SINTESIS DAN KARAKTERISASI NANOKOMPOSIT GRAPHENE-OKSIDA BESI

BERBASIS PASIR BESI DENGAN METODE HIDROTERMAL

Oleh :
MUHAMMAD FAJAR
F1C1 16 029

INTI SARI

Sintesis nanokomposit berbasis graphene-oksida besi telah berhasil dilakukan. Sintesis

nanokomposit dilakukan dengan menggunakan metode Hidrothermal dengan variasi
komposisi 90:10, 80:20, dan 70:30 dalam satuan (%v/v). Berdasarkan hasil karakterisasi yang
telah dilakukan menunjukkan bahwa nanokomposit graphene-oksida besi yang disintesis
berpotensi sebagai material fungsional untuk elektroda baterai. Pada karakterisasi FTIR
terdapat puncak serapan 2806.43 cm-1 yang diidentifikasi sebagai vibrasi C-H alifatik
stretching. Untuk C=C stretching pada puncak serapan 1633.71 cm-1. Vibrasi C=O stretching
pada puncak serapan 1749.44 cm-1. Pada puncak serapan 3138.18 cm-1 diidentifikasi sebagai
vibrasi O-H serta pada puncak serapan 574.79 cm-1 diidentifikasi sebagai vibrasi Fe-O. Pada
Karakterisasi XRD menunjukkan ciri khas kristal dari graphene dengan 2θ = 23,04ᴼ dan
indeks miller (001). Sementara terbentuk pula pola kristal pada 2θ = 30,1018°; 35,4787°;
43,4243°; 56,9932° dan 62,5536° dengan indeks miller (220), (311), (400), (511) dan (440)
untuk Fe3O4 dan 2θ = 32,7439°; 40,3028°; 77,1320° dengan indeks miller (104), (113) dan
(036) untuk Fe2O3. Dengan metode Cyclic Voltammetry (CV) diperoleh elektroda graphene-
oksida besi terbaik pada komposisi variasi 80:20 dengan arus puncak anodik (Ipa) 6,80 × 10-
5
A dan arus puncak katodik (Ipc) 7,75 × 10-5 A.

Kata kunci : Nanokomposit, graphene-oksida besi, graphene, oksida besi, Hidrotermal.

SYNTHESIS AND CHARACTERIZATION OF NANOCOMPOSITE GRAPHENE-IRON
OXIDE BASED ON IRON SAND WITH HYDROTHERMAL METHOD

By:

MUHAMMAD FAJAR
F1C1 16 029

Abstract

Synthesis of nanocomposite based on graphene-iron oxide has been successfully carried out.
Synthesis of nanocomposites was carried out using the Hydrothermal method with
composition variations of 90:10, 80:20, and 70:30 in units (% v/v). Based on the results of the
characterization that has been done shows that the synthesized of nanocomposite graphene-
iron oxide has the potential as a functional material for battery electrodes. In FTIR
characterization the peak at 2806.43 cm-1 was correspondend to the C-H stretching vibrations.
For C = C stretching the peak at 1633.71 cm -1. Vibration of C = O stretching the peak at
1749.44 cm-1. The peak at 3138.18 cm-1 was identified as O-H vibrations and in the peak at
574.79 cm-1 was identified as Fe-O vibrations. The XRD characterization shows the
characteristic crystals of graphene with 2θ = 23,04ᴼ and indeks miller (001). While also
formed a crystal pattern on 2θ = 30,1018°; 35,4787°; 43,4243°; 56,9932° and 62,5536° with
indeks miller (220), (311), (400), (511) and (440) to Fe 3O4 and 2θ = 32,7439°; 40,3028°;
77,1320° with indeks miller (104), (113) and (036) to Fe2O3. With the Cyclic Voltammetry
(CV) method, the best graphene-iron oxide electrode are obtained at variation of 80:20 with
anodic peak currents 6,80 × 10-5A and catodic peak currents (Ipc) 7,75 × 10-5 A.

Keywords: Nanocomposite, graphene-iron oxide, graphene, iron oxide, Hydrothermal.