Done by
Project Guide
Dr. P V Indira
National Institute of Technology, Calicut
MINI PROJECT
CERTIFICATE
This is to certify that this is a bonafide record of the project presented by the students, whose
names are given below, during Monsoon Semester 2010-11 in partial fulfillment of the
requirement of the course on environmental studies.
Project Guide
Course Coordinator
ACKNOWLEGEMENTS
We would like to thank the following for their kind support and valuable information provided
without whom it would have been impossible to complete the project successfully.
• Dr. Mini Remanan, faculty incharge of Mini Project Course for giving us this
opportunity.
• Dr. P V Indira, faculty guide for the project for her guidance and moral support.
• Mr. Y. Vijaya Bhaskar, M. Tech 2nd year, NIT Calicut for providing valuable information
regarding our project.
THANK YOU
Group Members
BRIEF DESCRIPTION OF THE WORK PROPOSED AND METHODOLOGY:
INTRODUCTION:
properties (compressive strength, split tensile strength, flexure strength) of self curing concrete
with Proper curing of concrete structures is important to ensure they meet their intended
performance and durability requirements. Internal curing (IC) is a very promising technique that
can provide additional moisture in concrete for a more effective hydration of the cement. During
hydration of cement, empty pores are created within the cement paste, leading to a reduction in
its internal relative humidity and cause cracks to develop at the early-age. This situation is
intensified in HPC which can be solved by using the self curing agents like polyethylene glycol
as they can retain the moisture for a long period of time.
Depletion of natural coarse aggregate and disposal of construction and demolition waste are
currently two problems of increasing magnitude, faced by infrastructure development sector.
Recycling demolished concrete waste as an alternative source of coarse aggregate for the
production of new concrete can help solve simultaneously the growing waste disposal crisis and
the problem of short supply of natural coarse aggregate for concrete. This practice leads to
eagerly awaited and preservation of environment to escape from climate disasters. Under the
pressure of these problems, several studies are reported in different countries on recycled coarse
aggregate.
OBJECTIVE OF THE PROJECT:
Our investigation is presented on evaluating the structural recycled coarse aggregate (RCA) and
concrete with conventional coarse aggregate (CCA), for comparison.
METHODOLOGY:
To acquire knowledge on self curing concrete with RCA, 12 cube specimens will be cast and
tested for determining the compressive strength, 12 cylinder specimens will be cast and tested for
determining the split tensile strength, 2 beams will be cast and tested for flexural strength and the
above procedure is repeated for concrete with conventional coarse aggregate, for comparison.
INDEX
Chapters:
1. Introduction
1.1 General
1.2 Recycled aggregate
1.3 Polyethylene glycol
2. Literature Review
2.1 Self curing of concrete using self curing agents
2.2 Self curing of concrete using LWA
3. Experimental Programme
3.1 Materials used
3.2 Casting programme
3.3 Testing programme
3.4 Experimental investigations
4. Results and Discussion
4.1 Effect of PEG 600 on properties of concrete
4.2 Effect of recycled coarse aggregate on properties of concrete
5. Conclusion
CHAPTER – 1
INTRODUCTION
1.1 GENERAL
Proper curing of concrete structures is important to ensure they meet their intended
performance and durability requirements. In conventional construction, this is achieved through
external curing, applied after mixing, placing and finishing. Internal curing (IC) is a very
promising technique that can provide additional moisture in concrete for a more effective
hydration of the cement and reduced self-desiccation. Internal curing implies the introduction of
a curing agent into concrete that will provide this additional moisture. Currently, there are two
major methods available for internal curing of concrete. The first method uses saturated porous
lightweight aggregate (LWA) in order to supply an internal source of water, which can replace
the water consumed by chemical shrinkage during cement hydration. The second method uses
super-absorbent polymers (SAP), as these particles can absorb a very large quantity of water
during concrete mixing and form large inclusions containing free water, thus preventing self-
desiccation during cement hydration. For optimum performance, the internal curing agent should
possess high water absorption capacity and high water desorption rates. Detailed information on
internal curing can be found in the new state-of-the-art report on internal curing of concrete from
RILEM TC-196.
The ACI-308 Code states that “internal curing refers to the process by which the
hydration of cement occurs because of the availability of additional internal water that is not part
of the mixing Water.” Conventionally, curing concrete means creating conditions such that water
is not lost from the surface i.e., curing is taken to happen ‘from the outside to inside’. In contrast,
‘internal curing’ is allowing for curing ‘from the inside to outside’ through the internal reservoirs
(in the form of saturated lightweight fine aggregates, superabsorbent polymers, or saturated
wood fibres) created. ‘Internal curing’ is often also referred as ‘Self–curing.’
When the mineral admixtures react completely in a blended cement system, their demand
for curing water (external or internal) can be much greater than that in a conventional ordinary
Portland cement concrete [10]. When this water is not readily available, due to depercolation of the
capillary porosity, for example, significant autogenous deformation and (early-age) cracking may
result.
Due to the chemical shrinkage occurring during cement hydration, empty pores are
created within the cement paste, leading to a reduction in its internal relative humidity and also
to shrinkage which may cause early-age cracking. This situation is intensified in HPC (compared
to conventional concrete) due to its generally higher cement content, reduced water/cement (w/c)
ratio and the pozzolanic mineral admixtures (fly ash, silica fume). The empty pores created
during self-desiccation induce shrinkage stresses and also influence the kinetics of cement
hydration process, limiting the final degree of hydration. The strength achieved by IC could be
more than that possible under saturated curing conditions.
Often specially in HPC, it is not easily possible to provide curing water from the top surface at
the rate required to satisfy the ongoing chemical shrinkage, due to the extremely low
permeabilities often achieved.
Continuous evaporation of moisture takes place from an exposed surface due to the
difference in chemical potentials (free energy) between the vapour and liquid phases. The
polymers added in the mix mainly form hydrogen bonds with water molecules and reduce the
chemical potential of the molecules which in turn reduces the vapour pressure, thus reducing the
rate of evaporation from the surface.
Some specific water-soluble chemicals added during the mixing can reduce water
evaporation from and within the set concrete, making it ‘self-curing.’ The chemicals should have
abilities to reduce evaporation from solution and to improve water retention in ordinary Portland
cement matrix.
1.1.7 Means of Providing Water for Self–curing using Light Weight Aggregates
1. Measuring weight-loss
6. Compressive strength
9. Water permeability
a. Internal curing (IC) is a method to provide the water to hydrate all the cement, accomplishing
what the mixing water alone cannot do. In low w/c ratio mixes (under 0.43 and increasingly
those below 0.40) absorptive lightweight aggregate, replacing some of the coarse aggregates,
provides water that is desorbed into the mortar fraction (paste) to be used as additional curing
water. The cement, not hydrated by low amount of mixing water, will have more water
available to it.
b. IC provides water to keep the relative humidity (RH) high, keeping self-desiccation from
occurring.
e. IC can make up for some of the deficiencies of external curing, both human related (critical
period when curing is required in the first 12 to 72 hours) and hydration related (because
hydration products clog the passageways needed for the fluid curing water to travel to the
cement particles thirsting for water). Following factors establish the dynamics of water
movement to the unhydrated cement particles:
ii. Capillary action of the pores in the concrete is very strong, and
iii. Water in the properly distributed particles of LWA (fine) is very fluid.
• Need for: reduced construction time, quicker turnaround time in precast plants, lower
maintenance cost, greater performance and predictability.
• Reduces permeability,
• Improved rheology
• Lower maintenance,
• Sharper edges,
• Higher performance,
The transport distance of water within the concrete is limited by de-percolation of the
capillary pores in low w/c ratio pastes. With water-reservoirs well distributed within the matrix,
shorter distances have to be covered by the curing water and the efficiency of the internal-curing
process is consequently improved. The concept of internal curing was established, based on
dispersion of very small, saturated LWA throughout the concrete, which serve as tiny reservoirs
with sufficient water to compensate for self-desiccation. The spacing between the LWA particles
is conveniently small so that the water travels smaller distances to counteract self-desiccation.
The amount of water in the LWA can therefore be minimized, thus economising on the content
of the LWA.
The IC can influence the ‘Early- Age Cracking Contributors’ which are mainly thermal
effects and autogenous shrinkage. During initial ages of concrete, hydration heat can raise
concrete temperature significantly (causing expansion), subsequent thermal contraction during
cooling can lead to early-age (global or local) cracking if restrained (globally or locally).
Another prominent effect would be autogenous shrinkage, especially in concretes with lower
water-binder ratios where sufficient curing water cannot be supplied externally, the chemical
shrinkage accompanying the hydration reactions will lead to self-desiccation and significant
autogenous shrinkage (and possibly cracking).
• Internal RH
• Autogenous deformation
• Degree of hydration
Taking the concept of sustainable development into consideration, the concrete industry need
to implement a variety of strategies with regard to future concrete use, for instance; improvement
in the durability of concrete and better use of recycled materials. In general, aggregates occupy
55% to 80% of concrete volume. Without proper alternative aggregates being utilized in the near
future, the concrete industry globally will consume 8 to 12 billion tonnes annually of natural
aggregates after the year 2010[11]. Such large consumption of natural aggregates will cause
destruction of the environment. Therefore, finding a suitable substitute for natural aggregates is
an urgent task. Even though the utilization of recycled aggregates is being done in the concrete
industry for many years, the promotion of this recycled material as an alternative has never been
easy in the industry.
Construction and Demolition (C&D) [11] waste constitutes a major portion of total solid waste
production in the world, and most of it is used in landfills. Research by concrete engineers has
clearly suggested the possibility of appropriately treating and reusing such waste as aggregate in
new concrete, especially in lower level applications. Initially, recycling of demolition waste was
first carried out after the Second World War in Germany (Khalaf et al.) [12]. since then, research
work carried out in several countries has demonstrated sufficient promise for developing use of
construction waste as a constituent in new concrete. Construction and demolition (C&D) waste
could be broken concrete, bricks from buildings, or broken pavement. Thus, Recycled Aggregate
(RA) could come from the demolition of buildings, bridge supports, airport runways, and
concrete roadbeds. Concrete made using such aggregates is referred to as recycled aggregate
concrete (RAC).
The significant research is in progress in the United States of America, the United Kingdom.
And encouraging results advocating utilization recycled aggregate for construction purposes,
especially for pavements of all types. Comprehensive research work is in progress at many place
including India to remove these reservations, many of the above countries have started
formulating their codes of standards /practice as guidelines for use of recycle aggregates for
construction purpose.
The problems in India are not as alarming as in the west. However, the day would not be very
far off, when India to may have to seriously think of reusing demolished rubble and concrete for
production of recycled construction material especially in the form of aggregate. There some
parts in northern India, especially, in the Gangetic basin, where crushed stone aggregate is not
available within several kilometers of radius. Conservation of natural resources in order to keep
ecological balance is the need for India too.
Processing of recycled material is a relatively simple process, but one that can require
expensive, heavy-duty equipment, capable of handling a variety of materials. Technology
basically involves crushing, sizing, and blending to meet the required product mix. The
schematic diagram of the recycled processing plant is shown in fig2.
There are many advantages through using the recycled aggregate. The advantages that
occur through usage of recycled aggregate are listed below.
• Environmental Gain
The major advantage is based on the environmental gain. Construction and demolition
waste makes up to around 40% of the total waste each year (estimate around 14 million tons)
going to land fill. Through recycled these material, it can keep diminishing the resources of
urban aggregated. Therefore, natural aggregate can be used in higher grade applications.
• Save Energy
The recycling process can be done on site. According to Kajima Technical Research
Institute (2002), Kajima is developing a method of recycling crushed concrete that used in the
construction, known as the Within-Site Recycling System. Everything can be done on the
construction site through this system, from the process of recycled aggregate, manufacture and
use them. This can save energy to transport the recycled materials to the recycling plants.
• Cost
Secondly is based on the cost. The cost of recycled aggregate is cheaper than virgin
aggregate. It depends on the aggregate size limitation and local availability. This is just around
one and half of the cost for natural aggregate that used in the construction works. In small scale
projects, where recycling plant proves to be costlier hand broken recycled aggregates can also be
used. Research is going on application of hand broken recycled aggregates.
• Sustainability
The amount of waste materials used for landfill will be reducing through usage of
recycled aggregate. This will reduce the amount of quarrying. Therefore this will extend the lives
of natural resources and also extend the lives of sites that using for landfill.
1.2.2 Disadvantages
Although there are many advantages by using recycled aggregate. But there are still some
disadvantages in recycled aggregate.
There is no specification or any guideline when using recycled concrete aggregate in the
constructions. In many cases, the strength characteristic will not meet the requirement when
using recycled concrete aggregate. Therefore, more testing should be considered when using
recycled concrete aggregate.
• Water Pollution
The recycled process will cause water pollution. The wash out water with the high pH is a
serious environmental issue. According to Building Green (1993), the alkalinity level of wash
water from the recycling plants is pH=12. This water is toxic to the fish and other aquatic life.
They are used to make emulsifying agents and detergents, and as plasticizers, humectants,
and water-soluble textile lubricants. The wide range of chain lengths provides identical physical
and chemical properties for the proper application selections directly or indirectly in the field of;
• Alkyd and polyester resin preparation to enhance water dispersability and water-based
coatings.
• Cleaners, detergents and soaps with low volatility and low toxicity solvent properties.
• Coupling agent, humectant, solvent and lubricant in cosmetics and personal care bases.
• Low volatile, water soluble and noncorrosive lubricant without staining residue in food and
package process.
LITERATURE REVIEW
Ole Mejlhede Jensen, Per Freiesleben Hansen [1] describes a new concept for the
prevention of self-desiccation in hardening cement-based materials. The concept consists of
using fine, superabsorbent polymer (SAP) particles as a concrete admixture. The SAP will
absorb water and form macro inclusions, which essentially consist of nothing but free water. This
leads to water entrainment, i.e. the formation of water-filled macro pore inclusions in the fresh
concrete. Consequently, the pore structure is actively designed to control self-desiccation. In his
work, self-desiccation and water entrainment are described and discussed. The description is
based on a reinterpretation of Powers' model for the phase distribution of a hydrating cement
paste.
Roland Tak Yong Liang, Robert Keith Sun [2] carried work on internal curing
composition for concrete which includes a glycol and a wax. The invention was based on the
observation that a combination of a wax and a glycol, when added to concrete, enables internal
curing of concrete which in many respects is equal to or superior to traditional forms of curing
concrete. The invention provides for the first time an internal curing composition which, when
added to concrete or other cementitious mixes meets the required standards of curing as per
Australian Standard AS 3799. A preferred internal curing composition according to the invention
includes a paraffin wax and a PEG of MW about 200.
Wen-Chen Jau [3] stated that “A Self Curing Concrete is provided to absorb water from
moisture from air to achieve better hydration of cement in concrete. It solves the problem that the
degree of cement hydration is lowered due to no curing or improper curing, and thus
unsatisfactory properties of concrete. According to the invention, high-performance self-curing
agent about 0.1~5 wt % of cement weight of the concrete is added to the concrete during mixing.
The self-curing agent can absorb moisture from atmosphere and then release it to concrete. The
self-curing concrete means that no curing is required for concrete, or even no external supplied
water is required after placing. The properties of the self-cured concrete of the invention are at
least comparable to even better than those of concrete with traditional curing.” In his invention
self curing agent contains poly-acrylic acid which has strong capability of absorbing moisture
from atmosphere and providing water required for curing concrete and also contains polyvalent
alcohol, selected from the group consisting of PEG, PG, DPG etc. His works are carried out at
RH of 50% ~ 85%.
A.S. El-Dieb [4] investigated water retention of concrete using water-soluble polymeric
glycol as self-curing agent. Concrete weight loss and internal relative humidity measurements
with time were carried out, in order to evaluate the water retention of self-curing concrete. Non-
evaporable water at different ages was measured to evaluate the hydration. Water transport
through concrete is evaluated by measuring absorption%, permeable voids%, water sorptivity,
and water permeability. The water transport through self-curing concrete is evaluated with age.
The effect of the concrete mix proportions on the performance of self-curing concrete were
investigated, such as, cement content and water/cement ratio.
Pietro Lura [5] carried work on autogenous deformation of cementitious materials and
internal curing as a means to reduce early-age shrinkage and self-induced stresses. The main aim
of his study was to reach a better comprehension of autogenous shrinkage in order to be able to
model it and possibly reduce it. Once the important role of self-desiccation shrinkage in
autogenous shrinkage is shown, the benefices of avoiding self-desiccation through internal
curing become apparent.
Silvia Weber and Hans W. Reinhardt [6] in 1996-97 introduced a new type of high
performance concrete by replacing 25% by volume of the aggregates by prewetted LWA which
creates water storage inside the concrete, which supports continuous wet curing. The most
important mechanical properties of the concrete under various curing conditions and the
microstructure of the hardened cement paste were investigated. The results obtained showed that
method of introducing a water reservoir can be successfully applied to obtain HPC with
improved properties while being relatively insensitive to curing.
Daniel Cusson and Ted Hoogeveen [9] carried work on “Internal curing of high-
performance concrete with pre-soaked fine lightweight aggregate for prevention of autogenous
shrinkage cracking”. Internal curing was supplied by pre-soaked fine LWA as a partial
replacement to regular sand. It was found that the use of 178 kg/m3 of saturated LWA in HPC,
providing 27 kg/m3 of IC water eliminated the tensile stress due to restrained autogenous
shrinkage without compromising the early-age strength and elastic modulus of HPC. Autogenous
expansion, observed during the first day for high levels of internal curing, can significantly
reduce the risk of cracking in concrete structures, as both the elastic and creep strains develop
initially in compression, enabling the tensile strength to increase further before tensile stresses
start to initiate later.
CHAPTER – 3
EXPERIMENTAL PROGRAMME
The experimental program was designed to investigate the strength of Self Curing of
Concrete using Polyethylene Glycol-600(PEG) with 100% replacement of Natural Aggregate
with Recycled Coarse Aggregate for the grade M25 on compressive strength, split tensile
strength, flexure strength.
The program consisted of casting and testing a total number of 18 cubes of size 150 X
150 X 150mm, 2 cylinders, 2 beams. Of these 6 cubes each correspond to normal curing concrete
with ordinary coarse aggregate, self curing concrete with ordinary coarse aggregate, self curing
concrete with recycled coarse aggregate. In this 3 cubes each correspond to curing for 7 days and
28days strength. 1 cylinder and 1 beam each correspond to self curing concrete with ordinary
coarse aggregate, self curing concrete with recycled coarse aggregate.
The fine aggregate conforming to zone III according to IS: 383-1970 was used.
The fine aggregate used was obtained from a near river source. The specific gravity of the sand
used was 2.54. The sand obtained was sieved as per IS sieves (i.e. 475, 2.36, 1.18, 600, 300, and
150µ). The details of particle size distribution and grading are given in table3.1.
Table 3.1 Proportions of different size fractions of sand
%passing
%Weight Cumulative
Sieve size Weight
retained % Passing Recommended
retained % weight
(mm) (gm) By IS:383-
(%) retained
1970
4.75 7 1.4 1.4 98.60 90-100
2.36 12 2.4 3.8 96.20 75-100
1.18 20 4.0 7.8 92.20 55-90
0.60 65 13.0 20.8 79.00 35-59
0.30 292 58.4 79.2 30.00 8-30
0.15 90 18.0 97.20 2.80 0-10
Crushed granite and RCA was used as coarse aggregate. The coarse aggregate
according to IS: 383-1970 was used. Maximum coarse aggregate size used 20 mm. The details of
particle size distribution and grading are given in table 3.2. Properties of natural & recycled
aggregate as shown in table 3.3.
%passing
%Weight Cumulative
Sieve size Weight
retained % Passing Recommended
retained % weight
(mm) (gm) By IS:383-
(%) retained
1970
40 - - - 100 100
20 - - - 100 95-100
16 1.428 28.56 28.56 71.44 75-90
12.5 1.545 30.90 59.46 40.54 60-75
10 1.323 26.46 85.92 14.08 25-55
4.75 0.668 13.36 99.28 0.72 0-10
Table-3.3 Properties of natural & recycled aggregate concretes:
NA RCA
Properties
Polyethylene glycol is a condensation polymers of ethylene oxide and water with the
general formula H(OCH2CH2)nOH, where n is the average number of repeating oxyethylene
groups typically from 4 to about 180. The abbreviation (PEG) is termed in combination with a
numeric suffix which indicates the average molecular weights. One common feature of PEG
appears to be the water-soluble. Specifications of PEG-600 are listed in table 3.4.
Polyethylene Glycol-600
Molecular Weight 600
Appearance Clear liquid
pH 5–7
Specific Gravity 1.126
3.1.5 Water:
Potable water was used in the experimental work for both mixing and curing purposes.
No. of CA ( Kg)
Nomenclat Cubes
PEG
ure + Cement FA Water
S.No Recycled (600)
of Mix Cylinders (Kg) (Kg) Natural (kg)
(ml)
+
Beams
1 NC-C-0 6+0+0 11.0 13.35 28.677 28.677 4.84 0
CHAPTER – 4
Table 4.1 shows the compressive strengths of the mix NC-C-0 and SC-C-1. From the
figure 1, it shows that there is a decrease in strength for 1% PEG used specimens when compared
to 0% PEG used specimens which were kept in wet curing. In the mix SC-C-1 the cube
specimens with 1% PEG have shown difference in the strength which is comparable to the NC-
C-0 cube specimens.
Table 4.1 shows the compressive strengths of the mix SC-C-1 and SC-R-1 and from the
figure 2, it is clear that the difference in strengths between the cube specimens with conventional
coarse aggregate and recycled coarse aggregate after 7 days of self curing is comparable where
as there is marginal difference between the cube specimens with conventional coarse aggregate
and recycled coarse aggregate after 28 days of self curing.
Table 4.1 shows the split tensile strengths of the mix SC-C-1 and SC-R-1 and, it is clear
that there is a marginal difference in tensile strengths between the cylinder specimens with
conventional coarse aggregate and recycled coarse aggregate.
Table 4.1 shows the flexure strengths of the mix SC-C-1 and SC-R-1 and, the table
shows that there is a marginal difference in tensile strengths between the cylinder specimens with
conventional coarse aggregate and recycled coarse aggregate.
Figure 1
Figure 2
CHAPTER – 5
CONCLUSIONS
➢ For the specimen with the 0% and 1% self curing agent, the mix SC-C-1 showed
compressive strength which is comparable with that of NC-C-0 after 7 days of curing. For the
specimen with the 1% self curing agent, the mix SC-C-1 showed a significant difference in
compressive strength after 28 days.
➢ For the specimen with the 1% self curing agent, the mix with conventional coarse aggregate
showed more split tensile strength than the mix with recycled coarse aggregate.
➢ For the specimen with the 1% self curing agent, the mix with conventional coarse aggregate
showed more flexure strength than the mix with recycled coarse aggregate.
REFERENCES
1. Roland Tak Yong Liang, Robert Keith Sun, “Compositions and Methods for Curing
Concrete”, Patent No. U.S. 6,468,344 B1 dated Oct. 22, 2002.
2. Wen-Chen Jau, “Self Curing Concrete”, Patent Application Publication No. U.S.
2008/0072799 A1 dated Mar. 27, 2008.
3. Ambily P.S, and Rajamane N P, “Self Curing Concrete An Introduction”, Structural
Engineering Research Centre, CSIR, Chennai.
4. Khalaf FM and DeVenny Alan S. “Recycling of demolished masonry rubble as coarse
aggregate in Concrete: review”. ASCE J Mater Civil Eng 2004:331–40.
5. Akash Raoa, Kumar N. Jha B, Sudhir Misra “Use of aggregates from recycled
construction and demolition waste in concrete”, Journal of Resources, Conservation and
Recycling (2006), Elsevier B.V.
6. D. S. R Murthy, S. Kanaka Durga “Performance of structural concrete with recycled
coarse aggregate”, Journal of Structural Engineering, SERC, Chennai