Soal:

0,5 kg/menit gas butana dibakar dengan 100% udara berlebih, reaktan masuk ruang pembakaran pada
temperature 25oC, tentukan temperature pembakaran. Berapa panas reaksi yang keluar

Penyelesaian:

Udara berlebih

100%

25oC
T…….?
0,5 kg/menit CO2

N2

O2 berlebih

H2O

Penyelesaian:

C4H10 + 13/2 O2 4 CO2 + 5H2O

0,5 kg/menit
1000 grmol
n C4H10 = kg = 8,62 x 10-3 kgmol/menit x = 8,62 grmol/menit
58 1 kgmol
kgmol

13
O2 teoritis = x 8,62 grmol/menit = 56,03 grmol/menit
2

O2 dari udara = (100 + 100)% x 56,03 grmol/menit = 112,06 grmol/menit

O2 berlebih = (112,06 – 56,03) grmol/menit

79
N2 dari udara = x 112,06 grmol/menit = 421,56 grmol/menit
21

n H2O = 5 x 8,62 grmol/menit = 43,1 grmol/menit

n CO2 = 4 x 8,62 grmol/menit = 34,48 grmol/menit

∆HoR = ∆Hp

Cp fungsi temperature

Cp CO2 = 6,339 + 10,14 x 10-3 T – 3,425 x 10-6 T2

Cp O2 = 6,117 + 3,167 x 10-3 T – 1,005 x 10-6 T2

Cp N2 = 6,457 + 1,389 x 10-3 T – 0,069 x 10-6 T2

Cp H2O = 7,136 + 2,640 x 10-3 T + 0,0459 x 10-6 T2

T
Q CO2 = n ∫ ❑Cp dT
298

10,14 3415
[
= 34,48 grmol/menit 6,339 (T-298) + 2 x 10 -3
(T 2
-298 2 −¿
) -6 3 3
3 x 10 (T -298 ) ]
= 218,56872T – 65133,47856 + 0,1748136T2 – 15524,14693 – 3,92 x 10-5 T3 + 1037,372

= 218,56872T + 0,1748136T2 – 3,92 x 10-5 T3 – 79620,25

T
Q O2 = n ∫ ❑Cp dT
298

3,167 1,005
[
= 56,03 grmol/menit 6,117 (T-298) + 2 x 10 -3
(T 2
-298 2 –
) -6 3 3
3 x 10 (T -298 ) ]
= 342,73551T – 102135,182 + 0,0887T2 – 7876,9148 – 1,877005 x 10-5 T3 + 496,722

= 342,73551T + 0,0887T2 – 1,877005 x 10-5 T3 – 109515,37

T
Q N2 = n ∫ ❑Cp dT
298

1,389 0,069
[
= 421,56 grmol/menit 6,457 (T-298) + 2 x 10 -3
(T 2
-298 2 –
) -6 3 3
3 x 10 (T -298 ) ]
= 2722,01292T – 811159,8502 + 0,29277T2 – 25999,14708 – 9,69588 x 10-6 T3 + 256,5878

= 2722,01292T + 0,29277T2 – 9,69588 x 10-6 T3 – 836902,4095

T
Q H2O = n ∫ ❑Cp dT
298

2,640 0,0459
[
= 43,1 grmol/menit 7,136 (T-298) + 2 x 10 -3
(T 2
-298 2 –
) 3 x 10-6 (T3-2983) ]
= 307,5616T – 91653,3568 + 0,056892T2 – 5052,237168 + 6,5943 x 10-7 T3 – 17,4508

= 307,5616T + 0,056892T2 – 6,5943 x 10-7 T3 – 96723,04477

Q campuran = 3590,87875T + 0,6131756T2 – 6,70065 x 10-5 T3 – 1122761,079

T (1600o K)

Q = 3590,87875 grcal/menit K (1600 K) + 0,6131756 grcal/menit K (16002)K – 6,70065 x 10-5

grcal/menit K (16003) K – 1122761,079

Q = 5917915,833 grcal/menit

T (1625o K)

Q = 3590,87875 grcal/menit K (1625 K) + 0,6131756 grcal/menit K (16252)K – 6,70065 x 10-5

grcal/menit K (16253) K – 1122761,079

Q = 6044057,77 grcal/menit

Interpolasi

X1 = 1600o K y1 = 5917915,833 grcal/menit

X2 = 1625o K y2 = 6044057,77 grcal/menit

y− y 1
X= . (x2-x1) + x1
y 2− y 1

( 5930404,84−5917915,833 ) grmol/menit
X= x (1625-1600) K + 1600 K = 1602,475 K
( 6044057,77−5917915,833 ) grmol/menit

Temperature pembakaran = 1602,475 K

Q out = (Q in + Q pembakaran) – Q loss

Qin pada T = 25o C

Q = 0

∆HoC = 687,982 Kcal/grmol

Q pembakaran C4H10 = 8,62 grmol/menit x 687982 cal/grmol

= 5930404,84 cal/menit

Q loss = 530 kw

530 kw 860,42065 kcal/h 1000 cal 1 jam

1 Kw 1 Kcal 60 menit

= 7600382,408 cal/menit

Q out = ( 0 + 5930404,84) cal/menit – 7600382,408 cal/menit

= -1669977,568 cal/menit