INDUSTRY
Brian E. Spencer
300
7
(I)
m
150 Procurement
100
50
Fiscal year
Fig. 49.1 Defense budget declines. (Courtesy of
Handbook of Composites. Edited by S.T. Peters. Published Westinghouse ESG news and department of
in 1998 by Chapman & Hall, London. ISBN 0 412 54020 7 defense budget.)
Introduction 1045
rackets have been fabricated by braiding. The bath, along the fiber path between the ten-
braiding process for composites is identical to sioning system and the delivery eye, through
braiding textiles, except that the fiber is usu- which the dry fibers are pulled. Both wet
ally braided as a prepreg. Prince introduced winding and prepreg winding are widely
the Vortex tennis racket, braided with co-min- used. The choice of technique depends on the
gled nylon and carbon fibers, in the late 1980s. application, cost and quality requirements.
Ski poles, kite tubes, arrow shafts, and similar Composites that have directionally oriented
hollow or solid shafts are made by the pultru- continuous fibers are analyzed by techniques
sion process. Pultrusion of composites is such as netting analysis, rule of mixtures, clas-
similar to extruding metals. The resin and sical lamination theory, and micromechanics.
fiber material are pulled through a heated die These analysis techniques all account for the
that forms the composite to shape and cures fact that composites have material properties
the resin in one continuous process. Since the that depend on the fiber directions of each ply.
fibers are essentially all aligned down the axis The overall directional properties of the lami-
of the part there is little transverse or hoop nate are calculated by adding the relative
strength unless hoop fibers or other off-axis effects of each ply. The analyses are more com-
reinforcement such as mats are added during plicated than with isotropic materials such as
the process. Arrow shafts have shattered on steel and aluminum. However, the wide-
impact because of this lack of strength in the spread use of computers has made the task of
hoop direction. analyzing composites relatively simple.
Resin transfer molding (RTM) consists of Composites are in many cases much
injecting resin into a mold containing fiber in a stronger and stiffer than metals such as steel,
preform pattern. Resin transfer molding is aluminum or titanium. When one takes into
usually used in conjunction with a fiber place- account the much lower density of composites
ment technique such as hand lay-up, braiding as compared to metals, composites have an
or filament winding. Some tennis rackets are even greater performance advantage over
fabricated using the resin transfer molding metals. To compare material properties on an
process4. equal weight basis (instead of an equal volume
The filament winding process is the basis), a property such as ultimate strength is
machine controlled technique of applying a divided by the density of the particular mater-
controlled amount of resin and oriented fiber ial. The resultant is termed specific strength.
on a mandrel that provides the finished com- The same can be applied to stiffness (modulus)
ponent shape. The mechanics of filament and is called specific modulus. Comparing
winding are illustrated in Fig. 49.2 The ten- materials this way is very important when
sioned fiber bands are accurately placed on designing weight critical parts.
the mandrel using numerically computer Figures 49.3 and 49.4 show the strength,
controlled or chain and gear mechanical modulus, and specific properties of represen-
winding machines. Fig. 49.2 shows the fiber tative composites and metals. The composite
being pulled from tensioned spools through data are for composites with all fibers oriented
the delivery eye onto the rotating mandrel. in one direction (unidirectional ply data). The
The resin can either be pre-applied on the fiber test loads are applied to the specimens in the
in an off-line operation (pre-impregnation, or same direction as the fibers. Also, all compos-
wet prepreg) or applied during the winding ite data presented here are for 60% fiber and
operation (wet winding). Prepregging usually 40% resin by volume samples. This ratio is
requires storing the material at low tempera- typical for advanced composite laminates. The
ture until required for winding to retard the epoxy resin used to make the samples is not
curing process. Wet winding uses a resin indicated specifically because its effect on the
Manufacturing techniques 1047
-MACHINE DRIVE
Fig. 49.2 Layout of a typical filament winding machine (Courtesyof Composites Machines Company.)
42 msi carbon
50 msi carbon
5-2 glass
E glass
Kevlar
Spectra 1000
Titanium
-
4340 Steel
Aluminum
0 100 200 300 400 500
Strength, ksi
Strength Specific Strength
Fig. 49.3 Strength of composites; comparison with metals at 60% fiber volume.
Specific Modulus, E6 in.
Material 800
34 msi carbon
42 msi carbon
50 msi carbon
S-2 glass
E glass
Kevlar
Spectra 1000
Titanium
4340 Steel
Aluminum
0 5 10 15 20 25 30 35
Modulus, Msi
-Modulus Specific Modulus
Fig. 49.4 Stiffness of composites; comparison with metals at 60% fiber volume.
Sporting goods applications 1049
-
34 msi carbon
42 msi carbon
-
50 msi carbon
-
S-2 glass
-
E glass
Kevlar
Titanium
4340 Steel
Aluminum
100 200 300 400 500 600
Alt. stress density, ksi/lb. per cu. in.
Fig. 49.5 Fatigue strength of composites; comparison with metals at 60% fiber volume.
The failure loads shown in Fig. 49.5 are because of the changes in 'feel' of the rod.
given as stress density which is the test stress Many golf shafts incorporate both
divided by the material density. For the mate- carbon/graphite and boron reinforcements to
rials tested, composites have two to six times change flex point, reduce shaft weight, increase
the specific fatigue resistance as metals. torque resistance and increase clubhead
It is important to mention that the previous speed5.
comparisons of metals and composites do not
tell the whole story. Often, the benefits of a
49.3 SPORTING GOODS APPLICATIONS
composite part compared to a metal one
would not be as great as indicated by the dif-
49.3.1 RACKETS
ferences in ply strength and stiffness. The
design allowable composite ply strength is There are approximately 22.5 million tennis
10-20% lower than the test specimen players and 7 million racquetball players in
strengths. Other factors including voids, long- the USA. These players purchased 2.45 mil-
term environmental effects, use temperature lion tennis rackets at a cost of $170 million and
and imperfect fiber alignment all reduce the 1 million racquetball rackets at a cost of $53.4
ultimate strength of composites. Finally, when million retail dollars in 1992. Approximately
all the reinforcing fibers are not in the direc- 73% of these rackets were composite4.
tion of the load, the fibers do not carry the load Most all of these rackets are produced in
as efficiently. However, when these factors are the Far East using a compression molding
adequately controlled, there are many applica- process with an internal bladder. This process
tions where composite structures greatly consists of hand lay-up of prepreg around a
outperform their metal counterparts. Sport straight metal mandrel and plastic bladder.
and recreation applications are one market After lay-up the prepreg/bladder is removed
area where composites have a decided advan- from the mandrel and placed in a compres-
tage over metals. sion mold. The mold is closed, the bladder is
There are other not easily quantifiable rea- pressurized, and the part is temperature
sons for choosing a particular composite or an cured. A significant portion of the labor in
individual lay-up. Fishmg rods generally do manufacturing a racket is in the surface fin-
not have hoop reinforcement or angle plies ishing, painting and labeling.
1050 Composites in the sporting goods industy
Tube and lug frames are relatively simple to helps to reduce the seam effect on perfor-
manufacture. However, the frames can have mance consistency.
durability problems if the tubes and tube to Grafalloy introduced a filament wound
lug joint are not properly designed to prevent shaft for the 1993 season. Filament wound
significant stiffness mismatches. Galvanic cor- shafts provide superior performance at low
rosion potential is a concern. Filament weight and cost compared to roll-wrapped
winding offers an inexpensive method for shafts available with comparable performance
manufacturing frame tubes. Wet winding specifications. Those familiar with the indus-
techniques allow using the required materials try believe filament winding will be the
in the lowest cost form. Since the process is process of choice in manufacturing golf shafts
machine controlled, labor requirements are in the next few years.
minimized. Currently the most widespread Player tests and mechanical golfer testing
manufacturing method is roll-wrapping. Roll- have proven the performance improvements
wrapping requires cutting prepreg plies of of a filament wound shaft over roll-wrapped
composite and hand wrapping them around a shafts. Many original equipment manufactur-
metal mandrel prior to curing. ers are evaluating filament wound shafts for
Frame tubes are not the only use of com- their product lines. One factor where roll-
posites in the bicycle industry. Handlebars are wrapped shafts can have an advantage over
filament wound, removed from the mandrel, filament wound shafts is in tip durability.
and then cured in a mold to provide the Filament winding can introduce more voids in
proper shape and curvature. An internal blad- the composite laminate than roll-wrapping.
der provides the compaction pressure. Seat Special attention is needed by filament
posts, swing arms, and handlebar extensions winders to insure that their product has suffi-
can be made using this process. Titanium cient tip strength.
tubes in some front wheel suspension systems ASTM is working to establish test methods
are reinforced with composite tubing. Wheels for golf shafts. Standard tests will allow for a
and spokes are also being made of composite better comparison of products and give the
materials using combinations of roll wrap- customer more confidence in the quality and
ping, hand lay-up and resin transfer molding. performance of the product being purchased.