Applied Science ICA 3. Due Date 19 April 2010. 1 RbF is an ionic compound but GeF4 is covalent.

Explain the terms ionic and covalent, and explain why the bonding in the two compounds is different. [9 marks] 2 (a) 22.6 g of KOH was dissolved in water and diluted to 150 cm3. (i) (ii) (b) What was the concentration of the solution (in mol L-1)? [1 marks] What was the pH of the solution? [2 marks] 108.9 g of HBr gas was completely dissolved in 1.48 L of water. (i) (ii) What was the concentration of the solution (in mol L-1)? [1 marks] What was the pH of the solution? [2 marks] 3 (a) Which of these are correct representations of phenol? OH OH OH OH

D [2 marks]

(a)

Draw this compound showing all atoms.

[3 marks] (b) Name the compound shown in question 4(a) above. Include any relevant designation of stereochemistry. [5 marks] (c) Complete this reaction for the synthesis of a secondary amine:

CH3CH3Br

CH3CH2NH2
[4 marks]

(a)

Identify the functional groups in these compounds (0.5 marks each):

(A) CH3CH2Cl (B) C6H5NO2 (C) CH3SSCH3 (D) CH3I (E) R-OH

CHO

(F) H (H) H

(G)

[4 marks] (b) Give the systematic name of this hydrocarbon:

[1 mark]

(a) (b)

Explain why acetone is soluble in water. [2 marks] What is the final product of the oxidation of (i) (ii) an aldehyde a ketone? [4 marks]

Briefly explain your answer.

This is Betanidin, the molecule responsible for the colour of beetroot. Identify which classes of functional groups it contains:
Glucose HO N
+

COO-

HOOC

N H

COOH

Betanidin

[3 marks] 8 (a) Briefly explain why you would expect an alcohol to have a higher or lower boiling point than an alkane of similar molecular weight [2 marks] (b) Complete this reaction showing the oxidation of a secondary alcohol. [O] indicates a mild oxidising agent. OH H3C CH3 [3 marks] H [O]

(a)

Systematically name this compound: CH3CH2CH2NH2 [1 mark]

(b)

Is the compound below a primary, secondary or tertiary amine? Explain why.

CH3CH2CH3

N CH3 H
[2 marks]

10

(a)

What is the systematic name for this compound?

[2 marks] (b) Complete the reaction sequence shown below: OH H3C H [5 marks] 11 (a) (b) List the three main classes of hormone. [3 marks] Some neurotransmitters, including DOPA (below), are synthesised from tyrosine. Draw the structure of the amino acid tyrosine. CH2 CH HO OH [5 marks] (c) What are antihistamines? [2 marks] NH3+ COOH

[O]

[O]

12

Which of the following are amino acids and which are not?

[4 marks] 13 Name the following three amino acids and give their three letter abbreviations. (a) (b) (c)

[6 marks]

14

(a)

Calculate the standard enthalpy of the following reaction C2H5OH(l) + O2(g) CH3CO2H(l) + H2O(l) from the following data: Hf(C2H5OH(l) ) = -277.7 kJ/mol Hf(CH3CO2H(l) ) = -484.5 kJ/mol Hf(H2O(l) ) = -285.8 kJ/mol [2 marks]

(b)

Calculate the molar heat capacity of copper (Cu), if it takes 103.3 J of energy to raise the temperature of 26.4 g by 11 oC. [2 marks]

15

(a)

Is the molecule below -D-glucose or -D-glucose?

[1 mark] (b) (c) Is it a furanose or a pyranose? [1 mark] Is it a tetrose, pentose or a hexose? [1 mark] 16 (a) What is the name of the sugar shown below?

[2 marks]

17

Below is the molecule maltose

What specific type of bond is between the glucose residues? [3 marks] 18 (a) Give the common name of the fatty acid shown below.

[2 marks] (b) Draw myristic acid (i.e the carbon 14 fatty acid with no double bonds). [2 marks] 19 (a) Draw the general basic structure of a steroid (i.e. the shape of the steroid nucleus). [3 marks] (b) Draw the basic molecular structure of a phospholipid. [3 marks]