Solution For Iit Jee 2011

DATE : 10/04/2011
Regd. Office : Aakash Tower, Plot No.-4, Sec-11, MLU, Dwarka, New Delhi-110075
Ph.: 011-47623456 Fax : 011-47623472
Time : 3 hrs.
Solutions Max. Marks: 240
for
IIT-JEE 2011
PAPER - 1 (Code - 4)
INSTRUCTIONS
1. The question paper consists of 3 parts (Chemistry, Physics and Mathematics). Each part consists
of four sections.
2. In Section I (Total Marks : 21), for each question you will be awarded 3 marks if you darken ONLY
the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other
cases, minus one (–1) mark will be awarded.
3. In Section II (Total Marks : 16), for each question you will be awarded 4 marks if you darken ALL
the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. There are no
negative marks in this section.
4. In Section III (Total Marks : 15), for each question you will be awarded 3 marks if you darken ONLY
the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other
cases, minus one (–1) mark will be awarded.
5. In Section IV (Total Marks : 28), for each question you will be awarded 4 marks if you darken
ONLY the bubble corresponding to the correct answer and zero marks otherwise. There are no
negative marks in this section.
IIT-JEE 2011 (Paper-1)
PART–I : CHEMISTRY
SECTION - I (Total Marks : 21)
(Single Correct Answer Type)
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
1. Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL. The molarity of
the solution is
(A) 1.78 M (B) 2.00 M (C) 2.05 M (D) 2.22 M
Answer (C)
wt. of solute 1000

Hints : M 
mol. wt. of solute volume of solution
120 1000
M  2.05
60 1120
1.15
2. AgNO3(aq.) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured.
The plot of conductance () versus the volume of AgNO3 is
   
td .)
e sL
e rvic
lS
na
volume volume
t i o
volume volume
(P) (Q)
u ca (R) (S)
Ed
sh
(A) (P) (B) (Q) (C) (R) (D) (S)
a ka
of A
Answer (D)
i on
vi s
Hints : Ag+ and K+ have nearly same ionic mobility
Di 3
 AgCl(s) + (KNO
AgNO3 + KCl 
conc. of KCl
3. Among the following compounds, the most acidic is

(A) p-nitrophenol (B) p-hydroxybenzoic acid (C) o-hydroxybenzoic acid (D) p-toluic acid
Answer (C)
O H O
–
C C

Hints : O –H O
H H
O O
Most acidic Stabilized by strong
intramolecular hydrogen
bonding
Aakash IIT-JEE - Regd. Office : Aakash Tower, Plot No. 4, Sector-11, Dwarka, New Delhi-75 Ph.: 011-47623417/23 Fax : 47623472
(2)
4. The major product of the following reaction is
O
C
(i) KOH
NH
C (ii) Br CH2 Cl
O
O O
C C
(A) N–CH2 Br (B) N CH2Cl
C C
O O
O O
C C
(C) N (D) N
O–CH2– Br O CH2Cl
Answer (A)
.)
More reactive
td
sL
site for SN2
e
rvic
O O
O
lClS e
a
C C Br CH2
N H
OH
N K
a t i on N CH2 Br
Hints :
du c
E
sh
C C
a ka O
of A
O O
i on
vi s
5. (D i
Extra pure N2 can be obtaine by heating
(A) NH3 with CuO (B) NH4NO3 (C) (NH4)2Cr2O7 (D) Ba(N3)2
Answer (D)
Hints : Ba(N3)2 
 Ba(s) + 3N2 
6. Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl–, CN– and H2O, respectively are
(A) Octahedral, tetrahedral and square planar
(B) Tetrahedral, square planar and octahedral
(C) Square planar, tetrahedral and octahedral
(D) Octahedral, square planar and octahedral
Answer (B)
Hints : Ni+2 + 4Cl– 

 [NiCl4]–2 (tetrahedral)
Ni+2 + 4CN– 
 Ni(CN)4–2 (square planar)
Ni+2 + H2O 
 Ni(H2O)6+2 (octahedral)
(3)
7. Bombardment of aluminium by -particle leads to its artificial disintegration in two ways, (i) and (ii) as shown.
Products X, Y and Z respectively are
(ii)
27 30
13Al 15P +Y
(i)
30 30
14 Si +X 14Si
+Z
(A) Proton, neutron, positron (B) Neutron, positron, proton
(C) Proton, positron, neutron (D) Positron, proton, neutron
Answer (A)
He4
Hints : 27
13 Al 
2
 30
14 Si  1H1
(X)
4
2 He
27
13 Al 
 30
15 P n
1
0
(Y)
30
14 Si  01 e
(Z)
SECTION - II (Total Marks : 16)

(Multiple Correct Answer Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE may be correct.
Amongst the given options the compound(s) in which all the atoms aresinLtone plane in all the possible
d. )
vice
8.
conformations (if any), is(are)
r
a l SHe
H H
i on
(A) C—C
ca tC—C
(B) H—C
d u
hE
H 2C CH2 CH2
s
ka(D)
a
of A
(C) H2C = C = O H2C = C = CH2
i on
Answer (B, C)
vi s
H (D i
Hints : C H
H
C
sp C
2
C C C O
H sp2 H
H
All atoms lie in one Planar

plane in all conformation
H
H
C C C
H is nonplanar
H
H
H
C C H
H C C
H H
Non-planar in many conformations due to rotation along.
C2 — C3 bond.
(4)
9. According to kinetic theory of gases
(A) Collisions are always elastic
(B) Heavier molecules transfer more momentum to the wall of the container
(C) Only a small number of molecules have very high velocity
(D) Between collisions the molecules move in straight lines with constant velocities
Answer (A, B, C)
Hints : According to Kinetic theory of gases
(i) Collisions are always elastic
(ii) Momentum transferred on wall
by one collision along x component = 2 mvx
Fraction of
(iii) molecule
Velocity
td .)
sL
vice is(are)
10. The correct statement(s) pertaining to the adsorption of a gas on a solid surface
er
lS
(A) Adsorption is always exothermic
a ti on a
du c
hE
(B) Physisorption may transform into chemisorption at high temperature
a s
(C) Physisorption increases with increasing temperature
f A ak but chemisorption decreases with increasing temperature
o
s i on
(D) Chemisorption is more exothermic that physisorption,
i
however it is very slow due to higher energy of activation
i v
Answer (B, D) (D
Hints : At high temperature, sufficient activation energy for chemical adsorption is provided.
Hadsorption for chemical lies between 200-400 kJ/mole. Chemisorption of H2 on glass is an endothermic process.
11. Extraction of metal from the ore cassiterite involves
(A) Carbon reduction of an oxide ore
(B) Self reduction of a sulphide ore
(C) Removal of copper impurity
(D) Removal of iron impurity
Answer (A, C, D)
1200 1300C
Hints : SnO2  Sn  CO
If after contain Fe and Cu as impurity,
(5)
SECTION - III (Total Marks : 15)

(Paragraph Type)
This section contains 2 paragraphs. Based upon one of the paragraph 2 multiple choice questions and based upon
the second paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices
(A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Questions Nos. 12 and 13

An acyclic hydrocarbon P, having molecular formula C6H10, gave acetone as the only organic product through the
following sequence of ractions, in which Q is an intermediate organic compound.
(i) conc. H2 SO4

(catalytic amount) O
(i) dil. H2SO4 / HgSO4 (–H2 O)
P Q 2 C
(ii) NaBH4 /ethanol (ii) O3
(C6H10) H3C CH3
(iii) dil. acid (iii) Zn /H2O
12. The structure of compound P is

(A) CH3CH2CH2CH2 – C  C – H (B) H3CH2C – C  C – CH2CH3
H3C H3C
(C) H – C – C  C – CH3 (D) H3C – C – C  C – H
H3C H3C
.)
Answer (D)
td
e sL
rvic
13. The structure of the compound Q is
lS e
aOH
H3C OH H3C
a t i on
(B) Hd c
u – C – C – CH3
3C
E
(A) H – C – C – CH2CH3
sh
a ka
H3C H H3C H
of A
i on
vi s
(D i
H3C OH OH
(C) H – C – CH2CHCH3 (D) CH 3CH 2CH 2CHCH 2CH 3
H3C
Answer (B)
Hints : (Q. 12 to Q.13)
O (i) NaBH4 OH
H3C 2+ + H3C + H3C
Hg /H3O (ii) dil H
H3C C – C C–H H3C C – C H3C C – C – H
H3C H3C CH3 H3C CH3

H3C H H3C H 
–H   H
C – C – CH3 H3C C – C
H3C CH3 H3C CH3
(i) O3
H3C CH3 CH3
(ii) Zn–H2O
C C 2 C O
H3C CH3 CH3
(6)
Paragraph for Questions Nos. 14 to 16

When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns
light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH3 dissolves
O and gives an intense blue solution.
14. The metal rod M is
(A) Fe (B) Cu (C) Ni (D) Co
Answer (B)
15. The compound N is

(A) AgNO3 (B) Zn(NO3)2 (C) Al(NO3)3 (D) Pb(NO3)2
Answer (A)
16. The final solution contains

(A) [Pb(NH3)4] 2+ and [CoCl4]2– (B) [Al(NH3)4] 3+ and [Cu(NH3)4] 2+
(C) [Ag(NH3)2]+ and [Cu(NH3)4 ] 2+ (D) [Ag(NH3)2]+ and [Ni(NH3)6 ] 2+
Answer (C)
Hints : (Q. 14 to Q.16)
Cu  Ag  Cu2  Ag
Ag  NaCl  AgCl

White ppt
td .)
e sL
AgCl  NH3 [Ag(NH3 )2 ] Cl
e rvic
a lS
Cu2  NH3  Cu(NH3 )24 a t i on
d u c
hE
(Blue)
ka s
M - Cu
f A a
io no
i vi s
N - Solution of AgNO3
O - AgCl (D
SECTION - IV (Total Marks : 28)
(Integer Answer Type)
This section contains 7 questions. The answer to each of the questions is a Single-digit integer, ranging from 0 to 9. The
bubble corresponding to the correct answer is to be darkened in the ORS.
17. The work function () of some metals is listed below. The number of metals which will show photoelectric effect
when light of 300 nm wavelength falls on the metal is
Metal Li Na K Mg Cu Ag Fe Pt W
 (eV) 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75
Answer (4)
Hints : Energy of incident photon should be higher than work function to slow photoelectric effect
6.62  1034  3  108

Energy of photon =  4.14 eV
300  109  1.6  1019
(7)
18. To an evacuated vessel with movable piston under external pressure of 1 atm., 0.1 mol of He and 1.0 mol of an
unknown compound (vapour pressure 0.68 atm. at 0°C) are introduced. Considering the ideal gas behaviour, the
total volume (in litre) of the gases at 0°C is close to
Answer (7)
1 atm PT = 1 atm
1 atm vapour pressure of compound = 0.68 atm
 PHe = 0.32
Hints :
PHeV = nHeRT
0.1 0.082  273

V= = 7 litre
0.32
19. Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate with evolution of CO2
gas. The number of sodium bromide molecules involved in the balanced chemical equation is
Answer (5)
Br2  2Br – 
.)
5
  5 Br2  2Br  10e 
–

td
Hints :
2 e 
e sL
e rvic
Br2 + 5Br2  10NaBr + 2NaBrO3 + 6CO2 + 6Na2CO3
a lS
a t i on
3Br2 + 3Na2CO3  5NaBr + NaBrO3 + 3CO2
d u c
hE
as of sulphur atoms in Na2S4O6 is
20. The difference in the oxidation numbers of the two ktypes
fA a
no
i si o
Answer (5)
v
Hints : Structure of S4O62– is (D i
O O
0
+5
O–S–S–S–S–O
O O
 Difference in oxidation state is +5 – 0 = +5.
21. A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and phenylalanine.
Glycine contributes 47.0% to the total weight of the hydrolysed products. The number of glycine units present
in the decapeptide is
Answer (6)
Hints : A decapeptide will have (9) peptide linkage
Mass of hydrolyzed product is (796 + 162) gm/mole
0.47  958
Number of glycine molecule = 6
75
(8)
22. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH
is
Answer (5)
Hints :
Br
3-bromo-3-cyclopentylhexane
Alc. KOH
+ +
(E + Z) (E + Z)
1 + 2 + 2
Total =5
Note : Dehydrobromination of alkyl bromides in the presence of alc. KOH follows E2 mechanism. Hence no
rearrangement in alkylchain is possible
23. The maximum number of electrons that can have principal quantum number, n = 3, and spin quantum number,
1
ms   , is
2
td .)
sL
Answer (9)
e
e rvic
Hints :
a lS
i on
3s 3p 3d
c a t
Out of 18 electrons present in 3rd shells.
d u
s hE
ka
1
Will have s  
f A a
no
2
io
i vi s
(D
PART–II : PHYSICS
This section contains 7 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which ONLY
ONE is correct.
24. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 Å. The wavelength of the
second spectral line in the Balmer series of singly-ionized helium atom is
(A) 1215 Å (B) 1640 Å (C) 2430 Å (D) 4687 Å
Answer (A)
1  1 1
Hints :  R – 
1 4 9
1 1 1 
 4R  – 
2  4 16 
2 5

1 27
 2 = 1215 Å
(9)
25. A ball of mass (m) 0.5 kg is attached to the end of a string having length (L) 0.5 m. The ball is rotated on a
horizontal circular path about vertical axis. The maximum tension that the string can bear is 324 N. The maximum
possible value of angular velocity of ball (in radian/s) is
(A) 9 (B) 18 (C) 27 (D) 36

Answer (D)
Hints : Tsin = m2l sin 
Tmax
 max =  T
ml
= 36 rad/s
T sin
26. A meter bridge is set-up as shown, to determine an unknown resistance X using a standard 10 ohm resistor. The
galvanometer shows null point when tapping key is at 52 cm mark. The end corrections are 1 cm and 2 cm
respectively for the ends A and B. The determined value of X is
X 10 
td .)
e sL
e rvic
a lS
a t i on
A
d u c B
shE
a ka(C)
fA
(A) 10.2 ohm (B) 10.6 ohm 10.8 ohm (D) 11.1 ohm
no
i si o
Answer (B)
v
X 10 (D i
Hints : 
53 50
 X = 10.6 
27. A 2 F capacitor is charged as shown in the figure. The percentage of its stored energy dissipated after the switch
S is turned to position 2 is
1 2
V 2 F 8 F
(A) 0% (B) 20% (C) 75% (D) 80%
(10)
Answer (D)
1
Hints : U1  C1V 2
2
q = C1V
q C1V
V 
C1  C2 C1  C2
V

5
1

Uf (C1  C2 )V 2
2
1
 C1V 2
10
U
 100 
80%
Ui
28. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall building which
reflects the sound waves. The speed of sound in air is 320 m/s. The frequency of the siren heard by the car driver
is
(A) 8.50 kHz (B) 8.25 kHz (C) 7.75 kHz (D) 7.50 kHz
Answer (A)
 v  v  u 
Hints : f = f0    td .)
v  u   v 
e sL
e rvic
 320  10 
a lS
i on
= 8  
 320 –10 
c a t
d u
s hE
ka
33
= 8
21
f A a
io no
i vi s
= 8.5 kHz
(D
29. 5.6 liter of helium gas at STP is adiabatically compressed to 0.7 liter. Taking the initial temperature to be T1, the
work done in the process is
9 3 15 9
(A) RT1 (B) RT1 (C) RT1 (D) RT1
8 2 8 2
Answer (A)
Hints : T1V1( – 1) = T2V2( – 1)
 –1
V 
T2 = T1  1 
 V2 
= 4T1 { = 5/3}
1
 = no. of moles =
4
–R(T2 – T1)
ext =
1– 
9
=  RT1
8
(11)

30. Consider an electric field E  E0 x , where E0 is a constant. The flux through the shaded area (as shown in the
figure) due to this field is
z
(a, 0, a) (a, a, a)
y
(0, 0, 0) (0, a, 0)
x
E0 a 2
(A) 2E0a2 (B) 2E0 a 2 (C) E 0 a 2 (D)
2
Answer (C)
 1  
Hints : A =  d1  d 2
2
= 
1 ˆ ˆ
2

ai  aj  akˆ  aiˆ – ajˆ  akˆ 
  
 = E  A E is constant
= E0a2
t d. )
c
This section contains 4 multiple choice questions. Each question has four choicese s L(A), (B), (C) and (D) out of which
rvi
l Se
n a
odisk of mass 'M' and radius 'R' (< L) is attached
atidisc
31. A metal rod of length 'L' and mass 'm' is pivoted at one end. A thin
at its center to the free end of the rod. Consider two waysuthe c
Edrotate about its center. The rod-disc system performs
is attached. ((case A): The disc is not free
to rotate about its center and (case B) the disc is freehto
SHM in vertical plane after being released from theka s displaced position. Which of the following statement(s)
a same
is (are) true?
n of A
io
D i vi s
(
(A) Restoring torque in case A = Restoring torque in case B

(B) Restoring torque in case A < Restoring torque in case B
(C) Angular frequency for case A > Angular frequency for case B
(D) Angular frequency for case A < Angular frequency for case B
Answer (A, D)
mgl mgl
Hints : B = 2
; A 
ml 1
ml 2  mr 2
2
(12)
32. A composite block is made of slabs A, B, C, D and E of different thermal conductivities (given in terms of a
constant K) and sizes (given in terms of length, L) as shown in the figure. All slabs are of same width. Heat 'Q'
flows only from left to right through the blocks. Then in steady state
0 1L 5L 6L
Heat
A B 3K E
1L
2K C 4K 6K
3L
D 5K
4L
(A) Heat flow through A and E slabs are same
(B) Heat flow through slab E is maximum
(C) Temperature difference across slab E is smallest
(D) Heat flow through C = heat flow through B + heat flow through D
Answer (A, C, D)
(D )
K  4L2 3K  4L2 ( B ) 4K  8L2 (C ) 5K  4L2
Hints : (T1 – T0 ) = (T2 – T1) + (T2 – T1 ) + (T2 – T1)
L 4L 4L 4L
(C) = (B) + (D)
33. An electron and a proton are moving on straight parallel paths with same velocity. They enter a semi-infinite region
of uniform magnetic field perpendicular to the velocity. Which of the following statement(s) is/are true?
(A) They will never come out of the magnetic field region
td .)
e sL
rvic
(B) They will come out travelling along parallel paths
lS e
a
(C) They will come out at the same time
a t i on
c
(D) They will come out at different times
d u
Answer (B, D)
s hE
a ka
f A
no
2
mv
 qvB
io
Hints :
i vi s
r
(D
mv
 r= p
qB
e
me < mp
 re < rp
 te < tp
34. A spherical metal shell A of radius RA and a solid metal sphere B of radius RB(< RA) are kept far apart and each
is given charge '+Q'. Now they are connected by a thin metal wire. Then
 A RB
(A) E Ainside  0 (B) QA > QB (C)   R (D) E Aon surface  E Bon surface
B A
Answer (A, B, C, D)
Hints : After connection,
VA = VB
qA qB
 R R
A B
(13)
EA(inside) = 0
 qA > qB
 A q A RB 2 RB
  
B qB RA 2 RA
E A  A RB
 
EB  B R A

(Paragraph Type)
This section contains 2 paragraphs. Based upon one of the paragraph 2 multiple choice questions and based on
the other paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices

A dense collection of equal number of electrons and positive ions is called neutral plasma. Certain solids containing
fixed positive ions surrounded by free electrons can be treated as neutral plasma. Let ‘N’ be the number density of
free electrons, each of mass ‘m’. When the electrons are subjected to an electric field, they are displaced relatively
away from the heavy positive ions. If the electric field becomes zero, the electrons begin to oscillate about the positive
ions with a natural angular frequency ‘p’, which is called the plasma frequency. To sustain the oscillations, a time
varying electric field needs to be applied that has an angular frequency , where a part of the energy is absorbed and
a part of it is reflected. As  approaches p, all the free electrons are set to resonance together and all the energy
.)
Lt d
is reflected. This is the explanation of high reflectivity of metals.
s
r vice analysis to determine the correct
35. Taking the electronic charge as ‘e’ and the permittivity as ‘0’, use dimensional
expression for p e lS
t i o na
uc a
Edm
m 0 m 0
2
Ne Ne
sh
(A) (B) (C) (D)
m 0
ka
Ne 0 Ne 2
f A a
Answer (C)
io no
( D i vi s
m–3  C2  Nm–2
Hints : {N = kg ms –2}
kg  C2
= s –2
36. Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons
N  4 × 1027 m–3. Take 0  10–11 and m  10–30, where these quantities are in proper SI units
(A) 800 nm (B) 600 nm (C) 300 nm (D) 200 nm
Answer (B)
2c
Hints :  =

2c
=  600 nm
Ne2
m0
(14)

Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. They are especially useful in
studying the changes in motion as initial position and momentum are changed. Here we consider some simple dynamical
systems in one-dimension. For such systems, phase space is a plane in which position is plotted along horizontal
axis and momentum is plotted along vertical axis. The phase space diagram is x(t) vs. p(t) curve in this plane. The
arrow on the curve indicates the time flow. For example, the phase space diagram for a particle moving with constant
velocity is a straight line as shown in the figure. We use the sign convention in which position or momentum upwards
(or to right) is positive and downwards (or to left) is negative.
Momentum
Position
37. The phase space diagram for a ball thrown vertically up from ground is
Momentum
Momentum
(A) (B) Position

Position
td .)
e sL
e rvic
lSna
a t i o
Momentum
d u cMomentum
s hE
a ka
f A
io no
(D i vi s
(C) (D)
Position Position
Answer (D)
Hints : p2  x
Momentum
38. The phase space diagram for simple harmonic motion is a circle
centered at the origin. In the figure, the two circles represent the
E1
same oscillator but for different initial conditions, and E1 and E2
are the total mechanical energies respectively. Then E2
2a
(A) E1  2E2 (B) E1  2E 2
a Position
(C) E1  4E2 (D) E1  16E2
Answer (C)
(15)
Hints : p1 = 2p2
E2 p22 1
  2 =
E1 p1 4
 E1 = 4E2
39. Consider the spring-mass system, with the mass submerged in water, as shown in the figure. The phase space
diagram for one cycle of this system is
Momentum Momentum
(A) Position (B) Position
t d. )
sL
Momentum
e
rvic
Momentum
lS e
a
a t i on
d u c
s hE
ka
(C) Position (D)
a
Position
f A
io no
( D i vi s
Answer (B)
Hints : Because of viscosity of water, momentum will not be same but less when it returns back.

This section contains 7 questions. The answer to each question is a Single-digit integer, ranging from 0 to 9. The bubble
corresponding to the correct answer is to be darkened in the ORS.
40. Steel wire of length 'L' at 40°C is suspended from the ceiling and then a mass 'm' is hung from its free end. The
wire is cooled down from 40°C to 30°C to regain its original length 'L'. The coefficient of linear thermal expansion
of the steel is 10–5/°C, Young's modulus of steel is 1011 N/m2 and radius of the wire is 1 mm. Assume that
L >> diameter of the wire. Then the value of 'm; in kg is nearly.
Answer (3)
F 
 
Hints :  A  y
  
 
  
(16)
mg 
  y …(i)
A 
After cooling

   10 …(ii)

So, m  3 kg
41. The activity of a freshly prepared radioactive sample is 1010 disintegrations per second, whose mean life is 109s.
The mass of an atom of this radioisotope is 10–25 kg. The mass (in mg) of the radioactive sample is
Answer (1)
dN
Hints :  – N  –1010
dt
 1

N 1010   

mtotal = N × m1
= 1010 × 109 × 10–25 × 106mg
= 1mg
tdto.) just prevent it from sliding

42. A block is moving on an inclined plane making an angle 45° with the horizontal and the coefficient of friction is
. The force required to just push it up the inclined plane is 3 times the force required
s L
down. If we define N = 10 , then N is i ce rv
e
Answer (5)
n al S
ti o
F1 = mg(sin  – cos)
u ca
Ed
Hints :
h
k as
F2 = mg(sin + cos)
fA a
no
= 3F1
v i si o
1
  = tan (D i
2
10 = N = 5
43. A boy is pushing a ring of mass 2 kg and radius 0.5 m with a stick as shown in the figure. The stick applies a
force of 2 N on the ring and rolls it without slipping with an acceleration of 0.3 m/s2. The coefficient of friction
between the ground and the ring is large enough that rolling always occurs and the coefficient of friction between
the stick and the ring is (P/10). The value of P is
Stick
Ground
Answer (4)
(17)
Hints : Fx 2  Fy 2 22 4 …(i)

(Fx – Fy)r = 2mr 2 = 2mra
Fx
 Fx – Fy = 2ma = 1.2 …(ii)
mg
P
Using F
y  Fx Fy
10
Fs
we get P  4
44. Four solid spheres each of diameter 5 cm and mass 0.5 kg are placed with their centers at the corners of a
square of side 4 cm. The moment of inertia of the system about the diagonal of the square is N × 10–4 kg-m2,
then N is
Answer (9)
   2 md 2 ma2 
2
2 md
Hints : IAB = 2 + 2    = 9 × 10–4 kg–m2
5 4 5 4 2 
45. A long circular tube of length 10 m and radius 0.3 m carries a current I along its curved surface as shown. A
wire-loop of resistance 0.005 ohm and of radius 0.1 m is placed inside the tube with its axis coinciding with the
axis of the tube. The current varies as I = I0cos(300 t) where I0 is constant. If the magnetic moment of the loop
is N0I0 sin(300 t), then 'N' is
td .)
e sL
e rvic
a lS
a t i on
d u c
s hEI
a ka
f A
io no
i vi s
Answer (6)
I
(D
Hints : B   0 
L
 0I
 B
L
 = B × r 2
I
 (d  / dt )
i 
Rs Rs
r 20  dI 
  
Rs L  dt 
Magnetic moment = i × r 2
2 r 40  dI 
=  
Rs L  dt 
= 60 I0 sin(300t)
(18)
46. Four point charges, each of +q, are rigidly fixed at the four corners of a square planar soap film of side 'a'. The
1/ N
 q2 
surface tension of the soap film is . The system of charges and planar film are in equilibrium, and a  k   ,
  
where 'k' is a constant. Then N is
Answer (3)
Hints : (2 × a × ) × c
 kq 2 Kq 2 1 
= 2  2  2  
a 2a 2
q 2   1 
 a3 = k   1 

  2 2
 q2 
 a3 = K   
 
1
 q 2 3
 a = K   
 
PART–III : MATHEMATICS
td .)
sL
vice
r
l
This section contains 7 multiple choice questions. Each question has 4 choices
a Se(A), (B), (C) and (D) out of which ONLY
ONE is correct. on ti
d u ca
47. Let P  { : sin   cos   2 cos } and Q  { : sin   coshE 2 sin }
as
be two sets. Then
a k
of A
(A) P Q and Q – P  (B) Q P
io n
vi s
(C) P Q (D) P = Q
Answer (D) (D i
Hints : We have
sin  
cos  2 cos 
 sin
 ( 2  1)cos 
1
 sin
 cos 
2 1
 ( 2  1)sin
 cos 
 2 sin   sin
 cos 
 2 sin
 sin   cos 
and it shows that the given equations
sin  
cos  2 cos 
and sin   cos
  2 sin 
are identical. Hence their solution sets are equal
 P=Q
(19)
48. Le the straight line x = b divide the area enclosed by y = (1 – x)2, y = 0 and x = 0 into two parts R1(0  x  b)
1
and R2(b  x  1) such that R1  R2 . Then b equals
4
3 1 1 1
(A) (B) (C) (D)
4 2 3 4
Answer (B)
Hints : The given parabola y = (x – 1)2 is as shown below
x=b
(1, 0)
According to the question,
b 1
1
 ( x  1) dx   ( x  1) dx 
2 2
 4
0 b
 1
b
 (b  1)3  1
 ( b  1)3
   0  
 3   3  4
td .)
sL
1
 (b  1)3 

e
rvic
8
lS e
1
a
i on
 b  1 
2
c a t
d u
hE
1 1
 b 1  
ka s
2 2
f A a
o
i s i on a10  2a8
49. Di2v = 0, with > . If an = n – n for n  1, then the value of
Let  and  be the roots of x2 – 6x(–
2a9
(A) 1 (B) 2 (C) 3 (D) 4

Answer (C)
Hints : We observe that
( + ) (n –1 – n –1) = n – n + (n – 2 – n–2)
 6an – 1 = an – 2an – 2
an  2 an 2
 6
an  1
an  2an 2
 3
 , n  2
2an 1
Putting n = 10, we get
a10  2a8
3
2a9
(20)
50. A straight line L through the point (3, – 2) is inclined at an angle 60° to the line 3x  y 
1. If L also intersects
the x-axis, then the equation of L is
(A) y  3 x  2  3 3 0 (B) y  3 x  2  3 3 0
(C) 3y  x  3  2 3 0 (D) 3y  x  3  2 3 0
Answer (B)
Hints : The question is too simple from the diagram, the given line
(0, 1)
120°
60°
 1 
 ,0 

 3 
 1 
3x  y 1 makes an angle 120° with x-axis and intersects at  , 0  . A line making an angle 60° with
 3 
the given line is either x-axis or different from x-axis. By observation it is clear that the straight line
y  3x  2  3 3 0 is the required line.
Second Solution
td .)
sL
The equation of the line through (–3, – 2) may be written as
e
y + 2 = m(x – 3)
e rvic
a lS
which will make 60° with 3x  y 
1 if
a t i on
d u c
m 3 s hE
 tan60 
a ka
1  3m f A
io no
m 3 (D i vi s
 3 
1  3m
 m
 
3 or m 0
Since the line intersects x-axis also, hence m  0 consequently m  3 and the required line is
y 
2 3( x  3)
 y  3x  2  3 3 0
51. Let (x0, y0) be the solution of the following equations
(2 x )ln 2  (3 y )ln3
3ln x  2ln y
Then x0 is
1 1 1
(A) (B) (C) (D) 6
6 3 2
(21)
Answer (C)
Hints : We have
(2x )ln 2  (3y )ln 3
 (ln2)log32x = (ln3)log33y
 log3y2x = log23
 (2x) = 3a, (3y) = 2a, say
Also 3lnx = 2lny
 lnx = lny(log32)
 logyx = log32
 x = 2k, y = 3k
 3a = 2k + 1
 a = 0 and k + 1 = 0
 2x = 3a
1
 x
2
ln 3
x sin x 2
52. The value of  sin x 2  sin(ln6  x 2 )
dx is
ln 2
.) (D)
1 3 1 3 3 1 3
Lt d
(A) ln (B) ln (C) ln ln
es
4 2 2 2 2 6 2
ic
Answer (A)
lS e rv
Hints : We have
t i o na
uc a
d
hE
ln3
x sin x 2
 dx
ka s
sin x 2  sin(ln6  x 2 )
f A a
no
ln 2
i si o
ln 3
dt Div
1 sin t
= 2 
ln 2
sin t  sin(ln 6  t ) (
1 1 1 3
 [ln3  ln2)] ln
2 2 4 2
    
53. Let a  iˆ  jˆ  kˆ, b  iˆ  jˆ  kˆ and c  iˆ  jˆ  kˆ be three vectors. A vector  in the plane of a and b , whose
 1
projection on c is , is given by
3
(A) iˆ  3 jˆ  3kˆ (B) 3iˆ  3 ˆj  kˆ (C) 3iˆ  ˆj  3kˆ (D) iˆ  3 ˆj  3kˆ
Answer (C)
 
Hints : A vector in the plane of a  iˆ  jˆ  kˆ and b  iˆ  jˆ  kˆ is given by
 
a  b
= (iˆ  jˆ  kˆ )  (iˆ  jˆ  kˆ )
= (1   )iˆ  (1   ) ˆj  (1   )kˆ
(22)
 1
whose projection on c  iˆ  ˆj  kˆ is given to be , hence
3
(1   )  (1   )  (1   ) 1
 
3 3
 –1=±1
  = 0 or  = 2
But  = 0 does not serve our purpose

when  = 2, v  3iˆ  ˆj  3kˆ

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
54. Let f :    be a function such that f(x + y) = f(x) + f(y), x, y   . If f(x) is differentiable at x = 0, then
(A) f(x) is differentiable only in a finite interval containing zero
(B) f(x) is continuous x 
(C) f(x) is constant x 
(D) f(x) is differentiable except at finitely many points
Answer (B, C)
td .)
sL
Hints : We have,
e
f(x + y) = f(x) + f(y) and f(x) is differentiable at x = 0
e rvic
nafor all x   and f (x) = k = constant. lS
ti o
Clearly f(x) = kx serves our purpose and hence f(x) is continuous
a
E du c
h
k as
x2 y2
 
1 be reciprocal to that of the ellipse x2 + 4y2 = 4. If the hyperbola
a
55. Let the eccentricity of the hyperbola
fA
a2 b2
no
isio2
passes through a focus of the ellipse, then
v
(A) The equation of the hyperbola is
(xD2 i 
y

1 (B) A focus of the hyperbola is (2, 0)
3 2
5
(C) The eccentricity of the hyperbola is (D) The equation of the hyperbola is x2 – 3y2 = 3
3
Answer (B, D)
Hints : The equation of the given ellipse is
x2 y 2
 
1
4 1
3
Whose eccentricity e 
2
Foci of ellipse are  
3, 0 and  3, 0  
2
Eccentricity of hyperbola =
3
 
2
x y2
Since given hyperbola  
1 passes through 3, 0 ,
a2 b2
(23)
3 0
Hence 2
 
1
a b2
 a2 = 3
b2 = a2(e2 – 1)
4 
 b  3   1 1
2
3 
Thus, the equation of the hyperbola is
x2 y 2
 
1
3 1
 x2 – 3y2 = 3
Foci of the hyperbola are (± 2, 0).
56. Let M and N be two 3 × 3 non-singular skew-symmetric matrices such that MN = NM. If PT denotes the transpose
of P, then M 2N 2(M TN) –1(MN –1) T is equal to
(A) M 2 (B) – N 2 (C) – M 2 (D) M N
Answer (Statement of the question is incorrect)
Hints : Every skew-symmetric matrix of odd order is always singular and inverse of a singular matrix does not exist.
The statement of the given question seems incorrect.
td .)
sL
If the matrix is given to be symmetric and non-singular, then
e
MT=M
e rvic
a lS
(MN) T = MN (as MN = NM given)
a t i on
d u c
hE
M 2 N 2(M T N) –1 (MN –1)T = M 2N 2(M N)–1((NT)–1 M T)
kaM)
= M 2N 2(N –1 M –1)(Na–1
s
fA
= M 2NM –1N o–1nMo
v i si
=M 2
(D i
If there may exist a non-singular skew-symmetric matrix (which does not exist), then
M 2N 2 (M TN)–1(MN –1) T = M 2N 2 (– MN)–1((N – 1) TM T)
= – M 2NM –1(– N –1(– M)) = – M 2
57. The vector(s) which is/are coplanar with vectors iˆ  ˆj  2kˆ and iˆ  2 ˆj  kˆ , and perpendicular to the vector iˆ  jˆ  kˆ
is/are
(A) ˆj  kˆ (B)  ˆj  kˆ (C) iˆ  jˆ (D)  ˆj  kˆ
Answer (A, D)
Hints : Required vector will be parallel or antiparallel to the vectors
 iˆ  jˆ  kˆ   (iˆ  jˆ  2kˆ)  (iˆ  2 jˆ  kˆ )

 4  iˆ  jˆ  2kˆ   4  iˆ  2 jˆ  kˆ 
4 ˆj  4kˆ
(24)

(Paragraph Type)
This section contains 2 paragraphs. Based upon one of the paragraph 2 multiple choice questions and based upon
the second paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices

Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls, and U2 contains only 1 white ball. A fair
coin is tossed. If head appears then 1 ball is drawn at random from U1 and put into U2. However, if tail appears then
2 balls are drawn at random from U1 and put into U2. Now 1 ball is drawn at random from U2.
58. The probability of the drawn ball from U2 being white is
13 23 19 11
(A) (B) (C) (D)
30 30 30 30
Answer (B)
Hints : We have the following tree-diagram under given conditions.
3
5 W
1 U1
2 H 2 R
5
3C2
1 T 5C2 WW
2 U1 3C 1, 2C1
5C2
td .)
e sL
rvic
2C2 WR
5C2
lS e
RR na
a ti o
du c
Probability of drawing white ball from U2
1 3 2 1 1 1h E
 1      ka s
1 3 1 2 1 1 3
 1    
2 5 3 2Aa
=
of
2 5 2 5 2 2 10 10 3
n
3 1 3 1 1
v i si o
(D i
=    
10 10 20 5 60
18  6  9  12  1
=
60
23
=
30
59. Given that the drawn ball from U2 is white, the probability that head appeared on the coin is
17 11 15 12
(A) (B) (C) (D)
23 23 23 23
Answer (D)
Hints : Using Baye's theorem,
1 3 1 2 1
   
2 5 2 5 2
Required probability =
23
30
4
10 12
= 23 =
23
30
(25)

Let a, b and c be three real numbers satisfying
1 9 7
[a b c ] 8 2 7   [0 0 0] ...(E)
7 3 7 
60. If the point P(a, b, c), with reference to (E), lies on the plane 2x + y + z = 1, then the value of 7a + b + c is
(A) 0 (B) 12 (C) 7 (D) 6
Answer (D)
Hints : From the given condition,
a + 8b + 7c = 0
9a + 2b + 3c = 0
7a + 7b + 7c = 0
a+ b+c=0
Also, 2a + b + c = 1
 a=1
 7a + b + c = 6a + (a + b + c) = 6
61. Let  be a solution of x3 – 1 = 0 with Im() > 0. If a = 2 with b and c satisfying (E), then the value of
3 1 3
 a


b

c
is equal to
td .)
e sL
(A) –2 (B) 2 (C) 3
e rvic (D) –3
a lS
i on
Answer (A)
c a t
Hints : When a = 2  b + c = –2
d u
s hE
ka
Also, 8b + 7c = –2
f A a
 b = 12 and c = –14 o
i on
Thus,
3

1

3
=
3

1 ivis3
(D 14
 a
 b

c

2
12
= 1 + 3 + 32
=1–3
= –2
62. Let b = 6, with a and c satisfying (E). If  and  are the roots of the quadratic equation ax2 + bx + c = 0, then
 n
 1 1
   
n 0 
 
6
(A) 6 (B) 7 (C) (D) 
7
Answer (B)
Hints : For b = 6  a + c = –6
a + 7c = –48
a + c = –6
whence a = 1, c = –7
(26)
 and  are roots of the given equation ax 2 + bx + c = 0, hence  +  = –6,  = –7

1 1  6
 
   7
 n 2
 1 1 6 6

1
   1      ......  6 7
n 0 
   7  
7
1
7

This section contains 7 questions. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. The
bubble corresponding to the correct answer is to be darkened in the ORS.
x
f ( t ) dt 3 x f ( x )  x 3 for all x  1, then
63. Let f : [1, )  [2, ) be a differentiable function such that f(1) = 2. If 6  
1
the value of f(2) is

Answer (6)
Hints : From the given condition, we have
x
6 
f ( t ) dt 3 x f ( x )  x 3
1
td .)
e sL
rvic
 6f(x) = 3f(x) + 3xf(x) – 3x 2
 lS e
xf(x) – f(x) = x2
a
a t i on
1
d u c
hE
 f ( x )  f (x) 
x
x
ka s
f A a
n o 
1
sio I.F. = e  e
 dx 1
 ln x
i vi
which is linear differential equation, whose x
(D
x
Solution of the given equation is
1 1
f (x) 
x
  x  x dx  c
 f(x) = x 2 + cx
Initially, for x = 1, f(1) = 2  c=1
 f(x) = x 2 + x
 f(2) = 4 + 2 = 6
64. If z is any complex number satisfying | z – 3 – 2i |  2, then the minimum value of | 2z – 6 + 5i | is

Answer (5)
Hints : From the given condition,
| z – 3 – 2i |  2
 | 2z – 6 – 4i |  4
 4  | (2z – 6 + 5i) – 9i |
(27)
 || 9i | – | 2z – 6 + 5i ||
 4  9 – | 2z – 6 + 5i |
 | 2z – 6 + 5i |  5
Minimum value of | 2z – 6 + 5i | is = 5
p
65. Let a1, a2, a3, ..., a100 be an arithmetic progression with a1 = 3 and 
Sp  a , 1  p  100 . For any integer n
i 1
i
Sm
with 1  n  20, let m = 5n. If does not depend on n, then a2 is
Sn
Answer (9)
Hints : We have,
a1 = 3, Sp = a1 + a2 + a3 + ...... + ap, 1  p  100
By the given condition,
Sm m 6  (m  1) d
  k , which is independent of m and n
Sn n 6  (n  1) d
 5(6 + (m – 1)d) = k(6 + (n – 1)d)
 30 + 25nd – 5d = 6k + nkd – kd
which is independent of n
Hence, on comparing the coefficients of like terms, we get
k = 25
30 – 5d = 150 – 25d
td .)

e sL
rvic
20d = 120
 d=6
lS e
a
a2 = 9
a t i on
du c
E
= 8x. Let 1 be the area ofshthe triangle formed by the end points of its latus rectum
ka
66. Consider the parabola y2
1  f A a
and the point P  , 2  on the parabola, and o
i o n 2 be the area of the triangle formed by drawing tangents at P and
ivis 1
2 
( D
at the end points of the latus rectum. Then is
2
Answer (2)
Hints :
y2 = 8x
B
R (2, 4)
A 1, 2
2
P
Q
(2, –4)
C
Clearly, ar(ABC) = 2(arPQR)
1 = 22
1
 2
2
(28)
  sin      d
67. Let f () sin  tan1    , where     . Then the value of (f ()) is
  cos 2   4 4 d (tan )
   
Answer (1)
Hints : We have,
  sin   
f() = sin  tan1  
  cos 2  
  
 1 x 
= sin  tan ; x sin 

 1  2x 2 
x
=
1 x2
sin 
= = tan 
cos 
df ()
1
d tan 
68. The minimum value of the sum of real numbers a–5, a–4, 3a–3, 1, a8 and a10 with a > 0 is
Answer (8)
Hints : For a > 0,
a 5  a 4  3a 3  1  a8  a10 8 5 4 9
 a  a  a  1 a8  a10
8
td .)
 a–5 + a–4 + 3a–3 + 1 + a8 + a10  8
e sL
 min(a–5 + a–4 + 3a–3 + 1 + a8 + a10) = 8
e rvic
na lS
1 a ti o
69. The positive integer value of n > 3 satisfying the equation 
d u c 1

1
is
E
h n   2   3 
k as
sin sin   sin  
A a    n   n 
of
Answer (7)
n
Hints : According to the question,
v i si o

1 1

1 (D i
 2 3
sin sin sin
n n n
2 3  3  2
 sin sin sin sin  sin sin
n n n n n n
 5 2 4  3
 cos  cos  cos   cos  cos
n n n n n n
9  5 
 sin  sin  sin  sin
2n 2n 2n n
9 5
 sin  sin
2n 2n
9  5
  (2k  1), say
2n
7
 n , k is an integer
2k  1
Let us put k = 0
Hence n = 7
  
(29)

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DATE : 10/04/2011

3. Among the following compounds, the most acidic is

4. The major product of the following reaction is

Hints : Ni+2 + 4Cl– 

SECTION - II (Total Marks : 16)

All atoms lie in one Planar

9. According to kinetic theory of gases

(A) Collisions are always elastic

(C) Only a small number of molecules have very high velocity

Hints : According to Kinetic theory of gases

(i) Collisions are always elastic

(ii) Momentum transferred on wall

by one collision along x component = 2 mvx

11. Extraction of metal from the ore cassiterite involves

(A) Carbon reduction of an oxide ore

(B) Self reduction of a sulphide ore

(C) Removal of copper impurity

(D) Removal of iron impurity

If after contain Fe and Cu as impurity,

SECTION - III (Total Marks : 15)

Paragraph for Questions Nos. 12 and 13

(i) conc. H2 SO4

12. The structure of compound P is

Hints : (Q. 12 to Q.13)

Paragraph for Questions Nos. 14 to 16

15. The compound N is

16. The final solution contains

Cu  Ag  Cu2  Ag

Ag  NaCl  AgCl

6.62  1034  3  108

0.1 0.082  273

 Difference in oxidation state is +5 – 0 = +5.

(A) 9 (B) 18 (C) 27 (D) 36

(A) 0% (B) 20% (C) 75% (D) 80%

SECTION - II (Total Marks : 16)

(A) Restoring torque in case A = Restoring torque in case B

SECTION - III (Total Marks : 15)

Paragraph for Questions Nos. 35 and 36

Paragraph for Questions Nos. 37 and 39

(A) (B) Position

(A) Position (B) Position

SECTION - IV (Total Marks : 28)

tdto.) just prevent it from sliding

Hints : Fx 2  Fy 2 22 4 …(i)

According to the question,

(A) 1 (B) 2 (C) 3 (D) 4

(2x )ln 2  (3y )ln 3

(A) iˆ  3 jˆ  3kˆ (B) 3iˆ  3 ˆj  kˆ (C) 3iˆ  ˆj  3kˆ (D) iˆ  3 ˆj  3kˆ

SECTION - II (Total Marks : 16)

Thus, the equation of the hyperbola is

(A) ˆj  kˆ (B)  ˆj  kˆ (C) iˆ  jˆ (D)  ˆj  kˆ

 iˆ  jˆ  kˆ   (iˆ  jˆ  2kˆ)  (iˆ  2 jˆ  kˆ )

SECTION - III (Total Marks : 15)

Paragraph for Questions Nos. 58 and 59

Paragraph for Questions Nos. 60 and 62

 and  are roots of the given equation ax 2 + bx + c = 0, hence  +  = –6,  = –7

SECTION - IV (Total Marks : 28)

the value of f(2) is

64. If z is any complex number satisfying | z – 3 – 2i |  2, then the minimum value of | 2z – 6 + 5i | is

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