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Multi-Effect Distillation

Multiple Effect
Distillation (MED)

IDE has been internationally recognized The combination of unparalleled


as a pioneer and market leader in the thermal efficiency, low temperature
delivery of Thermal Distillation plants operation, minimal scaling, easy
since its foundation in 1965. capacity regulation, stable automated
operation and the ability to utilize
MED plants utilize low grade input low grade, low cost energy sources
steam to produce distillate. The MED makes IDE MED the most cost efficient
unit is comprised of a train of horizontal seawater desalination unit available.
tubes and falling-film evaporative-
condensers, with a heat rejection IDE MED:
condenser at the end. Distillate is
produced in the MED unit through MED units are powered by heat from
repetitive steps of evaporation very low pressure (0.25 to 0.35 ata)
and condensation, each at a lower steam or hot water sources above
temperature and pressure - hence a 60°C. Where higher steam pressure
multiple quantity of distillate is obtained (over 2.0 ata) is available, the plant
from a given quantity of input steam. can be supplied with a thermal vapor
compression (TVC) unit. Use of a steam
jet thermo-compressor to recycle part
of the vapor in the MED unit further
increases its thermal efficiency.
IDE MED units are available with
capacities of up to 25,000 cu.m/day in a
single unit, with larger capacities being
realized by multiple unit installations.

• Low Temperature Seawater Distillation


• Low Pressure Steam Driven (Optional:
Cogeneration Scheme / Waste Heat
Recovery)
• Simple and Economical Operation
and Maintenance
• High Quality Product (5 ppm-TDS)
• Capacities: 600 - 25,000 cubic-meter/
day per unit

The MED process


Any number of evaporative-condensers
(effects) may be incorporated in
the plant’s heat recovery sections,
depending on the temperature / pressure
and cost of the available heat and
2 x MED-6,000 Kazakhstan – MAEK units
the optimal trade-off point between
investment and steam cost economy.
Technically the number of effects
is limited only by the temperature
difference between the steam and
seawater inlet temperatures (defining
the hot and cold ends of the unit) and
the minimum temperature differential
allowed on each effect.

The incoming seawater is de-aerated


and preheated in the heat rejection
condenser, and then divided into two
streams. One stream is discharged as
4 x MED-25,000
Tianjin, China

coolant (eg, back to the sea), and the


other becomes feed for the distillation
process.

The feed is pretreated with a scale


inhibiting additive and introduced
into the lowest temperature group of
heat recovery effects. A spray nozzle
system distributes it over the top
rows of tubes in each effect, where it
flows in thin films down each bank of
tubes. Part of the feed vaporizes as it
absorbs the latent heat released by
steam condensing inside the tubes.
The remaining feed, now slightly
concentrated, is pumped to the next
group of effects, which operate at
higher temperatures. The spray and
evaporation process is repeated there.
The remaining feed is pumped onward production, the MED unit can turn down
again until it leaves the hottest group of to as low as 65% of its nominal capacity
effects as concentrated brine. without operator intervention, and the
surplus steam may then be used for through the brine droplet separator
The production capacity of the MED increased electrical energy production. the vapor is drawn into the tubes of the
unit is proportional to, and inherently next effect, which operate at slightly
follows, the motive steam input. The input motive steam is fed into lower temperature and pressure.
Therefore the MED unit production the tubes of the hottest effect where
rate can be varied automatically by it condenses, releasing its latent The evaporation-condensation process
regulating the steam input rate. For heat to the saline water flowing over is repeated along the entire series
instance, in dual purpose installations the outer surface of the tubes. While of effects, each of which contributes
(power and water product), the system condensation (of steam/vapor) takes a significant amount of additional
will produce maximum quantities place on the inside of the tubes, there is distillate. The entire amount of
of fresh water during peak demand an almost equal amount of evaporation vapor obtained from the last effect is
periods – up to 110% of the nominal (of seawater) on the outside. In order to condensed by seawater coolant in a
rated output. During non-peak hours of maintain distillate purity, after passing heat rejection condenser.

MED and TVC process schematic

Heat Recovery Evaporator Effects Heat Rejection Condenser

Recycle Vapor High Pressure Steam High Pressure Steam


NCG
Seawater

High Pressure Steam


(for a TVC Plant)

Low Pressure Steam


(for a MED Plant)

Condensate Fresh Water


Tank
Brine

Coolant
Condensate Intermediate Scale Inhibitor
Return Pump Feed Pump Feed Pump
The condensate from the first effect The concentrated brine from the hottest
is collected, and part of the distillate effect is, like the distillate, cascaded
(equal to the amount of steam observed through a series of brine flash tanks and
by the MED unit) is returned to the flash-cooled to recover its heat. After
steam generator. The excess distillate, cooling, it is returned to the sea via the
above the original quantity of motive brine pump.
steam, flows into the first of a series of
special chambers, each ducted to the Non-Condensable Gases (NCG) are bled
cooler condensing section of the next from each tube, and then join the vapor
effect. Part of the distillate flashes off, flowing from one effect to the next,
cooling the remaining product stream, eventually reaching the condenser. From
while returning the heat given off to the there the NCG are concentrated inside
main body of heat recovery effects. the heat rejection condenser at the
cooler end of the MED and evacuated
The product stream is thus cascaded by a steam jet ejector or mechanical
and flash-cooled in stages. The heat that vacuum pumps.
is released increases the total efficiency
of the process. The cooled distillate
is finally discharged to storage by the
product delivery pump.

HIGHPRESS
URESTEAM
EXTRACTION STEAM
TO PROCESS
EXHAUST GASES

TURBINE

GEN. MED DESALINATION EXTRACTION STEAM


TO PROCESS
PLANT
STEAMTU
HRSG RBINE
FUEL
GEN. MED DESALINATION
BACK PRESSURE STEAM PLANT

PRODUCT GAS TURBINE


BACK PRESSURE STEAM

CONDENSATE
PRODUCT
RETURN TO BOILER
CONDENSATE
RETURN TO BOILER

SEA WATER INTAKE


SEA WATER INTAKE

BACK PRESSURE STEAM (0.25-0.35 BARA) BACK PRESSURE STEAM FROM COMBINED CYCLE
For very large, dual purpose applications ranging from 50 to This scheme is the optimal solution for IPP and/or Re-powering
500 MW and 20,000 to 200,000 tons/day of water. projects. Where combined cycles are applicable ranging from
50 to 600 MW, the installation of 10,000 to 160,000 ton/day of
water (respectively) is possible.

SYSTEM
AT 8 ATA EXHAUST GASES SYSTEM EXHAUST GASES
AT 8 ATA

MED DESALINATION MED DESALINATION


PLANT RECYCLE VAPOR PLANT RECYCLE VAPOR
W.H. HRSG
BOILER FUEL
DIESEL ENGINE

STEAM STEAM
JETTHERMOCOMPRESSOR JETTHERMOCOMPRESSOR
GAS TURBINE

FEED CONDENSATE FEED CONDENSATE

COOLINGW LUB. AIRCOOLER


PRODUCT ATER OILCOOLER PRODUCT
S.W. HEAT EX. S.W.
PUMP PUMP
COOLING WATER
COOLANT & COOLANT &
BRINE OUT BRINE OUT
MEVC-DIESEL DIESEL ENGINE
SYSTEM

WASTE HEAT FROM DIESEL ENGINE WASTE HEAT FROM GAS TURBINE
The MED will draw the motive energy from the waste heat Motive steam produced at the HRSG is used to activate a
recovered from the exhaust gases and the water cooling thermocompressor, thus increasing the economy ratio of the
system of a diesel engine. desalination plant.
TVC Thermal Vapor compression Extraction steam operation –
at anywhere from 2 to 10 ata:
Thermal Vapor Compression plants
utilize the MED system together with This scheme is applicable where the
a steam jet compressor. They are plant operates with an existing turbine,
designed for projects where relatively designed to supply 2- 10 ata. extraction
high steam pressure of 2 to 10 ata. is steam (eg, for an obsolete high
available. Due to the relatively high temperature MSF plant).
cost of this steam, a large number of
evaporation condenser heat recovery Two options are possible: A TVC plant
effects are normally justified. Optimal with a GOR in the range of 12 to 15, or
MED units have the thermo-compressor a MED plant fitted with an auxiliary low
operating across six or eight, of a total pressure steam turbine.
of anywhere up to fifteen, heat recovery
effects. As a result, MED-TVC plants The MED plant operating with low grade
feature superior efficiency, able to steam/heat offers superior economics,
achieve a Gain Operation Ratio GOR - but even the TVC plant, which
(a measure of energy efficiency) of consumes higher pressure steam,
15 tons distillate produced for each
ton of motive steam.

MED and TVC Economics


The ability of low temperature
distillation plants to make effective use
of low cost, low grade heat, or even
zero cost waste heat - where available
- maximizes the reduction of the energy
cost component of these plants.
Consequently, lower water production
costs can be obtained than with any
other seawater desalination system.

Low grade heat is available through will have lower operating costs than
cogeneration schemes with steam equivalent Seawater Reverse Osmosis
turbine, diesel generator and gas plants. 2 x MED - 17,500 units,
turbine power plants. The low grade Las Palmas,
heat is obtained through waste heat MED with an auxiliary Canary Islands, Spain
recovery from industrial cooling turbo-generator:
waters and exhaust gases, solid
waste incinerators, solar ponds and Another type of application, which
geothermal waters. expands the 2–10 ata extraction steam
in an auxiliary turbo-generator down
Steam cogeneration schemes to the 0.35 ata pressure required for
MED plant operation, will generate
Low grade steam operation – about 8 kWh of electric power per ton of
at anywhere from 0.3 to 0.4 ata: distilled water as a by-product.
This power will cover approximately the
Low temperature MED plants permit 1.2 kWh/ton required for MED process
further expansion of the steam in pumping, and the net saleable power
the turbine and minimize the losses exported will contribute anywhere from
in its heat rate, compared to high 15 to 60 US¢/ton, depending on the
temperature distillation plants that external selling price for power.
require motive steam of 2 to 3 ata.,
The cost of energy with extraction
There will be no loss of power steam operation will be limited, as with
output with this scheme if turbine back pressure turbine operation, to
throttle steam input is increased the cost of additional fuel consumed in
to compensate for back pressure order to generate the marginal quantity
operation. The cost of energy for the of throttle steam that is required to
desalination process will be limited maintain the same net power output.
to the marginal cost of fuel consumed
to generate the additional quantity of For the TVC plant option, the specific
steam required to maintain the same fuel consumption will be about 1.5 kg/ton
net power output. of product water. For the MED unit
with an auxiliary turbine scheme the
For back pressure steam MED plants, specific fuel consumption will be about
the specific fuel consumption will be in 2.2 kg/ton of product water. This fuel
the range of 1.2 to 1.7 kg only per ton of cost will, however, be somewhat offset
product water. by the benefit from the sale of by-product
power.
Diesel cogeneration schemes
In diesel generator cogeneration
schemes, most of the waste heat
3 x MED-5,000 unit
discharged by the diesel (through its US Virgin Islands (WAPA)
exhaust gases, jacket water and lube
oil cooling and if necessary, also from
charge air cooling) will be recovered.
This heat represents about 40-50% of
the diesel fuel heat content, increasing
overall thermal efficiency to over 80%.
200 – 250 tons/day of distillate can be
generated entirely by such waste heat,
for each MW of daily diesel generator
load.

The energy costs of a TVC plant


combined with the
diesel generator will
be limited to the
1.8 – 2.5 kWh/ton
required for process
and heat recovery
pumping.

Gas Turbine
and solid waste
incinerators will
operate with waste
heat boilers, and,
preferably, an
intermediate 4 x MED-24,000
steam turbine to RELIANCE
generate by-product Jamnagar Site
power.

Heated industrial coolant streams Waste heat from diesel engine


and solar and geothermal brines will The MED unit will draw the motive
most likely have their heat recovered energy from the waste heat recovered
and transferred, through plate type from the exhaust gases and the water
heat exchangers, to an intermediate, cooling system of a diesel engine.
recycled brine stream to avoid product
contamination. Waste heat from gas turbine
Motive steam produced at the HRSG is
Back pressure steam used to activate a Thermo-compressor
(0.25-0.35 Bara) (TVC), thus increasing the economy ratio
For very large, dual purpose of the desalination plant.
applications ranging from 50 to
500 MW and 20,000 to 200,000 tons/
day of water.
E 11.09

Back pressure steam from


combined cycle
This scheme is the optimal solution
for IPP and/or re-powering projects.
Combined cycles are applicable
ranging from 50 to 600 MW and
10,000 to 160,000 ton/day of water
(respectively).

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