Saturated salution:
Equation:
H2O
AgCl(s) Ag+(aq) + Cl-(aq)
Strict adherence to the rules for writing equilibrium constant expressions for
this reaction gives the following result.
The [Ag+] and [Cl-] terms represent the concentrations of the Ag+ and Cl-ions
in moles per liter when this solution is at equilibrium. The third term [AgCl]
is more ambiguous. It doesn't represent the concentration of AgCl
dissolved in water because we assume that AgCl dissociates into Ag+ions and
Cl- ions when it dissolves in water. It can't represent the amount of solid AgCl
in the system because the equilibrium is not affected by the amount of
excess solid added to the system. The [AgCl] term has to be translated quite
literally as the number of moles of AgCl in a liter of solid AgCl.
Since the [AgCl] term is a constant, which has no effect on the equilibrium, it
is built into the equilibrium constant for the reaction.
[Ag+][Cl-] = Kc x [AgCl]
Ksp = [Ag+][Cl-]
The Ksp expression for a salt is the product of the concentrations of the ions,
with each concentration raised to a power equal to the coefficient of that ion
in the balanced equation for the solubility equilibrium.
Examples :
Ksp = [Na+][Cl-]
Ksp = [Ag+][Cl-]
Ksp = [Pb2+][Cl-]2
Ksp is called the solubility product because it is literally the product of the
solubilities of the ions in moles per liter. The solubility product of a salt can
therefore be calculated from its solubility, or vice versa.
Photographic films are based on the sensitivity of AgBr to light. When light
hits a crystal of AgBr, a small fraction of the Ag+ ions are reduced to silver
metal. The rest of the Ag+ ions in these crystals are reduced to silver metal
when the film is developed. AgBr crystals that do not absorb light are then
removed from the film to "fix" the image.
Example: Let's calculate the solubility of AgBr in water in grams per liter, to
see whether AgBr can be removed by simply washing the film.
H2O
AgBr(s) Ag+(aq) + Br-(aq)
[Ag+] = [Br-]
Substituting this equation into the Ksp expression gives the following result.
Taking the square root of both sides of this equation gives the equilibrium
concentrations of the Ag+ and Br- ions.
Once we know how many moles of AgBr dissolve in a liter of water, we can
calculate the solubility in grams per liter.
The solubility of AgBr in water is only 0.00013 gram per liter. It therefore
isn't practical to try to wash the unexposed AgBr off photographic film with
water.
Solubility product calculations with 1:1 salts such as AgBr are relatively easy
to perform. In order to extend such calculations to compounds with more
complex formulas we need to understand the relationship between the
solubility of a salt and the concentrations of its ions at equilibrium. We will
use the symbol Cs to describe the amount of a salt that dissolves in water.
APPLICATIONS:
Ksp = [Ag+]2[S2-]
We then substituted the relationship between the concentrations of these
ions and the solubility of the salt into this equation.
When they see this for the first time, students often ask: "Why did you
double the Ag+ ion concentration and then square it? Aren't you counting this
term twice?"
This question results from confusion about the symbols used in the
calculation. Remember that the symbol Cs in this equation stands for the
solubility of Ag2S in moles per liter. Since we get two Ag+ ions for each Ag2S
formula unit that dissolves in water, the Ag+ ion concentration at equilibrium
is twice the solubility of the salt, or 2 Cs. We square the Ag+ion concentration
term because the equilibrium constant expression for this reaction is
proportional to the product of the concentrations of the three products of the
reaction.
Ksp = [Ag+][Ag+][S2-]
Ksp = [Ag+]2[S2-]
[S2-] = 2 [Ag+]
This seems reasonable to some, who argue that there are twice as many
Ag+ ions as S2- ions in the compound. But the equation is wrong. Because two
Ag+ ions are produced for each S2- ion, there are twice as many silver ions as
sulfide ions in this solution. This solution is correctly described by the
following equation.
[Ag+] = 2 [S2-]
PURIFICATION OF COMMON SALT:
[Na+] [Cl-] exceeds solubility product of NaCl thus pure solid NaCl is
precipitated
GROUp ANALYSIS:
For the precipitation of ionic metallic radicals use is made of the solubility
product principle.
In others words
EXPLAINATION:
common-ion effect, decrease in solubility of an ionic salt, i.e., one that dissociates in
solution into its ions, caused by the presence in solution of another solute that contains one of
the same ions as the salt. The common-ion effect is an example of chemical equilibrium.
Example
silver chloride, AgCl, is a slightly soluble salt that in solution dissociates into the ions Ag+ and
Cl−, the equilibrium state being represented by the equation AgClsolidAg++Cl−. According to Le
Châtelier's principle, when a stress is placed on a system in equilibrium, the system responds
by tending to reduce that stress. In the system taken as an example, if another solute
containing one of those ions is added, e.g., sodium chloride, NaCl, which supplies Cl− ions, the
solubility equilibrium of the solution will be shifted to remove more Cl− from the solution, so
that at the new equilibrium point there will be fewer Ag+ ions in solution and more AgCl
precipitated out as a solid.
When the metal ion is bonded to a group of surrounding molecules or ions are called
metal complexes or simply complexes. This phenomena is known as complex formation.
Some terms of complexes:
LIGANDS:
Ligands are the lewis bases attached to the metal in acomplex . an ion or the
molecule that coordinates to the metal atom or to ametal ion to form a complex is called a
ligand
COORDINATION SPHERE:
In forming a complex the ligands are said to be coordinated to the metal and the
ligand s bound to it constitute the coordination sphere of the complex
COORDINATION NUMBER:
The coordination number of metal atom in complex is the total number of bonds the
metal atom forms with ligands .
CHELATION:
The word chelation is derived from Greek χηλή, chelè, meaning claw; the ligands lie around the
central atom like the claws of a lobster.[2]
Chelation is the formation or presence of two or more separate coordinate bonds between
a polydentate(multiple bonded) ligand and a single central atom.[1]Usually
these ligands are organic compounds, and are called chelants, chelators, chelating agents, or
sequestering agents.
The ligand forms a chelate complex with the substrate. Chelate complexes are contrasted
withcoordination complexes composed of monodentate ligands, which form only one bond with
the central atom.