A strong acid is a substance that ionizes completely through the donation of a proton
(hydrogen ion). A strong base is a substance that ionizes completely through the
acceptance of a proton.
Strong bases included those substances that dissociate completely to produce a hydroxide
ion which, in turn, accepts a proton.
g s olute 1 0 .5g KI
% (m/m) x 1 0 0 x 1 0 0 2 5 .2% (m/m)
g s oln (1 0 .5g 3 1 .2g)
solvent
The major component in a solution – “the substance that dissolves the solute”
solution
a. a pH = 6.24.
1 .0 x 1 0-14
[H3O ] 2 .6 x 1 0-13 M
3 .9 0x 1 0-2
1
5. (8 points) Balance the following oxidation-reduction reaction for acidic conditions.
2-
red : (6 e- 1 4 H C r2O7 2 C r3 7 H2O ) 1
2
ox : (Fe Fe3 e- ) 6
2-
red : 6 e- 1 4 H C r2O7 2 C r3 7 H2O
ox : 6 Fe2 6 Fe3 6 e-
2-
overall: 1 4 H (aq) C r2O7 (aq) 6 Fe2 (aq) 2 C r3 (aq) 7 H2O (l) 6 Fe3 (aq)
6. (4 points) For the reaction above, identify the reducing agent and the oxidizing agent.
Indicate which element is being oxidized and which element is being reduced.
7. (5 points) What is the oxidation number of the underlined element in each compound?
a. Fe(OH)3 Fe = +3
b. H2SO4 S = +6
c. K2Cr2O7 Cr = +6
d. AsO43- As = +5
e. H2O2 O = -1
8. (6 points) Consider how each of the following factors will affect the solubility of a solute in
a solvent:
2
9. (5 points) How many grams of potassium dichromate and water are needed to produce
250.0 g of a 14.5% (m/m) solution?
determine the direction (left or right) that the equilibrium will be shifted by each of the
following changes:
11. (10 points) Balance the following chemical equations and write them as net-ionic
equations:
net-ionic equation:
net-ionic equation:
3
12. (8 points) What is the molarity of a 10.0% sodium hydroxide solution? Assume the
density of the solution is 1.1 g/mL.
A s s ume1 0 0g s oln!
1 mL s oln 1 x 1 0-3 L
1 0 0g s olnx x 0 .0 909 L s oln
1 .1 g s oln 1 mL
1 mol N aO H
1 0 .0g N aO Hx 0 .2 5 0mol N aO H
4 0 .0 0g N aO H
0 .2 5 0mol N aO H
2 .75 M N aO H 2 .8 M N aO H
0 .0 909 L s oln
13. (8 points) Sulfur dioxide and oxygen form an equilibrium with sulfur trioxide:
a. What is the equilibrium constant if the equilibrium concentrations are [N2] = 5.0
M, [H2] = 2.0 M, [NH3] = 10.0 M?
1/3 1/3
[N2 ][H2 ]3 K[N H3]2 (0 .4 0 )(3 .0)2
K [H2 ] 1 .1M
[N H3]2 [N2 ] 3 .0
14. (8 points) Identify whether the following process represent oxidation, reduction, or non-
redox process. Provide a brief explanation to support each of your choices:
e. Ca CaO
oxidation… the oxidation number of calcium has increased with the gain in oxygen
4
15. (12 points) A solution, prepared by dissolving 0.420 g K2CO3 into 50.0 mL of water, is
titrated with 0.105 M HCl.
1 mol
0 .4 2 0g x 0 .0 0 3 0
38 mol
1 3 8 .1 2g
0 .0 0 3 0
38 mol
0 .0 6 0 8M
0 .0 5 0 0L
b. Write the chemical equation for the reaction between potassium carbonate and
hydrochloric acid.
c. How many milliliters of the 0.105 M hydrochloric acid are required to neutralize the
potassium carbonate solution?
1 mL
0 .0 5 7 9L x 5 7 .9mL
1 x 1 0-3 L