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Materials technology
Contents
Cementitious materials Concrete Aggregate 67 71 73
Cementitious materials
The national cement specication is a performancebased specication where the early and 28-day strength of the cement are dened. This has resulted in a signicantly more consistent product than previous specications enforced.
All common cement products produced and sold in South Africa are obliged by law to comply with SANS 50197-1:2000[1]. This assures the customer that: The performance of the cement is controlled That the product complies with the specied performance requirements An acceptable manufacturing quality control system is in place All cements produced by Holcim comply with SANS 50197-1:2000 and bear the SABS mark.
Composition, %
GGBS Clinker
20
100
CEM II B-M
CEM III A
Blastfurnace cement
65
CEM III B
80
CEM III C
11
Requirements for the composition, 28-day strength, rate of early strength gain and other physical and chemical properties are dened by the specication for each type and strength class of cement. The full description of the cement communicates the type and composition, 28-day strength class and rate of early strength gain of the cement to the user, eg.
CEM II A-M (S) 42,5 N
CEM IV A
35
CEM IV B
18 18
55
95
CEM V A
0 30 30 100
(Adapted from Memento Cement Beton[2]) In practice the quantities of GGBS (S), limestone (L) and y ash (V) are generally xed within the limits of the specication. Therefore the quantities of the mineral components do not vary signicantly between different batches of cement but tend to receive small adjustments over time to ensure consistency of performance.
Technological advances in the production of cement, such as admixtures, plant control systems and alternative fuels, have given the cement producer the exibility to use a wider range of mineral components, such as GGBS, y ash and limestone, and produce cement with better technically acceptable properties. However a specication was needed to standardise the performance of cement allowing for these innovations and technological advances.
Portland cement Portland GGBS, limestone, y ash or composite cement CEM III Blastfurnace cement CEM I V Pozzolanic cement CEM V Composite cement
Composition
The range of proportions of each constituent material is specied for each cement type eg. CEM II A-M (S) consists of clinker with 6 to 20% ground granulated blastfurnace slag (GGBS). Included in the range of permitted mineral components may be additional constituents of up to 5%. Figure 1 shows percentages of different mineral components permitted in each cement type.
Strength class
Cement is produced in three different strength classes, denoted by 32,5; 42,5 and 52,5 in the cement description. Standard strength tests are routinely conducted on mortar samples made with a standard sand and xed water:cement ratio, to dene and verify the performance of different strength classes of cement in terms of mortar strength (see Figure 2), setting time and expansion (soundness). The cement in each strength class must meet the requirements given in Table 1. Figure 2: Mortar prism
Rapid Hard Cement requires a higher mortar prism compressive strength at 2 days (see Table 1 and Figure 3). Figure 3: Rate of strength gain for Normal and Rapid cements
In spec Out of spec
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Chemical requirements
Table 2: Chemical requirements for cements in general use in South Africa
Property Cement type Strength class 32,5 N Sulphate content CEM I CEM II 42,5 N 52,5 N 52,5 R All classes All classes All classes All classes 3% 5% 0,10% 42,5 R 32,5 R Requirements
3,5%
(expressed as SO3)
CEM V
4%
CEM III Loss on ignition Insoluble residue Chloride content CEM I CEM I CEM III CEM III All types
Compressive mortar strength, MPa Strength class 2 day 32,5 N 32,5 R 42,5 N 42,5 R 52,5 N 52,5 R 10 10 20 20 30
Early 7 day 16
Standard 28 day 32,5 32,5 42,5 42,5 52,5 52,5 62,5 62,5 52,5 52,5
75 75 60 60 45
10 10 10 10 10 10
Note: Cement type CEM III may contain more than 0,10% chloride but in that case the maximum chloride content must be stated on the packaging and/ or the delivery note.
Early strength
The sufx N or R at the end of the description of a cement type indicates rate of early strength gain: Normal or Rapid.
The proportions of different mineral components impart different properties to the cements and consequently to the concrete (or other applications) made with these cements.
In addition, prior to specifying any cement and entering into contractual negotiations, on-site trials using the specied aggregate and admixtures must be carried out to verify that the actual concrete, mortar or plaster made with the cement performs in practice. Our sales consultants can advise you, and will arrange to supply samples of the cements available in the different geographical areas.
Where sulphate attack, chloride ingress, permeability or alkali aggregate reaction are of concern, the use of composite cement containing GGBS or y ash is recommended. See also Compressive strength, p141 and Durability, p160.
It has been proven that with the correct concrete mix proportions, an early or 28-day specied strength can be achieved with any cement type, depending on w:c ratio, see Figure 4. See also strength gain curves, p144. Figure 4. Same nal concrete strength, different cements
35 30 25 20 15 10
MPa
CEM V A(S-V) 32,5 N; w:c ratio = 0,67 CEM II A-M(V) 42,5 N; w:c ratio = 0,67 CEM II A-L 32,5 N; w:c ratio = 0,67 CEM II A-M(S) 42,5 N; w:c ratio = 0,83
Cement with extended setting times, such as a mineral component cement in the 32,5 strength class, is more suitable for soil stabilisation applications because of the longer working times required to place and compact the material. The selection of a cement type and content is based on laboratory testing with the granular materials and two to three cement types available in the area of construction. See Stabilisation, p117 for detailed recommendations.
Days
28
We recently conducted a test programme to assess the performance of different cement types and plaster sands. The test programme consisted of plastering 3 m-wide panels of a 120 m-long wall with 14 types of cement, and sand from two different sources, and assessing surface nish, drying shrinkage cracking and strength at 14 and 28 days.
When selecting the most advantageous cementitious product for a specic application, the specier, engineer or architect should: Understand what SANS 50197-1:2000[1] means in terms of specied physical requirements in the nal product. Understand how these properties affect the properties of the fresh and hardened concrete (or other product) required for the project. Apply this knowledge to the cements available from specic producers and suppliers in different geographical areas. Factor in additional savings gained by using alternative cement and/or aggregate types, or using chemical admixtures.
However, economics and logistics govern the selection of the cement type. Any special requirements such as early strength or durability must be indicated in the specication to ensure that the mix design takes these requirements into account. The early rate of strength gain varies with different types of cement. If early strength is of importance, eg. for early stripping of formwork or precast moulds, the concrete specication must indicate a minimum early strength gain requirement, eg. 18 MPa at three days. Specifying concrete to achieve long-term durability in aggressive environments, eg. marine wharfs, requires special attention in the mix design.
The results of this project indicated that the quality of the plaster is far more dependent on the quality of the sand, and the type of mixing (hand vs machine mixing) than on the cement type. In general, All Purpose Cement gave high quality, workable plaster with excellent nishability when used with the plaster sands evaluated. In general, Holcim All Purpose Cement is recommended for all general construction work including foundations, slabs or oors on the ground, mortar and plaster, and also for mass concrete elements. In addition, this cement is highly recommended for soil stabilisation of sub-bases and base courses of asphalt or concrete-surfaced roads.
Holcim High Strength Cement should be specied for industrial oors on the ground, columns and suspended slabs, especially in high-rise buildings, factories, warehouses, and shopping centres, and for pre-cast concrete elements. Holcim Rapid Hard Cement is particularly useful where very high early strengths are required, eg. in pre-cast work. See also Applications, p109.
Concrete
The quality of readymix concrete is controlled by compliance with SANS 878:2004[3]. The quality of both product and service is controlled by compliance with ISO 9001:2000[4]. All Holcim Readymix plants are certied as ISO 9001:2000 compliant. Holcim Readymix is a member of SARMA, the South African Readymix Association. One of the requirements for SARMA membership is veried compliance with SANS 878:2004. See Useful references, p185. In order to comply with the above specications, Holcim Readymix ensures that the following factors are in place.
Cementitious materials are batched cumulatively by mass to within 2% Aggregate is batched to within 3% Admixtures are batched to within 2% or 50 ml Water is batched to within 2%
Batching tolerances
Contract
Types of concrete mixes, whether designed, prescribed, or designed with special requirements (such as minimum cement content or maximum water:cement ratio) together with the minimum required information are supplied by both purchaser and supplier to ensure that quotations accurately reect requirements.
Materials
Solid materials are batched by mass, liquids by mass or volume Appropriate adjustments are made for moisture in aggregate Control of water is done by measurement and maintenance of slump within specied tolerances Concrete is delivered with sufcient workability for placement and compaction
Cementitious materials used comply with SANS 50197-1:2000[1] Mineral components - y ash, silica fume and GGBS - comply with SANS 1491:2005[5] Aggregate complies with SANS 1083:2002[6], or has a proven record of satisfactory use in concrete Chemical admixtures comply with International standards Water is tested if the quality is in doubt. Where wash-out water is used in concrete to minimise disposal problems and thus reduce impact on the environment, density is closely monitored to restrict solids content.
Sampling and testing are carried out strictly in accordance with standard test methods for: Sampling freshly mixed concrete[7] Making and curing test specimens[8] Consistence of freshly-mixed concrete Slump[9] Compressive strength of concrete[10]
Storage of raw materials is designed to minimise segregation, contamination or deterioration Weighing equipment is regularly calibrated and checked, and monitoring devices are clearly visible to the operator Mixers, whether stationary or truck mounted, are kept in good repair and are able to fully mix concrete within the required time
Tolerances in slump
Concrete should be within the specied range for a period of 30 minutes from arrival on site. Table 3: Tolerances
Specied slump 50 mm and less 50 to 100 mm >100 mm Standards and specications Tolerance - 15 to + 25 mm 25 mm 40 mm
In the event of acceptance control values not being met, SANS 878:2004[3] and SANS 10100-2:1992 (amended 1994)[11] specify the procedure for taking and analyzing core test results.
Admixtures
In 2002, the European Committee for Standardisation (CEN) issued EN 934-2 2000[12]. Part 2 relates to concrete admixtures, denitions and requirements. American Society for Testing and Materials, ASTM C 494/C 494 M-1992[13], ASTM C 494 C 1017/1017 M-98[14] and American Cement Institute, ACI 212-4 R-93[15] cover the use of superplasticisers in concrete in America. The new Japanese Industrial Standard for Superplasticisers is JIS A 6204[16], issued in 1995. See also Production of concrete, p83 and Handling concrete, p98.
Compressive strength
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Process control testing is carried out by Holcim Readymix laboratories for their own quality control purposes to ensure that: No individual result falls below the characteristic strength minus 3 MPa, and The average of 30 valid cube results exceeds the specied strength by at least 1,64 times the current standard deviation Acceptance control is carried out by the customer on site to verify process control, and to ensure that: No individual result falls below the characteristic strength minus 3 MPa, and The average of three consecutive and overlapping results are at least equal to the specied strength plus 2 MPa
Aggregate
Aggregate products should comply with the following specications: SANS 1083:2002[6] (coarse and ne aggregate for concrete) SANS 1090:2002[17] (ne aggregate for mortar and plaster) SANS 1200-M:1982[18] and COLTO, 1998[19]* (for roadstone, base, subbase and pavement layers
Table 6 gives the specied requirements for sands used in the production of mortars and plasters. Table 6: Requirements for mortar and plaster sand[17]
Property Grading limits, % (m/m) passing sieve sizes, mm 4,750 2,360 1,180 0,600 0,300 0,15000 Dust content,** % (m/m) max Methylene blue adsorption value Clay content,*** max Drying shrinkage of mix, %, max 0,10 SABS requirements Plaster Mortar
Table 4 gives the specied requirements for coarse aggregate (stone) used in the production of both readymix and site-batched concrete. Table 4: Requirements for coarse aggregate[6]
Property Grading limits, % (m/m) passing sieve sizes, mm Requirements Nominal aggregate size, mm 75,0 53,0 37,5 26,5 19,0 13,2 9,5 6,7
12,5
0,12
75,0 100 100 53,0 0 - 50 85 - 100 100 37,5 0 - 25 0 - 50 85 - 100 100 26,5 0 -5 0 - 25 0 - 50 85 - 100 100 19,0 0 -5 0 - 25 0 - 50 85 - 100 100 13,2 0 - 25 0 - 50 85 - 100 100 0 -5 9,5 0 - 25 0 - 55 85 - 100 100 0 -5 6,7 0 -5 0 - 25 0 - 55 85 - 100 4,75 0 -5 0 - 25 0 - 55 2,36 0 -5 0 - 25 1 ,18 0 -5 Dust content**, 2,0 % (m/m), max 35
110 for aggregates used in concrete subject to surface abrasion, and for structural elements of reinforced concrete and prestressed concrete 70 for aggregates used in concrete not subject to surface abrasion
If the sand complies with the requirements for methylene blue adsorption or clay content, the limits for dust content may be increased to 12,5% for plaster and 17,5% for mortar sands.
Note: If the dust content exceeds the limits, carry out a methylene blue adsorption test. determine the clay content. the sand.
If the adsorption value exceeds the limits, If the clay content exceeds the limits, reject For mild exposure conditions or if the sand has been used safely in the past, drying shrinkage limits may be increased to 0,12% for plaster and 0,14% for mortar sands. The strength of mortar or plaster may be affected by: Solid deleterious impurities. The strength of mortar specimens should be at least 85% of the strength of washed sand mortar specimens. Organic impurities. The colour of the liquid above the sand should not be darker than the reference sample, except where requirements for solid deleterious impurities have been met.
* ASPASA / COLTO exclusion clauses, p54 to 55. ** Material passing 0,075 mm sieve *** Material smaller than 5 m
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Table 5 gives the specied requirements for ne aggregate (sand) used in the production of both readymix and site-batched concrete. Table 5: Requirements for ne aggregate[17]
Property Grading limits, % (m/m) passing sieve sizes, mm 4,75 0,1 50 Methylene blue absorption value, max Clay content*** , % m/m, max Dust content**, % m/m, max Fineness modulus 5 1,2 - 3,5 Requirements Natural sand 90 - 100 5 - 25 0,7 2,0 10 Crushed sand
Material specications require that aggregate for crushed-stone base or subbase is derived from hard, sound and durable rock. Table 7: G1 to G7 classication[19]
Use Material
G1
Base and subbase
G2 G3 G4 G5
Pavement layers
Uncrushed: 63 Crushed: 53 Uncrushed: 2/3 of compacted layer thickness Crushed: 75 Uncrushed: 2/3 of compacted layer thickness
Natural materials
G6
G7
N/A
Aggregate for G5 to G7 materials Gradings on these materials are mainly determined by a grading modulus as prescibed by COLTO.* Hardness Table 10: 10% FACT (ne aggregate crushing value)[19]
Rock type Matrix Non-siliceous cementing material Siliceous cementing material Dry, min 140 kN Wet, min Wet/dry relationship, min 75%
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Holcim aggregate complies with the following specications except where amended by ASPASA*. Requirements for approved target grading and tolerances For base and subbase, the mean grading (a minimum of six results) of the trial section (prior to compaction) meeting the grading limits and the requirements for approved target grading is determined. A smooth grading curve is then classied as the approved target grading for a specic project. All future gradings are evaluated against the target grading in accordance with specied tolerances. Table 8: Grading tolerances for G1 to G3 materials[19]
Property Grading limits, % (m/m) passing sieve sizes, mm 53,0 37,5 26,5 19,0 13,2 4,75 2,00 0,425 0,075 100 84 - 94 71 - 84 59 - 75 36 - 53 23 - 40 11 - 24 4 - 12 100 85 - 95 71 - 84 42 - 60 27 - 45 13 - 27 5 - 12 37,5 mm G1 - G3 Requirements 26,5 mm G3
75% 70%
75%
Hardness When tested in accordance with TMH1 method B1, the aggregate crushing value must not exceed 21 and when tested in accordance with TMH1 method B2 the 10% FACT value (dry) must be at least 210 kN. The wet:dry ratio should be at least 75%. The polished stone value (PSV) should be at least 50 unless otherwise specied or approved by the engineer. Shape The maximum akiness index, when tested in accordance with TMH1 method B3, should comply with the following requirement. Table 15: Flakiness index[19]
Nominal size of aggregate, mm 19,0 13,2 9,5 6,7 Flakiness index,% max Grade 1 25 25 30 30 Grade 2 and 3 30 30 35 35
Aggregate for surfacing should comply with the following requirements. Table 14: Properties and requirements for singlesized crushed aggregate grades 1, 2 and 3[19]
Property Grading limits, % (m/m) passing sieve sizes, mm 37,50 26,50 19,00 13,20 9,50 6,50 4,7 5 3,3 5 2,36 Grade
26,5 19,0
If required for special purposes, the average least dimension (ALD) should be indicated in the project specications. Sand grading limits and sand equivalent for sand for slurry Sand for slurry should be an approved crusher sand obtained from parent rock with an aggregate crushing value not exceeding 30 or a mixture of crusher sand and clean natural sand, where the mixture does not contain more than 25% of natural sand. The sand should be clean, tough, durable and angular in shape.
- 100 -1 -1 -1 -1 100 0 -1 0 -1 85 - 100 100 85 - 100 100 -1 0 - 30*1 10 - 5**1 0 - 30* 85 - 100 100 0 - 5** 0 - 30* 85 - 100 100 0 -1 -1 -1 0 - 301 0 - 5** 0 - 5 0 - 100 -1 -1
Fines content: Grade 1 Material passing Grade 2 a 0,425 mm sieve (max) Dust content: Grade 1 Material passing Grade 2 a 0,075 mm sieve (max)
Grade 3 exceptions: * 0 - 50 ** 0 - 1 0 0,5 1,5 N/A N/A 0,5 N/A 0,5 1,5 N/A N/A 0,5 N/A
Grading shall comply with the requirements for grades 1 and 2 with the following
Grade 3
Grade 3
Coarse aggregate for asphalt should comply with SANS 1083:2002 and ne aggregate should comply with SANS 1090:1994. Table 13 gives additional requirements for rolled-in chips.
Table 16: Grading and sand equivalent for ne aggregate for slurry seals[17, 19]
Property Grading limits, % (m/m) passing sieve sizes, mm 13,2 9,5 6,7 4,7 5 2,36 1 ,1 8 0,600 0,300 0,1 00 0,075 Fine slurry
Fine grade Medium grade Coarse grade
100 90 - 100 65 - 95 42 - 72 23 - 48 10 - 27 04 - 12
100 82 - 100 70 - 90 45 - 70 25 - 45 15 - 30 0 10 - 20 06 - 15 4 - 10
For stabilised material: Use the material if the pH is 6,0, the EC is < 0,02 Sm-1 and sulphates are not a problem. If not, analyse the material in accordance with the customers instructions, and submit proposals for use to the customer for approval. Where the salinity of water added for compaction causes the salinity of the material to increase, determine soluble salinity within 24 hours of compaction, before prime coat is applied.
Sand seal
Fine aggregate must comply with project specications and may be crusher sand complying with COLTO, or natural sand. The sand equivalent should be at least 35.
To assist in selecting aggregate for specic applications and ensure that the material complies with specied requirements, other tests may be carried out. See Table 17 for appropriate titles and standard test method numbers.
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5836:2002 5837:2002 5838:1976 5839:2002 5840:2002 5841:1994 5842:1994 5843:2002 5844:1994 5845:1994 5846:1976 5847:2002 5848:2002 5849:2002 5850-2:2002
Plastic limit and plasticity index of nes in aggregates for base-courses Linear shrinkage of nes in aggregates for base-courses pH Value of nes in aggregates for base-courses Concrete tests - Initial drying shrinkage and wetting expansion of concrete Aggregate impact value of coarse aggregate Electric conductivity of ne aggregate Particle size distribution of material of diameter smaller than 75 m in ne aggregate (Hydrometer method) Acid insolubility of aggregates Deleterious clay content of the nes in aggregate (methylene blue adsorption indicator test) Particles of diameter not exceeding 20 m and not exceeding 5 m and smaller, respectively, in ne aggregate (pipette method) Potential reactivity of aggregates with alkalis (accelerated mortar prism method) Treton impact value of aggregates
References
1. SANS 50197-1:2000, Cement Part 1: Composition, specications and conformity criteria for common cements, Pretoria: South African Bureau of Standards, 2000. 2. Huberty, JM. (ed), Memento Cement Beton, Brussels: Latteur, Federatie van de Belgische Cementnijwerheid. 3. SANS 878:2004, Ready-mixed concrete, Pretoria: South African Bureau of Standards, 2003. 4. ISO 9001:2000, Quality management systems - Requirements, Pretoria: South African Bureau of Standards, 2000. 5. SANS 1491:2005, Portland cement extenders. Part 1: Ground granulated blastfurnace slag, Part 2: Fly ash, Part 3: Condensed silica fume, Pretoria: South African Bureau of Standards, 1989. 6. SANS 1083:2002, Aggregates from natural sources - Aggregates for concrete, Pretoria: South African Bureau of Standards, 2002. 7. SANS 5861-2:1994, Concrete tests - Sampling of freshly mixed concrete, 1st rev, Pretoria: South African Bureau of Standards, 1994. 8. SANS 5861-3:1994, Concrete tests - Making and curing of test specimens, 1st rev, Pretoria: South African Bureau of Standards, 1994. 9. SANS 5862:1994, Concrete tests - Consistence of freshly mixed concrete. Part 1: Slump test, Part 2: Flow test, Part 3: Vebe test, Part 4: Compacting factor and compaction index, Pretoria: South African Bureau of Standards, 1994. 10. SANS 5863:1994, Concrete tests - Compressive strength of hardened concrete, 1st rev, Pretoria: South African Bureau of Standards, 1994. 11. SANS 10100-2:1992 (amended 1994), The structural use of concrete Part 2: Materials and execution of work, Pretoria: South African Bureau of Standards, 1994. 12. EN 934-2 2000, Standards for admixtures for concrete, mortar and aggregate, Brussels: European Committee for Standardisation, 2002. 13. ASTM C 494/C 494 M-1992, Chemical admixtures for concrete, West Conshohoken: American Society for Testing and Materials, 1992. 14. ASTM C 494 C 1017/1017 M-98, Chemical admixtures for use in owing concrete, West Conshohoken: American Society for Testing and Materials, 1998. 15. ACI 212-4 R-93, Guide for the use of High-range admixtures or superplasticisers in concrete, Michigan: American Cement Institute , 1993. 16. JIS A 6204, Superplasticisers, Tokyo, Japanese Standards Association, 1995. 17. SANS 1090:2002, Aggregates from natural sources - Fine aggregates for plaster and mortar, Pretoria: South African Bureau of Standards, 2002. 18. SANS 1200-M:1982, Standardised specication for civil engineering construction. Section M: Roads (general), Pretoria: South African Bureau of Standards, 1982. 19. COLTO Standard Specications for Road and Bridgeworks for State Road Authorities, Johannesburg: 1998.