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Sebanyak 1 gram sampel dilarutkan menjadi 100 mL --> dianalisis kadar Cd dengan AAS

No Standar Cd 5 ppm (mL) H2O (mL) [Cd] ppm Abs

1 0 10 0 0
2 0.8 9.2 0.4 0.123
3 1.6 8.4 0.8 0.218
4 2.4 7.6 1.2 0.318
5 3.2 6.8 1.6 0.398
6 4 6 2 0.504
Jumlah 6 1.561
Rata 1 0.26016667

Sxx = 2.8 Beta =

Sxy = 0.689 Alfa =

Y = 0,246 X + 0,014
Sampel Cd 10 ppm Volume
(gram) (mL) (mL)
A = 0,246 C + 0,014 1 - 100
1 2 100
1 4 100
1 6 100

XX XY
0 0
0.16 0.0492
0.64 0.1744
1.44 0.3816
2.56 0.6368
4 1.008
8.8 2.25

0.24607143
0.01409524

Abs [Terukur] mg/L [Terukur] mg/100 mL [Teoritis] mg/100 mL

0.234 0.894308943089 0.0894308943089431 -
0.273 1.052845528455 0.105284552845528 0.109430894308943
0.325 1.264227642276 0.126422764227642 0.129430894308943
0.373 1.459349593496 0.145934959349593 0.149430894308943
Rata-ratav=

[Cd] = 0.0920 mg/1 gram sampel

92.024 ppm (mg/kg)

10 mg/1000 mL
0.02 mg/ 2 mL
Recovery (%)

96.21
97.68
97.66
97.18
Rumus Std dev= √(∑▒(𝑥−𝑥 ̅ )
^2/(𝑁−1))

A = 0,246 C + 0,014

Sampel CRM 1 gram /

No 100 mL Abs [Cd] ppm (mg/L)
1 Pengukuran 1 0.234 0.8943089
2 Pengukuran 2 0.238 0.9105691
3 Pengukuran 2 0.229 0.8739837
4 Pengukuran 4 0.232 0.8861789
5 Pengukuran 5 0.23 0.8780488

m = 90 ppm
v= √(∑▒(𝑥−𝑥 ̅ )
𝑁−1))

[Cd] mg/100 mL [Cd] ppm (mg/kg) X - Rata2 (X-Rata2)2

0.0894309 89.4308943 0.56910569 0.32388129
0.0910569 91.0569106 2.19512195 4.81856038
0.0873984 87.3983740 -1.4634146 2.14158239
0.0886179 88.6178862 -0.2439024 0.0594884
0.0878049 87.8048780 -1.0569106 1.11705995
Jumlah 444.308943089431 8.46057241
Rata-Rata 88.8617886178862

Std Dev = 1.45435315609742

t hitung = -1.75
t tabel = 2.78 t tabel pada df = (N-1)
Karena t hitung < t tabel maka kedua data tidak berbeda secara signifikans
signifikans
Rumus

No Metode Baku X - Xrata (X-Xrata)2

1 87 -2.5 6.25
2 92 2.5 6.25
3 91 1.5 2.25
4 88 -1.5 2.25
Jml 358 17
Rata 89.5
Sd = 2.3804761428

No Metode 2 X - Xrata (X-Xrata)2 RSD =

1 90 1 1
2 87 -2 4
3 89 0 0
4 92 3 9
5 87 -2 4
Jml 445 18
Rata 89
sd = 2.1213203436
l pada df = (N1 + N2 -2)

Sp2 = 5

Sxx = 1.5

thit = 0.333333

t tabel 2.36

2.383506 %

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