ACETANILIDE

1. Product Identification Synonyms: N-Phenylacetamide; Acetamidobenzene; Acetic Acid Anilide; Acetanil; Acetylaminobenzene; N-Acetylaniline; n-Phenyl Acetamide CAS No.: 103-84-4 Molecular Weight: 135.17 Chemical Formula: C8H9NO Product Codes: 2. Composition/Information on Ingredients
Ingredient --------------------------------------Acetanilide CAS No -----------103-84-4 Percent Hazardous -------------99 - 100% Yes

3. Hazards Identification Emergency Overview WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE CYANOSIS. Health Rating: 1 - Slight Flammability Rating: 1 - Slight Reactivity Rating: 0 - None Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: Inhalation of dust or vapors may cause irritation to the respiratory tract and mucous membranes. May cause skin eruptions. Ingestion: High toxicity in man. Several grams may produce poisoning with circulatory collapse, cold extremities, paleness and feeble rapid pulse. Cyanosis is the prominent effect. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: Lengthy exposures may affect the ability of blood to carry oxygen (methemoglobinemia), resulting in bluish discoloration of lips and tongue (cyanosis). May also result in damage to the blood-forming organs, with anemia. Aggravation of Pre-existing Conditions: No information found.

4. First Aid Measures Inhalation: If inhaled, remove to fresh air. Administer amyl nitrite and oxygen if symptoms occur. Keep patient warm and at rest. DO NOT GIVE MOUTH-TO-MOUTH RESUSCITATION. Get medical attention. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Flash point: 174C (345F) CC Autoignition temperature: 530C (986F) Combustible solid. Moderate fire hazard when exposed to heat or flame. Explosion: Above the flash point, explosive vapor-air mixtures may be formed. Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document,

Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, airsupplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: White shining crystalline leaflets or white crystalline powder. Odor: Odorless. Solubility: 1gm/185 ml water Specific Gravity: 1.219 @ 15C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: 304C (579F) Melting Point: 113 - 115C (235 - 239F) Vapor Density (Air=1): 4.65 Vapor Pressure (mm Hg): 1 @ 114C (237F) Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Appreciably volatile at 95C (203F). Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Caustics, strong bases and strong oxidizers. Conditions to Avoid: Heat, flames, ignition sources and incompatibles. 11. Toxicological Information Oral rat LD50: 800 mg/kg. Investigated as a mutagen. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found.

13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information 15. Other Information NFPA Ratings: Health: 3 Flammability: 1 Reactivity: 0 Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY CAUSE CYANOSIS. Label Precautions: Avoid contact with eyes, skin and clothing. Keep container closed. Use only with adequate ventilation. Avoid breathing vapor. Wash thoroughly after handling. Label First Aid: IF INHALED, remove to fresh air. If not breathing, give artificial respiration. DO NOT GIVE MOUTH-TO-MOUTH RESUSCITATION. If breathing is difficult, give oxygen. Keep patient warm and at rest. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. In all cases, get medical attention. Product Use: Laboratory Reagent. Revision Information: No changes.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

Not regulated.

ACETIC ACID GLACIAL

1. Product Identification Synonyms: Acetic acid, methane carboxylic acid; ethanoic acid CAS No.: 64-19-7 Molecular Weight: 60.05 Chemical Formula: CH3COOH Product Codes: 2. Composition/Information on Ingredients
Ingredient Acetic Acid CAS No 64-19-7 Percent 99.5 - 10 Hazardous Yes

3. Hazards Identification Emergency Overview POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE. FLAMMABLE LIQUID AND VAPOR. Health Rating: 2 - Moderate Flammability Rating: 2 - Moderate Reactivity Rating: 2 - Moderate Contact Rating: 3 - Severe (Corrosive) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER Storage Color Code: White Stripe (Store Separately) Potential Health Effects Inhalation: Inhalation of concentrated vapors may cause serious damage to the lining of the nose, throat, and lungs. Breathing difficulties may occur. Neither odor nor degree of irritation are adequate to indicate vapor concentration. Ingestion: Swallowing can cause severe injury leading to death. Symptoms include sore throat, vomiting, and diarrhea. Ingestion of as little as 1.0 ml has resulted in perforation of the esophagus. Skin Contact: Contact with concentrated solution may cause serious damage to the skin. Effects may include redness, pain, skin burns. High vapor concentrations may cause skin sensitization. Eye Contact: Eye contact with concentrated solutions may cause severe eye damage followed by loss of sight. Exposure to vapor may cause intense watering and irritation to eyes. Chronic Exposure: Repeated or prolonged exposures may cause darkening of the skin, erosion of exposed front teeth, and chronic inflammation of the nose, throat, and bronchial tubes. Aggravation of Pre-existing Conditions:

Persons with pre-existing skin disorders or eye problems, or impaired respiratory function may be more susceptible to the effects of the substance. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: DO NOT INDUCE VOMITING! Give large quantities of water or milk if available. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Call a physician. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Flash point: 40C (104F) CC Autoignition temperature: 427C (801F) Flammable limits in air % by volume: lel: 4.0; uel: 16.0 Flammable Liquid and Vapor! Explosion: Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Vapors can flow along surfaces to distant ignition source and flash back. Contact with strong oxidizers may cause fire. Reacts with most metals to produce hydrogen gas, which can form an explosive mixture with air. Fire Extinguishing Media: Water, dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Water may be used to flush spills away from exposures and to dilute spills to non-flammable mixtures. Water diluted acid can react with metals to form hydrogen gas. 6. Accidental Release Measures Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Use water spray to dilute spill to a nonflammable mixture. Contain and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Use non-sparking tools and equipment. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of

reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tools and equipment, including explosion proof ventilation. Protect from freezing. Store above 17C (63F). Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL):10 ppm (TWA). -ACGIH Threshold Limit Value (TLV):10 ppm (TWA); 15 ppm (STEL). Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full facepiece respirator with organic vapor cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a fullfacepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Clear, colorless liquid. Odor: Strong, vinegar-like. Solubility: Infinitely soluble. Density: 1.05 pH: 2.4 (1.0M solution) % Volatiles by volume @ 21C (70F): 100

Boiling Point: 118C (244F) Melting Point: 16.6C (63F) Vapor Density (Air=1): 2.1 Vapor Pressure (mm Hg): 11 @ 20C (68F) Evaporation Rate (BuAc=1): 0.97 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Heat and sunlight can contribute to instability. Releases heat and toxic, irritating vapors when mixed with water. Acetic acid contracts slightly upon freezing which may cause the container to burst. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. May also release toxic and irritating vapors. Hazardous Polymerization: Will not occur. Incompatibilities: Acetic Acid is incompatible with chromic acid, nitric acid, ethylene glycol, perchloric acid, phosphorous trichloride, oxidizers, sodium peroxide, strong caustics, most metals (except aluminum), carbonates, hydroxides, oxides, and phosphates. Conditions to Avoid: Heat, flame, ignition sources, freezing, incompatibles 11. Toxicological Information Oral rat LD50: 3310 mg/kg; skin rabbit LD50: 1.06 g/kg; inhalation mouse LC50: 5620ppm/1hr; investigated as a mutagen, reproductive effector. 12. Ecological Information Environmental Fate: When released into the air, this material may be moderately degraded by reaction with photochemically produced hydroxyl radicals. When released into air, this material is expected to have a half-life between 10 and 30 days. When released into water, this material is expected to readily biodegrade. When released into the water, this material is expected to have a half-life between 1 and 10 days. Standard dilution BOD5/TOD = 58% When released into the soil, this material is expected to readily biodegrade. This material is not expected to significantly bioaccumulate. This material has an estimated bioconcentration factor (BCF) of less than 100. Environmental Toxicity: This material is expected to be slightly toxic to aquatic life. The LC50/96-hour values for fish are between 10 and 100 mg/l. For glacial acetic acid: EC50 (wheat fumigation) = 23.3 mg/m3/2-hr, effect: leaf injury LC50 (shrimp) = 100 - 300 mg/l/48-hr LC50 (fathead minnow) = 88 mg/l/96-hr This material may be toxic to aquatic life.

13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: ACETIC ACID, GLACIAL (WITH MORE THAN 80% ACID, BY MASS) Hazard Class: 8, 3 UN/NA: UN2789 International (Water, I.M.O.) Proper Shipping Name: ACETIC ACID, GLACIAL (WITH MORE THAN 80% ACID, BY MASS) Hazard Class: 8, 3.3 UN/NA: UN2789

15. Regulatory Information

Chemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes hronic: Yes Fire: Yes Pressure: No Reactivity: Yes (Pure / Liquid)

16. Other Information

NFPA Ratings: Health: 3 Flammability: 2 Reactivity: 0 Label Hazard Warning: POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE. FLAMMABLE LIQUID AND VAPOR. Label Precautions: Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep away from heat, sparks and flame. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not

breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases get medical attention immediately. Product Use: Laboratory Reagent. 17. Disclaimer Information contained in this material data sheet is believed to be reliable but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from them. It is upto the manufacturer / seller to ensure that the information contained in the material safety data sheet is relevant to the product manufactured / handled or sold by him as the case may be. The Qualigense Fine Chemical, a Div. of Glaxo India Ltd. makes no warranties expressed or implied in respect of the adequacy of this document for any particular purpose.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ACETIC ANHYDRIDE
1. Product Identification Synonyms: Acetyl oxide; Acetic acid anhydride; Acetic oxide; Ethanoic anhydride CAS No.: 108-24-7 Molecular Weight: 102.09 Chemical Formula: (CH3CO)2O Product Codes: 2. Composition/Information on Ingredients Ingredient Acetic Anhydride

CAS No 108-24-7

Percent

Hazardous Yes

97 - 100%

3. Hazards Identification Emergency Overview DANGER! CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. FLAMMABLE LIQUID AND VAPOR. WATER REACTIVE. HARMFUL IF SWALLOWED OR INHALED. VAPOR CAUSES RESPIRATORY TRACT IRRITATION AND SEVERE EYE IRRITATION. Health Rating: 3 - Severe (Poison) Flammability Rating: 2 - Moderate Reactivity Rating: 2 - Moderate Contact Rating: 3 - Severe (Corrosive) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER Storage Color Code: Red Stripe (Store Separately) Potential Health Effects Inhalation: Vapors are corrosive to the mucous membranes of the upper respiratory tract. Exposure to vapors may cause irritation of the nose, throat, and coughing. Exposure to high concentrations may result in severe damage to the lungs. Symptoms of lung edema are often delayed and are aggravated by physical effort. Ingestion: Corrosive. Causes a burning pain in the stomach, followed by nausea and vomiting. Skin Contact: Corrosive: Does not cause severe burning on contact but can cause delayed reaction burns. If not removed by washing, the skin may become reddened and later turn white and wrinkled. Continued skin contact may cause dermatitis. Eye Contact: Corrosive: Contact with the liquid or vapor may produce a burning sensation and tearing. Redness, pain and blurred vision may be followed by permanent eye damage. The appearance of eye burns may be delayed. Irritation effects begin with

airborne concentrations as low as 0.36 mg/m3. Chronic Exposure: Repeated and prolonged exposure to vapor may cause irritation of the skin and chronic eye irritation. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems, or impaired respiratory function may be more susceptible to the effects of the substance. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Flash point: 49C (120F) CC Autoignition temperature: 316C (601F) Flammable limits in air % by volume: LEL: 2.7; UEL: 10.3 Flammable. Explosion: Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Sealed containers may rupture when heated. Vapors can flow along surfaces to distant ignition source and flash back. A violent exothermic reaction occurs with water. Sufficient heat may be produced to ignite combustible materials. Sensitive to static discharge. Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Use water with caution as material reacts with water. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Use water spray to blanket fire, cool fire exposed containers, and to flush non-ignited spills or vapors away from fire. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Water spray may be used to disperse vapors and dilute spills to

nonflammable mixtures, but be aware of the potential for violent reaction with water. Neutralize with soda ash or lime. Contain and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

7. Handling and Storage Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tools and equipment, including explosion proof ventilation. Keep away from water. This material is corrosive to steel, galvanized iron, copper and copper alloys. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL):5 ppm (TWA) -ACGIH Threshold Limit Value (TLV): 5 ppm (TWA) -NIOSH Recommended Exposure Limit (REL):5 ppm (Ceiling) Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full facepiece respirator with organic vapor cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygendeficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Rubber and neoprene are recommended materials for personal protective equipment. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties Appearance: Clear, colorless liquid. Odor: Strong acetic odor; good warning properties. Solubility: Slowly soluble in water (reacts) Specific Gravity: 1.08 @ 15C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 100 Boiling Point: 140C (284F) Melting Point: -73C (-99F) Vapor Density (Air=1): 3.52 Vapor Pressure (mm Hg): 4 @ 20C (68F) Evaporation Rate (BuAc=1): 0.46 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Heat will contribute to instability. Hazardous Decomposition Products: When heated to decomposition, it emits toxic fumes such as acetic acid and carbon monoxide. Reacts violently with water to yield acetic acid and much heat. Hazardous Polymerization: Will not occur. Incompatibilities: Water, steam, mineral acids, oxidizing materials, alcohols, or amines may cause violent reaction. Contact with strong caustics will cause violent reaction and spattering. Corrosive to copper, brass, bronze, and iron. Conditions to Avoid: Heat, flames, ignition sources, water and incompatibles. 11. Toxicological Information Oral rat LD50: 1780 mg/Kg; inhalation rat LC50: 1000 ppm/4-hour; skin rabbit LD50 4 mL/kg; Irritation data: Skin rabbit, Open Draize, 10 mg/24H mild; Eye rabbit, Open Draize, 250 ug severe 12. Ecological Information Environmental Fate: When released into the soil, this material is expected to leach into groundwater. When released to water, this material is expected to react and form acetic acid. This material is not expected to significantly bio accumulate. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal

regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: ACETIC ANHYDRIDE Hazard Class: 8, 3 UN/NA: UN1715 Packing Group: II Information reported for product/size: 40LB International (Water, I.M.O.) Proper Shipping Name: ACETIC ANHYDRIDE Hazard Class: 8, 3.3 UN/NA: UN1715 Packing Group: II International (Air, I.C.A.O.) Proper Shipping Name: ACETIC ANHYDRIDE Hazard Class: 8, 3 UN/NA: UN1715 Packing Group: II 15. Regulatory Information Chemical Weapons Convention: No TSCA 12(b): No CDTA: Yes SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactivity: Yes (Pure / Liquid)

Australian Hazchem Code: 2P Poison Schedule: S6 WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. 16. Other Information NFPA Ratings: Health: 3 Flammability: 2 Reactivity: 1 Label Hazard Warning: DANGER! CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. FLAMMABLE LIQUID AND VAPOR. WATER REACTIVE. HARMFUL IF SWALLOWED OR INHALED. VAPOR CAUSES RESPIRATORY TRACT

IRRITATION AND SEVERE EYE IRRITATION. Label Precautions: Do not get in eyes, on skin, or on clothing. Do not contact with water. Do not breathe vapor. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep away from heat, sparks and flame. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. In all cases get medical attention immediately. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ACETONE
1. Product Identification Synonyms: Dimethylketone; 2-propanone; dimethylketal CAS No.: 67-64-1 Molecular Weight: 58.08 Chemical Formula: (CH3)2CO 2. Composition/Information on Ingredients Ingredint CAS No --------------------------------------Acetone 67-64-1

Percent --------99 - 100%

Hazardous ----Yes

3. Hazards Identification Emergency Overview DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL NERVOUS SYSTEM. Health Rating: 1 - Slight Flammability Rating: 4 - Extreme (Flammable) Reactivity Rating: 2 - Moderate Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER Storage Color Code: Red (Flammable) Potential Health Effects Inhalation: Inhalation of vapors irritates the respiratory tract. May cause coughing, dizziness, dullness, and headache. Higher concentrations can produce central nervous system depression, narcosis, and unconsciousness. Ingestion: Swallowing small amounts is not likely to produce harmful effects. Ingestion of larger amounts may produce abdominal pain, nausea and vomiting. Aspiration into lungs can produce severe lung damage and is a medical emergency. Other symptoms are expected to parallel inhalation. Skin Contact: Irritating due to defatting action on skin. Causes redness, pain, drying and cracking of the skin. Eye Contact: Vapors are irritating to the eyes. Splashes may cause severe irritation, with stinging, tearing, redness and pain. Chronic Exposure: Prolonged or repeated skin contact may produce severe irritation or dermatitis. Aggravation of Pre-existing Conditions: use of alcoholic beverages enhances toxic

effects. Exposure may increase the toxic potential of chlorinated hydrocarbons, such as chloroform, trichloroethane. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: Aspiration hazard. If swallowed, vomiting may occur spontaneously, but DO NOT INDUCE. If vomiting occurs, keep head below hips to prevent aspiration into lungs. Never give anything by mouth to an unconscious person. Call a physician immediately. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. 5. Fire Fighting Measures Fire: Flash point: -20C (-4F) CC Autoignition temperature: 465C (869F) Flammable limits in air % by volume: lel: 2.5; uel: 12.8 Extremely Flammable Liquid and Vapor! Vapor may cause flash fire. Explosion: Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Vapors can flow along surfaces to distant ignition source and flash back. Contact with strong oxidizers may cause fire. Sealed containers may rupture when heated. This material may produce a floating fire hazard. Sensitive to static discharge. Fire Extinguishing Media: Dry chemical, alcohol foam or carbon dioxide. Water may be ineffective. Water spray may be used to keep fire exposed containers cool, dilute spills to nonflammable mixtures, protect personnel attempting to stop leak and disperse vapors. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Use nonsparking tools and equipment. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures. US Regulations

(CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tools and equipment, including explosion proof ventilation. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: Acetone: -OSHA Permissible Exposure Limit (PEL):1000 ppm (TWA) -ACGIH Threshold Limit Value (TLV): 500 ppm (TWA), 750 ppm (STEL) A4 - not classifiable as a human carcinogen Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face organic vapor respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece organic vapor respirator may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties Appearance: Clear, colorless, volatile liquid. Odor: Fragrant, mint-like Solubility: Miscible in all proportions in water. Specific Gravity: 0.79 @ 20C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 100 Boiling Point: 56.5C (133F) @ 760 mm Hg Melting Point: -95C (-139F) Vapor Density (Air=1): 2.0 Vapor Pressure (mm Hg): 400 @ 39.5C (104F) Evaporation Rate (BuAc=1): ca. 7.7 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Concentrated nitric and sulfuric acid mixtures, oxidizing materials, chloroform, alkalis, chlorine compounds, acids, potassium t-butoxide. Conditions to Avoid: Heat, flames, ignition sources and incompatibles. 11. Toxicological Information Oral rat LD50: 5800 mg/kg; Inhalation rat LC50: 50,100mg/m3; Irritation eye rabbit, Standard Draize, 20 mg severe; investigated as a tumorigen, mutagen, reproductive effector. 12. Ecological Information Environmental Fate: When released into the soil, this material is expected to readily biodegrade. When released into the soil, this material is expected to leach into groundwater. When released into the soil, this material is expected to quickly evaporate. When released into water, this material is expected to readily biodegrade. When released to water, this material is expected to quickly evaporate. This material has a log octanol-water partition coefficient of less than 3.0. This material is not expected to significantly bioaccumulate. When released into the air, this material may be moderately degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material may be moderately degraded by photolysis. When released into the air, this material is expected to be readily removed from the atmosphere by wet deposition.

Environmental Toxicity: This material is not expected to be toxic to aquatic life. The LC50/96-hour values for fish are over 100 mg/l. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: ACETONE Hazard Class: 3 UN/NA: UN1090 Packing Group: II International (Water, I.M.O.) Proper Shipping Name: ACETONE Hazard Class: 3.1 UN/NA: UN1090 Packing Group: II 15. Regulatory Information

16. Other Information NFPA Ratings: Health: 1 Flammability: 3 Reactivity: 0 Label Hazard Warning: DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL NERVOUS SYSTEM. Label Precautions: Keep away from heat, sparks and flame. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid breathing vapor. Avoid contact with eyes, skin and clothing. Label First Aid: Aspiration hazard. If swallowed, vomiting may occur spontaneously, but DO NOT

INDUCE. If vomiting occurs, keep head below hips to prevent aspiration into lungs. Never give anything by mouth to an unconscious person. Call a physician immediately. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ACETONITRILE
1. Product Identification Synonyms: Methyl Cyanide; Cyanomethane; Ethanenitrile; Ethyl nitrile CAS No.: 75-05-8 Molecular Weight: 41.05 Chemical Formula: CH3 CN Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Acetonitrile Acrylonitrile 3. Hazards Identification Emergency Overview DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. AFFECTS CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEYS. FLAMMABLE LIQUID AND VAPOR. MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Health Rating: 3 - Severe (Life) Flammability Rating: 4 - Extreme (Flammable) Reactivity Rating: 1 - Slight Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER. Storage Color Code: Red (Flammable) Potential Health Effects In most cases, cyanide poisoning causes a deceptively healthy pink to red skin color. However, if a physical injury or lack of oxygen is involved, the skin color may be bluish. Reddening of the eyes and pupil dilation are symptoms of cyanide poisoning. Cyanosis (blue discoloration of the skin) tends to be associated with severe cyanide poisonings. Inhalation: Effects of overexposure are often delayed, possibly due to the slow formation of cyanide anions in the body. These cyanide anions prevent the body from using oxygen and can lead to internal asphyxiation. Early symptoms may include nose and throat irritation, flushing of the face, and chest tightness. Higher concentrations may produce headache, nausea, vomiting, respiratory depression, weakness, blood changes, thyroid changes, irregular heart beat, abdominal pain, convulsions, shock, unconsciousness and death, depending on concentration and time of exposure. This highly toxic material has 75-05-8 107-13-1

Percent 99.8 - 10 < 0.001%

Hazardous Yes No

insufficient warning properties to prevent personnel from working in contaminated atmospheres. Ingestion: Gastric irritation may occur. Other symptoms parallel those from inhalation exposure. Skin Contact: May cause irritation. May be absorbed through skin with health effects to parallel those of inhalation. Eye Contact: Splashes may cause eye irritation with redness and pain. Chronic Exposure: Long term exposures may affect liver, kidneys, and central nervous system. Aggravation of Pre-existing Conditions: Workers using cyanide should have preplacement and periodic medical exams. Those with history of central nervous system, heart or lung diseases, or liver, kidney, or thyroid problems may be more susceptible to the effects of this substance. 4. First Aid Measures FOLLOWING ANY ROUTE OF EXPOSURE GET MEDICAL ATTENTION IMMEDIATELY. SERIOUS TOXICITY IS PRECEDED BY VOMITING IN MOST CASES OF ORAL INGESTION. Although used in pre-hospital management of cyanide poisoning, amyl nitrite inhalants have not been shown to be beneficial in managing acetonitrile poisoning. Inhalation: If inhaled, remove to fresh air. If breathing is labored or with coughing, give 100% supplemental oxygen. If not breathing, begin artificial respiration. DO NOT GIVE MOUTH-TO-MOUTH RESUSCITATION. Ingestion: If swallowed, get medical attention immediately; do not induce vomiting. Never give anything by mouth to an unconscious person. If not breathing, begin artificial respiration. DO NOT GIVE MOUTH-TO-MOUTH RESUSCITATION. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Note to Physician: Any patient with ingestion or other significant exposure to acetonitrile should be observed in the intensive care unit for 24 hours. In-Hospital Management: Consider gastric lavage if patient is presented soon after ingestion. Administer charcoal slurry with or without saline cathartic or sorbitol. Immediately begin therapy with 100% oxygen. Observe for respiratory depression, seizures, hypotension or pulmonary edema. Acetonitrile metabolizes into cyanide over 2 to 8 hours, so symptoms or signs of toxicity may be delayed after significant exposures. Consider cyanide antidote as clinically indicated, such as sodium thiosulfate and sodium nitrate. Monitor cyanide levels, arterial blood gases, and acid-base balance.

5. Fire Fighting Measures Fire: Flash point: 2C (36F) CC Autoignition temperature: 524C (975F) Flammable limits in air % by volume: lel: 4.4; uel: 16.0 Flammable Liquid and Vapor! Contact with strong oxidizers may cause fire. Explosion: Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Vapors can flow along surfaces to distant ignition source and flash back. Sealed containers may rupture when heated. Sensitive to static discharge. Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. If a leak or spill has not ignited, use water spray to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures. May emit toxic and flammable fumes of cyanide if involved in a fire. 6. Accidental Release Measures Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Use nonsparking tools and equipment. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures. Spills can be reacted in an alkaline hypochlorite solution to produce cyanate and then neutralized. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tools and equipment, including explosion proof ventilation. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. Do Not attempt to clean empty containers since residue is difficult to remove. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, sparks, flame, static electricity or other sources of ignition: they may explode and cause injury or death.

8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL):40 ppm (TWA) -ACGIH Threshold Limit Value (TLV):40 ppm (TWA), 60 ppm (STEL) Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus. This substance has poor warning properties. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Clear, colorless liquid. Odor: Ether odor. Solubility: Miscible in water. Specific Gravity: 0.79 @ 15C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 100 Boiling Point: 81.6C (180F) Melting Point: -46C (-51F) Vapor Density (Air=1): 1.4 Vapor Pressure (mm Hg): 73 @ 20C (68F) Evaporation Rate (BuAc=1): 5.79 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Burning may produce fumes of cyanide, carbon monoxide, carbon dioxide, nitrogen oxides and sulfur oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Incompatible with oxidizing materials, sulfuric acid, oleum, chlorosulfonic acid, n-fluoro compounds, nitrating agents and perchlorates. Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

11. Toxicological Information Oral rat LD50: 2460 mg/kg; skin rabbit LD50: 1250 uL/kg; inhalation rat LC50: 7551 ppm/8H. Investigated as a tumorigen, mutagen, reproductive effector. 12. Ecological Information Environmental Fate: When released into the soil, this material may biodegrade to a moderate extent. When released into the soil, this material is expected to leach into groundwater. When released into the soil, this material may evaporate to a moderate extent. When released into water, this material may biodegrade to a moderate extent. When released into water, this material may evaporate to a moderate extent. This material has an estimated bioconcentration factor (BCF) of less than 100. This material is not expected to significantly bioaccumulate. When released into the air, this material is not expected to react with photochemically produced hydroxyl radicals. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material is expected to have a half-life of greater than 30 days. Environmental Toxicity: This material is not expected to be toxic to aquatic life. The LC50/96-hour values for fish are over 100 mg/l. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: ACETONITRILE Hazard Class: 3 UN/NA: UN1648 Packing Group: II International (Water, I.M.O.) Proper Shipping Name: ACETONITRILE Hazard Class: 3.2 UN/NA: UN1648 Packing Group: II

15. Other Information NFPA Ratings: Health: 2 Flammability: 3 Reactivity: 0 Label Hazard Warning: DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. AFFECTS CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEYS. FLAMMABLE LIQUID AND VAPOR. MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Label Precautions: Do not breathe vapor or mist. Do not get in eyes, on skin, or on clothing. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep away from heat, sparks and flame. Label First Aid: IN ALL CASES, CALL A PHYSICIAN IMMEDIATELY. DO NOT GIVE MOUTHTO-MOUTH RESUSCITATION Emergency response personnel must take precautions to avoid contact with this substance. If inhaled, remove to fresh air. Monitor for respiratory distress. If not breathing give artificial respiration. If cough or difficulty in breathing develops, administer 100% supplemental oxygen, as required. If swallowed, get medical attention immediately; do not induce vomiting. Never give anything by mouth to an unconscious person. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ACETYL CHLORIDE 1. Product Identification Synonyms: Acetic acid, chloride; Ethanoyl chloride; Acetic chloride CAS No.: 75-36-5 Molecular Weight: 78.50 Chemical Formula: CH3COCl Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Acetyl Chloride 75-36-5

Percent Hazardous 90 - 100% Yes

3. Hazards Identification Emergency Overview DANGER! CORROSIVE. CAUSES SEVERE BURNS TO EVERY AREA OF CONTACT. MAY BE FATAL IF SWALLOWED OR INHALED. FLAMMABLE LIQUID AND VAPOR. WATER REACTIVE. VAPORS CAUSE SEVERE IRRITATION TO EYES AND RESPIRATORY TRACT. Potential Health Effects Inhalation: Corrosive. Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. Inhalation may be fatal as a result of spasm inflammation and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Ingestion: Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach, leading to death. Can cause sore throat, vomiting, diarrhea. Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn can occur. Eye Contact: Corrosive! Vapors are irritating and may cause damage to the eyes. Contact may cause severe burns and permanent eye damage. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.

Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Flash point: 4C (39F) CC Autoignition temperature: 390C (734F) Flammable limits in air % by volume: lel: 5 Flammable. Explosion: Above the flash point, explosive vapor-air mixtures may be formed. Vapors can flow along surfaces to distant ignition source and flash back. Sensitive to static discharge. Fire Extinguishing Media: Carbon dioxide or dry chemical. Do not use water or foam. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Combustion by-products include phosgene and hydrogen chloride gases. Structural firefighter's protective clothing is ineffective for fires involving this material. Stay away from sealed containers. 6. Accidental Release Measures DANGER! FLAMMABLE. Reacts violently with water to release hydrogen chloride. Ventilate area of leak or spill. Keep water away from spilled material. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Cover liquid with powder from fire extinguisher and sodium bicarbonate, soda ash or slaked lime. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Use non-sparking tools and equipment. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tools and equipment, including explosion proof ventilation. Protect from moisture. Storage containers preferably to be of glass or Teflon. Containers of this material may be

hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-facepiece positive-pressure, airsupplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Colorless or slightly yellow fuming liquid. Odor: Strong pungent odor. Solubility: Decomposes violently in water. Specific Gravity: 1.11 @ 20C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 100 Boiling Point: 52C (126F) Melting Point: -112C (-170F) Vapor Density (Air=1): 2.7 Vapor Pressure (mm Hg): 740 @ 50C (122F) Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable in sealed containers at 25C (77F). Volatile. Will fume when exposed to moist air. Readily hydrolyzes to form HCL and acetic acid. Hazardous Decomposition Products: May produce carbon monoxide, carbon dioxide, hydrogen chloride and phosgene when heated to decomposition. Hazardous Polymerization: This substance does not polymerize.

Incompatibilities: Water, ethyl alcohol, dimethyl sulfoxide, amines, and alkalis. Readily hydrolyzes in moist air to form hydrogen chloride and acetic acid. Conditions to Avoid: Heat, flames, ignition sources and incompatibles. 11. Toxicological Information Oral rat LD50: 910 mg/kg. 12. Ecological Information Environmental Fate: Because its high reactivity, this material is not expected to persist if released to soil, water or air. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: ACETYL CHLORIDE Hazard Class: 3, 8 UN/NA: UN1717 Packing Group: II International (Water, I.M.O.) Proper Shipping Name: ACETYL CHLORIDE Hazard Class: 3.2, 8 UN/NA: UN1717 Packing Group: II 15. Regulatory Information Australian Hazchem Code: 4WE Poison Schedule: No information found.

16. Other Information NFPA Ratings: Health: 3 Flammability: 3 Reactivity: 2 Other: Water reactive Label Hazard Warning: DANGER! CORROSIVE. CAUSES SEVERE BURNS TO EVERY AREA OF CONTACT. MAY BE FATAL IF SWALLOWED OR INHALED. FLAMMABLE LIQUID AND VAPOR. WATER REACTIVE. VAPORS CAUSE SEVERE IRRITATION TO EYES AND RESPIRATORY TRACT. Label Precautions: Do not get in eyes, on skin, or on clothing. Do not breathe vapor. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep away from heat, sparks and flame. Do not contact with water. Label First Aid: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases get medical attention immediately. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ACRYLAMIDE
1. Product Identification Synonyms: 2-Propenamide; ethylene carboxamide; acrylic amide; vinyl amide CAS No.: 79-06-1 Molecular Weight: 71.09 Chemical Formula: CH2CHCONH2 Product Codes:

2. Composition/Information on Ingredients Ingredient CAS No Acrylamide 79-06-1 3. Hazards Identification

Percent 100%

Hazardous Yes

Emergency Overview WARNING! HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. AFFECTS CENTRAL AND PERIPHERAL NERVOUS SYSTEMS AND REPRODUCTIVE SYSTEM. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. SUSPECT CANCER HAZARD. MAY CAUSE CANCER. Risk of cancer depends on level and duration of exposure. POSSIBLE BIRTH DEFECT HAZARD. MAY CAUSE BIRTH DEFECTS BASED ON ANIMAL DATA. THERMALLY UNSTABLE. MAY POLYMERIZE EXPLOSIVELY IF HEATED TO THE MELTING POINT. Health Rating: 3 - Severe (Cancer Causing) Flammability Rating: 1 - Slight Reactivity Rating: 3 - Severe (Explosive) Contact Rating: 3 - Severe (Life) Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Yellow Stripe (Store Separately) Potential Health Effects Acrylamide is a suspected human carcinogen, severe neurotoxin, and causes irritation of the eyes, skin (is readily absorbed), and respiratory tract. Inhalation: May cause drowsiness, tingling sensations, fatigue, weakness, stumbling, slurred speech, and shaking. May cause central and peripheral nervous system damage. Severe intoxications may cause permanent nerve damage. Causes irritation to the respiratory tract. May affect reproductive system and act as a teratogen. Ingestion: Toxic! May cause systemic poisoning with symptoms paralleling those of inhalation. Skin Contact: May cause irritation and redness. Can be absorbed through the skin causing systemic poisoning; symptoms may parallel inhalation.

Eye Contact: Solutions may cause irritation. Chronic Exposure: Prolonged or repeated exposure through any route may cause muscular weakness, incoordination, skin rashes, excessive sweating of hands and feet, cold hands, peeling of the skin, numbness, abnormal skin or muscle sensations, fatigue, and cause central and peripheral nervous system damage. Suspect cancer hazard. May cause cancer. May affect the reproductive system and act as a teratogen. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders, eye problems or central or peripheral nervous system conditions may be more susceptible to the effects of this substance. 4. First Aid Measures Because of the toxic and highly absorptive nature of acrylamide, quickly providing first aid helps to minimize health effects. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician. Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Flash point: 138C (280F) CC Autoignition temperature: 240C (464F) Combustible solid. Explosion: Not considered an explosive hazard, but an explosion may occur upon polymerization. Polymerization may be caused by exposure to heat, U.V. light, oxidizers, or peroxides. Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free

number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Keep in a tightly closed container. Store in a cool, dry, ventilated area away from sources of heat or ignition. Protect against physical damage. Store separately from reactive or combustible materials, and out of direct sunlight. Isolate from oxidizing materials and peroxides. Store away from acids and alkalies. Wear special protective equipment (Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels. Wash hands, face, forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink, or smoke in workplace. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: Acrylamide: -OSHA Permissible Exposure Limit (PEL):0.3 mg/m3 (TWA) (skin) -ACGIH Threshold Limit Value (TLV):0.03 mg/m3 (TWA) (skin) Listed as A3, animal carcinogen Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face respirator with an organic vapor cartridge and high efficiency dust/mist filter may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece respirator with an organic vapor cartridge and high efficiency dust/mist filter may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygendeficient atmospheres. This compound possibly exists in both particulate and vapor phase. A gas/vapor cartridge should be used in addition to the particulate filter. If the vapor concentration alone exceeds the exposure limits, use a supplied air respirator, because warning properties are unknown for these compounds. Skin Protection: Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities

in work area. Other Control Measures: Comments: Stress good personal cleanliness and housekeeping to prevent skin contact. Wear clean work clothing daily. Do not home launder. If clothes become contaminated, remove at once, wash the skin with soap and water and launder clothing before reuse. Destroy contaminated leather goods. 9. Physical and Chemical Properties Appearance: Colorless crystals. Odor: Odorless. Solubility: 216 g/l00 g water @ 30C (86F) Specific Gravity: 1.1222 @ 30C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: 125C (257F) Melting Point: 84.5C (183F) Vapor Density (Air=1): 2.4 @ 175C Vapor Pressure (mm Hg): 0.007 @ 20C (68F) Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: May polymerize explosively. Thermally unstable. Polymerization may be caused by exposure to heat, U.V. light, oxidizers, or peroxides. May be stabilized with hydroquinone, t-butylpyrocatechol, N-phenyl-2-naphthylamine, or other antioxidants. Hazardous Decomposition Products: Burning may produce ammonia, carbon monoxide, carbon dioxide, nitrogen oxides. Hydrogen gas. Hazardous Polymerization: Acrylamide readily polymerizes on exposure to heat, U.V. light, oxidizers, or peroxides. Incompatibilities: Acids, oxidizing agents, and bases. Spontaneously reacts with hydroxyl-, amino-, and sulfhydryl- containing compounds. Conditions to Avoid: Heat, shock, UV light, ignition sources, and incompatibles.

11. Toxicological Information

For Acrylamide: oral rat LD50: 124 mg/kg; skin rabbit LD50: 1680 uL/kg; investigated as a tumorigen, mutagen, reproductive effector.

---NTP Carcinogen--Ingredient Acrylamide (79-06-1)

Known No

Anticipated Yes

IARC Category 2A

12. Ecological Information Environmental Fate: When released into the soil, this material is expected to leach into groundwater. When released into the soil, this material may biodegrade to a moderate extent. This material is not expected to significantly bioaccumulate. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. Environmental Toxicity: This material is not expected to be toxic to aquatic life. The LC50/96-hour values for fish are over 100 mg/l. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: ACRYLAMIDE Hazard Class: 6.1 UN/NA: UN2074 Packing Group: III International (Water, I.M.O.) Proper Shipping Name: ACRYLAMIDE, SOLID Hazard Class: 6.1 UN/NA: UN2074 Packing Group: III International (Air, I.C.A.O.) Proper Shipping Name: ACRYLAMIDE Hazard Class: 6.1 UN/NA: UN2074 Packing Group: III

15. Other Information NFPA Ratings: Health: 2 Flammability: 2 Reactivity: 2 Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH

SKIN. AFFECTS CENTRAL AND PERIPHERAL NERVOUS SYSTEMS AND REPRODUCTIVE SYSTEM. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. SUSPECT CANCER HAZARD. MAY CAUSE CANCER. Risk of cancer depends on level and duration of exposure. POSSIBLE BIRTH DEFECT HAZARD. MAY CAUSE BIRTH DEFECTS BASED ON ANIMAL DATA. THERMALLY UNSTABLE. MAY POLYMERIZE EXPLOSIVELY IF HEATED TO THE MELTING POINT. Label Precautions: Do not breathe dust.Do not get in eyes, on skin, or on clothing. Keep container closed.Use only with adequate ventilation. Wash thoroughly after handling.Keep away from heat, sparks and flame. Protect from U.V. light, oxidizers and peroxides. Label First Aid: If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ADIPIC ACID 1. Product Identification Synonyms: Hexanedioic acid; 1, 4-butanedicarboxylic acid. CAS No.: 124-04-9 Molecular Weight: 146.14 Chemical Formula: C6H10O4 Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Adipic Acid 124-04-9 3. Hazards Identification Emergency Overview CAUTION! CAUSES MODERATE EYE IRRITATION. MAY CAUSE IRRITATION TO SKIN AND RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED OR INHALED. MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR. Potential Health Effects Inhalation: Inhalation of dust may irritate the respiratory tract. May cause coughing and sneezing. Ingestion: Based on animal data, this material is presumed to be only slightly toxic. Skin Contact: May irritate the skin. Prolonged or repeated skin contact may cause dermatitis. Eye Contact: Causes moderate eye irritation with redness and pain. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician immediately. Skin Contact: Remove any contaminated clothing. Wash skin with soap or mild detergent and water for at least 15 minutes. Get medical attention if irritation develops or persists. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Percent 100%

Hazardous Yes

5. Fire Fighting Measures Fire: Flash point: 196C (385F) CC Autoignition temperature: 420C (788F) Slight fire hazard when exposed to heat or flame. Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Minimum explosible concentration in air (dust): 10-15 mg/L. Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion due to electrostatic discharge. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: - ACGIH Threshold Limit Value (TLV): 5 mg/m3 (TWA) Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by

the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Rubber gloves and lab coat, apron or coveralls. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: White crystals. Odor: Odorless. Solubility: Slightly soluble in water. Density: 1.36 pH: 3.2 (0.1% aq. soln.) @ 25C % Volatiles by volume @ 21C (70F): 0 Boiling Point: 337C (639F) @ 760 mm Hg (Decomposes) Melting Point: 152C (306F) Vapor Density (Air=1): 5.04 Vapor Pressure (mm Hg): 1 @ 159.5C (320F) Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Can react with oxidizing materials. Conditions to Avoid: Air, heat, and dusting conditions. 11. Toxicological Information Oral rat LD50: >11g/kg. Irritation eye rabbit: 20 mg/24H moderate. Investigated as a mutagen. ---NTP Carcinogen--Anticipated IARC Category No None

Ingredient Adipic Acid (124-04-9)

Known No

12. Ecological Information Environmental Fate: When released into the soil, this material may biodegrade to a moderate extent. When released into the soil, this material is not expected to evaporate significantly. When released into water, this material is expected to readily biodegrade. When released into the water, this material is expected to have a half-life between 1 and 10 days. This material has a log octanol-water partition coefficient of less than 3.0. This material is not expected to significantly bioaccumulate. When released into water, this material is not expected to evaporate significantly. When released into the air, this material may be moderately degraded by reaction with photochemically produced hydroxyl radicals. Environmental Toxicity: This material is expected to be slightly toxic to aquatic life. The LC50/96-hour values for fish are between 10 and 100 mg/l. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated.

15. Other Information NFPA Ratings: Health: 1 Flammability: 1 Reactivity: 0 Label Hazard Warning: CAUTION! CAUSES MODERATE EYE IRRITATION. MAY CAUSE IRRITATION TO SKIN AND RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED OR INHALED. MAY FORM COMBUSTIBLE DUST CONCENTRATIONS IN AIR. Label Precautions: Avoid breathing dust. Avoid contact with eyes, skin and clothing. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. Avoid dust cloud in presence of an ignition source. Label First Aid: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes. Call a physician if irritation develops or persists. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. If large amounts were swallowed, call a physician immediately. Product Use: Laboratory Reagent.

DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AGAR AGAR
1. Product Identification Synonyms: Polysaccharide Complex CAS No.: 9002-18-0 Molecular Weight: Not applicable. Chemical Formula: Not applicable. Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Agar 9002-18-0 3. Hazards Identification Emergency Overview As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the chemical substance and ensure prompt removal from skin, eyes and clothing. Health Rating: 0 - None Flammability Rating: 1 - Slight Reactivity Rating: 0 - None Contact Rating: 0 - None Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: No adverse health effects via inhalation. Ingestion: Not expected to be a health hazard via ingestion. Skin Contact: Not expected to be a health hazard from skin exposure. Eye Contact: Not expected to be a health hazard. Chronic Exposure: No adverse health effects expected. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Not expected to require first aid measures. Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: Not expected to require first aid measures. If large amounts were swallowed, give water to drink and get medical advice. Skin Contact: Not expected to require first aid measures. Wash exposed area with soap and water. Get medical advice if irritation develops. Eye Contact: Not expected to require first aid measures. Wash thoroughly with running water. Get medical advice if irritation develops.

Percent Hazardous 90 - 100% No

5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: Not expected to require any special ventilation. Personal Respirators (NIOSH Approved): Not expected to require personal respirator usage. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quickdrench facilities in work area. 9. Physical and Chemical Properties Appearance: Transparent strips, or thin translucent membranous pieces, or white to pale buff fine or coarse powder. Odor: Odorless. Solubility: Negligible (< 0.1%) Specific Gravity: No information found. pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: No information found. Melting Point: No information found. Vapor Density (Air=1): Not applicable. Vapor Pressure (mm Hg): Not applicable. Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Strong oxidizers. Conditions to Avoid: Moisture and incompatibles. 11. Toxicological Information Agar: 11 gm/kg rat oral LD50. Investigated as a tumorigen. Ingredient Agar (9002-18-0) 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Other Information NFPA Ratings: Health: 0 Flammability: 0 Reactivity: 0 Label Hazard Warning: As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the chemical substance and ensure prompt removal from skin, eyes and clothing. Label Precautions: None. Label First Aid: Not applicable. Product Use: Laboratory Reagent. Known No ---NTP Carcinogen--Anticipated IARC Category No None

DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

Albumin, Egg, Powder

1. Product Identification Synonyms: Ovalbumin CAS No.: 9006-50-2 Molecular Weight: Not applicable. Chemical Formula: Not applicable. Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Albumin, Egg, Powder 9006-50-2

Percent 90 - 100%

Hazardous No

3. Hazards Identification Emergency Overview As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the chemical substance and ensure prompt removal from skin, eyes and clothing. Health Rating: 0 - None Flammability Rating: 1 - Slight Reactivity Rating: 0 - None Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: No adverse health effects expected from inhalation. Ingestion: Not expected to be a health hazard via ingestion. Skin Contact: Not expected to be a health hazard from skin exposure. Eye Contact: Not expected to be a health hazard. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Not expected to require first aid measures. Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: Not expected to require first aid measures. If large amounts were swallowed, give water to drink and get medical advice. Skin Contact: Not expected to require first aid measures. Wash exposed area with soap and water. Get medical advice if irritation develops.

Eye Contact: Not expected to require first aid measures. Wash thoroughly with running water. Get medical advice if irritation develops. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: Not expected to require any special ventilation. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, airsupplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Light yellow Powder. Odor: No information found. Solubility: Appreciable (> 10%) Specific Gravity: No information found.

pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: No information found. Melting Point: No information found. Vapor Density (Air=1): Not applicable. Vapor Pressure (mm Hg): Not applicable. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: No information found. Conditions to Avoid: Heat. 11. Toxicological Information Oral rat LD50: 101 gm/kg. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated.

15. Other Information NFPA Ratings: Health: 0 Flammability: 0 Reactivity: 0 Label Hazard Warning: As part of good industrial and personal hygiene and safety procedure, avoid all unnecessary exposure to the chemical substance and ensure prompt removal from skin, eyes and clothing. Label Precautions: None. Label First Aid: Not applicable. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ALUMINUM AMMONIUM SULFATE

1. Product Identification Synonyms: Aluminum ammonium disulfate dodecahydrate;Aluminum ammonium disulfate, 12-hydrate; Ammonium alum; sulfuric acid aluminum ammonium salt (2:1:1), dodecahydrate CAS No.: 7784-25-0 (Anhydrous) Molecular Weight: 453.32 Chemical Formula: AlNH4(SO4)2 . 12H2O Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Sulfuric Acid, Aluminum Ammonium Salt 7784-25-0 (2:1:1) 3. Hazards Identification Emergency Overview WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 0 - None Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects This material hydrolyzes in water to form sulfuric acid, which is responsible for the irritating effects given below. Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Ingestion: Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. There have been two cases of fatal human poisonings from ingestion of 30 grams of alum. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found.

Percent 98 - 100%

Hazardous Yes

4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. May release flammable ammonia if involved in a fire. Explosion: Not considered to be an explosion hazard. Sealed containers may rupture when heated. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Keep in mind that addition of water can cause the formation of sulfuric acid. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Cover spill with sodium bicarbonate or soda ash and mix. Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.

7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL):2 mg/m3 (TWA) soluble salts as Al -ACGIH Threshold Limit Value (TLV):2 mg/m3 (TWA) soluble salts as Al

Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Colorless crystals. Odor: Odorless. Solubility: 14% in water, 200% in boiling water Density: 1.65 pH: 4.6 (0.05M solution) % Volatiles by volume @ 21C (70F): 0 Boiling Point: 280C (536F) Decomposes. Melting Point: 94.5C (201F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Toxic oxides of nitrogen, sulfur dioxide, ammonia, and sulfur trioxide may form at elevated temperatures. Hydrolyzes to form sulfuric acid. Hazardous Polymerization: Will not occur. Incompatibilities: Contact with alkalis may release ammonia gas. Corrosive to metals in the presence of water. Conditions to Avoid: Moisture and incompatibles.

11. Toxicological Information No LD50/LC50 information found relating to normal routes of occupational exposure. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Label Precautions: Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Label First Aid: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention. Product Use: Laboratory Reagent.

DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ALUMINUM CHLORIDE
1. Product Identification Synonyms: Aluminum trichloride hexahydrate; aluminum(III) chloride hexahydrate CAS No.: 7446-70-0 (Anhydrous) Molecular Weight: 241.43 Chemical Formula: Al Cl3.6H2O Product Codes: 2. Composition/Information on Ingredients Ingredient Aluminum Chloride 3. Hazards Identification Emergency Overview CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: May cause irritation to the respiratory tract. Symptoms may include coughing and shortness of breath. Ingestion: Low single dose toxicity. Ingestion of large amounts may cause nausea, vomiting and abdominal spasms. Skin Contact: May cause irritation. Eye Contact: May cause irritation, redness and pain. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of the substance. 4. First Aid Measures Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice. Skin Contact: Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if irritation develops or persists. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Water, carbon dioxide, or dry chemical. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved selfCAS No 7446-70-0 Percent 100% Hazardous Yes

contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. 7. Handling and Storage Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -ACGIH Threshold Limit Value (TLV):2 mg/m3 (TWA) soluble salts as Al Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: White crystalline powder. Odor: Odorless. Solubility: Soluble in water and alcohol. Density: 2.4 pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: Not applicable. Melting Point: 100C (212F) Decomposes. Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: May emit toxic chloride fumes when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Water, moist air. Conditions to Avoid: Moisture. 11. Toxicological Information Oral rat LD50: 3311 mg/Kg. Oral mouse LD50: 770 mg/kg. Irritation data: Skin human 7500 ug/3D-I mild. Investigated as a mutagen and reproductive effector.

12. Ecological Information

Environmental Fate: Aluminum chloride hydrolyzes in water to aluminum hydroxide and hydrochloric acid. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Label Hazard Warning: CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Label Precautions: Avoid breathing dust. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. Product Use: Laboratory Reagent. DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ALUMINUM NITRATE
1. Product Identification Synonyms: Aluminum (III) nitrate, nonohydrate (l:3:9); Nitric acid, aluminum salt; Aluminum nitrate, nonahydrate CAS No.: 13473-90-0 Molecular Weight: 375. Chemical Formula: Al(NO3)3 9H2O Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Aluminum Nitrate 13473-90-0 3. Hazards Identification Emergency Overview DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Health Rating: 2 - Moderate Flammability Rating: 0 - None Reactivity Rating: 3 - Severe (Oxidizer) Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Yellow (Reactive) Potential Health Effects Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Ingestion: May cause gastroenteritis and abdominal pains. Purging and diuresis can be expected. Rare cases of nitrates being converted to the more toxic nitrites have been reported, mostly with infants. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: Small repeated oral doses of nitrates may cause weakness, depression, headache, and mental impairment. Aggravation of Pre-existing Conditions: Persons with stomach diseases and infants are much more sensitive to nitrate ion toxicity. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Percent Hazardous 98 - 100% Yes

Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. 5. Fire Fighting Measures Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. When heated, gives off oxygen thus increasing fire hazard. Explosion: Contact with oxidizable substances may cause extremely violent combustion. Some nitrates may explode when shocked, exposed to heat or flame, or by spontaneous chemical reaction. Fire Extinguishing Media: Use water or water spray only. Water spray may be used to keep fire exposed containers cool. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. This oxidizing material can increase the flammability of adjacent combustible materials. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Cover spill with sodium bicarbonate or soda ash and mix. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Separate from incompatibilities. Separate from combustible, organic, or any other readily oxidizable materials. Do not store on wooden floors. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL):2 mg/m3 (TWA) soluble salts as Al -ACGIH Threshold Limit Value (TLV):2 mg/m3 (TWA) soluble salts as Al Ventilation System:

A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: White crystals. Odor: Odorless. Solubility: Very soluble. Specific Gravity: No information found. pH: Aqueous solution is acidic. % Volatiles by volume @ 21C (70F): 0 Boiling Point: 135C (275F) Decomposes. Melting Point: 73C (163F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Oxides of nitrogen. Hazardous Polymerization: Will not occur. Incompatibilities: Reducing agents, organic materials, cyanides, thiocyanides, acids, and heavy metals. Conditions to Avoid: Heat, shock, friction, incompatibles.

11. Toxicological Information (9-hydrate): Oral rat LD50: 3671 mg/kg; Investigated as a reproductive effector. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: ALUMINUM NITRATE Hazard Class: 5.1 UN/NA: UN1438 Packing Group: III International (Water, I.M.O.) Proper Shipping Name: ALUMINUM NITRATE Hazard Class: 5.1 UN/NA: UN1438 Packing Group: III

15. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Other: Oxidizer Label Hazard Warning: DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Label Precautions: Keep from contact with clothing and other combustible materials. Store in a tightly closed container. Use only with adequate ventilation. Avoid breathing dust. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.

Label First Aid: If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ALUMINUM OXIDE
1. Product Identification Synonyms: AluminAR(R) CC-10; Aluminum oxide; Alumina; activated Alumina; alphaAlumina CAS No.: 1344-28-1 Molecular Weight: 101.96 Chemical Formula: Al2O3 (contains about 11-12% bound water) Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Aluminum Oxide 1344-28-1 3. Hazards Identification Emergency Overview CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 0 - None Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: Hazard is principally that of a nuisance dust. Coughing or shortness of breath may occur in cases of excessive inhalation. Ingestion: No adverse effects expected. Skin Contact: May cause irritation with redness and pain. Eye Contact: No adverse effects expected but dust may cause mechanical irritation. Chronic Exposure: No adverse effects expected. Aggravation of Pre-existing Conditions: Not expected to be a health hazard. 4. First Aid Measures Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.

Percent 90 - 100%

Hazardous Yes

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire and to protect against the aluminum oxide dust that may be dispersed in the air. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: Alumina (Aluminum Oxide): -OSHA Permissible Exposure Limit (PEL):alpha alumina, 15 mg/m3 total dust, 5 mg/m3 respirable fraction -ACGIH Threshold Limit Value (TLV):aluminum oxide, 10 mg/m3 (TWA) inhalable (total) particulate matter containing no asbestos and < 1% crystalline silica, A4 Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the

maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quickdrench facilities in work area. 9. Physical and Chemical Properties Appearance: White powder. Odor: Odorless. Solubility: Insoluble in water. Density: 4.0 @ 20C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: 2980C (5396F) Melting Point: ca. 2000C (ca. 3632F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: No information found. Hazardous Polymerization: Will not occur. Incompatibilities: Chlorine trifluoride, Ethylene oxide. Conditions to Avoid: Incompatibles. 11. Toxicological Information No LD50/LC50 information found relating to normal routes of occupational exposure. Investigated as a tumorigen. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found.

13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information 16. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Label Hazard Warning: CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Label Precautions: Use with adequate ventilation. Keep container closed. Avoid breathing dust. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Label First Aid: If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ALUMINUM POTASSIUM SULFATE

1. Product Identification Synonyms: Sulfuric acid, aluminum potassium salt (2:1:1), dodecahydrate; potassium alum dodecahydrate; Alum Potassium USP Powder TAC; Potassium alum; Potash alum; Alum; Kalinite CAS No.: 10043-67-1 (Anhydrous) Molecular Weight: 474.38 Chemical Formula: AlK(SO4)2 12H2O Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Sulfuric Acid, Aluminum Potassium Salt 10043-67-1 (2:1:1) 3. Hazards Identification Emergency Overview WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 0 - None Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects This material hydrolyzes in water to form sulfuric acid, which is responsible for the irritating effects given below. Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Ingestion: Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. There have been two cases of fatal human poisonings from ingestion of 30 grams of alum. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found.

Percent 98 - 100%

Hazardous Yes

4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Keep in mind that addition of water can cause the formation of sulfuric acid. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Cover spill with sodium bicarbonate or soda ash and mix. Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL):2 mg/m3 (TWA) soluble salts as Al -ACGIH Threshold Limit Value (TLV):2 mg/m3 (TWA) soluble salts as Al Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred

because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Colorless crystals. Odor: Odorless. Solubility: 14% in water, 333% in boiling water Density: 1.73 pH: 3.3 (0.2 M solution) % Volatiles by volume @ 21C (70F): 0 Boiling Point: ca. 200C (ca. 392F) Loses water Melting Point: 92.5C (198F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Hydrolyzes to form dilute sulfuric acid. Toxic and corrosive oxides of sulfur may be formed when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Corrosive to metals in the presence of water. Conditions to Avoid: Moisture and incompatibles.

11. Toxicological Information Investigated as a reproductive effector. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information 16. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Label Precautions: Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Label First Aid: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention. Product Use: Laboratory Reagent.

DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ALUMINIUM SULFATE
1. Product Identification Synonyms: Sulfuric acid, aluminum salt (3:2), octadeca hydrate; Cake alum; Patent alum CAS No.: 10043-01-3 (Anhydrous) 7784-31-8 (Octadecahydrate) Molecular Weight: 666.44 Chemical Formula: Al2(SO4)3.18H2O Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Aluminum Sulfate 10043-01-3 3. Hazards Identification Emergency Overview WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 0 - None Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects This material hydrolyzes in water to form sulfuric acid, which is responsible for the irritating effects given below. Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Ingestion: Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. There have been two cases of fatal human poisonings from ingestion of 30 grams of alum. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Percent 98 - 100%

Hazardous Yes

Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Keep in mind that addition of water can cause the formation of sulfuric acid. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. Cover spill with sodium bicarbonate or soda ash and mix. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Aluminum sulfate absorbs moisture and becomes a safety hazard when spilled because it absorbs moisture and becomes slippery. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL):2 mg/m3 (TWA) soluble salts as Al -ACGIH Threshold Limit Value (TLV):2 mg/m3 (TWA) soluble salts as Al

Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Colorless crystals. Odor: Odorless. Solubility: 87 g/100 cc water @ 0C (32F). Specific Gravity: 1.69 @ 17C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: No information found. Melting Point: 87C (189F) Decomposes. Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Hydrolyzes to form dilute sulfuric acid. Toxic and corrosive oxides of sulfur may be formed when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Corrosive to metals in the presence of water. Conditions to Avoid: Moisture and incompatibles.

11. Toxicological Information Anhydrous Material: Oral mouse LD50: 6207 mg/kg; investigated as a mutagen and reproductive effector. 18-Hydrate: Oral mouse LD50: > 9 gm/kg; investigated as a mutagen. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information 16. Other Information NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0 Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Label Precautions: Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid contact with eyes, skin and clothing. Label First Aid: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention.

Product Use: Laboratory Reagent.

DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

Ammonia Solution, Strong

1. Product Identification Synonyms: Ammonia Aqueous; Aqua Ammonia; Ammonia TS CAS No.: Not applicable to mixtures. Molecular Weight: Not applicable to mixtures. Chemical Formula: Not applicable to mixtures. Product Codes:

2. Composition/Information on Ingredients
Ingredient Ammonia Water CAS No 7664-41-7 7732-18-5 Percent 27 - 31% 69 - 73% Hazardous Yes No

3. Hazards Identification Emergency Overview POISON! DANGER! CORROSIVE ALKALINE SOLUTION. CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. Health Rating: 3 - Severe (Poison) Flammability Rating: 1 - Slight Reactivity Rating: 2 - Moderate Contact Rating: 3 - Severe (Corrosive) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES Potential Health Effects Ammonia is very alkaline and reacts corrosively with all body tissues. Inhalation: Corrosive. Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. Inhalation may be fatal as a result of spasm inflammation and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Ingestion: Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach, leading to death. Can cause sore throat, vomiting, diarrhea. Skin Contact: Dermal contact with alkaline corrosives may produce pain, redness, severe irritation or full thickness burns. May be absorbed through the skin with possible systemic effects. Eye Contact: Corrosive. Can cause blurred vision, redness, pain, severe tissue burns and eye damage. Eye exposure may result in temporary or permanent blindness. Chronic Exposure: Prolonged or repeated skin exposure may cause dermatitis.

Prolonged or repeated exposure may cause eye, liver, kidney, or lung damage. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Note to Physician: DO NOT induce emesis, perform gastric lavage or attempt neutralization after ingestion. Dilution with milk or water may be of benefit. Endoscopic evaluation may be required. 5. Fire Fighting Measures Fire: Autoignition temperature: 651C (1204F) Flammable limits in air % by volume: lel: 16; uel: 25 Not considered to be a fire hazard. Explosion: Gives off flammable vapors. Vapors may form explosive mixture with air. Closed containers exposed to heat may explode. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Water spray may be used to keep fire exposed containers cool. Do not allow water runoff to enter sewers or waterways. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Approach release from upwind. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Carefuly neutrallize spill with dilute HCl. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Use water spray to cool, absorb, and disperse vapors. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The

toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Store below 25C. Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: For Ammonia: - OSHA Permissible Exposure Limit (PEL) -50 ppm (TWA) - ACGIH Threshold Limit Value (TLV)25 ppm (TWA), 35 ppm (STEL). Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full facepiece respirator with an ammonia/methylamine cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Clear, colorless liquid. Odor: Intense, pungent, sufficating odor. Solubility: Complete (100%) Specific Gravity: ca. 0.90 @ 25C/25C pH: 11.6 (1.0N) % Volatiles by volume @ 21C (70F): 100 Boiling Point: No information found. Melting Point: - 77C (-107F) Vapor Density (Air=1): 0.59 (ammonia gas)

Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Burning may produce ammonia, nitrogen oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Ammonia (anhydrous) is incompatible with mercury, chlorine, calcium hypochlorite, hydrofluoric acid (anhydrous), bromine pentaflouride, chlorine trifluoride, chloroformates, strong acids, strong oxidizing agents, brass, zinc, aluminum, copper, bronze, most common metals and dimethyl sulfate. Corrosive to copper, zinc and many metal surfaces. Reacts with hypochlorite or other halogen sources to form explosive compounds that are sensitive to pressure or increases in temperature. Reaction with sulfuric acid or other strong mineral acids is exothermic; mixture becomes boiling hot. Conditions to Avoid: Heat, direct sunlight, incompatibles. 11. Toxicological Information For Ammonia: LC50 inhalation rat 2000 ppm/4H. Investigated as a tumorigen and mutagen.

12. Ecological Information

Environmental Fate: No information found. Environmental Toxicity: No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Domestic (Land, D.O.T.) Proper Shipping Name: AMMONIA SOLUTIONS (WITH 10-35% AMMONIA) Hazard Class: 8 UN/NA: UN2672 Packing Group: III International (Water, I.M.O.) Proper Shipping Name: AMMONIA SOLUTIONS

Hazard Class: 8 UN/NA: UN2672 Packing Group: III

15. Regulatory Information 16. Other Information

NFPA Ratings: Health: 3 Flammability: 1 Reactivity: 0 Label Hazard Warning: POISON! DANGER! CORROSIVE ALKALINE SOLUTION. CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. Label Precautions: Do not get in eyes, on skin, or on clothing. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Label First Aid: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In all cases get medical attention immediately. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM ACETATE
1. Product Identification Synonyms: Acetic acid; ammonium salt CAS No.: 631-61-8 Molecular Weight: 77.08 Chemical Formula: CH3COONH4 Product Codes: 2. Composition/Information on Ingredients
Ingredient Ammonium Acetate CAS No 631-61-8 Percent 100% Hazardous Yes

3. Hazards Identification Emergency Overview CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED. Health Rating: 1 - Slight Flammability Rating: 1 - Slight Reactivity Rating: 1 - Slight Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: Dusts may irritate the respiratory tract with symptoms of coughing, and shortness of breath. Ingestion: May irritate the G. I. tract. Abdominal pain, nausea, and vomiting may occur. Ingestion of large amounts may result in diuresis and systemic ammonia poisoning. Normal human subjects infused with ammonium acetate exhibit flaccidity of facial muscles, tremor, generalized discomfort, anxiety and impairment of motor performance . Skin Contact: May cause irritation with redness and pain. Eye Contact: May cause irritation, redness and pain. Splashes from solutions may produce severe eye damage. Chronic Exposure: Chronic ammonium acetate ingestion may cause some liver dysfunction. Aggravation of Pre-existing Conditions: Persons with pre-existing liver damage may be more susceptible to the effects of this material. 4. First Aid Measures Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least

15 minutes. Call a physician. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Airpurifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat,

apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Transparent, colorless crystals. Odor: Slight acetic acid odor. Solubility: Very soluble in water. Specific Gravity: 1.07 pH: 7.0 Aqueous solution;very concentrated solution is slightly acidic % Volatiles by volume @ 21C (70F): No information found. Boiling Point: No information found. Melting Point: 114C (237F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hygroscopic. Readily absorbs moisture from the air. Tends to lose ammonia under normal conditions. Hazardous Decomposition Products: Burning may produce ammonia, nitrogen oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Decomposes on contact with Sodium Hypochlorite, strong acids. Conditions to Avoid: Heat, moisture, incompatibles. 11. Toxicological Information No LD50/LC50 information found relating to normal routes of occupational exposure. 12. Ecological Information Environmental Fate: When released into water, this material is expected to readily biodegrade. When released into the water, this material is expected to have a half-life between 1 and 10 days. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information Not regulated. 15. Regulatory Information

Chemical Weapons Convention: No TSCA 12(b): No SARA 311/312: Acute: Yes Chronic: Yes Fire: No Reactivity: No (Pure / Solid) CDTA: No Pressure: No

Australian Hazchem Code: No information found. Poison Schedule: No information found. 16. Other Information NFPA Ratings: Health: 1 Flammability: 1 Reactivity: 0 Label Hazard Warning: CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED. Label Precautions: Avoid breathing dust. Keep container closed. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Use with adequate ventilation. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In all cases call a physician. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM BICARBONATE 1. Product Identification Synonyms: Ammonium hydrogen carbonate; Ammonium acid carbonate CAS No.: 1066-33-7 Molecular Weight: 79.06 Chemical Formula: NH4HCO3 Product Codes: 2. Composition/Information on Ingredients
Ingredient Ammonium Bicarbonate CAS No 1066-33-7 Percent Hazardous 99 - 100% Yes

3. Hazards Identification Emergency Overview WARNING! HARMFUL IF INHALED. MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: Dust may cause irritation of the nose, throat, and lungs. Ammonia vapors released upon decomposition may cause irritation of the upper respiratory tract, with coughing, vomiting, and redness to the mucous membranes. Higher concentrations (> 1000 ppm) may cause restlessness, tightness in the chest, pulmonary edema, weak pulse, and cyanosis. Ingestion: Large oral doses may cause irritation to the gastrointestinal tract. Skin Contact: May cause irritation with redness and pain. Eye Contact: May cause irritation, redness and pain. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice. Skin Contact: Immediately flush skin with plenty of soap and water for at least 15

minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Irritating and toxic ammonia gas may form in fires. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Store at temperatures below 80F (27C) to minimize decomposition. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Airpurifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Fine white crystals. Odor: Slight ammonia odor. Solubility: 17.4% @ 20C (68F) in water. Specific Gravity: 1.59 pH: 7.8 % Volatiles by volume @ 21C (70F): 0 Boiling Point: Not applicable. Melting Point: 107.5C (226F) (Decomposes 36-60C) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Burning may produce ammonia, nitrogen oxides. Burning may produce ammonia, carbon monoxide, carbon dioxide, nitrogen oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Can react dangerously with acids, caustic alkalis and strong oxidizing agents. Conditions to Avoid: Heat, incompatibles. 11. Toxicological Information No LD50/LC50 information found relating to normal routes of occupational exposure. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may

differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information Chemical Weapons Convention: No TSCA 12(b): No No SARA 311/312: Acute: Yes Chronic: No Fire: No No Reactivity: No (Pure / Solid) Australian Hazchem Code: No information found. Poison Schedule: No information found. 16. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Label Hazard Warning: WARNING! HARMFUL IF INHALED. MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Label Precautions: Avoid contact with eyes, skin and clothing. Avoid breathing dust. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Label First Aid: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

CDTA: Pressure:

AMMONIUM BIFLUORIDE
1. Product Identification Synonyms: Ammonium hydrogen fluoride; ammonium difluoride; acid ammonium fluoride CAS No.: 1341-49-7 Molecular Weight: 57.04 Chemical Formula: NH4F HF Product Codes: 2. Composition/Information on Ingredients Ingredient CAS No Ammonium Bifluoride 1341-49-7 3. Hazards Identification Emergency Overview DANGER! MAY BE FATAL IF SWALLOWED OR INHALED. AFFECTS RESPIRATORY SYSTEM, HEART, SKELETON, CIRCULATORY SYSTEM, CENTRAL NERVOUS SYSTEM AND KIDNEYS. CAUSES IRRITATION AND BURNS TO SKIN, EYES AND RESPIRATORY TRACT. IRRITATION AND BURN EFFECTS MAY BE DELAYED. HARMFUL IF ABSORBED THROUGH SKIN. Health Rating: 3 - Severe (Poison) Flammability Rating: 0 - None Reactivity Rating: 2 - Moderate Contact Rating: 4 - Extreme (Corrosive) Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: White (Corrosive) Potential Health Effects If inhaled or swallowed, this compound can cause fluoride poisoning. Early symptoms include nausea, vomiting, diarrhea, and weakness. Later effects include central nervous system effects, cardiovascular effects and death. Inhalation: May cause irritation and burns to the respiratory tract, symptoms may include coughing, sore throat, and labored breathing. May be absorbed through inhalation of dust; symptoms may parallel those from ingestion exposure. Irritation and burning effects may not appear immediately. Ingestion: May cause salivation, nausea, vomiting, diarrhea, and abdominal pain, followed by symptoms of weakness, tremors, shallow respiration, carpopedal spasm, convulsions, and coma. May cause brain and kidney damage. Affects heart and circulatory system. Death may be caused by respiratory paralysis. Lethal dose estimated at between 1 teaspoonful and 1 oz. Skin Contact: Causes irritation and burns to the skin. Effects may not appear

Percent 100%

Hazardous Yes

immediately. Eye Contact: Causes irritation. May be extremely irritating with possible burns to eye tissue and permanent eye damage may result. Chronic Exposure: Chronic exposure may cause mottling of teeth and bone damage (osteosclerosis) and fluorosis. Symptoms of fluorisis include brittle bones,weight loss, anemia, calcified ligaments, general ill health and joint stiffness. Aggravation of Pre-existing Conditions: Populations that appear to be at increased risk from the effects of fluoride are individuals that suffer from diabetes insipidus or some forms of renal impairment. 4. First Aid Measures First aid procedures should be pre-planned for fluoride compound emergencies. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. CALL A PHYSICIAN IMMEDIATELY. Ingestion: Administer milk, chewable calcium carbonate tablets or milk of magnesia. Never give anything by mouth to an unconscious person. CALL A PHYSICIAN IMMEDIATELY. Skin Contact: Wipe off any excess material from skin and then immediately flush skin with large amounts of soapy water. Remove contaminated clothing and shoes. Wash clothing before re-use. Apply bandages soaked in magnesium sulfate. CALL A PHYSICIAN IMMEDIATELY. Eye Contact: Immediately flush eyes with gentle but large stream of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Call a physician immediately. Note to Physician: For large exposures, systemic effects (hypocalcemia and hypomagnesia) may occur. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Contact with water and metal at the same time may evolve flammable hydrogen gas. Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Do not use water. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The

toll free number for the US Coast Guard National Response Center is (800) 424-8802.

7. Handling and Storage Keep in a tightly closed container. Store in a cool, dry, ventilated area. Protect against physical damage. Separate from acids and alkalis. Do not store in metal containers, as contact with moisture and metal at the same time may release flammable hydrogen gas. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): 2.5 mg(F)/m3 (TWA) -ACGIH Threshold Limit Value (TLV): 2.5 mg(F)/m3 (TWA) Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: White crystals. Odor: Odorless. Solubility: 41.5g/l00 g Water @ 25C (68F) Specific Gravity: 1.51

pH: 3.5 (5% solution) % Volatiles by volume @ 21C (70F): 0 Boiling Point: 240C (464F) Melting Point: 124.6C (257F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Emits toxic fumes of hydrogen fluoride, nitric oxides, and ammonia when heated to decomposition. Upon contact with moisture and metal, this material may release hydrogen gas. Hazardous Polymerization: Will not occur. Incompatibilities: Reacts with acids to liberate hydrogen fluoride and base to liberate ammonia. When combined with moisture, will corrode glass, cement and most metals. Conditions to Avoid: No information found. 11. Toxicological Information No LD50/LC50 information found relating to normal routes of occupational exposure. 12. Ecological Information Environmental Fate: This material is not expected to significantly bioaccumulate. When released into water, this material may biodegrade to a moderate extent. Environmental Toxicity: This material is not expected to be toxic to aquatic life. The LC50/96-hour values for fish are over 100 mg/l. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: RQ, AMMONIUM HYDROGEN DIFLUORIDE, SOLID Hazard Class: 8 UN/NA: UN 1727 International (Water, I.M.O.) Proper Shipping Name: AMMONIUM HYDROGEN DIFLUORIDE, SOLID Hazard Class: 8 UN/NA: UN1727 International (Air, I.C.A.O.) Proper Shipping Name: AMMONIUM HYDROGEN DIFLUORIDE, SOLID Hazard Class: 8 UN/NA: UN1727 15. Regulatory Information

16. Other Information NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 0 Label Hazard Warning: DANGER! MAY BE FATAL IF SWALLOWED OR INHALED. AFFECTS RESPIRATORY SYSTEM, HEART, SKELETON, CIRCULATORY SYSTEM, CENTRAL NERVOUS SYSTEM AND KIDNEYS. CAUSES IRRITATION AND BURNS TO SKIN, EYES AND RESPIRATORY TRACT. IRRITATION AND BURN EFFECTS MAY BE DELAYED. HARMFUL IF ABSORBED THROUGH SKIN. Label Precautions: Do not breathe dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Label First Aid: In all cases call a physician immediately. First Aid procedures should be pre-planned for fluoride compound emergencies. If swallowed, administer milk, chewable calcium carbonate tablets or milk of magnesia. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing difficult, give artificial respiration. In case of skin contact wipe off any excess material then immediately flush skin with large amounts of soapy water. Remove contaminated clothing and shoes. Wash clothing before re-use. Apply bandages soaked in magnesium sulfate. In case of eye contact, immediately flush eyes with gentle but large stream of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a

trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM CHLORIDE
1. Product Identification Synonyms: Sal ammoniac; Ammonium muriate CAS No.: 12125-02-9 Molecular Weight: 53.49 Chemical Formula: NH4Cl Product Codes: 2. Composition/Information on Ingredients Ingredient Ammonium Chloride 3. Hazards Identification Emergency Overview WARNING! CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. HARMFUL IF SWALLOWED OR INHALED. Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 0 - None Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Ingestion: Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. At fire temperatures ammonium chloride begins to corrode metals and may dissociate into ammonia and hydrogen chloride. Mixtures of about 16% to 25% (by volume) ammonia gas in air are flammable. CAS No 12125-02-9 Percent Hazardous 99 - 100% Yes

Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Water spray may be used to keep fire exposed containers cool. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: Ammonium chloride: -ACGIH Threshold Limit Value (TLV):10 mg/m3 (TWA); 20 mg/m3 (STEL) Fume Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: White powder. Odor: Odorless. Solubility: 29.7g/100g water @ 0C (32F)

Specific Gravity: 1.53 pH: 5.5 (1% aq.sol.); 5.1 (3% aq.sol.); 5.0 (10% aq.sol.) % Volatiles by volume @ 21C (70F): 0 Boiling Point: 520C (968F) Melting Point: 338C (640F) Sublimes. Vapor Density (Air=1): 1.9 Vapor Pressure (mm Hg): 1.0 @ 160C (320F) Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Involvement in a fire causes decomposition to form hydrogen chloride and ammonia. Hazardous Polymerization: Will not occur. Incompatibilities: Concentrated acids, strong bases, silver salts, potassium chlorate, ammonium nitrate, bromine trifluoride and iodine heptafluoride. Ammonium chloride reacts explosively with potassium chlorate or bromine trifluoride, and violently with bromide pentafluoride, ammonium compounds, nitrates, and iodine heptafluoride. Explosive nitrogen trichloride may result from reaction of ammonium chloride and hydrogen cyanide. Conditions to Avoid: Heat, moisture, incompatibles. 11. Toxicological Information Oral rat LD50 : 1650 mg/kg Investigated as a mutagen. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information 16. Other Information NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0 Label Hazard Warning: WARNING! CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. HARMFUL IF

SWALLOWED OR INHALED. Label Precautions: Avoid contact with eyes, skin and clothing. Avoid breathing dust. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. In all cases, get medical attention. Product Use: Laboratory Reagent. DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM DICHROMATE
1. Product Identification Synonyms: Dichromic acid, diammonium salt; ammonium bichromate CAS No.: 7789-09-5 Molecular Weight: 252.07 Chemical Formula: (NH4)2Cr2O7 Product Codes: 2. Composition/Information on Ingredients
Ingredient Ammonium Bichromate CAS No 7789-09-5 Percent Hazardous 99 - 100% Yes

3. Hazards Identification Emergency Overview DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE A FIRE. CORROSIVE. CAUSES SEVERE BURNS TO EVERY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED. AFFECTS THE RESPIRATORY SYSTEM, LIVER, KIDNEYS, EYES, SKIN AND BLOOD. MAY CAUSE ALLERGIC REACTION. CANCER HAZARD. CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure. Health Rating: 4 - Extreme (Cancer Causing) Flammability Rating: 1 - Slight Reactivity Rating: 3 - Severe (Oxidizer) Contact Rating: 3 - Severe (Life) Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Yellow (Reactive) Potential Health Effects Inhalation: Corrosive. Extremely destructive to tissues of the mucous membranes and upper respiratory tract. May cause ulceration and perforation of the nasal septum. Symptoms may include sore throat, coughing, shortness of breath, and labored breathing. May produce pulmonary sensitization or allergic asthma. Higher exposures may cause pulmonary edema. Ingestion: Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach, leading to death. Can cause sore throat, vomiting, diarrhea. May cause violent gastroenteritis, peripheral vascular collapse, dizziness, intense thirst, muscle cramps, shock, coma, abnormal bleeding, fever, liver damage and acute renal failure. Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn can occur. Dusts and strong solutions may cause severe irritation. Contact with broken skin may cause ulcers (chrome sores) and absorption, which may cause systemic poisoning, affecting kidney and liver functions. May cause skin sensitization. Eye Contact: Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns. May cause corneal injury or blindness.

Chronic Exposure: Repeated or prolonged exposure can cause ulceration and perforation of the nasal septum, respiratory irritation, liver and kidney damage and ulceration of the skin. Ulcerations at first may be painless, but may penetrate to the bone producing "chrome holes." Known to be a human carcinogen. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders, asthma, allergies or known sensitization to chromic acid or chromates may be more susceptible to the effects of this material. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Autoignition temperature: 225C (437F) Combustible solid. Fire is possible at temperatures above decomposition 180C (356F) or by contact with an ignition source. Decomposition is self-sustaining above 225C (437F) with swelling, release of heat and nitrogen gas, and residue of green chromic oxide. Explosion: Contact with oxidizable substances may cause extremely violent combustion. Closed containers exposed to heat may explode. Fire Extinguishing Media: Use flooding amounts of water. Do not use dry chemical, carbon dioxide or Halon. Water spray may be used to keep fire exposed containers cool. Do not allow water runoff to enter sewers or waterways. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Closed containers readily rupture at decomposition temperature. 6. Accidental Release Measures Only specially trained or qualified personnel should handle the emergency. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Pick up spill for recovery or disposal and place in a closed container. Keep away from paper and wood products. If wet, slowly reduce with ferrous sulfate and acid, neutralize and package residue for disposal. Do not return spilled material to original container. US Regulations

(CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Protect against physical damage. Store in a dry location separate from combustible, organic or other readily oxidizable materials. Avoid storage on wood floors. Remove and dispose of any spilled dichromates; do not return to original containers. Wear special protective equipment (Sec. 8) for maintenance break-in or where exposures may exceed established exposure levels. Wash hands, face, forearms and neck when exiting restricted areas. Shower, dispose of outer clothing, change to clean garments at the end of the day. Avoid cross-contamination of street clothes. Wash hands before eating and do not eat, drink, or smoke in workplace. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: - OSHA Permissible Exposure Limit (PEL):For chromic acid and chromates, as CrO3 = 0.1 mg/m3 (ceiling) - ACGIH Threshold Limit Value (TLV):For water-soluble Cr(VI) compounds, as Cr = 0.05 mg/m3 (TWA), A1 - confirmed human carcinogen. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. (Natural rubber). Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties Appearance: Bright, orange-red crystals. Odor: Odorless. Solubility: 36.4 g/100 g water @ 20C (68F) Specific Gravity: 2.15 pH: 1% sol. = 3.95 10% sol. = 3.45 % Volatiles by volume @ 21C (70F): 0 Boiling Point: Not applicable. Melting Point: 180C (356F) Decomposes. Vapor Density (Air=1): 8.7 Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Can react explosively when in contact with certain organic substances. Hazardous Decomposition Products: Burning may produce chrome oxides. Burning may produce ammonia, nitrogen oxides. Hazardous Polymerization: Will not occur. Ammonia released due to decomposition forms flammable mixtures in air between 16% and 25%. Incompatibilities: Reducing agents, combustibles, organic materials, strong acids, alcohols, ethylene glycol, carbide, hydrazine, potassium chlorate, sodium nitrite and water. Avoid readily oxidizable substances, such as paper, wood, sulfur, aluminum, plastics, etc. Conditions to Avoid: Heat, flames, ignition sources and incompatibles. 11. Toxicological Information Investigated as a tumorigen and mutagen. ---NTP Carcinogen--Ingredient Ammonium Bichromate (7789-09-5) Known Yes Anticipated No IARC Category 1

12. Ecological Information Environmental Fate: When released into the soil, this material may leach into groundwater. When released into water, this material is not expected to evaporate significantly. This material may bioaccumulate to some extent. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. Environmental Toxicity: This material is expected to be toxic to aquatic life.

13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: RQ, AMMONIUM DICHROMATE Hazard Class: 5.1 UN/NA: UN1439 International (Water, I.M.O.) Proper Shipping Name: AMMONIUM DICHROMATE Hazard Class: 5.1 UN/NA: UN1439 15. Regulatory Information

16. Other Information NFPA Ratings: Health: 3 Flammability: 1 Reactivity: 1 Other: Oxidizer Label Hazard Warning: DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE A FIRE. CORROSIVE. CAUSES SEVERE BURNS TO EVERY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED. AFFECTS THE RESPIRATORY SYSTEM, LIVER, KIDNEYS, EYES, SKIN AND BLOOD. MAY CAUSE ALLERGIC REACTION. CANCER HAZARD. CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure. Label Precautions: Keep from contact with clothing and other combustible materials. Do not store near combustible materials. Do not get in eyes, on skin, or on clothing. Do not breathe dust or mist from solutions. Store in a tightly closed container. Keep container closed. Use only with adequate ventilation. Remove and wash contaminated clothing promptly. Wash thoroughly after handling. Label First Aid: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water.

Never give anything by mouth to an unconscious person. In all cases get medical attention immediately. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM MOLYBDATE
1. Product Identification Synonyms: Molybdic acid hexammonium salt tetrahydrate; ammonium molybdate tetrahydrate;ammonium heptamolybdate, tetrahydrate CAS No.: 12027-67-7 Molecular Weight: 1235.86 Chemical Formula: (NH4)6Mo7O24.4H2O Product Codes: 2. Composition/Information on Ingredients
Ingredient Hexaammonium Molybdate CAS No 12027-67-7 Percent 100% Hazardous Yes

3. Hazards Identification Emergency Overview WARNING! MAY BE HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS KIDNEYS AND BLOOD. Health Rating: 2 - Moderate Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation:Irritant for the upper respiratory system. Pungent taste in mouth and throat, coughing, labored breathing. Can be a route of absorption by the body with symptoms like ingestion. Ingestion: Irritant to the digestive system. Symptoms of sore throat, abdominal pain, nausea may occur. May cause anemia,gout, headaches, weight loss, joint pain, and liver or kidney damage. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: Prolonged or repeated exposure to this product may cause symptoms similar to ingestion. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders, blood disorders or eye problems, or impaired liver, kidney or respiratory function may be more susceptible to the effects of the substance.

4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Water spray may be used to keep fire exposed containers cool. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.

7. Handling and Storage Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): 5 mg/m3 for soluble molybdenum compounds as Mo 15 mg/m3 for insoluble molybdenum compounds as Mo -ACGIH Threshold Limit Value (TLV): 5 mg/m3 (TWA) for soluble molybdenum compounds as Mo

10 mg/m3 for insoluble molybdenum compounds as Mo Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: White to yellow-green crystals Odor: Odorless. Solubility: 43 g / 100 cc cold water. Density: 2.498 pH: 5.0 - 5.5 % Volatiles by volume @ 21C (70F): 0 Boiling Point: 190C (374F) Decomposes. Melting Point: 90C (194F) Loses 1 water @ this temperature. Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Burning may produce ammonia, nitrogen oxides and metal fumes. Hazardous Polymerization: Will not occur. Incompatibilities: Alkali metals Conditions to Avoid: Incompatibles.

11. Toxicological Information Investigated as a mutagen. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information 16. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Label Hazard Warning: WARNING! MAY BE HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS KIDNEYS AND BLOOD. Label Precautions: Avoid contact with eyes, skin and clothing. Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Label First Aid: If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases, get medical attention. Product Use: Laboratory Reagent.

DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM NITRATE
1. Product Identification Synonyms: Nitric acid, ammonium salt CAS No.: 6484-52-2 Molecular Weight: 80.04 Chemical Formula: NH4NO3 Product Codes: 2. Composition/Information on Ingredients Ingredient Hazardous Ammonium Nitrate 100% Yes 3. Hazards Identification Emergency Overview DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE OR EXPLOSION. MAY BE HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 3 - Severe (Oxidizer) Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Yellow (Reactive) Potential Health Effects Inhalation: May cause irritation to the respiratory tract; symptoms may include coughing, sore throat, and shortness of breath. At high temperatures, exposure to toxic nitrogen oxides decomposition products can quickly cause acute respiratory problems. Inhalation of large amounts causes systemic acidosis and abnormal hemoglobin. Ingestion: Large oral doses of nitrates may cause dizziness, abdominal pain, vomiting, bloody diarrhea, weakness, convulsions, and collapse. Harmful if swallowed. May cause methemoglobinemia resulting in cyanosis. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: Small repeated oral doses of nitrates may cause weakness, depression, headache, and mental impairment. Aggravation of Pre-existing Conditions: No information found.

CAS No 6484-52-2

Percent 99 -

4. First Aid Measures Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if irritation develops or persists. Eye Contact: Wash thoroughly with running water. Get medical advice if irritation develops. 5. Fire Fighting Measures Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. May support combustion in an existing fire. Explosion: Contact with oxidizable substances may cause extremely violent combustion. Sealed containers may rupture when heated. Sensitive to mechanical impact. Fire Extinguishing Media: Use flooding amounts of water in early stages of fire involving ammonium nitrate. Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Remove sources of heat and ignition. Collected waste may be transferred to a closed, preferably metal, container and sent to a RCRA approved waste disposal facility. Alternatively, sweep spill into noncombustible container and dissolve in large amount of water. Add soda ash. Mix and neutralize with 6M-HCl. Neutralized sludge may be sent to an approved waste disposal facility.

7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Protect against physical damage. Store in a dry location separate from combustible, organic or other readily oxidizable materials. Avoid storage on wood floors. Remove and dispose of any spilled dichromates; do not return to original containers. Do not store above 54C (130F) preferably below 30C (86F). Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Airpurifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quickdrench facilities in work area. 9. Physical and Chemical Properties Appearance: Colorless crystals. Odor: Odorless. Solubility: 118g/100g water @ 0C (32F). Specific Gravity: 1.73 @ 23C (77F) pH: 5.4 % Volatiles by volume @ 21C (70F): 0 Boiling Point: 210C (410F) Decomposes. Melting Point: 170C (338F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hygroscopic. Hazardous Decomposition Products: Emits nitrous oxides when heated to decomposition. Liberates ammonia in reaction with strong alkalis. Hazardous Polymerization: Will not occur. Incompatibilities: Aluminum, antimony, chromium, copper, iron, lead, magnesium, manganese, nickel, zinc, brass, oil, charcoal, organic material, acetic acid, ammonium chloride, bismuth, cadmium, chlorides, cobalt, phosphorus, potassium and ammonium sulfate, sodium, sodium hypochlorite, sodium perchlorate, sodium-potassium alloy, and sulfure. Conditions to Avoid: Heat, flame, ignition sources, dusting and incompatibles. Moisture and combustible materials. Shock sensitive.

11. Toxicological Information Oral rat LD50: 2217 mg/kg. 12. Ecological Information Environmental Fate: When released into the soil, this material is expected to leach into groundwater. When released into the soil, this material is not expected to evaporate significantly. When released into water, this material is expected to readily biodegrade. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: AMMONIUM NITRATE Hazard Class: 5.1 UN/NA: UN1942 International (Water, I.M.O.) Proper Shipping Name: AMMONIUM NITRATE Hazard Class: 5.1 UN/NA: UN1942

15. Regulatory Information

16. Other Information NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 3 Other: Oxidizer Label Hazard Warning: DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE OR EXPLOSION. MAY BE HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.

Label Precautions: Keep from contact with clothing and other combustible materials. Do not store near combustible materials. Store in a tightly closed container. Avoid breathing dust. Avoid contact with eyes, skin and clothing. Remove and wash contaminated clothing promptly. Use only with adequate ventilation. Wash thoroughly after handling. Store preferably below 30C Label First Aid: If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. In all cases, get medical attention. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM OXALATE
1. Product Identification Synonyms: Ethanedioic acid, diammonium salt monohydrate; Ammonium oxalate, monohydrate CAS No.: 1113-38-8 (Anhydrous) 6009-70-7(monohydrate) Molecular Weight: 142.11 Chemical Formula: NH4OCOCOONH4 . H2O Product Codes: 2. Composition/Information on Ingredients
Ingredient Ammonium Oxalate CAS No 1113-38-8 Percent Hazardous 99 - 100% Yes

3. Hazards Identification Emergency Overview POISON! DANGER! MAY BE FATAL IF SWALLOWED OR INHALED. MAY CAUSE BURNS TO RESPIRATORY TRACT AND SEVERE IRRITATION TO SKIN AND EYES. MAY AFFECT KIDNEYS. Health Rating: 3 - Severe (Poison) Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 3 - Severe (Corrosive) Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: White (Corrosive) Potential Health Effects Ammonium oxalate is very poisonous by ingestion and inhalation. Inhalation: Inhalation of dust is corrosive to mucous membranes. Oxalates can be absorbed through the lungs. Symptoms of poisoning include nervousness, cramps, central nervous system depression. Ingestion: Mean lethal dose for oxalates in adults is estimated at 15-30 grams with death within a few hours or even minutes. Corrosive action on the mucosa and severe gastrointestitis can occur with pain, vomiting, etc. Sharp reduction of serum calcium can cause disfunction of the brain. Calcium oxalate may be deposited in the kidneys. Skin Contact: Skin contact may produce severe skin irritation with burning, redness. Eye Contact: May cause severe irritation and pain. May cause burns. Chronic Exposure: Circulatory failure or nervous system irregularities may follow prolonged calcium metabolism disturbances due to oxalation. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more susceptible to the effects of the substance.

4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Note to Physician: Carefully monitor cardiovascular, respiratory, neurologic and renal functions. Treat supportively in consultation with a medical toxicologist. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Practice good personal hygiene and wash thoroughly after handing material. Do not eat, drink, or smoke in the workplace.

8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Airpurifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Colorless crystals or granules. Odor: Odorless. Solubility: 11.8 g/100 g water @ 50C (122F) Specific Gravity: 1.50 pH: 6.4 (0.1 molar solution) % Volatiles by volume @ 21C (70F): 0 Boiling Point: Not applicable. Melting Point: 70C (158F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Burning may produce ammonia, nitrogen oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Sodium hypochlorite plus ammonium acetate , strong acids. Conditions to Avoid: Heat, incompatibles.

11. Toxicological Information No LD50/LC50 information found relating to normal routes of occupational exposure. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: CORROSIVE SOLID,N.O.S. (AMMONIUM OXALATE) Hazard Class: 8 UN/NA: UN1759 International (Water, I.M.O.) Proper Shipping Name: CORROSIVE SOLID,N.O.S. (AMMONIUM OXALATE) Hazard Class: 8 UN/NA: UN1759 International (Air, I.C.A.O.) Proper Shipping Name: CORROSIVE SOLID,N.O.S. (AMMONIUM OXALATE) Hazard Class: 8 UN/NA: UN1759

15. Regulatory Information 16. Other Information NFPA Ratings: Health: 4 Flammability: 1 Reactivity: 0 Label Hazard Warning:

POISON! DANGER! MAY BE FATAL IF SWALLOWED OR INHALED. MAY CAUSE BURNS TO RESPIRATORY TRACT AND SEVERE IRRITATION TO SKIN AND EYES. MAY AFFECT KIDNEYS. Label Precautions: Do not get in eyes, on skin, or on clothing. Do not breathe dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Label First Aid: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In all cases get medical attention immediately. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM PERSULFATE
1. Product Identification Synonyms: Ammonium Peroxydisulfate; Peroxydisulfuric Acid, Diammonium Salt; Diammonium peroxydisulfate CAS No.: 7727-54-0 Molecular Weight: 228.20 Chemical Formula: (NH4)2S2O8 Product Codes: 2. Composition/Information on Ingredients
Ingredient Ammonium Persulfate CAS No 7727-54-0 Percent 98 - 100% Hazardous Yes

3. Hazards Identification Emergency Overview DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE BURNS TO SKIN AND EYES. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 3 - Severe (Oxidizer) Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Yellow (Reactive) Potential Health Effects Inhalation: May irritate the mucous membranes. May cause lung edema. Symptoms may include sore throat, shortness of breath, inflammation of nasal passages, coughing, and wheezing. Any exposure may cause an allergic reaction. Asthma-like symptoms and lifethreatening shock may result. Ingestion: Corrosive. May produce abdominal pain, nausea and vomiting. Skin Contact: Corrosive. May cause skin burns. Eye Contact: May cause severe irritation and pain. Chronic Exposure: Prolonged skin contact may cause an allergic reaction with dermatitis. Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effects of the substance.

4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Heating or contact with water releases oxygen which may intensify combustion in an existing fire. Explosion: An explosion hazard when mixed with finely powdered organic matter, metal powder, or reducing agents. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Do not use water. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Sealed containers may rupture when heated. 6. Accidental Release Measures Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Separate from combustibles, organic or other readily oxidizable materials. Avoid storage on wood floors. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection Airborne Exposure Limits: - ACGIH Threshold Limit Value (TLV): 5 mg/m3 (TWA) as persulfate Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Airpurifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quickdrench facilities in work area. 9. Physical and Chemical Properties Appearance: White crystals. Odor: Odorless. Solubility: 80 g/l00 ml water @ 25C (77F) Specific Gravity: 1.98 @ 20C/4C pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: Not applicable. Melting Point: 120C (248F) Decomposes. Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Stability decreases in the presence of moisture. Hazardous Decomposition Products: Decomposed by moisture to form oxygen and ozone. Burning may produce nitrogen oxides, sulfur oxides, and sulfuric acid. Hazardous Polymerization: Will not occur. Incompatibilities: Reducing agents, organic material, sodium peroxide, water and powdered metals especially aluminum. Conditions to Avoid: Moisture, combustible materials and incompatibles.

11. Toxicological Information Oral rat LD50: 689 mg/kg 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: AMMONIUM PERSULFATE Hazard Class: 5.1 UN/NA: UN1444 International (Water, I.M.O.) Proper Shipping Name: AMMONIUM PERSULPHATE Hazard Class: 5.1 UN/NA: UN1444 15. Regulatory Information 16. Other Information NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 1 Other: Oxidizer Label Hazard Warning: DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE BURNS TO SKIN AND EYES. MAY CAUSE ALLERGIC SKIN OR RESPIRATORY REACTION. Label Precautions: Keep from contact with clothing and other combustible materials. Do not get in eyes, on skin, or on clothing. Do not breathe dust. Store in a tightly closed container. Use with adequate ventilation.

Wash thoroughly after handling. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. In all cases get medical attention immediately. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM SULFATE
1. Product Identification Synonyms: Diammonium sulfate; sulfuric acid, diammonium salt; Actamaster; Dolamin; mascagnite CAS No.: 7783-20-2 Molecular Weight: 132.14 Chemical Formula: (NH4)2SO4 Product Codes: 2. Composition/Information on Ingredients
Ingredient Ammonium Sulfate CAS No 7783-20-2 Percent Hazardous 99 - 100% Yes

3. Hazards Identification Emergency Overview WARNING! CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED. Health Rating: 2 - Moderate Flammability Rating: 0 - None Reactivity Rating: 1 - Slight Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Ingestion: Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. It presents little toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.

Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Flammable ammonia gas may be released in a fire. Explosion: May explode if mixed with oxidizers, such as potassium nitrate, potassium nitrite, and potassium chlorate. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Water spray may be used to keep fire exposed containers cool. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Airpurifying respirators do not protect workers in oxygen-deficient atmospheres.

Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Fine white granules or crystals. Odor: Slight odor of ammonia. Solubility: Appreciable in water. 41.22 g/100 g water @ 25C (77F) Density: 1.77 @ 50C(122F) pH: 5.5 (0.1M aqueous solution) % Volatiles by volume @ 21C (70F): 0 Boiling Point: Not applicable. Melting Point: 235 - 280C (455 - 536F) Decomposes. Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Maintain at temperatures below 513C (955F). Hazardous Decomposition Products: May emit ammonia, oxides of sulfur, oxides of nitrogen, and oxides of carbon. Hazardous Polymerization: Will not occur. Incompatibilities: Sodium hypochlorite, potassium plus ammonium nitrate, potassium chlorate, potassium nitrite, and sodium-potassium powder plus ammonium nitrate, and other strong oxidizers. Conditions to Avoid: Heat, incompatibles. 11. Toxicological Information Oral rat LD50: 2840 mg/kg Investigated as a mutagen. 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found.

13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information 16. Other Information NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0 Label Hazard Warning: WARNING! CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. MAY BE HARMFUL IF SWALLOWED. Label Precautions: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. In all cases, get medical attention. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

AMMONIUM THIOCYANATE
1. Product Identification Synonyms: Ammonium sulfocyanide; ammonium rhodanide; thiocyanic acid, ammonium salt; ammonium sulfocyanate CAS No.: 1762-95-4 Molecular Weight: 76.12 Chemical Formula: NH4SCN Product Codes: 2. Composition/Information on Ingredients
Ingredient Ammonium Thiocyanate CAS No 1762-95-4 Percent > 98% Hazardous Yes

3. Hazards Identification Emergency Overview WARNING! HARMFUL IF SWALLOWED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Health Rating: 2 - Moderate Flammability Rating: 1 - Slight Reactivity Rating: 1 - Slight Contact Rating: 1 - Slight Lab Protective Equip: GOGGLES; LAB COAT Storage Color Code: Orange (General Storage) Potential Health Effects Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Ingestion: May cause vomiting, disorientation, weakness, low blood pressure, convulsions and death which may be delayed. The probable lethal dose is between 15-30 grams. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: Prolonged or repeated skin exposure may cause dermatitis. Repeated ingestion of small amounts may cause hives, abnormal bleeding, weight loss, mental effects, and an enlarged thyroid. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Not considered a fire hazard, but fire may decompose ammonium thiocyanate to form toxic gases more hazardous than ammonium thiocyanate itself. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from oxidizing materials. Store in the dark. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not

known, use a full-face positive-pressure, air-supplied respirator. WARNING: Airpurifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Colorless, deliquescent crystals. Odor: Odorless to slight ammonia odor. Solubility: 128g/100g water @ 0C (32F). Specific Gravity: 1.31 pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: 170C (338F) Decomposes (anhydrous). Melting Point: 150C (302F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Slowly decomposes on exposure to light. Hazardous Decomposition Products: Emits toxic fumes of ammonia, nitric oxides, sulfur oxides, thiocyanates, and cynanide when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Lead nitrate, chlorates, nitrates, nitric acid, organic peroxides, oxidizing agents, peroxides, sodium chlorate, and potassium chlorate. Reacts with acid to liberate toxic hydrogen cyanide. Conditions to Avoid: Heat, flames, ignition sources and incompatibles. 11. Toxicological Information Oral Rat LD50: 750 mg/kg. 12. Ecological Information Environmental Fate: This material is not expected to significantly bioaccumulate. Environmental Toxicity: No information found.

13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information 16. Other Information NFPA Ratings: Health: 2 Flammability: 1 Reactivity: 1 Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. Label Precautions: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing dust. Keep container closed. Use only with adequate ventilation. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. In all cases, get medical attention. Product Use: Laboratory Reagent. DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

Amyl Acetate (Mixed Isomers)

1. Product Identification Synonyms: Amylacetic Ester; Banana Oil; Pear Oil; n-Pentyl Acetate CAS No.: 628-63-7 Molecular Weight: 130.19 Chemical Formula: CH3COOC5H11 Product Codes: 2. Composition/Information on Ingredients
Ingredient n-Amyl Acetate 2-Methyl Butyl Acetate Isoamyl Acetate CAS No 628-63-7 624-41-9 123-92-2 Percent > 60% > 35% > 5% Hazardous Yes Yes Yes

3. Hazards Identification Emergency Overview WARNING! FLAMMABLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL NERVOUS SYSTEM. Health Rating: 2 - Moderate Flammability Rating: 3 - Severe (Flammable) Reactivity Rating: 1 - Slight Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER. Storage Color Code: Red (Flammable) Potential Health Effects Inhalation: Inhalation of vapors causes irritation to the respiratory tract. High concentrations can cause narcosis, headache, fatigue, chest pains, cough, nausea, dizziness, and possible damage to liver and kidneys. Ingestion: May be absorbed through the gastrointestinal tract; symptoms may parallel inhalation. Additional symptoms may include vomiting, stomach pain. Skin Contact: May cause irritation, redness, and pain. Liquid degreases the skin. Eye Contact: Vapors > 300 ppm cause burning sensations in the eyes. Contact causes irritation, redness, and pain. Chronic Exposure: Prolonged or repeated skin exposure may cause dermatitis. Chronic exposure may cause eye effects. Aggravation of Pre-existing Conditions: Use of alcoholic beverages may enhance toxic effects.

4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Flash point: 38C (100F) CC Autoignition temperature: 379C (714F) Flammable limits in air % by volume: lel: 1.1; uel: 7.5 Flammable Liquid and Vapor! Contact with strong oxidizers may cause fire. (Flash point and Auto Ignition values for the mixed isomer.) Explosion: Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Vapors can flow along surfaces to distant ignition source and flash back. Sealed containers may rupture when heated. Fire Extinguishing Media: Dry chemical, alcohol foam or carbon dioxide. Water may be ineffective. Special Information: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Use nonsparking tools and equipment. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! Have dry powder fire extinguisher on hand during clean-up operations. If a leak or spill has not ignited, use water spray to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. If a leak or spill has not ignited, use water spray to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures.

7. Handling and Storage Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tools and equipment, including explosion proof ventilation. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. Do Not attempt to clean empty containers since residue is difficult to remove. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, sparks, flame, static electricity or other sources of ignition: they may explode and cause injury or death. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: For n-Amyl Acetate: - OSHA Permissible Exposure Limit (PEL):100 ppm (TWA). - ACGIH Threshold Limit Value (TLV):100 ppm (TWA). Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face organic vapor respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece organic vapor respirator may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Clear, colorless liquid. Odor: Banana-like odor. Solubility: Slight (0.1-1%)

Specific Gravity: 0.88 pH: No information found. % Volatiles by volume @ 21C (70F): 100 Boiling Point: 149.25C (300F) (n-Amyl Acetate). Melting Point: -70.8C (-96F) (n-Amyl Acetate). Vapor Density (Air=1): 4.5 (n-Amyl Acetate). Vapor Pressure (mm Hg): 5 @ 25C (77F) (n-Amyl Acetate). Evaporation Rate (BuAc=1): 0.42 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Emits acrid smoke and fumes when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Strong alkalis, acids, nitrates and oxidizing agents. Conditions to Avoid: Heat, flames, ignition sources and incompatibles. 11. Toxicological Information For n-Amyl Acetate: No LD50/LC50 information found relating to normal routes of occupational exposure. For Isoamyl Acetate: LD50 oral rat: 16600 mg/kg. Investigated as a tumorigen. 12. Ecological Information Environmental Fate: For n-Amyl Acetate: When released into the soil, this material may leach into groundwater. When released into the water, this material is expected to have a half-life of less than 1 day. This material is not expected to significantly bioaccumulate. When released into the air, this material may be moderately degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material is expected to have a half-life between 1 and 10 days. For Isoamyl Acetate: When released into the soil, this material may leach into groundwater. When released into the soil, this material is expected to have a half-life of greater than 30 days. When released into water, this material is expected to readily biodegrade. When released to water, this material is expected to quickly evaporate. When released into the water, this material is expected to have a half-life of less than 1 day. This material has an estimated bioconcentration factor (BCF) of less than 100. This material has a log octanol-water partition coefficient of less than 3.0. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material is expected to be readily removed from the atmosphere by wet deposition. When released into the air, this

material is expected to have a half-life between 1 and 10 days. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: AMYL ACETATES Hazard Class: 3 UN/NA: UN1104 International (Water, I.M.O.) Proper Shipping Name: AMYL ACETATES Hazard Class: 3.3 UN/NA: UN1104 15. Regulatory Information 16. Other Information NFPA Ratings: Health: 1 Flammability: 3 Reactivity: 0 Label Hazard Warning: WARNING! FLAMMABLE LIQUID AND VAPOR. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. AFFECTS CENTRAL NERVOUS SYSTEM. Label Precautions: Avoid contact with eyes, skin and clothing. Avoid breathing vapor. Use only with adequate ventilation. Keep away from heat, sparks and flame. Wash thoroughly after handling. Keep container closed. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. In all cases, get medical attention. Product Use: Laboratory Reagent.
DISCLAIMER:

Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ANILINE 1. Product Identification Synonyms: Aminobenzene; aniline oil; phenylamine; aniline technical special CAS No.: 62-53-3 Molecular Weight: 93.12 Chemical Formula: C6H5NH2 Product Codes:

2. Composition/Information on Ingredients Ingredient Hazardous --------------------------------------Aniline CAS No -----------62-53-3 Percent ------99 - 100% -------Yes

3. Hazards Identification Emergency Overview -------------------------DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. COMBUSTIBLE LIQUID AND VAPOR. MAY CAUSE METHEMOGLOBINEMIA. AFFECTS BLOOD, CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEYS. Health Rating: 3 - Severe (Cancer Causing) Flammability Rating: 2 - Moderate Reactivity Rating: 2 - Moderate Contact Rating: 3 - Severe (Life) Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER Storage Color Code: Red (Flammable) Potential Health Effects Inhalation: Toxic. Affects ability of blood to carry oxygen. Symptoms may include bluish discoloration of lips and tongue, severe headache, nausea, confusion, dizziness, shock, respiratory paralysis, death. Ingestion: Toxic. Lethal dose may be as little as one gram. Symptoms of ingestion parallel those of inhalation exposure. Skin Contact: May be absorbed through skin. Symptoms of skin absorption parallel those from inhalation exposure. May cause skin irritation. Local contact may cause dermatitis. Eye Contact: Vapor is an eye irritant. May cause tearing, blurred vision. Splashes may cause corneal damage. Chronic Exposure: Aniline is a blood toxin, causing hemoglobin to convert to methemoglobin, resulting in cyanosis. Lengthy or repeated exposures may result in decreased appetite, anemia, weight loss, nervous system affects, and kidney, liver and bone marrow damage. Any exposure may cause an allergic skin reaction.

Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of the substance. A NIOSH study reported an excess bladder cancer risk in workers exposed to aniline in combination with other dyestuffs and intermediates, although it is not clear which of these materials, or combinations, were responsible for the higher incidence of bladder cancer. Based on the results of this study , historical epidemiology evidence which shows no correlation of pure aniline with bladder cancer, and experimental test results, it was concluded that aniline, most likely, is not responsible for the increased incidence of bladder tumors in the NIOSH study. 4. First Aid Measures Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do not give mouth to mouth resuscitation. CALL A PHYSICIAN IMMEDIATELY. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Flash point: 70C (158F) CC Autoignition temperature: 615C (1139F) Flammable limits in air % by volume: lel: 1.3; uel: 11.0 Combustible liquid and vapor. Flammable when exposed to heat or flame. Contact with strong oxidizers may cause fire or explosion. Explosion: Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Sealed containers may rupture when heated. Fire Extinguishing Media: Dry chemical, foam, carbon dioxide, or water spray. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Use water spray to blanket fire, cool fire exposed containers, and to flush non-ignited spills or vapors away from fire. 6. Accidental Release Measures Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Use non-sparking tools and equipment. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

7. Handling and Storage Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tools and equipment, including explosion proof ventilation. Protect from freezing. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): 5 ppm (TWA) skin -ACGIH Threshold Limit Value (TLV): 2 ppm (TWA) skin Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or fullfacepiece self-contained breathing apparatus. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. Other Control Measures: Provide clean work clothes daily to workers who regularly use this material. Wash hands before eating and do not eat, drink, or smoke in workplace. 9. Physical and Chemical Properties Appearance: Colorless, oily liquid. Darkens on exposure to light or air. Odor: Weakly amine. Solubility: 3.5 gm in 100 gm water @ 20C (68F). Specific Gravity: 1.022 @ 68F (20C) pH: 8.1 (0.2 M solution) % Volatiles by volume @ 21C (70F): 100 Boiling Point: 184C (363F) Melting Point: -6.2C (21F) Vapor Density (Air=1): 3.22 Vapor Pressure (mm Hg): 0.6 @ 20C (68F) Evaporation Rate (BuAc=1): < 1

10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Discolors on exposure to light. Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Strong acids and strong oxidizers, albumin, solutions of iron, zinc, aluminum, toluene diisocyanate, and alkalis. Ignites spontaneously in the presence of red fuming nitric acid, and with sodium. Conditions to Avoid: Heat, flames, ignition sources and incompatibles. 11. Toxicological Information Oral rat LD50: 250 mg/kg; skin rabbit LD50: 820 mg/kg; inhalation mouse LC50: 175 ppm (7 hours); irritation skin rabbit: 20 mg/24H moderate; irritation eye rabbit 102 mg severe. Investigated as a tumorigen, mutagen, and reproductive effector. Carcinogenic determination: limited evidence in experimental animals (IARC 27, 54, 1982). Aniline is listed by the International Agency for Research on Cancer (IARC) in Category 3, i. e., "Cannot be classified as to its carcinogenicity in humans." (IARC, Supplement 4, 1982). --------\Cancer Lists\----------------------------------------------------Ingredient Category -----------------------------------Aniline (62-53-3) 12. Ecological Information Environmental Fate: When released into the soil, this material is expected to readily biodegrade. When released into the soil, this material may leach into groundwater. When released into the soil, this material may evaporate to a moderate extent. When released into water, this material is expected to readily biodegrade. When released into water, this material is expected to have a half-life between 10 and 30 days. This material has an experimentally-determined bioconcentration factor (BCF) of less than 100. This material is not expected to significantly bioaccumulate. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals. When released into the air, this material is expected to be readily degraded by photolysis. When released into the air, this material is expected to have a half-life of less than 1 day. When released into the air, this material is not expected to adversely affect the ozone layer. Environmental Toxicity: This material is expected to be very toxic to terrestrial life. This material is expected to be very toxic to aquatic life. The LC50/96-hour values for fish are between 10 and 100 mg/l. The EC50/48-hour values for daphnia are less than 1 mg/l. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal ---NTP Carcinogen--Known Anticipated ----No ----------No IARC -----------3

regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information 15. Regulatory Information This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. 16. Other Information NFPA Ratings: Health: 3 Flammability: 2 Reactivity: 0 Label Hazard Warning: DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. COMBUSTIBLE LIQUID AND VAPOR. MAY CAUSE METHEMOGLOBINEMIA. AFFECTS BLOOD, CARDIOVASCULAR SYSTEM, CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEYS. Label Precautions: Do not breathe vapor. Do not get in eyes, on skin, or on clothing. Keep away from heat and flame. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Label First Aid: In all cases call a physician immediately. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. IF INHALED, remove to fresh air. If not breathing, give artificial respiration. DO NOT GIVE MOUTH-TO-MOUTH RESUSCITATION. If breathing is difficult, give oxygen. Keep patient warm and at rest. Product Use: Laboratory Reagent. DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

ANTIMONY TRIOXIDE 1. Product Identification Synonyms: Antimony oxide; antimony peroxide CAS No.: 1309-64-4 Molecular Weight: 291.50 Chemical Formula: Sb2O3 Product Codes:

2. Composition/Information on Ingredients Ingredient Hazardous --------------------------------------Antimony Trioxide CAS No -----------Percent --------------

1309-64-4

99 - 100%

Yes

3. Hazards Identification Emergency Overview WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES, RESPIRATORY AND GASTROINTESTINAL TRACTS. AFFECTS THE CARDIOVASCULAR SYSTEM. Health Rating: 3 - Severe (Life) Flammability Rating: 0 - None Reactivity Rating: 0 - None Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Blue (Health) ----------------------------------------------------------------------------------------------------------Potential Health Effects ---------------------------------Inhalation: Causes irritation to the respiratory tract. Symptoms can include sore throat, cough. Ingestion: Ingestion causes irritation to the mouth, nose and stomach. Other symptoms include salivation, cough, metallic taste, nausea, vomiting, bloody diarrhea, dizziness, irritability, and muscular pains. May cause heart to beat irregularly or stop. Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain. Eye Contact: Causes irritation, redness, and pain. Chronic Exposure: Prolonged or repeated exposure may damage the liver and the heart muscle. Prolonged skin contact may cause irritation, dermatitis, itching, and pimple eruptions. There is an association between antimony trioxide production and an increased incidence of lung cancer. Aggravation of Pre-existing Conditions:

Persons with pre-existing skin disorders, impaired respiratory function, or heart disorders (or disease) may be more susceptible to the effects of the substance. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Note to Physician: A urine test can be used to confirm exposure to antimony trioxide: 1 mg / ml is indicative of potentially harmful exposure. Chelators such as BAL and unithiol have been used in some countries. 5. Fire Fighting Measures Fire: Non-combustible, but powdered antimony trioxide may ignite and burn when heated in air. Explosion: Not considered to be an explosion hazard. Trivalent antimony compounds tend to form explosive mixtures with perchloric acid. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): 0.5 mg (Sb) m3 (TWA) -ACGIH Threshold Limit Value (TLV): 0.5 mg (Sb)/m3 (TWA) for handling and use, A2 suspected human carcinogen for production. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a full facepiece respirator with dust/mist filter may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: White polymorphic crystals. Odor: Odorless. Solubility:Insoluble in water @ 25C (77F);Slightly soluble in water @ 100C (212F) Density: 5.2 pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: 1425C (2597F) Melting Point: 655C (1211F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): 1 @ 574C (1065F) Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Toxic metal fumes may form when heated to decomposition. Hazardous Polymerization: Will not occur. Incompatibilities: Bromine trifluoride,strong acids, strong bases, reducing agents, perchloric acid, and chlorinated rubber. Reduction with hydrogen or if used near acids it may form a deadly gas (stibine). Conditions to Avoid: Dusting and incompatibles.

11. Toxicological Information Oral rat LD50: > 20 g/kg; investigated as a mutagen, tumorigen, reproductive effector. --------\Cancer Lists\----------------------------------------------------Ingredient Category -----------------------------------Antimony Trioxide (1309-64-4) 12. Ecological Information Environmental Fate: When released into the soil, this material is not expected to leach into groundwater. When released into the soil, this material is not expected to evaporate significantly. When released into water, this material is not expected to evaporate significantly. Environmental Toxicity: The LC50/96-hour values for fish are over 100 mg/l. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information 15. Regulatory Information ---NTP Carcinogen--Known Anticipated ----No ----------No IARC -----------2B

16. Other Information NFPA Ratings: Health: 2 Flammability: 1 Reactivity: 0 Label Hazard Warning: WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES, RESPIRATORY AND GASTROINTESTINAL TRACTS. AFFECTS THE CARDIOVASCULAR SYSTEM. Label Precautions: Avoid breathing dust. Avoid contact with eyes, skin and clothing. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Label First Aid: If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases

call a physician. Product Use: Laboratory Reagent. DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.

4-AMINOANTIPYRINE
1. Product Identification Synonyms: 4-Aminoantipyrine;4-AAP;Metapirazone CAS No.: 83-07-8 Molecular Weight: 203 Chemical Formula: C11H13N3O Product Codes: 2. Composition/Information on Ingredients
Ingredient --------------------------------------4-Aminoantipyrine CAS No -----------83-07-8 Percent Hazardous -------------90 - 100% Yes

3. Hazards Identification Emergency Overview CAUTION! MAY BE HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Health Rating: 2 - Moderate Flammability Rating: 1 - Slight Reactivity Rating: 1 - Slight Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Orange (General Storage) Potential Health Effects Information on the human health effects from exposure to this substance is limited. Inhalation: May cause irritation to the respiratory tract. Symptoms may include coughing and shortness of breath. Ingestion: Large oral doses may cause irritation to the gastrointestinal tract. Skin Contact: May cause irritation with redness and pain. Eye Contact: May cause irritation, redness and pain. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: No information found.

4. First Aid Measures Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists. 5. Fire Fighting Measures Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source. Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal.

7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection Airborne Exposure Limits: - OSHA Permissible Exposure Limit (PEL): 15 mg/m3 total dust, 5 mg/m3 respirable fraction for nuisance dusts. - ACGIH Threshold Limit Value (TLV): 10 mg/m3 total dust containing no asbestos and < 1% crystalline silica for Particulates Not Otherwise Classified (PNOC). Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Yellow powder. Odor: Odorless. Solubility: Soluble in water. Specific Gravity: No information found. pH: No information found. % Volatiles by volume @ 21C (70F): 0 Boiling Point: No information found. Melting Point: 107 - 109C (225 - 228F) Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found.

10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hazardous Decomposition Products: Burning may produce carbon monoxide, carbon dioxide, nitrogen oxides. Hazardous Polymerization: Will not occur. Incompatibilities: Strong oxidizers. Conditions to Avoid: No information found. 11. Toxicological Information Oral rat LD50: 1700 mg/kg Investigated as a mutagen. Ingredient Category -----------------------------------4-Aminoantipyrine (83-07-8) ---NTP Carcinogen--Known Anticipated ----No ----------No IARC -----------None

12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information : Not regulated. 15. Regulatory Information

16. Other Information NFPA Ratings: Health: 1 Flammability: 1 Reactivity: 0 Label Hazard Warning: CAUTION! MAY BE HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Label Precautions: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing dust. Keep container closed. Use with adequate ventilation.

Label First Aid: If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Product Use: Laboratory Reagent.
DISCLAIMER: Qualigens Fine Chemicals (QFC) provides this information which is commonly known and generally available in respect of this product; but makes no representation as to its comprehensiveness or accuracy. This information is given only as a guide to the appropriate precautionary handling of the material by a trained person. Persons receiving the information must use their judgement in determining its appropriateness for a particular purpose. QFC makes no representations or warranties, either express or implied, including without limitations any warranties of merchantability, fitness for a particular purpose with respect to the information given herein or the product to which the information refers. Accordingly, QFC will not be responsible for damages resulting from use of or reliance upon this information.