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4. No.of molesFe = 2.80/56= 0.05mol mol Cl2 5. No.of moles = (0.05x3)12= 0.07Q cm3 / of 6. Vofume cl2 ; o.ozsx 24 = 1'8dm3 1,800

1 1 1 ...6

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11 (a) of ratioof the number atomsfor eacfielement the that Formula shorvs simplest 1"'1 in themmpound.

(b)

Element Mass(%) Number of moles Ratioof moles

c
92.3

7.7

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(c)

formula: CH Empirical RMMof(GH)n= 76 = 78 [12+1]n 13n = 78 n =6 : formula C5H5 Molecular Procedure: withsandpaper ribbon 1. Cleanmagnesium and 2. Weighcru-cible its lid with its lid and ribbonintothe cnrcible weighthe crucible 3. put iragnesium 4. Heatstronglythe cruciblewithoutib lid the startsto burnandlift/raise lid whenthe magnesium S. Coverthe &uciOle a litdeat intervals bumtcompletely the 6. Remove lid whenthe magnesium for the 7. Heatstrongly crucible a fanrminutes its 8. Coolandweighthe cnrciblewith lid andthe content g. Repeat pricessesof heating, untila constant and cooling weighing the massis obtained Recordall the mass 10. Results:

1 1...5

1 1 'l 1 1 1 1 1 1

1 1

Element Mass(g)
I

Mg y-x
.t-|

o
z-y
,-y

Nur Etno;6olformula: Mg"oo/MgO ratioof moles Simolest

a

-6
b

1 14... Max 12

(d)

oxide ftommagnesium copper separate - Cannot coPPer - Cannotweigh

I 1

Y:2.8.7 15 (a) (i) Atom Answer Chemistry Perfect Score Module 2009 *

Atom :2.8.8.1 Z 17 Group Because atomY has7 valence elecfron period3 Because atomY hasthreeshellsoccupied eledrons with (ia) 2Na+ Ye* 2NaY Conectformulaof reactants and productconed Balance equation Ye+2NaOH + NaY+NaOY+HzO Conectformulaof reactants and produc{s correc{ Balance equation 15 (b) lonicomoound/bond 1- Theeledron anangement atomP = 2, 8, 1 I 2.8. 1 ll of Theelectonanangement atomQ = 2, 8, 7 I 2.8.7 of 2- to achievethe stableeleclronanangement $ atomof P donates/ givesone eledronto the atomof Q to form P* // half equation 4 - atomof Q receives acceptsone elecfon ftom atomof P to form Q' / l/ hatfequation * 5 -the P ion and Q - ionsare atraded by a strong electrostatic forceto formionicbond. &withformula PQ/ coneddiagram Covalent comoound bond / 7-Theelectron arangement ofatom R = 2, 6 / 2. 6 &to acfiieve stableelecfon anangement the $[atom R and atomQ shareelectrons] . 10- atomR contributes eledronsandatomQ contributes 4 one eledron 11- one atomR and4 atomQ share4 pairsof eledrons 12-to formcovalent compound the formula with RQr/ diagram Max10

1 1 1 1 1....6

1 1...4

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AnswerChemistry PerfectScoreModule2009
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Numberof mole Thesimplest ratio

0.48t'12 ilo.M 0.04/0.01 il4

0.05/1 //0.05 0.05/0.01 il5

0.28t14 ilo.o2 0.020.01 il2

0.16/16

tn.o1

0.01/0.01 ll1

= formula CaH5N2O Empirical ]n [CrHsNzO = 194 [97]n=194 ll2 n= 19487 = Molecular formula CeHioNrOz (c) by of the Ableto calculate molarmassandthe percentage nitrogen massin eachof the threefeftilisersand cftoosethe best fertiliser. = sulphate 1329/mol 1 molarmassof ammonium ll in sulphate= 28l132x1OOo/o of 2 percentage nibogen ammonium 21.2o/o 3 molarmassof urea= 60 g/mol 4 percentage nitrogenin urea= 28/ 60 x 100%ll 46.70/0 of = 5 molarmassof hydrazine 329/mol =281132 100%ll 87.5o/o x of 6 percentage nitogenin hydrazine compares other with of has source nitrogen 7 Hydrazine the richest fertilizers. hydrazine cftoose 8 Thefarmershould

1 1 1 1 1.....8

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a.
13 (a) is is of number 11ll Number proton 11 1. Theproton is23llAtomicmassis 23 number 2. Nucleon = 12 = 3. Number nzutron 2.g-^11 of 12n 11p 4. Nucfeus contains and the circulating nucleus 5. Position electron of of shellconsists electron 6. Coned number any6 is 7. Symbol sodium Na of 1 1 1 1 1 1.....6

(b)

(i)

in of Formula showsimplest ratio number atomsof eachelement that compound 12n+2n+16n= 180 2. n =6 3. CoHrzOe

1 1
1 1 ....4

= 180 (iD 1. Refativemolecularmassforn(CHzO) ll

(c) (i)

FE Element 1. Mass/o 2.80 2. No.of moles 2.80/56= 0.05 = 3. Ratioof moles/ 0.05/0.05 1 ratio Simolest

cl
5.32 = 5.3235.5 0.15 = 0.15/0.05 3 1.,.4 1 1 1

= formula FeCls 4. Empirical

(ii)

1. Formula the reactants of of 2. Formula produc{s equdion 3. Balance //,./ ZFe+3Clz+2Fe0ls

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STRUCTURE PAPER3

An$rver Suqqested (a)0 s = 95.0' C, 30 s = 85.0' C,60 s = 82.0oC, = = 90s = 80.0' Q,120s 80.0' C,150s 80.0' C,
180 s = 78.O" C. 21Os:7O.0 '

(c) (i)&(ll) tScore3&31

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d(i)

Suoqested Answer Theconstant temperature whichliquidbecomes solid at a tiuooestedAnstver Theheatreleased whenthe particles the liquidarange in to formsolid balanced the heatlossto the sunoundinos. bv Suggested Ansrer The airtapped in the conical fiaskis a poormnductor of heat.Theair helped minimize to heatlossto the sunoundinqs.to ensure / uniform coolino.

3 3

d(ii)

3 3

Fuss$d 3ns4cr

(ii) Whitesolidis formed/The massof crucible and its contentincreases(b) The massof crucible and lid = 25.35g.

(i) Magnesium oxideis formed

(iD Magnesium reacts withoxygen

Themassof cnrcible, and magnesium lid g. ribbon=27.75 Themassof crucible, andmagnesium lid oxidewhencooled= 29.35g

(c) (i) ThemassofMg=(27.75-25.35)9=2AOg (iD Themass 02=(29.3$27.75\=1.69 g of (iiD Thenumber molesMg=0.1 of mole Thenumber moles = 0.1mole of O Theratioof Mg:O=1:1 The empirieal formulais MgO.
(d)

0.1 mde of Mgreaclswith0.1moleof O/1moleof Mg reacts with 1 moleof O Ableto predid themanipulated variable, responding the variableand the mndant variable completely. Manipulated variable : metals Group1 elements// of potassium. sodium, lithium, Responding variable: the reactivity fte reaction of with water// the speedof movement on trewater surtace Constant variable: sizer/mass metals. of Volume water of Ableto date howto controlthe manipulated variables conecily Repeat experiment usingthe metals sodium, the by of llthium potassium and Ableto $:ateconectlythewayto nntrol the manipulated variable To observe howfastthe metals moveon the surface of water; Ableto use lhe metalgranules with thesamesize Usethe metalgranules the samesize. with

l8 (a)

18 (b)

Ableto statetfie rela0bnsht:p betweenthe manipulated variableandtherespondingvariable conectly.. 18 (c)

18 (d)

suggested ansrirer: reactivity Group1 elements The goingdorn the group. of increases Ableto anangeconec{y the reactivtty seriesof the metalsaccording descending to order. potassium, Ansurec sodium,lithium Ableto classiff the ionscorrectly. of group.l and [to nameor wtte all the formula the ionscorectlyat the cations anions positive cation: sodium Answer: ion/ ion/ Na+,hydrogen H+ ion/ Negative ion/anion hydroxide OH: ion/

AnswerChemistry PerfectScoreModule2009
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