Nama : Aisyah Larasaty .

S
NPM : 2027011002

Dicari Energi aktivasi Ea dan faktor frekuensi tumbukan (A) ?

Jawab :

T (K) K(L/gmol.detik) 1/T (K-1) Ln K

700 0.011 0.001429 -4.5099
730 0.035 0.00137 -3.3524
760 0.105 0.001316 -2.2537
790 0.343 0.001266 -1.0700
810 0.789 0.001235 -0.23698
840 2.17 0.0012 0.77472
910 20.0 0.001099 2.99573
1000 145 0.001 4.97673
 6

f(x) = − 22650.72 x + 27.71

4 R² = 1

ln k
0
0 0 0 0 0 0 0
-2

-4

-6

1/T (Kelvin-1)

Ea
K = Ae - RT

Berdasarkan plot linier di samping, diperoleh :

Kemiringan garis (slope) =
Ea = -22651 K
= - RT

lntersept = ln
A = 27,70

Maka R = 0,998 kal/gmol.K

Ea = -(0,998 kal/gmol.K) (-22651 K)

= 22,605 kkal/gmol
A = exp (27,70) = 1,07141 x 1012
=

Ln k = - Ea/R 1/T + ln A

Y=MX+B
DARI KIURVA DIPEROLEH PERSAMAAN Y = -22651X + 27,707  Y = MX B
A) M = SLOPE = -22651 MAKA M = -Ea/R slope : -22650,75
Ea = - (slope x R) = 188318,295 J/mol intersept : 27,70711

B) B = intersept = ln A = 27,707
A= exp (27,707) = 1,079E+12 9,2673E-13

C) ln k = -(-22651)/8,314 x 500 + ln A
ln k = 33,156
k = 2,509E + 14