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MATERIAL SAFETY DATA SHEET

Penetone Corporation, 700 Gotham Parkway, Carlstadt, NJ 07072

PENETONE 1112A

Page: 1 of 4 Date Prepared: December 26, 2007 MSD S No.: 4345-712R

SECTION 1 PRODUCT IDENTIFICATION & EMERGENCY INFORMATION


PRODUCT NAME: PEN ETO NE 1112A GENERAL USE: Carbon removal compound PRODUCT DESCRIPTION: Liquid alkaline cleaner GENERIC INGREDIENTS: W ater, glycol ethers, alkanolamine, surfactant EMERGENCY TELEPHONE NUMBERS: PENETONE 201-567-3000 CHEMTREC 800-424-9300

SECTION 2 HAZARDOUS INGREDIENT SECTION


This product is hazardous as defined in 29 CFR 1910.1200. OSHA HAZARD: CORROSIVE O S HA HA Z AR D OU S IN G R ED IE NT S E X P O S U R E L IM IT S 8 hr s. T W A ( pp m ) OS HA P EL ACG IH TLV Su pplier 3 25 (skin) 3 25 (skin) -----

CAS # Monoethanolamine Eth ylene glycol m onobu tyl ether 141-43-5 111-76-2

SECTION 3 HEALTH INFORMATION & PROTECTION


EMERGENCY OVERVIEW: Clear liquid with glycol ether odor. Can be corrosive to eyes and skin. POTENTIAL HEALTH EFFECTS: EYE CONTACT:
Corrosive to eyes.

SKIN CONTACT:
Frequent or prolonged contact may cause dryness and burns to the skin and may aggravate an existing dermatitis condition.

INHALATION:
Inhalation of s pray m ist m ay caus e irritation or burn s to the r esp iratory tract, head ach es, and naus ea.

INGESTION:
Inges tion may c aus e irritation or burn s to the d igestive trac t.

PENETONE 1112A

Page: 2 of 4 Date Prepared: December 26, 2007 MSD S No.: 4345-712R

CHRONIC:
Inges tion of large am ounts of ethan olamine h as c aus ed kidn ey and liver dam age in anim als. E thylene glycol m onobu tyl ether has produced damage to red blood cells by inhalation, skin adsorption, and ingestion in lab animals. Kidney and liver damage has res ulted f rom ing estion. R epeated ing estion has caus ed testic ular atrop hy b y ing estion only.

FIRST AID MEASURES: EYE CONTACT:


Flu sh eyes with larg e am oun ts of w ater. Se e ph ysic ian im mediately.

SKIN CONTACT:
Flus h s kin with large am ounts of water. R emove c ontam inated c lothing an d laund er before r eus e. If sk in irritation develops or persists, consult physician.

INHALATION:
R em ove pe rs on to fr esh air . A dm inis ter oxyg en or artif icial res piration as need ed. C all a phys ician im mediately.

INGESTION:
If s wallo wed , give plen ty of water. D O N O T IN D U C E VO MIT IN G . C all a phys ician im mediately.

WORKPLACE EXPOSURE CONTROLS: PERSONAL PROTECTION:


Saf ety glass es are rec omm ended for all workp lace c onditions . Ru bber g loves are recom men ded es pec ially where prolong ed skin exposure is expected.

VENTILATION:
Adequate ventilation to accommodate TLV limits. For enclosed areas, or where large amounts of the product are being used, the u se of fan s or other me ch anic al ventilation is rec om mended. O rgan ic vap or res pirator s m us t be u sed if th e T LV is exceeded.

SECTION 4 FIRE & EXPLOSION HAZARDS


FLASH POINT: N on e to b oilin g p oin t ( T CC , C O C ) FLAMMABLE LIMITS: Not d etermin ed AUTOIGNITION TEMPERATURE: Not d etermin ed GENERAL HAZARD:
T his is a water bas ed prod uc t and p resen ts n o unu su al hazards in a fire.

FIRE FIGHTING:
Cool containers with water.

HAZARDOUS COMBUSTION PRODUCTS:


Smoke, fumes, and oxides of carbon and nitrogen.

SECTION 5 SPILL CONTROL MEASURES


LAND SPILL:
For s mall s pills, us e absor bent m aterial suc h as towels or ab sorb ent pow ders . Pu t all material into proper w aste dis pos al container with lid tightly covered. For larger spills, dike spill, recover free liquid, and use absorbent material to dry area. Rinse area with water. Put all material into appropriate waste containers.

WATER SPILL:
Prod uc t is water b ased and w ater dilutable. S urf actants us ed in this produ ct are b iodegrad able. Loc alized high con cen tration of produ ct m ay caus e fish kills, bu t no pers istent or lon g term effec ts w ill result. C hec k with loc al environm ental regulatory agen cies for reporting requirements.

PENETONE 1112A

Page: 3 of 4 Date Prepared: December 26, 2007 MSD S No.: 4345-712R

SECTION 6 HANDLING & STORAGE


STORAGE TEMPERATURE, oF: GENERAL:
ambient. DO NO T ST OR E ABO VE 120 o F . K E EP FR O M FR E EZ IN G .

Do not store near strong acids and oxidizers.

SECTION 7 TYPICAL PHYSICAL & CHEMICAL PROPERTIES


BOILING POINT, oF:
about 212

VAPOR PRESSURE, mm Hg AT oF:


equal to water

EVAPORATION RATE:
equal to water

VAPOR DENSITY (Air = 1):


equal to water

SOLUBILITY IN WATER:
solu ble

WT % ORGANIC VOLATILES:
about 45

SPECIFIC GRAVITY at 75oF:


0.991

pH:
12.2

ODOR AND APPEARANCE:


clear liquid , glycol ether od or

SECTION 8 REACTIVITY DATA


GENERAL:
Th is product is stable and hazardous polymerization will not occur.

INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID:


Strong acids and oxidizers.

SECTION 9 REGULATORY INFORMATION


DEPARTMENT OF TRANSPORTATION (DOT): PROPER SHIPPING NAME:
CO RR O SIV E L IQ UID , BA SIC , O RG AN IC, N .O .S., (con tains eth anolamin e)

HAZARD CLASS: 8 IDENTIFICATION NUMBER: LABEL: CORRO SIVE FLASH POINT: TSCA:
none

PACKING GROUP: III


UN 3267

pH:

12.2

T he in gredients in th is p rod uc t are lis ted on th e T SC A inven tory.

CERCLA:
T his p roduc t con tains n o reportable C ER CL A m aterials. C ontact loc al authorities to d etermin e if there m ay be other local reporting requirements.

RCRA HAZARD CLASS:


D 00 2 C orro sive

PENETONE 1112A

Page: 4 of 4 Date Prepared: December 26, 2007 MSD S No.: 4345-712R

SARA TITLE III: 311/312 HAZARD CATEGORIES:


Ac ute health, C hronic health

313 REPORTABLE INGREDIENTS:


Eth ylene glycol m onobu tyl ether Dieth ylene glycol m onom ethyl ether Dieth ylene glycol m onobu tyl ether CA S# 11 1-76-2 CA S# 11 1-77-3 CAS # 112-34-5 <10 wt% <5 w t% <5 w t%

NEW JERSEY RIGHT-TO-KNOW INFORMATION:


This product contains water (CAS# 7732-18-5), monoethanolamine (CAS# 141-43-5), ethylene glycol monobutyl ether (CAS# 111-76-2), diethylene glycol monomethyl ether (CAS # 111-77-3 ), and diethylene glycol monobutyl ether (CA S# 11 2-34-5).

CALIFORNIA PROPOSITION 65 INFORMATION:


T his p roduc t does n ot contain any ch emic als rec ognized by the s tate of C alifornia to cau se c anc er and/or b irth def ects or r ep rod uc tive h ar m .

SCAQMD INFORMATION:
Is there a photochemically reactive material present? No W hat is the % by volume of photochemically reactive material? 0 W hat is th e VO C c ontent? 400 g/l W h at is th e vap or pr es s ur e of V O C 's ? <1 m m H g

SECTION 10 NOTES
HAZARD RATING SYSTEMS:
H E AL T H F LA M MA B IL IT Y R E AC T IV IT Y HM IS 2 0 0 NFPA 2 0 0 KEY 4 = Severe 3 = Serious 2 = M oderate 1 = Slight 0 = M inimal

REVISION SUMMARY:
Change in Section 9

SUPERSEDES ISSUE DATE:


February 24, 2004

FOR ADDITIONAL PRODUCT INFORMATION, CONTACT YOUR SALES ENGINEER FOR ADDITIONAL HEALTH/SAFETY INFORMATION, CALL 201-567-3000 THE INFORMATION PRESENTED HEREIN HAS BEEN COMPILED FROM SOURCES CONSIDERED TO BE DEPENDABLE AND ACCURATE TO THE BEST OF PENETONE'S KNOW LEDGE. THE INFORMATION RELATES TO THIS SPECIFIC MATERIAL. IT MAY NOT BE VALID FOR THIS MATERIAL IF USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY ONESELF AS TO THE SUITABILITY AND COMPLETENESS OF THIS INFORMATION FOR HIS OWN PARTICULAR USE.

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