www.elsevier.com/locate/compositesb
Abstract
A nonlinear material constitutive model, including a nonlinear in-plane shear formulation and the Tsai–Wu failure criterion, for fiber–
composite laminate materials is employed to carry out finite element buckling analyses for composite laminate skew plates under uniaxial
compressive loads. The influences of laminate layup, plate skew angle and plate aspect ratio on the buckling resistance of composite laminate
skew plates are presented. Comparing with the linearized buckling loads of the skew plates, one can observer that the nonlinear in-plane
shear together with the failure criterion have significant influence on the ultimate loads of the composite laminate skew plates with [Gq]10S
and [Gq/90/0]5S layups but not the [a/0]10S layup.
q 2005 Elsevier Ltd. All rights reserved.
* Corresponding author. Tel.: C886 6 2757575x63168; fax: C886 6 For fiber–composite laminate materials (Fig. 2), each
2358542. lamina can be considered as an orthotropic layer in a plane
E-mail address: hthu@mail.ncku.edu.tw (H.-T. Hu). stress condition. Let us define D{s 0 }ZD{s1,s2,t12}T,
1359-8368/$ - see front matter q 2005 Elsevier Ltd. All rights reserved. Dftt0 gZDft13 ; t23 gT , D{3 0 }ZD{31,32,g12}T, Dfgt0 gZDfg13 ;
doi:10.1016/j.compositesb.2005.05.004 g23 gT . Then the incremental stress-strain relations for
H.-T. Hu et al. / Composites: Part B 37 (2006) 26–36 27
Fig. 1. Composite laminate skew plate with simply supported edge condition.
a linear orthotropic lamina in the material coordinates the nonlinear incremental constitutive matrix for the lamina
(1,2,3) can be written as as follows:
2 3
Dfs 0 g Z ½Q10 Df3 0 g (1) E11 n12 E22
6 1Kn12 n21 1Kn12 n21 0 7
6 7
Dftt0 g Z ½Q20 Dfgt0 g (2) 6 n E
21 11 E 22 7
½Q10 Z 6
6 1Kn12 n21 1Kn12 n21 0 7
7 (6)
2 3 6 7
E11 n12 E22 4 1 5
0 0 0
6 1 K n12 n21 1 K n12 n21 7 1=G12 C3S6666 t212
6 7
½Q10 Z 6 n21 E11 E22 7 (3)
4 0 5 The validity of using Eq. (6) to model the nonlinear in-
1 K n12 n21 1 K n12 n21
0 0 G12 plane shear has been demonstrated by Hahn and Tsai [16]
and is not repeated here. Furthermore, it is assumed that the
" #
a1 G13 0 transverse shear stresses always behave linearly and do not
½Q20 Z (4) affect the nonlinear behavior of in-plane shear. Hence, the
0 a2 G23 same shear correction factors and shear moduli for
where a1 and a2 are the shear correction factors [21] and are transverse shear as those given in Eq. (4) also apply to the
taken to be 0.83 in this study. cases of nonlinear in-plane shear.
It is known that unidirectional fibrous composites exhibit
severe nonlinearity in in-plane shear stress-strain relation 2.2. Failure criterion and degradation of stiffness
[16]. Though deviation from linearity is also observed in
transverse loading direction, i.e. 2-direction, the degree of Among existing failure criteria, the Tsai–Wu criterion
this nonlinearity is not comparable to that in the in-plane [19] has been extensively used in literature and it is adopted
shear. Therefore, it has been suggested that the nonlinearity in this analysis. Under plane stress conditions, this failure
associated with the transverse loading direction could be criterion has the following form:
ignored for graphite/epoxy and boron/epoxy [17]. To model
the nonlinear in-plane shear behavior, the nonlinear strain- F1 s1 C F2 s2 C F11 s21 C 2F12 s1 s2 C F22 s22 C F66 t212 Z 1
stress relation for a composite lamina suggested by Hahn
(7)
and Tsai [16] is adopted in this study, which is given as
follows:
2 1 n21 3
8 9 6 E 0 8 9
78 s1 9
K
E22
< 31 = 6 n11 1 7 < = <0 >
> =
6 12 7 2
32 Z 6 K 0 7 s2 CS6666 t12 0
: ; 6 E11 E22 7: ; : >
> ;
g12 4 1 5 t12 t12
0 0
G12
(5)
In this model only one constant S6666 is required to account
for the in-plane shear nonlinearity. The value of S6666 can be
determined by a curve fit to various off-axis tension test data Fig. 2. Material, element and structure coordinates of fiber–composite
[16]. Inverting and differentiating Eq. (5), we obtain laminate materials.
28 H.-T. Hu et al. / Composites: Part B 37 (2006) 26–36
a numerical integration through the thickness of the specimens have two types of laminate layups, i.e. [0]16 and
composite shell section. For the linear material case, [(G45/02)3]S, and are both subjected to uniaxial compres-
the ½Q10 matrix used in Eq. (12) is taken from Eq. (3) and sive force in the longitudinal direction (Fig. 3). The two
the incremental stress resultants of the shell section can be loading edges of the laminates are assumed to be fixed and
written as a summation of integrals over the n laminae in the the remaining two edges are free. The laminates are
following form:
0 2 31
8 9 1 2 2 8 9
> DfNg > ðz z Þ½Q ðz z Þ½Q ½0 7C> Df3o g >
= B n 6
jt K jb 1 jt K jb 1
< BX 6 2 7C< =
DfMg Z B B
61 2
6 2 1 3 3 7C Dfkg
7C (18)
>
: ; @ jZ1 4 2 ðzjt K zjb Þ½Q1 3 ðzjt K zjb Þ½Q1
> ½0 5A>: >
;
DfVg Dfgt g
½0T ½0T ðzjt K zjb Þ½Q2
where zjt and zjb are distances from the mid-surface of the consisted of T800/924C carbon-fibre/epoxy composite
section to the top and the bottom of the jth layer with the following material properties: E11Z168 GPa,
respectively.
E22Z9.25 GPa, n12Z0.35, G12Z6 GPa, S6666Z7!10K20
Prior to numerical analyses, the ABAQUS program has 2:32 GPa, X 0 ZK1:62 GPa, Y Z 63 MPa,
(Pa) -3, XZ
been employed to analyze the buckling of composite 0 105 MPa. The thickness of each ply is
Y ZK63 MPa, SZ
cylindrical panels with cutout and buckling of isotropic
0.125 mm. Since the stress field is uniform throughout the
skew plates. These solutions are compared with known
specimen, only one shell element is used to model the entire
benchmark solutions [24,25] and satisfactory results are
composite laminate in the numerical analysis.
obtained [26].
Fig. 3 also shows the stress versus strain curves of the
composite laminates in the longitudinal direction. It can be
observed that the correlations are quite good between
3. Nonlinear finite element analysis the numerical results and the experimental data whether the
shear stresses in the laminate are significant (i.e. [(G45/
In the ABAQUS finite element program, the nonlinear
02)3]S layup) or not (i.e., [0]16 layup). The predicted ultimate
response of a structure is modeled by an updated Lagrangian
strength 1.6 GPa for [0]16 laminate is in good agreement
formulation and a modified Riks nonlinear incremental
with the experimental ultimate strength 1.55 GPa. The error
algorithm [20] can be used to construct the equilibrium
is only about 3.2%. In addition, the predicted ultimate
solution path. To model bifurcation from the prebuckling
strength 0.81 GPa for [(G45/02)3]S laminate is also in good
path to the postbuckling path, geometric imperfections of
composite plates are introduced by superimposing a small
fraction of the lowest eigenmode, determined by a
linearized buckling analysis, to the original nodal coordi-
nates of plate as
fIg Z ffg C bhfjg (19)
where {I} represents the vector containing imperfect nodal
coordinates of the plate, {f} is the vector containing
original nodal coordinates of the plate, {j} is the
normalized lowest eigenmode, and b is a scaling coefficient.
Based on the results of various imperfection analyses [27], it
1.6
is decided to use bZ0.005 throughout the numerical
analyses. [0] Exp.
16
1.2 [0] FEM
16
σx (GPa)
3 5
4
N (MN/m)
2
N (MN/m)
1 2
N (MN/m)
3 3
2 2
1 (c) [45/-45] 1 (d) [60/-60]
10S 10S
0 0
-15 -12 -9 -6 -3 0 -20 -15 -10 -5 0
u (mm) u (mm)
3
N (MN/m)
1
(e) [90/-90]
10S
0
-10 -8 -6 -4 -2 0
u (mm)
Fig. 5. Load–displacement curves for composite laminate skew plate with ½Gq10S layup under uniaxial compression (a/bZ1, aZ508).
H.-T. Hu et al. / Composites: Part B 37 (2006) 26–36 31
(a) 6 (a) 4
α=50˚
5 α=70˚
3
α=90˚
Ncr(MN/m)
Ncr(MN/m)
3 2
α =50o
2
1 α =70o
1 α =90
o
0 0
0 15 30 45 60 75 90 0 15 30 45 60 75 90
θ (degrees) θ (degrees)
Linearized buckling load Linearized buckling load
(b) 6 (b) 4
5 α=50˚ α =50o
α=70˚ 3
α =70o
N u (MN/m)
4
N u (MN/m)
α=90˚ α =90o
3 2
2
1
1
0 0
0 15 30 45 60 75 90 0 15 30 45 60 75 90
θ (degrees) θ (degrees)
Nonlinear shear with failure criterion Nonlinear shear with failure criterion
Fig. 6. Effect of skew angle a and material nonlinearity on buckling loads of Fig. 8. Effect of skew angle a and material nonlinearity on buckling loads of
composite laminate skew plate with ½Gq10S layup (a/bZ0.5). composite laminate skew plate with ½Gq10S layup (a/bZ2).
4 5
3 4
N (MN/m)
N (MN/m)
3
2
2
1 1
(a) [0/-0/90/0] (b) [45/-45/90/0]
5S 5S
0 0
-1.2 -1 -0.8 -0.6 -0.4 -0.2 0 -4 -3 -2 -1 0
u (mm) u (mm)
4
3
N (MN/m)
1
(c) [90/-90/90/0]
5S
0
-4 -3 -2 -1 0
u (mm)
Fig. 9. Load–displacement curves for composite laminate skew plate with ½Gq=90=05S layup under uniaxial compression (a/bZ1, aZ508).
and skew angles (aZ708, 908) show similar trends as those the angle q varies between 158 and 758, the influence of the
in Fig. 5 and are not duplicated here. Figs. 6–8 show the nonlinear shear with failure criterion on the ultimate load of
effect of skew angle a and material nonlinearity on buckling the skew plate is significant, especially for plates with small
loads of composite laminate skew plate with [Gq]10S layup. angle a. This conclusion is valid whether the plate aspect
From Figs. 6(a), 7(a) and 8(a), it can be observed that with ratio is small or large.
the same laminate layup and the same plate skew angle, the
linearized buckling load Ncr increases with the decrease of 4.3. Composite laminate skew plates with [Gq/90/0]5S
plate aspect ratio. In addition, with the same laminate layup layup
and plate aspect ratio, the linearized buckling load increases
with the decreasing of angle a. Furthermore, the curve with In this section composite laminate skew plates similar to
aZ708 is closer to that with aZ908 than to that with aZ those in previous section are analyzed. However, the
508. It can be concluded that the larger the a angle, the laminate layup is changed to [Gq/90/0]5S. Fig. 9 shows
smaller the increasing/decreasing rate in Ncr. When the plate the load-displacement curves for composite laminate skew
aspect ratio a/b is small (say a/b%0.5), the optimal fiber plates with aspect ratio a/bZ1 and skew angle aZ508. For
angle q for skew plate with [Gq]10S laminate layup seems to plates with [0/K0/90/0]5S and [90/K90/90/0]5S layups, it
close to 08. This phenomenon is more prominent when the can be seen that the curves computed by using linear and
skew angle a is equal to or greater than 708. On the other nonlinear in-plane shear formulations again are very close.
hand, when the plate aspect ratio a/b is large (say a/bS1), This is because all the fibers are parallel to or normal to the
the optimal fiber angle q seems to be around 458. This loading direction and the shear stresses in the plates are
phenomenon seems to be independent on the skew angle a. insignificant. For plate with [45/K45/90/0]5S layup, we
From Figs. 6(b), 7(b) and 8(b), it can be seen that the might expect that the nonlinear shear effect to be significant
ultimate load Nu seems to be independent on the fiber angle in the plate. However, the curve computed with nonlinear
q, the skew angle a and the aspect ratio a/b when the fiber in-plane shear formulation is also very close to that with
angle qS308. When q%308 and a/b is small (say a/b%0.5), linear in-plane shear formulation. The reason might be that
the ultimate load of the skew plate seems to be insensitive to the fibers in the 08 direction take the major portion of the
the skew angle a. When q%308 and a/b is large (say a/ loading and the shear stresses in the 458 and -458 laminae are
bS1), the ultimate load of the skew plate increases with the not significant enough to cause the difference between the
decreasing of angle a. When the plate aspect ratio a/b is linear and nonlinear shear formulations. As a result, the
small (say a/b%0.5), the optimal fiber angle q seems to be effect of nonlinear in-plane shear stress is insignificant for
08. When the plate aspect ratio a/b is large (say a/bS1), the the [Gq/90/0]5S composite laminate skew plates. The load-
optimal fiber angle q seems to be around 158. displacement curves for [Gq/90/0]5S composite laminate
Comparing Figs. 6(b), 7(b) and 8(b) with Figs. 6(a), 7(a) skew plates with other aspect ratios (a/bZ0.5, 2) and skew
and 8(a), we can observe that when the angle q is close to 08, angles (aZ708, 908) show similar trends as those in Fig. 9
the effect of nonlinear shear with failure criterion seems to and are not duplicated here.
be insignificant. When the angle q is close to 908, the effect Figs. 10–12 show the effect of skew angle a and material
of nonlinear shear with failure criterion is prominent for nonlinearity on buckling loads of composite laminate skew
plate with small angle a (say aZ508). This effect is less plate with [Gq/90/0]5S layup. From Figs. 10(a), 11(a) and
significant for plate with large angle a (say aZ908). When 12(a), it can be observed that with the same laminate layup
H.-T. Hu et al. / Composites: Part B 37 (2006) 26–36 33
(a) 6 (a) 4
5
3
4
N cr (MN/m)
N (MN/m)
3 2
cr
α =50o α =50 o
2
α =70o 1 α =70o
1 α =90o α =90o
0 0
0 15 30 45 60 75 90 0 15 30 45 60 75 90
θ (degrees) θ (degrees)
Linearized buckling load Linearized buckling load
(b) 6 (b) 4
5
3
4
N (MN/m)
N (MN/m)
3 2
u
o
u
2 α=50o α =50
α =70o
α =70o 1
1 o α =90o
α =90
0 0
0 15 30 45 60 75 90 0 15 30 45 60 75 90
θ (degrees) θ (degrees)
Nonlinear shear with failure criterion Nonlinear shear with failure criterion
Fig. 10. Effect of skew angle a and material nonlinearity on buckling loads Fig. 12. Effect of skew angle a and material nonlinearity on buckling loads
of composite laminate skew plate with ½Gq=90=05S layup (a/bZ0.5) of composite laminate skew plate with ½Gq=90=05S layup (a/bZ2).
(a) 4
and the same plate skew angle, the linearized buckling load
Ncr increases with the decrease of plate aspect ratio. In
3
addition, with the same laminate layup and plate aspect
N (MN/m)
3 2
N (MN/m)
N (MN/m)
2
1
1
(a) α =50 , [50/0] (b) α =70 , [70/0]
o o
10S 10S
0 0
-1.2 -1 -0.8 -0.6 -0.4 -0.2 0 -0.8 -0.6 -0.4 -0.2 0
u (mm) u (mm)
2
N (MN/m)
Fig. 13. Load–displacement curves for composite laminate skew plate with ½a=010S layup under uniaxial compression (a/bZ1).
ratio a/b is small (say a/b%0.5), the optimal fiber angle q for
skew plate with [Gq/90/0]5S laminate layup seems to close
to 08. This phenomenon is more prominent when the skew
angle a is equal to or greater than 708. When the plate aspect 4
ratio a/b is large (say a/bS1), the optimal fiber angle q
seems to be around 308 to 458.
Ncr or Nu (MN/m)
Fig. 13 shows the load-displacement curves for plates with Non linearshear with failre criterion
3
aspect ratio a/bZ1 and plate skew angle aZ508, 708, 908.
From these figures, it can be seen that the curves computed
by using linear and nonlinear in-plane shear formulations
2
are almost the same. This is because the fibers in the 08
direction take the major portion of the loading and the shear
(c) a/b = 2
stresses in the laminae with fibers in a direction are not 1
significant enough to cause the difference between the 50 60 70 80 90
α (degrees)
linear and nonlinear shear formulations. As a result, the
effect of nonlinear in-plane shear stress is insignificant for Fig. 14. Effect of skew angle a, aspect ratio a/b and material nonlinearity on
the [a/0]10S composite laminate skew plates. buckling loads of composite laminate skew plate with ½a=010S layup.
H.-T. Hu et al. / Composites: Part B 37 (2006) 26–36 35
Fig. 14 shows the effect of skew angle a, aspect ratio a/b a/b is large (say a/bS1), the optimal fiber angle q seems
and material nonlinearity on buckling loads of composite to be around 308 to 458.
laminate skew plate with [a/0]10S layup. It can be seen that (7) The influence of nonlinear shear with failure criterion
the linearized buckling loads Ncr of the skew plates again on the ultimate loads of laminate skew plates with
increase with the decreasing of plate aspect ratio a/b and [Gq/90/0]5S laminate layup is much less than those
with the decreasing of angle a. In addition, the ultimate with [Gq]10S laminate layup. Hence, the former
loads Nu of the skew plates calculated by the nonlinear shear laminate layup is a better design than the latter one in
formulation with Tsai–Wu failure criterion are very close to practical engineering applications.
the linearized buckling loads Ncr. Thus, influence of (8) The influence of nonlinear shear with failure criterion
nonlinear shear with failure criterion on the ultimate loads on the ultimate loads of laminate skew plates with
of laminate skew plates with [a/0]10S laminate layup is very [a/0]10S laminate layup is very limited and material
limited and material nonlinear buckling analysis of skew nonlinear buckling analysis of skew plates with this
plates with this type of laminate layup may be not necessary. type of laminate layup may be not necessary.
5. Conclusions
References
Based on the numerical results from the analyses, the
following conclusions may be drawn: [1] Crouzet-Pascal J. Buckling analysis of laminated composite plates.
Fibre Sci Technol 1978;11:413–46.
(1) No matter of plate aspect ratio and skew angle, [2] Hirano Y. Optimum design of laminated plates under axial
nonlinear in-plane shear alone has significant influence compression. AIAA J 1979;17:1017–9.
on the load-displacement curves of laminate skew [3] Rhodes MD, Mikulas MM, McGowan PE. Effects of orthotropy and
width on the compression strength of graphite-epoxy panels with
plates with [Gq]10S laminate layup. This influence is holes. AIAA J 1984;22:1283–92.
most significant when q is equal to 458 and less [4] Leissa AW. Buckling of laminated composite plates and shell panels,
significant when q deviates from 458. AFWAL-TR-85-3069. Flight Dynamics Laboratory, Air Force Wright
(2) Nonlinear in-plane shear alone has almost no influence Aeronautical Laboratories, Wright-Patterson Air Force Base, Ohio;
1985.
on the load-displacement curves of laminate skew
[5] Muc A. Optimal fibre orientation for simply-supported angle-ply
plates with [Gq/90/0]5S and [a/0]10S laminate layups. plates under biaxial compression. Compos Struct 1988;9:161–72.
(3) The linearized buckling loads of the plates with [6] Nemeth MP. Buckling behavior of compression-loaded symmetrically
[Gq]10S, [Gq/90/0]5S and [a/0]10S laminate layups laminated angle-ply plates with holes. AIAA J 1988;26:330–6.
increase with the decreasing of plate aspect ratio a/b [7] Vellaichamy S, Prakash BG, Brun S. Optimum design of cutouts in
and with the decreasing of angle a. laminated composite structures. Comput Struct 1990;37:241–6.
[8] Hu H-T, Lin B-H. Buckling optimization of symmetrically laminated
(4) For skew plates with both [Gq]10S and [Gq/90/0]5S rectangular plates with various geometry and end conditions. Compos
layups, the optimal fiber angle q for the linearized Sci Technol 1995;55:277–85.
buckling loads seems to close to 08 when the plate [9] Ari-Gur J, Simonetta SR. Dynamic pulse buckling of rectangular
aspect ratio a/b is small (say a/b%0.5). However, when composite plates. Compos Part B: Eng 1997;28:301–8.
the plate aspect ratio a/b is large (say a/bS1), the [10] Shrivastava AK, Singh RK. Effect of aspect ratio on buckling of
composite plates. Compos Sci Technol 1999;59:439–45.
optimal fiber angle q for plates with both laminate [11] Wang CM, Liew KM, Alwis WAM. Buckling of skew plates and
layups seems to be around 458. corner condition for simply supported edges. J Eng Mech, ASCE
(5) The influence of the nonlinear shear with failure 1992;118:651–62.
criterion on the ultimate loads of the laminate skew [12] Liao C-L, Lee Z-Y. Elastic stability of skew laminated composite
plates subjected to biaxial follower forces. Int J Numer Methods Eng
plates with [Gq]10S laminate layup is significant,
1993;36:1825–47.
especially for plates with small angle a. When the [13] Reddy ARK, Palaninathan R. Buckling of laminated skew plates.
plate aspect ratio a/b is small (say a/b%0.5), the Thin-Walled Struct 1995;22:241–59.
optimal fiber angle q for the ultimate load seems to be [14] Hu H-T, Tzeng W-L. Buckling analysis of skew laminate plates
08. When the plate aspect ratio a/b is large (say a/bS1), subjected to uniaxial inplane loads. Thin-Walled Struct 2000;38:
the optimal fiber angle q seems to be around 158. 53–77.
[15] Kant T, Babu CS. Thermal buckling analysis of skew fibre-reinforced
(6) The influence of the nonlinear shear with failure composite and sandwich plates using shear deformable finite element
criterion on the ultimate loads of the laminate skew models. Compos Struct 2000;49:77–85.
plates with [Gq/90/0]5S laminate layup is significant for [16] Hahn HT, Tsai SW. Nonlinear elastic behavior of unidirectional
plates with small a angle (say a%508) and is composite laminae. J Compos Mater 1973;7:102–18.
insignificant for plates with large a angle (say [17] Jones RM, Morgan HS. Analysis of nonlinear stress-strain behavior of
fiber-reinforced composite materials. AIAA J 1977;15:1669–76.
aS708). When the plate aspect ratio a/b is small [18] Hu H-T. Buckling analyses of fiber composite laminate plates
(say a/b%0.5), the optimal fiber angle q for the ultimate with material nonlinearity. Finite Elem Anal Design 1995;19:
load seems to close to 08. When the plate aspect ratio 169–79.
36 H.-T. Hu et al. / Composites: Part B 37 (2006) 26–36
[19] Tsai SW, Wu EM. A general theory of strength for anisotropic [26] Tzeng W-L. Buckling analysis of laminate parallelogram plates
materials. J Compos Mater 1971;5:58–80. subjected to uniaxial compression. MS Thesis.Department of Civil
[20] Hibbitt, Karlsson & Sorensen, Inc. ABAQUS user’s manuals and Engineering, National Cheng Kung University, Tainan, ROC;
theory manuals, Version 6.2. Rhode Island: Providence; 2002. 1996.
[21] Mindlin RD. Influence of rotatory inertia and shear on flexural [27] Yang C-H. Numerical analysis of laminate parallelogram plates with
motions of isotropic elastic plates. J Appl Mech 1951;18:31–8. material nonlinearity. MS Thesis. Department of Civil Engineering,
[22] Narayanaswami R, Adelman HM. Evaluation of the tensor National Cheng Kung University, Tainan, ROC; 1999.
polynomial and Hoffman strength theories for composite materials. [28] Soutis C. Measurement of the Static Compressive Strength of Carbon-
J Compos Mater 1977;11:366–77. Fibre/Epoxy Laminates. Composites Science and Technology 1991;
[23] Rowlands RE. Strength (failure) theories and their experimental 42:373–92.
correlation. In: Sih GC, Skudra AM, editors. Failure mechanics of [29] Lin W-P, Hu H-T. Nonlinear analysis of fiber-reinforced composite
composites. Amsterdam, The Netherlands: Elsevier; 1985. p. 71–125. laminates subjected to uniaxial tensile load. Journal of Composite
[24] Stanely GM. Continuum-based shell element.PhD Thesis.Department Materials 2002;36:1429–50.
of Mechanical Engineering, Stanford University;1985. [30] Lin W-P, Hu H-T. Parametric study on the failure of fiber-reinforced
[25] Morley LSD. Skew plates and structures. New York: Macmillan; composite laminates under biaxial tensile load. Journal of Composite
1963. Materials 2002;36:1481–504.