CHHATTISGARH SCIENCE

COLUMBIAD CLASS - XII

Hints & Solution

22. Coloured transition metal salts which are mostly paramagnetic
PART-I (Chemistry) give coloured meta borates with borax on heating in oxidising
2. 2H+ + 2e–  H2 flame. (ja
xhu laØ e.k /kkrqy o.k t kseq[; : i lsvuqp qEcd h; gS]cksjsDl
pH2 d slkFk vkWDlhd kjh Toky k esaxeZd jusij jaxhu esVk cksjsV nsrk gSA)
0.059
 RP = 0.0 – log  2 .
2 [H ] 23. (1), (2) & (3) are correct
(4) In this O2– occupy FCC lattice.
8. Electrophoresis means movement of colloidal particles under the
influence of electric field. (by sDVªkWQ ksjsfll d k vFkZfo|qr {ks=k d sizHkko 24. (i) Slag is a fusible mass. (/kkrqey ,d xy uh; nzO;eku gSA)
d svUrxZr d ksy ksbMh d .kksad h xfr'khy rk lsgSA) (ii) It has low melting point. (bld k xy uka d fuEu gksrk gSA)
9. Oxidising power (vkWDlhd kjh lkeF;Z) (iii) It is lighter than and immiscible with the molten metal. It is due
to these impurities that the slag floats as a separate layer on the
HClO > HClO2 > HClO3 < HClO4
molten metal and can thus be easily separated from the metal.
beacuse SRP values increase from HClO to HClO4.
The layer of the slag on the molten metal prevents the metal from
(D;ks
afd SRP eku esaHClO lsHClO4 rd of̀) gksrhgSA) being oxidised. It is used as one of the constituent of cement and
in building material. (;g gYd k gks rk gS rFkk xfy r /kkrq d s lkFk
vfeJ.kh; gksrkgSA bl d kj.kv'kqf) ;k¡xfy r /kkrqij ,d iF̀kd ijr d s
11.   120  Ans. (1) : i esarSjrhjgrhgSrFkk/kkrqlsljy rklsiF̀kd d j ld rsgSA xfy r /
kkrqij /kkrqey d hijr /kkrqd svkWDlhd r̀ gksuslslqj{kkd jrhgSvFkkZr~/
kkrqd k vkWDlhd j.k gksuslsjksd rh gSA bld k mi;ksx lhesUV d svo;o
rFkk fuekZ.kd kjh inkFkZd s: i esagksrk gSA)
2e  1
12. H2O  H2 +
O
2 2
25. Beckmanns rearrangement (cs
d eku iquZfoU;kl )
2 × 96500 C  22.4 × 1000 cm3 H2
2  96500  224
22.4  1000
C  224 cm3 H2 PART-II (Mathematics)
= 1930 C
26. (x – 1)(x – 3)(x – 5)(x – 7) = 9
13. T f = 0.2 × 1.2 × 1.86 = 0.45 (x2 – 8x + 7) (x2 – 8x + 15) = 9 Let y = x2 – 8x
therefore boiling point (blfy , DoFkukad ) = – 0.45ºC (y + 7)(y + 15) = 9
y2 + 22y + 96 = 0 y = – 6, – 16
14. 2CuSO4 + K4[Fe(CN)6]  Cu2 [Fe(CN)6](chocolate brown) + 2K2SO4
x2 – 8x = – 6, – 16
sum of roots (ew y ksad k ;ksxQ y ) = 8 + 8 = 16
Cl2
15. CH3CH2COOH    

Re d P
(HVZ reaction ) 27. Let (ekuk) 4 + x = y
 (y – 1)4 + (y + 1)4 = 16
KOH( alc .)  y2 = – 7, 1
   CH2 = CHCOOH
 y = ± 1
 x = –3, – 5
NO2
2 2
28. a1 x > – , a2x2 > – ,.....
HNO
3 Cl2 3 9
16.   
H2SO 4 FeCl3
2 2 2
 a1 x + a2x2 +......+ anxn > – – – –......
3 9 27

n
HNO 3
 1
17. CHCl3   CCl3NO2  a1 x + a2x2 +......+ an xn >   – 1
– H2 O 3

1
reduction  1 + a1 x + a2x2 + ...+ anxn >
18.   
3n
 1 + a1 x + a2x + ...+ anx > 0 for all n  N (lHkh n  N d sfy ,)
2 n

CHCl 3 / alc. KOH

      29. Locus of C is y = 5 (C d k fcUnq
iFk y = 5 gSA)

21. base added  pH of acidic / basic buffer 

({kkj fey kusij  vEy h;@{kkjh; cQ j d k pH )
acid added  pH of acidic / basic buffer 
(vEy fey kusij  vEy h;@{kkjh; cQ j d k pH )

RESONANCE Sol. - XII - 1

 2 f (nx ) f (nx )
1  xy3
30. (x + 1)2 + (y – 1)2 = 

 37. n f(x)n–1  f '(x) = f '(nx) . n  f ( x )
=
f (x)
4  2 

 7x2 + 7y2 + 2xy + 10x – 10y + 7 = 0 38. log2(a + b) + log2(c + d)  4

 log2(a + b)(c + d)  4
31.  f(xi)  yi  (a + b)(c + d)  16
i.e. no object goes to its scheduled place. Then number of one- AM  GM
one mappings (d ks bZHkhoLrqviusfu/kkZfjr LFkku ij ughagks]rks,d Sd h  (a + b) + (c + d)  2 (a  b )(c  d)  8
izfrfp=k.kd srjhd s)
 1  1  4n
 1 1 1 1 1 1 39. x =
= 6 ! 1   2
 1! 2!  3 !  4 !  5 !  6 ! 
  As x is integer (pawfd x iw.kk±d gS)
 1 + 4n must be a perfect square of an integer
1 1 1 1 1 (1 + 4n ,d iw.kk±d d k oxZgksxk)
= 6 !  2 !  3 !  4 !  5 !  6 ! 
   n = 2,6,12,20,30,42,56,,72,90
= 360 – 120 + 30 – 6 + 1 = 265  nine values of n. (n d s9 eku gS )

n 40. a2 + 2a + cosec2 (a + x) = (a + 1)2 + cot2 (a + x) = 0

32. C5 = n C3
 a = –1
n
C5 = n Cn – 3
1
5=n–3 41. sin , cos  and tan  are in G.P..
n=8 6

33. Each question can be disposed off in 3 ways because it can 1

either remain unansered or first alternative is answered or sec- ( sin , cos  rFkktan  xq
.kksÙkj Js.kh esagS)
6
ond alternative is answered.
(izR;sd iz'u d kspquus;k mld sfod Yi d kspquus;k uk pquusd srhu sin2 
 cos2  = , cos   0
izd kj gS) 6 cos 
 Total no. of ways of selecting questions = 38 = 6561 6cos3  + cos2  – 1 = 0

(d qy rjhd s= 38 = 6561)
This includes the choice when no question is attempted.  (2cos  – 1) (3cos2  + 2cos + 1) = 0
 Total no. of selections of one or more questions 1 
= 6561 – 1 = 6560.  cos  =    2n  ,nz
2 3
(ijUrqd e lsd e ,d iz 'u d kspq
uusd sd yq rjhd s= 6561 – 1 = 6560)
42. 2 tan2x – 3 sec x = 0
i.e. 2 sec2x – 3 sec x – 2 = 0
34. Let (ekuk)  = x  x  x  ........ i.e. (sec x – 2) (2 sec x + 1) = 0
 2 = x +  i.e. sec x = 2
2 –  – x = 0 
x = 2m ±
3
1  1  4x 1  1  4x
= = , {  0
2 2  7 values of x are
    
, 2 – , 2 + , 4 – , 4 + , 6
3 3 3 3 3
2
2 dx  
I=  1 – , 6 +
1  4x 3 3
0
     
Let (ekuk) 1 + 4x = t2  4dx = 2t dt (x d s7 eku , 2 – , 2 + , 4 – , 4 + , 6 – , 6 +
3 3 3 3 3 3
3
t dt 
I=  1 t = t – n (1  t )13 =2– n 2 gSaA)
3
1
 n
2–I= n 2  e2 – I = 2  6 +
3

2

x2 – y2 xy 1 n 38
35. Bisectors of x2 – 2pxy – y2 = 0 is =  6+  i.e. n
2 –p 3 2 3

x2 – y2 xy  least value of n is 13 (n d k U;w

ure eku 13 gS)
(x2 – 2pxy – y2 = 0 d sv) Z
d = )
2 –p 43. z = 
px2 + 2xy – py2 = 0  (z – z2 + 2z3)(2 – z + z2) = ( – 2 + 2) (2 –  + 2 )
Lines in new position will also have same angle bisectors. = |2 –  + 2 |2
(ubZfLFkfr es
aHkh ;gh d ks.k v) Zd gksxsaA) = | 2 – i 3 |2 = 7
 –3a – 2b  44. Length of focal chord (ukHkh; t hok d h y EckbZ) = 16a cosec2
36. ax + by +   = 0
 6 

6ax + 6by – 3a – 2b = 0 For minimum length ( U;w
ure y EckbZd sfy ,)  =
a(6x – 3) + b(6y – 2) = 0 4
x = 1/2, y = 1/3 minimum length (U;w
ure y EckbZ) = 32a

RESONANCE Sol. - XII - 2

45. All chord will be diameter of circle so infinite chords are possible.
(lHkh t hok,aoÙ̀k d k O;kl gksxh blfy , vuUr t hok,alaHko gS)
PART-III (Physics)
52. vA – vB = work done by electric field on + 1 coul. charge from
Centre of circle is (–2, – 3) and radius is 3.
A to B = E R
(oÙ̀k d k d s
Unz(–2, – 3) rFkk f=kT;k 3 gS)
+1 d wy kWe vkos'k ij A lsB rd fo-{ks=k }kjk fd ;k x;k d k;Z
vA – vB = E R
46. Vectors AR, AB & C are coplanar
 vB = vA – ER= v – ER
(lfn'k AR, AB vkSj C lery h; gSaA) 53. Let q1 = charge on inner sphere
Equation of the required plane (vHkh"V lery d k lehd j.k) q2 = change on outer sphere
C = common centre

kq1 kq2 kq1 kq2

+ = 10 , VC = + = 10Ans. (1)
a b a b

54.  = (µ – 1) A = 2°
So by rotating mirro by 1° in clockwise direction, emergent ray
after reflection will become horizontal.
vr% niZ.k d ks1° nf{k.kkorZ?kqekusij] fuxZr fd j.k ijkorZu d si'pkr~
{kSfrt gkst k;sxhA

55.
x – x1 y – y1 z – z1
x 2 – x1 y 2 – y1 z 2 – z1  0
d1 d2 d3
5R
x – x2 y – y2 z – z2 RAB = .
9
x1 – x 2 y1 – y 2 z1 – z 2  0
or
d1 d2 d3 1.5 2 1.5
 
56. E =
1 1 1  5, r  1
1 1 1 3 3
 
1 1 1

47. 5/3 5
Hence i = 
31/ 3 31
57. During the charging process, charge does not jump or cross the
area between the plates.

2 4  0 .i
1 1 58. B = (sin 1  sin  2 )
A1 = dx  n2 , A2 =  dx  n2 4d

1
x 2
x i

A1 = A2 7
10  100  3 1 
=   
48. (1) f(x) is continuous no where 3  1  2 2 
(2) g(x) is continuous at x = 1/2 1=60º 2=(360–30)º
P
(3) h(x) is continuous at x = 0 = 5 × 10–6 T ( 3 – 1)m
(4) k(x) is continuous at x = 0
 
cos 2  cos 2x 60. For calculation of
49. Let f(x) =  B  dl , current upwards shall be positive
x2  | x | ABCDA

and current downwardsshall be negative

(1) lim f ( x )
x  1  
for x = – 1 |x| = – x Bdl
Therefore 
ABCDA
= (I1I1) +I2 4I1 = 0
cos 2  cos 2x
f(x) =
x2  x Therefore I2  4I1 upwards.
 
lim
cos 2  cos 2x
(
0
)  B  dl d sifjd y u d sfy ,] /kkjk Å ij d h v ksj /kukRed gksxh
x  1 x2  x 0 ABCDA

2 sin 2x
rFkk /kkjk uhpsd h v ksj _ .kkRed gksxhA bl fy ,
= lim = 2sin2
x  1 2 x  1  
 B  d l = (I I ) +I  4I = 0
1 1 2 1
cos 2  cos 2 x 0 ABCDA
(2) lim ( )
x 1 x2  x 0 bl fy , I2 4I1 Å ij d h v ksj
2 sin 2 x
lim = 2sin2
x 1 2 x  1

RESONANCE Sol. - XII - 3

63. In P-type semiconductors, holes are the majority charge carriers 72. Rate of work done by external agent is :
(P-iz
d kj d sv ) Zp ky d ksaesagksy cgql a[;d v kos'k okgd gksrsgSA) cká d kjd }kjk d k;Zfd ;st kusd h nj gS%
V 0. 5 dw BL.dx
64. E = d  = 106 V/m = = B  Lv
5  10 – 7 dt dt
& thermal power dissipated in the resistor = e = (BvL)
66. It is a plastic rod so current cannot flow through it. (;g Iy kfLVd
rFkk Å "eh; Å t kZt ksizfrjks/k esa{k; gqbZgS= e = (BvL)
d h NM gSbl d kj.k blesals/kkjk izokfgr ughagksld rh gSA)
clearly both are equal, hence (1) . (nks uksacjkcj gSblfy , (1))
67. P av = vrms rms cos  If applied external force is doubled, the rod will experience a net
force and hence acceleration. As a result velocity increases,
200 2 2 hence (2). (vxj y xk;k x;k cy nq xuk fd ;k t k, rc NM+ij ,d
=
2
. cos (30º) =100 6 watt
2 ifj.kkeh cy o Roj.k y xsxkA ifj.kkekuql kj osx c<+rk gS] blfy , (2))
e
69. At resonance v uqukn ij (V C = V L) Since pw¡fd ;  =
R
Vrms On doubling‘R’, current and hence required power becomeshalf.
V= rms × R = ×R
Z ‘R’, d ksnq
xuk d jusij]/kkjk vkSj pkgh xbZ'kfDr vk/kh jgh t k,xhA
(here z = R) (;gkaz = R) Since blfy ,, P = B  Lv

100 73. The photo electric effect can be explained if photon is considered
V = V rms = 100 volt & rms = = 2 Amp. as particle i.e.quantum nature.
50
(iz
d k'k oS| qr izHkko d h O;k[;k Q ksVku d ksd .k ekuusij laHko gSA)
70. First excitation energy çFke mÙkst u Å t kZ
¼vFkkZ
r Dok.Ve iz
d f̀r½
 1 1  3
= RhC  2  2  = RhC 74. As the number of protons increases, Coulomb repulsive force
 1 2  4 among protons increases. To compensate, number of neutrons
which are neutral is increased.
3 4V
 RhC = V e.v..  RhC = e.v.. pwa
fd çks
VkWuks
ad hla[;kc<+
rhgSA çksVkWuksad se/; d w
y kW
e çfrd "kZ.kcy c<+rk
4 3
gS
A {kfriwfrZd jusd sfy, U;w
Vª
kWuks
a¼t ksmnklhu gS½ d hla[;k c<+rhgSA
71. (1) No, when object is between infinite and focus ,image is real.
dN ln 2 1 6.02  10 23
ugh, t c oLrqv uUr rFkk Q ksd l d se/; gS] izfrfcEc okLrfod gS 75. = n = T ×
dt 1/ 2 238
(3) when object is between pole and focus, image is magnified.
t c oLrq/kzqo rFkk Q ksd l d se/; gS] izfrfcEc v kof/kZr gksxk
ln 2  6.023  10 23
(4) when object is between pole and focus image formed by  T1/2 = = 4.5 × 109 yrs.
convex mirror is real. 238  1.24  10 4
t c oLrq/kzqo rFkk Q ksd l d se/; gS] mÙky niZ.k }kjk cuk izfrfcEc The activity = number of disintegration per second
okLrfod gksxk (l fØ ;rk = iz
fr l d S.M fo?kVu d h l a[;k)
= 1.24 × 104 dps

ANSWER KEY
Q.No. 1 2 3 4 5 6 7 8 9 10
Ans. 1 3 1 2 3 4 2 4 3 1

Q. No. 11 12 13 14 15 16 17 18 19 20

Ans. 1 3 1 2 3 3 4 2 3 2

Q. No. 21 22 23 24 25 26 27 28 29 30
Ans. 1,2,3,4 1,3,4 1,2,3 1,2,3,4 1,2,3,4 3 2 3 4 1
Q. No. 31 32 33 34 35 36 37 38 39 40

Ans. 2 2 2 3 4 1 1 3 3 3

Q. No. 41 42 43 44 45 46 47 48 49 50
Ans. 1 3 2 4 4 1, 2 3, 4 2,3,4 1, 2 1,2,3

Q. No. 51 52 53 54 55 56 57 58 59 60

Ans. 2 1 1 1 1 1 4 1 2 3

Q. No. 61 62 63 64 65 66 67 68 69 70

Ans. 3 3 3 1 3 4 3 1 1 3

Q. No. 71 72 73 74 75
Ans. 1,3,4 1,2,4 1.2.3 3,4 1,4

RESONANCE Sol. - XII - 4