HazardCommunication

HAZCOM Program Elements

 Terdiri dari :
 GHS, DOT, MSDS, NFPA, HMIS, Label, Signage, Risk
& Safety Phrase.
 Employee Information & training

 Prosedur tertulis (Written Plan)

 Hazardous chemicals list
(Chemical Inventory List).
 Communication with employees

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 OSHA - Hazard Communication Standard.
 Karyawan berhak tahu ttg bahaya bahan kimia di tempat
kerja.
 Manajemen wajib memberikan kepada karyawannya :
training yg sesuai, Informasi, PPE dan factor safety lainnya
terkait bahaya bahan kimia.
 Karyawan perlu :
 Mengikuti training secara serious.
 Baca Label dan MSDS (Material Safety Data Sheets)
 Tahu kemana mencari MSDS.
 Gunakan PPE yang sesuai.
 Fahami prosedur kedaruratan (emergency)
 Kembangkan kebiasaan kerja yg aman (safe work Habits).

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Slide 4 © 2001 By Default!

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 Major Changes/Impact of GHS
 Section 2 of the SDS
 9 pictograms that visually describe hazards
 2 signal words (danger and warning) that
describe the hazards
 72 individual and 17 combined precautionary
statements.

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 Flammables
Self Reactives
Pyrophorics Oxidizers
GHS Pictogram
Self-heating
Emits Flammable Gas
(8mandatory)
Organic Peroxides FLAME OVER
FLAME CIRCLE

Carcinogen
Corrosives Respiratory Sensitizer
Skin corrosion/burns, Reproductive Toxicity
eye damage Target Organ Toxicity
corrosive to metals Mutagenicity
HEALTH HAZARD Aspiration Toxicity
CORROSION

Acute
Irritant Toxicity
Dermal Sensitizer (severe) Aquatic toxicity
Acute Toxicity -- Not Mandatory --
(harmful)
Narcotic Effects SKULL & CROSSBONES
EXCLAMATION Respiratory Tract Irritation
MARK

Explosives Gases Under

Self Reactives Pressure
Organic Peroxides
GHS = Globally Harmonized System

EXPLODING BOMB
GAS CYLINDER 6
Slide 7 © 2001 By Default!

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 Material Safety Datasheet (MSDS)
 Adalah dokumen tentang satu bahan kimia yang harus
ada pada industri yang membuat , menyimpan, atau
mengguna-kannya, yang memberikan informasi tentang
bahan kimia tsb.
 Sebagai informasi acuan bagi para pekerja dan supervisor
yang menangani langsung dan mengelola bahan kimia
berbahaya dlm industri/lab. kimia.
 Diharapkan pekerja mempunyai naluri untuk mencegah
dan menghindari serta mampu menanggulangi
kecelakaan kimia yang mungkin terjadi.
 Informasi ini agar bersikap hati-hati dalam menangani
bahan kimia berbahaya.
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 Material Safety Datasheet (MSDS)
 Setiap bahan kimia harus dilengkapi dengan MSDS.
 Pihak manufaktur harus melengkapi setiap bahan kimia
yang di produksinya dengan MSDS.
 Tujuannya untuk mengkomunikasikan informasi tentang
bahan kimia tersebut serta cara bekerja yang aman
dengan bahan tersebut.
 Sebelum menggunakan bahan kimia baru, karyawan harus
membaca MSDS bahan tersebut terlebih dahulu.
 Lokasi penempatan MSDS : MSDS harus dapat diakses
oleh karyawan setiap saat diperlukan !!!!.
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 Material Safety Datasheet (MSDS) -
Kepmenaker 187 thn 1999
MSDS mencakup :
1. Identitas bahan dan 8. Pengendalian pemajanan dan
perusahaan APD
2. Komposisi bahan 9. Sifat-sifat fisika dan kimia
3. Identifikasi bahaya 10. Reaktifitas dan stabilitas
4. Tindakan P3K
11. Informasi toksikologi
5. Tindakan penanggulangan
kebakaran 12. Informasi ekologi
6. Tindakan thd tumpahan dan 13. Pembuangan limbah
kebocoran
14. Pengangkutan
7. Penyimpanan dan
penanganan bahan 15. Peraturan perundang2an
16. Informasi lain yang diperlukan
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 Contoh MSDS :

FORMALDEHYDE

 Apa yang perlu diperhatikan dari MSDS

nya??

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 Product Identification

1. Product Identification
Synonyms: Formaldehyde 37%; Formalin; Morbicid Acid;
Methylene Oxide; Methyl aldehyde CAS number is a unique
CAS No.: 50-00-0 identifier for each
Molecular Weight: 30.03 chemical (like a Social
Chemical Formula: HCHO and CH3OH in water Security Number). It
Product Codes: eliminates confusion
J.T. Baker: 2105, 2106, 2107, 2108 when there are
Mallinckrodt: 5014, 5016 numerous chemical
synonyms
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 Composition/Information on
Ingredients
2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous
------------------------------------- ------------ ------------ ---------
Formaldehyde 50-00-0 37% Yes
Methyl Alcohol 67-56-1 10 - 15% Yes
Water 7732-18-5 48 - 53% No

It is important to know A generic

how much of each determination of the
ingredient is present to chemical’s toxicity.
help determine toxicity Not supplied on all
MSDS’s

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 Hazard Identification
3. Hazards Identification General overview of
Emergency Overview chemicals risks
--------------------------
POISON! DANGER! SUSPECT CANCER HAZARD. MAY CAUSE
CANCER. Risk of cancer depends on level and duration of
exposure. VAPOR HARMFUL. HARMFUL IF INHALED OR
ABSORBED THROUGH SKIN. CAUSES IRRITATION TO SKIN,
EYES AND RESPIRATORY TRACT. STRONG SENSITIZER. MAY
BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. CANNOT
BE MADE NONPOISONOUS. FLAMMABLE LIQUID AND
VAPOR.

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 Hazard Identification
SAF-T-DATA(tm) Ratings (Provided here for your convenience)
--------------------------------------------------------------------------------Health Rating:
3 - Severe (Poison)
Flammability Rating: 2 - Moderate
Reactivity Rating: 2 - Moderate
Contact Rating: 3 - Severe (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT
HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
Storage Color Code: Red (Flammable)

Color coding
system on slide in
Section 7
Handling/Storage
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 Safety Data Sheets
 Formerly MSDS
 Required by OSHA in the Hazard Communication
Standard (HCS) – not effective until June 1, 2015
 Standardized sections (compared to MSDS) – 16 of
them
 Used to communicate hazards

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 Signal Words
 Two signal words; used to indicate the
relative level of severity of the hazard:
 Danger

 Warning

 Danger indicates a more serious hazard than

warning

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 SDS Section Titles
1. Identification
2. Hazard(s) identification
3. Composition/information on ingredients
4. First-aid measures
5. Fire-fighting measures
6. Accidental release measures
7. Handling and storage
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 SDS Section Titles
8. Exposure controls/personal protection
9. Physical and chemical properties
10. Stability and reactivity
11. Toxicological information
12. Ecological information
13. Disposal considerations
14. Transport information
15. Regulatory information
16. Other information
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The Major Change in SDSs

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The Major Change in SDSs

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The Major Change in SDSs

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The Major Change in SDSs

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Slide 24 © 2001 By Default!

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 Trade Name/Ingredients Statement

Trade
Name

Active
Ingredients
Common &
chemical name
Inert Ingredients
Dissolve active ingredient or affect how product works
(may contain synergist, spreader, etc.) 25
 Signal Words

 DANGER* - highly toxic

 WARNING – moderately toxic

 CAUTION – slightly toxic

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 WHO – Klasifikasi Toksisitas
LD50 pada tikus (mg/kg BB)
Class ORAL DERMAL
Solid Liquid Solid Liquid
Ia Extremely ≤5 ≤ 20 ≤ 10 ≤ 40
hazardous
Ib Highly 5 – 50 20 - 200 10 - 100 40 - 400
hazardous
II Moderately 50 - 500 200 - 2000 100 - 1000 400 - 4000
hazardous
III Slightly > 500 > 2000 > 1000 > 4000
hazardous
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 Label
DANGER - POISON
 Highly toxic by any route of entry

DANGER-POISON
PELIGRO
PRECAUTIONARY STATEMENTS
HAZARDS TO HUMANS
AND DOMESTIC ANIMALS

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 Label

WARNING
 Moderately toxic

WARNING
AVISO
PRECAUTIONARY STATEMENTS
HAZARDS TO HUMANS
AND DOMESTIC ANIMALS
DANGER
Causes moderate eye damage and/or skin irritation.....
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 Label

Caution
• slightly toxic

CAUTION
PRECAUCION
PRECAUTIONARY STATEMENTS
HAZARDS TO HUMANS
AND DOMESTIC ANIMALS
CAUTION
Avoid contact with eyes, skin or clothing.

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 Contoh Label
 Contoh label JT Baker dengan kode warna:

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 Container Label

Hazard Warnings Chemical Name

Manufacturer

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Slide 33 © 2001 By Default!

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 NFPA Diamond System
 NFPA (National Fire Protection Association
704 Diamond System.
 Setiap kotak berwarna yang berbentuk
“diamond” merepresentasikan kelas
bahaya yang berbeda.
 Setiap kelas bahaya dengan warna yang
berbeda, mempunyai skala dari 0 - 4.

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OX Oxidizing Agent
Labels - Health
SpecialHazard
Stability Hazard
Flammability
HazardHazard
4 Danger Deadly. May be fatal on short exposure.
W Water Reactive Specialized protective equipment
G Compressed Gas required
LN2 Liquid Nitrogen 3 Warning Extreme Danger. Corrosive or toxic.
Avoid skin contact or inhalation
LHE Liquid Helium
2 Warning Dangerous. May be harmful if inhaled or
COR Corrosive absorbed
BIO Biohazards Caution Slight Hazard. May be irritating
1
ACD Acid
0 No unusual hazard
POI Poison
ALK Alkali
4 Danger Ignites below 73 °F. Flammable gas or
RAD Radioactive extremely flammable liquid
4 Danger May detonate. Explosive material at
room temperature 3 Warning Ignites below or Flammable liquid flash
Danger May be explosive if shocked, heated point below 100°F
3
under confinement or mixed with water 2 Caution Ignites below 200°F. Combustible liquid
Warning Unstable or may react violently if mixed flash point of 100° to 200°F
2
with water 1 Ignites above 200°F. Combustible if
Caution Normally Stable. May react if heated or heated
1
mixed with water but not violently 0 Will not burn. Not combustible
0 Stable Not reactive when mixed with water 35
NFPA Diamond System

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Slide 37 © 2001 By Default!

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 Chemical Hazards
 Bentuk
Lain :
Hazardous Material Identification
System
Slide 40 © 2001 By Default!

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 Klasifikasi Lainnya

Risk Phrase & Safety Phrase.

 Selain klasifikasi NFPA dan HIMS , dalam
dokumen bahan kimia dipergunakan pula kode
Resiko (Risk = R) dan kode keselamatan (Safety =
S)

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 Kode Risiko Kesehatan

Contoh “Risk Phrases (R)” :

 R1 : eksplosif bila kering
 R2 : eksplosif bila kena benturan, gesekan, atau
sumber api.
 R3 : resiko tinggi terhadap eksplosif bila kena
benturan, gesekan, dan sumber api.
 R4 : membentuk senyawa metal yang eksplosif
 R 35 : penyebab kebakaran yang parah pada kulit.
 Dst.

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 Kode Keselamatan

Contoh Safety Phrases (S)

 S1 : jaga selalu tertutup
 S2 : jauhkan dari anak2
 S3 : simpan dalam suhu dingin
 S24 : hindarkan kontak dgn kulit
 S25 : hindarkan kontak dengan mata
 S26 : bila kena mata, cuci dg air dan pergi ke dokter
 Dst.

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 Contoh : Penggunaan Kode

 Trichloroacetic acid

R : 35 S : 24/25/26

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Slide 45 © 2001 By Default!

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Signage

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Signage

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Signage

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Signage in Lab

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Slide 53 © 2001 By Default!

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 Right to Know ( RTW )
5 Elements of your RTK Program

Written Policies Chemical

Inventory

Labeling Material Safety

Data Sheets
Training and Safety
Awareness
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