petrol)
EMERGENCY ACTION CODE: Flammable liquid
3[Y]E
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
Irritant
Harmful
EU Labelling
Symbol:
Flame
St. Andrew's Cross
Indication of danger:
EXTREMELY FLAMMABLE
HARMFUL
Contains:
Low boiling point naphtha - unspecified
Lead alkyls
Risk ( R ) Phrases:
R12 Extremely flammable
R20/21/22 Harmful by inhalation
in contact with the skin and if swallowed.
R33 Danger of cumulative effects.
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission
recommendation or authorization given or implied to practise any patented invention without a valid licence. The BP
Amoco Group shall not be responsible for any damage or injury resulting from abnormal use of the material
from any failure to adhere to recommendations
or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
03/09/96 2
3
8
12
14
15
19/06/2000 1
2
3
4
7
8
12
15
SHEET NO: SAV2103
ISSUE DATE: 19/06/2000
REVISION OF SHEET DATED: 11/03/98
______________________________________________________________________________
Application
Use only as a motor fuel for aviation. Should NOT be used as a solvent nor cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Lead alkyls, T+, N, R61 May cause harm to the unborn child., R62 Possible risk of impaired fertility, R26/27/28 Very
toxic by inhalation, in contact with skin and if swallowed, R33 Danger of cumulative effects, R50/53 Very toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic environment
(>0.1 - <0.5% Pb)
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable,
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed
Gasoline, EINECS No: 289-220-8, CAS No: 86290-81-5 F+,T, N, R12 Extremely flammable, R45 May cause cancer,
R65 Harmful: may cause lung damage if swallowed, R38 Irritating to skin, R67 Vapours may cause drowsiness and
dizziness, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Toxic by inhalation, in contact with skin and if swallowed.
Harmful if swallowed - aspiration hazard.
Danger of cumulative effects
May cause harm to the unborn child
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT use water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Toxic in contact with skin - contains lead.
Ingestion
Toxic if swallowed - contains lead.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Toxic by inhalation - contains lead
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
Lead is a cumulative poison. It can cause anaemia, central nervous system effects, gastro-intestinal symptoms and
kidney damage.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: 3
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld,
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
When cleaning storage tanks, sludges which may be contaminated with lead must be disposed of via a licensed waste
disposal contractor, in accordance with local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Motor spirit, Flammable liquid, Class 3, Item 3(b), Hazard Identification No 33
ADNR/ADN: Motor Spirit, Class 3, Item 3(b)
UN: MOTOR SPIRIT, Flammable liquid, Class 3. Packing Group II, UN Number 1203
IATA/ICAO: Motor spirit, Flammable liquid, Class 3, Packing group II
IMO: MOTOR SPIRIT, Flammable liquid, Class 3.1, Packing group II, MARINE POLLUTANT (Leaded Petrol)
EMERGENCY ACTION CODE: Flammable liquid, 3[Y]E
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
Carcinogenic category 2
Toxic to reproduction category 3
Toxic
Irritant
Harmful
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
TOXIC
Contains:
Low boiling point naphtha - unspecified
Lead alkyls
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R23/24/25 Also Toxic by inhalation, in contact with skin, and if swallowed
R65 Also Harmful: may cause lung damage if swallowed.
R61 May cause harm to the unborn child.
R33 Danger of cumulative effects.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
02/11/98 1
17/07/2000 2, 3, 4, 8, 15
Application
Use only as a motor fuel for aviation. Should NOT be used as a solvent nor cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Lead alkyls, T+, N, R61 May cause harm to the unborn child., R62 Possible risk of impaired fertility, R26/27/28 Very
toxic by inhalation, in contact with skin and if swallowed, R33 Danger of cumulative effects, R50/53 Very toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic environment
(0.05 - <0.1% Pb)
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable,
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed
Gasoline, EINECS No: 289-220-8, CAS No: 86290-81-5 F+,T, N, R12 Extremely flammable, R45 May cause cancer,
R65 Harmful: may cause lung damage if swallowed, R38 Irritating to skin, R67 Vapours may cause drowsiness and
dizziness, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful by inhalation, in contact with skin and if swallowed.
Harmful if swallowed - aspiration hazard.
Danger of cumulative effects
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT use water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Storage Conditions
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Store and use only in equipment/containers designed for use with this product.
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to
the safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Special health precautions must be taken during cleaning or maintenance operations on storage tanks which may
have contained leaded product at any time.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
_________________________________________________________________________________
11. TOXICOLOGICAL INFORMATION
Eyes
Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Harmful in contact with skin - contains lead.
Ingestion
Harmful if swallowed - contains lead.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Harmful by inhalation - contains lead
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
Lead is a cumulative poison. It can cause anaemia, central nervous system effects, gastro-intestinal symptoms and
kidney damage.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: 3
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
Contains:
Low boiling point naphtha - unspecified
Lead alkyls
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R20/21/22 Also Harmful by inhalation, in contact with the skin and if swallowed.
R65 Harmful: may cause lung damage if swallowed.
R33 Danger of cumulative effects.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
02/11/98 1
17/07/2000 2, 3, 4, 7, 15
______________________________________________________________________________
Application
Jet fuel, do not use for other purposes
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Kerosine - unspecified, Xn R10 Flammable, R38 Irritating to skin, R65 Harmful: may cause lung damage if swallowed.
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Flammable
Harmful if swallowed - aspiration hazard.
Likely to cause skin irritation.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate, medical assistance
must be called without delay. If breathing has failed respiration must be assisted, preferably by mouth to mouth
method.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: 2
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Dispose of product and container carefully and responsibly. Do not dispose of near ponds, ditches, down drains or
onto soil.
At sea, used or unwanted product should be stored for eventual discharge into port approved waste oil disposal
facilities.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Kerosene, Flammable Liquid, Class 3 , Item 31 (c), Hazard Identification No 30
UN: KEROSENE, Flammable liquid, Class 3, Packing Group III, UN Number 1223
IATA/ICAO: Kerosene, Flammable liquid, Class 3, Packing Group III
IMO: KEROSENE, Flammable liquid, Class 3.3, Packing Group III
EMERGENCY ACTION CODE: Flammable liquid, 3[Y]
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Flammable
Harmful
Irritant
EU Labelling
Symbol:
St. Andrew's Cross
Indication of danger:
HARMFUL
Contains:
Kerosine - unspecified
Risk ( R ) Phrases:
R10 Flammable
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
Safety ( S ) Phrases:
S24 Avoid contact with skin
S23 Do not breathe vapour
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
11/05/98 2, 4, 12, 15
02/11/98 1
17/07/2000 2, 9, 15
Avtag
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Avtag
Application
Wide cut aviation turbine fuel.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
A complex combination of volatile hydrocarbons consisting primarily of paraffins
cycloparaffins
aromatic and olefinic hydrocarbons having carbon numbers predominantly in the range C5 through C14 and boiling in
the range 20°C to 270°C.
Hazardous Components
Kerosine - unspecified
Xn R10 Flammable
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
(<95%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer
classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water
ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product
drench with water
remove clothing as soon as possible and wash skin with soap and water. Seek medical advice if skin becomes red
swollen or painful.
Ingestion
If contamination of the mouth occurs
wash out thoroughly with water.
Except as a deliberate act
the ingestion of large amounts of product is unlikely. If it should occur
do not induce vomiting
obtain medical advice.
Inhalation
If exposure to vapour
mists or fumes causes drowsiness
headache
blurred vision or irritation of the eyes
nose or throat
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents
and can cause severe and potentially fatal chemical pneumonitis
which will require urgent treatment. Because of the risk of aspiration
induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after
endotracheal intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam
dry powder or water fog. DO NOT use water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity
Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems
in basements etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water
prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect
environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours
mists or fumes which may be generated during use. If such vapour
mists or fumes are generated
their concentration in the workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Do not siphon product by mouth.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA)
2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely
wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained
overalls should be dry-cleaned
laundered and preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour
mist or fume may be anticipated
then suitable approved respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses
though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs
eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea
dizziness
headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous
however
abuse involving deliberate inhalation of very high concentrations of vapour
even for short periods
can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Petroleum distillates
n.o.s.
Flammable liquid
Class 3
Item 3(b)
Hazard Identification No. 33
UN: Petroleum distillates N.O.S.
Flammable liquid
Class 3
Packing group 1
UN No. 1268
IATA/ICAO: Petroleum Distillates N.O.S. Flammable Liquid
Class 3
Packing group 1
IMO: Petroleum Distillates N.O.S.
Flammable liquid
Class 3.1
Packing group 1
Emergency Action Code: 3[Y]E
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
Carcinogenic category 2
Harmful
Irritant
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
Contains:
Low boiling point naphtha - unspecified
Kerosine - unspecified
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S2 Keep out of reach of children
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell
seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire
use foam/dry powder/CO2. Never use water jets.
S62 If swallowed
do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission
recommendation or authorization given or implied to practise any patented invention without a valid licence. The BP
Amoco Group shall not be responsible for any damage or injury resulting from abnormal use of the material
from any failure to adhere to recommendations
or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
19/06/2000 1
2
3
4
7
8
10
15
SHEET NO: SAV2107
ISSUE DATE: 19/06/2000
REVISION OF SHEET DATED: 03/11/98
______________________________________________________________________________
Application
Use only as a motor fuel for aviation. Should NOT be used as a solvent nor cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
A complex mixture of volatile hydrocarbons containing paraffins
naphthenes
olefins and aromatics with carbon numbers predominantly between C4 and C12.
May contain oxygenates. May also contain small quantities of proprietary performance additives.
Contains lead compounds.
Hazardous Components
Lead alkyls
T+
N
R61 May cause harm to the unborn child.
R62 Possible risk of impaired fertility
R26/27/28 Very toxic by inhalation
in contact with skin and if swallowed
R33 Danger of cumulative effects
R50/53 Very toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
(>0.1 - <0.5% Pb)
Benzene
EINECS No. 200-753-7
CAS No. 71-43-2 F
T
R45 May cause cancer
R11 Highly flammable
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation
in contact with skin and if swallowed
(~ 5%)
Toluene
EINECS No. 203-625-9
CAS No. 108-88-3
F
Xn
R11 Highly Flammable
R20 Harmful by inhalation
(~ 20%)
Gasoline
EINECS No: 289-220-8
CAS No: 86290-81-5 F+
T
N
R12 Extremely flammable
R45 May cause cancer
R65 Harmful: may cause lung damage if swallowed
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness
R51/53 Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer
classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases
including leukaemia.
Toxic by inhalation
in contact with skin and if swallowed.
Harmful if swallowed - aspiration hazard.
Danger of cumulative effects
May cause harm to the unborn child
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water
ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product
drench with water
remove clothing as soon as possible and wash skin with soap and water. Seek medical advice if skin becomes red
swollen or painful.
Ingestion
If contamination of the mouth occurs
wash out thoroughly with water.
Except as a deliberate act
the ingestion of large amounts of product is unlikely. If it should occur
do not induce vomiting
obtain medical advice.
Inhalation
If exposure to vapour
mists or fumes causes drowsiness
headache
blurred vision or irritation of the eyes
nose or throat
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity
Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems
in basements etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water
prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect
environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Store and use only in equipment/containers designed for use with this product.
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to
the safe handling
storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Special health precautions must be taken during cleaning or maintenance operations on storage tanks which may
have contained leaded product at any time.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours
mists or fumes which may be generated during use. If such vapour
mists or fumes are generated
their concentration in the workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat
drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling
discharge or ullaging) and when sampling
there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces
or leaks occur from pressurised fuel pipes
the vapour or mists generated will create a flammability or explosion hazard.
Product contaminated rags
paper or material used to absorb spillages
represent a fire hazard
and should not be allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut
weld
solder or braze empty containers.
_________________________________________________________________________________
Gasoline
ACGIH (USA) : TLV 300 ppm (8hr TWA)
500 ppm (15min STEL)
A3 - Animal Carcinogen
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA)
2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Toluene
ACGIH (USA): TLV 50 ppm (8 hr TWA)
A4 - Not Classifiable as a Human Carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely
wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained
overalls should be dry-cleaned
laundered and preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour
mist or fume may be anticipated
then suitable approved respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Toxic in contact with skin - contains lead.
Ingestion
Toxic if swallowed - contains lead.
Will injure the lungs if aspiration occurs
eg. during vomiting.
Inhalation
Toxic by inhalation - contains lead
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea
dizziness
headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous
however
abuse involving deliberate inhalation of very high concentrations of vapour
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
Lead is a cumulative poison. It can cause anaemia
central nervous system effects
gastro-intestinal symptoms and kidney damage.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
When cleaning storage tanks
sludges which may be contaminated with lead must be disposed of via a licensed waste disposal contractor
in accordance with local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Motor spirit
Flammable liquid
Class 3
Item 3(b)
Hazard Identification No 33
ADNR/ADN: Motor Spirit
Class 3
Item 3(b)
UN: MOTOR SPIRIT
Flammable liquid
Class 3. Packing Group II
UN Number 1203
IATA/ICAO: Motor spirit
Flammable liquid
Class 3
Packing group II
IMO: MOTOR SPIRIT
Flammable liquid
Class 3
Packing group II
MARINE POLLUTANT (Leaded Petrol)
EMERGENCY ACTION CODE: Flammable liquid
3[Y]E
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
Carcinogenic category 2
Toxic to reproduction category 2
Toxic
Irritant
Harmful
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
TOXIC
Contains:
Low boiling point naphtha - unspecified
Lead alkyls
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R23/24/25 Also Toxic by inhalation
in contact with skin
and if swallowed
R65 Also Harmful: may cause lung damage if swallowed.
R61 May cause harm to the unborn child.
R33 Danger of cumulative effects.
R38 Irritating to skin
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell
seek medical advice immediately (show label where possible)
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission
recommendation or authorization given or implied to practise any patented invention without a valid licence. The BP
Amoco Group shall not be responsible for any damage or injury resulting from abnormal use of the material
from any failure to adhere to recommendations
or from any hazards inherent in the nature of the material.
______________________________________________________________________________
Application
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor
cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Asia Lubricants Business
BP Tower
21st Storey
396 Alexandra Road
Singapore 0511
_________________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon
numbers predominantly between C4 and C12.
May contain oxygenates. May also contain small quantities of proprietary performance additives.
Hazardous Components
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable,
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed
<5%
Gasoline, EINECS No: 289-220-8, CAS No: 86290-81-5 F+,T, N, R12 Extremely flammable, R45 May cause cancer,
R65 Harmful: may cause lung damage if swallowed, R38 Irritating to skin, R67 Vapours may cause drowsiness and
dizziness, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
40 - 100%
Toluene, EINECS No. 203-625-9, CAS No. 108-88-3 F, Xn, R11 Highly flammable, R20 Harmful by inhalation.
40 - 50%
Xylene, EINECS No. 202-422-2, CAS No. 95-47-6 Xn, Xi, R10 Flammable, R20/21 Harmful by inhalation and in
contact with skin, R38 Irritating to skin.
10 - 20%
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
Harmful by inhalation.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT use water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Harmful in contact with skin.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Harmful if vapour, mists or fumes generated during use are inhaled.
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld,
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Motor spirit, Flammable Liquid , Class 3, Item 3(b), Hazard Identification No 33
ADNR/ADN: Motor Spirit, Class 3, Item 3(b),
UN: MOTOR SPIRIT, Flammable liquid, Class 3, Packing Group II, UN Number 1203
IATA/ICAO: Motor spirit, Flammable liquid, Class 3, Packing group II
IMO: MOTOR SPIRIT, Flammable liquid, Class 3.1, Packing group II
EMERGENCY ACTION CODE: 3[Y]E
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
Carcinogenic category 2
Harmful
Irritant
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
Contains:
Low boiling point naphtha - unspecified
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R20 Also Harmful by inhalation
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S2 Keep out of reach of children
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
NATIONAL CONTACT DETAILS AND EMERGENCY CALL NUMBERS
Tata BP Lubricants India Ltd. 75-77 Maker Chambers VI, Nariman Point, Mumbai 21, India
Tel: +91 22 288 0497/8 Fax: +91 22 288 0514
For other Middle East, Central Asia & Indian Sub Continent
BP Middle East, PO Box 1699 Dubai, United Arab Emirates
Tel: +(971) 4 331 8842 Pgr: +(971) 9 394 9520
BP Oil (Thailand) Ltd. 29th floor, Seng Thong Thani Tower, 82 North Sathorn Road, Silom, Bangrak, Bangkok 10500,
Thailand. Tel: +(662) 6392688 Tel: +(62) 21 78831123 (Office Hrs) Pgr: +(662) 162 222210
BP Indonesia. Kuningan Plaza, South Tower #401, Jl. H.R.Rasuna Said Kav C11-14, Jakarta 12940, Indonesia
Tel: +(62) 21 78831123 (Office Hrs) H/p: +(62) 0818 727 560 +(62) 0816 898927
BP PETCO. 141B Ly Chinh Thang, 3rd Dist. Ho Chi Minh City, Vietnam
Pgr: +(84) 107 082784 Tel: +(84) 8 8467890
BP Taiwan Limited. 7F-C, Hung Kuo Building, 167 Tun Hua North Road, Taipei 105, Taiwan
Pgr: +(886) 95762 8305 Tel: +(886) 2 2715 1280 (Office hrs)
BP Oil China. 21/F, Super Ocean Financial Centre, 2067 West Yan An Road, Shanghai 200335, P.R.China
Tel: +(86) 21 6278 4858
BP Oil Malaysia. Lot 197 II & 197 III, Jalan Pelabuhan Utara, P O Box 62 Port Klang 42000, Selangor, Malaysia
Tel: +(6) 03-3695300 (Office hours) +(6) 03 9870097 H/p: +(6) 011 341994
BP Lubricant Korea. Room 308, Leema Bldg. 146-1, Susong-dong, Chongro-ku, Seoul 110-140, Korea
Tel: +(82) 2 725 8966 H/p: +(82) 11 796 8966
______________________________________________________________________________
BP Unleaded Gasoline
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
BP Unleaded Gasoline
Alternative Names: Quantum 98, Quantum 95 and Quantum 92, BP Mogas 118, Unleaded Motor Gasoline, Super
Unleaded, Extra Unleaded, Super Plus, Unleaded 98, 97 and 92
Application
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor
cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Asia Lubricants Business
BP Tower
21st Storey
396 Alexandra Road
Singapore 0511
_________________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon
numbers predominantly between C4 and C12.
May contain oxygenates. May also contain small quantities of proprietary performance additives.
Hazardous Components
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable,
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed
Gasoline, EINECS No: 289-220-8, CAS No: 86290-81-5 F+,T, N, R12 Extremely flammable, R45 May cause cancer,
R65 Harmful: may cause lung damage if swallowed, R38 Irritating to skin, R67 Vapours may cause drowsiness and
dizziness, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT use water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to
the safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld,
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Motor spirit, Flammable Liquid , Class 3, Item 3(b), Hazard Identification No 33
ADNR/ADN: Motor Spirit, Class 3, Item 3(b),
UN: MOTOR SPIRIT, Flammable liquid, Class 3, Packing Group II, UN Number 1203
IATA/ICAO: Motor spirit, Flammable liquid, Class 3, Packing group II
IMO: MOTOR SPIRIT, Flammable liquid, Class 3.1, Packing group II
EMERGENCY ACTION CODE: 3[Y]E
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Extremely flammable
Carcinogenic category 2
Harmful
Irritant
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
Contains:
Low boiling point naphtha - unspecified
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S2 Keep out of reach of children
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
NATIONAL CONTACT DETAILS AND EMERGENCY CALL NUMBERS
Tata BP Lubricants India Ltd. 75-77 Maker Chambers VI, Nariman Point, Mumbai 21, India
Tel: +91 22 288 0497/8 Fax: +91 22 288 0514
For other Middle East, Central Asia & Indian Sub Continent
BP Middle East, PO Box 1699 Dubai, United Arab Emirates
Tel: +(971) 4 331 8842 Pgr: +(971) 9 394 9520
BP Oil (Thailand) Ltd. 29th floor, Seng Thong Thani Tower, 82 North Sathorn Road, Silom, Bangrak, Bangkok 10500,
Thailand. Tel: +(662) 6392688 Tel: +(62) 21 78831123 (Office Hrs) Pgr: +(662) 162 222210
BP Indonesia. Kuningan Plaza, South Tower #401, Jl. H.R.Rasuna Said Kav C11-14, Jakarta 12940, Indonesia
Tel: +(62) 21 78831123 (Office Hrs) H/p: +(62) 0818 727 560 +(62) 0816 898927
BP PETCO. 141B Ly Chinh Thang, 3rd Dist. Ho Chi Minh City, Vietnam
Pgr: +(84) 107 082784 Tel: +(84) 8 8467890
BP Taiwan Limited. 7F-C, Hung Kuo Building, 167 Tun Hua North Road, Taipei 105, Taiwan
Pgr: +(886) 95762 8305 Tel: +(886) 2 2715 1280 (Office hrs)
BP Oil China. 21/F, Super Ocean Financial Centre, 2067 West Yan An Road, Shanghai 200335, P.R.China
Tel: +(86) 21 6278 4858
BP Oil Malaysia. Lot 197 II & 197 III, Jalan Pelabuhan Utara, P O Box 62 Port Klang 42000, Selangor, Malaysia
Tel: +(6) 03-3695300 (Office hours) +(6) 03 9870097 H/p: +(6) 011 341994
BP Lubricant Korea. Room 308, Leema Bldg. 146-1, Susong-dong, Chongro-ku, Seoul 110-140, Korea
Tel: +(82) 2 725 8966 H/p: +(82) 11 796 8966
______________________________________________________________________________
CONDENSATE
PRODUCT NAME
CONDENSATE
PRODUCT CATEGORY
Condensate
All components of this product are listed on the U.S. TSCA inventory.
The airborne benzene level shall not OSHA Regulation 29 CFR 1910.1028
exceed 1 ppm for an 8-hour workday or
5 ppm STEL
945-0277(MWH001)
EYE CONTACT
If splashed into the eyes, flush with clear water for 15 minutes or until
irritation subsides. If irritation persists, call a physician.
SKIN
In case of skin contact, remove any contaminated clothing and wash skin
with soap and water. Launder or dry-clean clothing before reuse. If
product is injected into or under the skin, or into any part of the body,
regardless of the appearance of the wound or its size, the individual
should be evaluated immediately by a physician as a surgical emergency.
Even though initial symptoms from high pressure injection may be minimal
or absent, early surgical treatment within the first few hours may
significantly reduce the ultimate extent of injury.
INHALATION
If overcome by vapor, immediately move to fresh air and call a physician.
INGESTION
If ingested, DO NOT induce vomiting; call a physician immediately.
EXTREMELY FLAMMABLE
AUTOIGNITION TEMPERATURE
Not determined
HANDLING PRECAUTIONS
This liquid is volatile and gives off invisible vapors. Either the liquid
or vapor may settle in low areas or travel some distance along the ground
or surface to ignition sources where they may ignite or explode.
Keep product away from ignition sources, such as heat, sparks, pilot
lights, static electricity, and open flames.
The following procedures for this type of product are based on the
Use dry chemical, foam or carbon dioxide to extinguish the fire. "Water
may be ineffective", but water should be used to keep fire-exposed
containers cool. If a leak or spill has ignited, use water spray to
disperse the vapors and to protect persons attempting to stop a leak.
Water spray may be used to flush spills away from exposures. Minimize
breathing of gases, vapor, fumes or decomposition products. Use
supplied-air breathing equipment for enclosed or confined spaces or as
otherwise needed.
Prolonged or repeated liquid contact with the skin will dry and defat the
skin, leading to possible irritation and dermatitis.
Benzene can cause anemia and other blood diseases, including leukemia
(cancer of the blood-forming system) after prolonged or repeated exposures
at high concentrations (e.g. 50-500 ppm). It has also caused fetal defects
in tests on laboratory animals.
Limited studies on oils of very active carcinogens have shown that washing
the animals' skin with soap and water between applications greatly reduces
tumor formation.
Product has a low order of acute oral and dermal toxicity, but minute
amounts aspirated into the lungs during ingestion or vomiting may cause
mild to severe pulmonary injury and possibly death.
This product is judged to have an acute oral LD50 (rat) greater than 5
g/kg of body weight, and an acute dermal LD50 (rabbit) greater than 3.16
g/kg of body weight.
F. PHYSICAL DATA
The following data are approximate or typical values and should not be
used for precise design purposes.
BOILING RANGE
Approximately -88 to 230 Deg. C
(-127 to 446 Deg. F)
VAPOR PRESSURE
Approximately 10-400 mm Hg @
20 Deg. C (68 Deg. F)
MOLECULAR WEIGHT
Complex mixture, components vary
pH
Essentially neutral
VISCOSITY
Not determined
G. REACTIVITY
This product is stable and will not react violently with water. Hazardous
polymerization will not occur. Avoid contact with strong oxidants such as
liquid chlorine, concentrated oxygen, sodium hypochlorite, calcium
hypochlorite, etc., as this presents a serious explosion hazard.
H. ENVIRONMENTAL INFORMATION
REPORTABLE QUANTITY (RQ), EPA REGULATION 40 CFR 302 (CERCLA Section 102)
This product is exempt from CERCLA Reporting Requirements. Refer to Clean
Water Act/Oil Pollution Act.
TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA Section
313)
This product may contain:
Approximately 0-5% benzene.
Approximately 0-2% cyclohexane.
Approximately 0-2% n-hexane.
Approximately 0-5% toluene.
Approximately 0-5% xylene.
VENTILATION
Use only with ventilation sufficient to prevent exceeding recommended
exposure limit or buildup of explosive concentrations of vapor in air. No
smoking, flame or other ignition sources.
RESPIRATORY PROTECTION
Use supplied-air respiratory protection in confined or enclosed spaces, if
needed.
PROTECTIVE GLOVES
Use chemical-resistant gloves, if needed, to avoid prolonged or repeated
skin contact.
EYE PROTECTION
Use splash goggles or face shield when eye contact may occur.
Keep containers closed when not in use. Do not store near heat, sparks,
flame or strong oxidants. Adequate ventilation is required in order to
prevent exceeding recommended exposure limit or buildup of explosive
concentrations of vapor in air. No smoking, flame or other ignition
sources.
PERSONAL HYGIENE
Minimize breathing vapor or mist. Avoid prolonged or repeated contact with
skin. Remove contaminated clothing; launder or dry-clean before re-use.
Remove contaminated shoes and thoroughly clean and dry before re-use.
Cleanse skin thoroughly after contact, before breaks and meals, and at end
of work period. Product is readily removed from skin by waterless hand
cleaners followed by washing thoroughly with soap and water.
*PG I - Initial Boiling Point equal to or less than 95 Deg. F (35 Deg. C)
*PG II - Initial Boiling Point greater than 95 Deg. F (35 Deg. C);
Flash Point less than 73 Deg. F (23 Deg. C)
*PG III - Flash Point equal to or greater than 73 Deg. F (23 Deg. C) and
less than 100 Deg. F (37.78 Deg. C)
*PG III - Flash point equal to or greater than 100 Deg. F (37.78 Deg. C)
and equal to or less than 141 Deg. F (60.5 Deg. C) and Transported by air
or marine
(Bulk, greater than 119 gallons, and non-bulk packaging)
OR
Petroleum distillate, n.o.s., Combustible Liquid, UN1268, PG III
Flash Point equal to or greater than 100 Deg. F (37.78 Deg. C) and less
than 200 Deg. F (93.33 Deg. C) and Transported by highway or Rail in Bulk
packaging (greater than 119 gallons)
Non-bulk packaging, less than 119 gallons, not regulated in highway and
rail transportation
DANGER!
EXTREMELY FLAMMABLE
LONG-TERM, REPEATED EXPOSURE MAY CAUSE CANCER, BLOOD AND NERVOUS SYSTEM
DAMAGE
CONTAINS: BENZENE
EXPOSURE LIMIT FOR TOTAL PRODUCT - The Occupational Safety and Health
Administration (OSHA) Permissible Exposure Limit (PEL), the American
Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit
Value (TLV), or Exxon's recommended Occupational Exposure Limit (OEL) is
shown. In some cases where carcinogens are present, a recommended limit
has not been established. For vapors, exposure limits are expressed in
parts per million (ppm) and in milligrams per cubic meter (mg/m3) of vapor
in air. For mists and fumes the limit is given in mg/m3. As noted in the
preface to published values adopted by the ACGIH, TLVs represent
"conditions under which it is believed that nearly all workers may be
repeatedly exposed day after day without adverse effect. Because of wide
variation in individual susceptibility, however, a small percentage of
workers may experience discomfort from some substances at concentrations
at or below the threshold limit; a smaller percentage may be affected more
seriously by aggravation of a preexisting condition or by development of
an occupational illness".
Application
Fuel blending component
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
3. HAZARDS IDENTIFICATION
May cause cancer, classified as a category 2 carcinogen.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Harmful if swallowed - aspiration hazard.
Likely to cause skin irritation.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
May contain hydrogen sulphide.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage, remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable
atmosphere is present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when
no alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved
type and following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see
the comments in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
mists generated will create a flammability or explosion hazard.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
This material contains significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which has been
shown by experimental studies to induce skin cancer.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
This material may accumulate in sediments.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed
waste disposal contractor.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Gas oil, Flammable Liquid Class 3, Item 31(c) Hazard Identification No 30
UN: GAS OIL, Flammable liquid, Class 3, Packing Group III, UN Number 1202
IATA/ICAO: Gas oil, Flammable liquid, Class 3, Packing group III
IMO: GAS OIL, Flammable liquid, Class 3.3, Packing group III
EMERGENCY ACTION CODE: 3[Z]
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Carcinogenic category 2
Harmful
Irritant
Dangerous for the environment
EU Labelling
Symbol:
Skull and crossbones
Dead tree and fish
Indication of danger:
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Cracked gas oil, EINECS No: 265-060-4, 265-062-5, 265-084-5
Substance name: Gas oil - unspecified, EINECS No: 300-227-8
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
Sheet Revisions
Date: Sections revised:
16/09/98 1, 3, 4, 7, 8, 11, 12, 15
17/07/2000 4, 7, 8, 12, 15
Cracked Naphtha
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Cracked Naphtha
Alternative Names: Light catalytic cracked naphtha, Light cat cracked spirit, Heavy catalytic cracked naphtha, Heavy
cat cracked spirit, Light hydrocracked naphtha, Heavy hydrocracked naphtha, Visbreaker cracked naphtha, Combi
Cracked naphtha
Application
Petroleum feedstock or fuel blending component
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Chemical Composition
Complex hydrocarbon substance, one of the following:
Naphtha (petroleum), light catalytic cracked. EINECS No: 265-056-2, CAS No: 64741-55-5
Naphtha (petroleum), heavy catalytic cracked. EINECS No: 265-055-7, CAS No: 64741-54-4
Naphtha (petroleum), light hydrocracked. EINECS No: 265-071-4, CAS No: 64741-69-1
Naphtha (petroleum), light thermal cracked. EINECS No. 265-075-6 CAS No. 64741-74-8,
Naphtha (petroleum), heavy hydrocracked. EINECS No: 265-079-8, CAS No: 64741-78-2
Naphtha (petroleum), heavy thermal cracked. EINECS No: 265-085-0, CAS No: 64741-83-9
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
May contain hydrogen sulphide.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Store and use only in equipment/containers designed for use with this product.
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to
the safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when
no alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved
type and following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see
the comments in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
If vapour, mists or fumes are generated, their concentration in the workplace air should be controlled to the lowest
reasonably practicable level.
Comply with current local occupational exposure limit. Where not established, the following limits are recommended.
Gasoline
ACGIH (USA) : TLV 300 ppm (8hr TWA); 500 ppm (15min STEL)
A3 - Animal Carcinogen
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Hydrogen sulphide
ACGIH (USA): TLV 10 ppm (8 hr TWA); 15ppm (15 min STEL)
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
EU Labelling
Symbol:
Flame
Skull and crossbones
Dead tree and fish
Indication of danger:
EXTREMELY FLAMMABLE
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Low boiling point cat-cracked naphtha, EINECS No: 265-056-2, 265-055-7
Substance name: Low boiling point naphtha - unspecified, EINECS No: 265-071-4, 265-079-8
Substance name: Low boiling point thermally cracked naphtha, EINECS No: 265-075-6, 265-085-0
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
11/09/98 1, 3, 4, 7, 8, 10, 11, 12, 14, 15
17/07/2000 1, 3, 4, 9, 15
Supersedes: 03-20-96
STAR Enterprise
TEXACO
NOTE: Read and understand Material Safety Data Sheet before handling or
disposing of product.
MATERIAL IDENTITY
Telephone Numbers:
Transportation Emergency -Company : (914) 831-3400
CHEMTREC : (800) 424-9300
Health Emergency -Company : (914) 831-3400
General MSDS Assistance : (914) 838-7204
Technical Information -Fuels : (914) 838-7336
-Chemical : (512) 459-6543
-Lubricant/Antifreezes : (800) 782-7852
-Additives : (713) 235-6278
-Solvents : (800) 876-3738
This Material Safety Data Sheet may be used for the following products for
Hazard Communications purposes only; not intended to imply identical
performance/technical specifications:
2. COMPOSITION/INFORMATION ON INGREDIENTS
Seq. Limit
None
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance: Bright and clear liquid (Tax Exempt Diesels - pale red liquid)
WARNING STATEMENT
WARNING!
MAY CAUSE DIZZINESS AND DROWSINESS
CAUSES SKIN IRRITATION
MAY CAUSE EYE IRRITATION
ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE
COMBUSTIBLE LIQUID AND VAPOR
USE ONLY AS A FUEL
MAY CAUSE DELAYED SKIN DAMAGE BASED ON ANIMAL DATA
ATTENTION!
CONTAINS MIDDLE DISTILLATES WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA
HMIS
Health: 1
Flammability: 2
Reactivity: 0
Special: -
NFPA
Health: 1
Flammability: 2
Reactivity: 0
Special: -
EFFECTS OF OVEREXPOSURE
Acute:
Skin:
Other than the potential skin irritation effects noted above, acute (short
term) adverse effects are not expected from brief skin contact; see other
effects, below, and Section 11 for information regarding potential long
term effects.
Inhalation:
Chronic:
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes.
Hold eyelids apart while flushing to rinse entire surface of eye and lids
with water. Get medical attention.
Other Instructions:
Aspiration of this product during induced emesis may result in severe lung
injury. If evacuation of stomach is necessary, use method least likely to
cause aspiration, such as gastric lavage after endotracheal intubation.
Contact a Poison Center for additional treatment information.
5. FIRE-FIGHTING MEASURES
Precautions to be Taken in
Handling: Eye wash and safety shower should be available nearby when this
product is handled or used.
Storage: Store away from heat and open flame. Periods of exposure to high
temperatures should be minimized. Water contamination should be avoided.
Exposure Limit for Total Product: None established for product; refer to
Section 2 for component exposure limits.
Appearance: Bright and clear liquid (Tax Exempt Diesels - pale red liquid)
Other: None
Air [ ]
Water [ ]
Heat [X]
Strong Oxidizers [X]
Others [ ]
None of These [ ]
Comments: None
Dermal: LD50 Similar product > 5.00 ml/kg (rabbit) practically non-toxic
Other:
Necrosis was seen on animals a few days after dermal application of this
product or a component of this product. However, the skin repaired itself
within the observation period.
Remarks
None
Transportation
DOT:
Proper Shipping Name: Fuel Oil
Hazard Class: Combustible liquid (LAND TRANSPORT ONLY-49CFR 173.120(b)(2))
Identification Number: NA 1993
Packing Group: III
Label Required: None
Marine pollutant: Not applicable
IMDG:
Proper Shipping Name: Not evaluated
ICAO:
Proper Shipping Name: Not evaluated
TDG:
Proper Shipping Name: Not evaluated
Federal Regulations:
None
Seq. TPQ RQ
None
None
Seq. RQ
01+ 5000
02+ 10
Other: None.
State Regulations:
Benzene 71-43-2
International Regulations:
Remarks: None
This product is not intended for use in space heaters. Do not use in
agricultural sprays.
Date: 04-15-96
[ ] New
[X] Revised, Supersedes: 03-20-96
26120 DIESEL 2
WARNING STATEMENT
WARNING!
MAY CAUSE DIZZINESS AND DROWSINESS
CAUSES SKIN IRRITATION
MAY CAUSE EYE IRRITATION
ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE
COMBUSTIBLE LIQUID AND VAPOR
USE ONLY AS A FUEL
MAY CAUSE DELAYED SKIN DAMAGE BASED ON ANIMAL DATA
ATTENTION!
CONTAINS MIDDLE DISTILLATES WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA
PRECAUTIONARY MEASURES
-Use only with adequate ventilation.
-Keep away from heat and flame.
-Avoid breathing vapor, mist, or gas.
-Avoid contact with eyes, skin, and clothing.
-Keep container closed.
-Never siphon by mouth.
-Wash thoroughly after handling.
FIRST AID
Eye Contact: Immediately flush eyes with plenty of water for at least 15
minutes. Hold eyelids apart while flushing to rinse entire surface of eye
and lids with water. Get medical attention.
FIRE
In case of fire, use water spray, dry chemical, foam or carbon dioxide.
Water may cause frothing. Use water spray to cool fire-exposed containers.
Pennsylvania Special
Hazardous Substance(s) CAS Number Range in %
HMIS
Health: 1
Flammability: 2
Reactivity: 0
Special: -
NFPA
Health: 1
Flammability: 2
Reactivity: 0
Special: -
Transportation
DOT:
Proper Shipping Name: Fuel Oil
Hazard Class: Combustible liquid (LAND TRANSPORT ONLY-49CFR 173.120(b)(2))
Identification Number: NA 1993
Packing Group: III
Label Required: None
Marine pollutant: Not applicable
TRANSPORTATION EMERGENCY
Company: (914) 831-3400
CHEMTREC: (800) 424-9300
HEALTH EMERGENCY
Company: (914) 831-3400
Application
Fuel for domestic burners; low sulphur industrial process fuel; solvent for certain industrial processes. Only Premium grade
should be used as fuel for flueless space heaters.
For specific application advice see appropriate Technical Data Sheet or consult your SRC representative
Company Identification
Singapore Refining Company Pte. Ltd.
Pulau Merlimau
Jurong
Singapore
Hazardous Components
Petroleum distillate
__________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Flammable
Harmful if swallowed - aspiration hazard.
Will be irritating to the skin.
__________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any pain or
redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing and
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce vomiting;
obtain medical advice.
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate, medical assistance must be
called without delay. If breathing has failed respiration must be assisted, preferably by mouth to mouth method.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of
vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotrachael intubation.
Monitor for cardiac disrhythmias.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Water may be used to cool nearby heat exposed areas/objects/packages. Avoid spraying directly into storage containers
because of the danger of boil-over.
FIRES IN CONFINED SPACES SHOULD BE DEALT WITH BY TRAINED PERSONNEL WEARING APPROVED
BREATHING APPARATUS.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillages contact the appropriate authorities.
Evacuate all non essential personnel from the immediate area.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillage, remove all sources of ignition including road traffic and ensure good ventilation.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage which
may be reasonably anticipated.
Recovery of large spillages should be effected by specialist personnel.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Spilled material may make surfaces slippery.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable atmosphere is
present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover product
from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate government/regulatory
authorities.
__________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Store and use only in equipment/containers designed for use with this product.
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to the
safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere
has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an
oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to effect a
quick rescue.
Handling Precautions
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even at
temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential
flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care
should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from
storage tanks.
Ensure equipment is electrically bonded and earthed to prevent static accumulation.
Product soaked rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to
accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never cut,
weld, solder or braze empty containers.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
Comply with current local occupational exposure limit.
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and preferably
starched after use.
Change heavily contaminated clothing as soon as reasonably practicable; dry clean, launder and preferably starch before re-
use. Wash any contaminated underlying skin with soap and water.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
__________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Typical Values
Grades:Dual Purpose Kerosene
Test Method Units
Physical state liquid
Colour light amber
Odour kerosine-like
Boiling point/range ASTM D 86 °C 150-
300
Kinematic viscosity @ 20°C ASTM D 445 mm /s2 2.0
Density @ 15°C ASTM D 1298 kg/m3 780
Flash point (PMC) ASTM D 93 °C 50
10. STABILITY AND REACTIVITY
Stable at ambient temperatures.
Hazardous polymerisation reactions will not occur.
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Will be irritating to the skin.
Unlikely to cause sensitization by skin contact
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
May have a narcotic effect if high concentrations of vapour are inhaled.
__________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
May be harmful to aquatic organisms.
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
__________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty
packaging and should not be removed.
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed the information contained herein which we received from sources outside SRC .
However, no warranty or representation, expressed or implied is made as to the accuracy or completeness of the data and
information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. SRC shall not be responsible for any damage or
injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any hazards
inherent in the nature of the material
Application
Experimental jet fuel additive.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL
Hazardous Components
Kerosine - unspecified, Xn, R65 Harmful: may cause lung damage if swallowed. (>40%)
2,6 - Di-tert - Butyl - 4 -Methylphenol, Xn R22 Harmful if swallowed, R36 Irritating to eyes. (<20%)
N, N' - disalicylidene - 1,2 - diaminopropane, Xn R22 Harmful if swallowed, R36/38 Irritating to eyes and skin., R43 May
cause sensitisation by skin contact, R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment (<10%)
__________________________________________________________________________________
3. HAZARDS IDENTIFICATION
This product is supplied for trial/research purposes only.
The hazard assessment has not been completed, the product should therefore be handled with care and exposure
kept to a minimum.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing and
wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce vomiting;
obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If symptoms
persist obtain medical advice.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of
vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation.
Monitor for cardiac dysrhythmias.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
In the event of spillage, remove all sources of ignition and ensure good ventilation.
Evacuate all non essential personnel from the immediate area.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Contain and recover spilled material using sand or other suitable inert absorbent material.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Spilled material may make surfaces slippery.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of large spills contact the appropriate authorities.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover product
from the surface. Protect environmentally sensitive areas and water supplies.
__________________________________________________________________________________
7. HANDLING AND STORAGE
Handling Precautions
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Avoid skin contact.
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or fumes
which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the workplace air
should be controlled to the lowest reasonably practicable level.
Good working practices, high standards of personal hygiene and plant cleanliness must be maintained at all times.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Fire Prevention
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to
accumulate. Dispose of safely immediately after use.
Storage Conditions
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Store and use only in equipment/containers designed for use with this product.
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to the
safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere
has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an
oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to effect a
quick rescue.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
There is no appropriate occupational exposure limit for this material.
If vapour, mists or fumes are generated, their concentration in the workplace air should be controlled to the lowest
reasonably practicable level.
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and preferably
starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
__________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Typical Values
Odour kerosine-like
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
May cause sensitization by skin contact.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
__________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
__________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Dispose of product and container carefully and responsibly. Do not dispose of near ponds, ditches, down drains or onto
soil.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of empty
packaging and should not be removed.
__________________________________________________________________________________
14. TRANSPORT INFORMATION
Not classified as hazardous for transport (ADR, RID, UN , IMO, IATA/ICAO).
__________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Harmful
Irritant
EU Labelling
Symbol: St. Andrew's Cross,
Indication of danger: HARMFUL,
Risk ( R ) Phrases:
R65 Harmful: may cause lung damage if swallowed.
R43 May cause sensitisation by skin contact
R36 Irritating to eyes.
Safety ( S ) Phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24 Avoid contact with skin
S28 After contact with skin wash immediately with plenty of soap and water
S43 - In case of fire use foam or dry powder. Never use water jets
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall not be responsible
for any damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or
from any hazards inherent in the nature of the material.
Application
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor
cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Chemical Composition
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon
numbers predominantly between C4 and C12.
May contain oxygenates. May also contain small quantities of proprietary performance additives.
Hazardous Components
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable,
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed
Gasoline, EINECS No: 289-220-8, CAS No: 86290-81-5 F+,T, N, R12 Extremely flammable, R45 May cause cancer,
R65 Harmful: may cause lung damage if swallowed, R38 Irritating to skin, R67 Vapours may cause drowsiness and
dizziness, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT use water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: 3
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld,
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
When cleaning storage tanks, sludges which may be contaminated with lead must be disposed of via a licensed waste
disposal contractor, in accordance with local regulations.
_________________________________________________________________________________
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
Contains:
Low boiling point naphtha - unspecified
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S2 Keep out of reach of children
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
08/5/98 2, 7, 8, 12, 15
02/11/98 1
17/07/2000 2, 3, 4, 7, 8, 9, 13, 15
Application
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor
cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon
numbers predominantly between C4 and C12.
May contain oxygenates. May also contain small quantities of proprietary performance additives.
Hazardous Components
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable,
R48/23/24/25 Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with
skin and if swallowed
Gasoline, EINECS No: 289-220-8, CAS No: 86290-81-5 F+,T, N, R12 Extremely flammable, R45 May cause cancer,
R65 Harmful: may cause lung damage if swallowed, R38 Irritating to skin, R67 Vapours may cause drowsiness and
dizziness, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: 3
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld,
solder or braze empty containers.
Materials contaminated with product should be treated as highly flammable. Disposal should be in accordance with
local regulations.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Motor spirit, Flammable Liquid , Class 3, Item 3(b), Hazard Identification No 33
ADNR/ADN: Motor Spirit, Class 3, Item 3(b),
UN: MOTOR SPIRIT, Flammable liquid, Class 3, Packing Group II, UN Number 1203
EU Labelling
Symbol:
Flame
Skull and crossbones
Indication of danger:
EXTREMELY FLAMMABLE
Contains:
Low boiling point naphtha - unspecified
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
Safety ( S ) Phrases:
S2 Keep out of reach of children
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
07/05/98 1, 2, 7, 8, 10, 12, 15
02/11/98 1
17/07/2000 2, 3, 4, 8, 9, 15
Hydrocarbon Condensate
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Hydrocarbon Condensate
Alternative Names: Natural gas condensate
Application
Refinery feedstock
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
May contain hydrogen sulphide.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when
no alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved
type and following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see
the comments in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Gasoline
ACGIH (USA) : TLV 300 ppm (8hr TWA); 500 ppm (15min STEL)
A3 - Animal Carcinogen
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Hydrogen sulphide
ACGIH (USA): TLV 10 ppm (8 hr TWA); 15ppm (15 min STEL)
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
EU Labelling
Symbol:
Flame
Skull and crossbones
Dead tree and fish
Indication of danger:
EXTREMELY FLAMMABLE
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Natural gas condensates (petroleum), EINECS No: 265-047-3
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
17/09/98 1, 3, 4, 7, 8, 10, 11, 12, 14, 15
17/07/2000 3, 4, 9, 15
Application
Refinery stream
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
3. HAZARDS IDENTIFICATION
Harmful if swallowed - aspiration hazard.
This material may contain significant quantities of polycyclic aromatic hydrocarbons (PCAs), some of which have been
shown by experimental studies to induce skin cancer.
Repeated exposure may cause skin dryness or cracking.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If inhalation of mists, fumes or vapour causes irritation to the nose or throat, or coughing, remove to fresh air. If
symptoms persist obtain medical advice.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage, remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable
atmosphere is present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
Will present a flammability hazard if heated above flash point but bulk liquids at normal storage temperatures will
present virtually no fire hazard. If fuel contacts hot surfaces, or leaks from high pressure fuel pipes, the vapour and/or
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure may lead to
dermatitis.
As with all such products containing potentially harmful levels of PCAs, prolonged or repeated skin contact may
eventually result in dermatitis or more serious irreversible skin disorders including cancer.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
This material may accumulate in sediments.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of by incineration or other suitable means under conditions approved by the local authority or via a licensed
waste disposal contractor.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
EU Labelling
Symbol:
St. Andrew's Cross
Dead tree and fish
Indication of danger:
HARMFUL
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R40 Possible risks of irreversible effects
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S24 Avoid contact with skin
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S36/37 Wear suitable protective clothing and gloves
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Distillates (petroleum), light hydrocracked, EINECS No: 265-078-2
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
11/09/98 1, 3, 12, 15
17/07/2000 3, 4, 15
Jet A-1
Jet A-1 containing FSII
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Jet A-1
Jet A-1 containing FSII
Alternative Names: Aviation Kerosine, Aviation Turbine Fuel, ATK
Jet A-1 synonyms: Jet A, AVTUR, F-35,
Jet A-1 containing FSII synonyms: AVTUR/FSII, JP-8, F-34,
Application
Jet fuel
do not use for other purposes
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL
Jet A-1 containing FSII - Contains small amounts of diethyleneglycol monomethyl ether
(DEGME
2-(2-methoxyethoxy)ethanol ) as a fuel icing inhibitor.
Hazardous Components
Kerosine - unspecified
Xn R10 Flammable
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Flammable
Harmful if swallowed - aspiration hazard.
Likely to cause skin irritation.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water
ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs
wash out thoroughly with water.
Except as a deliberate act
the ingestion of large amounts of product is unlikely. If it should occur
do not induce vomiting
obtain medical advice.
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate
medical assistance must be called without delay. If breathing has failed respiration must be assisted
preferably by mouth to mouth method.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents
and can cause severe and potentially fatal chemical pneumonitis
which will require urgent treatment. Because of the risk of aspiration
induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after
endotracheal intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam
dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity
Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage
remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection
section 8
of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems
in basements etc.).
If spillage has occurred in a confined space
ensure adequate ventilation and check that a safe
breathable atmosphere is present before entry.
In the case of spillage on water
prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect
environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Avoid
as far as reasonably practicable
inhalation of vapour
mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat
drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling
discharge or ullaging) and when sampling
there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags
paper or material used to absorb spillages
represent a fire hazard
and should not be allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut
weld
solder or braze empty containers.
_________________________________________________________________________________
Exposure Limits
There is no appropriate occupational exposure limit for this material.
If vapour
mists or fumes are generated
their concentration in the workplace air should be controlled to the lowest reasonably practicable level.
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely
wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained
overalls should be dry-cleaned
laundered and preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour
mist or fume may be anticipated
then suitable approved respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses
though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs
eg. during vomiting.
Inhalation
May cause irritation to eyes
nose and throat due to exposure to vapour
mists or fumes.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Dispose of product and container carefully and responsibly. Do not dispose of near ponds
ditches
down drains or onto soil.
At sea
used or unwanted product should be stored for eventual discharge into port approved waste oil disposal facilities.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Kerosene
Flammable Liquid
Class 3
Item 31 (c)
Hazard Identification No 30
UN: KEROSENE
Flammable liquid
Class 3
Packing Group III
UN Number 1223
IATA/ICAO: Kerosene
Flammable liquid
Class 3
Packing Group III
IMO: KEROSENE
Flammable liquid
Class 3.3
Packing Group III
EMERGENCY ACTION CODE: Flammable liquid
3[Y]
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Flammable
Harmful
Irritant
EU Labelling
Symbol:
St. Andrew's Cross
Indication of danger:
HARMFUL
Contains:
Kerosine - unspecified
Risk ( R ) Phrases:
R10 Flammable
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
Safety ( S ) Phrases:
S24 Avoid contact with skin
S23 Do not breathe vapour
S43 In case of fire
use foam/dry powder/CO2. Never use water jets.
S62 If swallowed
do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission
recommendation or authorization given or implied to practise any patented invention without a valid licence. The BP
Amoco Group shall not be responsible for any damage or injury resulting from abnormal use of the material
from any failure to adhere to recommendations
or from any hazards inherent in the nature of the material.
______________________________________________________________________________
Application
Fuel for domestic burners; low sulphur industrial process fuel; solvent for certain industrial processes. Premium grade
only can be used as fuel for flueless space heaters.
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Hazardous Components
Kerosine - unspecified, Xn R10 Flammable, R38 Irritating to skin, R65 Harmful: may cause lung damage if swallowed.
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Flammable
Harmful if swallowed - aspiration hazard.
Likely to cause skin irritation.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate, medical assistance
must be called without delay. If breathing has failed respiration must be assisted, preferably by mouth to mouth
method.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging
and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
German WGK Classification: 2
_________________________________________________________________________________
EU Labelling
Symbol:
St. Andrew's Cross
Indication of danger:
HARMFUL
Contains:
Kerosine - unspecified
Risk ( R ) Phrases:
R10 Flammable
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
Safety ( S ) Phrases:
S2 Keep out of reach of children
S24 Avoid contact with skin
S23 Do not breathe vapour
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
08/05/98 2, 12, 15
02/11/98 1
17/07/2000 2, 15
Application
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor cleaning
agent.
Company Identification
BP Oil UK Limited,
Witan Gate House
500-600 Witan Gate
Central Milton Keynes
MK9 1ES
Hazardous Components
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable, R48/23/24/25
Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if
swallowed
Gasoline. EINECS No: 289-220-8, CAS No: 86290-81-5 F+, T, N, R12 Extremely flammable, R45 May cause cancer,
R38 Irritating to skin, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
R65 Harmful: may cause lung damage if swallowed. (>90%)
__________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including
leukaemia.
Harmful if swallowed - aspiration hazard.
__________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any pain
or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing and
wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash skin
with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce vomiting;
obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat,
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of
vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation.
Monitor for cardiac dysrhythmias.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover product
from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities. If spillage occurs call the Environment Agency Emergency
Hotline on 0800 807060 (24 hours a day, 7 days a week).
__________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Store and use only in equipment/containers designed for use with this product.
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to the
safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere
has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an
oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to effect a
quick rescue.
Special health precautions must be taken during cleaning or maintenance operations on storage tanks which may have
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or fumes
which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the workplace air
should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated
will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to
accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never cut,
weld, solder or braze empty containers.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
If vapour, mists or fumes are generated, their concentration in the workplace air should be controlled to the lowest
reasonably practicable level.
Comply with current local occupational exposure limit. Where not established, the following limits are recommended.
Gasoline
ACGIH (USA) :
TLV 300 ppm, 890 mg/m3 (8hr TWA)
500 ppm, 1480 mg/m3 (15min STEL)
A3 - Animal Carcinogen
Benzene
UK publication EH40 (Occupational Exposure Limits):
Maximum Exposure Limit Long-term exposure limit (8-hr TWA) 5ppm, 16mg/m3
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and preferably
starched after use.
Respiratory Protection
If operations are such that significant exposure to vapour, mist or fume may be anticipated, then suitable approved
respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
__________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Note: National specifications may apply.
Typical Values
Grades:Leaded 4 Star petrol
Test Method Units
Physical state liquid
Colour light amber
Odour gasoline-like
Density @ 15°C ASTM D 1298 kg/m3 695 - 790
Vapour pressure @ 37.8°C ASTM D 323 kPa 45 - 115
(100°F)
Vapour density rel. to air ASTM 3-4
D2463/D2421
Explosion limits % 0.6 - 8.0
Flash point (COC) ASTM D 92 °C <-40
Boiling point/range ASTM D 86 °C 25 - 220
Partition Coefficient (n- Log10Pow >3
octanol/water)
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very high
concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms. May cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
EU Labelling
Symbol: Flame, Skull and crossbones
Indication of danger: EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
Safety ( S ) Phrases:
S2 Keep out of reach of children
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
hazards inherent in the nature of the material.
Supersedes: 03-20-96
STAR Enterprise
TEXACO
NOTE: Read and understand Material Safety Data Sheet before handling or
disposing of product.
MATERIAL IDENTITY
Telephone Numbers:
Transportation Emergency -Company : (914) 831-3400
CHEMTREC : (800) 424-9300
Health Emergency -Company : (914) 831-3400
General MSDS Assistance : (914) 838-7204
Technical Information -Fuels : (914) 838-7336
-Chemical : (512) 459-6543
-Lubricant/Antifreezes : (800) 782-7852
-Additives : (713) 235-6278
-Solvents : (800) 876-3738
2. COMPOSITION/INFORMATION ON INGREDIENTS
REGULATORY INFORMATION.
Seq. Limit
None
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance: Liquid
WARNING STATEMENT
WARNING!
MAY CAUSE DIZZINESS AND DROWSINESS
CAUSES SKIN IRRITATION
MAY CAUSE EYE IRRITATION
ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE
COMBUSTIBLE LIQUID AND VAPOR
USE ONLY AS A FUEL
MAY CAUSE DELAYED SKIN DAMAGE BASED ON ANIMAL DATA
ATTENTION!
CONTAINS MIDDLE DISTILLATES WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA
HMIS
Health: 1
Flammability: 2
Reactivity: 0
Special: -
NFPA
Health: 1
Flammability: 2
Reactivity: 0
Special: -
EFFECTS OF OVEREXPOSURE
Acute:
Skin:
Other than the potential skin irritation effects noted above, acute (short
term) adverse effects are not expected from brief skin contact; see other
effects, below, and Section 11 for information regarding potential long
term effects.
Inhalation:
Chronic:
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes.
Hold eyelids apart while flushing to rinse entire surface of eye and lids
with water. Get medical attention.
shower, flush skin thoroughly with large amounts of running water for at
least 15 minutes. Do not attempt to neutralize with chemical agents. Get
medical attention immediately. Discard or decontaminate clothing and shoes
before reuse.
Other Instructions:
Aspiration of this product during induced emesis may result in severe lung
injury. If evacuation of stomach is necessary, use method least likely to
cause aspiration, such as gastric lavage after endotracheal intubation.
Contact a Poison Center for additional treatment information.
5. FIRE-FIGHTING MEASURES
Precautions to be Taken in
Handling: Eye wash and safety shower should be available nearby when this
product is handled or used.
Storage: Store away from heat and open flame. Periods of exposure to high
temperatures should be minimized. Water contamination should be avoided.
Exposure Limit for Total Product: None established for product; refer to
Section 2 for component exposure limits.
Appearance: Liquid
Other: None
Comments: None
Dermal: LD50 Similar product > 5.00 ml/kg (rabbit) practically non-toxic
Eyes:
(Draize) Believed to be > 15.00 - 25.00/110 (rabbit) slightly irritating
Other:
Necrosis was seen on animals a few days after dermal application of this
product or a component of this product. However, the skin repaired itself
within the observation period.
Remarks
None
Transportation
DOT:
Proper Shipping Name: Fuel Oil
Hazard Class: Combustible liquid (LAND TRANSPORT ONLY-49CFR 173.120(b)(2))
Identification Number: NA 1993
Packing Group: III
Label Required: None
Marine pollutant: Not applicable
IMDG:
Proper Shipping Name: Not evaluated
ICAO:
Proper Shipping Name: Not evaluated
TDG:
Proper Shipping Name: Not evaluated
Federal Regulations:
None
Seq. TPQ RQ
None
N/A [ ]
None
Seq. RQ
01+ 5000
02+ 10
Other: None.
State Regulations:
Benzene 71-43-2
International Regulations:
This product is not intended for use in space heaters. Do not use in
agricultural sprays.
USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO
MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED
HEREIN.
Date: 04-15-96
[ ] New
[X] Revised, Supersedes: 03-20-96
WARNING STATEMENT
WARNING!
MAY CAUSE DIZZINESS AND DROWSINESS
CAUSES SKIN IRRITATION
MAY CAUSE EYE IRRITATION
ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE
COMBUSTIBLE LIQUID AND VAPOR
USE ONLY AS A FUEL
MAY CAUSE DELAYED SKIN DAMAGE BASED ON ANIMAL DATA
ATTENTION!
CONTAINS MIDDLE DISTILLATES WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA
PRECAUTIONARY MEASURES
-Use only with adequate ventilation.
-Keep away from heat and flame.
-Avoid breathing vapor, mist, or gas.
-Avoid contact with eyes, skin, and clothing.
-Keep container closed.
-Never siphon by mouth.
-Wash thoroughly after handling.
FIRST AID
Eye Contact: Immediately flush eyes with plenty of water for at least 15
minutes. Hold eyelids apart while flushing to rinse entire surface of eye
and lids with water. Get medical attention.
FIRE
In case of fire, use water spray, dry chemical, foam or carbon dioxide.
Water may cause frothing. Use water spray to cool fire-exposed containers.
Pennsylvania Special
Hazardous Substance(s) CAS Number Range in %
HMIS
Health: 1
Flammability: 2
Reactivity: 0
Special: -
NFPA
Health: 1
Flammability: 2
Reactivity: 0
Special: -
Transportation
DOT:
Proper Shipping Name: Fuel Oil
Hazard Class: Combustible liquid (LAND TRANSPORT ONLY-49CFR 173.120(b)(2))
Identification Number: NA 1993
Packing Group: III
Label Required: None
Marine pollutant: Not applicable
TRANSPORTATION EMERGENCY
Company: (914) 831-3400
CHEMTREC: (800) 424-9300
HEALTH EMERGENCY
Company: (914) 831-3400
Mogas 90 and 97
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF
THE COMPANY/UNDERTAKING
Identification of substance/preparation
Mogas 90 and 97
Application
Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a solvent nor cleaning
agent.
Company Identification
BP Middle East Limited
PO Box 92
Mina Al Fahal 116
Sultanate of Oman
Tel: 561801
Fax: 561283
Hazardous Components
Benzene, EINECS No. 200-753-7, CAS No. 71-43-2 F, T, R45 May cause cancer, R11 Highly flammable, R48/23/24/25
Toxic: Danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if
swallowed
Gasoline. EINECS No: 289-220-8, CAS No: 86290-81-5 F+, T, R12 Extremely flammable, R45 May cause cancer, R38
Irritating to skin, R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment,
R65 Harmful: may cause lung damage if swallowed.
Note: R65 is expected to be introduced with the 22nd Adaptation to Technical Progress of the Dangerous Substances
Directive.
__________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases, including
leukaemia.
Harmful if swallowed - aspiration hazard.
__________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any pain
or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing and
wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash skin
with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce vomiting;
obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat,
remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of
vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotrachael intubation.
Monitor for cardiac dysrhythmias.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT use water jets.
FIRES IN CONFINED SPACES SHOULD BE DEALT WITH BY TRAINED PERSONNEL WEARING APPROVED
BREATHING APPARATUS.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover product
from the surface. Protect environmentally sensitive areas and water supplies.
In the event of spillages contact the appropriate authorities.
Regular surveillance on the location of the spillage should be maintained.
__________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Store and use only in equipment/containers designed for use with this product.
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to the
safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere
has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an
oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to effect a
quick rescue.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or fumes
which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the workplace air
should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and preferably
starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
Typical Values
Grades:Leaded Motor Spirit
template
Test Method Units
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very high
concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Harmful to aquatic organisms. May cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
EU Labelling
Symbol: Flame, Skull and crossbones
Indication of danger: EXTREMELY FLAMMABLE
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R38 Irritating to skin
also
R65 Harmful: may cause lung damage if swallowed.
Note: R65 is expected to be introduced with the 22nd Adaptation to Technical Progress of the Dangerous Substances
Directive.
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breath spray
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-On-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
hazards inherent in the nature of the material.
MTBE
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
MTBE
Alternative Names: methyl-tert-butyl ether, 2-methoxy-propyl propane, tert-butyl-methyl ether
Application
Gasoline octane enhancer
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
3. HAZARDS IDENTIFICATION
Highly flammable
Will be irritating to the skin.
Harmful if swallowed - aspiration hazard.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash off immediately with soap and water. Change heavily contaminated clothing and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use alcohol resistant foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
This product is miscible with water, but in the case of major spillage prompt action may enable recovery.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Do not siphon product by mouth.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Will be irritating to the skin.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Unlikely to be harmful to aquatic organisms.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Incineration may be carried out under controlled conditions provided that local regulations for emissions are met.
Dispose of product and container carefully and responsibly. Do not dispose of near ponds, ditches, down drains or
onto soil.
Empty packages may contain some remaining product. Hazard warning labels are a guide to the safe handling of
empty packaging and should not be removed.
Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Never weld,
solder or braze empty containers.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID - Methyl tert-butyl ether, Flammable Liquid, Class 3, Item 3(b) Hazard identification No33
UN - Methyl tert-butyl ether, Class 3, Pack Gp II, UN Number 2398
IMO - Methyl tert-butyl ether, Class 3.1, Flammable Liquid, Pack Gp II
IATA/ICAO - Methyl tert-butyl ether, Flammable Liquid , Class 3, Pack Gp II,
EMERGENCY ACTION CODE: 3(Y)E
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Highly flammable
Harmful
Irritant
EU Labelling
Symbol:
Flame
St. Andrew's Cross
Indication of danger:
HIGHLY FLAMMABLE
HARMFUL
Risk ( R ) Phrases:
R11 Highly flammable
R65 Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
Safety ( S ) Phrases:
S16 Keep away from sources of ignition - No smoking
S24/25 Avoid contact with skin and eyes.
S28 After contact with skin, wash immediately with plenty of water.
S23 Do not breathe vapour
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: Substance name
Substance name: tert-butyl methyl ether (MTBE)
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
17/07/2000 4, 5, 7, 8, 10, 15
Mobil
100000-00
SUPPLIER:
MOBIL OIL CORP.
NORTH AMERICA MARKETING AND REFINING
3225 GALLOWS RD.
FAIRFAX, VA 22037
2. COMPOSITION/INFORMATION ON INGREDIENTS
3. HAZARDS IDENTIFICATION
present, see MSDB toxicology section. Gas is highly toxic and is absorbed
through the mucous membranes of the respiratory tract causing respiratory
paralysis and suffocation. Symptoms of overexposure include headache,
fatigue, insomnia, irritability and gastrointestinal problems. Loss of
sense of smell at 100 ppm, drowsiness, loss of consciousness, respiratory
failure or death can result from exposure above 100 ppm. Gasoline vapors
when administered in high concentrations over a prolonged period of time,
cause kidney damage and kidney cancer in rats and liver cancer in mice
(see MSDB toxicology section). Skin irritation. Respiratory irritation,
dizziness, nausea, loss of consciousness. Prolonged repeated skin contact
with low viscosity materials may defat the skin resulting in possible
irritation and dermatitis.
SKIN CONTACT: Wash contact areas with soap and water. Remove contaminated
clothing. Launder contaminated clothing before reuse.
5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog.
HANDLING: Trace amounts of H2S may be present. Keep face clear of tank
and/or tank car openings. Avoid contact with skin. Avoid inhalation of
vapors or mists. Use in well ventilated area away from all ignition
sources. Avoid sparking conditions. Ground and bond all transfer
equipment.
STORAGE: Drums must be grounded and bonded and equipped with self-closing
valves, pressure vacuum bungs and flame arresters. Store away from all
ignition sources in a cool area equipped with an automatic sprinkling
system. Outside or detached storage preferred. Storage containers should
be grounded and bonded.
NATURAL GASOLINE
(68425-31-0)
MOBIL 300 890
ACGIH 300 890 500 1480
BENZENE (71-43-2)
OSHA 1 5
Skin ACGIH 0.5 1.6 2.5 8
Typical physical properties are given below. Consult Product Data Sheet
for specific details.
APPEARANCE: Liquid
COLOR: Clear
ODOR: Hydrocarbon
ODOR THRESHOLD-ppm: NE
pH: NA
BOILING POINT C(F): > 4(40)
MELTING POINT C(F): NE
FLASH POINT C(F): -40(-40) (ASTM D-56)
FLAMMABILITY: NE
AUTO FLAMMABILITY: NE
EXPLOSIVE PROPERTIES: NA
OXIDIZING PROPERTIES: NA
VAPOR PRESSURE-mmHg 20 C: < 1201.0
NA=NOT APPLICABLE
NE=NOT ESTABLISHED
D=DECOMPOSES
---ACUTE TOXICOLOGY---
ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000
mg/kg). ---Based on testing of similar products and/or the components.
greater but less than 5). ---Based on testing of similar products and/or
the components.
USA DOT:
SHIPPING NAME: Gasoline
IMO:
HAZARD CLASS & DIV: 3.1
UN NUMBER: 1203
PACKING GROUP: PG II
SHIPPING NAME: Gasoline
LABEL(s): Flammable Liquid
MARPOL III STATUS: NA
ICAO/IATA:
HAZARD CLASS & DIV: 3
ID/UN Number: 1203
PACKING GROUP: PG II
SHIPPING NAME: Gasoline
SUBSIDIARY RISK: NA
LABEL(s): Flammable Liquid
Governmental Inventory Status: All components comply with TSCA and DSL.
U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This
product contains no "EXTREMELY HAZARDOUS SUBSTANCES".
CONTAINS GASOLINE
WARNING!
LONG-TERM EXPOSURE TO GASOLINE VAPOR HAS CAUSED KIDNEY AND LIVER CANCER IN
LABORATORY ANIMALS.
Keep away from heat, sparks, and flame. Avoid prolonged breathing of
vapor. Keep container closed. Use with adequate ventilation. Not to be
used as a solvent or skin cleaning agent. Never siphon by mouth. Avoid
contact with eyes and skin. Misuse of gasoline may cause serious injury or
illness.
This warning is given to comply with California Health and Safety Code
25249.6 and does not constitute an admission or a waiver of rights. This
product contains a chemical known to the State of California to cause
cancer. Refer to product Material Safety Data Bulletin for further safety
and health information.
For Internal Use Only: MHC: 1* 1* 2* 1* 2*, MPPEC: CF, REQ: HOUSTON GAS
LIQUIDS, SAFE USE: S
Mobil
Introduction
The MSDB meets all of the requirements of the OSHA Hazard Communication
Standard (29 CFR 1910.1200). As an additional customer service, we provide
an MSDB for our non-hazardous products as well.
Mobil - Exposure values utilized by Mobil for its facilities are displayed
if they are = or < the corresponding ACGIH TLV.
ppm - Parts of gas or vapor per million parts of air. Common unit of
measure for exposure limits for gases or vapors.
The less familiar terms used in this section are explained below. Some
properties are not addressed in the MSDB if they are not applicable (NA),
or if they have not been established for (NE), a given product.
Term Solubility
Negligible 0.0 - 0.1%
Slight 0.1 - 1.0%
Moderate 1.0 - 10%
Appreciable >10%
Complete 100%
FDA/USDA - If the product meets FDA criteria, or has a USDA approval, the
specific criteria and approval rating will be shown.
ACGIH A1- List of materials which, in the opinion of ACGIH, are confirmed
to cause cancer in humans.
TSCA 5a2 - List of materials covered by an EPA Significant New Use Rule
under TSCA Section 5(a)(2).
IL RTK - The Toxic Substance List developed pursuant to the Illinois Toxic
Substance Disclosure to Employees Act.
NJ RTK - Three lists developed pursuant to the New Jersey Worker and
Community Right-to-Know Act.
Primary Codes:
A - Minimal protective equipment for a given facility's operations
(determined locally).
B - Code A + eye protection.
C - Code A + skin protection
D - Code A + eye and skin protection.
E - Protection from severe eye and skin hazard needed.
X - Special protective equipment needed.
Ancillary Codes:
P - Particulate respiratory protection.
V - Vapor respirator needed.
H - Noxious vapors released when heated.
F - Flash point <100 Deg. F (37.8 Deg. C)
EMERGENCY OVERVIEW:
-------------------
Clear Liquid With Hydrocarbon Odor. May Be Dyed For Identification.
Danger! Harmful or Fatal If Swallowed. Aspiration Hazard If
Swallowed--Can Enter Lungs and Cause Damage. May Be Irritating To the
Eyes and Respiratory Tract. Causes Skin Irritation. Vapors May Be
Harmful. Possible Cancer Hazard - Contains Material Which May Cause
Cancer Based On Animal Data. Combustible Liquid & Vapor.
EYE:
----
Exposure to vapors, fumes or mists may cause irritation.
INHALATION:
-----------
May cause respiratory tract irritation. Exposure may cause central
nervous system symptoms similar to those listed under "Ingestion"
(see Ingestion section). Degenerative changes in the liver, kidneys
and bone marrow may occur with prolonged, high concentrations.
Repeated or prolonged exposures may cause behavioral changes.
INGESTION:
----------
Aspiration into lungs may cause pneumonitis. May cause
gastrointestinal disturbances. Symptoms may include irritation,
nausea, vomiting and diarrhea. May cause harmful central nervous
system effects. Effects may include excitation, euphoria, headache,
dizziness, drowsiness, blurred vision, fatigue, tremors, convulsions,
loss of consciousness, coma, respiratory arrest and death.
SKIN:
-----
Remove contaminated clothing immediately. Wash area of contact
thoroughly with soap and water. Get medical attention if irritation
persists. High pressure skin injections are serious medical
emergencies. Thermal burns require immediate medical attention. Get
immediate medical attention.
EYE:
----
Flush immediately with large amounts of water for at least 15
minutes. Eyelids should be held away from the eyeball to ensure
thorough rinsing. Get medical attention if irritation persists.
Thermal burns require immediate medical attention.
INHALATION:
-----------
Remove affected person from source of exposure. If not breathing,
ensure clear airway and institute cardiopulmonary resuscitation (CPR).
If breathing is difficult, administer oxygen if available. After
administration of oxygen, continue to monitor closely. Get medical
attention.
INGESTION:
----------
Do not induce vomiting because of danger of aspirating liquid into
lungs. Get immediate medical attention. If spontaneous vomiting
occurs, monitor for breathing difficulty.
NOTES TO PHYSICIAN:
-------------------
In case of ingestion, gastric lavage with activated charcoal can be
used promptly to prevent absorption. Consideration should be given to
the use of an endotracheal tube, to prevent aspiration. Individuals
intoxicated by Diesel Fuel No. 2 should be hospitalized immediately,
with acute and continuing attention to neurologic and cardiopulmonary
function. Positive pressure ventilation may be necessary. After the
initial episode, individuals should be followed for changes in blood
variables and the delayed appearance of pulmonary edema and chemical
pneumonitis. Such patients should be followed for several days or
weeks for delayed effects, including bone marrow toxicity, hepatic
and renal impairment. Individuals with chronic pulmonary disease will
be more seriously impaired, and recovery from inhalation exposure may
be complicated. In case of skin injection, prompt debridement of the
wound is necessary to minimize necrosis and tissue loss.
Group Number: 33
CHRIS Code: OTD
HANDLING:
---------
Use non-sparking tools. Ground lines and equipment used during
transfer to reduce the possibility of static spark-initiated fire or
explosion.
STORAGE:
--------
Store in tightly closed containers in cool, dry, isolated,
well-ventilated area away from heat, sources of ignition and
incompatibles.
ENGINEERING CONTROLS:
---------------------
Ventilation may be used to control or reduce airborne concentrations.
STABILITY/INCOMPATIBILITY:
--------------------------
Stable. Avoid contact with strong oxidizers.
OTHER:
------
An extensive profile which characterizes adverse health effects
information for this material has been prepared by the Agency for
Toxic Substances Disease Registry (ATSDR). Individuals interested in
a summary of the toxicology of this material should reference this
document. This profile can be obtained from the National Technical
Information Services (NTIS).
NOTIFICATION:
-------------
Any spill or release, or substantial threat of release, of this
material to navigable water (virtually any surface water) sufficient
to cause a visible sheen upon the water must be reported immediately
to the National Response Center (800/424-8802), as required by U.S.
Federal Law. Failure to report may result in substantial civil and
criminal penalties. Also contact the Coast Guard and appropriate
state and local regulatory agencies.
2. Composition/information on ingredients
Chemical name* CAS No. % EC Number Symbol R-Phrases
1) NAPHTHA (PETROLEUM), LIGHT STEAM-CRACKED 64742-83-2 100 265-187-5 F, T R11, R22, R45, R65
Contains:
3. Hazards identification
Physical/chemical Hazards : Highly flammable.
Human health hazards : Inhalation of vapour/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness, and
nausea, and may lead to unconsciousness or death. Aspiration of this material into the lungs may cause chemical pneumonia
and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this material.
Causes eye irritation. Causes skin irritation. CANCER HAZARD.
CAN CAUSE CANCER. Harmful if absorbed through the skin. Repeated or prolonged exposure to the substance can produce
blood disorders.
Effects and symptoms
Eyes : Causes eye irritation.
Skin : Causes skin irritation. CANCER HAZARD.
CAN CAUSE CANCER. Repeated or prolonged exposure to the substance can produce blood disorders.
Inhalation : Inhalation of vapour/aerosol concentrations above the recommended exposure limits causes headaches, drowsiness, and
nausea, and may lead to unconsciousness or death. Causes respiratory tract irritation. CANCER HAZARD.
CAN CAUSE CANCER. Repeated or prolonged exposure to the substance can produce blood disorders.
Ingestion : Aspiration of this material into the lungs may cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur
while vomiting after ingestion of this material.
Ingestion may cause gastrointestinal irritation and diarrhoea. CANCER HAZARD.
CAN CAUSE CANCER. Repeated or prolonged exposure to the substance can produce blood disorders.
4. First-aid measures
First-Aid measures
Eye Contact : In case of contact, immediately flush eyes with a copious amount of water for at least 15 minutes. Obtain medical attention
immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing
before reuse. Contaminated leather, particularly footwear, must be discarded. Note that contaminated clothing may be a fire
hazard. Get medical attention if irritation develops.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Obtain
medical attention immediately.
Ingestion : If swallowed, do NOT induce vomiting. Never give anything by mouth to an unconscious person. If large quantities of this
material are swallowed, call a physician immediately.
5. Fire-fighting measures
Extinguishing Media
Suitable : In case of fire, use water spray (fog), foam, dry chemical, or CO2.
Hazardous decomposition products : These products are carbon oxides (CO, CO2).
Unusual fire/explosion Hazards : Highly flammable liquid and vapour. Vapours may form explosive mixtures with air. Vapour may cause flash fire. Vapours
may accumulate in low or confined areas, travel a considerable distance to a source of ignition and flash back. Runoff to sewer
may create fire or explosion hazard. Container explosion may occur under fire conditions or when heated.
Special fire-fighting procedures : None identified.
Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus (SCBA) and full turnout gear. Firefighters'
protective clothing will provide limited protection. DO NOT FIGHT FIRE WHEN IT REACHES MATERIAL. Withdraw from fire
and let it burn. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
Benzene: Acute toxicity of benzene results primarily from depression of the central nervous system (CNS). Inhalation of
concentrations over 50 ppm can produce headache, lassitude, weariness, dizziness, drowsiness, or excitation. Exposure to very
high levels can result in unconsciousness and death.
Chronic toxicity : Benzene: Long-term overexposure to benzene has been associated with certain types of leukemia in humans. In addition, the
International Agency for Research on Cancer (IARC), the National Toxicology Program, and OSHA consider benzene to be a
human carcinogen. Chronic exposures to benzene at levels of 100 ppm and below have been reported to cause adverse blood
effects including anemia. Benzene exposure can occur by inhalation and absorption through the skin.
Inhalation and forced feeding studies of benzene in laboratory animals have produced a carcinogenic response in a variety of
organs, including possibly leukemia, other adverse effects on the blood, chromosomal changes and some effects on the
immune system. Exposure to benzene at levels up to 300 ppm did not produce birth defects in animal studies; however,
exposure to the higher dosage levels (greater than 100 ppm) resulted in a reduction of body weight of the rat pups (fetotoxicity).
Changes in the testes have been observed in mice exposed to benzene at 300 ppm, but reproductive performance was not
altered in rats exposed to benzene at the same level.
Carcinogenic effects : CANCER HAZARD
CONTAINS MATERIAL WHICH CAN CAUSE CANCER Risk of cancer depends on duration and level of exposure.
Classified A1 (Confirmed for humans.) by ACGIH, 1 (Proven for humans.) by IARC, 1 (Known To Be Human Carcinogens.) by
NTP, + (Proven.) by OSHA, + (Proven.) by NIOSH, 1 (Proven for humans.) by European Union [Benzene].
EU Category 1: Known to be carcinogenic to humans.
Land - Road/Railway
UN number : UN3295
Proper shipping name : Hydrocarbons, liquids, n.o.s. (Contains Benzene)
ADR/RID Class : 3
Packing group : II
CEFIC Tremcard Number: : Not available.
UK Emergency Action Code: : Not available.
Sea
Proper shipping name : Hydrocarbons, liquids, n.o.s. (Contains Benzene)
IMDG Class : 3
UN number : UN3295
Packing group : II
Medical First Aid Guide (MFAG) : 310 312
Air
Proper shipping name : Hydrocarbons, liquids, n.o.s. (Contains Benzene)
IATA-DGR Class : 3
UN/ID number : UN3295
Packing group : II
Inland waterways
UN/ID number : UN3295
Proper shipping name : Hydrocarbons, liquids, n.o.s. (Contains Benzene)
ADNR Classification : 3
062 22 1
Sheet No: STI2211 Material Name: Pyrolysis Gasoline Issue Date : 17/07/2000 Revision of Sheet Dated:15/09/98 Page:
Pyrolysis Gasoline
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Pyrolysis Gasoline
Application
Fuel blending component
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
May contain hydrogen sulphide.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Gasoline
ACGIH (USA) : TLV 300 ppm (8hr TWA); 500 ppm (15min STEL)
A3 - Animal Carcinogen
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
EU Labelling
Symbol:
Flame
Skull and crossbones
Dead tree and fish
Indication of danger:
EXTREMELY FLAMMABLE
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Gasoline, pyrolysis, debutanizer bottoms, EINECS No: 271-726-5
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
15/09/98 1, 3, 7, 8, 10, 12, 14, 15
17/07/2000 3, 4, 7, 8, 11, 15
Reformate
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Reformate
Application
Fuel blending component
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Gasoline
ACGIH (USA) : TLV 300 ppm (8hr TWA); 500 ppm (15min STEL)
A3 - Animal Carcinogen
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
EU Labelling
Symbol:
Flame
Indication of danger:
EXTREMELY FLAMMABLE
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S23 Do not breathe vapour
S24 Avoid contact with skin
S29 Do not empty into drains
S43 In case of fire, use foam/dry powder/CO2. Never use water jets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Naphtha (petroleum), light catalytic reformed, EINECS No: 265-065-1
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
CITGO
Health Precautions:
DANGER: BENZENE CANCER HAZARD. Harmful if swallowed. Do not ingest. If
swallowed, do not induce vomiting - call physician immediately. Inhalation
of vapors may result in blood abnormalities and central nervous system
depression. Material may be absorbed through the skin. This material may
contain Hydrogen Sulfide (H2S). At elevated concentrations, H2S acts as a
systemic poison and causes unconsciousness and death by respiratory
paralysis.
Safety Precautions:
DANGER: HIGHLY VOLATILE, FLAMMABLE LIQUID. Vapors are heavier than air and
may travel some distance to an ignition source and flash back.
HMIS Rating(1):
Health: 2*
Flammability: 3
Reactivity: 0
NA-Not Applicable
ND-No Data
NE-Not Established
Benzene 71-43-2 0 - 1
Heptanes Mixture 0 - 12
Toluene 108-88-3 0 - 1
Octanes Mixture 1 - 15
Combustible No
Flammable Yes
Pyrophoric No
Compressed Gas No
Organic Peroxide No
Reactive No
Explosive No
Oxidizer No
Stable Yes
Solubility in Water: No
pH of Undiluted Product: NA
NFPA Rating(2)
Health: 2
Flammability: 3
Reactivity: 0
Flammable Limits
Lower: 1.0
Upper: 7.6
(LFL and UFL estimates are based upon component information)
Extinguishing Media
Use dry chemical, foam or carbon dioxide. Water may be ineffective as an
extinguishing media but may be used to cool containers exposed to fire.
Stability: Stable.
Control ignition sources around spill area. Use of a fire fighting foam
blanket on spilled material will reduce vapor release and fire potential.
Waste Disposal:
Highly Toxic No
Sensitizer No
Toxic Yes(a)
Reproductive Effects No
Corrosive No
Mutagen No
Irritant Yes
Target Organ (central nervous
system, hematopoietic system,
respiratory system, and
peripheral nervous system) Yes
Carcinogen:
Toxicity Summary:
Subchronic inhalation of a component of this material, benzene, by rats
produced decreased white blood cell counts, decreased bone marrow cell
activity, increased red blood cell activity and cataracts. Chronic
inhalation or oral administration of benzene in rats produced cancers of
the liver, mouth and glands.
This material contains xylene. Xylene is irritating to the eyes, skin, and
mucous membranes. Over exposure to xylene can cause shortness of breath,
loss of appetite, nausea, vomiting, dermatitis, fatigue, headache,
dizziness, loss of coordination, irritability, slowed reaction time,
Eye: May cause eye irritation with corneal injury. Small areas of
superficial cornea necrosis may also be noted. Liquid material entering
the eye may cause clouding of the cornea.
Injection: Injection under the skin, in muscle or into the blood stream
can cause irritation, inflammation, swelling, fever, and systemic effects,
including pulmonary edema, pneumonia and mild central nervous system
depression. Injection of pressurized hydrocarbons can cause severe,
permanent tissue damage.
Skin: Prolonged and repeated contact with the skin may cause redness,
blistering, dryness and/or scaly dermatitis. Overexposure of the component
n-hexane can cause peripheral nervous system damage and central nervous
system depression.
Dermal: Remove contaminated clothing. Wash exposed skin with soap and
water. Launder clothing before use. Seek medical attention if tissue
appears damaged or if irritation persists.
Eyes: Flush eyes with cool water while occasionally lifting and lowering
eyelids. Seek medical attention if excessive tearing, irritation or pain
persists.
Injection: Injection under the skin, in muscle or into the blood stream is
a medical emergency. Seek medical attention immediately.
Notes to Physician:
mixed isomers
Hexane isomers, NE NE No
mixed (other
than n-hexane)
Eyes: Use chemical splash goggles to prevent contact with the eyes.
Storage: Do not use or store this product near heat, flame or other
potential ignition sources. Do not store with oxidizers. Do not store this
product in unlabeled containers. Keep container closed.
Danger: Flammable Liquid. Vapors are heavier than air and may travel some
distance to an ignition source and flash back. Use only in a well
ventilated area. Never siphon by mouth. Empty containers may contain
product residues which can ignite with explosive force. Consult
appropriate federal, state and local authorities before reusing,
reconditioning, reclaiming, recycling or disposing of empty containers
and/or residues of this product.
DOT Information:
Proper Shipping Name: Gasoline
Hazard Class: 3
Packaging Group: II
Hazard identification No.: UN 1203
Placard: Flammable Liquid
Benzene 71-43-2 0 - 1
n-hexane 110-54-3 0 - 2
Toluene 108-88-3 0 - 1
Xylenes 1330-20-7 1 - 7
Hydrogen Sulfide 7783-06-4 ND
This product meets the criteria of one or more of the Hazard Categories as
defined by 40 CFR Part 370 as established by Sections 311 and 312 of SARA:
Acute (Immediate Health Hazard) Yes
Sudden Release of Pressure Hazard No
Chronic (Delayed Health Hazard) Yes
Reactive Hazard No
Fire Hazard Yes
Benzene 71-43-2 0 - 1 10
Xylenes (mixed) 1330-20-7 1 - 7 100
Hydrogen Sulfide 7783-06-4 ND 100
Toluene 108-88-3 0 - 2 1,000
10.0 LABELING
DANGER:
CONTAINS BENZENE - CANCER HAZARD
FLAMMABLE LIQUID.
POISONOUS - CONTAINS H2S
Harmful or fatal if swallowed - can enter the lungs and cause damage.
Can cause skin, eye or respiratory tract irritation.
Target Organ(s): Hematopoietic system, respiratory system, and central
nervous system, peripheral nervous system.
HANDLING:
Keep away from heat, sparks and flames.
Keep container closed.
Do not breathe vapors or mists.
Prevent direct eye or skin contact with liquid or mists.
Use gloves, safety goggles, chemical resistant clothing and boots.
Use only with adequate ventilation.
FIRST AID:
Inhalation: Move victim from exposure. If breathing is interrupted,
provide CPR. Seek medical attention immediately.
Dermal: Wash exposed skin with soap and water. Seek medical attention if
irritation persists.
Application
Refinery stream
Company Identification
BP Oil UK Ltd, Coryton Refinery, The Manorway, Stanford-le-Hope, Essex SS17 9LL
BP Oil Grangemouth Refinery Ltd, Bo'Ness Road, Grangemouth, Stirlingshire FK3 9XQ
3. HAZARDS IDENTIFICATION
Flammable
Harmful if swallowed - aspiration hazard.
Likely to cause skin irritation.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
__________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any pain
or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing and
wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce vomiting;
obtain medical advice.
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate, medical assistance must
be called without delay. If breathing has failed respiration must be assisted, preferably by mouth to mouth method.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of
vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation.
Monitor for cardiac dysrhythmias.
__________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
FIRES IN CONFINED SPACES SHOULD BE DEALT WITH BY TRAINED PERSONNEL WEARING APPROVED
BREATHING APPARATUS.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
__________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage, remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection, section 8, of this Safety Data Sheet.
Spilled material may make surfaces slippery. Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements etc.).
If spillage has occurred in a confined space, ensure adequate ventilation and check that a safe, breathable atmosphere is
present before entry.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover product
from the surface. Protect environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate government/regulatory
authorities.
In the event of spillages contact the appropriate authorities. If spillage occurs call the Environment Agency Emergency
Hotline on 0800 807060 (24 hours a day, 7 days a week).
Regular surveillance on the location of the spillage should be maintained.
__________________________________________________________________________________
7. HANDLING AND STORAGE
Storage Conditions
Store and dispense only in well ventilated areas away from heat and sources of ignition.
Store and use only in equipment/containers designed for use with this product.
Containers must be properly labelled and kept closed when not in use.
Do not remove warning labels from containers.
Empty packages may contain some remaining product. Retain hazard warning labels on empty packages as a guide to the
safe handling, storage and disposal of empty packaging.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank atmosphere
has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability limit and an
oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to effect a
quick rescue.
Handling Precautions
Avoid, as far as reasonably practicable, inhalation of vapour, mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Wash hands thoroughly after contact.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards even
at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the potential
flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care
should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from
storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to
accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never cut,
weld, solder or braze empty containers.
__________________________________________________________________________________
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits
There is no appropriate occupational exposure limit for this material.
If vapour, mists or fumes are generated, their concentration in the workplace air should be controlled to the lowest
reasonably practicable level.
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and preferably
starched after use.
Respiratory Protection
If operations are such that significant exposure to vapour, mist or fume may be anticipated, then suitable approved
respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
__________________________________________________________________________________
9. PHYSICAL AND CHEMICAL PROPERTIES
Typical Values
Grades:Straight run Kerosine
Test Method Units
Physical state low viscosity liquid
Colour colourless --> pale yellow
Odour kerosine-like
Density @ 15°C ASTM D 1298 kg/m3 800
approx
Boiling point/range ASTM D 86 °C 145 - 300
Flash point (Abel) ASTM D 3828 °C 21 - 55
Explosion limits % 0.6 - 6.5
Solubility in water g/l <0.02
Partition Coefficient (n- Log10Pow >3
octanol/water)
10. STABILITY AND REACTIVITY
Conditions to Avoid
Stable at ambient temperatures.
Hazardous polymerisation reactions will not occur.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
May cause irritation to eyes, nose and throat due to exposure to vapour, mists or fumes.
__________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms. May cause long term effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.
Irritant
Dangerous for the environment
EU Labelling
Symbol: St. Andrew's Cross, Dead tree and fish
Indication of danger: FLAMMABLE, HARMFUL, DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R10 Flammable
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S24 Avoid contact with skin
S23 Do not breathe vapour
S43 - In case of fire use foam or dry powder. Never use water jets
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
The label must carry the following additional information: "EC Label", Substance name, EINECS No. (232-366-4)
__________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the date
specified below. We have reviewed any information contained herein which we received from sources outside the BP
Group of Companies. However, no warranty or representation, express or implied is made as to the accuracy or
completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws
and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or authorization
given or implied to practise any patented invention without a valid licence. The BP Group shall not be responsible for any
damage or injury resulting from abnormal use of the material, from any failure to adhere to recommendations, or from any
hazards inherent in the nature of the material.
Straight-Run Naphtha
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Straight-Run Naphtha
Alternative Names: Light straight-run naphtha, Heavy straight-run naphtha, Full-range straight-run naphtha
Application
Petroleum feedstock or fuel blending component
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
Naphtha (petroleum), heavy straight-run. EINECS No: 265-041-0, CAS No: 64741-41-9
Naphtha (petroleum), full-range straight-run. EINECS No: 265-042-6, CAS No: 64741-42-0
Naphtha (petroleum), light straight-run. EINECS No: 265-046-8, CAS No: 64741-46-4
3. HAZARDS IDENTIFICATION
Extremely flammable.
Explosive air/vapour mixtures may form at ambient temperature.
Likely to cause skin irritation.
May cause cancer, classified as a category 2 carcinogen.
Contains Benzene. Prolonged or repeated exposure to benzene can cause anaemia and other blood diseases,
including leukaemia.
Harmful if swallowed - aspiration hazard.
Vapours may cause drowsiness and dizziness.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
May contain hydrogen sulphide.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
In extreme situations of saturation with this product, drench with water, remove clothing as soon as possible and wash
skin with soap and water. Seek medical advice if skin becomes red, swollen or painful.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
EXPOSURE TO HYDROGEN SULPHIDE:
Casualties suffering ill effects as a result of exposure to hydrogen sulphide should be immediately removed to fresh air
and medical assistance obtained without delay.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
It is advisable that all who are engaged in operations in which contact with H2S may reasonably be anticipated, should
be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Medical Advice
Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
Inhalation of hydrogen sulphide may cause central respiratory depression leading to coma and death. It is irritant to the
respiratory tract causing chemical pneumonitis and pulmonary oedema. The onset of pulmonary oedema may be
delayed for 24 to 48 hours. Treat with oxygen and ventilate as appropriate. Administer broncho-dilators if indicated and
consider administration of corticosteroids. Keep casualty under surveillance for 48 hours in case pulmonary oedema
develops.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Vapours containing hydrogen sulphide may accumulate during storage or transport and may also be vented during
filling of tanks. Hydrogen sulphide has a typical "bad egg" smell but at high concentrations the sense of smell is rapidly
lost, therefore do not rely on sense of smell for detecting hydrogen sulphide. Use specially designed measuring
instruments for determining its concentration.
Confined spaces contaminated with hydrogen sulphide must always be considered as constituting potentially life
threatening environments. Entry into such spaces must never be undertaken except under extreme emergency when
no alternative is possible and then only by trained operators wearing air-supplied breathing apparatus of an approved
type and following procedures strictly in accordance with the Statutory Regulations governing such entry. Please see
the comments in Section 8 (Exposure Controls/Personal Protection) of this data sheet.
It is advisable that all who are engaged in operations in which contact with hydrogen sulphide may be reasonably
anticipated, should be trained in the techniques of emergency resuscitation and in the care of an unconscious patient.
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat, drink or smoke.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut, weld, solder or braze empty containers.
_________________________________________________________________________________
Gasoline
ACGIH (USA) : TLV 300 ppm (8hr TWA); 500 ppm (15min STEL)
A3 - Animal Carcinogen
Benzene
ACGIH (USA): TLV 0.5ppm (8hr TWA); 2.5 ppm (15min STEL)
A1 - Confirmed human carcinogen
Skin Notation - Can be absorbed through skin
Hydrogen sulphide
ACGIH (USA): TLV 10 ppm (8 hr TWA); 15ppm (15 min STEL)
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that the excessive generation of vapour, mist or fume may be anticipated, to which operators
may unavoidably be exposed, then suitable approved respiratory equipment should be worn. Note: Approved air-
supplied breathing apparatus must be worn where there may be potential for inhalation of hydrogen sulphide gas.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic accident).
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
May be toxic by inhalation when hydrogen sulphide is present in the vapour.
Hydrogen sulphide gas may in addition produce irritation of the eyes and respiratory tract.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
Carcinogenicity/Chronic Toxicity
Exposure to benzene may result in affects to the hematopoietic system causing blood disorders including anaemia and
leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans ( Group 1)
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
EU Labelling
Symbol:
Flame
Skull and crossbones
Dead tree and fish
Indication of danger:
EXTREMELY FLAMMABLE
DANGEROUS FOR THE ENVIRONMENT
Risk ( R ) Phrases:
R12 Extremely flammable
R45 May cause cancer
R65 Also Harmful: may cause lung damage if swallowed.
R38 Irritating to skin
R67 Vapours may cause drowsiness and dizziness.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety ( S ) Phrases:
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Low boiling point naphtha, EINECS No: 265-041-0, 265-042-6, 265-046-8
For non-fuel use only - "Restricted to professional users. Attention - Avoid exposure - obtain special instructions before
use." must be marked on packaging.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex, TW16 7LN
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
22/09/98 1, 3, 4, 7, 8, 10, 11, 12, 14, 15
17/07/2000 1, 2, 3, 4, 9, 15
Toluene
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
Toluene
Application
Fuel blending component
Chemical feedstock
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
BP Oil International Limited
Britannic House
1 Finsbury Circus
London, EC2M 7BA
3. HAZARDS IDENTIFICATION
Highly flammable
Harmful if vapour, mists or fumes generated during use are inhaled.
Harmful if swallowed - aspiration hazard.
May be irritating to eyes
May be irritating to the skin
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any
pain or redness develops or persists.
Skin
Wash off immediately with soap and water. Change heavily contaminated clothing and wash underlying skin.
Ingestion
If contamination of the mouth occurs, wash out thoroughly with water.
Except as a deliberate act, the ingestion of large amounts of product is unlikely. If it should occur, do not induce
vomiting; obtain medical advice.
Inhalation
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or
throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.
Unconscious casualties must be placed in the recovery position. Monitor breathing and pulse rate and if breathing has
failed, or is deemed inadequate, respiration must be assisted, preferably by the mouth to mouth method. Administer
external cardiac massage if necessary. Seek medical attention immediately.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can cause severe and
potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction
of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal
intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam, dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Any spillage should be regarded as a potential fire risk.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity, Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
As this product has a very low flash point any spillage or leak is a severe fire and/or explosion hazard.
Spilled material may make surfaces slippery.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems, in basements
etc.).
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
In the case of spillage on water, prevent the spread of product by the use of suitable barrier equipment. Recover
product from the surface. Protect environmentally sensitive areas and water supplies.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Handling Precautions
Ensure good ventilation and avoid as far as reasonably practicable the inhalation and contact with vapours, mists or
fumes which may be generated during use. If such vapour, mists or fumes are generated, their concentration in the
workplace air should be controlled to the lowest reasonably practicable level.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Do not siphon product by mouth.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. Tank headspaces should always be regarded as
potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling,
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a risk of static
discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists
generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be
Toluene
ACGIH (USA): TLV 50ppm (8hr TWA)
A4 - Not classifiable as a human carcinogen
Skin Notation - Can be absorbed through skin.
BEI (Biological Exposure Indice) Substance
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely, wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained; overalls should be dry-cleaned, laundered and
preferably starched after use.
Respiratory Protection
If operations are such that exposure to vapour, mist or fume may be anticipated, then suitable approved respiratory
equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Avoid excessive heat.
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Can be absorbed via intact skin. Repeated or prolonged contact may cause skin irritation.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause nausea and
diarrhoea.
Will injure the lungs if aspiration occurs, eg. during vomiting.
Inhalation
Harmful if vapour, mists or fumes generated during use are inhaled.
Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled.
May cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
ABUSE:
Under normal conditions of use the product is not hazardous; however, abuse involving deliberate inhalation of very
high concentrations of vapour, even for short periods, can produce unconsciousness and/or result in a sudden fatality.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Harmful to aquatic organisms.
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
EU Labelling
Symbol:
Flame
St. Andrew's Cross
Indication of danger:
HIGHLY FLAMMABLE
HARMFUL
Risk ( R ) Phrases:
R11 Highly flammable
R20 Harmful by inhalation
Safety ( S ) Phrases:
S2 Keep out of reach of children
S16 Keep away from sources of ignition - No smoking
S25 Avoid contact with eyes.
S29 Do not empty into drains
S33 Take precautionary measures against static discharges
The label must carry the following additional information: "EC Label", Substance name, EINECS No.
Substance name: Toluene, EINECS No: 203-625-9
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
This data sheet and the health, safety and environmental information it contains is considered to be accurate as of the
date specified below. We have reviewed any information contained herein which we received from sources outside the
BP Amoco Group of Companies. However, no warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information contained in this data sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission, recommendation or
authorization given or implied to practise any patented invention without a valid licence. The BP Amoco Group shall
not be responsible for any damage or injury resulting from abnormal use of the material, from any failure to adhere to
recommendations, or from any hazards inherent in the nature of the material.
Sheet Revisions
Date: Sections revised:
17/07/2000
TS-1
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of substance/preparation
TS-1
Application
Jet fuel
do not use for other purposes
For specific application advice see appropriate Technical Data Sheet or consult your BP representative
Company Identification
Air BP International
Breakspear Park
Breakspear Way
Hemel Hempstead
Hertfordshire
HP2 4UL
_________________________________________________________________________________
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Composition
A mixture of kerosene streams
May contain small quantities of proprietary performance additives.
Hazardous Components
Kerosine - unspecified
Xn R10 Flammable
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
(>90%)
_________________________________________________________________________________
3. HAZARDS IDENTIFICATION
Flammable
Harmful if swallowed - aspiration hazard.
Likely to cause skin irritation.
_________________________________________________________________________________
4. FIRST-AID MEASURES
Eyes
Wash eye thoroughly with copious quantities of water
ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists.
Skin
Wash skin thoroughly with soap and water as soon as reasonably practicable. Remove heavily contaminated clothing
and wash underlying skin.
Ingestion
If contamination of the mouth occurs
wash out thoroughly with water.
Except as a deliberate act
the ingestion of large amounts of product is unlikely. If it should occur
do not induce vomiting
obtain medical advice.
Inhalation
If fumes are inhaled the patient should be removed to fresh air and if recovery is not immediate
medical assistance must be called without delay. If breathing has failed respiration must be assisted
preferably by mouth to mouth method.
Medical Advice
Product can be aspirated on swallowing or following regurgitation of stomach contents
and can cause severe and potentially fatal chemical pneumonitis
which will require urgent treatment. Because of the risk of aspiration
induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after
endotracheal intubation. Monitor for cardiac dysrhythmias.
_________________________________________________________________________________
5. FIRE-FIGHTING MEASURES
For major fires call the Fire Service. Ensure an escape path is always available from any fire.
There is a danger of flashback if sparks or hot surfaces ignite vapour.
Use foam
dry powder or water fog. DO NOT USE water jets.
Fires in confined spaces should be dealt with by trained personnel wearing approved breathing apparatus.
Combustion Products
Toxic fumes may be evolved on burning or exposure to heat.
See Stability and Reactivity
Section 10 of this Safety Data Sheet.
_________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
Any spillage should be regarded as a potential fire risk.
In the event of spillage
remove all sources of ignition and ensure good ventilation.
Wear protective clothing. See Exposure Controls/Personal Protection
section 8
of this Safety Data Sheet.
Spilled material may make surfaces slippery.
Clean up spilled material immediately.
Contain and recover spilled material using sand or other suitable inert absorbent material.
Recovery of large spillages should be effected by specialist personnel.
It is advised that stocks of suitable absorbent material should be held in quantities sufficient to deal with any spillage
which may be reasonably anticipated.
Large and uncontained spillages should be smothered with foam to reduce the risk of ignition.
The foam blanket should be maintained until the area is declared safe.
Protect drains from potential spills to minimise contamination. Do not wash product into drainage system.
Vapour is heavier than air and may travel to remote sources of ignition (eg. along drainage systems
in basements etc.).
If spillage has occurred in a confined space
ensure adequate ventilation and check that a safe
breathable atmosphere is present before entry.
In the case of spillage on water
prevent the spread of product by the use of suitable barrier equipment. Recover product from the surface. Protect
environmentally sensitive areas and water supplies.
In the case of spillage at sea approved dispersants may be used where authorised by the appropriate
government/regulatory authorities.
Regular surveillance on the location of the spillage should be maintained.
In the event of spillages contact the appropriate authorities.
_________________________________________________________________________________
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and the tank
atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1% of the lower flammability
limit and an oxygen concentration of at least 20% volume.
Always have sufficient people standing by outside the tank with appropriate breathing apparatus and equipment to
effect a quick rescue.
Handling Precautions
Avoid
as far as reasonably practicable
inhalation of vapour
mists or fumes generated during use.
Avoid contact with skin and observe good personal hygiene.
Avoid contact with eyes. If splashing is likely to occur wear a full face visor or chemical goggles as appropriate.
Do not siphon product by mouth.
Whilst using do not eat
drink or smoke.
Wash hands thoroughly after contact.
Use disposable cloths and discard when soiled. Do not put soiled cloths into pockets.
Take all necessary precautions against accidental spillage into soil or water.
Fire Prevention
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/explosion hazards
even at temperatures below the normal flash point (note: flash point must not be regarded as a reliable indicator of the
potential flammability of vapour in tank headspaces). Tank headspaces should always be regarded as potentially
flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling
ullaging and sampling from storage tanks.
When the product is pumped (e.g. during filling
discharge or ullaging) and when sampling
there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
Product contaminated rags
paper or material used to absorb spillages
represent a fire hazard
and should not be allowed to accumulate. Dispose of safely immediately after use.
Empty containers represent a fire hazard as they may contain some remaining flammable product and vapour. Never
cut
weld
solder or braze empty containers.
_________________________________________________________________________________
Protective Clothing
Wear face visor or goggles in circumstances where eye contact can accidentally occur.
If skin contact is likely
wear impervious protective clothing and/or gloves.
Protective clothing should be regularly inspected and maintained
Respiratory Protection
If operations are such that exposure to vapour
mist or fume may be anticipated
then suitable approved respiratory equipment should be worn.
The use of respiratory equipment must be strictly in accordance with the manufacturers' instructions and any statutory
requirements governing its selection and use.
_________________________________________________________________________________
Conditions to Avoid
Sources of ignition
Materials to Avoid
Avoid contact with strong oxidizing agents.
Skin
Likely to cause skin irritation.
Ingestion
Unlikely to cause harm if accidentally swallowed in small doses
though larger quantities may cause nausea and diarrhoea.
Will injure the lungs if aspiration occurs
eg. during vomiting.
Inhalation
May cause irritation to eyes
nose and throat due to exposure to vapour
mists or fumes.
_________________________________________________________________________________
12. ECOLOGICAL INFORMATION
Mobility
Spillages may penetrate the soil causing ground water contamination.
Bioaccumulative potential
There is no evidence to suggest bioaccumulation will occur.
Aquatic toxicity
Toxic to aquatic organisms
may cause long-term adverse effects in the aquatic environment
Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be
impaired.
_________________________________________________________________________________
13. DISPOSAL CONSIDERATIONS
Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations.
Dispose of product and container carefully and responsibly. Do not dispose of near ponds
ditches
down drains or onto soil.
At sea
used or unwanted product should be stored for eventual discharge into port approved waste oil disposal facilities.
_________________________________________________________________________________
14. TRANSPORT INFORMATION
ADR/RID: Kerosene
Flammable Liquid
Class 3
Item 31 (c)
Hazard Identification No 30
UN: KEROSENE
Flammable liquid
Class 3
Packing Group III
UN Number 1223
IATA/ICAO: Kerosene
Flammable liquid
Class 3
Packing Group III
IMO: KEROSENE
Flammable liquid
Class 3.3
Packing Group III
EMERGENCY ACTION CODE: Flammable liquid
3[Y]
_________________________________________________________________________________
15. REGULATORY INFORMATION
EU Category of Danger
Flammable
Harmful
Irritant
EU Labelling
Symbol:
St. Andrew's Cross
Indication of danger:
HARMFUL
Contains:
Kerosine - unspecified
Risk ( R ) Phrases:
R10 Flammable
R38 Irritating to skin
R65 Harmful: may cause lung damage if swallowed.
Safety ( S ) Phrases:
S24 Avoid contact with skin
S23 Do not breathe vapour
S43 In case of fire
use foam/dry powder/CO2. Never use water jets.
S62 If swallowed
do not induce vomiting: seek medical advice immediately and show this container or label.
S61 Avoid release into the environment. Refer to special instructions/Safety data sheets.
_________________________________________________________________________________
16. OTHER INFORMATION
Compiled by:
Product Stewardship Group
BP Oil Technology Centre
Chertsey Road
Sunbury-on-Thames
Middlesex
TW16 7LN
reviewed any information contained herein which we received from sources outside the BP Amoco Group of
Companies. However
no warranty or representation
express or implied is made as to the accuracy or completeness of the data and information contained in this data
sheet.
Health and safety precautions and environmental advice noted in this data sheet may not be accurate for all individuals
and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations. No statement made in this data sheet shall be construed as a permission
recommendation or authorization given or implied to practise any patented invention without a valid licence. The BP
Amoco Group shall not be responsible for any damage or injury resulting from abnormal use of the material
from any failure to adhere to recommendations
or from any hazards inherent in the nature of the material.
______________________________________________________________________________
NPVLA 6-70
Section I
MANUFACTURER'S NAME
PARKS CORPORATION
STREET ADDRESS
ONE MAIN STREET
TRADE NAME
VM&P NAPHTHA
CHEMICAL FAMILY
PETROLEUM HYDROCARBON
FORMULA
Complex mixture of petroleum hydrocarbons
CATALYST ADDITIVES
VEHICLE OTHERS
(Units)
SOLUBILITY IN WATER
Negligible
FLAMMABLE LIMITS
1.0% Lel
6.0% Uel
EXTINGUISHING MEDIA
Foam, dry chemical, CO2, or water fog or spray.
EFFECTS OF OVEREXPOSURE
Inhalation of high vapor concentrations may have results ranging from
dizziness and headaches to unconsciousness. Prolonged or repeated
liquid contact with the skin will dry and defat the skin leading to
irritation and dermatitis.
CONDITIONS TO AVOID
HAZARDOUS POLYMERIZATION
WILL OCCUR
WILL NOT OCCUR X
CONDITIONS TO AVOID
VENTILATION
LOCAL EXHAUST
Face velocity >60 FPM
SPECIAL
Use only with adequate ventilation
MECHANICAL
Use explosion-proof equipment.
OTHER
No smoking or open lights.
PROTECTIVE GLOVES
Use chemical-resistant gloves to avoid repeated or prolonged skin
contact.
EYE PROTECTION
Use splash goggles or face shield when eye contact may occur.
OTHER PRECAUTIONS
Avoid breathing vapors. Avoid prolonged or repeated contact with skin.
Remove contaminated clothing. Remove contaminated shoes and dry before
reuse. Wash with soap and water after contact.