Penentuan linieritas dan LoD & LoQ metode Volumetri 700

600
konsentrasi y ŷ y- ŷ (y- ŷ)2 f(x) = 10 x − 13.25
500 R² = 0.995855994243
0 0 -13.25 13.25 175.5625

Volume titrasi
20 175.5 186.75 -11.25 126.5625 400
40 369.5 386.75 -17.25 297.5625 300
60 602 586.75 15.25 232.5625 200
∑ 832.2500 100
SD 20.3991 0
slope 10 0 10 20
intersep -13.25 Konsentr
lod 6.1197
loq 20.3991

Penentuan Presisi
Metode Gravimetri Metode Volumetri
pengulangan C c bar-ci (c-ci)^2 pengulangan
1 56.43 0.1214 0.0147 1
2 56.26 -0.0486 0.0024 2
3 56.13 -0.1786 0.0319 3
4 56.16 -0.1486 0.0221 4
5 56.14 -0.1686 0.0284 5
6 56.12 -0.1886 0.0356 6
7 56.92 0.6114 0.3738 7
c bar 56.31 0.5089 c bar
SD 0.2912 SD
%RSD 0.5172 %RSD

Penentuan Akurasi
Metode Gravimetri Metode Volumetri
Pengulangan kadar Pengulangan
1 56.68 1
2 56.37 2
3 56.48 3
Cspike 56.51 Cspike
C std 0.2185 C std
Cdispike 56.31 Cdispike
%recovery 91.53 %recovery

Penentuan Ketidakpastian pengukuran

Gravimetri Volumetri
Sumber x ux ux/x ux/x^2 Sumber
bobot endapan 0.1079 0.0173 0.1603 2.571.E-02 volume sampel
bobot sampel 0.0602 0.0001 0.0017 2.759.E-06 massa endapan
Ar Ca 40.08 0.0023 0.0001 3.293.E-09 pengulangan
Pengulangan 1 0.1101 0.1101 0.0121 Ar Ca
Mr CaCO3 128.0996 0.0026 2.02967E-05 4.120.E-10 volume sampel
Jumlah 0.0378 Normalitas KMnO4
jumlah^0,5 0.1945
kadar 56.31
10.9525
µD 21.9050
 f(x) = 10 x − 13.25
R² = 0.995855994243952

0 10 20 30 40 50 60 70
Konsentrasi standar kalsium mg/L

C c bar-ci (c-ci)^2
57.10 -0.0129 0.0002
57.54 0.4271 0.1825
56.66 -0.4529 0.2051
56.89 -0.2229 0.0497
57.11 -0.0029 0.0000
57.13 0.0171 0.0003
57.36 0.2471 0.0611
57.11 0.4987
0.2883
0.5048

e Volumetri
kadar
57.64
56.13
59.25
57.67
0.2185
57.11
257.82

x ux ux/x ux/x^2
75 0.0248 0.0003 1.09E-07
0.06 0.0001 0.0017 2.78E-06
1 0.1090 0.1090 0.0119
40.08 0.0023 5.74E-05 3.29E-09
16.66 0.0248 1.49E-03 2.22E-06
0.1 8.52E-05 8.5.E-04 7.26E-07
Jumlah 0.0119
jumlah^0,5 0.1090
kadar 57.11
6.2265
µD 12.4530